Misplaced Pages

#392607

83-596: Franklin W. Smith was an amateur architect and pioneer experimenter in poured concrete construction. His winter home, Villa Zorayda, was the first residence built in the Moorish Revival style in Florida, and the first poured concrete building in St. Augustine. Smith's concrete mix, which used crushed coquina shells as an aggregate, and his method of pouring it in successive levels, was adopted by Henry Morrison Flagler ,

166-575: A Standard Oil partner and Florida developer, for his nearby hotels and churches on an even grander scale. Villa Zorayda could also be considered the first example of fantasy architecture in Florida. Smith was an early member of the Republican Party , and danced with his wife at Abraham Lincoln 's inaugural ball in 1861. He was also a founder of the Boston YMCA , and was involved in many reform efforts and schemes for public improvement in

249-524: A solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form. The geological definition of mineral normally excludes compounds that occur only in living organisms. However, some minerals are often biogenic (such as calcite ) or organic compounds in the sense of chemistry (such as mellite ). Moreover, living organisms often synthesize inorganic minerals (such as hydroxylapatite ) that also occur in rocks. The concept of mineral

332-585: A bend in the middle that is caused by start of the twin. Penetration twins consist of two single crystals that have grown into each other; examples of this twinning include cross-shaped staurolite twins and Carlsbad twinning in orthoclase. Cyclic twins are caused by repeated twinning around a rotation axis. This type of twinning occurs around three, four, five, six, or eight-fold axes, and the corresponding patterns are called threelings, fourlings, fivelings , sixlings, and eightlings. Sixlings are common in aragonite. Polysynthetic twins are similar to cyclic twins through

415-417: A bigger coordination numbers because of the increase in relative size as compared to oxygen (the last orbital subshell of heavier atoms is different too). Changes in coordination numbers leads to physical and mineralogical differences; for example, at high pressure, such as in the mantle , many minerals, especially silicates such as olivine and garnet , will change to a perovskite structure , where silicon

498-594: A building stone in Florida for over 400 years, coquina forms the walls of the Castillo in St. Augustine. The stone made a very good material for building forts, particularly those built during the period of heavy cannon use. Because of coquina's softness, cannonballs would sink into, rather than shatter or puncture the walls. The first Saint Augustine lighthouse , built by the Spanish, was also made of coquina. Coquina

581-432: A chemical compound occurs naturally with different crystal structures, each structure is considered a different mineral species. Thus, for example, quartz and stishovite are two different minerals consisting of the same compound, silicon dioxide . The International Mineralogical Association (IMA) is the generally recognized standard body for the definition and nomenclature of mineral species. As of November 2024 ,

664-649: A common find all over the world, with the depositional requirements to form a coquina being a common thing in many marine facies . Adjacent to Shark Bay Road beginning 45 kilometres (28 mi) southeast of Denham is an approximately 110 kilometres (68 mi) long stretch of coastline composed of billions of tiny shells of the Shark Bay cockle ( Fragum erugatum ), averaging less than 14 millimetres (0.55 in) in length. The shell deposit, between 8 and 9 metres (26 and 30 ft) thick, has compacted and cemented in some areas into solid masses of limestone that formerly

747-473: A distinct mineral: The details of these rules are somewhat controversial. For instance, there have been several recent proposals to classify amorphous substances as minerals, but they have not been accepted by the IMA. The IMA is also reluctant to accept minerals that occur naturally only in the form of nanoparticles a few hundred atoms across, but has not defined a minimum crystal size. Some authors require

830-469: A few meters thick, found 15 to 20 metres (49 to 66 ft) above present mean sea level. The ancient Maya built their city of Toniná in the highlands of what is now Chiapas in southern Mexico using native rocks to construct its masonry buildings, among them large coquina flagstones from which they made blocks and bricks for floors, walls, and stairways. Coquina has a very limited distribution in southeastern North Carolina . The best known outcrop

913-555: A hotel. The building underwent renovations beginning in 2003 and reopened to the public in 2008. Audio tours are available in English, Spanish, and French. Audio tours provide an extensive overview of the history of the building, the building's role in St. Augustine's history, and the entire antique and art collection inside. The museum is open daily The Villa Zorayda Museum contains intricate interior details, including most notably work in cast plaster with ground alabaster matching that of

