Hulu Langat District is a district of Malaysia located in the southeastern corner of Selangor , between Kuala Lumpur and Negeri Sembilan . It is bordered by the state of Pahang to the east and north, Gombak district to the north-west, Federal Territory of Kuala Lumpur and Petaling district to the west, Sepang district to the south-west, and state of Negeri Sembilan to the south.
71-695: Kajang is a town in Hulu Langat District , Selangor , Malaysia , located southeast of Kuala Lumpur . Kajang, along with much of Hulu Langat District, is governed by the Kajang Municipal Council . Kajang town is located on the eastern banks of the Langat River . It is surrounded by Cheras , Semenyih , Bangi , Putrajaya and Serdang . According to the 2020 census, the local authority area (which includes Kajang, Cheras, Balakong, Bangi, Semenyih and Pekan Hulu Langat) has
142-498: A covalent structure in which electrons cannot move freely. α-tin is a dull-gray powdery material with no common uses other than specialized semiconductor applications. γ-tin and σ-tin exist at temperatures above 161 °C (322 °F) and pressures above several GPa . In cold conditions β-tin tends to transform spontaneously into α-tin, a phenomenon known as " tin pest " or "tin disease". Some unverifiable sources also say that, during Napoleon 's Russian campaign of 1812,
213-438: A superconductor below 3.72 K and was one of the first superconductors to be studied. The Meissner effect , one of the characteristic features of superconductors, was first discovered in superconducting tin crystals. Tin resists corrosion from water , but can be corroded by acids and alkalis . Tin can be highly polished and is used as a protective coat for other metals. When heated in air it oxidizes slowly to form
284-553: A high neutron capture cross section for fast neutrons, at 30 barns . Tin-117 has a cross section of 2.3 barns, one order of magnitude smaller, while tin-119 has a slightly smaller cross section of 2.2 barns. Before these cross sections were well known, it was proposed to use tin-lead solder as a coolant for fast reactors because of its low melting point. Current studies are for lead or lead-bismuth reactor coolants because both heavy metals are nearly transparent to fast neutrons, with very low capture cross sections. In order to use
355-541: A major "tin crisis" ensued—tin was delisted from trading on the London Metal Exchange for about three years. ITC dissolved soon afterward, and the price of tin, now in a free-market environment, fell to $ 4 per pound and remained around that level through the 1990s. The price increased again by 2010 with a rebound in consumption following the 2007–2008 economic crisis , accompanying restocking and continued growth in consumption. London Metal Exchange (LME)
426-509: A marathon. There are two hots spring in Hulu Langat one is Dusun Tua Hot Spring located at 16th mile and Sungai Serai Hot Spring. Balakong consists of various shopping malls that are frequented by tourists and locals, such as AEON (Jusco) Cheras Selatan Balakong. Kajang town on the other hand is famous for its satay, which is very popular amongst the locals as well as tourists. Pekan Batu 14 Hulu Langat Pekan Batu 14 Hulu Langat
497-525: A median income of RM8361 (2019), which is the fourth highest in the state and country behind Petaling, Sepang and Gombak. The figure is higher than both the state, RM8210 (2019) and national median income of RM5873 (2019). According to the Department of Statistics, Malaysia, Hulu Langat's population increased from 1,138,198 in 2010 to 1,400,416 in 2020. The following is based on the Department of Statistics Malaysia 2020 forecast. Hulu Langat District
568-423: A nuclear spin of 1/2. It is thought that tin has such a great multitude of stable isotopes because of tin's atomic number being 50, which is a " magic number " in nuclear physics. Tin is one of the easiest elements to detect and analyze by NMR spectroscopy , which relies on molecular weight and its chemical shifts are referenced against tetramethyltin ( SnMe 4 ). Of the stable isotopes, tin-115 has
639-545: A population of 1,400,461 at the 2020 Census (provisional result). It is also the second most densely populated district with approximately 1688 people per km . It has a mix of urban and rural settlements with a majority of the population settling in towns near Kuala Lumpur . These population centers, such as Cheras and Ampang effectively became suburbs of the greater metropolitan area (both Cheras and Ampang are communities now divided administratively between Kuala Lumpur Federal Territory and Selangor State). Hulu Langat has
