114-486: Trinitrotoluene ( / ˌ t r aɪ ˌ n aɪ t r oʊ ˈ t ɒ lj u iː n / ), more commonly known as TNT (and more specifically 2,4,6-trinitrotoluene , and by its preferred IUPAC name 2-methyl-1,3,5-trinitrobenzene ), is a chemical compound with the formula C 6 H 2 (NO 2 ) 3 CH 3 . TNT is occasionally used as a reagent in chemical synthesis , but it is best known as an explosive material with convenient handling properties. The explosive yield of TNT
228-515: A cancer cure, which the American Cancer Society has warned against due to both its unproven effectiveness and potential danger in use. Edzard Ernst has called the promotion of sodium bicarbonate as a cancer cure "one of the more sickening alternative cancer scams I have seen for a long time". Sodium bicarbonate can be added to local anaesthetics , to speed up the onset of their effects and make their injection less painful. It
342-506: A civilian context and in armour-piercing projectiles. DU is not removed by normal laundering; washing with about 6 ounces (170 g) of baking soda in 2 gallons (7.5 L) of water will help wash it out. It is often claimed that baking soda is an effective odor remover and recommended that an open box be kept in the refrigerator to absorb odor. This idea was promoted by the leading U.S. brand of baking soda, Arm & Hammer , in an advertising campaign starting in 1972. Though this campaign
456-537: A coding system that represented long sequences of amino acids. This would allow for these sequences to be compared to try to find homologies . These codes can consist of either a one-letter code or a three-letter code. These codes make it easier and shorter to write down the amino acid sequences that make up proteins . The nucleotide bases are made up of purines ( adenine and guanine ) and pyrimidines ( cytosine and thymine or uracil ). These nucleotide bases make up DNA and RNA . These nucleotide base codes make
570-420: A dry or wet deodorant . Sodium bicarbonate may be used as a buffering agent , combined with table salt, when creating a solution for nasal irrigation . It is used in eye hygiene to treat blepharitis . This is done by adding a teaspoon of sodium bicarbonate to cool water that was recently boiled followed by gentle scrubbing of the eyelash base with a cotton swab dipped in the solution. Sodium bicarbonate
684-575: A long snake-like ash as a combustion product of the other main component, sucrose . Sodium bicarbonate also delays combustion reactions through the release of carbon dioxide and water, both of which are flame retardants, when heated. It has weak disinfectant properties and it may be an effective fungicide against some organisms. As baking soda will absorb musty smells, it has become a reliable method for used booksellers when making books less malodorous. Sodium bicarbonate can be used to extinguish small grease or electrical fires by being thrown over
798-1014: A member state of the Chemical Weapons Convention (CWC), are of concern to chemical scientists and engineers around the globe and we stand ready to support your mission of implementing the CWC." According to the CWC, "the use, stockpiling, distribution, development or storage of any chemical weapons is forbidden by any of the 192 state party signatories." IUPAC is governed by several committees that all have different responsibilities. The committees are as follows: Bureau, CHEMRAWN (Chem Research Applied to World Needs) Committee, Committee on Chemistry Education, Committee on Chemistry and Industry, Committee on Printed and Electronic Publications, Evaluation Committee, Executive Committee, Finance Committee, Interdivisional Committee on Terminology, Nomenclature and Symbols, Project Committee, and Pure and Applied Chemistry Editorial Advisory Board. Each committee
912-444: A mild saponification effect, producing a soapy foam that can help smother the fire. Sodium bicarbonate reacts spontaneously with acids, releasing CO 2 gas as a reaction product. It is commonly used to neutralize unwanted acid solutions or acid spills in chemical laboratories. It is not appropriate to use sodium bicarbonate to neutralize base even though it is amphoteric , reacting with both acids and bases. Sodium bicarbonate
1026-461: A mixture of fuming nitric acid and sulfuric acid. TNT is one of the most commonly used explosives for military, industrial, and mining applications. TNT has been used in conjunction with hydraulic fracturing (popularly known as fracking), a process used to acquire oil and gas from shale formations. The technique involves displacing and detonating nitroglycerin in hydraulically induced fractures followed by wellbore shots using pelletized TNT. TNT
1140-461: A paste made from baking soda with minimal water as a gentle scouring powder. Such a paste can be useful in removing surface rust because the rust forms a water-soluble compound when in a concentrated alkaline solution. Cold water should be used since hot-water solutions can corrode steel. Sodium bicarbonate attacks the thin protective oxide layer that forms on aluminium, making it unsuitable for cleaning this metal. A solution in warm water will remove
1254-529: A pollutant whose removal is a priority. The USEPA maintains that TNT levels in soil should not exceed 17.2 milligrams per kilogram of soil and 0.01 milligrams per litre of water. Dissolution is a measure of the rate that solid TNT in contact with water is dissolved. The relatively low aqueous solubility of TNT causes solid particles to be continuously released to the environment over extended periods of time. Studies have shown that TNT dissolves more slowly in saline water than in freshwater. However, when salinity
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#17327663096141368-500: A possible human carcinogen , with carcinogenic effects demonstrated in animal experiments with rats, although effects upon humans so far amount to none (according to IRIS of March 15, 2000). Consumption of TNT produces red urine through the presence of breakdown products and not blood as sometimes believed. Some military testing grounds are contaminated with wastewater from munitions programs, including contamination of surface and subsurface waters which may be colored pink because of
1482-421: A pressure wave from a starter explosive, called an explosive booster . Although blocks of TNT are available in various sizes (e.g. 250 g, 500 g, 1,000 g), it is more commonly encountered in synergistic explosive blends comprising a variable percentage of TNT plus other ingredients. Examples of explosive blends containing TNT include: Upon detonation , TNT undergoes a decomposition equivalent to
1596-430: A process called sulfitation, where the crude TNT is treated with aqueous sodium sulfite solution to remove less stable isomers of TNT and other undesired reaction products. The rinse water from sulfitation is known as red water and is a significant pollutant and waste product of TNT manufacture. Control of nitrogen oxides in feed nitric acid is very important because free nitrogen dioxide can result in oxidation of