SECTION 10

#1732776783393

996-463: A key to defining a substance as a mineral. A 2011 article defined icosahedrite , an aluminium-iron-copper alloy, as a mineral; named for its unique natural icosahedral symmetry , it is a quasicrystal . Unlike a true crystal, quasicrystals are ordered but not periodic. A rock is an aggregate of one or more minerals or mineraloids. Some rocks, such as limestone or quartzite , are composed primarily of one mineral – calcite or aragonite in

1079-409: A mineral defines how much it can resist scratching or indentation. This physical property is controlled by the chemical composition and crystalline structure of a mineral. The most commonly used scale of measurement is the ordinal Mohs hardness scale, which measures resistance to scratching. Defined by ten indicators, a mineral with a higher index scratches those below it. The scale ranges from talc,

1162-432: A sedimentary mineral, and silicic acid ): Under low-grade metamorphic conditions, kaolinite reacts with quartz to form pyrophyllite (Al 2 Si 4 O 10 (OH) 2 ): As metamorphic grade increases, the pyrophyllite reacts to form kyanite and quartz: Alternatively, a mineral may change its crystal structure as a consequence of changes in temperature and pressure without reacting. For example, quartz will change into

1245-406: A tetrahedral fashion; on the other hand, graphite is composed of sheets of carbons in sp hybrid orbitals, where each carbon is bonded covalently to only three others. These sheets are held together by much weaker van der Waals forces , and this discrepancy translates to large macroscopic differences. Twinning is the intergrowth of two or more crystals of a single mineral species. The geometry of

1328-935: A variety of its SiO 2 polymorphs , such as tridymite and cristobalite at high temperatures, and coesite at high pressures. Classifying minerals ranges from simple to difficult. A mineral can be identified by several physical properties, some of them being sufficient for full identification without equivocation. In other cases, minerals can only be classified by more complex optical , chemical or X-ray diffraction analysis; these methods, however, can be costly and time-consuming. Physical properties applied for classification include crystal structure and habit, hardness, lustre, diaphaneity, colour, streak, cleavage and fracture, and specific gravity. Other less general tests include fluorescence , phosphorescence , magnetism , radioactivity , tenacity (response to mechanical induced changes of shape or form), piezoelectricity and reactivity to dilute acids . Crystal structure results from

1411-502: A variety of minerals because of the need to balance charges. Because the eight most common elements make up over 98% of the Earth's crust, the small quantities of the other elements that are typically present are substituted into the common rock-forming minerals. The distinctive minerals of most elements are quite rare, being found only where these elements have been concentrated by geological processes, such as hydrothermal circulation , to

1494-595: A white mica, can be used for windows (sometimes referred to as isinglass), as a filler, or as an insulator. Ores are minerals that have a high concentration of a certain element, typically a metal. Examples are cinnabar (HgS), an ore of mercury; sphalerite (ZnS), an ore of zinc; cassiterite (SnO 2 ), an ore of tin; and colemanite , an ore of boron . Gems are minerals with an ornamental value, and are distinguished from non-gems by their beauty, durability, and usually, rarity. There are about 20 mineral species that qualify as gem minerals, which constitute about 35 of

1577-707: Is a sedimentary rock composed primarily of organically derived carbon. In rocks, some mineral species and groups are much more abundant than others; these are termed the rock-forming minerals. The major examples of these are quartz, the feldspars , the micas , the amphiboles , the pyroxenes , the olivines , and calcite; except for the last one, all of these minerals are silicates. Overall, around 150 minerals are considered particularly important, whether in terms of their abundance or aesthetic value in terms of collecting. Commercially valuable minerals and rocks, other than gemstones, metal ores, or mineral fuels, are referred to as industrial minerals . For example, muscovite ,

1660-487: Is classified as a biosparite (fossiliferous limestone) according to the Folk classification of sedimentary rocks . Coquinas accumulate in high-energy marine and lacustrine environments where currents and waves result in the vigorous winnowing, abrasion, fracturing, and sorting of the shells that compose them. As a result, they typically exhibit well-developed bedding or cross-bedding , close packing, and good orientation of

