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Sodium carbonate

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Sodium carbonate (also known as washing soda , soda ash and soda crystals ) is the inorganic compound with the formula Na 2 CO 3 and its various hydrates . All forms are white, odourless, water-soluble salts that yield alkaline solutions in water. Historically, it was extracted from the ashes of plants grown in sodium-rich soils, and because the ashes of these sodium-rich plants were noticeably different from ashes of wood (once used to produce potash ), sodium carbonate became known as "soda ash". It is produced in large quantities from sodium chloride and limestone by the Solvay process , as well as by carbonating sodium hydroxide which is made using the chloralkali process .

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91-574: Sodium carbonate is obtained as three hydrates and as the anhydrous salt: The decahydrate is formed from water solutions crystallizing in the temperature range −2.1 to +32.0 °C, the heptahydrate in the narrow range 32.0 to 35.4 °C and above this temperature the monohydrate forms. In dry air the decahydrate and heptahydrate lose water to give the monohydrate. Other hydrates have been reported, e.g. with 2.5 units of water per sodium carbonate unit ("Penta hemihydrate"). Sodium carbonate decahydrate (Na 2 CO 3 ·10H 2 O), also known as washing soda,

182-508: A diner . Teishoku means a meal of fixed menu (for example, grilled fish with rice and soup), a dinner à prix fixe served at shokudō ( 食堂 , "dining hall") or ryōriten ( 料理店 , "restaurant") , which is somewhat vague ( shokudō can mean a diner-type restaurant or a corporate lunch hall); writer on Japanese popular culture Ishikawa Hiroyoshi defines it as fare served at teishoku dining halls ( 定食食堂 , teishoku-shokudō ) , and comparable diner-like establishments. Emphasis

273-449: A food additive ( European Food Safety Authority number E500) as an acidity regulator, anticaking agent , raising agent , and stabilizer. It is also used in the production of snus to stabilize the pH of the final product. While it is less likely to cause chemical burns than lye, care must still be taken when working with sodium carbonate in the kitchen, as it is corrosive to aluminum cookware, utensils, and foil. Sodium carbonate

364-418: A 2007 survey showed that 70% of Japanese still eat it once or twice a day, its popularity is now declining. In the 20th century there has been a shift in dietary habits, with an increasing number of people choosing wheat-based products (such as bread and noodles) over rice. Japanese rice is short-grained and becomes sticky when cooked. Most rice is sold as hakumai (白米, "white rice"), with the outer portion of

455-409: A browning as lye, but is much safer and easier to work with. Sodium carbonate is used in the production of sherbet powder. The cooling and fizzing sensation results from the endothermic reaction between sodium carbonate and a weak acid, commonly citric acid , releasing carbon dioxide gas, which occurs when the sherbet is moistened by saliva. Sodium carbonate also finds use in the food industry as

546-522: A favourable pH as a float conditioner besides CaO and other mildly basic compounds. Sodium bicarbonate (NaHCO 3 ) or baking soda, also a component in fire extinguishers, is often generated from sodium carbonate. Although NaHCO 3 is itself an intermediate product of the Solvay process, the heating needed to remove the ammonia that contaminates it decomposes some NaHCO 3 , making it more economical to react finished Na 2 CO 3 with CO 2 : In

637-402: A form of clathrate . An important example is methane hydrate (also known as gas hydrate, methane clathrate, etc.). Nonpolar molecules such as methane can form clathrate hydrates with water, especially under high pressure. Although there is no hydrogen bonding between water and guest molecules when methane is the guest molecule of the clathrate, guest–host hydrogen bonding often forms when

728-413: A gathering of composers of haiku or renga , and the simplified version of the honzen dishes served at the poem parties became kaiseki ryōri . However, the meaning of kaiseki ryōri degenerated to become just another term for a sumptuous carousing banquet, or shuen ( 酒宴 ) . The traditional Japanese table setting has varied considerably over the centuries, depending primarily on

819-404: A low integer , though it is possible for fractional values to occur. For example, in a monohydrate n  = 1, and in a hexahydrate n  = 6. Numerical prefixes mostly of Greek origin are: A hydrate that has lost water is referred to as an anhydride ; the remaining water, if any exists, can only be removed with very strong heating. A substance that does not contain any water

910-420: A main dish has been cooked, spices such as minced ginger and various pungent herbs may be added as a garnish, called tsuma . Finally, a dish may be garnished with minced seaweed in the form of crumpled nori or flakes of aonori . Inedible garnishes are featured in dishes to reflect a holiday or the season. Generally these include inedible leaves, flowers native to Japan or with a long history of being grown in

