113-476: Lithium (from Ancient Greek λίθος ( líthos ) 'stone') is a chemical element ; it has symbol Li and atomic number 3. It is a soft, silvery-white alkali metal . Under standard conditions , it is the least dense metal and the least dense solid element. Like all alkali metals, lithium is highly reactive and flammable, and must be stored in vacuum, inert atmosphere, or inert liquid such as purified kerosene or mineral oil. It exhibits
226-508: A diagonal relationship with magnesium , an element of similar atomic and ionic radius . Chemical resemblances between the two metals include the formation of a nitride by reaction with N 2 , the formation of an oxide ( Li 2 O ) and peroxide ( Li 2 O 2 ) when burnt in O 2 , salts with similar solubilities , and thermal instability of the carbonates and nitrides. The metal reacts with hydrogen gas at high temperatures to produce lithium hydride (LiH). Lithium forms
339-543: A pitch accent . In Modern Greek, all vowels and consonants are short. Many vowels and diphthongs once pronounced distinctly are pronounced as /i/ ( iotacism ). Some of the stops and glides in diphthongs have become fricatives , and the pitch accent has changed to a stress accent . Many of the changes took place in the Koine Greek period. The writing system of Modern Greek, however, does not reflect all pronunciation changes. The examples below represent Attic Greek in
452-402: A rhombohedral crystal system (with a nine-layer repeat spacing); at higher temperatures it transforms to face-centered cubic and then body-centered cubic . At liquid-helium temperatures (4 K) the rhombohedral structure is prevalent. Multiple allotropic forms have been identified for lithium at high pressures. Lithium has a mass specific heat capacity of 3.58 kilojoules per kilogram-kelvin,
565-494: A variable void fraction which depends on how the material is agitated or poured. It might be loose or compact, with more or less air space depending on handling. In practice, the void fraction is not necessarily air, or even gaseous. In the case of sand, it could be water, which can be advantageous for measurement as the void fraction for sand saturated in water—once any air bubbles are thoroughly driven out—is potentially more consistent than dry sand measured with an air void. In
678-525: A fifth major dialect group, or it is Mycenaean Greek overlaid by Doric, with a non-Greek native influence. Regarding the speech of the ancient Macedonians diverse theories have been put forward, but the epigraphic activity and the archaeological discoveries in the Greek region of Macedonia during the last decades has brought to light documents, among which the first texts written in Macedonian , such as
791-407: A flame, lithium compounds give off a striking crimson color, but when the metal burns strongly, the flame becomes a brilliant silver. Lithium will ignite and burn in oxygen when exposed to water or water vapor. In moist air, lithium rapidly tarnishes to form a black coating of lithium hydroxide (LiOH and LiOH·H 2 O), lithium nitride (Li 3 N) and lithium carbonate (Li 2 CO 3 , the result of
904-518: A higher than usual concentration of lithium (such as Centaurus X-4 ) orbit massive objects—neutron stars or black holes—whose gravity evidently pulls heavier lithium to the surface of a hydrogen-helium star, causing more lithium to be observed. On 27 May 2020, astronomers reported that classical nova explosions are galactic producers of lithium-7. Although lithium is widely distributed on Earth, it does not naturally occur in elemental form due to its high reactivity. The total lithium content of seawater
1017-641: A major source of artificial lithium fractionation, with the light isotope Li being retained by industry and military stockpiles to such an extent that it has caused slight but measurable change in the Li to Li ratios in natural sources, such as rivers. This has led to unusual uncertainty in the standardized atomic weight of lithium, since this quantity depends on the natural abundance ratios of these naturally-occurring stable lithium isotopes, as they are available in commercial lithium mineral sources. Both stable isotopes of lithium can be laser cooled and were used to produce
1130-447: A metallic luster . It corrodes quickly in air to a dull silvery gray, then black tarnish. It does not occur freely in nature, but occurs mainly as pegmatitic minerals, which were once the main source of lithium. Due to its solubility as an ion, it is present in ocean water and is commonly obtained from brines . Lithium metal is isolated electrolytically from a mixture of lithium chloride and potassium chloride . The nucleus of
1243-550: A prefix /e-/, called the augment . This was probably originally a separate word, meaning something like "then", added because tenses in PIE had primarily aspectual meaning. The augment is added to the indicative of the aorist, imperfect, and pluperfect, but not to any of the other forms of the aorist (no other forms of the imperfect and pluperfect exist). The two kinds of augment in Greek are syllabic and quantitative. The syllabic augment
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#17327932899781356-417: A secondary reaction between LiOH and CO 2 ). Lithium is one of the few metals that react with nitrogen gas. Because of its reactivity with water, and especially nitrogen, lithium metal is usually stored in a hydrocarbon sealant, often petroleum jelly . Although the heavier alkali metals can be stored under mineral oil , lithium is not dense enough to fully submerge itself in these liquids. Lithium has
1469-482: A single valence electron that, in the presence of solvents, is easily released to form Li. Because of this, lithium is a good conductor of heat and electricity as well as a highly reactive element, though it is the least reactive of the alkali metals. Lithium's lower reactivity is due to the proximity of its valence electron to its nucleus (the remaining two electrons are in the 1s orbital , much lower in energy, and do not participate in chemical bonds). Molten lithium
1582-942: A solution sums to density of the solution, ρ = ∑ i ρ i . {\displaystyle \rho =\sum _{i}\rho _{i}.} Expressed as a function of the densities of pure components of the mixture and their volume participation , it allows the determination of excess molar volumes : ρ = ∑ i ρ i V i V = ∑ i ρ i φ i = ∑ i ρ i V i ∑ i V i + ∑ i V E i , {\displaystyle \rho =\sum _{i}\rho _{i}{\frac {V_{i}}{V}}\,=\sum _{i}\rho _{i}\varphi _{i}=\sum _{i}\rho _{i}{\frac {V_{i}}{\sum _{i}V_{i}+\sum _{i}{V^{E}}_{i}}},} provided that there
