Misplaced Pages

#86913

59-517: The atmospheric infrared sounder ( AIRS ) is one of six instruments flying on board NASA's Aqua satellite , launched on May 4, 2002. The instrument is designed to support climate research and improve weather forecasting . Working in combination with its partner microwave instrument, the Advanced Microwave Sounding Unit (AMSU-A), AIRS observes the global water and energy cycles, climate variation and trends, and

118-516: A decline in basic activity level and information usage at 1000 ppm, when compared to 500 ppm. However a review of the literature found that a reliable subset of studies on the phenomenon of carbon dioxide induced cognitive impairment to only show a small effect on high-level decision making (for concentrations below 5000 ppm). Most of the studies were confounded by inadequate study designs, environmental comfort, uncertainties in exposure doses and differing cognitive assessments used. Similarly

177-446: A fixed structure. However, in a Coulomb explosion imaging experiment, an instantaneous image of the molecular structure can be deduced. Such an experiment has been performed for carbon dioxide. The result of this experiment, and the conclusion of theoretical calculations based on an ab initio potential energy surface of the molecule, is that none of the molecules in the gas phase are ever exactly linear. This counter-intuitive result

236-611: A glass state similar to other members of its elemental family, like silicon dioxide (silica glass) and germanium dioxide . Unlike silica and germania glasses, however, carbonia glass is not stable at normal pressures and reverts to gas when pressure is released. At temperatures and pressures above the critical point, carbon dioxide behaves as a supercritical fluid known as supercritical carbon dioxide . Table of thermal and physical properties of saturated liquid carbon dioxide: Table of thermal and physical properties of carbon dioxide (CO 2 ) at atmospheric pressure: Carbon dioxide

295-578: A global daily 3-D view of Earth's ozone layer , showing how ozone is transported. The instrument also gives scientists their best view of atmospheric ozone in the Antarctic region during the polar winter. AIRS is also able to identify concentrations of sulphur dioxide and dust. [REDACTED]  This article incorporates public domain material from How Airs Works . National Aeronautics and Space Administration .  (and other articles). Aqua (satellite) The name "Aqua" comes from

354-491: A mature forest will produce as much CO 2 from respiration and decomposition of dead specimens (e.g., fallen branches) as is used in photosynthesis in growing plants. Contrary to the long-standing view that they are carbon neutral, mature forests can continue to accumulate carbon and remain valuable carbon sinks , helping to maintain the carbon balance of Earth's atmosphere. Additionally, and crucially to life on earth, photosynthesis by phytoplankton consumes dissolved CO 2 in

413-428: A much larger denominator and a much smaller value than the true K a1 . The bicarbonate ion is an amphoteric species that can act as an acid or as a base, depending on pH of the solution. At high pH, it dissociates significantly into the carbonate ion ( CO 2− 3 ): In organisms, carbonic acid production is catalysed by the enzyme known as carbonic anhydrase . In addition to altering its acidity,

472-433: A particular wavelength, a temperature profile, or sounding of the atmosphere, can be made. While prior space instruments had only 15 detectors, AIRS has 2378. This greatly improves the accuracy, making it comparable to measurements made by weather balloons . Thick clouds act like a wall to the infrared energy measured by AIRS. However, microwave instruments on board Aqua can see through the clouds with limited accuracy. Using

531-516: A re-entry by 2046. Aqua carries six instruments for studies of water on the Earth's surface and in the atmosphere , of which four are still operating: The Aqua spacecraft has a mass of about 2,850 kilograms (6,280 lb), plus propellant of about 230 kilograms (510 lb) at launch. Stowed for launch, the satellite fit in a volume of 2.68 m x 2.49 m x 6.49 m. Deployed, Aqua is 4.81 m x 16.70 m x 8.04 m. Carbon dioxide Carbon dioxide

590-418: A scan swath that extends roughly 800 kilometers on either side of the ground track . Within the instrument, an advanced, high-resolution spectrometer separates the infrared energy into wavelengths . Each infrared wavelength is sensitive to temperature and water vapor over a range of heights in the atmosphere , from the surface up into the stratosphere . By having multiple infrared detectors, each sensing

