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122-605: Chimney Tops is one of the few instances of a bare rock summit in the Smokies. The rock atop the mountain has been exposed to natural weathering . The bedrock is mostly Anakeesta Formation metamorphic rock , especially slate , phyllite , and metasiltstone . It was formed 200 million years ago when the North American and African plates collided during the Appalachian orogeny . The Cherokee name for Chimney Tops

244-424: A mean prokaryotic density of roughly 10 organisms per gram, whereas the ocean has no more than 10 prokaryotic organisms per milliliter (gram) of seawater. Organic carbon held in soil is eventually returned to the atmosphere through the process of respiration carried out by heterotrophic organisms, but a substantial part is retained in the soil in the form of soil organic matter; tillage usually increases

366-588: A dissected limestone pavement . This process is most effective along the joints, widening and deepening them. In unpolluted environments, the pH of rainwater due to dissolved carbon dioxide is around 5.6. Acid rain occurs when gases such as sulfur dioxide and nitrogen oxides are present in the atmosphere. These oxides react in the rain water to produce stronger acids and can lower the pH to 4.5 or even 3.0. Sulfur dioxide , SO 2 , comes from volcanic eruptions or from fossil fuels, and can become sulfuric acid within rainwater, which can cause solution weathering to

488-594: A habitat for soil organisms , a recycling system for nutrients and organic wastes , a regulator of water quality , a modifier of atmospheric composition , and a medium for plant growth , making it a critically important provider of ecosystem services . Since soil has a tremendous range of available niches and habitats , it contains a prominent part of the Earth's genetic diversity . A gram of soil can contain billions of organisms, belonging to thousands of species, mostly microbial and largely still unexplored. Soil has

610-691: A mineral crystal exposes ions whose electrical charge attracts water molecules. Some of these molecules break into H+ that bonds to exposed anions (usually oxygen) and OH- that bonds to exposed cations. This further disrupts the surface, making it susceptible to various hydrolysis reactions. Additional protons replace cations exposed on the surface, freeing the cations as solutes. As cations are removed, silicon-oxygen and silicon-aluminium bonds become more susceptible to hydrolysis, freeing silicic acid and aluminium hydroxides to be leached away or to form clay minerals. Laboratory experiments show that weathering of feldspar crystals begins at dislocations or other defects on

732-418: A more humid chemical microenvironment. The attachment of these organisms to the rock surface enhances physical as well as chemical breakdown of the surface microlayer of the rock. Lichens have been observed to pry mineral grains loose from bare shale with their hyphae (rootlike attachment structures), a process described as plucking , and to pull the fragments into their body, where the fragments then undergo

854-549: A pH of 9, plant growth is reduced. High pH results in low micro-nutrient mobility, but water-soluble chelates of those nutrients can correct the deficit. Sodium can be reduced by the addition of gypsum (calcium sulphate) as calcium adheres to clay more tightly than does sodium causing sodium to be pushed into the soil water solution where it can be washed out by an abundance of water. There are acid-forming cations (e.g. hydronium, aluminium, iron) and there are base-forming cations (e.g. calcium, magnesium, sodium). The fraction of

976-403: A process of chemical weathering not unlike digestion. On a larger scale, seedlings sprouting in a crevice and plant roots exert physical pressure as well as providing a pathway for water and chemical infiltration. Most rock forms at elevated temperature and pressure, and the minerals making up the rock are often chemically unstable in the relatively cool, wet, and oxidizing conditions typical of

1098-687: A reduction in the other. The pore space allows for the infiltration and movement of air and water, both of which are critical for life existing in soil. Compaction , a common problem with soils, reduces this space, preventing air and water from reaching plant roots and soil organisms. Given sufficient time, an undifferentiated soil will evolve a soil profile that consists of two or more layers, referred to as soil horizons. These differ in one or more properties such as in their texture , structure , density , porosity, consistency, temperature, color, and reactivity . The horizons differ greatly in thickness and generally lack sharp boundaries; their development

1220-731: A result of a trade-off between toxicity and requirement most nutrients are better available to plants at moderate pH, although most minerals are more soluble in acid soils. Soil organisms are hindered by high acidity, and most agricultural crops do best with mineral soils of pH 6.5 and organic soils of pH 5.5. Given that at low pH toxic metals (e.g. cadmium, zinc, lead) are positively charged as cations and organic pollutants are in non-ionic form, thus both made more available to organisms, it has been suggested that plants, animals and microbes commonly living in acid soils are pre-adapted to every kind of pollution, whether of natural or human origin. In high rainfall areas, soils tend to acidify as

1342-401: A result, layers (horizons) form in the soil profile. The alteration and movement of materials within a soil causes the formation of distinctive soil horizons . However, more recent definitions of soil embrace soils without any organic matter, such as those regoliths that formed on Mars and analogous conditions in planet Earth deserts. An example of the development of a soil would begin with

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1464-477: A result, thermal stress weathering is sometimes called insolation weathering , but this is misleading. Thermal stress weathering can be caused by any large change of temperature, and not just intense solar heating. It is likely as important in cold climates as in hot, arid climates. Wildfires can also be a significant cause of rapid thermal stress weathering. The importance of thermal stress weathering has long been discounted by geologists, based on experiments in