1710-474: A very limited amount of mineralization of TNT in a liquid culture, though not in soil. An organism capable of the remediation of large amounts of TNT in soil has yet to be discovered. Both wild and transgenic plants can phytoremediate explosives from soil and water. IUPAC The International Union of Pure and Applied Chemistry ( IUPAC / ˈ aɪ juː p æ k , ˈ juː -/ ) is an international federation of National Adhering Organizations working for
1824-406: A yellow color. Baking powder , also sold for cooking, contains around 30% of bicarbonate, and various acidic ingredients that are activated by the addition of water, without the need for additional acids in the cooking medium. Many forms of baking powder contain sodium bicarbonate combined with calcium acid phosphate , sodium aluminium phosphate , or cream of tartar . Baking soda is alkaline;
1938-421: Is cyclohexanol : Basic IUPAC inorganic nomenclature has two main parts: the cation and the anion . The cation is the name for the positively charged ion and the anion is the name for the negatively charged ion. An example of IUPAC nomenclature of inorganic chemistry is potassium chlorate (KClO 3 ): IUPAC also has a system for giving codes to identify amino acids and nucleotide bases. IUPAC needed
2052-689: Is Germany. Germany's exclusion was a result of prejudice towards Germans by the Allied powers after World War I . Germany was finally admitted into IUPAC in 1929. However, Nazi Germany was removed from IUPAC during World War II . During World War II, IUPAC was affiliated with the Allied powers , but had little involvement during the war effort itself. After the war, East and West Germany were readmitted to IUPAC in 1973. Since World War II, IUPAC has been focused on standardizing nomenclature and methods in science without interruption. In 2016, IUPAC denounced
2166-651: Is a book about soil structures and the molecular processes that occur in soil. Structure and Surface Reactions of Soil Particles is aimed at any researcher researching soil or in the field of anthropology . It goes into depth on topics such as: fractal analysis of particle dimensions; computer modeling of the structure; reactivity of humics; applications of atomic force microscopy; and advanced instrumentation for analysis of soil particles. Metal Speciation and Bioavailability in Aquatic Systems, Series on Analytical and Physical Chemistry of Environmental Systems Vol. 3
2280-468: Is a book about the effect of trace metals on aquatic life. This book is considered a specialty book for researchers interested in observing the effect of trace metals in the water supply. This book includes techniques to assess how bioassays can be used to evaluate how an organism is affected by trace metals. Also, Metal Speciation and Bioavailability in Aquatic Systems, Series on Analytical and Physical Chemistry of Environmental Systems Vol. 3 looks at
2394-407: Is a book that delves into aerosol science. This book is aimed as a reference for graduate students and atmospheric researchers. Atmospheric Particles goes into depth on the properties of aerosols in the atmosphere and their effect. Topics covered in this book are: acid rain ; heavy metal pollution; global warming ; and photochemical smog. Atmospheric Particles also covers techniques to analyze
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#17327663096142508-463: Is a book that discusses techniques and devices to monitor aquatic systems and how new devices and techniques can be developed. This book emphasizes the future use of micro-analytical monitoring techniques and microtechnology . In Situ Monitoring of Aquatic Systems: Chemical Analysis and Speciation is aimed at researchers and laboratories that analyze aquatic systems such as rivers, lakes, and oceans. Structure and Surface Reactions of Soil Particles
2622-517: Is a book that gives background information on thermal analysis and calorimetry . Thermoanalytical and calorimetric techniques along with thermodynamic and kinetic properties are also discussed. Later volumes of this book discuss the applications and principles of these thermodynamic and kinetic methods. Equations of State for Fluids and Fluid Mixtures Part I is a book that gives up to date equations of state for fluids and fluid mixtures. This book covers all ways to develop equations of state. It gives
2736-459: Is a function of their ability to associate with the mobile phase (water) and a stationary phase (soil). Materials that associate strongly with soils move slowly through soil. The association constant for TNT with soil is 2.7 to 11 L/kg of soil. This means that TNT has a one- to tenfold tendency to adhere to soil particulates than not when introduced into the soil. Hydrogen bonding and ion exchange are two suggested mechanisms of adsorption between
2850-474: Is a major process that impacts the transformation of energetic compounds. The alteration of a molecule in photolysis occurs by direct absorption of light energy or by the transfer of energy from a photosensitized compound. Phototransformation of TNT "results in the formation of nitrobenzenes , benzaldehydes , azodicarboxylic acids, and nitrophenols , as a result of the oxidation of methyl groups , reduction of nitro groups , and dimer formation." Evidence of
2964-735: Is a reactive molecule and is particularly prone to react with reduced components of sediments or photodegradation in the presence of sunlight. TNT is thermodynamically and kinetically capable of reacting with a wide number of components of many environmental systems. This includes wholly abiotic reactants, like hydrogen sulfide , Fe , or microbial communities, both oxic and anoxic and photochemical degradation. Soils with high clay contents or small particle sizes and high total organic carbon content have been shown to promote TNT transformation. Possible TNT transformations include reduction of one, two, or three nitro-moieties to amines and coupling of amino transformation products to form dimers . Formation of
3078-526: Is a white solid that is crystalline but often appears as a fine powder. It has a slightly salty, alkaline taste resembling that of washing soda ( sodium carbonate ). The natural mineral form is nahcolite , although it is more commonly found as a component of the mineral trona . As it has long been known and widely used, the salt has many different names such as baking soda, bread soda, cooking soda, brewing soda and bicarbonate of soda and can often be found near baking powder in stores. The term baking soda
