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104-701: The 20% tax rate on war booty stems from the practice of khums ( Arabic : خُمْس , lit.   'fifth') in Islamic states. It was institutionalized from the start of the Islamic conquest , with the rate set down in Qur'an 8:41: Know that whatever spoils you take, one-fifth is for Allah and the Messenger, his close relatives, orphans, the poor, and ˹needy˺ travellers, if you ˹truly˺ believe in Allah and what We revealed to Our servant on that decisive day when

208-486: A bullet cast from silver is often supposed in such folklore the only weapon that is effective against a werewolf , witch , or other monsters . From this the idiom of a silver bullet developed into figuratively referring to any simple solution with very high effectiveness or almost miraculous results, as in the widely discussed software engineering paper " No Silver Bullet ." Other powers attributed to silver include detection of poison and facilitation of passage into

312-496: A covalent character and are relatively weak. This observation explains the low hardness and high ductility of single crystals of silver. Silver has a brilliant, white, metallic luster that can take a high polish , and which is so characteristic that the name of the metal itself has become a color name . Protected silver has greater optical reflectivity than aluminium at all wavelengths longer than ~450 nm. At wavelengths shorter than 450 nm, silver's reflectivity

416-590: A monopoly of mercury production, through its mines at Almadén in Spain and at Huancavelica in Peru . In 1648 the Viceroy of Peru declared that Potosí and Huancavelica were "the two pillars that support this kingdom and that of Spain." Moreover, the viceroy thought that Spain could, if necessary, dispense with the silver from Potosí, but it could not dispense with the mercury from Huancavelica. Tax rate In

520-503: A tax system, the tax rate is the ratio (usually expressed as a percentage ) at which a business or person is taxed. The tax rate that is applied to an individual's or corporation's income is determined by tax laws of the country and can be influenced by many factors such as income level, type of income, and so on. There are several methods used to present a tax rate: statutory, average, marginal, flat, and effective. These rates can also be presented using different definitions applied to

624-409: A 25% exclusive sales tax rate yields $ 20 in taxes owed. Since the sales tax is added "on the top", the individual pays $ 20 of tax on $ 80 of pre-tax goods for a total cost of $ 100. In either case, the tax base of $ 100 can be treated as two parts—$ 80 of after-tax spending money and $ 20 of taxes owed. A 25% exclusive tax rate approximates a 20% inclusive tax rate after adjustment. By including taxes owed in

728-448: A certain percentage of U.S. tax that would apply on such income if U.S. tax had been applicable to the income. An interesting phenomenon connected with effective tax rate is its negativity called negative effective tax rate, which occurs when the tax benefits received by an individual or corporation exceed the taxable income . A negative tax rate can happen because of factors such as tax credits, deductions, or incentives, for example, if

832-450: A colorant in stained glass , and in specialized confectionery. Its compounds are used in photographic and X-ray film. Dilute solutions of silver nitrate and other silver compounds are used as disinfectants and microbiocides ( oligodynamic effect ), added to bandages , wound-dressings, catheters , and other medical instruments . Silver is similar in its physical and chemical properties to its two vertical neighbours in group 11 of

936-496: A corporation has a pre-tax income of $ 100k and tax benefits of $ 110k, then the corporation has a negative effective tax rate. It also works with individuals and in this system government pays individuals. Tax rates can be presented differently due to differing definitions of tax base, which can make comparisons between tax systems confusing. Some tax systems include the taxes owed in the tax base (tax-inclusive, Before Tax), while other tax systems do not include taxes owed as part of

1040-491: A designated higher bracket, which in 2016 in the United States was $ 415,050. For annual income that was above the cut-off point in that higher bracket, the marginal tax rate in 2016 was 39.6%. For income below the $ 415,050 cut off, the lower tax rate was 35% or less. The marginal tax rate on income can be expressed mathematically as follows: where t is the total tax liability and i is total income, and ∆ refers to

1144-592: A non-Indo-European Wanderwort . Some scholars have thus proposed a Paleo-Hispanic origin, pointing to the Basque form zilharr as an evidence. The chemical symbol Ag is from the Latin word for silver , argentum (compare Ancient Greek ἄργυρος , árgyros ), from the Proto-Indo-European root * h₂erǵ- (formerly reconstructed as *arǵ- ), meaning ' white ' or ' shining ' . This

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1248-438: A numerical change. In accounting practice, the tax numerator in the above equation usually includes taxes at federal, state, provincial, and municipal levels. Marginal tax rates are applied to income in countries with progressive taxation schemes, with incremental increases in income taxed in progressively higher tax brackets , resulting in the tax burden being distributed amongst those who can most easily afford it. An example of

1352-492: A pack of cigarettes containing 20 cigarettes but in the United Kingdom. In the United Kingdom, the flat tax rate is at 16.5 % of the retail price and also £ 6.33 per pack of 20. Let’s say that the price of the pack of cigarettes before tax is £10.00. Then specific tax is £ 6.33 and flat tax rate is £10.00 * 16.5% = £1.65. Then a pack of 20 cigarettes costs £17.98 and the tax expense is £7.98. The effective tax rate

