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Dark state

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In atomic physics , a dark state refers to a state of an atom or molecule that cannot absorb (or emit) photons. All atoms and molecules are described by quantum states ; different states can have different energies and a system can make a transition from one energy level to another by emitting or absorbing one or more photons . However, not all transitions between arbitrary states are allowed. A state that cannot absorb an incident photon is called a dark state. This can occur in experiments using laser light to induce transitions between energy levels, when atoms can spontaneously decay into a state that is not coupled to any other level by the laser light, preventing the atom from absorbing or emitting light from that state.

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74-437: A dark state can also be the result of quantum interference in a three-level system, when an atom is in a coherent superposition of two states, both of which are coupled by lasers at the right frequency to a third state. With the system in a particular superposition of the two states, the system can be made dark to both lasers as the probability of absorbing a photon goes to 0. Experiments in atomic physics are often done with

148-672: A wavefunction solution of the Schrödinger equation for a quantum mechanical object. Then the probability P ( x ) {\displaystyle P(x)} of observing the object at position x {\displaystyle x} is P ( x ) = | Ψ ( x , t ) | 2 = Ψ ∗ ( x , t ) Ψ ( x , t ) {\displaystyle P(x)=|\Psi (x,t)|^{2}=\Psi ^{*}(x,t)\Psi (x,t)} where * indicates complex conjugation . Quantum interference concerns

222-445: A 'spectrum' of fringe patterns each of slightly different spacing. If all the fringe patterns are in phase in the centre, then the fringes will increase in size as the wavelength decreases and the summed intensity will show three to four fringes of varying colour. Young describes this very elegantly in his discussion of two slit interference. Since white light fringes are obtained only when the two waves have travelled equal distances from

296-576: A bright state. Therefore, in a collection of atoms, over time, decay into the dark state will inevitably result in the system being "trapped" coherently in that state, a phenomenon known as coherent population trapping . Quantum interference In physics , interference is a phenomenon in which two coherent waves are combined by adding their intensities or displacements with due consideration for their phase difference . The resultant wave may have greater intensity ( constructive interference ) or lower amplitude ( destructive interference ) if

370-400: A certain polarization. Consider for example the hydrogen atom. The transition from the state 1 2 S 1 / 2 {\displaystyle 1^{2}S_{1/2}} with m j =-1/2 to the state 2 2 P 3 / 2 {\displaystyle 2^{2}P_{3/2}} with m j =-1/2 is only allowed for light with polarization along

444-411: A fully stable digital state. Metastability in the brain is a phenomenon studied in computational neuroscience to elucidate how the human brain recognizes patterns. Here, the term metastability is used rather loosely. There is no lower-energy state, but there are semi-transient signals in the brain that persist for a while and are different than the usual equilibrium state. Gilbert Simondon invokes

518-450: A laser of a specific frequency ω {\displaystyle \omega } (meaning the photons have a specific energy), so they only couple one set of states with a particular energy E 1 {\displaystyle E_{1}} to another set of states with an energy E 2 = E 1 + ℏ ω {\displaystyle E_{2}=E_{1}+\hbar \omega } . However,

592-581: A mixing angle θ {\displaystyle \theta } as with This means that when the atoms are in this state, they will stay in this state indefinitely. This is a dark state, because it can not absorb or emit any photons from the applied fields. It is, therefore, effectively transparent to the probe laser, even when the laser is exactly resonant with the transition. Spontaneous emission from | 3 ⟩ {\displaystyle |3\rangle } can result in an atom being in this dark state or another coherent state, known as

666-454: A narrow spectrum of frequency waves of finite duration (but shorter than their coherence time), will give a series of fringe patterns of slightly differing spacings, and provided the spread of spacings is significantly less than the average fringe spacing, a fringe pattern will again be observed during the time when the two waves overlap. Conventional light sources emit waves of differing frequencies and at different times from different points in

740-413: A sense, an electron that happens to find itself in a metastable configuration is trapped there. Since transitions from a metastable state are not impossible (merely less likely), the electron will eventually decay to a less energetic state, typically by an electric quadrupole transition, or often by non-radiative de-excitation (e.g., collisional de-excitation). This slow-decay property of a metastable state