1001-456: A minimalist amount. In the absence of meat, fish was served as the main protein, as Japan is an island nation. Fish has influenced many iconic Japanese dishes today. In the 9th century, grilled fish and sliced raw fish were widely popular. Japanese people who could afford it would eat fish at every meal; others would have to make do without animal protein for many of their meals. In traditional Japanese cuisine, oil and fat are usually avoided within

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1092-430: A related reaction, sodium carbonate is used to make sodium bisulfite (NaHSO 3 ), which is used for the "sulfite" method of separating lignin from cellulose. This reaction is exploited for removing sulfur dioxide from flue gases in power stations: This application has become more common, especially where stations have to meet stringent emission controls. Sodium carbonate is used by the cotton industry to neutralize

1183-663: A solution of alkaline salts used to give Japanese ramen noodles their characteristic flavour and chewy texture; a similar solution is used in Chinese cuisine to make lamian , for similar reasons. Cantonese bakers similarly use sodium carbonate as a substitute for lye-water to give moon cakes their characteristic texture and improve browning. In German cuisine (and Central European cuisine more broadly), breads such as pretzels and lye rolls traditionally treated with lye to improve browning can be treated instead with sodium carbonate; sodium carbonate does not produce quite as strong

1274-569: A standalone, and usually not with a side dish, in terms of general custom. It may have toppings, but they are called gu ( 具 ) . The fried battered shrimp tempura sitting in a bowl of tempura-soba would be referred to as "the shrimp" or "the tempura", and not so much be referred to as a topping ( gu ). The identical toppings, if served as a dish to be eaten with plain white rice could be called okazu , so these terms are context-sensitive. Some noodle dishes derive their name from Japanese folklore, such as kitsune and tanuki , reflecting dishes in which

1365-409: A traditional tatami room, sitting upright on the floor is common. In a casual setting, men usually sit with their feet crossed and women sit with both legs to one side. Only men are supposed to sit cross-legged. The formal way of sitting for both sexes is a kneeling style known as seiza . To sit in a seiza position, one kneels on the floor with legs folded under the thighs and the buttocks resting on

1456-520: A very popular flavor. Almost all manufacturers produce a version of it. Kakigōri is a shaved ice dessert flavored with syrup or condensed milk. It is usually sold and eaten at summer festivals. A dessert very popular amongst children in Japan is dorayaki . They are sweet pancakes filled with a sweet red bean paste. They are mostly eaten at room temperature but are also considered very delicious hot. Green tea may be served with most Japanese dishes. It

1547-460: Is goma-ae ( 胡麻和え ) where usually vegetables such as green beans are tossed with white or black sesame seeds ground in a suribachi mortar bowl, flavored additionally with sugar and soy sauce. Shira-ae ( 白和え ) adds tofu (bean curd) in the mix. An aemono is tossed with vinegar-white miso mix and uses wakegi scallion and baka-gai ( バカガイ / 馬鹿貝 , a trough shell , Mactra chinensis ) as standard. Rice has historically been

1638-489: Is a stronger base than baking soda ( sodium bicarbonate ) but weaker than lye (which may refer to sodium hydroxide or, less commonly, potassium hydroxide ). Alkalinity affects gluten production in kneaded doughs, and also improves browning by reducing the temperature at which the Maillard reaction occurs. To take advantage of the former effect, sodium carbonate is therefore one of the components of kansui ( かん水 ) ,

1729-401: Is also a common additive in swimming pools and aquarium water to maintain a desired pH and carbonate hardness (KH). In dyeing with fiber-reactive dyes, sodium carbonate (often under a name such as soda ash fixative or soda ash activator) is used as mordant to ensure proper chemical bonding of the dye with cellulose (plant) fiber. It is also used in the froth flotation process to maintain

1820-523: Is also a key input for tableware glass manufacturing. Hard water usually contains calcium or magnesium ions. Sodium carbonate is used for removing these ions and replacing them with sodium ions. Sodium carbonate is a water-soluble source of carbonate. The calcium and magnesium ions form insoluble solid precipitates upon treatment with carbonate ions: The water is softened because it no longer contains dissolved calcium ions and magnesium ions. Sodium carbonate has several uses in cuisine, largely because it

1911-487: Is also frowned upon by traditional etiquette. Although this tradition of not placing other foods on rice originated from classical Chinese dining formalities, especially after the adoption of Buddhist tea ceremonies; it became most popular and common during and after the Kamakura period , such as in the kaiseki . Although present-day Chinese cuisine has abandoned this practice, Japanese cuisine retains it. One exception

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2002-470: Is also sometimes served raw as sashimi or as sushi . Seafood and vegetables are also deep-fried in a light batter, as tempura . Apart from rice, a staple includes noodles, such as soba and udon . Japan also has many simmered dishes, such as fish products in broth called oden , or beef in sukiyaki and nikujaga . Historically influenced by Chinese cuisine , Japanese cuisine has also opened up to influence from Western cuisines in