1456-531: A pack of cigarettes containing 20 cigarettes in California. The California tax rate is $ 0.1435 per cigarette stick and $ 2.87 per pack of 20 cigarettes. So if a pack costs $ 10 or $ 12, the tax rate for both is $ 2.87. For some goods exists a combination of two tax rates. The commonly known mixed tax rate is specific and flat at once. Usually, it is used for excise taxation or sin taxation used on tobacco, alcohol, or fuel. For example, we can again have

1560-614: A reward for betrayal, references the bribe Judas Iscariot is said in the New Testament to have taken from Jewish leaders in Jerusalem to turn Jesus of Nazareth over to soldiers of the high priest Caiaphas. Ethically, silver also symbolizes greed and degradation of consciousness; this is the negative aspect, the perverting of its value. The abundance of silver in the Earth's crust is 0.08  parts per million , almost exactly

1664-629: A scale unparalleled before the discovery of the New World . Reaching a peak production of 200 tonnes per year, an estimated silver stock of 10,000 tonnes circulated in the Roman economy in the middle of the second century AD, five to ten times larger than the combined amount of silver available to medieval Europe and the Abbasid Caliphate around AD 800. The Romans also recorded the extraction of silver in central and northern Europe in

1768-409: A tax base: inclusive and exclusive. A statutory tax rate is the legally imposed rate. An income tax could have multiple statutory rates for different income levels, where a sales tax may have a flat statutory rate. The statutory tax rate is expressed as a percentage and will always be higher than the effective tax rate. An average tax rate is the ratio of the total amount of taxes paid to

1872-400: A tax exclusive basis. For direct rate comparisons between exclusive and inclusive taxes, one rate must be manipulated to look like the other. When a tax system imposes taxes primarily on income , the tax base is a household's pre-tax income. The appropriate income tax rate is applied to the tax base to calculate taxes owed. Under this formula, taxes to be paid are included in the base on which

1976-567: Is cognate with Old High German silabar ; Gothic silubr ; or Old Norse silfr , all ultimately deriving from Proto-Germanic *silubra . The Balto-Slavic words for silver are rather similar to the Germanic ones (e.g. Russian серебро [ serebró ], Polish srebro , Lithuanian sidãbras ), as is the Celtiberian form silabur . They may have a common Indo-European origin, although their morphology rather suggest

2080-465: Is the difluoride , AgF 2 , which can be obtained from the elements under heat. A strong yet thermally stable and therefore safe fluorinating agent, silver(II) fluoride is often used to synthesize hydrofluorocarbons . In stark contrast to this, all four silver(I) halides are known. The fluoride , chloride , and bromide have the sodium chloride structure, but the iodide has three known stable forms at different temperatures; that at room temperature

2184-470: Is Ag 3 O which behaves as a metallic conductor. Silver(I) sulfide , Ag 2 S, is very readily formed from its constituent elements and is the cause of the black tarnish on some old silver objects. It may also be formed from the reaction of hydrogen sulfide with silver metal or aqueous Ag ions. Many non-stoichiometric selenides and tellurides are known; in particular, AgTe ~3 is a low-temperature superconductor . The only known dihalide of silver

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2288-551: Is a chemical element ; it has symbol Ag (from Latin argentum  'silver', derived from Proto-Indo-European *h₂erǵ ' shiny, white ' ) and atomic number 47. A soft, white, lustrous transition metal , it exhibits the highest electrical conductivity , thermal conductivity , and reflectivity of any metal . Silver is found in the Earth's crust in the pure, free elemental form (" native silver"), as an alloy with gold and other metals, and in minerals such as argentite and chlorargyrite . Most silver

2392-467: Is a fixed amount of tax on a specific good or service. It means that the tax rate is not in the form of percentages but in the form of single units which does not depend on the price of goods but on the amount of units. Specific tax is used in tobacco taxation because it has been proved that a high specific tax significantly enlarges the price of cigarettes and it is an effective way to reduce the consumption of goods like cigarettes. For example, we can have

2496-661: Is a flat tax rate in Colorado. There is a flat tax rate determined at 4.4%. Assuming that an annual taxable income is $ 100,000, then the income tax is equal to $ 4,400. In practice, a flat tax rate on income is used in many states of the USA , like Colorado, Illinois, Indiana, Kentucky, Massachusetts, Michigan, North Carolina, Pennsylvania, and Utah, or internationally, for example in many post-Soviet countries like Hungary, Serbia, Estonia or Ukraine, and also in Iceland or Bolivia. On

2600-525: Is also lowered, and the average tax rate decreases too. Their value depends highly on the top marginal tax bracket. For example, if we have an individual whose top marginal tax bracket is 10% then the maximum deductions from $ 2000 is $ 200. On the other hand, if we have an individual whose top marginal tax rate is 37% then the maximum deduction from $ 2000 is $ 740. A tax credit is an amount that can be subtracted directly from an individual tax bill, which means that credits increase an individual's refund or reduce

2704-438: Is because its filled 4d shell is not very effective in shielding the electrostatic forces of attraction from the nucleus to the outermost 5s electron, and hence silver is near the bottom of the electrochemical series ( E (Ag /Ag) = +0.799 V). In group 11, silver has the lowest first ionization energy (showing the instability of the 5s orbital), but has higher second and third ionization energies than copper and gold (showing

2808-453: Is called the Laffer curve (named after economist Arthur Laffer ). Laffer curve is a hump-shaped curve, that compares the relationship between tax rate and tax revenue. The Laffer curve tells us that raising tax rates beyond some level may reduce incentives enough to reduce output and tax revenues. There is, then, a tax rate at which tax revenues are maximized. Silver Silver

