Misplaced Pages

#671328

85-475: OPX may refer to: Science [ edit ] OPX, a class of Martian meteorites Orthopyroxene , a type of rock-forming mineral Technology [ edit ] Off-premises extension , an extension telephone Open Programming Extension, a DLL mechanism of the Open programming language Silver Xpress, a mail format used on FidoNet Topics referred to by

170-455: A = m 1 x 1 + m 2 x 2 + . . . + m N x N {\displaystyle {\overline {m}}_{a}=m_{1}x_{1}+m_{2}x_{2}+...+m_{N}x_{N}} where m 1 , m 2 , ..., m N are the atomic masses of each individual isotope, and x 1 , ..., x N are the relative abundances of these isotopes. Several applications exist that capitalize on

255-511: A chemical symbol is used, e.g. "C" for carbon, standard notation (now known as "AZE notation" because A is the mass number , Z the atomic number , and E for element ) is to indicate the mass number (number of nucleons) with a superscript at the upper left of the chemical symbol and to indicate the atomic number with a subscript at the lower left (e.g. 2 He , 2 He , 6 C , 6 C , 92 U , and 92 U ). Because

340-524: A Martian origin. In 2000, an article by Treiman, Gleason and Bogard gave a survey of all the arguments used to conclude the SNC meteorites (of which 14 had been found at the time) were from Mars. They wrote, "There seems little likelihood that the SNCs are not from Mars. If they were from another planetary body, it would have to be substantially identical to Mars as it now is understood." As of April 25, 2018, 192 of

425-441: A crater count chronology of different regions on Mars, suggest the nakhlites formed on the large volcanic construct of either Tharsis , Elysium , or Syrtis Major Planum . It has been shown that the nakhlites were suffused with liquid water around 620 million years ago and that they were ejected from Mars around 10.75 million years ago by an asteroid impact. They fell to Earth within the last 10,000 years. The first chassignite,

510-505: A double pairing of 2 protons and 2 neutrons prevents any nuclides containing five ( 2 He , 3 Li ) or eight ( 4 Be ) nucleons from existing long enough to serve as platforms for the buildup of heavier elements via nuclear fusion in stars (see triple alpha process ). Only five stable nuclides contain both an odd number of protons and an odd number of neutrons. The first four "odd-odd" nuclides occur in low mass nuclides, for which changing

595-419: A given element all have the same number of electrons and share a similar electronic structure. Because the chemical behaviour of an atom is largely determined by its electronic structure, different isotopes exhibit nearly identical chemical behaviour. The main exception to this is the kinetic isotope effect : due to their larger masses, heavier isotopes tend to react somewhat more slowly than lighter isotopes of

680-407: A glowing patch on the plate at the point it struck. Thomson observed two separate parabolic patches of light on the photographic plate (see image), which suggested two species of nuclei with different mass-to-charge ratios. He wrote "There can, therefore, I think, be little doubt that what has been called neon is not a simple gas but a mixture of two gases, one of which has an atomic weight about 20 and

765-468: A nonoptimal number of neutrons or protons decay by beta decay (including positron emission ), electron capture , or other less common decay modes such as spontaneous fission and cluster decay . Most stable nuclides are even-proton-even-neutron, where all numbers Z , N , and A are even. The odd- A stable nuclides are divided (roughly evenly) into odd-proton-even-neutron, and even-proton-odd-neutron nuclides. Stable odd-proton-odd-neutron nuclides are

850-427: A nucleus. As the number of protons increases, so does the ratio of neutrons to protons necessary to ensure a stable nucleus (see graph at right). For example, although the neutron:proton ratio of 2 He is 1:2, the neutron:proton ratio of 92 U is greater than 3:2. A number of lighter elements have stable nuclides with the ratio 1:1 ( Z = N ). The nuclide 20 Ca (calcium-40)

935-405: A product of stellar nucleosynthesis or another type of nucleosynthesis such as cosmic ray spallation , and have persisted down to the present because their rate of decay is very slow (e.g. uranium-238 and potassium-40 ). Post-primordial isotopes were created by cosmic ray bombardment as cosmogenic nuclides (e.g., tritium , carbon-14 ), or by the decay of a radioactive primordial isotope to