710-534: A population of 1.05 million people. The name Kajang is believed to have originated from the language of Temuan tribes ( Orang Asli ) who populated the Langat valley in the 17th-18th centuries. In their language kajang referred to their art of weaving screwpine or pandanus leaves, which were prevalent in much of the country. A similar theory stated that settlers from the neighboring domain of Sungai Ujong ( Negeri Sembilan ) once constructed huts ( pondok ) in
781-469: A thin passivation layer of stannic oxide ( SnO 2 ) that inhibits further oxidation. Tin has ten stable isotopes , the greatest number of any element. Their mass numbers are 112, 114, 115, 116, 117, 118, 119, 120, 122, and 124. Tin-120 makes up almost a third of all tin. Tin-118 and tin-116 are also common. Tin-115 is the least common stable isotope. The isotopes with even mass numbers have no nuclear spin , while those with odd mass numbers have
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#1732772230470852-608: A tin or tin-lead coolant, the tin would first have to go through isotopic separation to remove the isotopes with odd mass number. Combined, these three isotopes make up about 17% of natural tin but represent nearly all of the capture cross section. Of the remaining seven isotopes tin-112 has a capture cross section of 1 barn. The other six isotopes forming 82.7% of natural tin have capture cross sections of 0.3 barns or less, making them effectively transparent to neutrons. Tin has 31 unstable isotopes, ranging in mass number from 99 to 139. The unstable tin isotopes have half-lives of less than
923-448: A year except for tin-126 , which has a half-life of about 230,000 years. Tin-100 and tin-132 are two of the very few nuclides with a " doubly magic " nucleus which despite being unstable, as they have very uneven neutron–proton ratios , are the endpoints beyond which tin isotopes lighter than tin-100 and heavier than tin-132 are much less stable. Another 30 metastable isomers have been identified for tin isotopes between 111 and 131,
994-410: Is corrosion -resistant tin plating of steel . Because of the low toxicity of inorganic tin, tin-plated steel is widely used for food packaging as " tin cans ". Some organotin compounds can be extremely toxic. Tin is a soft, malleable , ductile and highly crystalline silvery-white metal . When a bar of tin is bent a crackling sound known as the " tin cry " can be heard from the twinning of
1065-607: Is 22 km from Kuala Lumpur , 8 km from Semenyih and 43 km from Seremban . A stretch of Federal Route 1 is concurrent with the Cheras-Kajang toll road (aka the Grand Saga Expressway ) between Taman Connaught and Bukit Dukung. The SILK Expressway starts in Serdang , which then runs through Balakong and then forms a beltway around downtown Kajang before ending near Bandar Baru Bangi . It
1136-417: Is a chemical element ; it has symbol Sn (from Latin stannum ) and atomic number 50. A silvery-colored metal, tin is soft enough to be cut with little force, and a bar of tin can be bent by hand with little effort. When bent, the so-called " tin cry " can be heard as a result of twinning in tin crystals. Tin is a post-transition metal in group 14 of the periodic table of elements. It
1207-620: Is an old town which 14 miles from Kuala Lumpur. Landmark - Masjid Sultan Hisamuddin Alam Shah - Dewan Dato Nazir Hulu Langat - Balai Polis Pekan Batu 14 Hulu Langat Pekan Batu 18 Hulu Langat Pekan Batu 18 Hulu Langat is an old town which 18 miles from Kuala Lumpur. It is also a Famous Place for Cycling Gathering Point Landmark - Balai Polis Pekan Batu 18 Hulu Langat - SJK (C) CHOON HWA [REDACTED] Media related to Hulu Langat District at Wikimedia Commons Tin Tin
1278-562: Is divided into 7 mukims , which are: List of Hulu Langat district representatives in the Federal Parliament (Dewan Rakyat) List of Hulu Langat district representatives in the State Legislative Assembly (Dewan Undangan Negeri) Hentian Kajang is the main bus terminal that provides access to both intercity and local destinations with Rapid Bus as the main service provider. Bus routes within
1349-473: Is evidence that Cornwall in the first centuries AD was the main source of tin. Tin extraction and use can be dated to the beginnings of the Bronze Age around 3000 BC, when it was observed that copper objects formed of polymetallic ores with different metal contents had different physical properties. The earliest bronze objects had a tin or arsenic content of less than 2% and are believed to be
1420-570: Is generated via the long s -process in low-to-medium mass stars (with masses of 0.6 to 10 times that of the Sun ), and finally by beta decay of the heavy isotopes of indium . Tin is the 49th most abundant element in Earth's crust , representing 2 ppm compared with 75 ppm for zinc, 50 ppm for copper, and 14 ppm for lead. Tin does not occur as the native element but must be extracted from various ores. Cassiterite ( SnO 2 )