2912-549: Is higher than that of lead (1.87), and its electron affinity of 125.6 kJ/mol is much higher than that of hydrogen (72.8 kJ/mol) and not much less than that of oxygen (141.0 kJ/mol). Due to its full d-subshell, silver in its main +1 oxidation state exhibits relatively few properties of the transition metals proper from groups 4 to 10, forming rather unstable organometallic compounds , forming linear complexes showing very low coordination numbers like 2, and forming an amphoteric oxide as well as Zintl phases like

3016-428: Is inferior to that of aluminium and drops to zero near 310 nm. Very high electrical and thermal conductivity are common to the elements in group 11, because their single s electron is free and does not interact with the filled d subshell, as such interactions (which occur in the preceding transition metals) lower electron mobility. The thermal conductivity of silver is among the highest of all materials, although

3120-413: Is much less stable, fuming in moist air and reacting with glass. Silver(II) complexes are more common. Like the valence isoelectronic copper(II) complexes, they are usually square planar and paramagnetic, which is increased by the greater field splitting for 4d electrons than for 3d electrons. Aqueous Ag , produced by oxidation of Ag by ozone, is a very strong oxidising agent, even in acidic solutions: it

3224-410: Is not reversible because the silver atom liberated is typically found at a crystal defect or an impurity site, so that the electron's energy is lowered enough that it is "trapped". White silver nitrate , AgNO 3 , is a versatile precursor to many other silver compounds, especially the halides, and is much less sensitive to light. It was once called lunar caustic because silver was called luna by

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3328-424: Is pale yellow, becoming purplish on exposure to light; it projects slightly from the surface of the artifact or coin. The precipitation of copper in ancient silver can be used to date artifacts, as copper is nearly always a constituent of silver alloys. Silver metal is attacked by strong oxidizers such as potassium permanganate ( KMnO 4 ) and potassium dichromate ( K 2 Cr 2 O 7 ), and in

3432-402: Is produced as a byproduct of copper , gold, lead , and zinc refining . Silver has long been valued as a precious metal . Silver metal is used in many bullion coins , sometimes alongside gold : while it is more abundant than gold, it is much less abundant as a native metal . Its purity is typically measured on a per-mille basis; a 94%-pure alloy is described as "0.940 fine". As one of

3536-415: Is rare in the periodic table. The atomic weight is 107.8682(2) u ; this value is very important because of the importance of silver compounds, particularly halides, in gravimetric analysis . Both isotopes of silver are produced in stars via the s-process (slow neutron capture), as well as in supernovas via the r-process (rapid neutron capture). Twenty-eight radioisotopes have been characterized,

3640-536: Is reflected in the relative decomposition temperatures of AgMe (−50 °C) and CuMe (−15 °C) as well as those of PhAg (74 °C) and PhCu (100 °C). The C–Ag bond is stabilized by perfluoroalkyl ligands, for example in AgCF(CF 3 ) 2 . Alkenylsilver compounds are also more stable than their alkylsilver counterparts. Silver- NHC complexes are easily prepared, and are commonly used to prepare other NHC complexes by displacing labile ligands. For example,

3744-472: Is stabilized in phosphoric acid due to complex formation. Peroxodisulfate oxidation is generally necessary to give the more stable complexes with heterocyclic amines , such as [Ag(py) 4 ] and [Ag(bipy) 2 ] : these are stable provided the counterion cannot reduce the silver back to the +1 oxidation state. [AgF 4 ] is also known in its violet barium salt, as are some silver(II) complexes with N - or O -donor ligands such as pyridine carboxylates. By far

3848-459: Is the percent of their income that an individual or a corporation pays in taxes. The term is used in financial reporting to measure the total tax paid as a percentage of the company's accounting income, instead of as a percentage of the taxable income. International Accounting Standard 12, define it as income tax expense or benefit for accounting purposes divided by accounting profit. In Generally Accepted Accounting Principles (United States) ,

3952-413: Is the cubic zinc blende structure. They can all be obtained by the direct reaction of their respective elements. As the halogen group is descended, the silver halide gains more and more covalent character, solubility decreases, and the colour changes from the white chloride to the yellow iodide as the energy required for ligand-metal charge transfer (X Ag → XAg) decreases. The fluoride is anomalous, as

4056-726: Is used in vacuum brazing . The two metals are completely miscible as liquids but not as solids; their importance in industry comes from the fact that their properties tend to be suitable over a wide range of variation in silver and copper concentration, although most useful alloys tend to be richer in silver than the eutectic mixture (71.9% silver and 28.1% copper by weight, and 60.1% silver and 28.1% copper by atom). Most other binary alloys are of little use: for example, silver–gold alloys are too soft and silver– cadmium alloys too toxic. Ternary alloys have much greater importance: dental amalgams are usually silver–tin–mercury alloys, silver–copper–gold alloys are very important in jewellery (usually on

4160-482: Is usually obtained by reacting silver or silver monofluoride with the strongest known oxidizing agent, krypton difluoride . Silver and gold have rather low chemical affinities for oxygen, lower than copper, and it is therefore expected that silver oxides are thermally quite unstable. Soluble silver(I) salts precipitate dark-brown silver(I) oxide , Ag 2 O, upon the addition of alkali. (The hydroxide AgOH exists only in solution; otherwise it spontaneously decomposes to