649-468: A special computer algorithm , data from AIRS and the microwave instruments are combined to provide highly accurate measurements in all cloud conditions resulting in a daily global snapshot of the state of the atmosphere. AIRS and its companion microwave sounder AMSU observe the entire atmospheric column from Earth's surface to the top of the atmosphere. The primary data they return is the infrared spectrum in 2378 individual frequencies. The infrared spectrum

SECTION 10

#1732776479087

708-416: A study on the effects of the concentration of CO 2 in motorcycle helmets has been criticized for having dubious methodology in not noting the self-reports of motorcycle riders and taking measurements using mannequins. Further when normal motorcycle conditions were achieved (such as highway or city speeds) or the visor was raised the concentration of CO 2 declined to safe levels (0.2%). Poor ventilation

767-467: A typical single C–O bond, and shorter than most other C–O multiply bonded functional groups such as carbonyls . Since it is centrosymmetric, the molecule has no electric dipole moment . As a linear triatomic molecule, CO 2 has four vibrational modes as shown in the diagram. In the symmetric and the antisymmetric stretching modes, the atoms move along the axis of the molecule. There are two bending modes, which are degenerate , meaning that they have

826-437: A very useful space instrument to observe and study the response of the atmosphere to increased greenhouse gases. The instrument can detect carbon monoxide emissions from the burning of plant materials and animal waste by humans in rainforests and large cities. It can follow giant plumes of this gas moving across the planet from these large burns, allowing scientists to better monitor pollution transport patterns. AIRS provides

885-485: A waste product. In turn, oxygen is consumed and CO 2 is released as waste by all aerobic organisms when they metabolize organic compounds to produce energy by respiration . CO 2 is released from organic materials when they decay or combust, such as in forest fires. When carbon dioxide dissolves in water, it forms carbonate and mainly bicarbonate ( HCO − 3 ), which causes ocean acidification as atmospheric CO 2 levels increase. Carbon dioxide

944-469: Is Emiliania huxleyi whose calcite scales have formed the basis of many sedimentary rocks such as limestone , where what was previously atmospheric carbon can remain fixed for geological timescales. Plants can grow as much as 50% faster in concentrations of 1,000 ppm CO 2 when compared with ambient conditions, though this assumes no change in climate and no limitation on other nutrients. Elevated CO 2 levels cause increased growth reflected in

1003-419: Is 304.128(15) K (30.978(15) °C) at 7.3773(30) MPa (72.808(30) atm). Another form of solid carbon dioxide observed at high pressure is an amorphous glass-like solid. This form of glass, called carbonia , is produced by supercooling heated CO 2 at extreme pressures (40–48  GPa , or about 400,000 atmospheres) in a diamond anvil . This discovery confirmed the theory that carbon dioxide could exist in

1062-569: Is 53% more dense than dry air, but is long lived and thoroughly mixes in the atmosphere. About half of excess CO 2 emissions to the atmosphere are absorbed by land and ocean carbon sinks . These sinks can become saturated and are volatile, as decay and wildfires result in the CO 2 being released back into the atmosphere. CO 2 is eventually sequestered (stored for the long term) in rocks and organic deposits like coal , petroleum and natural gas . Nearly all CO2 produced by humans goes into

1121-406: Is a chemical compound with the chemical formula CO 2 . It is made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature and at normally-encountered concentrations it is odorless. As the source of carbon in the carbon cycle , atmospheric CO 2 is the primary carbon source for life on Earth. In

1180-415: Is an end product of cellular respiration in organisms that obtain energy by breaking down sugars, fats and amino acids with oxygen as part of their metabolism . This includes all plants, algae and animals and aerobic fungi and bacteria. In vertebrates , the carbon dioxide travels in the blood from the body's tissues to the skin (e.g., amphibians ) or the gills (e.g., fish ), from where it dissolves in

1239-402: Is commercially used in its solid form, commonly known as " dry ice ". The solid-to-gas phase transition occurs at 194.7 Kelvin and is called sublimation . The symmetry of a carbon dioxide molecule is linear and centrosymmetric at its equilibrium geometry. The length of the carbon–oxygen bond in carbon dioxide is 116.3  pm , noticeably shorter than the roughly 140 pm length of

