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112-455: The interstellar medium is composed of multiple phases distinguished by whether matter is ionic, atomic, or molecular, and the temperature and density of the matter. The interstellar medium is composed primarily of hydrogen , followed by helium with trace amounts of carbon , oxygen , and nitrogen . The thermal pressures of these phases are in rough equilibrium with one another. Magnetic fields and turbulent motions also provide pressure in

224-478: A coolant in the rotor and the stator in 1937 at Dayton , Ohio, owned by the Dayton Power & Light Co. This was justified by the high thermal conductivity and very low viscosity of hydrogen gas, thus lower drag than air. This is the most common coolant used for generators 60 MW and larger; smaller generators are usually air-cooled . The nickel–hydrogen battery was used for the first time in 1977 aboard

336-465: A nucleus which is usually composed of one proton. That is why H is often called a proton. This species is central to discussion of acids . Under the Brønsted–Lowry acid–base theory , acids are proton donors, while bases are proton acceptors. A bare proton, H , cannot exist in solution or in ionic crystals because of its strong attraction to other atoms or molecules with electrons. Except at

448-494: A stoichiometric quantity of hydrogen at the anode. For hydrides other than group 1 and 2 metals, the term is quite misleading, considering the low electronegativity of hydrogen. An exception in group 2 hydrides is BeH 2 , which is polymeric. In lithium aluminium hydride , the [AlH 4 ] anion carries hydridic centers firmly attached to the Al(III). Although hydrides can be formed with almost all main-group elements,

560-525: A typical disk diameter of 30,000 parsecs. Gas and stars in the disk orbit the galactic centre with typical orbital speeds of 200 km/s. This is much faster than the random motions of atoms in the ISM, but since the orbital motion of the gas is coherent, the average motion does not directly affect structure in the ISM. The vertical scale height of the ISM is set in roughly the same way as the Earth's atmosphere, as

672-569: A 100-parsec radius region of coronal gas. In October 2020, astronomers reported a significant unexpected increase in density in the space beyond the Solar System as detected by the Voyager 1 and Voyager 2 space probes . According to the researchers, this implies that "the density gradient is a large-scale feature of the VLISM (very local interstellar medium) in the general direction of

784-449: A balance between the local gravitation field (dominated by the stars in the disk) and the pressure. Further from the disk plane, the ISM is mainly in the low-density warm and coronal phases, which extend at least several thousand parsecs away from the disk plane. This galactic halo or 'corona' also contains significant magnetic field and cosmic ray energy density. The rotation of galaxy disks influences ISM structures in several ways. Since

896-437: A fire. Anaerobic oxidation of iron by the protons of water at high temperature can be schematically represented by the set of following reactions: Many metals such as zirconium undergo a similar reaction with water leading to the production of hydrogen. François Isaac de Rivaz built the first de Rivaz engine , an internal combustion engine powered by a mixture of hydrogen and oxygen in 1806. Edward Daniel Clarke invented

1008-507: A greatly upgraded database for tracking polycyclic aromatic hydrocarbons (PAHs) in the universe. According to scientists, more than 20% of the carbon in the universe may be associated with PAHs, possible starting materials for the formation of life . PAHs seem to have been formed shortly after the Big Bang , are widespread throughout the universe, and are associated with new stars and exoplanets . In April 2019, scientists, working with

1120-424: A laboratory high-vacuum chamber. Within our galaxy, by mass , 99% of the ISM is gas in any form, and 1% is dust. Of the gas in the ISM, by number 91% of atoms are hydrogen and 8.9% are helium, with 0.1% being atoms of elements heavier than hydrogen or helium, known as " metals " in astronomical parlance. By mass this amounts to 70% hydrogen, 28% helium, and 1.5% heavier elements. The hydrogen and helium are primarily

1232-633: A molar basis ) because of its light weight, which enables it to escape the atmosphere more rapidly than heavier gases. However, hydrogen is the third most abundant element on the Earth's surface, mostly in the form of chemical compounds such as hydrocarbons and water. OB stars OB stars are hot, massive stars of spectral types O or early-type B that form in loosely organized groups called OB associations . They are short lived, and thus do not move very far from where they formed within their life. During their lifetime, they will emit much ultraviolet radiation. This radiation rapidly ionizes

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1344-448: A monatomic gas at cryogenic temperatures. According to quantum theory, this behavior arises from the spacing of the (quantized) rotational energy levels, which are particularly wide-spaced in H 2 because of its low mass. These widely spaced levels inhibit equal partition of heat energy into rotational motion in hydrogen at low temperatures. Diatomic gases composed of heavier atoms do not have such widely spaced levels and do not exhibit

1456-515: A natural consequence of our points of view to assume that the whole of space is filled with electrons and flying electric ions of all kinds. We have assumed that each stellar system in evolutions throws off electric corpuscles into space. It does not seem unreasonable therefore to think that the greater part of the material masses in the universe is found, not in the solar systems or nebulae , but in 'empty' space" ( Birkeland 1913 ). Thorndike (1930) noted that "it could scarcely have been believed that

1568-545: A partial negative charge. These compounds are often known as hydrides . Hydrogen forms many compounds with carbon called the hydrocarbons , and even more with heteroatoms that, due to their association with living things, are called organic compounds . The study of their properties is known as organic chemistry and their study in the context of living organisms is called biochemistry . By some definitions, "organic" compounds are only required to contain carbon. However, most of them also contain hydrogen, and because it