4264-848: The Koenigs–Knorr reaction . In the Fétizon oxidation , silver carbonate on celite acts as an oxidising agent to form lactones from diols . It is also employed to convert alkyl bromides into alcohols . Silver fulminate , AgCNO, a powerful, touch-sensitive explosive used in percussion caps , is made by reaction of silver metal with nitric acid in the presence of ethanol . Other dangerously explosive silver compounds are silver azide , AgN 3 , formed by reaction of silver nitrate with sodium azide , and silver acetylide , Ag 2 C 2 , formed when silver reacts with acetylene gas in ammonia solution. In its most characteristic reaction, silver azide decomposes explosively, releasing nitrogen gas: given

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4368-545: The Lahn region, Siegerland , Silesia , Hungary , Norway , Steiermark , Schwaz , and the southern Black Forest . Most of these ores were quite rich in silver and could simply be separated by hand from the remaining rock and then smelted; some deposits of native silver were also encountered. Many of these mines were soon exhausted, but a few of them remained active until the Industrial Revolution , before which

4472-666: The mythical realm of fairies . Silver production has also inspired figurative language. Clear references to cupellation occur throughout the Old Testament of the Bible , such as in Jeremiah 's rebuke to Judah: "The bellows are burned, the lead is consumed of the fire; the founder melteth in vain: for the wicked are not plucked away. Reprobate silver shall men call them, because the Lord hath rejected them." (Jeremiah 6:19–20) Jeremiah

4576-433: The periodic table : copper , and gold . Its 47 electrons are arranged in the configuration [Kr]4d 5s , similarly to copper ([Ar]3d 4s ) and gold ([Xe]4f 5d 6s ); group 11 is one of the few groups in the d-block which has a completely consistent set of electron configurations. This distinctive electron configuration, with a single electron in the highest occupied s subshell over a filled d subshell, accounts for many of

4680-435: The platinum complexes (though they are formed more readily than those of the analogous gold complexes): they are also quite unsymmetrical, showing the weak π bonding in group 11. Ag–C σ bonds may also be formed by silver(I), like copper(I) and gold(I), but the simple alkyls and aryls of silver(I) are even less stable than those of copper(I) (which tend to explode under ambient conditions). For example, poor thermal stability

4784-526: The post-transition metals . Unlike the preceding transition metals, the +1 oxidation state of silver is stable even in the absence of π-acceptor ligands . Silver does not react with air, even at red heat, and thus was considered by alchemists as a noble metal , along with gold. Its reactivity is intermediate between that of copper (which forms copper(I) oxide when heated in air to red heat) and gold. Like copper, silver reacts with sulfur and its compounds; in their presence, silver tarnishes in air to form

4888-731: The 19th century, primary production of silver moved to North America, particularly Canada , Mexico , and Nevada in the United States : some secondary production from lead and zinc ores also took place in Europe, and deposits in Siberia and the Russian Far East as well as in Australia were mined. Poland emerged as an important producer during the 1970s after the discovery of copper deposits that were rich in silver, before

4992-594: The Caliphal administration and army. Schools of Islamic law were divided on whether the fifth extended to treasure troves and mining. Some schools (notably, the Hanafite ), regarded treasure and mines as 'spoils' and thus subject to the fifth, while others (notably the Shafi'ite and Hanbalite ) regarded them as subject only to the conventional rates, e.g. zakat . The medieval Taifa kingdoms of al-Andalus embraced

5096-576: The Greek and Roman civilizations, silver coins were a staple of the economy: the Greeks were already extracting silver from galena by the 7th century BC, and the rise of Athens was partly made possible by the nearby silver mines at Laurium , from which they extracted about 30 tonnes a year from 600 to 300 BC. The stability of the Roman currency relied to a high degree on the supply of silver bullion, mostly from Spain, which Roman miners produced on

5200-475: The Hanafi argument and institutionalized the fifth on war spoils, treasure troves and mining. In Christian kingdoms, the royal fifth partly comes from the medieval legal conception of seigneural or regalian rights over the natural patrimony , which assigned to the monarch or feudal overlord original property rights over all unclaimed, undiscovered and undeveloped natural resources (e.g. precious metals in

5304-520: The Spanish empire until the 18th century. In 1723, it was reduced to a diezmo (10%) and in 1777 it was reduced further to 3%, with an additional duty of 2% if shipped to Spain. Rather than levy the tax on the basis of the amount of silver or gold produced, the Spanish government tracked the amount of mercury used. Mercury was essential for the refinement of silver and gold in the patio process (see also amalgamation ). The Spanish government had

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5408-436: The age of exploration, Spanish and Portuguese captains and conquistadores were careful to always set aside the royal fifth from any spoils they captured, and accusations of embezzling the 'royal fifth' ended the careers of a few of them (e.g. Alonso de Ojeda , Pedro Alonso Niño ). Nonetheless, to encourage exploration and colonization, Iberian monarchs often allowed explorers and colonial developers to retain part or all of

5512-435: The amount of taxes that an individual owes. Tax credits again lower the average tax rate but tax credits are not influenced by the marginal tax rate. If an individual has $ 2000 of tax credits then his taxes are directly smaller by $ 2000. The standard theory of optimal tax rate aims to design the tax to maximize social welfare while collecting a certain level of revenue. One of the theories on how to find optimal tax rates