SECTION 10

#1732776609672

1020-506: A proton to a neutron or vice versa would lead to a very lopsided proton-neutron ratio ( 1 H , 3 Li , 5 B , and 7 N ; spins 1, 1, 3, 1). The only other entirely "stable" odd-odd nuclide, 73 Ta (spin 9), is thought to be the rarest of the 251 stable nuclides, and is the only primordial nuclear isomer , which has not yet been observed to decay despite experimental attempts. Many odd-odd radionuclides (such as

1105-478: A radioactive radiogenic nuclide daughter (e.g. uranium to radium ). A few isotopes are naturally synthesized as nucleogenic nuclides, by some other natural nuclear reaction , such as when neutrons from natural nuclear fission are absorbed by another atom. As discussed above, only 80 elements have any stable isotopes, and 26 of these have only one stable isotope. Thus, about two-thirds of stable elements occur naturally on Earth in multiple stable isotopes, with

1190-486: A recent study suggests that magnetite in the meteorite could have been produced by Martian microbes. The study, published in the journal of the Geochemical and Meteoritic Society, used more advanced high resolution electron microscopy than was possible in 1996. A serious difficulty with the claims for a biogenic origin of the magnetites is that the majority of them exhibit topotactic crystallographic relationships with

1275-499: A single location on Mars by a single impact event. Some of the shergottites also seem to form distinct groups according to their CRE ages and formation ages, again indicating ejection of several different shergottites from Mars by a single impact. However, CRE ages of shergottites vary considerably (~0.5–19 Ma), and several impact events are required to eject all the known shergottites. It had been asserted that there are no large young craters on Mars that are candidates as sources for

1360-424: A single stable isotope (of these, 19 are so-called mononuclidic elements , having a single primordial stable isotope that dominates and fixes the atomic weight of the natural element to high precision; 3 radioactive mononuclidic elements occur as well). In total, there are 251 nuclides that have not been observed to decay. For the 80 elements that have one or more stable isotopes, the average number of stable isotopes

1445-497: A stable (non-radioactive) element was found by J. J. Thomson in 1912 as part of his exploration into the composition of canal rays (positive ions). Thomson channelled streams of neon ions through parallel magnetic and electric fields, measured their deflection by placing a photographic plate in their path, and computed their mass to charge ratio using a method that became known as the Thomson's parabola method. Each stream created

1530-457: A terrestrial origin. The names derive from the location of where the first meteorite of their type was discovered. Roughly three-quarters of all Martian meteorites can be classified as shergottites. They are named after the Shergotty meteorite , which fell at Sherghati , India in 1865. Shergottites are igneous rocks of mafic to ultramafic lithology . They fall into three main groups,

1615-434: A topic of debate among planetary scientists, but generally consistent with the earlier evidence provided by Martian meteorites. Any liquid water present is likely too minimal to support life. Isotope Isotopes are distinct nuclear species (or nuclides ) of the same chemical element . They have the same atomic number (number of protons in their nuclei ) and position in the periodic table (and hence belong to

1700-622: A total 30 + 2(9) = 48 stable odd-even isotopes. There are also five primordial long-lived radioactive odd-even isotopes, 37 Rb , 49 In , 75 Re , 63 Eu , and 83 Bi . The last two were only recently found to decay, with half-lives greater than 10 years. Actinides with odd neutron number are generally fissile (with thermal neutrons ), whereas those with even neutron number are generally not, though they are fissionable with fast neutrons . All observationally stable odd-odd nuclides have nonzero integer spin. This

1785-681: Is aluminium-26 , which is not naturally found on Earth but is found in abundance on an astronomical scale. The tabulated atomic masses of elements are averages that account for the presence of multiple isotopes with different masses. Before the discovery of isotopes, empirically determined noninteger values of atomic mass confounded scientists. For example, a sample of chlorine contains 75.8% chlorine-35 and 24.2% chlorine-37 , giving an average atomic mass of 35.5 atomic mass units . According to generally accepted cosmology theory , only isotopes of hydrogen and helium, traces of some isotopes of lithium and beryllium, and perhaps some boron, were created at