1491-541: Is headquartered in Kajang. Kajang has multiple shopping complexes, amongst them is the Billion Shopping Center formerly in Kajang town, which now has relocated to Bandar Teknologi Kajang. Other shopping centres located in Kajang are Plaza Metro Kajang, Metro Point and Kompleks Kota Kajang. Metro Avenue is a new shopping district located opposite SMJK Yu Hua Kajang and Kajang High School. Kajang Hospital
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#17327722304701562-430: Is obtained chiefly from the mineral cassiterite , which contains stannic oxide , SnO 2 . Tin shows a chemical similarity to both of its neighbors in group 14, germanium and lead , and has two main oxidation states , +2 and the slightly more stable +4. Tin is the 49th most abundant element on Earth, making up 0.00022% of its crust, and with 10 stable isotopes, it has the largest number of stable isotopes in
1633-438: Is the allotrope (structural form) of elemental tin that is stable at and above room temperature. It is metallic and malleable, and has body-centered tetragonal crystal structure. α-tin, or gray tin , is the nonmetallic form. It is stable below 13.2 °C (55.8 °F) and is brittle . α-tin has a diamond cubic crystal structure, as do diamond and silicon . α-tin does not have metallic properties because its atoms form
1704-477: Is the colonial quarter near the Stadium Kajang MRT station , including the streets of Jalan Mendaling, Jalan Stadium, Jalan Sulaiman and Jalan Raja Haroun. The buildings in the area were constructed around the 1900s to 1930s. The architecture of these shophouses are a combination of traditional Chinese and European designs. The ground floor was used mostly for commercial activities and the upper floor as
1775-502: Is the main ring road for Kajang. PLUS Expressway exit 210 (Kajang Interchange) serves the vicinity of Kajang and Bangi. It also links the expressway to SILK Expressway and SKVE Expressway as well as B11 which runs concurrently with SILK and SKVE from SKVE's Serdang Interchange at Seri Kembangan until SILK's Sungai Chua Interchange at Kajang, before being detoured out of SILK after the interchange. B11 continues on its own separate route until its terminus at Stadium Kajang just before
1846-443: Is the only commercially important source of tin, although small quantities of tin are recovered from complex sulfides such as stannite , cylindrite , franckeite , canfieldite , and teallite . Minerals with tin are almost always associated with granite rock, usually at a level of 1% tin oxide content. Because of the higher specific gravity of tin dioxide, about 80% of mined tin is from secondary deposits found downstream from
1917-570: Is the primary public hospital in the city. Private medical centres function 24 hours and include facilities such as Poliklinik MUC @Metro Point , Klinik Mediviron Prima Saujana , Kajang Plaza Medical Centre (KPMC) and KPJ Kajang Specialist Hospital . The Hulu Langat District Police Headquarters are located in the town centre, across the Highway 1 junction from the Post Office. Federal government agencies with their branch in Kajang include
1988-529: Is the southern terminal of the MRT line. Kajang station, though so named, does not directly serve downtown Kajang; Stadium Kajang MRT is located in the actual downtown area, along with Sungai Jernih MRT . Kajang is famous for its satay , a form of skewered barbecued meat. Informally, Kajang is known as the Satay Town. The Malaysia Prison Complex ( Kompleks Penjara Kajang ), Prison Department of Malaysia
2059-642: Is tin's principal trading site. Other tin contract markets are Kuala Lumpur Tin Market (KLTM) and Indonesia Tin Exchange (INATIN). Due to factors involved in the 2021 global supply chain crisis , tin prices almost doubled during 2020–21 and have had their largest annual rise in over 30 years. Global refined tin consumption dropped 1.6 percent in 2020 as the COVID-19 pandemic disrupted global manufacturing industries. In 2018, just under half of all tin produced
2130-505: The r -process (rapid neutron capture) in supernovae and neutron star mergers . Tin isotopes 115, 117 through 120, and 122 are produced via both the s -process and the r -process, The two lightest stable isotopes, tin-112 and tin-114, cannot be made in significant amounts in the s - or r -processes and are among the p-nuclei whose origins are not well understood. Some theories about their formation include proton capture and photodisintegration . Tin-115 might be partially produced in