5616-557: The ancient alchemists, who believed that silver was associated with the Moon. It is often used for gravimetric analysis, exploiting the insolubility of the heavier silver halides which it is a common precursor to. Silver nitrate is used in many ways in organic synthesis , e.g. for deprotection and oxidations. Ag binds alkenes reversibly, and silver nitrate has been used to separate mixtures of alkenes by selective absorption. The resulting adduct can be decomposed with ammonia to release

5720-410: The base (tax-exclusive, After Tax). In the United States , sales taxes are usually quoted exclusively and income taxes are quoted inclusively. The majority of Europe, value added tax (VAT) countries, include the tax amount when quoting merchandise prices, including Goods and Services Tax (GST) countries, such as Australia and New Zealand . However, those countries still define their tax rates on

5824-637: The black silver sulfide (copper forms the green sulfate instead, while gold does not react). While silver is not attacked by non-oxidizing acids, the metal dissolves readily in hot concentrated sulfuric acid , as well as dilute or concentrated nitric acid . In the presence of air, and especially in the presence of hydrogen peroxide , silver dissolves readily in aqueous solutions of cyanide . The three main forms of deterioration in historical silver artifacts are tarnishing, formation of silver chloride due to long-term immersion in salt water, as well as reaction with nitrate ions or oxygen. Fresh silver chloride

5928-712: The centre of production returned to the Americas the following decade. Today, Peru and Mexico are still among the primary silver producers, but the distribution of silver production around the world is quite balanced and about one-fifth of the silver supply comes from recycling instead of new production. Silver plays a certain role in mythology and has found various usage as a metaphor and in folklore. The Greek poet Hesiod 's Works and Days (lines 109–201) lists different ages of man named after metals like gold, silver, bronze and iron to account for successive ages of humanity. Ovid 's Metamorphoses contains another retelling of

6032-434: The dominant producers of silver until around the beginning of the 18th century, particularly Peru , Bolivia , Chile , and Argentina : the last of these countries later took its name from that of the metal that composed so much of its mineral wealth. The silver trade gave way to a global network of exchange . As one historian put it, silver "went round the world and made the world go round." Much of this silver ended up in

6136-411: The elements in groups 10–14 (except boron and carbon ) have very complex Ag–M phase diagrams and form the most commercially important alloys; and the remaining elements on the periodic table have no consistency in their Ag–M phase diagrams. By far the most important such alloys are those with copper: most silver used for coinage and jewellery is in reality a silver–copper alloy, and the eutectic mixture

6240-529: The exceptions are the nitrate, perchlorate, and fluoride. The tetracoordinate tetrahedral aqueous ion [Ag(H 2 O) 4 ] is known, but the characteristic geometry for the Ag cation is 2-coordinate linear. For example, silver chloride dissolves readily in excess aqueous ammonia to form [Ag(NH 3 ) 2 ] ; silver salts are dissolved in photography due to the formation of the thiosulfate complex [Ag(S 2 O 3 ) 2 ] ; and cyanide extraction for silver (and gold) works by

6344-534: The fluoride ion is so small that it has a considerable solvation energy and hence is highly water-soluble and forms di- and tetrahydrates. The other three silver halides are highly insoluble in aqueous solutions and are very commonly used in gravimetric analytical methods. All four are photosensitive (though the monofluoride is so only to ultraviolet light), especially the bromide and iodide which photodecompose to silver metal, and thus were used in traditional photography . The reaction involved is: The process

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6448-523: The formation of the complex [Ag(CN) 2 ] . Silver cyanide forms the linear polymer {Ag–C≡N→Ag–C≡N→}; silver thiocyanate has a similar structure, but forms a zigzag instead because of the sp - hybridized sulfur atom. Chelating ligands are unable to form linear complexes and thus silver(I) complexes with them tend to form polymers; a few exceptions exist, such as the near-tetrahedral diphosphine and diarsine complexes [Ag(L–L) 2 ] . Under standard conditions, silver does not form simple carbonyls, due to

6552-412: The free alkene. Yellow silver carbonate , Ag 2 CO 3 can be easily prepared by reacting aqueous solutions of sodium carbonate with a deficiency of silver nitrate. Its principal use is for the production of silver powder for use in microelectronics. It is reduced with formaldehyde , producing silver free of alkali metals: Silver carbonate is also used as a reagent in organic synthesis such as

6656-573: The gold-rich side) and have a vast range of hardnesses and colours, silver–copper–zinc alloys are useful as low-melting brazing alloys, and silver–cadmium– indium (involving three adjacent elements on the periodic table) is useful in nuclear reactors because of its high thermal neutron capture cross-section , good conduction of heat, mechanical stability, and resistance to corrosion in hot water. The word silver appears in Old English in various spellings, such as seolfor and siolfor . It

6760-459: The hands of the Chinese. A Portuguese merchant in 1621 noted that silver "wanders throughout all the world... before flocking to China, where it remains as if at its natural center." Still, much of it went to Spain, allowing Spanish rulers to pursue military and political ambitions in both Europe and the Americas. "New World mines", concluded several historians, "supported the Spanish empire." In