SECTION 20

#1732776479087

1298-632: Is one of the main causes of excessive CO 2 concentrations in closed spaces, leading to poor indoor air quality . Carbon dioxide differential above outdoor concentrations at steady state conditions (when the occupancy and ventilation system operation are sufficiently long that CO 2 concentration has stabilized) are sometimes used to estimate ventilation rates per person. Higher CO 2 concentrations are associated with occupant health, comfort and performance degradation. ASHRAE Standard 62.1–2007 ventilation rates may result in indoor concentrations up to 2,100 ppm above ambient outdoor conditions. Thus if

1357-410: Is ordinarily a difficult and slow reaction: The redox potential for this reaction near pH 7 is about −0.53 V versus the standard hydrogen electrode . The nickel-containing enzyme carbon monoxide dehydrogenase catalyses this process. Photoautotrophs (i.e. plants and cyanobacteria ) use the energy contained in sunlight to photosynthesize simple sugars from CO 2 absorbed from

1416-405: Is produced as a by-product. Ribulose-1,5-bisphosphate carboxylase oxygenase , commonly abbreviated to RuBisCO, is the enzyme involved in the first major step of carbon fixation, the production of two molecules of 3-phosphoglycerate from CO 2 and ribulose bisphosphate , as shown in the diagram at left. RuBisCO is thought to be the single most abundant protein on Earth. Phototrophs use

1475-577: Is rich in information on numerous gases in the atmosphere. AIRS primary scientific achievement has been to improve weather prediction and provide new information on the water and energy cycle. The instrument also yields information on several important greenhouse gases . Weather and climate forecasting AIRS data are used by weather forecasting centers around the world. By incorporating AIRS measurements into their models , forecasters have been able to extend reliable mid-range weather forecasts by more than six hours. AIRS data have also improved forecasts of

1534-472: Is the true first acid dissociation constant, defined as where the denominator includes only covalently bound H 2 CO 3 and does not include hydrated CO 2 (aq). The much smaller and often-quoted value near 4.16 × 10 (or pK a1 = 6.38) is an apparent value calculated on the (incorrect) assumption that all dissolved CO 2 is present as carbonic acid, so that Since most of the dissolved CO 2 remains as CO 2 molecules, K a1 (apparent) has

1593-503: Is the main cause of these increased CO 2 concentrations, which are the primary cause of climate change . Its concentration in Earth's pre-industrial atmosphere since late in the Precambrian was regulated by organisms and geological features. Plants , algae and cyanobacteria use energy from sunlight to synthesize carbohydrates from carbon dioxide and water in a process called photosynthesis , which produces oxygen as

1652-419: Is trivially due to the fact that the nuclear motion volume element vanishes for linear geometries. This is so for all molecules except diatomic molecules . Carbon dioxide is soluble in water, in which it reversibly forms H 2 CO 3 (carbonic acid), which is a weak acid , because its ionization in water is incomplete. The hydration equilibrium constant of carbonic acid is, at 25 °C: Hence,

1711-465: Is used in CO 2 scrubbers and has been suggested as a possible starting point for carbon capture and storage by amine gas treating . Only very strong nucleophiles, like the carbanions provided by Grignard reagents and organolithium compounds react with CO 2 to give carboxylates : In metal carbon dioxide complexes , CO 2 serves as a ligand , which can facilitate the conversion of CO 2 to other chemicals. The reduction of CO 2 to CO

1770-585: The Latin word for water. The satellite was launched from Vandenberg Air Force Base on May 4, 2002, aboard a Delta II rocket . Aqua operated in a Sun-synchronous orbit as the third in the satellite formation called the " A Train " with several other satellites ( OCO-2 , the Japanese GCOM W1 , PARASOL , CALIPSO , Cloud Sat , and Aura ) for most of its first 20 years; but in January 2022 Aqua left

1829-454: The A-Train (as Cloud Sat, CALIPSO and PARASOL had already done) when, due to its fuel limitations, it transitioned to a free-drift mode, wherein its equatorial crossing time is slowly drifting to later times, from its tightly controlled orbit. Aqua is one of NASA's missions for Earth science operating in the A-Train constellation. It has demonstrated a very high level of precision in making