1680-477: A partial positive charge. When bonded to a more electronegative element, particularly fluorine , oxygen , or nitrogen , hydrogen can participate in a form of medium-strength noncovalent bonding with another electronegative element with a lone pair, a phenomenon called hydrogen bonding that is critical to the stability of many biological molecules. Hydrogen also forms compounds with less electronegative elements, such as metals and metalloids , where it takes on

1792-508: A portion of the ISM, different heating and cooling mechanisms determine the temperature of the gas. Grain heating by thermal exchange is very important in supernova remnants where densities and temperatures are very high. Gas heating via grain-gas collisions is dominant deep in giant molecular clouds (especially at high densities). Far infrared radiation penetrates deeply due to the low optical depth. Dust grains are heated via this radiation and can transfer thermal energy during collisions with

1904-405: A proton and an electron, the hydrogen atom , together with the spectrum of light produced from it or absorbed by it, has been central to the development of the theory of atomic structure. Furthermore, study of the corresponding simplicity of the hydrogen molecule and the corresponding cation H + 2 brought understanding of the nature of the chemical bond , which followed shortly after

2016-435: A result of primordial nucleosynthesis , while the heavier elements in the ISM are mostly a result of enrichment (due to stellar nucleosynthesis ) in the process of stellar evolution . The ISM plays a crucial role in astrophysics precisely because of its intermediate role between stellar and galactic scales. Stars form within the densest regions of the ISM, which ultimately contributes to molecular clouds and replenishes

2128-538: A serious incident. Hydrogen-lifted airships were used as observation platforms and bombers during the war. The first non-stop transatlantic crossing was made by the British airship R34 in 1919. Regular passenger service resumed in the 1920s and the discovery of helium reserves in the United States promised increased safety, but the U.S. government refused to sell the gas for this purpose. Therefore, H 2

2240-440: A similar experiment with iron and sulfuric acid. However, in all likelihood, "sulfureous" should here be understood to mean "combustible". In 1766, Henry Cavendish was the first to recognize hydrogen gas as a discrete substance, by naming the gas from a metal-acid reaction "inflammable air". He speculated that "inflammable air" was in fact identical to the hypothetical substance " phlogiston " and further finding in 1781 that

2352-570: A small disk component, with ISM similar to spirals, buried close to their centers. The ISM of lenticular galaxies , as with their other properties, appear intermediate between spirals and ellipticals. Very close to the center of most galaxies (within a few hundred light years at most), the ISM is profoundly modified by the central supermassive black hole : see Galactic Center for the Milky Way, and Active galactic nucleus for extreme examples in other galaxies. The rest of this article will focus on

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2464-498: A smaller portion comes from energy-intensive methods such as the electrolysis of water . Its main industrial uses include fossil fuel processing, such as hydrocracking , and ammonia production , with emerging uses in fuel cells for electricity generation and as a heat source. When used in fuel cells, hydrogen's only emission at point of use is water vapor, though combustion can produce nitrogen oxides . Hydrogen's interaction with metals may cause embrittlement . Hydrogen gas

2576-471: A spark or flame, they do not react at room temperature in the absence of a catalyst. The ground state energy level of the electron in a hydrogen atom is −13.6  eV , equivalent to an ultraviolet photon of roughly 91 nm wavelength. The energy levels of hydrogen can be calculated fairly accurately using the Bohr model of the atom, in which the electron "orbits" the proton, like how Earth orbits

2688-450: A species. To avoid the implication of the naked "solvated proton" in solution, acidic aqueous solutions are sometimes considered to contain a less unlikely fictitious species, termed the " hydronium ion" ( [H 3 O] ). However, even in this case, such solvated hydrogen cations are more realistically conceived as being organized into clusters that form species closer to [H 9 O 4 ] . Other oxonium ions are found when water

2800-406: A spin singlet state having spin S = 0 {\displaystyle S=0} . The equilibrium ratio of ortho- to para-hydrogen depends on temperature. At room temperature or warmer, equilibrium hydrogen gas contains about 25% of the para form and 75% of the ortho form. The ortho form is an excited state , having higher energy than the para form by 1.455 kJ/mol, and it converts to

2912-485: A star. These effects are caused by scattering and absorption of photons and allow the ISM to be observed with the naked eye in a dark sky. The apparent rifts that can be seen in the band of the Milky Way – a uniform disk of stars – are caused by absorption of background starlight by dust in molecular clouds within a few thousand light years from Earth. This effect decreases rapidly with increasing wavelength ("reddening"

3024-438: A term that is used fairly loosely. The term "hydride" suggests that the H atom has acquired a negative or anionic character, denoted H ; and is used when hydrogen forms a compound with a more electropositive element. The existence of the hydride anion , suggested by Gilbert N. Lewis in 1916 for group 1 and 2 salt-like hydrides, was demonstrated by Moers in 1920 by the electrolysis of molten lithium hydride (LiH), producing

3136-421: A warm intercloud phase ( T  ~ 10 K), consisting of rarefied neutral and ionized gas. McKee & Ostriker (1977) added a dynamic third phase that represented the very hot ( T  ~ 10 K) gas that had been shock heated by supernovae and constituted most of the volume of the ISM. These phases are the temperatures where heating and cooling can reach a stable equilibrium. Their paper formed