6864-547: The last $ 5,000 of income (30%). In total, they would pay $ 4,500, or an 18% average tax rate. Flat tax rate also known as single-rate is one of the simplest taxations. For flat is a single tax rate (same percentage) on the whole taxable amount. A flat tax rate is used because of its simplicity, transparency, neutrality, and stability. Flat tax rates are quite transparent because it makes it easier for taxpayer to estimate their tax liability and for policymakers to estimate how changes would impact tax revenue. One simplified example

6968-618: The metal. The situation changed with the discovery of cupellation , a technique that allowed silver metal to be extracted from its ores. While slag heaps found in Asia Minor and on the islands of the Aegean Sea indicate that silver was being separated from lead as early as the 4th millennium BC , and one of the earliest silver extraction centres in Europe was Sardinia in the early Chalcolithic period , these techniques did not spread widely until later, when it spread throughout

7072-434: The most important oxidation state for silver in complexes is +1. The Ag cation is diamagnetic, like its homologues Cu and Au , as all three have closed-shell electron configurations with no unpaired electrons: its complexes are colourless provided the ligands are not too easily polarized such as I . Ag forms salts with most anions, but it is reluctant to coordinate to oxygen and thus most of these salts are insoluble in water:

7176-546: The most stable being Ag with a half-life of 41.29 days, Ag with a half-life of 7.45 days, and Ag with a half-life of 3.13 hours. Silver has numerous nuclear isomers , the most stable being Ag ( t 1/2 = 418 years), Ag ( t 1/2 = 249.79 days) and Ag ( t 1/2 = 8.28 days). All of the remaining radioactive isotopes have half-lives of less than an hour, and the majority of these have half-lives of less than three minutes. Isotopes of silver range in relative atomic mass from 92.950 u ( Ag) to 129.950 u ( Ag);

7280-588: The only objects with a high-enough palladium-to-silver ratio to yield measurable variations in Ag abundance. Radiogenic Ag was first discovered in the Santa Clara meteorite in 1978. Pd– Ag correlations observed in bodies that have clearly been melted since the accretion of the Solar System must reflect the presence of unstable nuclides in the early Solar System. Silver is a rather unreactive metal. This

7384-625: The ores of copper, copper-nickel, lead, and lead-zinc obtained from Peru , Bolivia , Mexico , China , Australia , Chile , Poland and Serbia . Peru, Bolivia and Mexico have been mining silver since 1546, and are still major world producers. Top silver-producing mines are Cannington (Australia), Fresnillo (Mexico), San Cristóbal (Bolivia), Antamina (Peru), Rudna (Poland), and Penasquito (Mexico). Top near-term mine development projects through 2015 are Pascua Lama (Chile), Navidad (Argentina), Jaunicipio (Mexico), Malku Khota (Bolivia), and Hackett River (Canada). In Central Asia , Tajikistan

7488-400: The other hand, it must be said that, in practice, no state has a perfectly flat income tax rate, and every state makes certain distinctions between types of income and has several discounts and reductions. A poll tax , also known as a head tax, is a flat tax of a set dollar amount per person. As an example, in the history of the USA, a poll tax was introduced in 1870, which was a fee paid for

7592-423: The oxide.) Silver(I) oxide is very easily reduced to metallic silver, and decomposes to silver and oxygen above 160 °C. This and other silver(I) compounds may be oxidized by the strong oxidizing agent peroxodisulfate to black AgO, a mixed silver(I,III) oxide of formula Ag Ag O 2 . Some other mixed oxides with silver in non-integral oxidation states, namely Ag 2 O 3 and Ag 3 O 4 , are also known, as

7696-577: The photosensitivity of silver salts, this behaviour may be induced by shining a light on its crystals. Silver complexes tend to be similar to those of its lighter homologue copper. Silver(III) complexes tend to be rare and very easily reduced to the more stable lower oxidation states, though they are slightly more stable than those of copper(III). For instance, the square planar periodate [Ag(IO 5 OH) 2 ] and tellurate [Ag{TeO 4 (OH) 2 } 2 ] complexes may be prepared by oxidising silver(I) with alkaline peroxodisulfate . The yellow diamagnetic [AgF 4 ]

7800-961: The presence of potassium bromide ( KBr ). These compounds are used in photography to bleach silver images, converting them to silver bromide that can either be fixed with thiosulfate or redeveloped to intensify the original image. Silver forms cyanide complexes ( silver cyanide ) that are soluble in water in the presence of an excess of cyanide ions. Silver cyanide solutions are used in electroplating of silver. The common oxidation states of silver are (in order of commonness): +1 (the most stable state; for example, silver nitrate , AgNO 3 ); +2 (highly oxidising; for example, silver(II) fluoride , AgF 2 ); and even very rarely +3 (extreme oxidising; for example, potassium tetrafluoroargentate(III), KAgF 4 ). The +3 state requires very strong oxidising agents to attain, such as fluorine or peroxodisulfate , and some silver(III) compounds react with atmospheric moisture and attack glass. Indeed, silver(III) fluoride

7904-406: The primary decay mode before the most abundant stable isotope, Ag, is electron capture and the primary mode after is beta decay . The primary decay products before Ag are palladium (element 46) isotopes, and the primary products after are cadmium (element 48) isotopes. The palladium isotope Pd decays by beta emission to Ag with a half-life of 6.5 million years. Iron meteorites are