Atmospheric infrared sounder - Misplaced Pages Continue

1888-618: The Aqua data to address NASA's 6 interdisciplinary Earth science focus areas: Atmospheric Composition, Weather, Carbon Cycle and Ecosystems, Water and Energy Cycle, Climate Variability and Change, and Earth Surface and Interior. Aqua has experienced some minor, non-mission ending anomalies. Because of a 2007 anomaly with the Solid State Recorder (SSR) it can only hold two orbits worth of data. A series of solar array and array regulator electronics anomalies starting in 2010 has led to

1947-1002: The Earth's Radiant Energy System (CERES), and the Advanced Microwave Scanning Radiometer-EOS (AMSR-E). Aqua is part of NASA's " A-train ," a series of high-inclination, Sun-synchronous satellites in low Earth orbit designed to make long-term global observations of the land surface, biosphere , solid Earth, atmosphere , and ocean. AIRS data are free and available to the public through the Goddard Earth Sciences Data Information and Services Center. NASA's Jet Propulsion Laboratory in Pasadena, California, manages AIRS for NASA's Science Mission Directorate in Washington, D.C. The term "sounder" in AIRS's name refers to

2006-479: The SSR and stopping all data streams until it was recovered on September 2, 2020. The current end of mission plan is to let Aqua's orbit decay naturally at least until June 2024 and continue data collection into 2026 or even 2027, dependent on such items as budget, fuel, hardware, power, and end-of mission requirements. Aqua's life could be extended with a possible re-fueling mission. A worst-case scenario would result in

2065-449: The ability to predict the future. Atmospheric Composition, Greenhouse Gases, and Air Quality AIRS maps the concentration of carbon dioxide and methane globally. Its ability to provide simultaneous observations of the Earth's atmospheric temperature, water vapor, ocean surface temperature, and land surface temperature and infrared spectral emissivity, as well as humidity, clouds and the distribution of greenhouse gases, makes AIRS/AMSU

2124-439: The air and water: Carbon dioxide is colorless. At low concentrations, the gas is odorless; however, at sufficiently high concentrations, it has a sharp, acidic odor. At standard temperature and pressure , the density of carbon dioxide is around 1.98 kg/m , about 1.53 times that of air . Carbon dioxide has no liquid state at pressures below 0.51795(10) MPa (5.11177(99) atm ). At a pressure of 1 atm (0.101325 MPa),

2183-444: The air, carbon dioxide is transparent to visible light but absorbs infrared radiation , acting as a greenhouse gas . Carbon dioxide is soluble in water and is found in groundwater , lakes , ice caps , and seawater . It is a trace gas in Earth's atmosphere at 421  parts per million (ppm) , or about 0.042% (as of May 2022) having risen from pre-industrial levels of 280 ppm or about 0.028%. Burning fossil fuels

2242-430: The atmosphere. Less than 1% of CO2 produced annually is put to commercial use, mostly in the fertilizer industry and in the oil and gas industry for enhanced oil recovery . Other commercial applications include food and beverage production, metal fabrication, cooling, fire suppression and stimulating plant growth in greenhouses. Carbon dioxide cannot be liquefied at atmospheric pressure. Low-temperature carbon dioxide

2301-869: The condition. There are few studies of the health effects of long-term continuous CO 2 exposure on humans and animals at levels below 1%. Occupational CO 2 exposure limits have been set in the United States at 0.5% (5000 ppm) for an eight-hour period. At this CO 2 concentration, International Space Station crew experienced headaches, lethargy, mental slowness, emotional irritation, and sleep disruption. Studies in animals at 0.5% CO 2 have demonstrated kidney calcification and bone loss after eight weeks of exposure. A study of humans exposed in 2.5 hour sessions demonstrated significant negative effects on cognitive abilities at concentrations as low as 0.1% (1000   ppm) CO 2 likely due to CO 2 induced increases in cerebral blood flow. Another study observed

2360-517: The degenerate pair of bending modes at 667 cm (wavelength 15.0 μm). The symmetric stretching mode does not create an electric dipole so is not observed in IR spectroscopy, but it is detected in Raman spectroscopy at 1388 cm (wavelength 7.20 μm), with a Fermi resonance doublet at 1285 cm . In the gas phase, carbon dioxide molecules undergo significant vibrational motions and do not keep