2093-435: Is also used as a relatively strong base in various fields. As a common alkali, it is preferred in many chemical processes because it is cheaper than sodium hydroxide and far safer to handle. Its mildness especially recommends its use in domestic applications. For example, it is used as a pH regulator to maintain stable alkaline conditions necessary for the action of the majority of photographic film developing agents. It

2184-543: Is also used to describe the first course served in standard kaiseki cuisine nowadays. The origin of Japanese "one soup, three sides" cuisine is a dietary style called Ichiju-Issai (一汁一菜, "one soup, one dish"), tracing back to the Five Great Zen Temples of the 12-century Kamakura period ( Kamakura Gozan ), developed as a form of meal that emphasized frugality and simplicity. Rice is served in its own small bowl ( chawan ), and each main course item

2275-509: Is blended with the ingredient here is often sanbaizu  [ ja ] ( 三杯酢 , "three cupful/spoonful vinegar") which is a blend of vinegar, mirin, and soy sauce. A tosazu  [ ja ] ( 土佐酢 , " Tosa vinegar") adds katsuo dashi to this. An aemono  [ ja ] ( 和え物 ) is another group of items, describable as a sort of "tossed salad" or "dressed" (though aemono also includes thin strips of squid or fish sashimi ( itozukuri ) etc. similarly prepared). One type

2366-487: Is called black ash . The soda ash is extracted from the black ash with water. Evaporation of this extract yields solid sodium carbonate. This extraction process was termed lixiviating . The hydrochloric acid produced by the Leblanc process was a major source of air pollution, and the calcium sulfide byproduct also presented waste disposal issues. However, it remained the major production method for sodium carbonate until

2457-545: Is coupled to the Haber process and offers better atom economy by eliminating the production of calcium chloride, since ammonia no longer needs to be regenerated. The by-product ammonium chloride can be sold as a fertilizer. Hydrate In chemistry , a hydrate is a substance that contains water or its constituent elements. The chemical state of the water varies widely between different classes of hydrates, some of which were so labeled before their chemical structure

2548-557: Is generally seen as an eating establishment which is slightly more casual or informal compared to the kaiseki . The kaiseki ( 懐石 , lit. "warming stone") is tied with the Japanese tea ceremony . The kaiseki is considered a (simplified) form of honzen-ryōri ( 本膳料理 , lit. "main tray cooking") , which was formal banquet dining where several trays of food were served. The homophone term kaiseki ryōri ( 会席料理 , lit. "gathering + seating") originally referred to

2639-803: Is mined in several areas of the US and provides nearly all the US consumption of sodium carbonate. Large natural deposits found in 1938, such as the one near Green River, Wyoming , have made mining more economical than industrial production in North America. There are important reserves of trona in Turkey; two million tons of soda ash have been extracted from the reserves near Ankara. Several " halophyte " (salt-tolerant) plant species and seaweed species can be processed to yield an impure form of sodium carbonate, and these sources predominated in Europe and elsewhere until

2730-495: Is now the common word for traditional Japanese cooking. The term kappō  [ ja ] ( 割烹 , lit. "cutting and boiling (meats)") is synonymous with "cooking", but became a reference to mostly Japanese cooking, or restaurants, and was much used in the Meiji and Taishō eras. It has come to connote a certain standard, perhaps even of the highest caliber, a restaurant with the most highly trained chefs. However, kappō

2821-411: Is one of the few metal carbonates that is soluble in water. Some common applications of sodium carbonate include: Sodium carbonate serves as a flux for silica (SiO 2 , melting point 1,713 °C), lowering the melting point of the mixture to something achievable without special materials. This "soda glass" is mildly water-soluble, so some calcium carbonate is added to the melt mixture to make

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2912-420: Is placed on seasonality of food or shun ( 旬 ) , and dishes are designed to herald the arrival of the four seasons or calendar months. Seasonality means taking advantage of the "fruit of the mountains" ( 山の幸 , yama no sachi , alt. "bounty of the mountains") (for example, bamboo shoots in spring, chestnuts in the autumn) as well as the "fruit of the sea" ( 海の幸 , umi no sachi , alt. "bounty of

3003-571: Is placed on its own small plate ( sara ) or bowl ( hachi ) for each individual portion. This is done even in Japanese homes. This contrasts with Western-style home dinners in which each individual takes helpings from large serving dishes of food placed in the middle of the dining table. Japanese style traditionally abhors different flavored dishes touching each other on a single plate, so different dishes are given their own individual plates as mentioned or are partitioned using, for example, leaves. Placing main dishes on top of rice, thereby "soiling" it,