3248-482: A while before caus'd to be purposely fil'd off from a piece of good steel. This metalline powder being moistn'd in the viol with a little of the menstruum, was afterwards drench'd with more; whereupon the mixture grew very hot, and belch'd up copious and stinking fumes; which whether they consisted altogether of the volatile sulfur of the Mars [iron], or of metalline steams participating of a sulfureous nature, and join'd with

3360-579: Is exothermic and produces enough heat to evaporate most of the liquid if not converted first to parahydrogen during the cooling process. Catalysts for the ortho-para interconversion, such as ferric oxide and activated carbon compounds, are used during hydrogen cooling to avoid this loss of liquid. While H 2 is not very reactive under standard conditions, it does form compounds with most elements. Hydrogen can form compounds with elements that are more electronegative , such as halogens (F, Cl, Br, I), or oxygen ; in these compounds hydrogen takes on

3472-428: Is a chemical element ; it has symbol H and atomic number 1. It is the lightest element and, at standard conditions , is a gas of diatomic molecules with the formula H 2 , sometimes called dihydrogen , but more commonly called hydrogen gas , molecular hydrogen or simply hydrogen. It is colorless, odorless, non-toxic, and highly combustible . Constituting about 75% of all normal matter , hydrogen

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3584-538: Is absorbed, and the longest radio waves observed, 1 km, can only propagate 10-50 parsecs through the Local Bubble. The frequency at which a particular nebula becomes optically thick depends on its emission measure the column density of squared electron number density. Exceptionally dense nebulae can become optically thick at centimetre wavelengths: these are just-formed and so both rare and small ('Ultra-compact H II regions') The general transparency of

3696-405: Is again due to a range of temperature/density in which runaway cooling occurs. The densest molecular clouds have significantly higher pressure than the interstellar average, since they are bound together by their own gravity. When stars form in such clouds, especially OB stars, they convert the surrounding gas into the warm ionized phase, a temperature increase of several hundred. Initially the gas

3808-469: Is caused by greater absorption of blue than red light), and becomes almost negligible at mid- infrared wavelengths (> 5 μm). Extinction provides one of the best ways of mapping the three-dimensional structure of the ISM, especially since the advent of accurate distances to millions of stars from the Gaia mission . The total amount of dust in front of each star is determined from its reddening, and

3920-559: Is characteristic of a gas, and free gaseous molecules are certainly there, since they are probably constantly being expelled by the Sun and stars." The same year, Victor Hess 's discovery of cosmic rays , highly energetic charged particles that rain onto the Earth from space, led others to speculate whether they also pervaded interstellar space. The following year, the Norwegian explorer and physicist Kristian Birkeland wrote: "It seems to be

4032-505: Is crucial in acid-base reactions , which mainly involve proton exchange among soluble molecules. In ionic compounds , hydrogen can take the form of either a negatively charged anion , where it is known as hydride , or as a positively charged cation , H . The cation, usually just a proton (symbol p ), exhibits specific behavior in aqueous solutions and in ionic compounds involves screening of its electric charge by surrounding polar molecules or anions. Hydrogen's unique position as

4144-416: Is detected in order to probe primordial hydrogen. The large amount of neutral hydrogen found in the damped Lyman-alpha systems is thought to dominate the cosmological baryonic density of the universe up to a redshift of z  = 4. Under ordinary conditions on Earth, elemental hydrogen exists as the diatomic gas, H 2 . Hydrogen gas is very rare in Earth's atmosphere (around 0.53 ppm on

4256-400: Is highly flammable: Enthalpy of combustion : −286 kJ/mol. Hydrogen gas forms explosive mixtures with air in concentrations from 4–74% and with chlorine at 5–95%. The hydrogen autoignition temperature , the temperature of spontaneous ignition in air, is 500 °C (932 °F). Pure hydrogen-oxygen flames emit ultraviolet light and with high oxygen mix are nearly invisible to

4368-453: Is in acidic solution with other solvents. Although exotic on Earth, one of the most common ions in the universe is the H + 3 ion, known as protonated molecular hydrogen or the trihydrogen cation. Hydrogen has three naturally occurring isotopes, denoted H , H and H . Other, highly unstable nuclei ( H to H ) have been synthesized in the laboratory but not observed in nature. Unique among

4480-498: Is produced, hence there is little loss of energy and the temperature can stay high for periods of hundreds of millions of years. In contrast, once the temperature falls to O(10 K) with correspondingly higher density, protons and electrons can recombine to form hydrogen atoms, emitting photons which take energy out of the gas, leading to runaway cooling. Left to itself this would produce the warm neutral medium. However, OB stars are so hot that some of their photons have energy greater than

4592-484: Is soluble in both nanocrystalline and amorphous metals . Hydrogen solubility in metals is influenced by local distortions or impurities in the crystal lattice . These properties may be useful when hydrogen is purified by passage through hot palladium disks, but the gas's high solubility is a metallurgical problem, contributing to the embrittlement of many metals, complicating the design of pipelines and storage tanks. Hydrogen compounds are often called hydrides ,

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4704-458: Is still at molecular cloud densities, and so at vastly higher pressure than the ISM average: this is a classical H II region. The large overpressure causes the ionized gas to expand away from the remaining molecular gas (a Champagne flow ), and the flow will continue until either the molecular cloud is fully evaporated or the OB stars reach the end of their lives, after a few millions years. At this point

