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29-398: Feldspar , quartz , and garnet are common minerals which form augen. Augen form in rocks which have undergone metamorphism and shearing . The core of the augen is a porphyroblast or porphyroclast of a hard, resilient mineral such as garnet. The augen grows by crystallisation of a mantle of new mineral around the porphyroblast. The mantle is formed contiguous with the foliation which

58-494: A Mars rock. Immiscibility Miscibility ( / ˌ m ɪ s ɪ ˈ b ɪ l ɪ t i / ) is the property of two substances to mix in all proportions (that is, to fully dissolve in each other at any concentration ), forming a homogeneous mixture (a solution ). Such substances are said to be miscible (etymologically equivalent to the common term " mixable "). The term is most often applied to liquids but also applies to solids and gases . An example in liquids

87-516: A form of shear direction information. A metamorphic rock which is clotted with augen is often called an augen gneiss . A long wall of this augen gneiss can be felt at the Mineral and Lapidary Museum of Western North Carolina . This article related to petrology is a stub . You can help Misplaced Pages by expanding it . Feldspar Feldspar ( / ˈ f ɛ l ( d ) ˌ s p ɑːr / FEL(D) -spar ; sometimes spelled felspar )

116-435: A light microscope, whereas cryptoperthitic textures can be seen only with an electron microscope. Buddingtonite is an ammonium feldspar with the chemical formula: NH 4 AlSi 3 O 8 . It is a mineral associated with hydrothermal alteration of the primary feldspar minerals. Barium feldspars form as the result of the substitution of barium for potassium in the mineral structure. Barium feldspars are sometimes classified as

145-473: A mild abrasive action. The USGS estimated global production of feldspar in 2020 to be 26 million tonnes, with the top four producing countries being: China 2 million tonnes; India 5 million tonnes; Italy 4 million; Turkey 7.6 million tonnes. Typical mineralogical and chemical analyses of three commercial grades used in ceramics are: In October 2012, the Curiosity rover found high feldspar content in

174-409: A mixture will be possible in the molten state, but upon freezing, the metals separate into layers. This property allows solid precipitates to be formed by rapidly freezing a molten mixture of immiscible metals. One example of immiscibility in metals is copper and cobalt , where rapid freezing to form solid precipitates has been used to create granular GMR materials. Some metals are immiscible in

203-399: A separate group of feldspars, and sometimes they are classified as a sub-group of alkali feldspars. The barium feldspars are monoclinic and include the following: The plagioclase feldspars are triclinic . The plagioclase series follows (with percent anorthite in parentheses): Intermediate compositions of exsolve to two feldspars of contrasting composition during cooling, but diffusion

232-616: A short distance in cold and/or dry conditions that did not promote weathering, and that it was quickly buried by other sediment. Sandstones with large amounts of feldspar are called arkoses . Feldspar is a common raw material used in glassmaking, ceramics, and to some extent as filler and an extender in paint, plastics, and rubber. In the US, about 66% of feldspar is consumed in glassmaking, including glass containers and glass fibre. Ceramics (including electrical insulators, sanitaryware, tableware and tile) and other uses, such as fillers, accounted for

261-725: A source of alkalies and alumina in glazes. The composition of feldspar used in different ceramic formulations varies depending on various factors, including the properties of the individual grade, the other raw materials and the requirements of the finished products. However, typical additions include: tableware, 15% to 30% feldspar; high-tension electrical porcelains, 25% to 35%; sanitaryware, 25%; wall tile, 0% to 10%; and dental porcelain up to 80% feldspar. Earth sciences : In earth sciences and archaeology, feldspars are used for potassium-argon dating , argon-argon dating and luminescence dating . Minor use : Some household cleaners (such as Bar Keepers Friend and Bon Ami ) use feldspar to give