3094-586: Is produced in Japan and prepared in various forms such as matcha , the tea used in the Japanese tea ceremony . Beer production started in Japan in the 1860s. The most commonly consumed beers in Japan are pale-coloured light lagers , with an alcohol strength of around 5.0% ABV. Lager beers are the most commonly produced beer style in Japan, but beer-like beverages, made with lower levels of malts called Happoshu (発泡酒, literally, "bubbly alcohol") or non-malt Happousei (発泡性, literally "effervescence") have captured

3185-465: Is referred to as anhydrous . Some anhydrous compounds are hydrated so easily that they are said to be hygroscopic and are used as drying agents or desiccants . In organic chemistry, a hydrate is a compound formed by the hydration, i.e. "Addition of water or of the elements of water (i.e. H and OH) to a molecular entity". For example: ethanol , CH 3 −CH 2 −OH , is the product of the hydration reaction of ethene , CH 2 =CH 2 , formed by

3276-467: Is the most common hydrate of sodium carbonate containing 10 molecules of water of crystallization . Soda ash is dissolved in water and crystallized to get washing soda. Na 2 CO 3 + 10 H 2 O ⟶ Na 2 CO 3 ⋅ 10 H 2 O {\displaystyle {\ce {Na2CO3 + 10H2O -> Na2CO3.10H2O}}} It

3367-520: Is the popular donburi , in which toppings are directly served on rice. The small rice bowl ( 茶碗 , chawan ) , literally "tea bowl", doubles as a word for the large tea bowls in tea ceremonies. Thus in common speech, the drinking cup is referred to as yunomi-jawan or yunomi for the purpose of distinction. Among the nobility, each course of a full-course Japanese meal would be brought on serving napkins called zen ( 膳 ) , which were originally platformed trays or small dining tables. In

3458-423: Is then lowered to below 10 °C. Solubility of ammonium chloride is higher than that of sodium chloride at 30 °C and lower at 10 °C. Due to this temperature-dependent solubility difference and the common-ion effect , ammonium chloride is precipitated in a sodium chloride solution. The Chinese name of Hou's process, lianhe zhijian fa ( 联合制碱法 ), means "coupled manufacturing alkali method": Hou's process

3549-413: Is to place a bowl of rice on the diner’s left and to place a bowl of miso soup on the diner’s right side at the table. Behind these, each okazu is served on its own individual plate. Based on the standard three okazu formula, behind the rice and soup are three flat plates to hold the three okazu ; one to far back left, one at far back right, and one in the center. Pickled vegetables are often served on

3640-494: Is typically seasoned with a combination of dashi , soy sauce , sake and mirin , vinegar, sugar, and salt. A modest number of herbs and spices may be used during cooking as a hint or accent, or as a means of neutralizing fishy or gamy odors present. Examples of such spices include ginger , perilla and takanotsume  [ ja ] ( 鷹の爪 ) red pepper. Intense condiments such as wasabi or Japanese mustard are provided as condiments to raw fish, due to their effect on

3731-538: Is used in toothpastes, where it acts as a foaming agent and an abrasive, and to temporarily increase mouth pH. Sodium carbonate is also used in the processing and tanning of animal hides. The integral enthalpy of solution of sodium carbonate is −28.1 kJ/mol for a 10% w/w aqueous solution. The Mohs hardness of sodium carbonate monohydrate is 1.3. Sodium carbonate is soluble in water, and can occur naturally in arid regions, especially in mineral deposits ( evaporites ) formed when seasonal lakes evaporate. Deposits of

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3822-619: The Agency for Cultural Affairs recommended that 'Washoku: Traditional Dietary Cultures of the Japanese' be added to the UNESCO Representative List of the Intangible Cultural Heritage of Humanity . On December 4, 2013, "Washoku, traditional dietary cultures [ sic ] of the Japanese, notably for the celebration of New Year" was added to UNESCO's Intangible Cultural Heritage, bringing

3913-521: The Edo period . The consumption of whale and terrapin meat were not forbidden under this definition. Despite this, the consumption of red meat did not completely disappear in Japan. Eating wild game—as opposed to domesticated livestock—was tolerated; in particular, trapped hare was counted using the measure word wa ( 羽 ) , a term normally reserved for birds. In 1872 of the Meiji restoration, as part of

4004-506: The Mannheim process . This reaction produces sodium sulfate ( salt cake ) and hydrogen chloride : The salt cake and crushed limestone ( calcium carbonate ) was reduced by heating with coal . This conversion entails two parts. First is the carbothermic reaction whereby the coal, a source of carbon , reduces the sulfate to sulfide : The second stage is the reaction to produce sodium carbonate and calcium sulfide : This mixture

4095-598: The Meiji Restoration , the government began to adopt Western customs, including the use of animal products in food. The new ruler staged a New Years' feast designed to embrace the Western world and countries in 1872. The feast contained food that reflected European cuisine. For the first time in a thousand years, people were allowed to consume meat in public, and the general population started to include meat in their regular diets. The word washoku ( 和食 )