2201-622: The Malayan Emergency with fighting soon spreading to Kajang. Guerrilla leader Lau Yew died in combat just outside Kajang in July 1948; British forces photographed his corpse and printed the image onto leaflets to distribute around Kajang. Kajang was granted municipal status on 1 January 1997. Previously it was under the jurisdiction of the Hulu Langat District Council ( Majlis Daerah Hulu Langat , MDHL). Kajang
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2272-596: The Malaysia Federal Route 1 system. By railway, it is about 40 minutes' ride from KL Sentral on the MRT Kajang line . The first planned township built and developed just outside Kajang is Bandar Baru Bangi which was first developed in 1974 by the Selangor state government. As a satellite town to Kajang proper, some government offices including the district land office begin operating out of
2343-748: The SILK Expressway , Kajang-Seremban Expressway , Grand Saga Expressway and the North–South Expressway Southern Route . Some adjacent areas in the neighbouring Sepang region including Kampung Sungai Merab, Desa Pinggiran Putra and Kampung Dato Abu Bakar Baginda, though rarely regarded as part of Kajang, are included in Kajang's postal code of 43000 due to their proximity to Kajang than to Sepang town itself. The townships in Bandar Seri Putra and Bukit Mahkota, while closer to Bangi Lama (Bangi old town) also use
2414-608: The s -process, both directly and as the daughter of long-lived indium-115 , and also from the decay of indium-115 produced via the r -process. The word tin is shared among Germanic languages and can be traced back to reconstructed Proto-Germanic * tin-om ; cognates include German Zinn , Swedish tenn and Dutch tin . It is not found in other branches of Indo-European , except by borrowing from Germanic (e.g., Irish tinne from English). The Latin name for tin, stannum , originally meant an alloy of silver and lead, and came to mean 'tin' in
2485-534: The Kindersley brothers, who were among the first to plant rubber in the country on a commercial basis. During the Japanese invasion , Kajang was bombed on 12 January 1942, a day after the fall of Kuala Lumpur . The bombs, meant for the railway station , missed its target, and hit a nearby church instead. In 1948, a Communist insurgency against British forces and their allies across Malaya began, which led to
2556-732: The Legislative Assembly (MLA) David Cheong Kian Young of PH since 2023. Before that, Kajang was one of the state seats within the Hulu Langat parliamentary seat in the Dewan Rakyat of the Parliament besides Semenyih and Dusun Tua . Hulu Langat District Hulu Langat is the fifth largest district in Selangor State with an area of 840 square kilometres and the second most populous district with
2627-919: The National Registration Department, Immigration Department, Transportation Department, and Hulu Langat Education Office. Kajang is home to institutions of higher learning, which includes: Kajang is a state seat in the Selangor State Legislative Assembly and one of three state seats within the Bangi parliamentary seat in the Dewan Rakyat of the Parliament besides Balakong and Sungai Ramal . Bangi has been represented by Member of Parliament (MP) Syahredzan Johan of Pakatan Harapan (PH) since 2022 and Kajang has been represented by Member of
2698-464: The Near East where arsenic is commonly found with copper ore, but the health risks were quickly realized and the quest for sources of the much less hazardous tin ores began early in the Bronze Age. This created the demand for rare tin metal and formed a trade network that linked the distant sources of tin to the markets of Bronze Age cultures. Cassiterite ( SnO 2 ), the oxide form of tin,
2769-654: The United States has neither mined (since 1993) nor smelted (since 1989) tin, it was the largest secondary producer, recycling nearly 14,000 tonnes in 2006. New deposits are reported in Mongolia , and in 2009, new deposits of tin were discovered in Colombia. Tin is produced by carbothermic reduction of the oxide ore with carbon or coke. Both reverberatory furnace and electric furnace can be used: The ten largest tin-producing companies produced most of
2840-463: The aftermath of the Klang War . In its early days, it was settled by Mandailings and Minangkabau people from Sumatra in the then- Dutch East Indies , followed by Chinese tin miners. As with other towns in Selangor, Kajang as a modern town owes its rise in particular to tin mines and plantations which were opened around the 1890s. A famous coffee estates was Inch Kenneth Estate managed by
2911-474: The area with thatched roof made from folded ( lipat kajang ) screwpine leaves. It is also believed that the name kajang may have originated from the Buginese word berkajang , meaning camp or accommodation . Kajang is about 22 km (14 miles), about a half hour's drive, from Kuala Lumpur's central business district, primarily through Jalan Cheras and the Grand Saga Expressway ; both routes are part of