1695-542: A strong Northwest Greek influence, and can in some respects be considered a transitional dialect, as exemplified in the poems of the Boeotian poet Pindar who wrote in Doric with a small Aeolic admixture. Thessalian likewise had come under Northwest Greek influence, though to a lesser degree. Pamphylian Greek , spoken in a small area on the southwestern coast of Anatolia and little preserved in inscriptions, may be either
1808-455: A substance does not increase its density; rather it increases its mass. Other conceptually comparable quantities or ratios include specific density , relative density (specific gravity) , and specific weight . The understanding that different materials have different densities, and of a relationship between density, floating, and sinking must date to prehistoric times. Much later it was put in writing. Aristotle , for example, wrote: There
1921-399: A temperature increase on the order of thousands of degrees Celsius . In contrast, the density of gases is strongly affected by pressure. The density of an ideal gas is ρ = M P R T , {\displaystyle \rho ={\frac {MP}{RT}},} where M is the molar mass , P is the pressure, R is the universal gas constant , and T
2034-483: A variety of binary and ternary materials by direct reaction with the main group elements. These Zintl phases , although highly covalent, can be viewed as salts of polyatomic anions such as Si 4 , P 7 , and Te 5 . With graphite, lithium forms a variety of intercalation compounds . It dissolves in ammonia (and amines) to give [Li(NH 3 ) 4 ] and the solvated electron . Lithium forms salt-like derivatives with all halides and pseudohalides. Some examples include
2147-422: A very low density (0.534 g/cm), comparable with pine wood . It is the least dense of all elements that are solids at room temperature; the next lightest solid element (potassium, at 0.862 g/cm) is more than 60% denser. Apart from helium and hydrogen , as a solid it is less dense than any other element as a liquid, being only two-thirds as dense as liquid nitrogen (0.808 g/cm). Lithium can float on
2260-510: A vowel or /n s r/ ; final stops were lost, as in γάλα "milk", compared with γάλακτος "of milk" (genitive). Ancient Greek of the classical period also differed in both the inventory and distribution of original PIE phonemes due to numerous sound changes, notably the following: The pronunciation of Ancient Greek was very different from that of Modern Greek . Ancient Greek had long and short vowels ; many diphthongs ; double and single consonants; voiced, voiceless, and aspirated stops ; and
2373-654: A wide variety of natural processes, including mineral formation (chemical precipitation), metabolism , and ion exchange . Lithium ions substitute for magnesium and iron in octahedral sites in clay minerals, where Li is preferred to Li, resulting in enrichment of the light isotope in processes of hyperfiltration and rock alteration. The exotic Li is known to exhibit a neutron halo , with 2 neutrons orbiting around its nucleus of 3 protons and 6 neutrons. The process known as laser isotope separation can be used to separate lithium isotopes, in particular Li from Li. Nuclear weapons manufacture and other nuclear physics applications are
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#17327932899782486-411: Is mass divided by volume . As there are many units of mass and volume covering many different magnitudes there are a large number of units for mass density in use. The SI unit of kilogram per cubic metre (kg/m ) and the cgs unit of gram per cubic centimetre (g/cm ) are probably the most commonly used units for density. One g/cm is equal to 1000 kg/m . One cubic centimetre (abbreviation cc)
2599-520: Is ρ (the lower case Greek letter rho ), although the Latin letter D can also be used. Mathematically, density is defined as mass divided by volume: ρ = m V , {\displaystyle \rho ={\frac {m}{V}},} where ρ is the density, m is the mass, and V is the volume. In some cases (for instance, in the United States oil and gas industry), density
2712-560: Is actually [BuLi] 6 and MeLi is actually [MeLi] 4 ) which feature multi-center bonding and increase the coordination number around lithium. These clusters are broken down into smaller or monomeric units in the presence of solvents like dimethoxyethane (DME) or ligands like tetramethylethylenediamine (TMEDA). As an exception to the duet rule, a two-coordinate lithate complex with four electrons around lithium, [Li(thf) 4 ][((Me 3 Si) 3 C) 2 Li], has been characterized crystallographically. Lithium production has greatly increased since
2825-418: Is added to stems beginning with consonants, and simply prefixes e (stems beginning with r , however, add er ). The quantitative augment is added to stems beginning with vowels, and involves lengthening the vowel: Some verbs augment irregularly; the most common variation is e → ei . The irregularity can be explained diachronically by the loss of s between vowels, or that of the letter w , which affected
2938-478: Is also found in brown dwarf substellar objects and certain anomalous orange stars. Because lithium is present in cooler, less-massive brown dwarfs, but is destroyed in hotter red dwarf stars, its presence in the stars' spectra can be used in the "lithium test" to differentiate the two, as both are smaller than the Sun. Certain orange stars can also contain a high concentration of lithium. Those orange stars found to have
3051-435: Is apparently caused by the "mixing" of lithium into the interior of stars, where it is destroyed, while lithium is produced in younger stars. Although it transmutes into two atoms of helium due to collision with a proton at temperatures above 2.4 million degrees Celsius (most stars easily attain this temperature in their interiors), lithium is more abundant than computations would predict in later-generation stars. Lithium
3164-448: Is considered by some linguists to have been closely related to Greek . Among Indo-European branches with living descendants, Greek is often argued to have the closest genetic ties with Armenian (see also Graeco-Armenian ) and Indo-Iranian languages (see Graeco-Aryan ). Ancient Greek differs from Proto-Indo-European (PIE) and other Indo-European languages in certain ways. In phonotactics , ancient Greek words could end only in
3277-583: Is difficult. One reason for this is that most lithium classification schemes are developed for solid ore deposits, whereas brine is a fluid that is problematic to treat with the same classification scheme due to varying concentrations and pumping effects. In 2019, world production of lithium from spodumene was around 80,000t per annum, primarily from the Greenbushes pegmatite and from some Chinese and Chilean sources. The Talison mine in Greenbushes