290-574: A standard for partition equilibria . The straight-chain carboxylic acids up to butanoic acid (with four carbon atoms) are miscible with water, pentanoic acid (with five carbons) is partly soluble, and hexanoic acid (with six) is practically insoluble, as are longer fatty acids and other lipids ; the very long carbon chains of lipids cause them almost always to be immiscible with water. Analogous situations occur for other functional groups such as aldehydes and ketones . Immiscible metals are unable to form alloys with each other. Typically,

319-476: A three-dimensional network. Compositions of major elements in common feldspars can be expressed in terms of three endmembers : Solid solutions between K-feldspar and albite are called alkali feldspar. Solid solutions between albite and anorthite are called plagioclase , or, more properly, plagioclase feldspar. Only limited solid solution occurs between K-feldspar and anorthite, and in the two other solid solutions, immiscibility occurs at temperatures common in

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348-708: Is a group of rock-forming aluminium tectosilicate minerals , also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the plagioclase (sodium-calcium) feldspars and the alkali (potassium-sodium) feldspars. Feldspars make up about 60% of the Earth's crust and 41% of the Earth's continental crust by weight. Feldspars crystallize from magma as both intrusive and extrusive igneous rocks and are also present in many types of metamorphic rock . Rock formed almost entirely of calcic plagioclase feldspar

377-407: Is imparted upon the rock, and forms a blanket which tapers off from either side of the porphyroblast within the strain shadows. During shearing, the porphyroblast may rotate, to form a characteristic augen texture of asymmetric shearing. In this case, the position of the tails is unequal across the foliation, with some augen showing clear drag folding of the mantle into the strain shadow. This derives

406-451: Is kinked. Each crankshaft chain links to neighbouring crankshaft chains to form a three-dimensional network of fused four-member rings. The structure is open enough for cations (typically sodium, potassium, or calcium) to fit into the structure and provide charge balance. Chemical weathering of feldspars happens by hydrolysis and produces clay minerals , including illite , smectite , and kaolinite . Hydrolysis of feldspars begins with

435-667: Is known as anorthosite . Feldspars are also found in many types of sedimentary rocks . The name feldspar derives from the German Feldspat , a compound of the words Feld ("field") and Spat ("flake"). Spat had long been used as the word for "a rock easily cleaved into flakes"; Feldspat was introduced in the 18th century as a more specific term, referring perhaps to its common occurrence in rocks found in fields (Urban Brückmann, 1783) or to its occurrence as "fields" within granite and other minerals (René-Just Haüy, 1804). The change from Spat to -spar

464-449: Is much slower than in alkali feldspar, and the resulting two-feldspar intergrowths typically are too fine-grained to be visible with optical microscopes. The immiscibility gaps in the plagioclase solid solutions are complex compared to the gap in the alkali feldspars. The play of colours visible in some feldspar of labradorite composition is due to very fine-grained exsolution lamellae known as Bøggild intergrowth. The specific gravity in

493-442: Is the miscibility of water and ethanol as they mix in all proportions. By contrast, substances are said to be immiscible if the mixture does not form a solution for certain proportions. For one example, oil is not soluble in water, so these two solvents are immiscible. As another example, butanone (methyl ethyl ketone) is significantly soluble in water, but these two solvents are also immiscible because in some proportions

522-455: Is then boiled away, leaving nearly pure silver. If a mixture of polymers has lower configurational entropy than the components, they are likely to be immiscible in one another even in the liquid state. Miscibility of two materials is often determined optically. When the two miscible liquids are combined, the resulting liquid is clear. If the mixture is cloudy the two materials are immiscible. Care must be taken with this determination. If

551-463: The Earth's crust means that clays are very abundant weathering products. About 40% of minerals in sedimentary rocks are clays and clays are the dominant minerals in the most common sedimentary rocks, mudrocks . They are also an important component of soils . Feldspar that has been replaced by clay looks chalky compared to more crystalline and glassy unweathered feldspar grains. Feldspars, especially plagioclase feldspars, are not very stable at