3192-470: Is acidic, making a lighter product with a less acidic taste. Since the reaction occurs slowly at room temperature, mixtures (cake batter, etc.) can be allowed to stand without rising until they are heated in the oven. Heat can also by itself cause sodium bicarbonate to act as a raising agent in baking because of thermal decomposition , releasing carbon dioxide at temperatures above 80 °C (180 °F), as follows: When used this way on its own, without
3306-461: Is also a component of Moffett's solution , used in nasal surgery. It has been proposed that acidic diets weaken bones. One systematic meta-analysis of the research shows no such effect. Another also finds that there is no evidence that alkaline diets improve bone health, but suggests that there "may be some value" to alkaline diets for other reasons. Antacid (such as baking soda) solutions have been prepared and used by protesters to alleviate
3420-592: Is also known for standardizing the atomic weights of the elements through one of its oldest standing committees, the Commission on Isotopic Abundances and Atomic Weights (CIAAW). The need for an international standard for chemistry was first addressed in 1860 by a committee headed by German scientist Friedrich August Kekulé von Stradonitz . This committee was the first international conference to create an international naming system for organic compounds . The ideas that were formulated at that conference evolved into
3534-507: Is altered, TNT dissolves at the same speed. Because TNT is moderately soluble in water, it can migrate through subsurface soil, and cause groundwater contamination. Adsorption is a measure of the distribution between soluble and sediment adsorbed contaminants following attainment of equilibrium. TNT and its transformation products are known to adsorb to surface soils and sediments, where they undergo reactive transformation or remained stored. The movement or organic contaminants through soils
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3648-411: Is an effective gastrointestinal lavage preparation and laxative prior to gastrointestinal surgery, gastroscopy , etc. Intravenous sodium bicarbonate in an aqueous solution is sometimes used for cases of acidosis , or when insufficient sodium or bicarbonate ions are in the blood. In cases of respiratory acidosis, the infused bicarbonate ion drives the carbonic acid/bicarbonate buffer of plasma to
3762-407: Is considered a classic of marketing, leading within a year to more than half of American refrigerators containing a box of baking soda, there is little evidence that it is effective in this application. An educational science experiment known as the "Baking Soda and Vinegar Volcano" uses the acid-base reaction with vinegar acid to mimic a volcanic eruption. The rapid production of CO 2 causes
3876-414: Is considered to be the standard comparative convention of bombs and asteroid impacts. In chemistry , TNT is used to generate charge transfer salts . TNT was first synthesized in 1861 by German chemist Joseph Wilbrand and was originally used as a yellow dye. Its potential as an explosive was not recognized for three decades, mainly because it was so much less sensitive than other explosives known at
3990-494: Is faster at 200 °C (392 °F): Most bicarbonates undergo this dehydration reaction . Further heating converts the carbonate into the oxide (above 850 °C/1,560 °F): The generation of carbon dioxide and water partially explain the fire-extinguishing properties of NaHCO 3 , although other factors like heat absorption and radical scavenging are more significant. In nature, sodium bicarbonate occurs almost exclusively as either nahcolite or trona . Trona
4104-423: Is generally saturated with the maximum amount of TNT that will dissolve in water (about 150 parts per million (ppm).) However it has an indefinite composition that depends on the exact process; in particular, it may also contain cyclotrimethylenetrinitramine (RDX) if the plant uses TNT/RDX mixtures, or HMX if TNT/HMX is used. Red water (also known as "Sellite water") is produced during the process used to purify
4218-406: Is in sodium carbonate (Na 2 CO 3 ). The modern chemical formulas of these compounds now express their precise chemical compositions which were unknown when the name bi-carbonate of potash was coined (see also: bicarbonate ). In cooking, baking soda is primarily used in baking as a leavening agent . When it reacts with acid or is heated, carbon dioxide is released, which causes expansion of
4332-448: Is likely to be lower "than TNT in subsurface environments where specific adsorption to clay minerals dominates the sorption process." Thus, the mobility of TNT and its transformation products are dependent on the characteristics of the sorbent. The mobility of TNT in groundwater and soil has been extrapolated from "sorption and desorption isotherm models determined with humic acids , in aquifer sediments, and soils". From these models, it
4446-832: Is made up of members of different National Adhering Organizations from different countries. The steering committee hierarchy for IUPAC is as follows: Chemical Nomenclature and Structure Representation Division (Division VIII) Current officers of the Executive Committee : Scientists framed a systematic method for naming organic compounds based on their structures. Hence, the naming rules were formulated by IUPAC. IUPAC establishes rules for harmonized spelling of some chemicals to reduce variation among different local English-language variants. For example, they recommend " aluminium " rather than "aluminum", " sulfur " rather than "sulphur", and " caesium " rather than "cesium". IUPAC organic nomenclature has three basic parts:
4560-465: Is meant to be a compilation of other IUPAC works. The second edition of this book was published in 1997. This book made large changes to the first edition of the Compendium of Chemical Terminology . These changes included updated material and an expansion of the book to include over seven thousand terms. The second edition was the topic of an IUPAC XML project. This project made an XML version of
4674-483: Is meant to give an overview of a technique based on fractal geometry and the processes of environmental systems. This book gives ideas on how to use fractal geometry to compare and contrast different ecosystems . It also gives an overview of the knowledge needed to solve environmental problems. Finally, Biophysical Chemistry of Fractal Structures and Processes in Environmental Systems shows how to use
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4788-466: Is mentioned in the novel Captains Courageous by Rudyard Kipling as being used extensively in the 1800s in commercial fishing to prevent freshly caught fish from spoiling. In 1919, US Senator Lee Overman declared that bicarbonate of soda could cure the Spanish flu . In the midst of the debate on 26 January 1919, he interrupted the discussion to announce the discovery of a cure. "I want to say, for