8008-419: The reaction of the bis(NHC)silver(I) complex with bis(acetonitrile)palladium dichloride or chlorido(dimethyl sulfide)gold(I) : Silver forms alloys with most other elements on the periodic table. The elements from groups 1–3, except for hydrogen , lithium , and beryllium , are very miscible with silver in the condensed phase and form intermetallic compounds; those from groups 4–9 are only poorly miscible;

8112-512: The region and beyond. The origins of silver production in India , China , and Japan were almost certainly equally ancient, but are not well-documented due to their great age. When the Phoenicians first came to what is now Spain , they obtained so much silver that they could not fit it all on their ships, and as a result used silver to weight their anchors instead of lead. By the time of

8216-400: The right to vote. The marginal tax in these scenarios would be constant (in case of a poll tax—zero), however, these are both forms of regressive taxation and place a higher tax burden on those who are least able to cope with it, and often results in an underfunded government leading to increased deficits. A marginal tax rate is the tax rate on income set at a higher rate for incomes above

8320-701: The royal fifth, for at least some period of time. The conditions were usually spelled out in captaincy contracts or royal grants, e.g. in 1402, Jean de Béthencourt was allowed to keep the royal fifth as a condition for the conquest of the Canary Island for Castile; in 1443, the Portuguese Prince Henry the Navigator was granted the royal fifth on all enterprise in the Madeira islands and sub-saharan Africa; in 1492, Christopher Columbus

8424-701: The same as that of mercury . It mostly occurs in sulfide ores, especially acanthite and argentite , Ag 2 S. Argentite deposits sometimes also contain native silver when they occur in reducing environments, and when in contact with salt water they are converted to chlorargyrite (including horn silver ), AgCl, which is prevalent in Chile and New South Wales . Most other silver minerals are silver pnictides or chalcogenides ; they are generally lustrous semiconductors. Most true silver deposits, as opposed to argentiferous deposits of other metals, came from Tertiary period vulcanism. The principal sources of silver are

8528-693: The same time period. This production came to a nearly complete halt with the fall of the Roman Empire, not to resume until the time of Charlemagne : by then, tens of thousands of tonnes of silver had already been extracted. Central Europe became the centre of silver production during the Middle Ages , as the Mediterranean deposits exploited by the ancient civilisations had been exhausted. Silver mines were opened in Bohemia , Saxony , Alsace ,

8632-440: The seven metals of antiquity , silver has had an enduring role in most human cultures. Other than in currency and as an investment medium ( coins and bullion ), silver is used in solar panels , water filtration , jewellery , ornaments, high-value tableware and utensils (hence the term " silverware "), in electrical contacts and conductors , in specialized mirrors, window coatings, in catalysis of chemical reactions, as

8736-429: The singular properties of metallic silver. Silver is a relatively soft and extremely ductile and malleable transition metal , though it is slightly less malleable than gold. Silver crystallizes in a face-centered cubic lattice with bulk coordination number 12, where only the single 5s electron is delocalized, similarly to copper and gold. Unlike metals with incomplete d-shells, metallic bonds in silver are lacking

8840-422: The stability of the 4d orbitals), so that the chemistry of silver is predominantly that of the +1 oxidation state, reflecting the increasingly limited range of oxidation states along the transition series as the d-orbitals fill and stabilize. Unlike copper , for which the larger hydration energy of Cu as compared to Cu is the reason why the former is the more stable in aqueous solution and solids despite lacking

8944-445: The stable filled d-subshell of the latter, with silver this effect is swamped by its larger second ionisation energy. Hence, Ag is the stable species in aqueous solution and solids, with Ag being much less stable as it oxidizes water. Most silver compounds have significant covalent character due to the small size and high first ionization energy (730.8 kJ/mol) of silver. Furthermore, silver's Pauling electronegativity of 1.93

9048-411: The story, containing an illustration of silver's metaphorical use of signifying the second-best in a series, better than bronze but worse than gold: But when good Saturn , banish'd from above, Was driv'n to Hell, the world was under Jove . Succeeding times a silver age behold, Excelling brass, but more excell'd by gold. In folklore, silver was commonly thought to have mystic powers: for example,

9152-463: The structure of the silver is largely unchanged while the electron concentration rises as more zinc is added. Increasing the electron concentration further leads to body-centred cubic (electron concentration 1.5), complex cubic (1.615), and hexagonal close-packed phases (1.75). Naturally occurring silver is composed of two stable isotopes , Ag and Ag, with Ag being slightly more abundant (51.839% natural abundance ). This almost equal abundance

9256-604: The subsoil, salt in the rock, virgin forests, fish in the sea, etc.) within his jurisdiction. Consequently, private individuals who extracted these natural resources owed compensation to their original 'owner', the monarch. It was adopted by the Christian states of the Iberian Peninsula ( Castile , Portugal , etc.) during the reconquista and extended to their overseas colonies in the Americas, Africa and Asia. They became an important part of crown finance. During

9360-480: The surface of conductors rather than through the interior. During World War II in the US, 13540 tons of silver were used for the electromagnets in calutrons for enriching uranium , mainly because of the wartime shortage of copper. Silver readily forms alloys with copper, gold, and zinc . Zinc-silver alloys with low zinc concentration may be considered as face-centred cubic solid solutions of zinc in silver, as