1743-428: Is distinct from rock , which is any bulk solid geologic material that is relatively homogeneous at a large enough scale. A rock may consist of one type of mineral or may be an aggregate of two or more different types of minerals, spacially segregated into distinct phases . Some natural solid substances without a definite crystalline structure, such as opal or obsidian , are more properly called mineraloids . If

SECTION 20

#1732776783393

1826-448: Is in octahedral coordination. Other examples are the aluminosilicates kyanite , andalusite , and sillimanite (polymorphs, since they share the formula Al 2 SiO 5 ), which differ by the coordination number of the Al ; these minerals transition from one another as a response to changes in pressure and temperature. In the case of silicate materials, the substitution of Si by Al allows for

1909-677: Is located in New Hanover County , near Fort Fisher , along the southern tip of North Carolina's coast. It is one of the few naturally occurring outcrops in the coastal plain region of North Carolina, described as “a low-relief plain underlain by beds of shallow-marine, estuarine, shoreline, and fluvial sediments" in The Geology of the Carolinas . These sediments were deposited during numerous episodes of sea level rise and fall over hundreds of thousands of years. The coastlines of

1992-408: Is possible for one element to be substituted for another. Chemical substitution will occur between ions of a similar size and charge; for example, K will not substitute for Si because of chemical and structural incompatibilities caused by a big difference in size and charge. A common example of chemical substitution is that of Si by Al , which are close in charge, size, and abundance in the crust. In

2075-470: Is possible for two rocks to have an identical or a very similar bulk rock chemistry without having a similar mineralogy. This process of mineralogical alteration is related to the rock cycle . An example of a series of mineral reactions is illustrated as follows. Orthoclase feldspar (KAlSi 3 O 8 ) is a mineral commonly found in granite , a plutonic igneous rock . When exposed to weathering, it reacts to form kaolinite (Al 2 Si 2 O 5 (OH) 4 ,

2158-524: Is the angle opposite the a-axis, viz. the angle between the b and c axes): The hexagonal crystal family is also split into two crystal systems  – the trigonal , which has a three-fold axis of symmetry, and the hexagonal, which has a six-fold axis of symmetry. Chemistry and crystal structure together define a mineral. With a restriction to 32 point groups, minerals of different chemistry may have identical crystal structure. For example, halite (NaCl), galena (PbS), and periclase (MgO) all belong to

2241-405: Is the hardest natural substance, has an adamantine lustre, and belongs to the isometric crystal family, whereas graphite is very soft, has a greasy lustre, and crystallises in the hexagonal family. This difference is accounted for by differences in bonding. In diamond, the carbons are in sp hybrid orbitals, which means they form a framework where each carbon is covalently bonded to four neighbours in

2324-456: Is typical of garnet, prismatic (elongated in one direction), and tabular, which differs from bladed habit in that the former is platy whereas the latter has a defined elongation. Related to crystal form, the quality of crystal faces is diagnostic of some minerals, especially with a petrographic microscope. Euhedral crystals have a defined external shape, while anhedral crystals do not; those intermediate forms are termed subhedral. The hardness of

2407-738: The Atlantic Coastal Ridge , a Pleistocene barrier island chain that extends from Duval County to Dade County . Other coquina deposits are found in the state, but only in limited areas. The Anastasia Formation is naturally exposed in a number of places along the east coast including Washington Oaks Gardens State Park , Gilbert's Bar House of Refuge , Hutchinson Island in Martin County and Blowing Rocks Preserve , owned by The Nature Conservancy , in Martin County. Still occasionally quarried or mined , and used as

2490-654: The Baja California peninsula, including submerged "reefs". So-called coquina "reefs" occur at Punta Borrascosa, San Felipe and Coloraditos on the northeast coast of Baja California. These have been uranium-thorium dated to the Pleistocene epoch, with an age estimated at 130,000 ybp . Semi-continuous coquina outcrops have been found 13 kilometres (8.1 mi) east of Puerto Peñasco , in the shallow subtidal zone or partly submerged under intertidal sands. Other Pleistocene outcrops occur along both coastlines of