814-598: A single grain causes large parts of it to collapse. The avalanche is a well-known problem with large piles of snow and ice crystals on steep slopes. In dry conditions, snow slopes act similarly to sandpiles. An entire mountainside of snow can suddenly slide due to the presence of a skier, or even a loud noise or vibration. Aggregated systems of subatomic particles described by quantum mechanics ( quarks inside nucleons , nucleons inside atomic nuclei , electrons inside atoms , molecules , or atomic clusters ) are found to have many distinguishable states. Of these, one (or

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888-426: A single laser beam is used in interferometry, though interference has been observed using two independent lasers whose frequencies were sufficiently matched to satisfy the phase requirements. This has also been observed for widefield interference between two incoherent laser sources. It is also possible to observe interference fringes using white light. A white light fringe pattern can be considered to be made up of

962-493: A small degenerate set ) is indefinitely stable: the ground state or global minimum . All other states besides the ground state (or those degenerate with it) have higher energies. Of all these other states, the metastable states are the ones having lifetimes lasting at least 10 to 10 times longer than the shortest lived states of the set. A metastable state is then long-lived (locally stable with respect to configurations of 'neighbouring' energies) but not eternal (as

1036-476: A system of atoms or molecules involving a change in chemical bond can be in a metastable state, which lasts for a relatively long period of time. Molecular vibrations and thermal motion make chemical species at the energetic equivalent of the top of a round hill very short-lived. Metastable states that persist for many seconds (or years) are found in energetic valleys which are not the lowest possible valley (point 1 in illustration). A common type of metastability

1110-692: A thermodynamic trough without being at the lowest energy state is known as having kinetic stability or being kinetically persistent. The particular motion or kinetics of the atoms involved has resulted in getting stuck, despite there being preferable (lower-energy) alternatives. Metastable states of matter (also referred as metastates ) range from melting solids (or freezing liquids), boiling liquids (or condensing gases) and sublimating solids to supercooled liquids or superheated liquid-gas mixtures. Extremely pure, supercooled water stays liquid below 0 °C and remains so until applied vibrations or condensing seed doping initiates crystallization centers. This

1184-414: A wave at the original frequency, traveling to the right like its components, whose amplitude is proportional to the cosine of φ / 2 {\displaystyle \varphi /2} . A simple form of interference pattern is obtained if two plane waves of the same frequency intersect at an angle. One wave is travelling horizontally, and the other is travelling downwards at an angle θ to

1258-480: A wave of a different polarization state . Quantum mechanically the theories of Paul Dirac and Richard Feynman offer a more modern approach. Dirac showed that every quanta or photon of light acts on its own which he famously stated as "every photon interferes with itself". Richard Feynman showed that by evaluating a path integral where all possible paths are considered, that a number of higher probability paths will emerge. In thin films for example, film thickness which

1332-429: A whole (see Metastable states of matter and grain piles below). The abundance of states is more prevalent as the systems grow larger and/or if the forces of their mutual interaction are spatially less uniform or more diverse. In dynamic systems (with feedback ) like electronic circuits, signal trafficking, decisional, neural and immune systems, the time-invariance of the active or reactive patterns with respect to

1406-438: Is isomerisation . Higher energy isomers are long lived because they are prevented from rearranging to their preferred ground state by (possibly large) barriers in the potential energy . During a metastable state of finite lifetime, all state-describing parameters reach and hold stationary values. In isolation: The metastability concept originated in the physics of first-order phase transitions . It then acquired new meaning in

1480-408: Is isomerism . The stability or metastability of a given chemical system depends on its environment, particularly temperature and pressure . The difference between producing a stable vs. metastable entity can have important consequences. For instances, having the wrong crystal polymorph can result in failure of a drug while in storage between manufacture and administration. The map of which state

1554-456: Is a common situation for the droplets of atmospheric clouds. Metastable phases are common in condensed matter and crystallography. This is the case for anatase , a metastable polymorph of titanium dioxide , which despite commonly being the first phase to form in many synthesis processes due to its lower surface energy , is always metastable, with rutile being the most stable phase at all temperatures and pressures. As another example, diamond

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1628-423: Is a stable phase only at very high pressures, but is a metastable form of carbon at standard temperature and pressure . It can be converted to graphite (plus leftover kinetic energy), but only after overcoming an activation energy – an intervening hill. Martensite is a metastable phase used to control the hardness of most steel. Metastable polymorphs of silica are commonly observed. In some cases, such as in