3390-489: Is equal to one millilitre. In industry, other larger or smaller units of mass and or volume are often more practical and US customary units may be used. See below for a list of some of the most common units of density. The litre and tonne are not part of the SI, but are acceptable for use with it, leading to the following units: Densities using the following metric units all have exactly the same numerical value, one thousandth of
3503-529: Is estimated (2020) to have the largest reserves by far (9.2 million tonnes), and Australia the highest annual production (40,000 tonnes). One of the largest reserve bases of lithium is in the Salar de Uyuni area of Bolivia, which has 5.4 million tonnes. Other major suppliers include Australia, Argentina and China. As of 2015, the Czech Geological Survey considered the entire Ore Mountains in
Lithium - Misplaced Pages Continue
3616-425: Is found in trace amount in numerous plants, plankton, and invertebrates, at concentrations of 69 to 5,760 parts per billion (ppb). In vertebrates the concentration is slightly lower, and nearly all vertebrate tissue and body fluids contain lithium ranging from 21 to 763 ppb. Marine organisms tend to bioaccumulate lithium more than terrestrial organisms. Whether lithium has a physiological role in any of these organisms
3729-398: Is loosely defined as its weight per unit volume , although this is scientifically inaccurate – this quantity is more specifically called specific weight . For a pure substance the density has the same numerical value as its mass concentration . Different materials usually have different densities, and density may be relevant to buoyancy , purity and packaging . Osmium
3842-403: Is necessary to have an understanding of the type of density being measured as well as the type of material in question. The density at all points of a homogeneous object equals its total mass divided by its total volume. The mass is normally measured with a scale or balance ; the volume may be measured directly (from the geometry of the object) or by the displacement of a fluid. To determine
3955-474: Is not understood. Even the exact mechanisms involved in lithium toxicity are not fully understood. Petalite (LiAlSi 4 O 10 ) was discovered in 1800 by the Brazilian chemist and statesman José Bonifácio de Andrada e Silva in a mine on the island of Utö , Sweden. However, it was not until 1817 that Johan August Arfwedson , then working in the laboratory of the chemist Jöns Jakob Berzelius , detected
4068-464: Is present in biological systems in trace amounts. It has no established metabolic function in humans. Lithium-based drugs are useful as a mood stabilizer and antidepressant in the treatment of mental illness such as bipolar disorder . The alkali metals are also called the lithium family, after its leading element. Like the other alkali metals (which are sodium (Na), potassium (K), rubidium (Rb), caesium (Cs), and francium (Fr)), lithium has
4181-479: Is reported to be the largest and to have the highest grade of ore at 2.4% Li 2 O (2012 figures). Ancient Greek language Ancient Greek ( Ἑλληνῐκή , Hellēnikḗ ; [hellɛːnikɛ́ː] ) includes the forms of the Greek language used in ancient Greece and the ancient world from around 1500 BC to 300 BC. It is often roughly divided into the following periods: Mycenaean Greek ( c. 1400–1200 BC ), Dark Ages ( c. 1200–800 BC ),
4294-418: Is significantly more reactive than its solid form. Lithium metal is soft enough to be cut with a knife. It is silvery-white. In air it oxidizes to lithium oxide . Its melting point of 180.50 °C (453.65 K; 356.90 °F) and its boiling point of 1,342 °C (1,615 K; 2,448 °F) are each the highest of all the alkali metals while its density of 0.534 g/cm is the lowest. Lithium has
4407-453: Is small. The compressibility for a typical liquid or solid is 10 bar (1 bar = 0.1 MPa) and a typical thermal expansivity is 10 K . This roughly translates into needing around ten thousand times atmospheric pressure to reduce the volume of a substance by one percent. (Although the pressures needed may be around a thousand times smaller for sandy soil and some clays.) A one percent expansion of volume typically requires
4520-488: Is so great a difference in density between salt and fresh water that vessels laden with cargoes of the same weight almost sink in rivers, but ride quite easily at sea and are quite seaworthy. And an ignorance of this has sometimes cost people dear who load their ships in rivers. The following is a proof that the density of a fluid is greater when a substance is mixed with it. If you make water very salt by mixing salt in with it, eggs will float on it. ... If there were any truth in
4633-428: Is so much denser than air that the buoyancy effect is commonly neglected (less than one part in one thousand). Mass change upon displacing one void material with another while maintaining constant volume can be used to estimate the void fraction, if the difference in density of the two voids materials is reliably known. In general, density can be changed by changing either the pressure or the temperature . Increasing
Lithium - Misplaced Pages Continue
4746-609: Is the absolute temperature . This means that the density of an ideal gas can be doubled by doubling the pressure, or by halving the absolute temperature. In the case of volumic thermal expansion at constant pressure and small intervals of temperature the temperature dependence of density is ρ = ρ T 0 1 + α ⋅ Δ T , {\displaystyle \rho ={\frac {\rho _{T_{0}}}{1+\alpha \cdot \Delta T}},} where ρ T 0 {\displaystyle \rho _{T_{0}}}
4859-418: Is the densest known element at standard conditions for temperature and pressure . To simplify comparisons of density across different systems of units, it is sometimes replaced by the dimensionless quantity " relative density " or " specific gravity ", i.e. the ratio of the density of the material to that of a standard material, usually water. Thus a relative density less than one relative to water means that
4972-487: Is the density at a reference temperature, α {\displaystyle \alpha } is the thermal expansion coefficient of the material at temperatures close to T 0 {\displaystyle T_{0}} . The density of a solution is the sum of mass (massic) concentrations of the components of that solution. Mass (massic) concentration of each given component ρ i {\displaystyle \rho _{i}} in