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2982-604: The complex agreements between producer countries and consumer countries dating back to 1921. Earlier agreements tended to be somewhat informal and led to the "First International Tin Agreement" in 1956, the first of a series that effectively collapsed in 1985. Through these agreements, the International Tin Council (ITC) had a considerable effect on tin prices. ITC supported the price of tin during periods of low prices by buying tin for its buffer stockpile and
3053-402: The crystals. This trait is shared by indium , cadmium , zinc , and mercury in its solid state. Tin melts at about 232 °C (450 °F), the lowest in group 14, and boils at 2,602 °C (4,716 °F), the second lowest (ahead of lead ) in its group. The melting point is further lowered to 177.3 °C (351.1 °F) for 11 nm particles. β-tin, also called white tin ,
3124-478: The district fall under the Ampang Corridor and Cheras Corridor . Hulu Langat District is home to a number of higher education institutions. Hulu Langat town is famous for its durians. This town is also popular for its recreational activities and natural surroundings. Due to its near location to the city of Kuala Lumpur Hulu Langat is a popular spot to the local tourist for recreational activities. Among
3195-500: The family living quarters. One of Kajang's landmarks is Kajang Stadium which is situated in the heart of the town. The stadium can accommodate up to 5,000 people and is used throughout the year for the community soccer competitions. Another landmark is the Kajang Jamek Mosque, which is recognisable by its bright yellow facade. Kajang is served by a network of tolled expressways and federal highways. Federal Route 1,
3266-591: The fourth century —the earlier Latin word for it was plumbum candidum , or "white lead". Stannum apparently came from an earlier stāgnum (meaning the same substance), the origin of the Romance and Celtic terms for tin , such as French étain , Spanish estaño , Italian stagno , and Irish stán . The origin of stannum / stāgnum is unknown; it may be pre- Indo-European . The Meyers Konversations-Lexikon suggests instead that stannum came from Cornish stean , and
3337-439: The great majority of its compounds, tin has the oxidation state II or IV. Compounds containing bivalent tin are called stannous while those containing tetravalent tin are termed stannic . Halide compounds are known for both oxidation states. For Sn(IV), all four halides are well known: SnF 4 , SnCl 4 , SnBr 4 , and SnI 4 . The three heavier members are volatile molecular compounds, whereas
3408-517: The inhibiting effect of small amounts of bismuth, antimony, lead, and silver present as impurities. Alloying elements such as copper, antimony, bismuth, cadmium, and silver increase the hardness of tin. Tin easily forms hard, brittle intermetallic phases that are typically undesirable. It does not mix into a solution with most metals and elements so tin does not have much solid solubility. Tin mixes well with bismuth , gallium , lead , thallium and zinc , forming simple eutectic systems. Tin becomes
3479-402: The intersection with Jalan Cheras , Jalan Semenyih and Jalan Reko From Ampang Jaya , one can reach Kajang with state routes B62 and B52 . KB06 KG35 Kajang railway station is the principal rail station of Kajang. It is an interchange station between the 9 MRT Kajang Line , 1 KTM Seremban Line and ETS KTM ETS . The station
3550-451: The late 1970s and early 1980s, the U.S. reduced its strategic tin stockpile, partly to take advantage of historically high tin prices. The 1981–82 recession damaged the tin industry. Tin consumption declined dramatically. ITC was able to avoid truly steep declines through accelerated buying for its buffer stockpile; this activity required extensive borrowing. ITC continued to borrow until late 1985 when it reached its credit limit. Immediately,
3621-455: The market and mining technology. It is estimated that, at current consumption rates and technologies, the Earth will run out of mine-able tin in 40 years. In 2006 Lester Brown suggested tin could run out within 20 years based on conservative estimates of 2% annual growth. Scrap tin is an important source of the metal. Recovery of tin through recycling is increasing rapidly as of 2019. Whereas
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#17327722304703692-412: The most stable being tin-121m, with a half-life of 43.9 years. The relative differences in the abundances of tin's stable isotopes can be explained by how they are formed during stellar nucleosynthesis . Tin-116 through tin-120, along with tin-122, are formed in the s -process (slow neutron capture) in most stars which leads to them being the most common tin isotopes, while tin-124 is only formed in