1702-458: Is also used to refer to specific situations in mass spectrometry and spectrochemistry. A digital circuit is supposed to be found in a small number of stable digital states within a certain amount of time after an input change. However, if an input changes at the wrong moment a digital circuit which employs feedback (even a simple circuit such as a flip-flop ) can enter a metastable state and take an unbounded length of time to finally settle into

1776-403: Is an odd multiple of π . If the difference between the phases is intermediate between these two extremes, then the magnitude of the displacement of the summed waves lies between the minimum and maximum values. Consider, for example, what happens when two identical stones are dropped into a still pool of water at different locations. Each stone generates a circular wave propagating outwards from

1850-480: Is an intermediate energetic state within a dynamical system other than the system's state of least energy . A ball resting in a hollow on a slope is a simple example of metastability. If the ball is only slightly pushed, it will settle back into its hollow, but a stronger push may start the ball rolling down the slope. Bowling pins show similar metastability by either merely wobbling for a moment or tipping over completely. A common example of metastability in science

1924-423: Is apparent in phosphorescence , the kind of photoluminescence seen in glow-in-the-dark toys that can be charged by first being exposed to bright light. Whereas spontaneous emission in atoms has a typical timescale on the order of 10 seconds, the decay of metastable states can typically take milliseconds to minutes, and so light emitted in phosphorescence is usually both weak and long-lasting. In chemical systems,

1998-405: Is characterised by lifetimes on the order of 10 years (as compared with the lifetime of the universe, which is thought to be around 1.3787 × 10 years). Sandpiles are one system which can exhibit metastability if a steep slope or tunnel is present. Sand grains form a pile due to friction . It is possible for an entire large sand pile to reach a point where it is stable, but the addition of

2072-461: Is forbidden. In the rotating wave approximation , the semi-classical Hamiltonian is given by with where Ω p {\displaystyle \Omega _{p}} and Ω c {\displaystyle \Omega _{c}} are the Rabi frequencies of the probe field (of frequency ω p {\displaystyle \omega _{p}} ) and

2146-515: Is not a multiple of light wavelength will not allow the quanta to traverse, only reflection is possible. The discussion above assumes that the waves which interfere with one another are monochromatic, i.e. have a single frequency—this requires that they are infinite in time. This is not, however, either practical or necessary. Two identical waves of finite duration whose frequency is fixed over that period will give rise to an interference pattern while they overlap. Two identical waves which consist of

2220-403: Is often used for a state that is not accessible by the specific laser in use even though transitions from this state are in principle allowed. Whether or not we say a transition between a state | 1 ⟩ {\displaystyle |1\rangle } and a state | 2 ⟩ {\displaystyle |2\rangle } is allowed often depends on how detailed

2294-553: Is the wavenumber and ω = 2 π f {\displaystyle \omega =2\pi f} is the angular frequency of the wave. Suppose a second wave of the same frequency and amplitude but with a different phase is also traveling to the right W 2 ( x , t ) = A cos ⁡ ( k x − ω t + φ ) {\displaystyle W_{2}(x,t)=A\cos(kx-\omega t+\varphi )} where φ {\displaystyle \varphi }

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2368-413: Is the most stable as a function of pressure, temperature and/or composition is known as a phase diagram . In regions where a particular state is not the most stable, it may still be metastable. Reaction intermediates are relatively short-lived, and are usually thermodynamically unstable rather than metastable. The IUPAC recommends referring to these as transient rather than metastable. Metastability

2442-460: Is the phase difference between the waves in radians . The two waves will superpose and add: the sum of the two waves is W 1 + W 2 = A [ cos ⁡ ( k x − ω t ) + cos ⁡ ( k x − ω t + φ ) ] . {\displaystyle W_{1}+W_{2}=A[\cos(kx-\omega t)+\cos(kx-\omega t+\varphi )].} Using

2516-563: Is used to divide the light into two beams travelling in different directions, which are then superimposed to produce the interference pattern. The Michelson interferometer and the Mach–Zehnder interferometer are examples of amplitude-division systems. In wavefront-division systems, the wave is divided in space—examples are Young's double slit interferometer and Lloyd's mirror . Interference can also be seen in everyday phenomena such as iridescence and structural coloration . For example,