5085-485: Is the only low numbered element that can produce net energy through nuclear fission . The two lithium nuclei have lower binding energies per nucleon than any other stable nuclides other than hydrogen-1 , deuterium and helium-3 . As a result of this, though very light in atomic weight, lithium is less common in the Solar System than 25 of the first 32 chemical elements. Seven radioisotopes have been characterized,
5198-699: Is through the Western Lithium Corporation in the United States. At 20 mg lithium per kg of Earth's crust, lithium is the 31st most abundant element. According to the Handbook of Lithium and Natural Calcium , "Lithium is a comparatively rare element, although it is found in many rocks and some brines, but always in very low concentrations. There are a fairly large number of both lithium mineral and brine deposits but only comparatively few of them are of actual or potential commercial value. Many are very small, others are too low in grade." Chile
5311-678: Is unknown. Lithium concentrations in human tissue averages about 24 ppb (4 ppb in blood , and 1.3 ppm in bone ). Lithium is easily absorbed by plants and lithium concentration in plant tissue is typically around 1 ppm . Some plant families bioaccumulate more lithium than others. Dry weight lithium concentrations for members of the family Solanaceae (which includes potatoes and tomatoes ), for instance, can be as high as 30 ppm while this can be as low as 0.05 ppb for corn grains . Studies of lithium concentrations in mineral-rich soil give ranges between around 0.1 and 50−100 ppm , with some concentrations as high as 100−400 ppm, although it
5424-761: Is unlikely that all of it is available for uptake by plants . Lithium accumulation does not appear to affect the essential nutrient composition of plants. Tolerance to lithium varies by plant species and typically parallels sodium tolerance ; maize and Rhodes grass , for example, are highly tolerant to lithium injury while avocado and soybean are very sensitive. Similarly, lithium at concentrations of 5 ppm reduces seed germination in some species (e.g. Asian rice and chickpea ) but not in others (e.g. barley and wheat ). Many of lithium's major biological effects can be explained by its competition with other ions. The monovalent lithium ion Li competes with other ions such as sodium (immediately below lithium on
5537-466: Is very large and is estimated as 230 billion tonnes, where the element exists at a relatively constant concentration of 0.14 to 0.25 parts per million (ppm), or 25 micromolar ; higher concentrations approaching 7 ppm are found near hydrothermal vents . Estimates for the Earth's crustal content range from 20 to 70 ppm by weight. In keeping with its name, lithium forms a minor part of igneous rocks , with
5650-679: The Archaic or Epic period ( c. 800–500 BC ), and the Classical period ( c. 500–300 BC ). Ancient Greek was the language of Homer and of fifth-century Athenian historians, playwrights, and philosophers . It has contributed many words to English vocabulary and has been a standard subject of study in educational institutions of the Western world since the Renaissance . This article primarily contains information about
5763-606: The Epic and Classical periods of the language, which are the best-attested periods and considered most typical of Ancient Greek. From the Hellenistic period ( c. 300 BC ), Ancient Greek was followed by Koine Greek , which is regarded as a separate historical stage, though its earliest form closely resembles Attic Greek , and its latest form approaches Medieval Greek . There were several regional dialects of Ancient Greek; Attic Greek developed into Koine. Ancient Greek
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#17327932899785876-501: The Pella curse tablet , as Hatzopoulos and other scholars note. Based on the conclusions drawn by several studies and findings such as Pella curse tablet , Emilio Crespo and other scholars suggest that ancient Macedonian was a Northwest Doric dialect , which shares isoglosses with its neighboring Thessalian dialects spoken in northeastern Thessaly . Some have also suggested an Aeolic Greek classification. The Lesbian dialect
5989-521: The coordination complex [Li(H 2 O) 4 ] predominates for many lithium salts. Related complexes are known with amines and ethers. Organolithium compounds are numerous and useful. They are defined by the presence of a bond between carbon and lithium. They serve as metal-stabilized carbanions , although their solution and solid-state structures are more complex than this simplistic view. Thus, these are extremely powerful bases and nucleophiles . They have also been applied in asymmetric synthesis in
6102-542: The displacement of the water. Upon this discovery, he leapt from his bath and ran naked through the streets shouting, "Eureka! Eureka!" ( Ancient Greek : Εύρηκα! , lit. 'I have found it'). As a result, the term eureka entered common parlance and is used today to indicate a moment of enlightenment. The story first appeared in written form in Vitruvius ' books of architecture , two centuries after it supposedly took place. Some scholars have doubted
6215-603: The epic poems , the Iliad and the Odyssey , and in later poems by other authors. Homeric Greek had significant differences in grammar and pronunciation from Classical Attic and other Classical-era dialects. The origins, early form and development of the Hellenic language family are not well understood because of a lack of contemporaneous evidence. Several theories exist about what Hellenic dialect groups may have existed between
6328-1082: The periodic table ), which like lithium is also a monovalent alkali metal . Lithium also competes with bivalent magnesium ions, whose ionic radius (86 pm ) is approximately that of the lithium ion (90 pm). Mechanisms that transport sodium across cellular membranes also transport lithium. For instance, sodium channels (both voltage-gated and epithelial ) are particularly major pathways of entry for lithium. Lithium ions can also permeate through ligand-gated ion channels as well as cross both nuclear and mitochondrial membranes . Like sodium, lithium can enter and partially block (although not permeate ) potassium channels and calcium channels . The biological effects of lithium are many and varied but its mechanisms of action are only partially understood. For instance, studies of lithium-treated patients with bipolar disorder show that, among many other effects, lithium partially reverses telomere shortening in these patients and also increases mitochondrial function, although how lithium produces these pharmacological effects