4902-664: Is more common in the United States, while bicarbonate of soda is more common in Australia, the United Kingdom, and New Zealand. Abbreviated colloquial forms such as sodium bicarb , bicarb soda , bicarbonate , and bicarb are common. The prefix bi- in "bicarbonate" comes from an outdated naming system predating molecular knowledge. It is based on the observation that there is twice as much carbonate (CO 3 ) per sodium in sodium bicarbonate (NaHCO 3 ) as there
5016-545: Is more common, as nahcolite is more soluble in water and the chemical equilibrium between the two minerals favors trona. Significant nahcolite deposits are in the United States, Botswana and Kenya, Uganda, Turkey, and Mexico. The biggest trona deposits are in the Green River basin in Wyoming. Nahcolite is sometimes found as a component of oil shale . If kept cool ( room temperature ) and dry (an airtight container
5130-402: Is predicted that TNT has a low retention and transports readily in the environment. Compared to other explosives, TNT has a higher association constant with soil, meaning it adheres more with soil than with water. Conversely, other explosives, such as RDX and HMX with low association constants (ranging from 0.06 to 7.3 L/kg and 0 to 1.6 L/kg respectively) can move more rapidly in water. TNT
5244-613: Is produced in a three-step process. First, toluene is nitrated with a mixture of sulfuric and nitric acid to produce mononitrotoluene (MNT). The MNT is separated and then renitrated to dinitrotoluene (DNT). In the final step, the DNT is nitrated to trinitrotoluene (TNT) using an anhydrous mixture of nitric acid and oleum . Nitric acid is consumed by the manufacturing process, but the diluted sulfuric acid can be reconcentrated and reused. After nitration, TNT can either be purified by crystallization from an organic solvent or stabilized by
5358-409: Is recommended to keep out moist air), sodium bicarbonate can be kept without a significant amount of decomposition for at least two or three years. The word natron has been in use in many languages throughout modern times (in the forms of anatron , natrum and natron ) and originated (like Spanish , French and English natron as well as ' sodium ') via Arabic naṭrūn (or anatrūn ; cf.
5472-759: Is relatively well received as being useful for reviewing chemical toxicology. Macromolecular Symposia is a journal that publishes fourteen issues a year. This journal includes contributions to the macromolecular chemistry and physics field. The meetings of IUPAC are included in this journal along with the European Polymer Federation , the American Chemical Society , and the Society of Polymer Science in Japan. The Experimental Thermodynamics books series covers many topics in
5586-553: Is sometimes used to treat aspirin overdoses. Aspirin requires an acidic environment for proper absorption, and a basic environment will diminish aspirin absorption in cases of overdose. Sodium bicarbonate has also been used in the treatment of tricyclic antidepressant overdose . It can also be applied topically as a paste, with three parts baking soda to one part water, to relieve some kinds of insect bites and stings (as well as accompanying swelling). Some alternative practitioners, such as Tullio Simoncini , have promoted baking soda as
5700-779: Is taken as a sports supplement to improve muscular endurance. Studies conducted mostly in males have shown that sodium bicarbonate is most effective in enhancing performance in short-term, high-intensity activities. Sodium bicarbonate can prevent the growth of fungi when applied on leaves, although it will not kill the fungus. Excessive amounts of sodium bicarbonate can cause discolouration of fruits (two percent solution) and chlorosis (one percent solution). Sodium bicarbonate mixed with water can be used as an antacid to treat acid indigestion and heartburn . Its reaction with stomach acid produces salt , water, and carbon dioxide : A mixture of sodium bicarbonate and polyethylene glycol such as PegLyte, dissolved in water and taken orally,
5814-533: Is the Compendium of Analytical Nomenclature (the "Orange Book"; 1st edition 1978). This book was revised in 1987. The second edition has many revisions that come from reports on nomenclature between 1976 and 1984. In 1992, the second edition went through many different revisions, which led to the third edition. Pure and Applied Chemistry is the official monthly journal of IUPAC. This journal debuted in 1960. The goal statement for Pure and Applied Chemistry
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#17327663096145928-769: Is the recognized world authority in developing standards for naming the chemical elements and compounds . Since its creation, IUPAC has been run by many different committees with different responsibilities. These committees run different projects which include standardizing nomenclature , finding ways to bring chemistry to the world, and publishing works. IUPAC is best known for its works standardizing nomenclature in chemistry, but IUPAC has publications in many science fields including chemistry, biology, and physics. Some important work IUPAC has done in these fields includes standardizing nucleotide base sequence code names; publishing books for environmental scientists, chemists, and physicists; and improving education in science. IUPAC
6042-443: Is to "publish highly topical and credible works at the forefront of all aspects of pure and applied chemistry." The journal itself is available by subscription, but older issues are available in the archive on IUPAC's website. Pure and Applied Chemistry was created as a central way to publish IUPAC endorsed articles. Before its creation, IUPAC did not have a quick, official way to distribute new chemistry information. Its creation
6156-430: Is used as a cattle feed supplement, in particular as a buffering agent for the rumen . Sodium bicarbonate is used in a process to remove paint and corrosion called sodablasting . As a blasting medium, sodium bicarbonate is used to remove surface contamination from softer and less resilient substrates such as aluminium, copper, or timber that could be damaged by silica sand abrasive media. A manufacturer recommends
6270-461: Is used as a reference point for many other explosives, including nuclear weapons, as their energy content is measured in equivalent tonnes (metric tons, t) of TNT. The energy used by NIST to define the equivalent is 4.184 GJ /t. For safety assessments, it has been stated that the detonation of TNT, depending on circumstances, can release 2.673–6.702 GJ/t. The heat of combustion however is 14.5 GJ/t (14.5 MJ/kg or 4.027 kWh/kg), which requires that