4816-537: Is still used, in preference to non-flammable but more expensive helium, as a lifting gas for weather balloons . Deuterium was discovered in December 1931 by Harold Urey , and tritium was prepared in 1934 by Ernest Rutherford , Mark Oliphant , and Paul Harteck . Heavy water , which consists of deuterium in the place of regular hydrogen, was discovered by Urey's group in 1932. The first hydrogen-cooled turbogenerator went into service using gaseous hydrogen as

4928-490: Is the most abundant chemical element in the universe . Stars , including the Sun , mainly consist of hydrogen in a plasma state , while on Earth, hydrogen is found in water , organic compounds , as dihydrogen , and in other molecular forms . The most common isotope of hydrogen (protium, H) consists of one proton , one electron , and no neutrons . In the early universe , the formation of hydrogen's protons occurred in

5040-412: Is the carbon-hydrogen bond that gives this class of compounds most of its particular chemical characteristics, carbon-hydrogen bonds are required in some definitions of the word "organic" in chemistry. Millions of hydrocarbons are known, and they are usually formed by complicated pathways that seldom involve elemental hydrogen. Hydrogen is highly soluble in many rare earth and transition metals and

5152-502: The Hindenburg airship was a notorious example of hydrogen combustion and the cause is still debated. The visible flames in the photographs were the result of carbon compounds in the airship skin burning. H 2 is unreactive compared to diatomic elements such as halogens or oxygen. The thermodynamic basis of this low reactivity is the very strong H–H bond, with a bond dissociation energy of 435.7 kJ/mol. The kinetic basis of

5264-511: The Hubble Space Telescope , reported the confirmed detection of the large and complex ionized molecules of buckminsterfullerene (C 60 ) (also known as "buckyballs") in the interstellar medium spaces between the stars. In September 2020, evidence was presented of solid-state water in the interstellar medium, and particularly, of water ice mixed with silicate grains in cosmic dust grains. Hydrogen Hydrogen

5376-579: The International Union of Pure and Applied Chemistry (IUPAC) allows any of D, T, H , and H to be used, though H and H are preferred. The exotic atom muonium (symbol Mu), composed of an anti muon and an electron , can also be considered a light radioisotope of hydrogen. Because muons decay with lifetime 2.2  µs , muonium is too unstable for observable chemistry. Nevertheless, muonium compounds are important test cases for quantum simulation , due to

5488-504: The Lyman limit , E > 13.6 eV , enough to ionize hydrogen. Such photons will be absorbed by, and ionize, any neutral hydrogen atom they encounter, setting up a dynamic equilibrium between ionization and recombination such that gas close enough to OB stars is almost entirely ionized, with temperature around 8000 K (unless already in the coronal phase), until the distance where all the ionizing photons are used up. This ionization front marks

5600-607: The Lyman-alpha transition, and also at the other Lyman series lines. Therefore, it is nearly impossible to see light emitted at those wavelengths from a star farther than a few hundred light years from Earth, because most of it is absorbed during the trip to Earth by intervening neutral hydrogen. All photons with wavelength < 91.6 nm, the Lyman limit, can ionize hydrogen and are also very strongly absorbed. The absorption gradually decreases with increasing photon energy, and

5712-549: The Magellanic Clouds have similar interstellar mediums to spirals, but less organized. In elliptical galaxies the ISM is almost entirely in the coronal phase, since there is no coherent disk motion to support cold gas far from the center: instead, the scale height of the ISM must be comperable to the radius of the galaxy. This is consistent with the observation that there is little sign of current star formation in ellipticals. Some elliptical galaxies do show evidence for

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5824-435: The angular velocity declines with increasing distance from the centre, any ISM feature, such as giant molecular clouds or magnetic field lines, that extend across a range of radius are sheared by differential rotation, and so tend to become stretched out in the tangential direction; this tendency is opposed by interstellar turbulence (see below) which tends to randomize the structures. Spiral arms are due to perturbations in

5936-403: The black body limit as ∝ λ 2.1 {\displaystyle \propto \lambda ^{2.1}} , and at wavelengths long enough that this limit is reached, they become opaque. Thus metre-wavelength observations show H II regions as cool spots blocking the bright background emission from Galactic synchrotron radiation, while at decametres the entire galactic plane

6048-408: The heliospheric nose ". The interstellar medium begins where the interplanetary medium of the Solar System ends. The solar wind slows to subsonic velocities at the termination shock , 90–100 astronomical units from the Sun. In the region beyond the termination shock, called the heliosheath , interstellar matter interacts with the solar wind. Voyager 1 , the farthest human-made object from

6160-434: The line of sight to this star. This discovery launched the study of the interstellar medium. Interstellar gas was further confirmed by Slipher in 1909, and then by 1912 interstellar dust was confirmed by Slipher. Interstellar sodium was detected by Mary Lea Heger in 1919 through the observation of stationary absorption from the atom's "D" lines at 589.0 and 589.6 nanometres towards Delta Orionis and Beta Scorpii . In

6272-431: The "planetary orbit" differs from electron motion. Molecular H 2 exists as two spin isomers , i.e. compounds that differ only in the spin states of their nuclei. In the orthohydrogen form, the spins of the two nuclei are parallel, forming a spin triplet state having a total molecular spin S = 1 {\displaystyle S=1} ; in the parahydrogen form the spins are antiparallel and form

6384-433: The "quite surprising result that the calcium line at 393.4 nanometres does not share in the periodic displacements of the lines caused by the orbital motion of the spectroscopic binary star". The stationary nature of the line led Hartmann to conclude that the gas responsible for the absorption was not present in the atmosphere of the star, but was instead located within an isolated cloud of matter residing somewhere along