580-420: The Earth's surface due to their high formation temperature. This lack of stability is why feldspars are easily weathered to clays. Because of this tendency to weather easily, feldspars are usually not prevalent in sedimentary rocks. Sedimentary rocks that contain large amounts of feldspar indicate that the sediment did not undergo much chemical weathering before being buried. This means it was probably transported

609-464: The alkali feldspars occur only in higher temperature environments. Sanidine is stable at the highest temperatures, and microcline at the lowest. Perthite is a typical texture in alkali feldspar, due to exsolution of contrasting alkali feldspar compositions during cooling of an intermediate composition. The perthitic textures in the alkali feldspars of many granites can be seen with the naked eye. Microperthitic textures in crystals are visible using

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638-443: The continuous Bowen's reaction series . K-feldspar is the final feldspar to crystallize from the magma. Alkali feldspars are grouped into two types: those containing potassium in combination with sodium, aluminium, or silicon; and those where potassium is replaced by barium. The first of these include: Potassium and sodium feldspars are not perfectly miscible in the melt at low temperatures, therefore intermediate compositions of

667-474: The crust of the Earth. Albite is considered both a plagioclase and alkali feldspar. The ratio of alkali feldspar to plagioclase feldspar, together with the proportion of quartz , is the basis for the QAPF classification of igneous rock. Calcium-rich plagioclase is the first feldspar to crystallize from cooling magma, then the plagioclase becomes increasingly sodium-rich as crystallization continues. This defines

696-429: The feldspar dissolving in water, which happens best in acidic or basic solutions and less well in neutral ones. The speed at which feldspars are weathered is controlled by how quickly they are dissolved. Dissolved feldspar reacts with H or OH ions and precipitates clays. The reaction also produces new ions in solution, with the variety of ions controlled by the type of feldspar reacting. The abundance of feldspars in

725-453: The liquid state. One with industrial importance is that liquid zinc and liquid silver are immiscible in liquid lead , while silver is miscible in zinc. This leads to the Parkes process , an example of liquid-liquid extraction , whereby lead containing any amount of silver is melted with zinc. The silver migrates to the zinc, which is skimmed off the top of the two-phase liquid, and the zinc

754-429: The mixture will separate into two phases . In organic compounds , the weight percent of hydrocarbon chain often determines the compound's miscibility with water. For example, among the alcohols , ethanol has two carbon atoms and is miscible with water, whereas 1-butanol with four carbons is not. 1-Octanol , with eight carbons, is practically insoluble in water, and its immiscibility leads it to be used as

783-488: The plagioclase series increases from albite (2.62) to anorthite (2.72–2.75). The structure of a feldspar crystal is based on aluminosilicate tetrahedra. Each tetrahedron consists of an aluminium or silicon ion surrounded by four oxygen ions. Each oxygen ion, in turn, is shared by a neighbouring tetrahedron to form a three-dimensional network. The structure can be visualized as long chains of aluminosilicate tetrahedra, sometimes described as crankshaft chains because their shape

812-487: The remainder. Glass : Feldspar provides both K 2 O and Na 2 O for fluxing, and Al 2 O 3 and CaO as stabilizers. As an important source of Al 2 O 3 for glassmaking, feldspar is valued for its low iron and refractory mineral content, a low cost per unit of Al 2 O 3 , no volatiles and no waste. Ceramics : Feldspars are used in the ceramic industry as a flux to form a glassy phase in bodies during firing, and thus promote vitrification. They also are used as

841-595: Was influenced by the English word spar , meaning a non-opaque mineral with good cleavage. Feldspathic refers to materials that contain feldspar. The alternate spelling, felspar , has fallen out of use. The term 'felsic', meaning light coloured minerals such as quartz and feldspars, is an acronymic word derived from fel dspar and si lica, unrelated to the obsolete spelling 'felspar'. The feldspar group of minerals consists of tectosilicates , silicate minerals in which silicon ions are linked by shared oxygen ions to form

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