6384-453: Is usually considered more problematic, as TNT has very low soil mobility. Red water is significantly more toxic and as such it has always been considered hazardous waste. It has traditionally been disposed of by evaporation to dryness (as the toxic components are not volatile), followed by incineration. Much research has been conducted to develop better disposal processes. Because of its suitability in construction and demolition, TNT has become
6498-493: Is valued partly because of its insensitivity to shock and friction, with reduced risk of accidental detonation compared to more sensitive explosives such as nitroglycerin . TNT melts at 80 °C (176 °F), far below the temperature at which it will spontaneously detonate, allowing it to be poured or safely combined with other explosives. TNT neither absorbs nor dissolves in water, which allows it to be used effectively in wet environments. To detonate, TNT must be triggered by
6612-540: The Indian Institutes of Technology using noble-metal quantum clusters could detect TNT at the sub- zeptomolar (10 mol/m) level. TNT is poisonous, and skin contact can cause skin irritation, causing the skin to turn a bright yellow-orange color. During the First World War , female munition workers who handled the chemical found that their skin turned bright yellow, which resulted in their acquiring
6726-472: The steric hindrance of the NO 2 group in the ortho position . Research has shown that in freshwater environments, with high abundances of Ca, the adsorption of TNT and its transformation products to soils and sediments may be lower than observed in a saline environment, dominated by K and Na. Therefore, when considering the adsorption of TNT, the type of soil or sediment and the ionic composition and strength of
6840-420: The substituents , carbon chain length, and chemical affix. The substituents are any functional groups attached to the main carbon chain. The main carbon chain is the longest possible continuous chain. The chemical affix denotes what type of molecule it is. For example, the ending ane denotes a single bonded carbon chain, as in "hexane" ( C 6 H 14 ). Another example of IUPAC organic nomenclature
6954-478: The tarnish from silver when the silver is in contact with a piece of aluminium foil . Baking soda is commonly added to washing machines as a replacement for water softener and to remove odors from clothes. When diluted with warm water, it is also almost as effective in removing heavy tea and coffee stains from cups as sodium hydroxide . During the Manhattan Project to develop the nuclear bomb in
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#17327663096147068-524: The 20th century amatol , a mixture of TNT with ammonium nitrate , was a widely used military explosive. TNT can be detonated with a high velocity initiator or by efficient concussion. For many years, TNT used to be the reference point for the Figure of Insensitivity . TNT had a rating of exactly 100 on the "F of I" scale. The reference has since been changed to a more sensitive explosive called RDX , which has an F of I rating of 80. The energy density of TNT
7182-575: The IUPAC Council during the General Assembly. Below is the list of IUPAC Presidents since its inception in 1919. Sodium bicarbonate Sodium bicarbonate ( IUPAC name : sodium hydrogencarbonate ), commonly known as baking soda or bicarbonate of soda , is a chemical compound with the formula NaHCO 3 . It is a salt composed of a sodium cation ( Na ) and a bicarbonate anion ( HCO 3 ). Sodium bicarbonate
7296-680: The Lower Egyptian “Natrontal” Wadi El Natrun , where a mixture of sodium carbonate and sodium hydrogen carbonate for the dehydration of mummies was used ) from Greek nítron (νίτρον) (Herodotus; Attic lítron (λίτρον) ), which can be traced back to ancient Egyptian ntr . The Greek nítron (soda, saltpeter) was also used in Latin (sal) nitrum and in German Salniter (the source of Nitrogen , Nitrat etc.). The word saleratus , from Latin sal æratus (meaning "aerated salt"),
7410-549: The Pacific Ocean are a result of reduced chlorophyll for phytoplankton production. It does this by reviewing information from research in the 1990s. This book goes into depth about: chemical speciation; analytical techniques; transformation of iron; how iron limits the development of high nutrient low chlorophyll areas in the Pacific Ocean . In Situ Monitoring of Aquatic Systems: Chemical Analysis and Speciation
7524-633: The Terrestrial Ecosystem gives techniques to analyze minerals, microorganisms, and organic components together. This book also has a large section positing why environmental scientists working in the specific fields of minerals, microorganisms, and organic components of soil should work together and how they should do so. The Biogeochemistry of Iron in Seawater is a book that describes how low concentrations of iron in Antarctica and
7638-500: The Terrestrial Ecosystem is about how minerals, microorganisms, and organic components work together to affect terrestrial systems . This book identifies that there are many different techniques and theories about minerals, microorganisms, and organic components individually, but they are not often associated with each other. It further goes on to discuss how these components of soil work together to affect terrestrial life. Interactions Between Soil Particles and Microorganisms: Impact on
7752-487: The Thermodynamic Properties of Multiple Phases is a book that includes multiple techniques that are used to study multiple phases of pure component systems. Also included in this book are the measurement techniques to obtain activity coefficients , interfacial tension , and critical parameters . This book was written for researchers and graduate students as a reference source. Atmospheric Particles
7866-423: The Thermodynamic Properties of Single Phases is a book that gives an overview of techniques for measuring the thermodynamic quantities of single phases. It also goes into experimental techniques to test many different thermodynamic states precisely and accurately. Measurement of the Thermodynamic Properties of Single Phases was written for people interested in measuring thermodynamic properties. Measurement of
7980-442: The acid used in baking powder avoids a metallic taste when the chemical change during baking creates sodium carbonate. It is often used in conjunction with other bottled water food additives to add taste. Its European Union E number is E500. Sodium bicarbonate is one of the main components of the common "black snake" firework . The effect is caused by the thermal decomposition, which produces carbon dioxide gas to produce
8094-646: The advancement of the chemical sciences, especially by developing nomenclature and terminology. It is a member of the International Science Council (ISC). IUPAC is registered in Zürich , Switzerland , and the administrative office, known as the "IUPAC Secretariat", is in Research Triangle Park , North Carolina , United States . IUPAC's executive director heads this administrative office, currently Greta Heydenrych. IUPAC