6496-831: The Alfvén wave speed, the behaviour is more like subsonic turbulence. Stars are born deep inside large complexes of molecular clouds , typically a few parsecs in size. During their lives and deaths, stars interact physically with the ISM. Stellar winds from young clusters of stars (often with giant or supergiant HII regions surrounding them) and shock waves created by supernovae inject enormous amounts of energy into their surroundings, which leads to hypersonic turbulence. The resultant structures – of varying sizes – can be observed, such as stellar wind bubbles and superbubbles of hot gas, seen by X-ray satellite telescopes or turbulent flows observed in radio telescope maps. Stars and planets, once formed, are unaffected by pressure forces in

6608-417: The Earth (after 1998), crossed the termination shock December 16, 2004 and later entered interstellar space when it crossed the heliopause on August 25, 2012, providing the first direct probe of conditions in the ISM ( Stone et al. 2005 ). Dust grains in the ISM are responsible for extinction and reddening , the decreasing light intensity and shift in the dominant observable wavelengths of light from

6720-490: The ISM begins to become transparent again in soft X-rays , with wavelengths shorter than about 1 nm. The ISM is usually far from thermodynamic equilibrium . Collisions establish a Maxwell–Boltzmann distribution of velocities, and the 'temperature' normally used to describe interstellar gas is the 'kinetic temperature', which describes the temperature at which the particles would have the observed Maxwell–Boltzmann velocity distribution in thermodynamic equilibrium. However,

6832-441: The ISM in the disk plane of spirals, far from the galactic center. Astronomers describe the ISM as turbulent , meaning that the gas has quasi-random motions coherent over a large range of spatial scales. Unlike normal turbulence, in which the fluid motions are highly subsonic , the bulk motions of the ISM are usually larger than the sound speed . Supersonic collisions between gas clouds cause shock waves which compress and heat

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6944-483: The ISM since they are below its plasma frequency . At higher frequencies, the plasma has a significant refractive index, decreasing with increasing frequency, and also dependent on the density of free electrons. Random variations in the electron density cause interstellar scintillation , which broadens the apparent size of distant radio sources seen through the ISM, with the broadening decreasing with frequency squared. The variation of refractive index with frequency causes

7056-422: The ISM to radio waves, especially microwaves, may seem surprising since radio waves at frequencies > 10 GHz are significantly attenuated by Earth's atmosphere (as seen in the figure). But the column density through the atmosphere is vastly larger than the column through the entire Galaxy, due to the extremely low density of the ISM. The word 'interstellar' (between the stars) was coined by Francis Bacon in

7168-423: The ISM with matter and energy through planetary nebulae , stellar winds , and supernovae . This interplay between stars and the ISM helps determine the rate at which a galaxy depletes its gaseous content, and therefore its lifespan of active star formation. Voyager 1 reached the ISM on August 25, 2012, making it the first artificial object from Earth to do so. Interstellar plasma and dust will be studied until

7280-477: The ISM, and are typically more important, dynamically , than the thermal pressure. In the interstellar medium, matter is primarily in molecular form and reaches number densities of 10 molecules per m (1 trillion molecules per m). In hot, diffuse regions, gas is highly ionized, and the density may be as low as 100 ions per m. Compare this with a number density of roughly 10 molecules per m for air at sea level, and 10 molecules per m (10 quadrillion molecules per m) for

7392-505: The ISM, and so do not take part in the turbulent motions, although stars formed in molecular clouds in a galactic disk share their general orbital motion around the galaxy center. Thus stars are usually in motion relative to their surrounding ISM. The Sun is currently traveling through the Local Interstellar Cloud , an irregular clump of the warm neutral medium a few parsecs across, within the low-density Local Bubble ,

7504-502: The OB stars explode as supernovas , creating blast waves in the warm gas that increase temperatures to the coronal phase ( supernova remnants , SNR). These too expand and cool over several million years until they return to average ISM pressure. Most discussion of the ISM concerns spiral galaxies like the Milky Way , in which nearly all the mass in the ISM is confined to a relatively thin disk , typically with scale height about 100 parsecs (300 light years ), which can be compared to

7616-430: The Sun and other stars). The charged particles are highly influenced by magnetic and electric fields. For example, in the solar wind they interact with the Earth's magnetosphere giving rise to Birkeland currents and the aurora . Hydrogen is found in the neutral atomic state in the interstellar medium because the atoms seldom collide and combine. They are the source of the 21-cm hydrogen line at 1420 MHz that

7728-457: The Sun and the CNO cycle of nuclear fusion in case of stars more massive than the Sun . Throughout the universe, hydrogen is mostly found in the atomic and plasma states, with properties quite distinct from those of molecular hydrogen. As a plasma, hydrogen's electron and proton are not bound together, resulting in very high electrical conductivity and high emissivity (producing the light from

7840-464: The Sun. However, the electron and proton are held together by electrostatic attraction, while planets and celestial objects are held by gravity . Due to the discretization of angular momentum postulated in early quantum mechanics by Bohr, the electron in the Bohr model can only occupy certain allowed distances from the proton, and therefore only certain allowed energies. A more accurate description of

7952-589: The U.S. Navy's Navigation technology satellite-2 (NTS-2). The International Space Station , Mars Odyssey and the Mars Global Surveyor are equipped with nickel-hydrogen batteries. In the dark part of its orbit, the Hubble Space Telescope is also powered by nickel-hydrogen batteries, which were finally replaced in May 2009, more than 19 years after launch and 13 years beyond their design life. Because of its simple atomic structure, consisting only of