3763-550: The periodic table, due to its magic number of protons. It has two main allotropes : at room temperature, the stable allotrope is β-tin, a silvery-white, malleable metal; at low temperatures it is less dense grey α-tin, which has the diamond cubic structure. Metallic tin does not easily oxidize in air and water. The first tin alloy used on a large scale was bronze , made of 1 ⁄ 8 tin and 7 ⁄ 8 copper (12.5% and 87.5% respectively), from as early as 3000 BC. After 600 BC, pure metallic tin
3834-887: The popular spots of eco-tourism are the Sungai Gabai Waterfalls , the Semenyih Water Reservoir and the Congkak River Forest Recreational Center. Another latest hot spot for tourism is the Sungai Lopoh, located at 22nd Mile of Jalan Hulu Langat and the Kuala Lumpur Look Out Point Tourist Complex, located at Jalan Ampang–Hulu Langat . Near Lembah Pangsun lies Mount Nuang (1,483m), a training ground for hikers and runners before they climb Mount Kinabalu or do
3905-513: The postal code of Kajang. Bangi Lama, Bandar Seri Putra and Bukit Mahkota are located in Mukim Kajang. Orang Asli tribes had already established settlements in what is now Kajang as early as the 16th century, however the first recorded settlement was found in 1709 by additional Orang Asli settlers who relocated from the Klang valley . Kajang town in its present form was founded in the 1870s, in
3976-477: The premier north–south federal route of Peninsular Malaysia, runs through downtown Kajang as Jalan Cheras from Cheras until Sungai Jernih and Stadium Kajang and then southwards as Jalan Semenyih from Stadium Kajang until Semenyih , Beranang and neighbouring Seremban , Negeri Sembilan with the rest of the route terminating in Johor Bahru , Johor - the route's southern terminus. On Federal Route 1, Kajang
4047-613: The primary lodes. Tin is often recovered from granules washed downstream in the past and deposited in valleys or the sea. The most economical ways of mining tin are by dredging , hydraulicking , or open pits . Most of the world's tin is produced from placer deposits, which can contain as little as 0.015% tin. About 253,000 tonnes of tin were mined in 2011, mostly in China (110,000 t), Indonesia (51,000 t), Peru (34,600 t), Bolivia (20,700 t) and Brazil (12,000 t). Estimates of tin production have historically varied with
4118-472: The reaction of hydrochloric acid and tin produces SnCl 2 and hydrogen gas. Alternatively SnCl 4 and Sn combine to stannous chloride by a process called comproportionation : Tin can form many oxides, sulfides, and other chalcogenide derivatives. The dioxide SnO 2 (cassiterite) forms when tin is heated in the presence of air . SnO 2 is amphoteric , which means that it dissolves in both acidic and basic solutions. Stannates with
4189-456: The result of unintentional alloying due to trace metal content in the copper ore. The addition of a second metal to copper increases its hardness, lowers the melting temperature, and improves the casting process by producing a more fluid melt that cools to a denser, less spongy metal. This was an important innovation that allowed for the much more complex shapes cast in closed molds of the Bronze Age. Arsenical bronze objects appear first in
4260-678: The structure [ Sn(OH) 6 ] , like K 2 [ Sn(OH) 6 ], are also known, though the free stannic acid H 2 [ Sn(OH) 6 ] is unknown. Sulfides of tin exist in both the +2 and +4 oxidation states: tin(II) sulfide and tin(IV) sulfide ( mosaic gold ). Stannane ( SnH 4 ), with tin in the +4 oxidation state, is unstable. Organotin hydrides are however well known, e.g. tributyltin hydride (Sn(C 4 H 9 ) 3 H). These compounds release transient tributyl tin radicals, which are rare examples of compounds of tin(III). Organotin compounds, sometimes called stannanes, are chemical compounds with tin–carbon bonds. Of
4331-578: The temperatures became so cold that the tin buttons on the soldiers' uniforms disintegrated over time, contributing to the defeat of the Grande Armée , a persistent legend. The α-β transformation temperature is 13.2 °C (55.8 °F), but impurities (e.g. Al, Zn, etc.) lower it well below 0 °C (32 °F). With the addition of antimony or bismuth the transformation might not occur at all, increasing durability. Commercial grades of tin (99.8% tin content) resist transformation because of
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#17327722304704402-420: The tetrafluoride is polymeric. All four halides are known for Sn(II) also: SnF 2 , SnCl 2 , SnBr 2 , and SnI 2 . All are polymeric solids. Of these eight compounds, only the iodides are colored. Tin(II) chloride (also known as stannous chloride) is the most important commercial tin halide. Illustrating the routes to such compounds, chlorine reacts with tin metal to give SnCl 4 whereas