4186-446: The abundant seafood supply. It is the opinion of some food scholars that the Japanese diet always relied mainly on "grains with vegetables or seaweeds as main, with poultry secondary, and red meat in slight amounts" even before the advent of Buddhism which placed an even stronger taboo. The eating of "four-legged creatures" ( 四足 , yotsuashi ) was spoken of as taboo, unclean or something to be avoided by personal choice through

4277-427: The addition of H to one C and OH to the other C, and so can be considered as the hydrate of ethene. A molecule of water may be eliminated, for example, by the action of sulfuric acid . Another example is chloral hydrate , CCl 3 −CH(OH) 2 , which can be formed by reaction of water with chloral , CCl 3 −CH=O . Many organic molecules, as well as inorganic molecules, form crystals that incorporate water into

4368-641: The availability of cooking oil due to increased productivity. Dishes such as tempura , aburaage , and satsuma age are now part of established traditional Japanese cuisine. Words such as tempura or hiryōzu (synonymous with ganmodoki ) are said to be of Portuguese origin. Also, certain rustic sorts of traditional Japanese foods such as kinpira , hijiki , and kiriboshi daikon usually involve stir-frying in oil before stewing in soy sauce. Some standard osōzai or obanzai dishes feature stir-fried Japanese greens with either age or chirimen-jako  [ ja ] , dried sardines. Traditional Japanese food

4459-478: The banning of all mammals except whale, which were categorized as fish. During the Asuka period, chopsticks were introduced to Japan. Initially, they were only used by the nobility. The general population used their hands, as utensils were quite expensive. Due to the lack of meat products, Japanese people minimized spice utilization. Spices were rare to find at the time. Spices like pepper and garlic were only used in

4550-538: The bowl close to the mouth, and sucking in the noodles with the aid of chopsticks . The resulting loud slurping noise is considered normal in Japan, although in the 2010s concerns began to be voiced about the slurping being offensive to others, especially tourists. The word nuuhara (ヌーハラ, from "nuudoru harasumento", noodle harassment) was coined to describe this. Traditional Japanese sweets are known as wagashi . Ingredients such as red bean paste and mochi are used. More modern-day tastes includes green tea ice cream ,

4641-454: The cooking process, because Japanese people were trying to keep a healthy lifestyle. Preserving fish became a sensation; sushi was originated as a means of preserving fish by fermenting it in boiled rice. Fish that are salted and then placed in rice are preserved by lactic acid fermentation , which helps prevent the proliferation of the bacteria that bring about putrefaction. During the 15th century, advancement and development helped shorten

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4732-503: The country with the most 3-starred Michelin restaurants ; as of 2018 , the capital of Tokyo has maintained the title of the city with the most 3-starred restaurants in the world. In 2013, Japanese cuisine was added to the UNESCO Intangible Heritage List . Rice is a staple in Japanese cuisine. Wheat and soybeans were introduced shortly after rice. All three act as staple foods in Japanese cuisine today. At

4823-479: The country, as well as their artificial counterparts. The o-hitashi or hitashi-mono ( おひたし ) is boiled green-leaf vegetables bunched and cut to size, steeped in dashi broth, eaten with dashes of soy sauce. Another item is sunomono ( 酢の物 , "vinegar item") , which could be made with wakame seaweed, or be something like a kōhaku namasu ( 紅白なます , "red white namasu") made from thin toothpick slices of daikon and carrot. The so-called vinegar that

4914-437: The crystalline structure without chemical alteration of the organic molecule ( water of crystallization ). The sugar trehalose , for example, exists in both an anhydrous form ( melting point 203 °C) and as a dihydrate (melting point 97 °C). Protein crystals commonly have as much as 50% water content. Molecules are also labeled as hydrates for historical reasons not covered above. Glucose , C 6 H 12 O 6 ,

5005-481: The early 19th century. The land plants (typically glassworts or saltworts ) or the seaweed (typically Fucus species) were harvested, dried, and burned. The ashes were then " lixivated " (washed with water) to form an alkali solution. This solution was boiled dry to create the final product, which was termed "soda ash"; this very old name derives from the Arabic word soda , in turn applied to Salsola soda , one of

5096-541: The end of the Kofun Period and beginning of the Asuka Period , Buddhism became the official religion of the country. Therefore, eating meat and fish was prohibited. In 675 AD, Emperor Tenmu prohibited the eating of horses, dogs, monkeys, and chickens. In the 8th and 9th centuries, many emperors continued to prohibit killing many types of animals. The number of regulated meats increased significantly, leading to

