Calcium oxide ( formula : Ca O ), commonly known as quicklime or burnt lime , is a widely used chemical compound . It is a white, caustic , alkaline , crystalline solid at room temperature . The broadly used term lime connotes calcium-containing inorganic compounds , in which carbonates , oxides , and hydroxides of calcium, silicon , magnesium , aluminium , and iron predominate. By contrast, quicklime specifically applies to the single compound calcium oxide. Calcium oxide that survives processing without reacting in building products , such as cement , is called free lime .
32-466: 50°51′36″N 2°22′40″W / 50.8600°N 2.3777°W / 50.8600; -2.3777 The Dorset Downs are an area of chalk downland in the centre of the county Dorset in south west England . The downs are the most western part of a larger chalk formation which also includes (from west to east) Cranborne Chase , Salisbury Plain , Hampshire Downs , Chiltern Hills , North Downs and South Downs . The Dorset Downs are bounded on
64-466: A factor of at least 2.5. Hydroxyapatite's free CaO content rises with increased calcination temperatures and longer times. It also pinpoints particular temperature cutoffs and durations that impact the production of CaO, offering information on how calcination parameters impact the composition of the material. In 80 BC, the Roman general Sertorius deployed choking clouds of caustic lime powder to defeat
96-422: A few are more recent. A mixture of chalk and mercury can be used as fingerprint powder . However, because of the toxicity of the mercury, the use of such mixtures for fingerprinting was abandoned in 1967. Quicklime Quicklime is relatively inexpensive. Both it and the chemical derivative calcium hydroxide (of which quicklime is the base anhydride ) are important commodity chemicals. Calcium oxide
128-642: Is mined from chalk deposits both above ground and underground . Chalk mining boomed during the Industrial Revolution , due to the need for chalk products such as quicklime and bricks . Most people first encounter chalk in school where it refers to blackboard chalk , which was originally made of mineral chalk, since it readily crumbles and leaves particles that stick loosely to rough surfaces, allowing it to make writing that can be readily erased. Blackboard chalk manufacturers now may use mineral chalk, other mineral sources of calcium carbonate, or
160-610: Is a fine-textured, earthy type of limestone distinguished by its light colour, softness, and high porosity. It is composed mostly of tiny fragments of the calcite shells or skeletons of plankton , such as foraminifera or coccolithophores . These fragments mostly take the form of calcite plates ranging from 0.5 to 4 microns in size, though about 10% to 25% of a typical chalk is composed of fragments that are 10 to 100 microns in size. The larger fragments include intact plankton skeletons and skeletal fragments of larger organisms, such as molluscs , echinoderms , or bryozoans . Chalk
192-399: Is a substitute for dolomitic lime as a flux in steelmaking. Because of vigorous reaction of quicklime with water, quicklime causes severe irritation when inhaled or placed in contact with moist skin or eyes. Inhalation may cause coughing, sneezing, and labored breathing. It may then evolve into burns with perforation of the nasal septum, abdominal pain, nausea and vomiting. Although quicklime
224-508: Is also the only form of limestone that commonly shows signs of compaction. Flint (a type of chert ) is very common as bands parallel to the bedding or as nodules in seams , or linings to fractures , embedded in chalk. It is probably derived from sponge spicules or other siliceous organisms as water is expelled upwards during compaction. Flint is often deposited around larger fossils such as Echinoidea which may be silicified (i.e. replaced molecule by molecule by flint). Chalk
256-428: Is applied to the hands and feet to remove perspiration and reduce slipping. Chalk may also be used as a house construction material instead of brick or wattle and daub : quarried chalk was cut into blocks and used as ashlar , or loose chalk was rammed into blocks and laid in mortar. There are still houses standing which have been constructed using chalk as the main building material. Most are pre- Victorian though
288-518: Is commonly used as a drying agent to obtain better grip by gymnasts and rock climbers. Glazing putty mainly contains chalk as a filler in linseed oil . Chalk and other forms of limestone may be used for their properties as a base . Chalk is a source of quicklime by thermal decomposition , or slaked lime following quenching of quicklime with water. In agriculture , chalk is used for raising pH in soils with high acidity . Small doses of chalk can also be used as an antacid . Additionally,
320-582: Is now usually made of talc (magnesium silicate). Chalk beds form important petroleum reservoirs in the North Sea and along the Gulf Coast of North America. In southeast England, deneholes are a notable example of ancient chalk pits. Such bell pits may also mark the sites of ancient flint mines, where the prime object was to remove flint nodules for stone tool manufacture. The surface remains at Cissbury are one such example, but perhaps