4473-523: The tetraorgano derivatives, are prepared by redistribution reactions : Divalent organotin compounds are uncommon, although more common than related divalent organogermanium and organosilicon compounds. The greater stabilization enjoyed by Sn(II) is attributed to the " inert pair effect ". Organotin(II) compounds include both stannylenes (formula: R 2 Sn, as seen for singlet carbenes ) and distannylenes (R 4 Sn 2 ), which are roughly equivalent to alkenes . Both classes exhibit unusual reactions. Tin
4544-588: The tin compounds, the organic derivatives are commercially the most useful. Some organotin compounds are highly toxic and have been used as biocides . The first organotin compound to be reported was diethyltin diiodide ((C 2 H 5 ) 2 SnI 2 ), reported by Edward Frankland in 1849. Most organotin compounds are colorless liquids or solids that are stable to air and water. They adopt tetrahedral geometry. Tetraalkyl- and tetraaryltin compounds can be prepared using Grignard reagents : The mixed halide-alkyls, which are more common and more important commercially than
4615-546: The township. The Kajang bus and taxi terminal called Hentian Kajang is also located at the eastern end of the township. More townships were developed closer to Kajang town in recent years, such as Taman Prima Saujana, Sungai Chua and Taman Kajang Perdana (Kajang Highlands). High-end developments in Kajang include Twin Palms, Sri Banyan, Country Heights, Jade Hills, Saujana Impian, TTDI Grove, Tropicana Heights and Prima Paramount. Areas surrounding these townships are accessible via
4686-606: The world's tin in 2007. Most of the world's tin is traded on LME, from 8 countries, under 17 brands. The International Tin Council was established in 1947 to control the price of tin. It collapsed in 1985. In 1984, the Association of Tin Producing Countries was created, with Australia, Bolivia, Indonesia, Malaysia, Nigeria, Thailand, and Zaire as members. Tin is unique among mineral commodities because of
4757-458: Was able to restrain the price during periods of high prices by selling from the stockpile. This was an anti-free-market approach, designed to assure a sufficient flow of tin to consumer countries and a profit for producer countries. However, the buffer stockpile was not sufficiently large, and during most of those 29 years tin prices rose, sometimes sharply, especially from 1973 through 1980 when rampant inflation plagued many world economies. During
4828-549: Was most likely the original source of tin. Other tin ores are less common sulfides such as stannite that require a more involved smelting process. Cassiterite often accumulates in alluvial channels as placer deposits because it is harder, heavier, and more chemically resistant than the accompanying granite . Cassiterite is usually black or dark in color, and these deposits can be easily seen in river banks . Alluvial ( placer ) deposits may incidentally have been collected and separated by methods similar to gold panning . In
4899-541: Was produced. Pewter , which is an alloy of 85–90% tin with the remainder commonly consisting of copper , antimony , bismuth, and sometimes lead and silver, has been used for flatware since the Bronze Age . In modern times, tin is used in many alloys, most notably tin-lead soft solders , which are typically 60% or more tin, and in the manufacture of transparent, electrically conducting films of indium tin oxide in optoelectronic applications. Another large application
4970-790: Was the administrative centre of the Hulu Langat region until it was relocated to Bandar Baru Bangi in 1992. In the 2020 census, the Kajang Municipal Council is home to 1.05 million people, making it Malaysia's second most populous local authority after Kuala Lumpur . Over 350,000 people reside in Kajang town itself and its immediate suburbs. Kajang's main population centres are Sg. Sekamat, Taman Saujana Impian, Sg. Kantan, Sg. Jelok, Sg. Ramal, Sungai Chua, Jalan Reko, Jalan Bukit, Taman Jenaris, Taman Prima Saujana, Taman Kantan Permai, Taman Kajang Perdana, Taman Sri Ramal, Taman Bukit Mewah, Kajang Prima, Bandar Teknologi Kajang, Hillpark and Bandar Baru Bangi. The city centre of Kajang
5041-415: Was used in solder. The rest was divided between tin plating, tin chemicals, brass and bronze alloys, and niche uses. Pigment Yellow 38, tin(IV) sulfide , is known as mosaic gold . Purple of Cassius , Pigment Red 109, a hydrous double stannate of gold , was mainly, in terms of painting, restricted to miniatures due to its high cost. It was widely used to make cranberry glass . It has also been used in
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