SECTION 20

#1732776609672

1870-547: Is 251/80 ≈ 3.14 isotopes per element. The proton:neutron ratio is not the only factor affecting nuclear stability. It depends also on evenness or oddness of its atomic number Z , neutron number N and, consequently, of their sum, the mass number A . Oddness of both Z and N tends to lower the nuclear binding energy , making odd nuclei, generally, less stable. This remarkable difference of nuclear binding energy between neighbouring nuclei, especially of odd- A isobars , has important consequences: unstable isotopes with

1955-641: Is a radioactive form of carbon, whereas C and C are stable isotopes. There are about 339 naturally occurring nuclides on Earth, of which 286 are primordial nuclides , meaning that they have existed since the Solar System 's formation. Primordial nuclides include 35 nuclides with very long half-lives (over 100 million years) and 251 that are formally considered as " stable nuclides ", because they have not been observed to decay. In most cases, for obvious reasons, if an element has stable isotopes, those isotopes predominate in

2040-663: Is because the single unpaired neutron and unpaired proton have a larger nuclear force attraction to each other if their spins are aligned (producing a total spin of at least 1 unit), instead of anti-aligned. See deuterium for the simplest case of this nuclear behavior. Only 78 Pt , 4 Be , and 7 N have odd neutron number and are the most naturally abundant isotope of their element. Elements are composed either of one nuclide ( mononuclidic elements ), or of more than one naturally occurring isotopes. The unstable (radioactive) isotopes are either primordial or postprimordial. Primordial isotopes were

2125-435: Is denoted with symbols "u" (for unified atomic mass unit) or "Da" (for dalton ). The atomic masses of naturally occurring isotopes of an element determine the standard atomic weight of the element. When the element contains N isotopes, the expression below is applied for the average atomic mass m ¯ a {\displaystyle {\overline {m}}_{a}} : m ¯

2210-659: Is different from Wikidata All article disambiguation pages All disambiguation pages Martian meteorites#Subdivision There are three groups of Martian meteorite: shergottites , nakhlites and chassignites , collectively known as SNC meteorites . Several other Martian meteorites are ungrouped . These meteorites are interpreted as Martian because they have elemental and isotopic compositions that are similar to rocks and atmospheric gases on Mars , which have been measured by orbiting spacecraft , surface landers and rovers . The term does not include meteorites found on Mars, such as Heat Shield Rock . By

2295-544: Is evidence for fossilized Martian life forms. The most significant of these is a meteorite found in the Allan Hills of Antarctica ( ALH 84001 ). Ejection from Mars seems to have taken place about 16 million years ago. Arrival on Earth was about 13 000 years ago. Cracks in the rock appear to have filled with carbonate materials (implying groundwater was present) between 4 and 3.6 billion-years-ago. Evidence of polycyclic aromatic hydrocarbons (PAHs) have been identified with

2380-608: Is not totally understood, and a few scientists have suggested that some may actually have formed prior to the times given by their radiometric ages, a suggestion not accepted by most scientists. Formation ages of SNC meteorites are often linked to their cosmic-ray exposure (CRE) ages, as measured from the nuclear products of interactions of the meteorite in space with energetic cosmic ray particles. Thus, all measured nakhlites give essentially identical CRE ages of approximately 11 Ma, which when combined with their possible identical formation ages indicates ejection of nakhlites into space from

2465-628: Is observationally the heaviest stable nuclide with the same number of neutrons and protons. All stable nuclides heavier than calcium-40 contain more neutrons than protons. Of the 80 elements with a stable isotope, the largest number of stable isotopes observed for any element is ten (for the element tin ). No element has nine or eight stable isotopes. Five elements have seven stable isotopes, eight have six stable isotopes, ten have five stable isotopes, nine have four stable isotopes, five have three stable isotopes, 16 have two stable isotopes (counting 73 Ta as stable), and 26 elements have only

2550-429: Is still an area of active research and debate. It has been suggested the 3-million-year-old crater Mojave , 58.5 km in diameter, was a potential source of these meteorites. A paper published in 2021, however, disputes this, proposing instead the 28 km crater Tooting , or possibly the crater 09-000015 as the crater source of the depleted olivine-phyric shergottites ejected 1.1 Ma ago. Nakhlites are named after

2635-399: Is thought that the meteorites all originate in relatively few impacts every few million years on Mars. The impactors would be kilometers in diameter and the craters they form on Mars tens of kilometers in diameter. Models of impacts on Mars are consistent with these findings. Ages since impact determined so far include Several Martian meteorites have been found to contain what some think