2590-1103: The Hermitian conjugate of the entire expression. We will write the atomic wave function as Solving the Schrödinger equation i ℏ | ψ ˙ ⟩ = H | ψ ⟩ {\displaystyle i\hbar |{\dot {\psi }}\rangle =H|\psi \rangle } , we obtain the solutions c ˙ 1 = i 2 Ω p c 3 {\displaystyle {\dot {c}}_{1}={\frac {i}{2}}\Omega _{p}c_{3}} c ˙ 2 = i 2 Ω c c 3 {\displaystyle {\dot {c}}_{2}={\frac {i}{2}}\Omega _{c}c_{3}} c ˙ 3 = i 2 ( Ω p c 1 + Ω c c 2 ) . {\displaystyle {\dot {c}}_{3}={\frac {i}{2}}(\Omega _{p}c_{1}+\Omega _{c}c_{2}).} Using

2664-488: The allotropes of solid boron , acquiring a sample of the stable phase is difficult. The bonds between the building blocks of polymers such as DNA , RNA , and proteins are also metastable. Adenosine triphosphate (ATP) is a highly metastable molecule, colloquially described as being "full of energy" that can be used in many ways in biology. Generally speaking, emulsions / colloidal systems and glasses are metastable. The metastability of silica glass, for example,

2738-786: The trigonometric identity for the sum of two cosines: cos ⁡ a + cos ⁡ b = 2 cos ⁡ ( a − b 2 ) cos ⁡ ( a + b 2 ) , {\textstyle \cos a+\cos b=2\cos \left({a-b \over 2}\right)\cos \left({a+b \over 2}\right),} this can be written W 1 + W 2 = 2 A cos ⁡ ( φ 2 ) cos ⁡ ( k x − ω t + φ 2 ) . {\displaystyle W_{1}+W_{2}=2A\cos \left({\varphi \over 2}\right)\cos \left(kx-\omega t+{\varphi \over 2}\right).} This represents

2812-628: The atom can remain in this excited state for a very long time, such an excited state is called a metastable state . We start with a three-state Λ-type system, where | 1 ⟩ ↔ | 3 ⟩ {\displaystyle |1\rangle \leftrightarrow |3\rangle } and | 2 ⟩ ↔ | 3 ⟩ {\displaystyle |2\rangle \leftrightarrow |3\rangle } are dipole-allowed transitions and | 1 ⟩ ↔ | 2 ⟩ {\displaystyle |1\rangle \leftrightarrow |2\rangle }

2886-414: The atom can still decay spontaneously into a third state by emitting a photon of a different frequency. The new state with energy E 3 < E 2 {\displaystyle E_{3}<E_{2}} of the atom no longer interacts with the laser simply because no photons of the right frequency are present to induce a transition to a different level. In practice, the term dark state

2960-434: The colours seen in a soap bubble arise from interference of light reflecting off the front and back surfaces of the thin soap film. Depending on the thickness of the film, different colours interfere constructively and destructively. Quantum interference – the observed wave-behavior of matter – resembles optical interference . Let Ψ ( x , t ) {\displaystyle \Psi (x,t)} be

3034-402: The converse, then multiplies both sides by e i 2 π N . {\displaystyle e^{i{\frac {2\pi }{N}}}.} The Fabry–Pérot interferometer uses interference between multiple reflections. A diffraction grating can be considered to be a multiple-beam interferometer; since the peaks which it produces are generated by interference between

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3108-450: The coupling field (of frequency ω c {\displaystyle \omega _{c}} ) in resonance with the transition frequencies ω 3 − ω 1 {\displaystyle \omega _{3}-\omega _{1}} and ω 3 − ω 2 {\displaystyle \omega _{3}-\omega _{2}} , respectively, and H.c. stands for

3182-421: The distance between the sources increases from left to right. When the plane of observation is far enough away, the fringe pattern will be a series of almost straight lines, since the waves will then be almost planar. Interference occurs when several waves are added together provided that the phase differences between them remain constant over the observation time. It is sometimes desirable for several waves of

3256-410: The energy is redistributed to other areas. For example, when two pebbles are dropped in a pond, a pattern is observable; but eventually waves continue, and only when they reach the shore is the energy absorbed away from the medium. Constructive interference occurs when the phase difference between the waves is an even multiple of π (180°), whereas destructive interference occurs when the difference

3330-414: The external influences defines stability and metastability (see brain metastability below). In these systems, the equivalent of thermal fluctuations in molecular systems is the " white noise " that affects signal propagation and the decision-making. Non-equilibrium thermodynamics is a branch of physics that studies the dynamics of statistical ensembles of molecules via unstable states. Being "stuck" in