8208-561: The armour of British capital ships , whereas the British Lyddite -filled shells tended to explode upon striking armour, thus expending much of their energy outside the ship. The British started replacing Lyddite with TNT in 1907. The United States Navy continued filling armour-piercing shells with explosive D after some other nations had switched to TNT, but began filling naval mines , bombs , depth charges , and torpedo warheads with burster charges of crude grade B TNT with
8322-704: The atmosphere and ways to take atmospheric samples. Environmental Colloids and Particles: Behaviour, Separation and Characterisation is a book that discusses environmental colloids and current information available on them. This book focuses on environmental colloids and particles in aquatic systems and soils. It also goes over techniques such as techniques for sampling environmental colloids, size fractionation, and how to characterize colloids and particles. Environmental Colloids and Particles: Behaviour, Separation and Characterisation also delves into how these colloids and particles interact. Biophysical Chemistry of Fractal Structures and Processes in Environmental Systems
8436-436: The batter and forms the characteristic texture and grain in cakes, quick breads , soda bread , and other baked and fried foods. When an acid is used, the acid–base reaction can be generically represented as follows: Acidic materials that induce this reaction include hydrogen phosphates , cream of tartar , lemon juice, yogurt , buttermilk , cocoa , and vinegar . Baking soda may be used together with sourdough , which
8550-513: The benefit of those who are making this investigation," he reported, "that I was told by a judge of a superior court in the mountain country of North Carolina they have discovered a remedy for this disease." The purported cure implied a critique of modern science and an appreciation for the simple wisdom of simple people. "They say that common baking soda will cure the disease," he continued, "that they have cured it with it, that they have no deaths up there at all; they use common baking soda, which cures
8664-554: The book that includes over seven thousand terms. The XML version of the book includes an open editing policy, which allows users to add excerpts of the written version. IUPAC and UNESCO were the lead organizations coordinating events for the International Year of Chemistry , which took place in 2011. The International Year of Chemistry was originally proposed by IUPAC at the general assembly in Turin , Italy. This motion
8778-516: The carbon in TNT fully react with atmospheric oxygen, which does not occur in the initial event. For comparison, gunpowder contains 3 MJ/kg, dynamite contains 7.5 MJ/kg, and gasoline contains 47.2 MJ/kg (though gasoline requires an oxidant , so an optimized gasoline and O 2 mixture contains 10.4 MJ/kg). Various methods can be used to detect TNT, including optical and electrochemical sensors and explosive-sniffing dogs. In 2013, researchers from
8892-431: The color of brown sugar and requiring an explosive booster charge of granular crystallized grade A TNT for detonation. High-explosive shells were filled with grade A TNT, which became preferred for other uses as industrial chemical capacity became available for removing xylene and similar hydrocarbons from the toluene feedstock and other nitrotoluene isomer byproducts from the nitrating reactions. In industry, TNT
9006-404: The crude TNT. It has a complex composition containing more than a dozen aromatic compounds, but the principal components are inorganic salts ( sodium sulfate , sodium sulfite , sodium nitrite and sodium nitrate ) and sulfonated nitroaromatics . Pink and red water are colorless at the time of generation; the color is produced by photolytic reactions under the influence of sunlight. Despite
9120-463: The disease." Sodium bicarbonate is produced industrially from sodium carbonate : It is produced on the scale of about 100,000 tonnes/year (as of 2001) with a worldwide production capacity of 2.4 million tonnes per year (as of 2002). Commercial quantities of baking soda are also produced by a similar method: soda ash, mined in the form of the ore trona , is dissolved in water and treated with carbon dioxide. Sodium bicarbonate precipitates as
9234-404: The early 1940s, the chemical toxicity of uranium was an issue. Uranium oxides were found to stick very well to cotton cloth and did not wash out with soap or laundry detergent . However, the uranium would wash out with a 2% solution of sodium bicarbonate. Clothing can become contaminated with toxic dust of depleted uranium (DU), which is very dense, hence it is used for counterweights in
9348-470: The effect of an equipment setup on an experiment. Fundamental Toxicology is a textbook that proposes a curriculum for toxicology courses. Fundamental Toxicology is based on the book Fundamental Toxicology for Chemists . Fundamental Toxicology is enhanced through many revisions and updates. New information added in the revisions includes: risk assessment and management; reproductive toxicology; behavioral toxicology; and ecotoxicology . This book
9462-442: The effects of exposure to tear gas during protests. Similarly to its use in baking, sodium bicarbonate is used together with a mild acid such as tartaric acid as the excipient in effervescent tablets: when such a tablet is dropped in a glass of water, the carbonate leaves the reaction medium as carbon dioxide gas (HCO 3 + H → H 2 O + CO 2 ↑ or, more precisely, HCO 3 + H 3 O → 2 H 2 O + CO 2 ↑). This makes
9576-511: The exudated liquid into the fuze screw thread can form fire channels , increasing the risk of accidental detonation. Fuze malfunction can also result from the liquid migrating into the fuze mechanism. Calcium silicate is mixed with TNT to mitigate the tendency towards exudation. Pink water and red water are two distinct types of wastewater related to trinitrotoluene. Pink water is produced from equipment washing processes after munitions filling or demilitarization operations, and as such
9690-522: The fields of thermodynamics. Measurement of the Transport Properties of Fluids is a book that is published by Blackwell Science . The topics that are included in this book are low and high-temperature measurements, secondary coefficients, diffusion coefficients , light scattering , transient methods for thermal conductivity , methods for thermal conductivity, falling-body viscometers, and vibrating viscometers . Solution Calorimetry
9804-548: The fire, as heating of sodium bicarbonate releases carbon dioxide. However, it should not be applied to fires in deep fryers ; the sudden release of gas may cause the grease to splatter. Sodium bicarbonate is used in BC dry chemical fire extinguishers as an alternative to the more corrosive monoammonium phosphate in ABC extinguishers. The alkaline nature of sodium bicarbonate makes it the only dry chemical agent, besides Purple-K , that