2573-618: The CIPW norm , which gives reasonable estimates for volcanic rock formed from dry magma. The chemical composition may vary between end member species of a solid solution series. For example, the plagioclase feldspars comprise a continuous series from sodium -rich end member albite (NaAlSi 3 O 8 ) to calcium -rich anorthite (CaAl 2 Si 2 O 8 ) with four recognized intermediate varieties between them (given in order from sodium- to calcium-rich): oligoclase , andesine , labradorite , and bytownite . Other examples of series include

Villa Zorayda - Misplaced Pages Continue

2656-544: The Spanish word for " cockle " and "shellfish". For a sediment to be considered to be a coquina, the particles composing it should average 2 mm (0.079 in) or greater in size. Coquina can vary in hardness from poorly to moderately cemented . Incompletely consolidated and poorly cemented coquinas are considered grainstones in the Dunham classification system for carbonate sedimentary rocks. A well-cemented coquina

2739-539: The Tidewater region of North Carolina change constantly in response to wind and wave action, sedimentary deposition, tidal movements, and changes in sea level. Although the inner coastal plain is considered to be more stable, the coastal plain was inundated by repeated marine transgressions due to fluctuating sea levels during the late Pliocene and early Pleistocene. Historical records and extant buildings, foundations, basements, and retaining walls indicate that coquina

2822-496: The hydrosphere , atmosphere , and biosphere . The group's scope includes mineral-forming microorganisms, which exist on nearly every rock, soil, and particle surface spanning the globe to depths of at least 1600 metres below the sea floor and 70 kilometres into the stratosphere (possibly entering the mesosphere ). Biogeochemical cycles have contributed to the formation of minerals for billions of years. Microorganisms can precipitate metals from solution , contributing to

2905-473: The olivine group . Besides the essential chemical composition and crystal structure, the description of a mineral species usually includes its common physical properties such as habit , hardness , lustre , diaphaneity , colour, streak , tenacity , cleavage , fracture , parting, specific gravity , magnetism , fluorescence , radioactivity , as well as its taste or smell and its reaction to acid . Minerals are classified by key chemical constituents;

2988-478: The 1930s, large-scale mining of coquina for use in highway construction began at Fort Fisher in North Carolina. Large pieces of coquina of unusual shape are sometimes used as landscape decoration. Because coquina often includes a component of phosphate , it is sometimes mined for use as fertilizer . Mineral In geology and mineralogy , a mineral or mineral species is, broadly speaking,

3071-455: The 78 mineral classes listed in the Dana classification scheme. Skinner's (2005) definition of a mineral takes this matter into account by stating that a mineral can be crystalline or amorphous. Although biominerals are not the most common form of minerals, they help to define the limits of what constitutes a mineral proper. Nickel's (1995) formal definition explicitly mentioned crystallinity as

3154-853: The Alhambra Palace in Granada, Spain. These alabaster and plaster reliefs are referred to as traceries or arabesques and are replicas of walls in the Alhambra Palace. The saying, "There is no conqueror but God", the same phrase reproduced in the tracery of the Alhambra, is inscribed in Arabic script above the front entrance. The architecture of the building is accompanied by fine detail including hand painted wood panels and tiles, intricately designed fireplaces and doorways, and geometrically shaped windows and stained glass. The collection also includes hand-pierced brass lamps from Damascus and other parts of

3237-761: The Barremian and Aptian sag phase of the continental crust subsidence. Coquina deposits in Florida occur mostly along the eastern coast of the peninsula. This coquina is named the Anastasia Formation after Anastasia Island , where the Spanish quarried the rock to construct the Castillo de San Marcos , the fortress they built to defend St. Augustine . The Anastasia Formation stretches from just north of St. Augustine in St. Johns County to southern Palm Beach County . The formation and associated sand form part of

3320-591: The Cape Fear". Sprunt compared Sedgeley Abbey in dimensions and appearance to the two-story, cellared, Governor Dudley mansion that still stands in Wilmington . Like many southern plantations, Sedgeley Abbey was abandoned after the Civil War . The vacant house was demolished in the 1870s and the coquina rubble was burned and spread on the fields as fertilizer. A cellar eight feet deep carved into solid coquina