352-437: Is slower to react and may have other disadvantages compared with lime, depending on the application; however, limestone is considerably less expensive than lime. Calcined gypsum is an alternative material in industrial plasters and mortars. Cement, cement kiln dust, fly ash, and lime kiln dust are potential substitutes for some construction uses of lime. Magnesium hydroxide is a substitute for lime in pH control, and magnesium oxide
SECTION 10
#1732764725108384-604: Is so common in Cretaceous marine beds that the Cretaceous Period was named for these deposits. The name Cretaceous was derived from Latin creta , meaning chalk . Some deposits of chalk were formed after the Cretaceous. The Chalk Group is a European stratigraphic unit deposited during the late Cretaceous Period. It forms the famous White Cliffs of Dover in Kent , England, as well as their counterparts of
416-401: Is typically almost pure calcite, CaCO 3 , with just 2% to 4% of other minerals. These are usually quartz and clay minerals , though collophane (cryptocrystalline apatite , a phosphate mineral) is also sometimes present, as nodules or as small pellets interpreted as fecal pellets. In some chalk beds, the calcite has been converted to dolomite , CaMg(CO 3 ) 2 , and in a few cases
448-413: Is usually made by the thermal decomposition of materials, such as limestone or seashells , that contain calcium carbonate (CaCO 3 ; mineral calcite ) in a lime kiln . This is accomplished by heating the material to above 825 °C (1,517 °F), a process called calcination or lime-burning , to liberate a molecule of carbon dioxide (CO 2 ), leaving quicklime behind. This is also one of
480-752: The Cap Blanc Nez on the other side of the Dover Strait . The Champagne region of France is mostly underlain by chalk deposits, which contain artificial caves used for wine storage . Some of the highest chalk cliffs in the world occur at Jasmund National Park in Germany and at Møns Klint in Denmark . Chalk deposits are also found in Cretaceous beds on other continents, such as the Austin Chalk , Selma Group , and Niobrara Formations of
512-526: The Characitani of Hispania , who had taken refuge in inaccessible caves. A similar dust was used in China to quell an armed peasant revolt in 178 AD, when lime chariots equipped with bellows blew limestone powder into the crowds. Quicklime is also thought to have been a component of Greek fire . Upon contact with water, quicklime would increase its temperature above 150 °C (302 °F) and ignite
544-732: The North American interior. Chalk is also found in western Egypt (Khoman Formation) and western Australia ( Miria Formation ). Chalk of Oligocene to Neogene age has been found in drill cores of rock under the Pacific Ocean at Stewart Arch in the Solomon Islands . There are layers of chalk, containing Globorotalia , in the Nicosia Formation of Cyprus , which formed during the Pliocene . Chalk
576-548: The chalk came mostly form low-magnesium calcite skeletons, so the sediments were already in the form of highly stable low-magnesium calcite when deposited. This is in contrast with most other limestones, which formed from high-magnesium calcite or aragonite that rapidly converted to the more stable low-magnesium calcite after deposition, resulting in the early cementation of such limestones. In chalk, absence of this calcium carbonate conversion process prevented early cementation, which partially accounts for chalk's high porosity. Chalk
608-713: The chalk disappears beneath the Bagshot Beds which form the heathlands of the county, between Dorchester and Wareham . South of the River Frome , the chalk reappears in a narrower strip, forming coastal cliffs east of Weymouth and, further east, the steep ridge of the Purbeck Hills . This southerly strip of the visible chalk (sometimes referred to as the South Dorset Downs or South Dorset Ridgeway ) continues westwards behind Weymouth, and rejoins
640-494: The dolomitized chalk has been dedolomitized back to calcite. Chalk is highly porous, with typical values of porosity ranging from 35 to 47 per cent. While it is similar in appearance to both gypsum and diatomite , chalk is identifiable by its hardness, fossil content, and its reaction to acid (it produces effervescence on contact). In Western Europe, chalk was formed in the Late Cretaceous Epoch and
672-437: The early Palaeocene Epoch (between 100 and 61 million years ago). It was deposited on extensive continental shelves at depths between 100 and 600 metres (330 and 1,970 ft), during a time of nonseasonal (likely arid) climate that reduced the amount of erosion from nearby exposed rock. The lack of nearby erosion explains the high purity of chalk. The coccolithophores, foraminifera, and other microscopic organisms from which
SECTION 20