OPX - Misplaced Pages Continue

2720-474: The Big Bang , while all other nuclides were synthesized later, in stars and supernovae, and in interactions between energetic particles such as cosmic rays, and previously produced nuclides. (See nucleosynthesis for details of the various processes thought responsible for isotope production.) The respective abundances of isotopes on Earth result from the quantities formed by these processes, their spread through

2805-447: The CNO cycle . The nuclides 3 Li and 5 B are minority isotopes of elements that are themselves rare compared to other light elements, whereas the other six isotopes make up only a tiny percentage of the natural abundance of their elements. 53 stable nuclides have an even number of protons and an odd number of neutrons. They are a minority in comparison to

2890-702: The Chassigny meteorite , fell at Chassigny, Haute-Marne , France in 1815. There has been only one other chassignite recovered, named Northwest Africa (NWA) 2737. NWA 2737 was found in Morocco or Western Sahara in August 2000 by meteorite hunters Bruno Fectay and Carine Bidaut, who gave it the temporary name "Diderot." It was shown by Beck et al. that its " mineralogy , major and trace element chemistry as well as oxygen isotopes revealed an unambiguous Martian origin and strong affinities with Chassigny." Among these,

2975-566: The Viking landers . Several scientists suggested these characteristics implied the origin of SNC meteorites from a relatively large parent body, possibly Mars. Then in 1983, various trapped gases were reported in impact-formed glass of the EET79001 shergottite, gases which closely resembled those in the Martian atmosphere as analyzed by Viking. These trapped gases provided direct evidence for

3060-542: The basaltic , olivine -phyric (such as the Tissint group found in Morocco in 2011 ) and Lherzolitic shergottites, based on their crystal size and mineral content. They can be categorised alternatively into three or four groups based on their rare-earth element content. These two classification systems do not line up with each other, hinting at complex relationships between the various source rocks and magmas from which

3145-410: The binding energy of the nucleus (see mass defect ), the slight difference in mass between proton and neutron, and the mass of the electrons associated with the atom, the latter because the electron:nucleon ratio differs among isotopes. The mass number is a dimensionless quantity . The atomic mass, on the other hand, is measured using the atomic mass unit based on the mass of the carbon-12 atom. It

3230-465: The fissile 92 U . Because of their odd neutron numbers, the even-odd nuclides tend to have large neutron capture cross-sections, due to the energy that results from neutron-pairing effects. These stable even-proton odd-neutron nuclides tend to be uncommon by abundance in nature, generally because, to form and enter into primordial abundance, they must have escaped capturing neutrons to form yet other stable even-even isotopes, during both

3315-425: The isotope concept (grouping all atoms of each element) emphasizes chemical over nuclear. The neutron number greatly affects nuclear properties, but its effect on chemical properties is negligible for most elements. Even for the lightest elements, whose ratio of neutron number to atomic number varies the most between isotopes, it usually has only a small effect although it matters in some circumstances (for hydrogen,

3400-436: The residual strong force . Because protons are positively charged, they repel each other. Neutrons, which are electrically neutral, stabilize the nucleus in two ways. Their copresence pushes protons slightly apart, reducing the electrostatic repulsion between the protons, and they exert an attractive nuclear force on each other and on protons. For this reason, one or more neutrons are necessary for two or more protons to bind into

3485-421: The s-process and r-process of neutron capture, during nucleosynthesis in stars . For this reason, only 78 Pt and 4 Be are the most naturally abundant isotopes of their element. 48 stable odd-proton-even-neutron nuclides, stabilized by their paired neutrons, form most of the stable isotopes of the odd-numbered elements; the very few odd-proton-odd-neutron nuclides comprise

OPX - Misplaced Pages Continue

3570-544: The 207 Martian meteorites are divided into three rare groups of achondritic (stony) meteorites : shergottites (169), nakhlites (20), chassignites (3), and ones otherwise (15) (containing the orthopyroxenite (OPX) Allan Hills 84001, as well as 10 basaltic breccia meteorites). Consequently, Martian meteorites as a whole are sometimes referred to as the SNC group (pronounced / s n ɪ k / ). They have isotope ratios that are consistent with each other and inconsistent with