8064-580: The arrival times of pulses from pulsars and Fast radio bursts to be delayed at lower frequencies (dispersion). The amount of delay is proportional to the column density of free electrons (Dispersion measure, DM), which is useful for both mapping the distribution of ionized gas in the Galaxy and estimating distances to pulsars (more distant ones have larger DM). A second propagation effect is Faraday rotation , which affects linearly polarized radio waves, such as those produced by synchrotron radiation , one of

8176-548: The availability of photons, but often such photons can penetrate throughout the neutral phase and only get absorbed in the outer layers of molecular clouds. Photons with E > 4 eV or so can break up molecules such as H 2 and CO, creating a photodissociation region (PDR) which is more or less equivalent to the Warm neutral medium. These processes contribute to the heating of the WNM. The distinction between Warm and Cold neutral medium

8288-516: The background star field of the galaxy; the most prominent are listed in his Barnard Catalogue . The first direct detection of cold diffuse matter in interstellar space came in 1904, when Johannes Hartmann observed the binary star Mintaka (Delta Orionis) with the Potsdam Great Refractor . Hartmann reported that absorption from the "K" line of calcium appeared "extraordinarily weak, but almost perfectly sharp" and also reported

8400-782: The basis for further study over the subsequent three decades. However, the relative proportions of the phases and their subdivisions are still not well understood. The basic physics behind these phases can be understood through the behaviour of hydrogen, since this is by far the largest constituent of the ISM. The different phases are roughly in pressure balance over most of the Galactic disk, since regions of excess pressure will expand and cool, and likewise under-pressure regions will be compressed and heated. Therefore, since P = n k T , hot regions (high T ) generally have low particle number density n . Coronal gas has low enough density that collisions between particles are rare and so little radiation

8512-429: The boundary between the Warm ionized and Warm neutral medium. OB stars, and also cooler ones, produce many more photons with energies below the Lyman limit, which pass through the ionized region almost unabsorbed. Some of these have high enough energy (> 11.3 eV) to ionize carbon atoms, creating a C II ("ionized carbon") region outside the (hydrogen) ionization front. In dense regions this may also be limited in size by

8624-524: The context of the ancient theory of a literal sphere of fixed stars . Later in the 17th century, when the idea that stars were scattered through infinite space became popular, it was debated whether that space was a true vacuum or filled with a hypothetical fluid, sometimes called aether , as in René Descartes ' vortex theory of planetary motions. While vortex theory did not survive the success of Newtonian physics , an invisible luminiferous aether

8736-425: The disk orbits - essentially ripples in the disk, that cause orbits to alternately converge and diverge, compressing and then expanding the local ISM. The visible spiral arms are the regions of maximum density, and the compression often triggers star formation in molecular clouds, leading to an abundance of H II regions along the arms. Coriolis force also influences large ISM features. Irregular galaxies such as

8848-452: The dust is then located along the line of sight by comparing the dust column density in front of stars projected close together on the sky, but at different distances. By 2022 it was possible to generate a map of ISM structures within 3 kpc (10,000 light years) of the Sun. Far ultraviolet light is absorbed effectively by the neutral hydrogen gas in the ISM. Specifically, atomic hydrogen absorbs very strongly at about 121.5 nanometers,

8960-430: The elements, distinct names are assigned to its isotopes in common use. During the early study of radioactivity, heavy radioisotopes were given their own names, but these are mostly no longer used. The symbols D and T (instead of H and H ) are sometimes used for deuterium and tritium, but the symbol P was already used for phosphorus and thus was not available for protium. In its nomenclatural guidelines,

9072-540: The enormous gaps between the stars are completely void. Terrestrial aurorae are not improbably excited by charged particles emitted by the Sun. If the millions of other stars are also ejecting ions, as is undoubtedly true, no absolute vacuum can exist within the galaxy." In September 2012, NASA scientists reported that polycyclic aromatic hydrocarbons (PAHs) , subjected to interstellar medium (ISM) conditions, are transformed, through hydrogenation , oxygenation and hydroxylation , to more complex organics , "a step along

9184-527: The estimated mission end date of 2025. Its twin Voyager 2 entered the ISM on November 5, 2018. Table 1 shows a breakdown of the properties of the components of the ISM of the Milky Way. Field, Goldsmith & Habing (1969) put forward the static two phase equilibrium model to explain the observed properties of the ISM. Their modeled ISM included a cold dense phase ( T  < 300  K ), consisting of clouds of neutral and molecular hydrogen, and

9296-497: The first reliable form of air-travel following the 1852 invention of the first hydrogen-lifted airship by Henri Giffard . German count Ferdinand von Zeppelin promoted the idea of rigid airships lifted by hydrogen that later were called Zeppelins ; the first of which had its maiden flight in 1900. Regularly scheduled flights started in 1910 and by the outbreak of World War I in August 1914, they had carried 35,000 passengers without

9408-441: The first second after the Big Bang ; neutral hydrogen atoms only formed about 370,000 years later during the recombination epoch as the universe cooled and plasma had cooled enough for electrons to remain bound to protons. Hydrogen, typically nonmetallic except under extreme pressure , readily forms covalent bonds with most nonmetals, contributing to the formation of compounds like water and various organic substances. Its role