6441-501: The present , future , and imperfect are imperfective in aspect; the aorist , present perfect , pluperfect and future perfect are perfective in aspect. Most tenses display all four moods and three voices, although there is no future subjunctive or imperative. Also, there is no imperfect subjunctive, optative or imperative. The infinitives and participles correspond to the finite combinations of tense, aspect, and voice. The indicative of past tenses adds (conceptually, at least)
6554-1031: The 5th century BC. Ancient pronunciation cannot be reconstructed with certainty, but Greek from the period is well documented, and there is little disagreement among linguists as to the general nature of the sounds that the letters represent. /oː/ raised to [uː] , probably by the 4th century BC. Greek, like all of the older Indo-European languages , is highly inflected. It is highly archaic in its preservation of Proto-Indo-European forms. In ancient Greek, nouns (including proper nouns) have five cases ( nominative , genitive , dative , accusative , and vocative ), three genders ( masculine , feminine , and neuter ), and three numbers (singular, dual , and plural ). Verbs have four moods ( indicative , imperative , subjunctive , and optative ) and three voices (active, middle, and passive ), as well as three persons (first, second, and third) and various other forms. Verbs are conjugated through seven combinations of tenses and aspect (generally simply called "tenses"):
6667-495: The Archaic period of ancient Greek (see Homeric Greek for more details): Μῆνιν ἄειδε, θεά, Πηληϊάδεω Ἀχιλῆος οὐλομένην, ἣ μυρί' Ἀχαιοῖς ἄλγε' ἔθηκε, πολλὰς δ' ἰφθίμους ψυχὰς Ἄϊδι προΐαψεν ἡρώων, αὐτοὺς δὲ ἑλώρια τεῦχε κύνεσσιν οἰωνοῖσί τε πᾶσι· Διὸς δ' ἐτελείετο βουλή· ἐξ οὗ δὴ τὰ πρῶτα διαστήτην ἐρίσαντε Ἀτρεΐδης τε ἄναξ ἀνδρῶν καὶ δῖος Ἀχιλλεύς. The beginning of Apology by Plato exemplifies Attic Greek from
6780-584: The Classical period of ancient Greek. (The second line is the IPA , the third is transliterated into the Latin alphabet using a modern version of the Erasmian scheme .) Ὅτι [hóti Hóti μὲν men mèn ὑμεῖς, hyːmêːs hūmeîs, Density#Unit Density ( volumetric mass density or specific mass ) is a substance's mass per unit of volume . The symbol most often used for density
6893-689: The Czech Republic as lithium province. Five deposits are registered, one near Cínovec [ cs ] is considered as a potentially economical deposit, with 160 000 tonnes of lithium. In December 2019, Finnish mining company Keliber Oy reported its Rapasaari lithium deposit has estimated proven and probable ore reserves of 5.280 million tonnes. In June 2010, The New York Times reported that American geologists were conducting ground surveys on dry salt lakes in western Afghanistan believing that large deposits of lithium are located there. These estimates are "based principally on old data, which
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#17327932899787006-545: The Dorians. The Greeks of this period believed there were three major divisions of all Greek people – Dorians, Aeolians, and Ionians (including Athenians), each with their own defining and distinctive dialects. Allowing for their oversight of Arcadian, an obscure mountain dialect, and Cypriot, far from the center of Greek scholarship, this division of people and language is quite similar to the results of modern archaeological-linguistic investigation. One standard formulation for
7119-431: The accuracy of this tale, saying among other things that the method would have required precise measurements that would have been difficult to make at the time. Nevertheless, in 1586, Galileo Galilei , in one of his first experiments, made a possible reconstruction of how the experiment could have been performed with ancient Greek resources From the equation for density ( ρ = m / V ), mass density has any unit that
7232-550: The aorist. Following Homer 's practice, the augment is sometimes not made in poetry , especially epic poetry. The augment sometimes substitutes for reduplication; see below. Almost all forms of the perfect, pluperfect, and future perfect reduplicate the initial syllable of the verb stem. (A few irregular forms of perfect do not reduplicate, whereas a handful of irregular aorists reduplicate.) The three types of reduplication are: Irregular duplication can be understood diachronically. For example, lambanō (root lab ) has
7345-460: The atomic weight of lithium in some "natural sources" of lithium ion which had been "contaminated" by lithium salts discharged from isotope separation facilities, which had found its way into ground water. Lithium is used to decrease the melting temperature of glass and to improve the melting behavior of aluminium oxide in the Hall-Héroult process . These two uses dominated the market until
7458-419: The augment when it was word-initial. In verbs with a preposition as a prefix, the augment is placed not at the start of the word, but between the preposition and the original verb. For example, προσ(-)βάλλω (I attack) goes to προσ έ βαλoν in the aorist. However compound verbs consisting of a prefix that is not a preposition retain the augment at the start of the word: αὐτο(-)μολῶ goes to ηὐ τομόλησα in
7571-404: The body then can be expressed as m = ∫ V ρ ( r → ) d V . {\displaystyle m=\int _{V}\rho ({\vec {r}})\,dV.} In practice, bulk materials such as sugar, sand, or snow contain voids. Many materials exist in nature as flakes, pellets, or granules. Voids are regions which contain something other than
7684-407: The bottom of a fluid results in convection of the heat from the bottom to the top, due to the decrease in the density of the heated fluid, which causes it to rise relative to denser unheated material. The reciprocal of the density of a substance is occasionally called its specific volume , a term sometimes used in thermodynamics . Density is an intensive property in that increasing the amount of
7797-416: The case of non-compact materials, one must also take care in determining the mass of the material sample. If the material is under pressure (commonly ambient air pressure at the earth's surface) the determination of mass from a measured sample weight might need to account for buoyancy effects due to the density of the void constituent, depending on how the measurement was conducted. In the case of dry sand, sand
7910-405: The considered material. Commonly the void is air, but it could also be vacuum, liquid, solid, or a different gas or gaseous mixture. The bulk volume of a material —inclusive of the void space fraction — is often obtained by a simple measurement (e.g. with a calibrated measuring cup) or geometrically from known dimensions. Mass divided by bulk volume determines bulk density . This is not