#1732764725108704-401: The few chemical reactions known in prehistoric times. The quicklime is not stable and, when cooled, will spontaneously react with CO 2 from the air until, after enough time, it will be completely converted back to calcium carbonate unless slaked with water to set as lime plaster or lime mortar . Annual worldwide production of quicklime is around 283 million tonnes. China is by far
736-551: The fuel. David Hume , in his History of England , recounts that early in the reign of Henry III , the English Navy destroyed an invading French fleet by blinding the enemy fleet with quicklime. Quicklime may have been used in medieval naval warfare – up to the use of "lime-mortars" to throw it at the enemy ships. Limestone is a substitute for lime in many applications, which include agriculture, fluxing, and sulfur removal. Limestone, which contains less reactive material,
768-555: The level of the water table. The downs are the native home to the Dorset Down sheep . Chalk Chalk is a soft, white, porous , sedimentary carbonate rock . It is a form of limestone composed of the mineral calcite and originally formed deep under the sea by the compression of microscopic plankton that had settled to the sea floor . Chalk is common throughout Western Europe , where deposits underlie parts of France, and steep cliffs are often seen where they meet
800-675: The main body of the downs at their western extremity at Eggardon Hill . In the west the chalk dips down under marl . Together with Cranborne Chase, the Dorset Downs have been designated as National Character Area 134 by Natural England , the UK Government's advisor on the natural environment. In Dorset this area is bounded by the Dorset Heaths and Weymouth Lowlands to the south, the Marshwood and Powerstock Vales to
832-528: The mineral gypsum ( calcium sulfate ). While gypsum-based blackboard chalk is the lowest cost to produce, and thus widely used in the developing world , use of carbonate-based chalk produces larger particles and thus less dust, and it is marketed as "dustless chalk". Coloured chalks, pastel chalks, and sidewalk chalk (shaped into larger sticks and often coloured), used to draw on sidewalks , streets, and driveways , are primarily made of gypsum rather than calcium carbonate chalk. Magnesium carbonate chalk
864-562: The most famous is the extensive complex at Grimes Graves in Norfolk . Chalk was traditionally used in recreation. In field sports, such as tennis played on grass, powdered chalk was used to mark the boundary lines of the playing field or court. If a ball hits the line, a cloud of chalk or pigment dust will be visible. In recent years, powdered chalk has been replaced with titanium dioxide . In gymnastics, rock-climbing, weightlifting and tug of war , chalk — now usually magnesium carbonate —
896-577: The north, along the steep scarp face, by the Blackmore Vale , a large clay and limestone valley . On the east, the Downs were once, thousands of years ago, continuous with Cranborne Chase, but the River Stour now cuts a valley between them, which is the location of Blandford Forum and the eastern boundary of the downs. From the northern scarp face, the hills dip gently southwards before
928-562: The sea in places such as the Dover cliffs on the Kent coast of the English Channel . Chalk is mined for use in industry, such as for quicklime , bricks and builder's putty , and in agriculture , for raising pH in soils with high acidity . It is also used for " blackboard chalk " for writing and drawing on various types of surfaces, although these can also be manufactured from other carbonate-based minerals, or gypsum . Chalk
960-436: The small particles of chalk make it a substance ideal for cleaning and polishing. For example, toothpaste commonly contains small amounts of chalk, which serves as a mild abrasive . Polishing chalk is chalk prepared with a carefully controlled grain size, for very fine polishing of metals. French chalk (also known as tailor's chalk) is traditionally a hard chalk used to make temporary markings on cloth, mainly by tailors . It
992-497: The west and the Blackmore Vale to the north. The main land uses on the downs are arable agriculture , woodland and calcareous grassland , a habitat which is growing as farmers are encouraged to set aside land with subsidies . Chalk is a rough rock and the Dorset Downs hold a large water table which acts as a reservoir of drinking water for much of the county. This property of chalk also means there are many seasonal rivers, called winterbournes , that flow depending upon
Dorset Downs - Misplaced Pages Continue
1024-422: The world's largest producer, with a total of around 170 million tonnes per year. The United States is the next largest, with around 20 million tonnes per year. Approximately 1.8 t of limestone is required per 1.0 t of quicklime. Quicklime has a high affinity for water and is a more efficient desiccant than silica gel . The reaction of quicklime with water is associated with an increase in volume by
#107892