9520-462: The gas produces water when burned. He is usually given credit for the discovery of hydrogen as an element. In 1783, Antoine Lavoisier identified the element that came to be known as hydrogen when he and Laplace reproduced Cavendish's finding that water is produced when hydrogen is burned. Lavoisier produced hydrogen for his experiments on mass conservation by reacting a flux of steam with metallic iron through an incandescent iron tube heated in

9632-424: The gas, increasing the sounds speed so that the flow is locally subsonic; thus supersonic turbulence has been described as 'a box of shocklets', and is inevitably associated with complex density and temperature structure. In the ISM this is further complicated by the magnetic field, which provides wave modes such as Alfvén waves which are often faster than pure sound waves: if turbulent speeds are supersonic but below

9744-424: The gas. A measure of efficiency in the heating is given by the accommodation coefficient: α = T 2 − T T d − T {\displaystyle \alpha ={\frac {T_{2}-T}{T_{d}-T}}} where T is the gas temperature, T d the dust temperature, and T 2 the post-collision temperature of the gas atom or molecule. This coefficient

9856-427: The high temperatures associated with plasmas, such protons cannot be removed from the electron clouds of atoms and molecules, and will remain attached to them. However, the term 'proton' is sometimes used loosely and metaphorically to refer to positively charged or cationic hydrogen attached to other species in this fashion, and as such is denoted " H " without any implication that any single protons exist freely as

9968-503: The hydrogen atom comes from a quantum analysis that uses the Schrödinger equation , Dirac equation or Feynman path integral formulation to calculate the probability density of the electron around the proton. The most complex formulas include the small effects of special relativity and vacuum polarization . In the quantum mechanical treatment, the electron in a ground state hydrogen atom has no angular momentum—illustrating how

10080-399: The hydrogen gas blowpipe in 1819. The Döbereiner's lamp and limelight were invented in 1823. Hydrogen was liquefied for the first time by James Dewar in 1898 by using regenerative cooling and his invention, the vacuum flask . He produced solid hydrogen the next year. The first hydrogen-filled balloon was invented by Jacques Charles in 1783. Hydrogen provided the lift for

10192-466: The interstellar radiation field is typically much weaker than a medium in thermodynamic equilibrium; it is most often roughly that of an A star (surface temperature of ~10,000 K) highly diluted. Therefore, bound levels within an atom or molecule in the ISM are rarely populated according to the Boltzmann formula ( Spitzer 1978 , § 2.4). Depending on the temperature, density, and ionization state of

10304-486: The lines' rest wavelength through the Doppler Effect . These observations confirming that matter is not distributed homogeneously were the first evidence of multiple discrete clouds within the ISM. The growing evidence for interstellar material led Pickering (1912) to comment: "While the interstellar absorbing medium may be simply the ether, yet the character of its selective absorption, as indicated by Kapteyn ,

10416-400: The low reactivity is the nonpolar nature of H 2 and its weak polarizability. It spontaneously reacts with chlorine and fluorine to form hydrogen chloride and hydrogen fluoride , respectively. The reactivity of H 2 is strongly affected by the presence of metal catalysts. Thus, while mixtures of H 2 with O 2 or air combust readily when heated to at least 500°C by

10528-402: The mass difference between the antimuon and the proton, and IUPAC nomenclature incorporates such hypothetical compounds as muonium chloride (MuCl) and sodium muonide (NaMu), analogous to hydrogen chloride and sodium hydride respectively. Table of thermal and physical properties of hydrogen (H 2 ) at atmospheric pressure: In 1671, Irish scientist Robert Boyle discovered and described

10640-481: The mass of the universe, however, is not in the form of chemical-element type matter, but rather is postulated to occur as yet-undetected forms of mass such as dark matter and dark energy . Hydrogen is found in great abundance in stars and gas giant planets. Molecular clouds of H 2 are associated with star formation . Hydrogen plays a vital role in powering stars through the proton-proton reaction in case of stars with very low to approximately 1 mass of

10752-411: The most common sources of radio emission in astrophysics. Faraday rotation depends on both the electron density and the magnetic field strength, and so is used as a probe of the interstellar magnetic field. The ISM is generally very transparent to radio waves, allowing unimpeded observations right through the disk of the Galaxy. There are a few exceptions to this rule. The most intense spectral lines in

10864-501: The naked eye, as illustrated by the faint plume of the Space Shuttle Main Engine , compared to the highly visible plume of a Space Shuttle Solid Rocket Booster , which uses an ammonium perchlorate composite . The detection of a burning hydrogen leak, may require a flame detector ; such leaks can be very dangerous. Hydrogen flames in other conditions are blue, resembling blue natural gas flames. The destruction of

10976-649: The number and combination of possible compounds varies widely; for example, more than 100 binary borane hydrides are known, but only one binary aluminium hydride. Binary indium hydride has not yet been identified, although larger complexes exist. In inorganic chemistry , hydrides can also serve as bridging ligands that link two metal centers in a coordination complex . This function is particularly common in group 13 elements , especially in boranes ( boron hydrides) and aluminium complexes, as well as in clustered carboranes . Oxidation of hydrogen removes its electron and gives H , which contains no electrons and

11088-655: The only neutral atom for which the Schrödinger equation can be directly solved, has significantly contributed to the foundational principles of quantum mechanics through the exploration of its energetics and chemical bonding . Hydrogen gas was first produced artificially in the early 16th century by reacting acids with metals. Henry Cavendish , in 1766–81, identified hydrogen gas as a distinct substance and discovered its property of producing water when burned; hence its name means "water-former" in Greek. Most hydrogen production occurs through steam reforming of natural gas ;