8023-710: The density can be calculated. One dalton per cubic ångström is equal to a density of 1.660 539 066 60 g/cm . A number of techniques as well as standards exist for the measurement of density of materials. Such techniques include the use of a hydrometer (a buoyancy method for liquids), Hydrostatic balance (a buoyancy method for liquids and solids), immersed body method (a buoyancy method for liquids), pycnometer (liquids and solids), air comparison pycnometer (solids), oscillating densitometer (liquids), as well as pour and tap (solids). However, each individual method or technique measures different types of density (e.g. bulk density, skeletal density, etc.), and therefore it
8136-427: The density of a liquid or a gas, a hydrometer , a dasymeter or a Coriolis flow meter may be used, respectively. Similarly, hydrostatic weighing uses the displacement of water due to a submerged object to determine the density of the object. If the body is not homogeneous, then its density varies between different regions of the object. In that case the density around any given location is determined by calculating
8249-488: The density of a small volume around that location. In the limit of an infinitesimal volume the density of an inhomogeneous object at a point becomes: ρ ( r → ) = d m / d V {\displaystyle \rho ({\vec {r}})=dm/dV} , where d V {\displaystyle dV} is an elementary volume at position r → {\displaystyle {\vec {r}}} . The mass of
8362-615: The dialect of Sparta ), and Northern Peloponnesus Doric (including Corinthian ). All the groups were represented by colonies beyond Greece proper as well, and these colonies generally developed local characteristics, often under the influence of settlers or neighbors speaking different Greek dialects. After the conquests of Alexander the Great in the late 4th century BC, a new international dialect known as Koine or Common Greek developed, largely based on Attic Greek , but with influence from other dialects. This dialect slowly replaced most of
8475-530: The dialects is: West vs. non-West Greek is the strongest-marked and earliest division, with non-West in subsets of Ionic-Attic (or Attic-Ionic) and Aeolic vs. Arcadocypriot, or Aeolic and Arcado-Cypriot vs. Ionic-Attic. Often non-West is called 'East Greek'. Arcadocypriot apparently descended more closely from the Mycenaean Greek of the Bronze Age. Boeotian Greek had come under
8588-510: The divergence of early Greek-like speech from the common Proto-Indo-European language and the Classical period. They have the same general outline but differ in some of the detail. The only attested dialect from this period is Mycenaean Greek , but its relationship to the historical dialects and the historical circumstances of the times imply that the overall groups already existed in some form. Scholars assume that major Ancient Greek period dialect groups developed not later than 1120 BC, at
8701-520: The electrolysis of lithium chloride by Robert Bunsen and Augustus Matthiessen . The discovery of this procedure led to commercial production of lithium in 1923 by the German company Metallgesellschaft AG , which performed an electrolysis of a liquid mixture of lithium chloride and potassium chloride . Australian psychiatrist John Cade is credited with reintroducing and popularizing the use of lithium to treat mania in 1949. Shortly after, throughout
8814-450: The end of World War II . The main sources of lithium are brines and ores . Lithium metal is produced through electrolysis applied to a mixture of fused 55% lithium chloride and 45% potassium chloride at about 450 °C. The small ionic size makes it difficult for lithium to be included in early stages of mineral crystallization. As a result, lithium remains in the molten phases, where it gets enriched, until it gets solidified in
8927-584: The fact that lithium-based soaps have a higher melting point than other alkali soaps, and are less corrosive than calcium based soaps. The small demand for lithium soaps and lubricating greases was supported by several small mining operations, mostly in the US. The demand for lithium increased dramatically during the Cold War with the production of nuclear fusion weapons . Both lithium-6 and lithium-7 produce tritium when irradiated by neutrons, and are thus useful for
9040-570: The final stages. Such lithium enrichment is responsible for all commercially promising lithium ore deposits. Brines (and dry salt) are another important source of Li. Although the number of known lithium-containing deposits and brines is large, most of them are either small or have too low Li concentrations. Thus, only a few appear to be of commercial value. The US Geological Survey (USGS) estimated worldwide identified lithium reserves in 2020 and 2021 to be 17 million and 21 million tonnes , respectively. An accurate estimate of world lithium reserves
9153-521: The first quantum degenerate Bose – Fermi mixture. Although it was synthesized in the Big Bang , lithium (together with beryllium and boron) is markedly less abundant in the universe than other elements. This is a result of the comparatively low stellar temperatures necessary to destroy lithium, along with a lack of common processes to produce it. According to modern cosmological theory, lithium—in both stable isotopes (lithium-6 and lithium-7)—was one of
9266-419: The gods and replacing it with another, cheaper alloy . Archimedes knew that the irregularly shaped wreath could be crushed into a cube whose volume could be calculated easily and compared with the mass; but the king did not approve of this. Baffled, Archimedes is said to have taken an immersion bath and observed from the rise of the water upon entering that he could calculate the volume of the gold wreath through
9379-581: The halides LiF , LiCl , LiBr , LiI , as well as the pseudohalides and related anions. Lithium carbonate has been described as the most important compound of lithium. This white solid is the principal product of beneficiation of lithium ores. It is a precursor to other salts including ceramics and materials for lithium batteries. The compounds LiBH 4 and LiAlH 4 are useful reagents . These salts and many other lithium salts exhibit distinctively high solubility in ethers, in contrast with salts of heavier alkali metals. In aqueous solution,
9492-441: The highest of all solids. Because of this, lithium metal is often used in coolants for heat transfer applications. Naturally occurring lithium is composed of two stable isotopes , Li and Li, the latter being the more abundant (95.15% natural abundance ). Both natural isotopes have anomalously low nuclear binding energy per nucleon (compared to the neighboring elements on the periodic table , helium and beryllium ); lithium