3404-404: The famous double-slit experiment , laser speckle , anti-reflective coatings and interferometers . In addition to classical wave model for understanding optical interference, quantum matter waves also demonstrate interference. The above can be demonstrated in one dimension by deriving the formula for the sum of two waves. The equation for the amplitude of a sinusoidal wave traveling to

3478-493: The figure above and to the right as stationary blue-green lines radiating from the centre. Interference of light is a unique phenomenon in that we can never observe superposition of the EM field directly as we can, for example, in water. Superposition in the EM field is an assumed phenomenon and necessary to explain how two light beams pass through each other and continue on their respective paths. Prime examples of light interference are

3552-493: The first wave. Assuming that the two waves are in phase at the point B , then the relative phase changes along the x -axis. The phase difference at the point A is given by Δ φ = 2 π d λ = 2 π x sin ⁡ θ λ . {\displaystyle \Delta \varphi ={\frac {2\pi d}{\lambda }}={\frac {2\pi x\sin \theta }{\lambda }}.} It can be seen that

3626-409: The frequency of light waves (~10 Hz) is too high for currently available detectors to detect the variation of the electric field of the light, it is possible to observe only the intensity of an optical interference pattern. The intensity of the light at a given point is proportional to the square of the average amplitude of the wave. This can be expressed mathematically as follows. The displacement of

3700-546: The global minimum is). Being excited – of an energy above the ground state – it will eventually decay to a more stable state, releasing energy. Indeed, above absolute zero , all states of a system have a non-zero probability to decay; that is, to spontaneously fall into another state (usually lower in energy). One mechanism for this to happen is through tunnelling . Some energetic states of an atomic nucleus (having distinct spatial mass, charge, spin, isospin distributions) are much longer-lived than others ( nuclear isomers of

3774-546: The initial condition we can solve these equations to obtain with Ω = Ω c 2 + Ω p 2 {\displaystyle \Omega ={\sqrt {\Omega _{c}^{2}+\Omega _{p}^{2}}}} . We observe that we can choose the initial conditions which gives a time-independent solution to these equations with no probability of the system being in state | 3 ⟩ {\displaystyle |3\rangle } . This state can also be expressed in terms of

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3848-595: The intensities of the individual waves as I ( r ) = I 1 ( r ) + I 2 ( r ) + 2 I 1 ( r ) I 2 ( r ) cos ⁡ [ φ 1 ( r ) − φ 2 ( r ) ] . {\displaystyle I(\mathbf {r} )=I_{1}(\mathbf {r} )+I_{2}(\mathbf {r} )+2{\sqrt {I_{1}(\mathbf {r} )I_{2}(\mathbf {r} )}}\cos[\varphi _{1}(\mathbf {r} )-\varphi _{2}(\mathbf {r} )].} Thus,

3922-577: The interference pattern maps out the difference in phase between the two waves, with maxima occurring when the phase difference is a multiple of 2 π . If the two beams are of equal intensity, the maxima are four times as bright as the individual beams, and the minima have zero intensity. Classically the two waves must have the same polarization to give rise to interference fringes since it is not possible for waves of different polarizations to cancel one another out or add together. Instead, when waves of different polarization are added together, they give rise to

3996-486: The invention of the laser was done using such sources and had a wide range of successful applications. A laser beam generally approximates much more closely to a monochromatic source, and thus it is much more straightforward to generate interference fringes using a laser. The ease with which interference fringes can be observed with a laser beam can sometimes cause problems in that stray reflections may give spurious interference fringes which can result in errors. Normally,

4070-1112: The issue of this probability when the wavefunction is expressed as a sum or linear superposition of two terms Ψ ( x , t ) = Ψ A ( x , t ) + Ψ B ( x , t ) {\displaystyle \Psi (x,t)=\Psi _{A}(x,t)+\Psi _{B}(x,t)} : P ( x ) = | Ψ ( x , t ) | 2 = | Ψ A ( x , t ) | 2 + | Ψ B ( x , t ) | 2 + ( Ψ A ∗ ( x , t ) Ψ B ( x , t ) + Ψ A ( x , t ) Ψ B ∗ ( x , t ) ) {\displaystyle P(x)=|\Psi (x,t)|^{2}=|\Psi _{A}(x,t)|^{2}+|\Psi _{B}(x,t)|^{2}+(\Psi _{A}^{*}(x,t)\Psi _{B}(x,t)+\Psi _{A}(x,t)\Psi _{B}^{*}(x,t))} Metastable state In chemistry and physics , metastability