11200-420: The para form over the course of several minutes when cooled to low temperature. The thermal properties of the forms differ because they differ in their allowed rotational quantum states , resulting in different thermal properties such as the heat capacity. The ortho-to-para ratio in H 2 is an important consideration in the liquefaction and storage of liquid hydrogen : the conversion from ortho to para

11312-494: The path toward amino acids and nucleotides , the raw materials of proteins and DNA , respectively". Further, as a result of these transformations, the PAHs lose their spectroscopic signature , which could be one of the reasons "for the lack of PAH detection in interstellar ice grains , particularly the outer regions of cold, dense clouds or the upper molecular layers of protoplanetary disks ." In February 2014, NASA announced

11424-477: The quantum mechanical treatment of the hydrogen atom had been developed in the mid-1920s. One of the first quantum effects to be explicitly noticed (but not understood at the time) was a Maxwell observation involving hydrogen, half a century before full quantum mechanical theory arrived. Maxwell observed that the specific heat capacity of H 2 unaccountably departs from that of a diatomic gas below room temperature and begins to increasingly resemble that of

11536-658: The radio spectrum can become opaque, so that only the surface of the line-emitting cloud is visible. This mainly affects the carbon monoxide lines at millimetre wavelengths that are used to trace molecular clouds, but the 21-cm line from neutral hydrogen can become opaque in the cold neutral medium. Such absorption only affects photons at the line frequencies: the clouds are otherwise transparent. The other significant absorption process occurs in dense ionized regions. These emit photons, including radio waves, via thermal bremsstrahlung . At short wavelengths, typically microwaves , these are quite transparent, but their brightness approaches

11648-502: The reaction between iron filings and dilute acids , which results in the production of hydrogen gas. Having provided a saline spirit [hydrochloric acid], which by an uncommon way of preparation was made exceeding sharp and piercing, we put into a vial, capable of containing three or four ounces of water, a convenient quantity of filings of steel, which were not such as are commonly sold in shops to Chymists and Apothecaries, (those being usually not free enough from rust) but such as I had

11760-430: The result of the superposition of multiple absorption lines, each corresponding to the same atomic transition (for example the "K" line of calcium), but occurring in interstellar clouds with different radial velocities . Because each cloud has a different velocity (either towards or away from the observer/Earth), the absorption lines occurring within each cloud are either blue-shifted or red-shifted (respectively) from

11872-506: The saline exhalations of the menstruum, is not necessary to be here discuss'd. But whencesoever this stinking smoak proceeded, so inflammable it was, that upon the approach of a lighted candle to it, it would readily enough take fire, and burn with a blewish and somewhat greenish flame at the mouth of the viol for a good while together; and that, though with little light, yet with more strength than one would easily suspect. The word "sulfureous" may be somewhat confusing, especially since Boyle did

11984-405: The same effect. Antihydrogen ( H ) is the antimatter counterpart to hydrogen. It consists of an antiproton with a positron . Antihydrogen is the only type of antimatter atom to have been produced as of 2015 . Hydrogen, as atomic H, is the most abundant chemical element in the universe, making up 75% of normal matter by mass and >90% by number of atoms. Most of

12096-458: The series of investigations, Viktor Ambartsumian introduced the now commonly accepted notion that interstellar matter occurs in the form of clouds. Subsequent observations of the "H" and "K" lines of calcium by Beals (1936) revealed double and asymmetric profiles in the spectra of Epsilon and Zeta Orionis . These were the first steps in the study of the very complex interstellar sightline towards Orion . Asymmetric absorption line profiles are

12208-506: Was equipped for spectroscopy, which enabled breakthrough observations. From around 1889, Edward Barnard pioneered deep photography of the sky, finding many 'holes in the Milky Way'. At first he compared them to sunspots , but by 1899 was prepared to write: "One can scarcely conceive a vacancy with holes in it, unless there is nebulous matter covering these apparently vacant places in which holes might occur". These holes are now known as dark nebulae , dusty molecular clouds silhouetted against

12320-484: Was measured by ( Burke & Hollenbach 1983 ) as α  = 0.35. Despite its extremely low density, photons generated in the ISM are prominent in nearly all bands of the electromagnetic spectrum. In fact the optical band, on which astronomers relied until well into the 20th century, is the one in which the ISM is least obvious. Radio waves are affected by the plasma properties of the ISM. The lowest frequency radio waves, below ≈ 0.1 MHz, cannot propagate through

12432-409: Was re-introduced in the early 19th century as the medium to carry light waves; e.g., in 1862 a journalist wrote: "this efflux occasions a thrill, or vibratory motion, in the ether which fills the interstellar spaces." In 1864, William Huggins used spectroscopy to determine that a nebula is made of gas. Huggins had a private observatory with an 8-inch telescope, with a lens by Alvan Clark ; but it

12544-527: Was used in the Hindenburg airship, which was destroyed in a midair fire over New Jersey on 6 May 1937. The incident was broadcast live on radio and filmed. Ignition of leaking hydrogen is widely assumed to be the cause, but later investigations pointed to the ignition of the aluminized fabric coating by static electricity . But the damage to hydrogen's reputation as a lifting gas was already done and commercial hydrogen airship travel ceased . Hydrogen

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