9605-434: The largest concentrations in granites . Granitic pegmatites also provide the greatest abundance of lithium-containing minerals, with spodumene and petalite being the most commercially viable sources. Another significant mineral of lithium is lepidolite which is now an obsolete name for a series formed by polylithionite and trilithionite. Another source for lithium is hectorite clay, the only active development of which
9718-513: The lightest hydrocarbon oils and is one of only three metals that can float on water, the other two being sodium and potassium . Lithium's coefficient of thermal expansion is twice that of aluminium and almost four times that of iron . Lithium is superconductive below 400 μK at standard pressure and at higher temperatures (more than 9 K) at very high pressures (>20 GPa). At temperatures below 70 K, lithium, like sodium, undergoes diffusionless phase change transformations . At 4.2 K it has
9831-541: The lithium atom verges on instability, since the two stable lithium isotopes found in nature have among the lowest binding energies per nucleon of all stable nuclides . Because of its relative nuclear instability, lithium is less common in the solar system than 25 of the first 32 chemical elements even though its nuclei are very light: it is an exception to the trend that heavier nuclei are less common. For related reasons, lithium has important uses in nuclear physics . The transmutation of lithium atoms to helium in 1932
9944-516: The mid 20th century, lithium's mood stabilizing applicability for mania and depression took off in Europe and the United States. The production and use of lithium underwent several drastic changes in history. The first major application of lithium was in high-temperature lithium greases for aircraft engines and similar applications in World War II and shortly after. This use was supported by
10057-426: The middle of the 1990s. After the end of the nuclear arms race , the demand for lithium decreased and the sale of department of energy stockpiles on the open market further reduced prices. In the mid-1990s, several companies started to isolate lithium from brine which proved to be a less expensive option than underground or open-pit mining. Most of the mines closed or shifted their focus to other materials because only
10170-431: The most stable being Li with a half-life of 838 ms and Li with a half-life of 178 ms. All of the remaining radioactive isotopes have half-lives that are shorter than 8.6 ms. The shortest-lived isotope of lithium is Li, which decays through proton emission and has a half-life of 7.6 × 10 s. The Li isotope is one of only five stable nuclides to have both an odd number of protons and an odd number of neutrons,
10283-508: The older dialects, although the Doric dialect has survived in the Tsakonian language , which is spoken in the region of modern Sparta. Doric has also passed down its aorist terminations into most verbs of Demotic Greek . By about the 6th century AD, the Koine had slowly metamorphosed into Medieval Greek . Phrygian is an extinct Indo-European language of West and Central Anatolia , which
10396-416: The ore from zoned pegmatites could be mined for a competitive price. For example, the US mines near Kings Mountain , North Carolina, closed before the beginning of the 21st century. The development of lithium-ion batteries increased the demand for lithium and became the dominant use in 2007. With the surge of lithium demand in batteries in the 2000s, new companies have expanded brine isolation efforts to meet
10509-636: The other four stable odd-odd nuclides being hydrogen-2 , boron-10 , nitrogen-14 , and tantalum-180m . Li is one of the primordial elements (or, more properly, primordial nuclides ) produced in Big Bang nucleosynthesis . A small amount of both Li and Li are produced in stars during stellar nucleosynthesis , but it is further " burned " as fast as produced. Li can also be generated in carbon stars . Additional small amounts of both Li and Li may be generated from solar wind, cosmic rays hitting heavier atoms, and from early solar system Be radioactive decay. Lithium isotopes fractionate substantially during
10622-487: The perfect stem eilēpha (not * lelēpha ) because it was originally slambanō , with perfect seslēpha , becoming eilēpha through compensatory lengthening. Reduplication is also visible in the present tense stems of certain verbs. These stems add a syllable consisting of the root's initial consonant followed by i . A nasal stop appears after the reduplication in some verbs. The earliest extant examples of ancient Greek writing ( c. 1450 BC ) are in
10735-506: The pharmaceutical industry. For laboratory organic synthesis, many organolithium reagents are commercially available in solution form. These reagents are highly reactive, and are sometimes pyrophoric . Like its inorganic compounds, almost all organic compounds of lithium formally follow the duet rule (e.g., BuLi , MeLi ). However, it is important to note that in the absence of coordinating solvents or ligands, organolithium compounds form dimeric, tetrameric, and hexameric clusters (e.g., BuLi
10848-498: The presence of a new element while analyzing petalite ore. This element formed compounds similar to those of sodium and potassium , though its carbonate and hydroxide were less soluble in water and less alkaline . Berzelius gave the alkaline material the name " lithion / lithina ", from the Greek word λιθoς (transliterated as lithos , meaning "stone"), to reflect its discovery in a solid mineral, as opposed to potassium, which had been discovered in plant ashes, and sodium, which
10961-416: The pressure always increases the density of a material. Increasing the temperature generally decreases the density, but there are notable exceptions to this generalization. For example, the density of water increases between its melting point at 0 °C and 4 °C; similar behavior is observed in silicon at low temperatures. The effect of pressure and temperature on the densities of liquids and solids
11074-474: The production of tritium by itself, as well as a form of solid fusion fuel used inside hydrogen bombs in the form of lithium deuteride . The US became the prime producer of lithium between the late 1950s and the mid-1980s. At the end, the stockpile of lithium was roughly 42,000 tonnes of lithium hydroxide. The stockpiled lithium was depleted in lithium-6 by 75%, which was enough to affect the measured atomic weight of lithium in many standardized chemicals, and even