3655-551: The Kaidun meteorite is a carbonaceous chondrite , Kaidun is not a Martian meteorite in the strict sense. However, it may contain small fragments of material from the Martian surface. The Martian meteorite NWA 7034 (nicknamed "Black Beauty"), found in the Sahara desert during 2011, has ten times the water content of other Mars meteorites found on Earth. The meteorite contains components as old as 4.42 ± 0.07 Ga (billion years), and

3740-614: The Martian meteorites, but subsequent studies claimed to have a likely source for ALH 84001 , and a possible source for other shergottites. In a 2014 paper, several researchers claimed that all shergottites meteorites come from the Mojave Crater on Mars. The amount of time spent in transit from Mars to Earth can be estimated by measurements of the effect of cosmic radiation on the meteorites, particularly on isotope ratios of noble gases . The meteorites cluster in families that seem to correspond to distinct impact events on Mars. It

3825-429: The almost integral masses for the two isotopes Cl and Cl. After the discovery of the neutron by James Chadwick in 1932, the ultimate root cause for the existence of isotopes was clarified, that is, the nuclei of different isotopes for a given element have different numbers of neutrons, albeit having the same number of protons. A neutral atom has the same number of electrons as protons. Thus different isotopes of

3910-463: The atomic number is given by the element symbol, it is common to state only the mass number in the superscript and leave out the atomic number subscript (e.g. He , He , C , C , U , and U ). The letter m (for metastable) is sometimes appended after the mass number to indicate a nuclear isomer , a metastable or energetically excited nuclear state (as opposed to

3995-640: The beta decay of actinium-230 forms thorium-230. The term "isotope", Greek for "at the same place", was suggested to Soddy by Margaret Todd , a Scottish physician and family friend, during a conversation in which he explained his ideas to her. He received the 1921 Nobel Prize in Chemistry in part for his work on isotopes. In 1914 T. W. Richards found variations between the atomic weight of lead from different mineral sources, attributable to variations in isotopic composition due to different radioactive origins. The first evidence for multiple isotopes of

4080-405: The early 1980s, it was obvious that the SNC group of meteorites (Shergottites, Nakhlites, and Chassignites) were significantly different from most other meteorite types. Among these differences were younger formation ages, a different oxygen isotopic composition, the presence of aqueous weathering products, and some similarity in chemical composition to analyses of the Martian surface rocks in 1976 by

4165-510: The element carbon with mass numbers 12, 13, and 14, respectively. The atomic number of carbon is 6, which means that every carbon atom has 6 protons so that the neutron numbers of these isotopes are 6, 7, and 8 respectively. A nuclide is a species of an atom with a specific number of protons and neutrons in the nucleus, for example, carbon-13 with 6 protons and 7 neutrons. The nuclide concept (referring to individual nuclear species) emphasizes nuclear properties over chemical properties, whereas

4250-500: The elemental abundance found on Earth and in the Solar System. However, in the cases of three elements ( tellurium , indium , and rhenium ) the most abundant isotope found in nature is actually one (or two) extremely long-lived radioisotope(s) of the element, despite these elements having one or more stable isotopes. Theory predicts that many apparently "stable" nuclides are radioactive, with extremely long half-lives (discounting

4335-410: The even-even isotopes, which are about 3 times as numerous. Among the 41 even- Z elements that have a stable nuclide, only two elements (argon and cerium) have no even-odd stable nuclides. One element (tin) has three. There are 24 elements that have one even-odd nuclide and 13 that have two odd-even nuclides. Of 35 primordial radionuclides there exist four even-odd nuclides (see table at right), including

SECTION 50

#1732776609672

4420-472: The famous specimen Allan Hills 84001 has a different rock type from other Martian meteorites: it is an orthopyroxenite (an igneous rock dominantly composed of orthopyroxene ). For this reason it is classified within its own group, the "OPX Martian meteorites". This meteorite received much attention after an electron microscope revealed structures that were considered to be the fossilized remains of bacteria -like lifeforms . As of 2005 , scientific consensus

4505-549: The first of them, the Nakhla meteorite , which fell in El-Nakhla , Alexandria , Egypt in 1911 and had an estimated weight of 10  kg . Nakhlites are igneous rocks that are rich in augite and were formed from basaltic magma from at least four eruptions, spanning around 90 million years, from 1416 ± 7 to 1322 ± 10 million years ago. They contain augite and olivine crystals . Their crystallization ages, compared to