4144-801: The light at r is given by I ( r ) = ∫ U ( r , t ) U ∗ ( r , t ) d t ∝ A 1 2 ( r ) + A 2 2 ( r ) + 2 A 1 ( r ) A 2 ( r ) cos ⁡ [ φ 1 ( r ) − φ 2 ( r ) ] . {\displaystyle I(\mathbf {r} )=\int U(\mathbf {r} ,t)U^{*}(\mathbf {r} ,t)\,dt\propto A_{1}^{2}(\mathbf {r} )+A_{2}^{2}(\mathbf {r} )+2A_{1}(\mathbf {r} )A_{2}(\mathbf {r} )\cos[\varphi _{1}(\mathbf {r} )-\varphi _{2}(\mathbf {r} )].} This can be expressed in terms of

4218-415: The light source, they can be very useful in interferometry, as they allow the zero path difference fringe to be identified. To generate interference fringes, light from the source has to be divided into two waves which then have to be re-combined. Traditionally, interferometers have been classified as either amplitude-division or wavefront-division systems. In an amplitude-division system, a beam splitter

4292-418: The light transmitted by each of the elements in the grating; see interference vs. diffraction for further discussion. Mechanical and gravity waves can be directly observed: they are real-valued wave functions; optical and matter waves cannot be directly observed: they are complex valued wave functions . Some of the differences between real valued and complex valued wave interference include: Because

4366-679: The magnitude of the displacement, φ represents the phase and ω represents the angular frequency . The displacement of the summed waves is U ( r , t ) = A 1 ( r ) e i [ φ 1 ( r ) − ω t ] + A 2 ( r ) e i [ φ 2 ( r ) − ω t ] . {\displaystyle U(\mathbf {r} ,t)=A_{1}(\mathbf {r} )e^{i[\varphi _{1}(\mathbf {r} )-\omega t]}+A_{2}(\mathbf {r} )e^{i[\varphi _{2}(\mathbf {r} )-\omega t]}.} The intensity of

4440-478: The model is that we use for the atom-light interaction. From a particular model follow a set of selection rules that determine which transitions are allowed and which are not. Often these selection rules can be boiled down to conservation of angular momentum (the photon has angular momentum). In most cases we only consider an atom interacting with the electric dipole field of the photon. Then some transitions are not allowed at all, others are only allowed for photons of

4514-416: The point where the stone was dropped. When the two waves overlap, the net displacement at a particular point is the sum of the displacements of the individual waves. At some points, these will be in phase, and will produce a maximum displacement. In other places, the waves will be in anti-phase, and there will be no net displacement at these points. Thus, parts of the surface will be stationary—these are seen in

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4588-394: The right along the x-axis is W 1 ( x , t ) = A cos ⁡ ( k x − ω t ) {\displaystyle W_{1}(x,t)=A\cos(kx-\omega t)} where A {\displaystyle A} is the peak amplitude, k = 2 π / λ {\displaystyle k=2\pi /\lambda }

4662-604: The same isotope ), e.g. technetium-99m . The isotope tantalum-180m , although being a metastable excited state, is long-lived enough that it has never been observed to decay, with a half-life calculated to be least 4.5 × 10 years, over 3 million times the current age of the universe . Some atomic energy levels are metastable. Rydberg atoms are an example of metastable excited atomic states. Transitions from metastable excited levels are typically those forbidden by electric dipole selection rules . This means that any transitions from this level are relatively unlikely to occur. In

4736-1205: The same frequency and amplitude to sum to zero (that is, interfere destructively, cancel). This is the principle behind, for example, 3-phase power and the diffraction grating . In both of these cases, the result is achieved by uniform spacing of the phases. It is easy to see that a set of waves will cancel if they have the same amplitude and their phases are spaced equally in angle. Using phasors , each wave can be represented as A e i φ n {\displaystyle Ae^{i\varphi _{n}}} for N {\displaystyle N} waves from n = 0 {\displaystyle n=0} to n = N − 1 {\displaystyle n=N-1} , where φ n − φ n − 1 = 2 π N . {\displaystyle \varphi _{n}-\varphi _{n-1}={\frac {2\pi }{N}}.} To show that ∑ n = 0 N − 1 A e i φ n = 0 {\displaystyle \sum _{n=0}^{N-1}Ae^{i\varphi _{n}}=0} one merely assumes