3403-474: The IMA recognizes 6,100 official mineral species. The chemical composition of a named mineral species may vary somewhat due to the inclusion of small amounts of impurities. Specific varieties of a species sometimes have conventional or official names of their own. For example, amethyst is a purple variety of the mineral species quartz . Some mineral species can have variable proportions of two or more chemical elements that occupy equivalent positions in

Villa Zorayda - Misplaced Pages Continue

3486-431: The IMA's decision to exclude biogenic crystalline substances. For example, Lowenstam (1981) stated that "organisms are capable of forming a diverse array of minerals, some of which cannot be formed inorganically in the biosphere." Skinner (2005) views all solids as potential minerals and includes biominerals in the mineral kingdom, which are those that are created by the metabolic activities of organisms. Skinner expanded

3569-455: The IMA. They are most commonly named after a person , followed by discovery location; names based on chemical composition or physical properties are the two other major groups of mineral name etymologies. Most names end in "-ite"; the exceptions are usually names that were well-established before the organization of mineralogy as a discipline, for example galena and diamond . A topic of contention among geologists and mineralogists has been

3652-755: The Late Barremian to Early Aptian, and the younger rift/sag microbial limestones deposited during the Aptian, just before the establishment of the major evaporitic sag basin between South America and Africa." There are abundant beds of coquina in the Outer High of the Santos Basin , similar to those from the neighboring Campos. Pre-salt stratigraphy of the Santos Basin shows lacustrine sediments composed of coarse pelecypod (bivalve) coquina during

3735-556: The Latin species , "a particular sort, kind, or type with distinct look, or appearance". The abundance and diversity of minerals is controlled directly by their chemistry, in turn dependent on elemental abundances in the Earth. The majority of minerals observed are derived from the Earth's crust . Eight elements account for most of the key components of minerals, due to their abundance in the crust. These eight elements, summing to over 98% of

3818-466: The Middle East, Oriental rugs, sculptures, carved furniture, decorative tiles, and Egyptian artifacts. Coquina Coquina ( / k oʊ ˈ k iː n ə / ) is a sedimentary rock that is composed either wholly or almost entirely of the transported, abraded, and mechanically sorted fragments of mollusks , trilobites , brachiopods , or other invertebrates . The term coquina comes from

3901-581: The Pampo and Linguado Fields in 1978. The coquinas of the Morro do Chaves Formation were formed by non-marine bivalves and ostracods . The shells of the bivalves, which lived in shallow oxygenated water, were transported and deposited as washout over stream fans and beaches by storms and long-shore drift . The palynological record of coquinas of the Sergipe-Alagoas Basin has been analyzed and

3984-488: The aluminium abundance is unusually high, the excess aluminium will form muscovite or other aluminium-rich minerals. If silicon is deficient, part of the feldspar will be replaced by feldspathoid minerals. Precise predictions of which minerals will be present in a rock of a particular composition formed at a particular temperature and pressure requires complex thermodynamic calculations. However, approximate estimates may be made using relatively simple rules of thumb , such as

4067-449: The bulk chemistry of the parent body. For example, in most igneous rocks, the aluminium and alkali metals (sodium and potassium) that are present are primarily found in combination with oxygen, silicon, and calcium as feldspar minerals. However, if the rock is unusually rich in alkali metals, there will not be enough aluminium to combine with all the sodium as feldspar, and the excess sodium will form sodic amphiboles such as riebeckite . If

4150-424: The case of limestone, and quartz in the latter case. Other rocks can be defined by relative abundances of key (essential) minerals; a granite is defined by proportions of quartz, alkali feldspar , and plagioclase feldspar . The other minerals in the rock are termed accessory minerals , and do not greatly affect the bulk composition of the rock. Rocks can also be composed entirely of non-mineral material; coal

4233-543: The coast of northeastern Brazil hold coquina reservoirs of oil. The coquinas are generally heterogeneous in their porosity and permeability, but like other lacustrine carbonates, they are uncommonly reservoirs. Corbett et al. (2015) in their discussion of the reservoirs say the finding of the Badejo Field ( Campos Basin ) in 1975 was the first hydrocarbon discovery in the coquinas of the Lagoa Feia, followed by that of