4590-486: The galaxy, and the rates of decay for isotopes that are unstable. After the initial coalescence of the Solar System , isotopes were redistributed according to mass, and the isotopic composition of elements varies slightly from planet to planet. This sometimes makes it possible to trace the origin of meteorites . The atomic mass ( m r ) of an isotope (nuclide) is determined mainly by its mass number (i.e. number of nucleons in its nucleus). Small corrections are due to

4675-401: The ground state of tantalum-180) with comparatively short half-lives are known. Usually, they beta-decay to their nearby even-even isobars that have paired protons and paired neutrons. Of the nine primordial odd-odd nuclides (five stable and four radioactive with long half-lives), only 7 N is the most common isotope of a common element. This is the case because it is a part of

4760-546: The host carbonates (i.e., there are 3D orientation relationships between the magnetite and carbonate lattices), which is strongly indicative that the magnetites have grown in-situ by a physico-chemical mechanism. While water is no indication of life, many of the meteorites found on Earth have shown water, including NWA 7034 which formed during the Amazonian period of Martian geological history. Other signs of surface liquid water on Mars (such as recurring slope lineae ) are

4845-409: The integers 20 and 22 and that neither is equal to the known molar mass (20.2) of neon gas. This is an example of Aston's whole number rule for isotopic masses, which states that large deviations of elemental molar masses from integers are primarily due to the fact that the element is a mixture of isotopes. Aston similarly showed in 1920 that the molar mass of chlorine (35.45) is a weighted average of

4930-464: The largest number of stable isotopes for an element being ten, for tin ( 50 Sn ). There are about 94 elements found naturally on Earth (up to plutonium inclusive), though some are detected only in very tiny amounts, such as plutonium-244 . Scientists estimate that the elements that occur naturally on Earth (some only as radioisotopes) occur as 339 isotopes ( nuclides ) in total. Only 251 of these naturally occurring nuclides are stable, in

5015-482: The least common. The 146 even-proton, even-neutron (EE) nuclides comprise ~58% of all stable nuclides and all have spin 0 because of pairing. There are also 24 primordial long-lived even-even nuclides. As a result, each of the 41 even-numbered elements from 2 to 82 has at least one stable isotope , and most of these elements have several primordial isotopes. Half of these even-numbered elements have six or more stable isotopes. The extreme stability of helium-4 due to

5100-689: The levels increasing away from the surface. Other Antarctic meteorites do not contain PAHs. Earthly contamination should presumably be highest at the surface. Several minerals in the crack fill are deposited in phases, specifically, iron deposited as magnetite , that are claimed to be typical of biodepositation on Earth. There are also small ovoid and tubular structures that might be nanobacteria fossils in carbonate material in crack fills (investigators McKay, Gibson, Thomas-Keprta, Zare). Micropaleontologist Schopf, who described several important terrestrial bacterial assemblages, examined ALH 84001 and opined that

5185-517: The lightest element, the isotope effect is large enough to affect biology strongly). The term isotopes (originally also isotopic elements , now sometimes isotopic nuclides ) is intended to imply comparison (like synonyms or isomers ). For example, the nuclides 6 C , 6 C , 6 C are isotopes (nuclides with the same atomic number but different mass numbers ), but 18 Ar , 19 K , 20 Ca are isobars (nuclides with

SECTION 60

#1732776609672

5270-402: The longest-lived isotope), and thorium X ( Ra) are impossible to separate. Attempts to place the radioelements in the periodic table led Soddy and Kazimierz Fajans independently to propose their radioactive displacement law in 1913, to the effect that alpha decay produced an element two places to the left in the periodic table, whereas beta decay emission produced an element one place to

5355-699: The lowest-energy ground state ), for example 73 Ta ( tantalum-180m ). The common pronunciation of the AZE notation is different from how it is written: 2 He is commonly pronounced as helium-four instead of four-two-helium, and 92 U as uranium two-thirty-five (American English) or uranium-two-three-five (British) instead of 235-92-uranium. Some isotopes/nuclides are radioactive , and are therefore referred to as radioisotopes or radionuclides , whereas others have never been observed to decay radioactively and are referred to as stable isotopes or stable nuclides . For example, C