4810-443: The same point, then the amplitude is the sum of the individual amplitudes—this is constructive interference. If a crest of one wave meets a trough of another wave, then the amplitude is equal to the difference in the individual amplitudes—this is known as destructive interference. In ideal mediums (water, air are almost ideal) energy is always conserved, at points of destructive interference, the wave amplitudes cancel each other out, and

4884-606: The source. If the light is split into two waves and then re-combined, each individual light wave may generate an interference pattern with its other half, but the individual fringe patterns generated will have different phases and spacings, and normally no overall fringe pattern will be observable. However, single-element light sources, such as sodium- or mercury-vapor lamps have emission lines with quite narrow frequency spectra. When these are spatially and colour filtered, and then split into two waves, they can be superimposed to generate interference fringes. All interferometry prior to

4958-469: The study of aggregated subatomic particles (in atomic nuclei or in atoms) or in molecules, macromolecules or clusters of atoms and molecules. Later, it was borrowed for the study of decision-making and information transmission systems. Metastability is common in physics and chemistry – from an atom (many-body assembly) to statistical ensembles of molecules ( viscous fluids , amorphous solids , liquid crystals , minerals , etc.) at molecular levels or as

5032-453: The two waves are in phase or out of phase, respectively. Interference effects can be observed with all types of waves, for example, light , radio , acoustic , surface water waves , gravity waves , or matter waves as well as in loudspeakers as electrical waves. The word interference is derived from the Latin words inter which means "between" and fere which means "hit or strike", and

5106-626: The two waves are in phase when x sin ⁡ θ λ = 0 , ± 1 , ± 2 , … , {\displaystyle {\frac {x\sin \theta }{\lambda }}=0,\pm 1,\pm 2,\ldots ,} and are half a cycle out of phase when x sin ⁡ θ λ = ± 1 2 , ± 3 2 , … {\displaystyle {\frac {x\sin \theta }{\lambda }}=\pm {\frac {1}{2}},\pm {\frac {3}{2}},\ldots } Constructive interference occurs when

5180-690: The two waves at a point r is: U 1 ( r , t ) = A 1 ( r ) e i [ φ 1 ( r ) − ω t ] {\displaystyle U_{1}(\mathbf {r} ,t)=A_{1}(\mathbf {r} )e^{i[\varphi _{1}(\mathbf {r} )-\omega t]}} U 2 ( r , t ) = A 2 ( r ) e i [ φ 2 ( r ) − ω t ] {\displaystyle U_{2}(\mathbf {r} ,t)=A_{2}(\mathbf {r} )e^{i[\varphi _{2}(\mathbf {r} )-\omega t]}} where A represents

5254-469: The two waves overlap and the fringe spacing is uniform throughout. A point source produces a spherical wave. If the light from two point sources overlaps, the interference pattern maps out the way in which the phase difference between the two waves varies in space. This depends on the wavelength and on the separation of the point sources. The figure to the right shows interference between two spherical waves. The wavelength increases from top to bottom, and

5328-520: The waves are in phase, and destructive interference when they are half a cycle out of phase. Thus, an interference fringe pattern is produced, where the separation of the maxima is d f = λ sin ⁡ θ {\displaystyle d_{f}={\frac {\lambda }{\sin \theta }}} and d f is known as the fringe spacing. The fringe spacing increases with increase in wavelength , and with decreasing angle θ . The fringes are observed wherever

5402-494: The z axis (quantization axis) of the atom. The state 2 2 P 3 / 2 {\displaystyle 2^{2}P_{3/2}} with m j =-1/2 therefore appears dark for light of other polarizations. Transitions from the 2S level to the 1S level are not allowed at all. The 2S state can not decay to the ground state by emitting a single photon. It can only decay by collisions with other atoms or by emitting multiple photons. Since these events are rare,

5476-406: Was used in the context of wave superposition by Thomas Young in 1801. The principle of superposition of waves states that when two or more propagating waves of the same type are incident on the same point, the resultant amplitude at that point is equal to the vector sum of the amplitudes of the individual waves. If a crest of a wave meets a crest of another wave of the same frequency at

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