5187-403: The entrance. In Japan, it is customary to say itadakimasu ("I [humbly] receive") before starting to eat a meal. When saying itadakimasu , both hands are put together in front of the chest or on the lap. Itadakimasu is preceded by complimenting the appearance of food. Another customary and important etiquette is to say go-chisō-sama deshita ("It was a feast") to the host after the meal and

5278-496: The fermentation of sushi to about one to two weeks. Sushi thus became a popular snack food and main entrée, combining fish with rice. During the late Edo period (early-19th century), sushi without fermentation was introduced. Sushi was still being consumed with and without fermentation till the 19th century when the hand-rolled and nigiri-type sushi was invented. In 1854, Japan started to enter new trade deals with Western countries. When Emperor Meiji took power in 1868 as part of

5369-432: The glass insoluble. Bottle and window glass (" soda–lime glass " with transition temperature ~570 °C) is made by melting such mixtures of sodium carbonate, calcium carbonate, and silica sand ( silicon dioxide (SiO 2 )). When these materials are heated, the carbonates release carbon dioxide. In this way, sodium carbonate is a source of sodium oxide. Soda–lime glass has been the most common form of glass for centuries. It

5460-557: The grains (糠, nuka ) polished away. Unpolished brown rice (玄米, genmai ) is considered less desirable, but its popularity has been increasing. Japanese noodles often substitute for a rice-based meal. Soba (thin, grayish-brown noodles containing buckwheat flour) and udon (thick wheat noodles) are the main traditional noodles, while ramen is a modern import and now very popular. There are also other, less common noodles, such as somen (thin, white noodles containing wheat flour). Japanese noodles, such as soba and udon, are eaten as

5551-412: The guest is a larger organic molecule such as tetrahydrofuran . In such cases the guest–host hydrogen bonds result in the formation of L-type Bjerrum defects in the clathrate lattice. The stability of hydrates is generally determined by the nature of the compounds, their temperature, and the relative humidity (if they are exposed to air). Japanese cuisine Japanese cuisine encompasses

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5642-413: The heels. When dining out in a restaurant, the customers are guided to their seats by the host. The honored or eldest guest will usually be seated at the center of the table farthest from the entrance. In the home, the most important guest is also seated farthest away from the entrance. If there is a tokonoma , or alcove, in the room, the guest is seated in front of it. The host sits next to or closest to

5733-455: The late 1880s. In 1861, the Belgian industrial chemist Ernest Solvay developed a method to make sodium carbonate by first reacting sodium chloride , ammonia , water, and carbon dioxide to generate sodium bicarbonate and ammonium chloride : The resulting sodium bicarbonate was then converted to sodium carbonate by heating it, releasing water and carbon dioxide: Meanwhile, the ammonia

5824-481: The many species of seashore plants harvested for production. "Barilla" is a commercial term applied to an impure form of potash obtained from coastal plants or kelp . The sodium carbonate concentration in soda ash varied very widely, from 2–3 percent for the seaweed-derived form (" kelp "), to 30 percent for the best barilla produced from saltwort plants in Spain. Plant and seaweed sources for soda ash, and also for

5915-455: The mineral natron have been mined from dry lake bottoms in Egypt since ancient times, when natron was used in the preparation of mummies and in the early manufacture of glass. The anhydrous mineral form of sodium carbonate is quite rare and called nitrite. Sodium carbonate also erupts from Ol Doinyo Lengai , Tanzania's unique volcano, and it is presumed to have erupted from other volcanoes in

6006-423: The modern age, faldstool trays or stackup-type legged trays may still be seen used in zashiki , i.e. tatami -mat rooms, for large banquets or at a ryokan type inn. Some restaurants might use the suffix -zen ( 膳 ) as a more sophisticated though dated synonym to the more familiar teishoku ( 定食 ) , since the latter basically is a term for a combo meal served at a taishū-shokudō , akin to

6097-574: The modern era. Dishes inspired by foreign food—in particular Chinese food—like ramen and gyōza , as well as foods like spaghetti , curry and hamburgers , have been adapted to Japanese tastes and ingredients. Traditionally, the Japanese shunned meat as a result of adherence to Buddhism , but with the modernization of Japan in the 1880s, meat-based dishes such as tonkatsu and yakiniku have become common. Since this time, Japanese cuisine, particularly sushi and ramen, has become popular globally. In 2011, Japan overtook France to become

6188-447: The monks were killed during the break-in attempt, and the remainder were arrested. On the other hand, the consumption of meat was accepted by the common people. Gyūnabe (beef hot pot), the prototype of sukiyaki , became the rage of the time. Western restaurants moved in, and some of them changed their form to Yōshoku . Vegetable consumption has dwindled while processed foods have become more prominent in Japanese households due to