5440-457: The meaning behind the name is that different isotopes of a single element occupy the same position on the periodic table . It was coined by Scottish doctor and writer Margaret Todd in a 1913 suggestion to the British chemist Frederick Soddy , who popularized the term. The number of protons within the atom's nucleus is called its atomic number and is equal to the number of electrons in

5525-421: The neutral (non-ionized) atom. Each atomic number identifies a specific element, but not the isotope; an atom of a given element may have a wide range in its number of neutrons . The number of nucleons (both protons and neutrons) in the nucleus is the atom's mass number , and each isotope of a given element has a different mass number. For example, carbon-12 , carbon-13 , and carbon-14 are three isotopes of

5610-417: The other about 22. The parabola due to the heavier gas is always much fainter than that due to the lighter, so that probably the heavier gas forms only a small percentage of the mixture." F. W. Aston subsequently discovered multiple stable isotopes for numerous elements using a mass spectrograph . In 1919 Aston studied neon with sufficient resolution to show that the two isotopic masses are very close to

5695-689: The other naturally occurring nuclides are radioactive but occur on Earth due to their relatively long half-lives, or else due to other means of ongoing natural production. These include the afore-mentioned cosmogenic nuclides , the nucleogenic nuclides, and any radiogenic nuclides formed by ongoing decay of a primordial radioactive nuclide, such as radon and radium from uranium. An additional ~3000 radioactive nuclides not found in nature have been created in nuclear reactors and in particle accelerators. Many short-lived nuclides not found naturally on Earth have also been observed by spectroscopic analysis, being naturally created in stars or supernovae . An example

5780-726: The others. There are 41 odd-numbered elements with Z = 1 through 81, of which 39 have stable isotopes ( technetium ( 43 Tc ) and promethium ( 61 Pm ) have no stable isotopes). Of these 39 odd Z elements, 30 elements (including hydrogen-1 where 0 neutrons is even ) have one stable odd-even isotope, and nine elements: chlorine ( 17 Cl ), potassium ( 19 K ), copper ( 29 Cu ), gallium ( 31 Ga ), bromine ( 35 Br ), silver ( 47 Ag ), antimony ( 51 Sb ), iridium ( 77 Ir ), and thallium ( 81 Tl ), have two odd-even stable isotopes each. This makes

5865-415: The possibility of proton decay , which would make all nuclides ultimately unstable). Some stable nuclides are in theory energetically susceptible to other known forms of decay, such as alpha decay or double beta decay, but no decay products have yet been observed, and so these isotopes are said to be "observationally stable". The predicted half-lives for these nuclides often greatly exceed the estimated age of

5950-432: The primary exceptions). The vibrational modes of a molecule are determined by its shape and by the masses of its constituent atoms; so different isotopologues have different sets of vibrational modes. Because vibrational modes allow a molecule to absorb photons of corresponding energies, isotopologues have different optical properties in the infrared range. Atomic nuclei consist of protons and neutrons bound together by

6035-457: The properties of the various isotopes of a given element. Isotope separation is a significant technological challenge, particularly with heavy elements such as uranium or plutonium. Lighter elements such as lithium, carbon, nitrogen, and oxygen are commonly separated by gas diffusion of their compounds such as CO and NO. The separation of hydrogen and deuterium is unusual because it is based on chemical rather than physical properties, for example in

6120-586: The relative mass difference between isotopes is much less so that the mass-difference effects on chemistry are usually negligible. (Heavy elements also have relatively more neutrons than lighter elements, so the ratio of the nuclear mass to the collective electronic mass is slightly greater.) There is also an equilibrium isotope effect . Similarly, two molecules that differ only in the isotopes of their atoms ( isotopologues ) have identical electronic structures, and therefore almost indistinguishable physical and chemical properties (again with deuterium and tritium being

6205-451: The right. Soddy recognized that emission of an alpha particle followed by two beta particles led to the formation of an element chemically identical to the initial element but with a mass four units lighter and with different radioactive properties. Soddy proposed that several types of atoms (differing in radioactive properties) could occupy the same place in the table. For example, the alpha-decay of uranium-235 forms thorium-231, whereas