11187-472: The rising demand. It has been argued that lithium will be one of the main objects of geopolitical competition in a world running on renewable energy and dependent on batteries, but this perspective has also been criticised for underestimating the power of economic incentives for expanded production. Lithium reacts with water easily, but with noticeably less vigor than other alkali metals. The reaction forms hydrogen gas and lithium hydroxide . When placed over
11300-402: The same thing as the material volumetric mass density. To determine the material volumetric mass density, one must first discount the volume of the void fraction. Sometimes this can be determined by geometrical reasoning. For the close-packing of equal spheres the non-void fraction can be at most about 74%. It can also be determined empirically. Some bulk materials, however, such as sand, have
11413-465: The stories they tell about the lake in Palestine it would further bear out what I say. For they say if you bind a man or beast and throw him into it he floats and does not sink beneath the surface. In a well-known but probably apocryphal tale, Archimedes was given the task of determining whether King Hiero 's goldsmith was embezzling gold during the manufacture of a golden wreath dedicated to
11526-426: The substance floats in water. The density of a material varies with temperature and pressure. This variation is typically small for solids and liquids but much greater for gases. Increasing the pressure on an object decreases the volume of the object and thus increases its density. Increasing the temperature of a substance (with a few exceptions) decreases its density by increasing its volume. In most materials, heating
11639-517: The syllabic script Linear B . Beginning in the 8th century BC, however, the Greek alphabet became standard, albeit with some variation among dialects. Early texts are written in boustrophedon style, but left-to-right became standard during the classic period. Modern editions of ancient Greek texts are usually written with accents and breathing marks , interword spacing , modern punctuation , and sometimes mixed case , but these were all introduced later. The beginning of Homer 's Iliad exemplifies
11752-488: The three elements synthesized in the Big Bang. Though the amount of lithium generated in Big Bang nucleosynthesis is dependent upon the number of photons per baryon , for accepted values the lithium abundance can be calculated, and there is a " cosmological lithium discrepancy " in the universe: older stars seem to have less lithium than they should, and some younger stars have much more. The lack of lithium in older stars
11865-467: The time of the Dorian invasions —and that their first appearances as precise alphabetic writing began in the 8th century BC. The invasion would not be "Dorian" unless the invaders had some cultural relationship to the historical Dorians . The invasion is known to have displaced population to the later Attic-Ionic regions, who regarded themselves as descendants of the population displaced by or contending with
11978-506: The value in (kg/m ). Liquid water has a density of about 1 kg/dm , making any of these SI units numerically convenient to use as most solids and liquids have densities between 0.1 and 20 kg/dm . In US customary units density can be stated in: Imperial units differing from the above (as the Imperial gallon and bushel differ from the US units) in practice are rarely used, though found in older documents. The Imperial gallon
12091-480: Was Aeolic. For example, fragments of the works of the poet Sappho from the island of Lesbos are in Aeolian. Most of the dialect sub-groups listed above had further subdivisions, generally equivalent to a city-state and its surrounding territory, or to an island. Doric notably had several intermediate divisions as well, into Island Doric (including Cretan Doric ), Southern Peloponnesus Doric (including Laconian ,
12204-452: Was a pluricentric language , divided into many dialects. The main dialect groups are Attic and Ionic , Aeolic , Arcadocypriot , and Doric , many of them with several subdivisions. Some dialects are found in standardized literary forms in literature , while others are attested only in inscriptions. There are also several historical forms. Homeric Greek is a literary form of Archaic Greek (derived primarily from Ionic and Aeolic) used in
12317-443: Was based on the concept that an Imperial fluid ounce of water would have a mass of one Avoirdupois ounce, and indeed 1 g/cm ≈ 1.00224129 ounces per Imperial fluid ounce = 10.0224129 pounds per Imperial gallon. The density of precious metals could conceivably be based on Troy ounces and pounds, a possible cause of confusion. Knowing the volume of the unit cell of a crystalline material and its formula weight (in daltons ),
12430-662: Was gathered mainly by the Soviets during their occupation of Afghanistan from 1979–1989". The Department of Defense estimated the lithium reserves in Afghanistan to amount to the ones in Bolivia and dubbed it as a potential "Saudi-Arabia of lithium". In Cornwall , England, the presence of brine rich in lithium was well known due to the region's historic mining industry , and private investors have conducted tests to investigate potential lithium extraction in this area. Lithium
12543-403: Was known partly for its high abundance in animal blood. He named the new element "lithium". Arfwedson later showed that this same element was present in the minerals spodumene and lepidolite . In 1818, Christian Gmelin was the first to observe that lithium salts give a bright red color to flame. However, both Arfwedson and Gmelin tried and failed to isolate the pure element from its salts. It
12656-536: Was not isolated until 1821, when William Thomas Brande obtained it by electrolysis of lithium oxide , a process that had previously been employed by the chemist Sir Humphry Davy to isolate the alkali metals potassium and sodium. Brande also described some pure salts of lithium, such as the chloride, and, estimating that lithia ( lithium oxide ) contained about 55% metal, estimated the atomic weight of lithium to be around 9.8 g/mol (modern value ~6.94 g/mol). In 1855, larger quantities of lithium were produced through
12769-467: Was the first fully human-made nuclear reaction , and lithium deuteride serves as a fusion fuel in staged thermonuclear weapons . Lithium and its compounds have several industrial applications, including heat-resistant glass and ceramics , lithium grease lubricants, flux additives for iron, steel and aluminium production, lithium metal batteries , and lithium-ion batteries . These uses consume more than three-quarters of lithium production. Lithium
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