6279-541: The mucous membrane which paralyze the sense of smell, particularly from fish odors. A sprig of mitsuba or a piece of yuzu rind floated on soups are called ukimi . Minced shiso leaves and myoga often serve as yakumi , a type of condiment paired with tataki of katsuo or soba . Shichimi is also a very popular spice mixture often added to soups, noodles and rice cakes. Shichimi is a chilli-based spice mix which contains seven spices: chilli, sansho, orange peel, black sesame, white sesame, hemp, ginger, and nori. Once

6370-420: The noodles can be changed, but the broth and garnishes correspond to their respective legend. Hot noodles are usually served in a bowl already steeped in their broth and are called kakesoba or kakeudon . Cold soba arrive unseasoned and heaped atop a zaru or seiro , and are picked up with a chopstick and dunked in their dipping sauce. The broth can consist of many ingredients but is generally based on dashi;

6461-478: The number of Japanese assets listed on UNESCO's Intangible Cultural Heritage list to 22. A characteristic of traditional Japanese food is the sparing use of red meat , oils and fats, and dairy products. Use of ingredients such as soy sauce , miso , and umeboshi tends to result in dishes with high salt content, though there are low-sodium versions of these available. As Japan is an island nation surrounded by an ocean, its people have always taken advantage of

6552-479: The opening up of Japan to Western influence, Emperor Meiji lifted the ban on the consumption of red meat . The removal of the ban encountered resistance and in one notable response, ten monks attempted to break into the Imperial Palace. The monks asserted that due to foreign influence, large numbers of Japanese had begun eating meat and that this was "destroying the soul of the Japanese people." Several of

6643-579: The past, but due to these minerals' instability at the Earth's surface, are likely to be eroded. All three mineralogical forms of sodium carbonate, as well as trona , trisodium hydrogendi carbonate dihydrate, are also known from ultra-alkaline pegmatitic rocks , that occur for example in the Kola Peninsula in Russia. Extra terrestrially, known sodium carbonate is rare. Deposits have been identified as

6734-409: The regional and traditional foods of Japan , which have developed through centuries of political, economic, and social changes. The traditional cuisine of Japan ( Japanese : washoku ) is based on rice with miso soup and other dishes with an emphasis on seasonal ingredients. Side dishes often consist of fish, pickled vegetables, and vegetables cooked in broth. Common seafood is often grilled, but it

6825-479: The related alkali " potash ", became increasingly inadequate by the end of the 18th century, and the search for commercially viable routes to synthesizing soda ash from salt and other chemicals intensified. In 1792, the French chemist Nicolas Leblanc patented a process for producing sodium carbonate from salt, sulfuric acid , limestone , and coal. In the first step, sodium chloride is treated with sulfuric acid in

6916-486: The restaurant staff when leaving. Japanese cuisine is based on combining the staple food , which is steamed white rice or gohan ( 御飯 ) , with one or more okazu , "main" or "side" dishes. This may be accompanied by a clear or miso soup and tsukemono (pickles). The phrase ichijū-sansai ( 一汁三菜 , "one soup, three sides") refers to the makeup of a typical meal served but has roots in classic kaiseki , honzen , and yūshoku cuisine. The term

7007-495: The rising costs of general foodstuffs. Nonetheless, Kyoto vegetables, or Kyoyasai , are rising in popularity and different varieties of Kyoto vegetables are being revived. Generally speaking, traditional Japanese cuisine is prepared with little cooking oil. A major exception is the deep-frying of foods. This cooking method was introduced during the Edo period due to influence from Western (formerly called nanban-ryōri ( 南蛮料理 ) ) and Chinese cuisine, and became commonplace with

7098-493: The sauce, called tsuyu, is usually more concentrated and made from soy sauce, dashi and mirin, sake or both. In the simple form, yakumi (condiments and spices) such as shichimi , nori, finely chopped scallions, wasabi, etc. are added to the noodles, besides the broth/dip sauce. Udon may also be eaten in kama-age style, piping hot straight out of the boiling pot, and eaten with plain soy sauce and sometimes with raw egg also. Japanese noodles are traditionally eaten by bringing

7189-745: The sea") as they come into season. Thus the first catch of skipjack tunas ( 初鰹 , hatsu-gatsuo ) that arrives with the Kuroshio Current has traditionally been greatly prized. If something becomes available rather earlier than what is usual for the item in question, the first crop or early catch is called hashiri . Use of tree leaves and branches as decor is also characteristic of Japanese cuisine. Maple leaves are often floated on water to exude coolness or ryō ( 涼 ) ; sprigs of nandina are popularly used. The haran ( Aspidistra ) and sasa bamboo leaves were often cut into shapes and placed underneath or used as separators. In February 2012,