2419-566: The dispersing effects of wind, it can collect in sheltered/pocketed locations below average ground level, causing animals located therein to be suffocated. Carrion feeders attracted to the carcasses are then also killed. Children have been killed in the same way near the city of Goma by CO 2 emissions from the nearby volcano Mount Nyiragongo . The Swahili term for this phenomenon is mazuku . Adaptation to increased concentrations of CO 2 occurs in humans, including modified breathing and kidney bicarbonate production, in order to balance

Atmospheric infrared sounder - Misplaced Pages Continue

2478-541: The effects of blood acidification ( acidosis ). Several studies suggested that 2.0 percent inspired concentrations could be used for closed air spaces (e.g. a submarine ) since the adaptation is physiological and reversible, as deterioration in performance or in normal physical activity does not happen at this level of exposure for five days. Yet, other studies show a decrease in cognitive function even at much lower levels. Also, with ongoing respiratory acidosis , adaptation or compensatory mechanisms will be unable to reverse

2537-551: The electrical conductivity of fully deionized water without CO 2 saturation is comparably low in relation to these data. CO 2 is a potent electrophile having an electrophilic reactivity that is comparable to benzaldehyde or strongly electrophilic α,β-unsaturated carbonyl compounds . However, unlike electrophiles of similar reactivity, the reactions of nucleophiles with CO 2 are thermodynamically less favored and are often found to be highly reversible. The reversible reaction of carbon dioxide with amines to make carbamates

2596-411: The fact that the instrument measures temperature and water vapor as a function of height ( atmospheric sounding ). AIRS measures the infrared brightness coming up from Earth's surface and from the atmosphere. Its scan mirror rotates around an axis along the line of flight and directs infrared energy from the Earth into the instrument. As the spacecraft moves along, this mirror sweeps the ground creating

2655-469: The gas deposits directly to a solid at temperatures below 194.6855(30) K (−78.4645(30) °C) and the solid sublimes directly to a gas above this temperature. In its solid state, carbon dioxide is commonly called dry ice . Liquid carbon dioxide forms only at pressures above 0.51795(10) MPa (5.11177(99) atm); the triple point of carbon dioxide is 216.592(3) K (−56.558(3) °C) at 0.51795(10) MPa (5.11177(99) atm) (see phase diagram). The critical point

2714-601: The harvestable yield of crops, with wheat, rice and soybean all showing increases in yield of 12–14% under elevated CO 2 in FACE experiments. Increased atmospheric CO 2 concentrations result in fewer stomata developing on plants which leads to reduced water usage and increased water-use efficiency . Studies using FACE have shown that CO 2 enrichment leads to decreased concentrations of micronutrients in crop plants. This may have knock-on effects on other parts of ecosystems as herbivores will need to eat more food to gain

2773-516: The location and magnitude of predicted storms. AIRS temperature and water vapor profiles are available in real time to regional weather forecasters, providing twice-daily weather measurements for the entire Pacific Ocean, once in the morning and once in the evening. AIRS measurements form a "fingerprint" of the state of the atmosphere for a given time and place that can be used as a climate data record for future generations. They have become important tools for understanding current climate and increasing

2832-633: The loss of 23 strings of solar cells out of a total of 132 strings. A 2005 short circuit within a battery cell led to a partial loss of cell capacity. In 2009, a solar panel thermistor failed and an error in the Solar Array offset was detected. The offset issue has been corrected periodically since then. On September 8, 2007, the Dual Thruster Module (DTM-2) Heater experienced an anomaly. On August 16, 2020, The Formatter Multiplexer Unit (FMU) experienced an anomaly, corrupting some data in

2891-444: The majority of the carbon dioxide is not converted into carbonic acid, but remains as CO 2 molecules, not affecting the pH. The relative concentrations of CO 2 , H 2 CO 3 , and the deprotonated forms HCO − 3 ( bicarbonate ) and CO 2− 3 ( carbonate ) depend on the pH . As shown in a Bjerrum plot , in neutral or slightly alkaline water (pH > 6.5), the bicarbonate form predominates (>50%) becoming