6290-452: The same chemical element), but different nucleon numbers ( mass numbers ) due to different numbers of neutrons in their nuclei. While all isotopes of a given element have similar chemical properties, they have different atomic masses and physical properties. The term isotope is derived from the Greek roots isos ( ἴσος "equal") and topos ( τόπος "place"), meaning "the same place"; thus,

6375-441: The same element. This is most pronounced by far for protium ( H ), deuterium ( H ), and tritium ( H ), because deuterium has twice the mass of protium and tritium has three times the mass of protium. These mass differences also affect the behavior of their respective chemical bonds, by changing the center of gravity ( reduced mass ) of the atomic systems. However, for heavier elements,

6460-489: The same mass number ). However, isotope is the older term and so is better known than nuclide and is still sometimes used in contexts in which nuclide might be more appropriate, such as nuclear technology and nuclear medicine . An isotope and/or nuclide is specified by the name of the particular element (this indicates the atomic number) followed by a hyphen and the mass number (e.g. helium-3 , helium-4 , carbon-12 , carbon-14 , uranium-235 and uranium-239 ). When

6545-403: The same term [REDACTED] This disambiguation page lists articles associated with the title OPX . If an internal link led you here, you may wish to change the link to point directly to the intended article. Retrieved from " https://en.wikipedia.org/w/index.php?title=OPX&oldid=1214358628 " Category : Disambiguation pages Hidden categories: Short description

6630-406: The sense of never having been observed to decay as of the present time. An additional 35 primordial nuclides (to a total of 286 primordial nuclides), are radioactive with known half-lives, but have half-lives longer than 100 million years, allowing them to exist from the beginning of the Solar System. See list of nuclides for details. All the known stable nuclides occur naturally on Earth;

6715-401: The shergottites formed. The shergottites appear to have crystallised as recently as 180 million years ago, which is a surprisingly young age considering how ancient the majority of the surface of Mars appears to be, and the small size of Mars itself. Because of this, some have advocated the idea that the shergottites are much older than this. This "Shergottite Age Paradox" remains unsolved and

6800-405: The structures are too small to be Earthly bacteria and don't look especially like lifeforms to him. The size of the objects is consistent with Earthly " nanobacteria ", but the existence of nanobacteria itself has been largely discredited. Many studies disputed the validity of the fossils. For example, it was found that most of the organic matter in the meteorite was of terrestrial origin. But,

6885-420: The universe, and in fact, there are also 31 known radionuclides (see primordial nuclide ) with half-lives longer than the age of the universe. Adding in the radioactive nuclides that have been created artificially, there are 3,339 currently known nuclides . These include 905 nuclides that are either stable or have half-lives longer than 60 minutes. See list of nuclides for details. The existence of isotopes

6970-513: Was first suggested in 1913 by the radiochemist Frederick Soddy , based on studies of radioactive decay chains that indicated about 40 different species referred to as radioelements (i.e. radioactive elements) between uranium and lead, although the periodic table only allowed for 11 elements between lead and uranium inclusive. Several attempts to separate these new radioelements chemically had failed. For example, Soddy had shown in 1910 that mesothorium (later shown to be Ra), radium ( Ra,

7055-488: Was heated during the Amazonian geologic period on Mars. A meteorite that fell in 1986 in Dayanpo, China contained a magnesium silicate mineral called " Elgoresyte ", a mineral not found on Earth. The majority of SNC meteorites are quite young compared to most other meteorites and seem to imply that volcanic activity was present on Mars only a few hundred million years ago. The young formation ages of Martian meteorites

7140-570: Was one of the early recognized characteristics that suggested their origin from a planetary body such as Mars. Among Martian meteorites, only ALH 84001 and NWA 7034 have radiometric ages older than about 1400 Ma (Ma = million years). All nakhlites, as well as Chassigny and NWA 2737, give similar if not identical formation ages around 1300 Ma, as determined by various radiometric dating techniques. Formation ages determined for many shergottites are variable and much younger, mostly ~150–575 Ma. The chronological history of shergottites

7225-514: Was that the microfossils were not indicative of Martian life, but of contamination by earthly biofilms . ALH 84001 is as old as the basaltic and intermediate shergottite groups – i.e., 4.1 billion years old. In March 2004 it was suggested that the unique Kaidun meteorite , which landed in Yemen on December 3, 1980, may have originated on the Martian moon of Phobos . Because Phobos has similarities to C-type asteroids and because

#671328