9464-486: The tax base, an exclusive tax rate can be directly compared to an inclusive tax rate. Tax deductions and tax credits are two ways how to decrease taxpayer’s liability. Individuals can claim credits and deductions when they file their tax returns to lower their taxes, which is connected with marginal and average tax rates. A tax deduction is an amount you can subtract from your taxable income, so you do not have to pay tax on it. By lowering individual taxes, taxable income

9568-429: The tax rate is imposed. If an individual's gross income is $ 100 and income tax rate is 20%, taxes owed equals $ 20. The income tax is taken "off the top", so the individual is left with $ 80 in after-tax money. Some tax laws impose taxes on a tax base equal to the pre-tax portion of a good's price. Unlike the income tax example above, these taxes do not include actual taxes owed as part of the base. A good priced at $ 80 with

9672-431: The term is used in official guidance only with respect to determining income tax expense for interim (e.g. quarterly) periods by multiplying accounting income by an "estimated annual effective tax rate", the definition of which rate varies depending on the reporting entity's circumstances. In U.S. income tax law, the term can be used in relation to determining whether a foreign income tax on specific types of income exceeds

9776-540: The thermal conductivity of carbon (in the diamond allotrope ) and superfluid helium-4 are higher. The electrical conductivity of silver is the highest of all metals, greater even than copper. Silver also has the lowest contact resistance of any metal. Silver is rarely used for its electrical conductivity, due to its high cost, although an exception is in radio-frequency engineering , particularly at VHF and higher frequencies where silver plating improves electrical conductivity because those currents tend to flow on

9880-420: The top tax rate. For example, consider a system with three tax brackets, 10%, 20%, and 30%, where the 10% rate applies to income from $ 1 to $ 10,000, the 20% rate applies to income from $ 10,001 to $ 20,000, and the 30% rate applies to all income above $ 20,000. Under this system, someone earning $ 25,000 would pay $ 1,000 for the first $ 10,000 of income (10%); $ 2,000 for the second $ 10,000 of income (20%); and $ 1,500 for

9984-491: The total tax base (taxable income or spending), expressed as a percentage. Average tax rates is used to measure tax burden of individuals and corporations and how taxes affect the individuals and corporations ability to consum. In a proportional tax , the tax rate is fixed and the average tax rate equals this tax rate. In case of tax brackets , commonly used for progressive taxes , the average tax rate increases as taxable income increases through tax brackets, asymptoting to

10088-486: The two armies met ˹at Badr˺. And Allah is Most Capable of everything. In practice, the share of the fifth reserved to the Prophet's family lapsed after Muhammad 's death. The early Rashidun Caliphs , notably Caliph Omar , set down regulatory guidelines for what could and could not be regarded as war spoils , and assigned the fifth for welfare distribution. The 'fifth' eventually became an important source of financing for

10192-490: The usage of marginal tax rates and tax brackets used in the USA in 2023 can be seen below. The layout can be seen in the following table. For an income equal to $ 58,000 per year then $ 11,000 of it is taxed by 10%, $ 33,725 by 12%, and $ 13,275 by 22%. The marginal tax of this individual is equal to 22%. This is also an example of how progressive taxation works in practice. Marginal taxes are used by governments to generate revenue. A specific tax rate , or per unit tax rate,

10296-458: The weakness of the Ag–C bond. A few are known at very low temperatures around 6–15 K, such as the green, planar paramagnetic Ag(CO) 3 , which dimerizes at 25–30 K, probably by forming Ag–Ag bonds. Additionally, the silver carbonyl [Ag(CO)] [B(OTeF 5 ) 4 ] is known. Polymeric AgLX complexes with alkenes and alkynes are known, but their bonds are thermodynamically weaker than even those of

10400-499: The world production of silver was around a meagre 50 tonnes per year. In the Americas, high temperature silver-lead cupellation technology was developed by pre-Inca civilizations as early as AD 60–120; silver deposits in India, China, Japan, and pre-Columbian America continued to be mined during this time. With the discovery of America and the plundering of silver by the Spanish conquistadors, Central and South America became

10504-460: Was allowed to retain 10% of the royal fifth of the West Indies (although he famously argued he was promised more); the 1532 contracts of the captains-donatary of colonial Brazil allowed them to retain 5% of the royal fifth. In Spain, the quinto real on mining of precious metals was codified by the edict of February 1504, and (with occasional exceptional grants) remained in force through all

10608-413: Was also aware of sheet silver, exemplifying the malleability and ductility of the metal: "Silver spread into plates is brought from Tarshish, and gold from Uphaz, the work of the workman, and of the hands of the founder: blue and purple is their clothing: they are all the work of cunning men." (Jeremiah 10:9) Silver also has more negative cultural meanings: the idiom thirty pieces of silver , referring to

10712-510: Was more often used ornamentally or as money. Since silver is more reactive than gold, supplies of native silver were much more limited than those of gold. For example, silver was more expensive than gold in Egypt until around the fifteenth century BC: the Egyptians are thought to have separated gold from silver by heating the metals with salt, and then reducing the silver chloride produced to

10816-457: Was the usual Proto-Indo-European word for the metal, whose reflexes are missing in Germanic and Balto-Slavic. Silver was known in prehistoric times: the three metals of group 11, copper, silver, and gold, occur in the elemental form in nature and were probably used as the first primitive forms of money as opposed to simple bartering. Unlike copper, silver did not lead to the growth of metallurgy , on account of its low structural strength; it

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