SECTION 50

#1732776783393

4316-415: The coordination of the silicate is by a number: in the case of the silica tetrahedron, the silicon is said to have a coordination number of 4. Various cations have a specific range of possible coordination numbers; for silicon, it is almost always 4, except for very high-pressure minerals where the compound is compressed such that silicon is in six-fold (octahedral) coordination with oxygen. Bigger cations have

4399-756: The course of his long life. He is buried in the Mount Auburn Cemetery in Cambridge, Massachusetts . One block east of Villa Zorayda is the largest building Smith constructed in St. Augustine, the Casa Monica Hotel (later purchased by Henry Flagler and renamed the Cordova Hotel). In addition to its intended purpose as a private residence, the Villa Zorayda has been used as a restaurant, a nightclub and gambling casino, and

4482-417: The crust by weight, are, in order of decreasing abundance: oxygen , silicon , aluminium , iron , magnesium , calcium , sodium and potassium . Oxygen and silicon are by far the two most important – oxygen composes 47% of the crust by weight, and silicon accounts for 28%. The minerals that form are those that are most stable at the temperature and pressure of formation, within the limits imposed by

4565-434: The difference in charge has to accounted for by making a second substitution of Si by Al . Coordination polyhedra are geometric representations of how a cation is surrounded by an anion. In mineralogy, coordination polyhedra are usually considered in terms of oxygen, due its abundance in the crust. The base unit of silicate minerals is the silica tetrahedron – one Si surrounded by four O . An alternate way of describing

4648-414: The dipyramidal point group. These differences arise corresponding to how aluminium is coordinated within the crystal structure. In all minerals, one aluminium ion is always in six-fold coordination with oxygen. Silicon, as a general rule, is in four-fold coordination in all minerals; an exception is a case like stishovite (SiO 2 , an ultra-high pressure quartz polymorph with rutile structure). In kyanite,

4731-528: The discovery of the Lula Field by Petrobras and partners in 2006 opened petroleum exploration in the Barremian/ Aptian pre-salt play in the offshore Santos and Campos basins, and consequently deeper coquina reservoirs have become important targets. He says the two main reservoir targets recognized for the pre-salt within the study areas are: "late rift coquinas, lacustrine facies deposited at

4814-517: The example of plagioclase, there are three cases of substitution. Feldspars are all framework silicates, which have a silicon-oxygen ratio of 2:1, and the space for other elements is given by the substitution of Si by Al to give a base unit of [AlSi 3 O 8 ] ; without the substitution, the formula would be charge-balanced as SiO 2 , giving quartz. The significance of this structural property will be explained further by coordination polyhedra. The second substitution occurs between Na and Ca ; however,

4897-778: The formation of ore deposits. They can also catalyze the dissolution of minerals. Prior to the International Mineralogical Association's listing, over 60 biominerals had been discovered, named, and published. These minerals (a sub-set tabulated in Lowenstam (1981) ) are considered minerals proper according to Skinner's (2005) definition. These biominerals are not listed in the International Mineral Association official list of mineral names; however, many of these biomineral representatives are distributed amongst

4980-410: The generic AX 2 formula; these two groups are collectively known as the pyrite and marcasite groups. Polymorphism can extend beyond pure symmetry content. The aluminosilicates are a group of three minerals – kyanite , andalusite , and sillimanite  – which share the chemical formula Al 2 SiO 5 . Kyanite is triclinic, while andalusite and sillimanite are both orthorhombic and belong to

5063-451: The hexaoctahedral point group (isometric family), as they have a similar stoichiometry between their different constituent elements. In contrast, polymorphs are groupings of minerals that share a chemical formula but have a different structure. For example, pyrite and marcasite , both iron sulfides, have the formula FeS 2 ; however, the former is isometric while the latter is orthorhombic. This polymorphism extends to other sulfides with