9918-707: The formation of carbonic acid and hydroxide ion: Sodium bicarbonate can sometimes be used as a mild neutralization agent and a safer alternative to strong bases like sodium hydroxide . Reaction of sodium bicarbonate and an acid produces a salt and carbonic acid, which readily decomposes to carbon dioxide and water: Sodium bicarbonate reacts with acetic acid (found in vinegar), producing sodium acetate , water, and carbon dioxide : Sodium bicarbonate reacts with bases such as sodium hydroxide to form carbonates: At temperatures from 80–100 °C (176–212 °F), sodium bicarbonate gradually decomposes into sodium carbonate , water, and carbon dioxide. The conversion
10032-530: The fractal approach to understand the reactivity of flocs , sediments, soils, microorganisms, and humic substances. Interactions Between Soil Particles and Microorganisms: Impact on the Terrestrial Ecosystem is meant to be read by chemists and biologists that study environmental systems. Also, this book should be used as a reference for earth scientists, environmental geologists, environmental engineers, and professionals in microbiology and ecology. Interactions Between Soil Particles and Microorganisms: Impact on
10146-467: The genome of an organism much smaller and easier to read. The codes for amino acids (24 amino acids and three special codes) are: Principles and Practices of Method Validation is a book entailing methods of validating and analyzing many analytes taken from a single aliquot . Also, this book goes over techniques for analyzing many samples at once. Some methods discussed include chromatographic methods, estimation of effects, matrix-induced effects, and
10260-431: The ground water are important factors. The association constants for TNT and its degradation products with clays have been determined. Clay minerals have a significant effect on the adsorption of energetic compounds. Soil properties, such as organic carbon content and cation exchange capacity have significant impacts on the adsorption coefficients. Additional studies have shown that the mobility of TNT degradation products
10374-403: The left, and thus raises the pH. For this reason, sodium bicarbonate is used in medically supervised cardiopulmonary resuscitation . Infusion of bicarbonate is indicated only when the blood pH is markedly low (< 7.1–7.0). HCO 3 is used for treatment of hyperkalemia , as it will drive K back into cells during periods of acidosis. Since sodium bicarbonate can cause alkalosis , it
10488-742: The limitations of the use of bioassays to observe the effects of trace metals on organisms. Physicochemical Kinetics and Transport at Biointerfaces is a book created to aid environmental scientists in fieldwork. The book gives an overview of chemical mechanisms, transport, kinetics, and interactions that occur in environmental systems . Physicochemical Kinetics and Transport at Biointerfaces continues from where Metal Speciation and Bioavailability in Aquatic Systems leaves off. IUPAC color code their books in order to make each publication distinguishable. One extensive book on almost all nomenclature written (IUPAC nomenclature of organic chemistry and IUPAC nomenclature of inorganic chemistry) by IUPAC committee
10602-411: The liquid to foam up and overflow its container. Other ingredients such as dish soap and food coloring can be added to enhance the visual effect. If this reaction is performed inside of a closed vessel (such as a bottle) with no way for gas to escape, it can cause an explosion if the pressure is high enough. Sodium bicarbonate is an amphoteric compound. Aqueous solutions are mildly alkaline due to
10716-553: The methyl group of toluene. This reaction is highly exothermic and carries with it the risk of a runaway reaction leading to an explosion. In the laboratory, 2,4,6-trinitrotoluene is produced by a two-step process. A nitrating mixture of concentrated nitric and sulfuric acids is used to nitrate toluene to a mixture of mono- and di-nitrotoluene isomers, with careful cooling to maintain temperature. The nitrated toluenes are then separated, washed with dilute sodium bicarbonate to remove oxides of nitrogen, and then carefully nitrated with
10830-545: The most widely used explosive and thus its toxicity is the most characterized and reported. Residual TNT from manufacture, storage, and use can pollute water, soil, the atmosphere , and the biosphere . The concentration of TNT in contaminated soil can reach 50 g/kg of soil, where the highest concentrations can be found on or near the surface. In September 2001, the United States Environmental Protection Agency (USEPA) declared TNT
10944-518: The names, red and pink water are not necessarily different shades; the color depends mainly on the duration of solar exposure. If exposed long enough, "pink" water may turn various shades of pink, red, rusty orange, or black. Because of the toxicity of TNT, the discharge of pink water to the environment has been prohibited in the US and many other countries for decades, but ground contamination may exist in very old plants. However, RDX and tetryl contamination
11058-411: The nickname " canary girls " or simply "canaries". People exposed to TNT over a prolonged period tend to experience anemia and abnormal liver functions. Blood and liver effects, spleen enlargement and other harmful effects on the immune system have also been found in animals that ingested or breathed trinitrotoluene. There is evidence that TNT adversely affects male fertility . TNT is listed as
11172-513: The nitro functional groups and soil colloids. The number of functional groups on TNT influences the ability to adsorb into soil. Adsorption coefficient values have been shown to increase with an increase in the number of amino groups. Thus, adsorption of the TNT decomposition product 2,4-diamino-6-nitrotoluene (2,4-DANT) was greater than that for 4-amino-2,6-dinitrotoluene (4-ADNT), which was greater than that for TNT. Lower adsorption coefficients for 2,6-DNT compared to 2,4-DNT can be attributed to
11286-441: The official IUPAC nomenclature of organic chemistry . IUPAC stands as a legacy of this meeting, making it one of the most important historical international collaborations of chemistry societies . Since this time, IUPAC has been the official organization held with the responsibility of updating and maintaining official organic nomenclature . IUPAC as such was established in 1919. One notable country excluded from this early IUPAC