7280-609: The side but are not counted as part of the three okazu . Chopsticks are generally placed at the very front of the tray near the diner with pointed ends facing left and supported by a chopstick rest , or hashioki . Many restaurants and homes in Japan are equipped with Western-style chairs and tables. However, traditional Japanese low tables and cushions, usually found on tatami floors, are also very common. Tatami mats, which are made of straw, can be easily damaged and are hard to clean, thus shoes or any type of footwear are always taken off when stepping on tatami floors. When dining in

7371-600: The source of bright spots on Ceres , interior material that has been brought to the surface. While there are carbonates on Mars , and these are expected to include sodium carbonate, deposits have yet to be confirmed, this absence is explained by some as being due to a global dominance of low pH in previously aqueous Martian soil . The initial large-scale chemical procedure was established in England in 1823 to manufacture soda ash. Trona , also known as trisodium hydrogendicarbonate dihydrate (Na 3 HCO 3 CO 3 ·2H 2 O),

7462-479: The staple food of the Japanese people. Its fundamental importance is evident from the fact that the word for cooked rice, gohan or meshi , also stands for a "meal". While rice has an ancient history of cultivation in Japan, its use as a staple has not been universal. Notably, in northern areas (northern Honshū and Hokkaidō), other grains such as wheat were more common into the 19th century. In most of Japan, rice used to be consumed for almost every meal, and although

7553-432: The sulfuric acid needed for acid delinting of fuzzy cottonseed. It is also used to form carbonates of other metals by ion exchange, often with the other metals' sulphates. Sodium carbonate is used by the brick industry as a wetting agent to reduce the amount of water needed to extrude the clay. In casting, it is referred to as "bonding agent" and is used to allow wet alginate to adhere to gelled alginate. Sodium carbonate

7644-458: The temperatures required (250 °F (121 °C) to 300 °F (149 °C)) to convert baking soda to sodium carbonate are readily achieved in conventional kitchen ovens . This process was developed by Chinese chemist Hou Debang in the 1930s. The earlier steam reforming by-product carbon dioxide was pumped through a saturated solution of sodium chloride and ammonia to produce sodium bicarbonate by these reactions: The sodium bicarbonate

7735-399: The term deuterate may be used in place of hydrate . A colorful example is cobalt(II) chloride , which turns from blue to red upon hydration , and can therefore be used as a water indicator. The notation " hydrated compound ⋅ n H 2 O ", where n is the number of water molecules per formula unit of the salt, is commonly used to show that a salt is hydrated. The n is usually

7826-428: The type of table common during a given era. Before the 19th century, small individual box tables ( hakozen , 箱膳) or flat floor trays were set before each diner. Larger low tables ( chabudai , ちゃぶ台) that accommodated entire families were gaining popularity by the beginning of the 20th century, but these gave way to Western-style dining tables and chairs by the end of the 20th century. The traditional Japanese table setting

7917-399: Was collected as a precipitate due to its low solubility and then heated up to approximately 80 °C (176 °F) or 95 °C (203 °F) to yield pure sodium carbonate similar to last step of the Solvay process. More sodium chloride is added to the remaining solution of ammonium and sodium chlorides; also, more ammonia is pumped at 30-40 °C to this solution. The solution temperature

8008-590: Was originally thought of as C 6 (H 2 O) 6 and described as a carbohydrate . Hydrate formation is common for active ingredients . Many manufacturing processes provide an opportunity for hydrates to form and the state of hydration can be changed with environmental humidity and time. The state of hydration of an active pharmaceutical ingredient can significantly affect the solubility and dissolution rate and therefore its bioavailability . Clathrate hydrates (also known as gas hydrates, gas clathrates, etc.) are water ice with gas molecules trapped within; they are

8099-416: Was produced by the Solvay process, and the last Leblanc process plant closed in the early 1920s. The second step of the Solvay process, heating sodium bicarbonate, is used on a small scale by home cooks and in restaurants to make sodium carbonate for culinary purposes (including pretzels and alkali noodles ). The method is appealing to such users because sodium bicarbonate is widely sold as baking soda, and

8190-593: Was regenerated from the ammonium chloride byproduct by treating it with the lime ( calcium oxide ) left over from carbon dioxide generation: The Solvay process recycles its ammonia. It consumes only brine and limestone, and calcium chloride is its only waste product. The process is substantially more economical than the Leblanc process, which generates two waste products, calcium sulfide and hydrogen chloride . The Solvay process quickly came to dominate sodium carbonate production worldwide. By 1900, 90% of sodium carbonate

8281-426: Was understood. Hydrates are inorganic salts "containing water molecules combined in a definite ratio as an integral part of the crystal " that are either bound to a metal center or that have crystallized with the metal complex. Such hydrates are also said to contain water of crystallization or water of hydration . If the water is heavy water in which the constituent hydrogen is the isotope deuterium , then

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