SECTION 60

#1732776783393

5146-461: The material to be a stable or metastable solid at room temperature (25 °C). However, the IMA only requires that the substance be stable enough for its structure and composition to be well-determined. For example, it has recently recognized meridianiite (a naturally occurring hydrate of magnesium sulfate ) as a mineral, even though it is formed and stable only below 2 °C. As of November 2024 , 6,100 mineral species are approved by

5229-433: The mineral's structure; for example, the formula of mackinawite is given as (Fe,Ni) 9 S 8 , meaning Fe x Ni 9- x S 8 , where x is a variable number between 0 and 9. Sometimes a mineral with variable composition is split into separate species, more or less arbitrarily, forming a mineral group ; that is the case of the silicates Ca x Mg y Fe 2- x - y SiO 4 ,

5312-494: The most common gemstones. Gem minerals are often present in several varieties, and so one mineral can account for several different gemstones; for example, ruby and sapphire are both corundum , Al 2 O 3 . The first known use of the word "mineral" in the English language ( Middle English ) was the 15th century. The word came from Medieval Latin : minerale , from minera , mine, ore. The word "species" comes from

5395-428: The most encompassing of these being the six crystal families. These families can be described by the relative lengths of the three crystallographic axes, and the angles between them; these relationships correspond to the symmetry operations that define the narrower point groups. They are summarized below; a, b, and c represent the axes, and α, β, γ represent the angle opposite the respective crystallographic axis (e.g. α

5478-402: The olivine series of magnesium-rich forsterite and iron-rich fayalite, and the wolframite series of manganese -rich hübnerite and iron-rich ferberite . Chemical substitution and coordination polyhedra explain this common feature of minerals. In nature, minerals are not pure substances, and are contaminated by whatever other elements are present in the given chemical system. As a result, it

5561-622: The orderly geometric spatial arrangement of atoms in the internal structure of a mineral. This crystal structure is based on regular internal atomic or ionic arrangement that is often expressed in the geometric form that the crystal takes. Even when the mineral grains are too small to see or are irregularly shaped, the underlying crystal structure is always periodic and can be determined by X-ray diffraction. Minerals are typically described by their symmetry content. Crystals are restricted to 32 point groups , which differ by their symmetry. These groups are classified in turn into more broad categories,

5644-563: The point where they can no longer be accommodated in common minerals. Changes in temperature and pressure and composition alter the mineralogy of a rock sample. Changes in composition can be caused by processes such as weathering or metasomatism ( hydrothermal alteration ). Changes in temperature and pressure occur when the host rock undergoes tectonic or magmatic movement into differing physical regimes. Changes in thermodynamic conditions make it favourable for mineral assemblages to react with each other to produce new minerals; as such, it

5727-498: The porous coquina was protected by lime plaster. With the exception of a few residences that have been restored in St. Augustine, the coquina masonry of these structures is today exposed to the elements and is slowly deteriorating. Overlying the fossiliferous sands and sandy clays of the upper San Fernando River in northeastern Mexico is a bed of coquina limestone dating probably to the Cenozoic era. Coquina deposits also occur in

5810-447: The presence of repetitive twinning; however, instead of occurring around a rotational axis, polysynthetic twinning occurs along parallel planes, usually on a microscopic scale. Crystal habit refers to the overall shape of crystal. Several terms are used to describe this property. Common habits include acicular, which describes needlelike crystals as in natrolite , bladed, dendritic (tree-pattern, common in native copper ), equant, which

5893-568: The previous definition of a mineral to classify "element or compound, amorphous or crystalline, formed through biogeochemical processes," as a mineral. Recent advances in high-resolution genetics and X-ray absorption spectroscopy are providing revelations on the biogeochemical relations between microorganisms and minerals that may shed new light on this question. For example, the IMA-commissioned "Working Group on Environmental Mineralogy and Geochemistry " deals with minerals in

5976-485: The second aluminium is in six-fold coordination; its chemical formula can be expressed as Al Al SiO 5 , to reflect its crystal structure. Andalusite has the second aluminium in five-fold coordination (Al Al SiO 5 ) and sillimanite has it in four-fold coordination (Al Al SiO 5 ). Differences in crystal structure and chemistry greatly influence other physical properties of the mineral. The carbon allotropes diamond and graphite have vastly different properties; diamond