11400-454: The photolysis of TNT has been seen due to the color change to pink of TNT-containing wastewaters when exposed to sunlight. Photolysis is more rapid in river water than in distilled water. Ultimately, photolysis affects the fate of TNT primarily in the aquatic environment but could also affect the fate of TNT in soil when the soil surface is exposed to sunlight. The ligninolytic physiological phase and manganese peroxidase system of fungi can cause
11514-408: The presence of TNT. Such contamination, called "pink water", may be difficult and expensive to remedy . TNT is prone to exudation of dinitrotoluenes and other isomers of trinitrotoluene when projectiles containing TNT are stored at higher temperatures in warmer climates. Exudation of impurities leads to formation of pores and cracks (which in turn cause increased shock sensitivity). Migration of
11628-424: The presence of an acidic component (whether in the batter or by the use of a baking powder containing acid), only half the available CO 2 is released (one CO 2 molecule is formed for every two equivalents of NaHCO 3 ). Additionally, in the absence of acid, thermal decomposition of sodium bicarbonate also produces sodium carbonate , which is strongly alkaline and gives the baked product a bitter, soapy taste and
11742-541: The reaction plus some of the reactions and The reaction is exothermic but has a high activation energy in the gas phase (~62 kcal/mol). The condensed phases (solid or liquid) show markedly lower activation energies of roughly 35 kcal/mol due to unique bimolecular decomposition routes at elevated densities. Because of the production of carbon , TNT explosions have a sooty appearance. Because TNT has an excess of carbon, explosive mixtures with oxygen-rich compounds can yield more energy per kilogram than TNT alone. During
11856-479: The strengths and weaknesses of each equation. Some equations discussed include: virial equation of state cubic equations; generalized Van der Waals equations ; integral equations; perturbation theory; and stating and mixing rules. Other things that Equations of State for Fluids and Fluid Mixtures Part I goes over are: associating fluids, polymer systems, polydisperse fluids, self-assembled systems, ionic fluids, and fluids near their critical points. Measurement of
11970-521: The tablet disintegrate, leaving the medication suspended and/or dissolved in the water together with the resulting salt (in this example, sodium tartrate ). Sodium bicarbonate is also used as an ingredient in some mouthwashes. It has anticaries and abrasive properties. It works as a mechanical cleanser on the teeth and gums, neutralizes the production of acid in the mouth, and also acts as an antiseptic to help prevent infections. Sodium bicarbonate in combination with other ingredients can be used to make
12084-534: The time. Its explosive properties were discovered in 1891 by another German chemist, Carl Häussermann. TNT can be safely poured when liquid into shell cases, and is so insensitive that in 1910 it was exempted from the UK's Explosives Act 1875 and was not considered an explosive for the purposes of manufacture and storage. The German armed forces adopted it as a filling for artillery shells in 1902. TNT-filled armour-piercing shells would explode after they had penetrated
12198-470: The two monoamino transformation products, 2-ADNT and 4-ADNT, is energetically favored, and therefore is observed in contaminated soils and ground water. The diamino products are energetically less favorable, and even less likely are the triamino products. The transformation of TNT is significantly enhanced under anaerobic conditions as well as under highly reducing conditions. TNT transformations in soils can occur both biologically and abiotically. Photolysis
12312-607: The use of chlorine as a chemical weapon . The organization pointed out their concerns in a letter to Ahmet Üzümcü, the director of the Organisation for the Prohibition of Chemical Weapons (OPCW), in regards to the practice of utilizing chlorine for weapon usage in Syria among other locations. The letter stated, "Our organizations deplore the use of chlorine in this manner. The indiscriminate attacks, possibly carried out by
12426-529: Was adopted by UNESCO at a meeting in 2008. The main objectives of the International Year of Chemistry were to increase public appreciation of chemistry and gain more interest in the world of chemistry . This event is also being held to encourage young people to get involved and contribute to chemistry. A further reason for this event being held is to honour how chemistry has made improvements to everyone's way of life. IUPAC Presidents are elected by
12540-510: Was decided that the journal would reprint old journal editions to keep all chemistry knowledge available. The Compendium of Chemical Terminology , also known as the "Gold Book", was originally worked on by Victor Gold . This book is a collection of names and terms already discussed in Pure and Applied Chemistry . The Compendium of Chemical Terminology was first published in 1987. The first edition of this book contains no original material, but
12654-644: Was established in 1919 as the successor of the International Congress of Applied Chemistry for the advancement of chemistry . Its members, the National Adhering Organizations, can be national chemistry societies , national academies of sciences , or other bodies representing chemists. There are fifty-four National Adhering Organizations and three Associate National Adhering Organizations. IUPAC's Inter-divisional Committee on Nomenclature and Symbols ( IUPAC nomenclature )
12768-537: Was first suggested at the Paris IUPAC Meeting of 1957. During this meeting the commercial publisher of the journal was discussed and decided on. In 1959, the IUPAC Pure and Applied Chemistry Editorial Advisory Board was created and put in charge of the journal. The idea of one journal being a definitive place for a vast amount of chemistry was difficult for the committee to grasp at first. However, it
12882-460: Was used in large-scale fire suppression systems installed in commercial kitchens. Sodium bicarbonate has several fire-extinguishing mechanisms that act simultaneously. It decomposes into water and carbon dioxide when heated, an endothermic reaction that deprives the fire of heat. In addition, it forms intermediates that can scavenge the free radicals which are responsible for the propagation of fire . With grease fires specifically, it also has
12996-744: Was widely used in the 19th century for both sodium bicarbonate and potassium bicarbonate . In 1791, French chemist Nicolas Leblanc produced sodium carbonate (also known as soda ash). Pharmacist Valentin Rose the Younger is credited with the discovery of sodium bicarbonate in 1801 in Berlin. In 1846, two American bakers, John Dwight and Austin Church , established the first factory in the United States to produce baking soda from sodium carbonate and carbon dioxide . Saleratus , potassium or sodium bicarbonate,
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