2950-443: The most prevalent (>95%) at the pH of seawater. In very alkaline water (pH > 10.4), the predominant (>50%) form is carbonate. The oceans, being mildly alkaline with typical pH = 8.2–8.5, contain about 120 mg of bicarbonate per liter. Being diprotic , carbonic acid has two acid dissociation constants , the first one for the dissociation into the bicarbonate (also called hydrogen carbonate) ion ( HCO − 3 ): This

3009-495: The presence of carbon dioxide in water also affects its electrical properties. When carbon dioxide dissolves in desalinated water, the electrical conductivity increases significantly from below 1 μS/cm to nearly 30 μS/cm. When heated, the water begins to gradually lose the conductivity induced by the presence of C O 2 {\displaystyle \mathrm {CO_{2}} } , especially noticeable as temperatures exceed 30 °C. The temperature dependence of

SECTION 50

#1732776479087

3068-499: The presence of sufficient oxygen, manifesting as dizziness, headache, visual and hearing dysfunction, and unconsciousness within a few minutes to an hour. Concentrations of more than 10% may cause convulsions, coma, and death. CO 2 levels of more than 30% act rapidly leading to loss of consciousness in seconds. Because it is heavier than air, in locations where the gas seeps from the ground (due to sub-surface volcanic or geothermal activity) in relatively high concentrations, without

3127-401: The primary long-term measurements of the mission. These highly calibrated climate quality measurements of radiance, reflectance, and backscatter have been used to cross-calibrate past and present sensors launched by NASA, as well as a variety of sensors launched from other agencies and the international community. Thousands of scientists and operational users from around the world have made use of

3186-496: The products of their photosynthesis as internal food sources and as raw material for the biosynthesis of more complex organic molecules, such as polysaccharides , nucleic acids , and proteins. These are used for their own growth, and also as the basis of the food chains and webs that feed other organisms, including animals such as ourselves. Some important phototrophs, the coccolithophores synthesise hard calcium carbonate scales. A globally significant species of coccolithophore

3245-540: The response of the climate system to increased greenhouse gases . AIRS uses infrared technology to create three-dimensional maps of air and surface temperature, water vapor , and cloud properties. AIRS can also measure trace greenhouse gases such as ozone , carbon monoxide , carbon dioxide , and methane . AIRS and AMSU-A share the Aqua satellite with the Moderate Resolution Imaging Spectroradiometer ( MODIS ), Clouds and

3304-420: The same amount of protein. The concentration of secondary metabolites such as phenylpropanoids and flavonoids can also be altered in plants exposed to high concentrations of CO 2 . Plants also emit CO 2 during respiration, and so the majority of plants and algae, which use C3 photosynthesis , are only net absorbers during the day. Though a growing forest will absorb many tons of CO 2 each year,

3363-411: The same frequency and same energy, because of the symmetry of the molecule. When a molecule touches a surface or touches another molecule, the two bending modes can differ in frequency because the interaction is different for the two modes. Some of the vibrational modes are observed in the infrared (IR) spectrum : the antisymmetric stretching mode at wavenumber 2349 cm (wavelength 4.25 μm) and

3422-535: The upper ocean and thereby promotes the absorption of CO 2 from the atmosphere. Carbon dioxide content in fresh air (averaged between sea-level and 10 kPa level, i.e., about 30 km (19 mi) altitude) varies between 0.036% (360 ppm) and 0.041% (412 ppm), depending on the location. In humans, exposure to CO 2 at concentrations greater than 5% causes the development of hypercapnia and respiratory acidosis . Concentrations of 7% to 10% (70,000 to 100,000 ppm) may cause suffocation, even in

3481-546: The water, or to the lungs from where it is exhaled. During active photosynthesis, plants can absorb more carbon dioxide from the atmosphere than they release in respiration. Carbon fixation is a biochemical process by which atmospheric carbon dioxide is incorporated by plants, algae and cyanobacteria into energy-rich organic molecules such as glucose , thus creating their own food by photosynthesis. Photosynthesis uses carbon dioxide and water to produce sugars from which other organic compounds can be constructed, and oxygen

#86913