6059-570: The sediments dated to the late Barremian age ; the results suggest a marine and/or brackish environment. Daniel Thompson (2013) asserts that the coquinas of the Morro do Chaves Formation include a wide range of marine mollusca characteristic of brackish environmental conditions, suggesting periodic marine ingression during the Early Cretaceous . According to a paper by Senira Kattah published in The Sedimentary Record ,

6142-470: The shell fragments. The high-energy marine or lacustrine environments associated with coquinas include beaches, shallow submarine raised banks, swift tidal channels, and barrier bars. Coquina is composed mainly of the mineral calcite , often including some phosphate , in the form of seashells or coral . Coquinas dating from the Devonian period through to the much more recent Pleistocene epoch are

6225-610: The south in New Smyrna , a large storehouse and wharf were constructed of coquina at the 1770s Andrew Turnbull colony. Around 1816, John Addison constructed a kitchen house of coquina on his plantation on the Tomoka River . The material was also used in the construction of sugar mill buildings on sugar plantations in the 1820s and 1830s. Examples are the Bulow , Dunlawton and New Smyrna sugar mills. In these early structures,

6308-478: The stone is also at first much too soft to be used for building. In order to be used as a building material, the stone is left out to dry for approximately one to three years, which causes the stone to harden into a usable, but still comparatively soft, form. Coquina has also been used as a source of paving material. It is usually poorly cemented and easily breaks into component shell or coral fragments, which can be substituted for gravel or crushed harder rocks . In

6391-439: The twinning is controlled by the mineral's symmetry. As a result, there are several types of twins, including contact twins, reticulated twins, geniculated twins, penetration twins, cyclic twins, and polysynthetic twins. Contact, or simple twins, consist of two crystals joined at a plane; this type of twinning is common in spinel. Reticulated twins, common in rutile, are interlocking crystals resembling netting. Geniculated twins have

6474-472: The two dominant systems are the Dana classification and the Strunz classification. Silicate minerals comprise approximately 90% of the Earth's crust . Other important mineral groups include the native elements , sulfides , oxides , halides , carbonates , sulfates , and phosphates . The International Mineralogical Association has established the following requirements for a substance to be considered

6557-600: The upper Gulf of California . On the Vizcaino Peninsula of western Baja California, the informally named " Tivela stultorum " coquina is abundant in shells of the Pismo clam. Until analysis of the shells by U-series and amino-acids methods is concluded, this marine transgression is assigned an approximate age of 200,000 ybp. Outcrops in Bahía de San Hipolito and Bahía de Asunción are loosely consolidated, sandy beachrock

6640-470: Was being mined in North Carolina by at least 1760, evidenced by the extant architectural ruins at the colonial-era Clear Springs Plantation near New Bern . Sedgeley Abbey , an 18th-century plantation house on the lower Cape Fear River was built of locally quarried coquina. The house that once stood on a vast tract of land directly across the river from Orton was described by local historian and author James Sprunt as "the grandest colonial residence of

6723-524: Was located during archaeological investigations on the site of the former plantation in 1978. In the past coquina was used for the construction of buildings in Denham, Western Australia , but quarrying is no longer permitted in the World Heritage Site . When first quarried, coquina is extremely soft. This softness makes it very easy to remove from the quarry and cut into shape. However,

6806-728: Was quarried and cut into blocks used in local construction. St Andrew's Anglican Church, the Old Pearler Restaurant, and parts of the Shark Bay Hotel in Shark Bay were built from coquina shell blocks. The church, built in 1954, has walls infilled with coquina shell blocks between a light steel frame and a shell facing, while the Old Pearler was built in 1974–1977 with buttressed coquina shell block walls. Recently discovered petroleum-bearing formations off

6889-515: Was used as building stone in St. Augustine as early as 1598 for construction of a powder house. This was the beginning of a building tradition that extended into the 1930s along Florida's Atlantic Coast. In the St. Augustine vicinity, the Castillo de San Marcos, Fort Matanzas , the old city gates, the Cathedral , Spanish and British Period residential structures, property line walls and tombs were constructed of coquina quarried on Anastasia Island. To

#392607