1586-408: A silt loam soil by percent volume A typical soil is about 50% solids (45% mineral and 5% organic matter), and 50% voids (or pores) of which half is occupied by water and half by gas. The percent soil mineral and organic content can be treated as a constant (in the short term), while the percent soil water and gas content is considered highly variable whereby a rise in one is simultaneously balanced by

1708-407: A slower reaction kinetics , this process is thermodynamically favored at low temperature, because colder water holds more dissolved carbon dioxide gas (due to the retrograde solubility of gases). Carbonate dissolution is therefore an important feature of glacial weathering. Carbonate dissolution involves the following steps: Carbonate dissolution on the surface of well-jointed limestone produces

1830-412: A soil can be said to be developed, and can be described further in terms of color, porosity, consistency, reaction ( acidity ), etc. Water is a critical agent in soil development due to its involvement in the dissolution, precipitation, erosion, transport, and deposition of the materials of which a soil is composed. The mixture of water and dissolved or suspended materials that occupy the soil pore space

1952-399: A soil determines its ability to supply available plant nutrients and affects its physical properties and the health of its living population. In addition, a soil's chemistry also determines its corrosivity , stability, and ability to absorb pollutants and to filter water. It is the surface chemistry of mineral and organic colloids that determines soil's chemical properties. A colloid

2074-469: A threat to the environment and occupant safety. Design strategies can moderate the impact of environmental effects, such as using of pressure-moderated rain screening, ensuring that the HVAC system is able to effectively control humidity accumulation and selecting concrete mixes with reduced water content to minimize the impact of freeze-thaw cycles. Granitic rock, the most abundant crystalline rock exposed at

2196-472: A valence of two, converts to (40 ÷ 2) × 1 milliequivalent = 20 milliequivalents of hydrogen ion per 100 grams of dry soil or 20 meq/100 g. The modern measure of CEC is expressed as centimoles of positive charge per kilogram (cmol/kg) of oven-dry soil. Most of the soil's CEC occurs on clay and humus colloids, and the lack of those in hot, humid, wet climates (such as tropical rainforests ), due to leaching and decomposition, respectively, explains

2318-535: Is Duniskwalgunyi , or "forked antler", referring to its resemblance to the deer antlers. In the Cherokee legend "Aganunitsi and the Uktena", the captured medicine man, Aganunitsi, in order to free himself, searches remote parts of the Smokies to find the giant reptile, the Uktena, and seize an amulet from its forehead. In his quest, Aganunitsi searches distant gaps and peaks in the Smokies before going to Duniskwalgunyi,

2440-426: Is acid hydrolysis , in which protons (hydrogen ions), which are present in acidic water, attack chemical bonds in mineral crystals. The bonds between different cations and oxygen ions in minerals differ in strength, and the weakest will be attacked first. The result is that minerals in igneous rock weather in roughly the same order in which they were originally formed ( Bowen's Reaction Series ). Relative bond strength

2562-553: Is 0.04%, but in the soil pore space it may range from 10 to 100 times that level, thus potentially contributing to the inhibition of root respiration. Calcareous soils regulate CO 2 concentration by carbonate buffering , contrary to acid soils in which all CO 2 respired accumulates in the soil pore system. At extreme levels, CO 2 is toxic. This suggests a possible negative feedback control of soil CO 2 concentration through its inhibitory effects on root and microbial respiration (also called soil respiration ). In addition,

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2684-550: Is 14 megapascals (2,000 psi). This is still much greater than the tensile strength of granite, which is about 4 megapascals (580 psi). This makes frost wedging, in which pore water freezes and its volumetric expansion fractures the enclosing rock, appear to be a plausible mechanism for frost weathering. Ice will simply expand out of a straight open fracture before it can generate significant pressure. Thus, frost wedging can only take place in small tortuous fractures. The rock must also be almost completely saturated with water, or

2806-403: Is a less well characterized mechanism of physical weathering. It takes place because ice grains always have a surface layer, often just a few molecules thick, that resembles liquid water more than solid ice, even at temperatures well below the freezing point. This premelted liquid layer has unusual properties, including a strong tendency to draw in water by capillary action from warmer parts of

2928-603: Is a measure of the acidity or alkalinity of the soil. More precisely, it is a measure of hydronium concentration in an aqueous solution and ranges in values from 0 to 14 (acidic to basic) but practically speaking for soils, pH ranges from 3.5 to 9.5, as pH values beyond those extremes are toxic to life forms. At 25 °C an aqueous solution that has a pH of 3.5 has 10 moles H 3 O (hydronium ions) per litre of solution (and also 10 moles per litre OH ). A pH of 7, defined as neutral, has 10 moles of hydronium ions per litre of solution and also 10 moles of OH per litre; since

3050-509: Is a small, insoluble particle ranging in size from 1 nanometer to 1 micrometer , thus small enough to remain suspended by Brownian motion in a fluid medium without settling. Most soils contain organic colloidal particles called humus as well as the inorganic colloidal particles of clays . The very high specific surface area of colloids and their net electrical charges give soil its ability to hold and release ions . Negatively charged sites on colloids attract and release cations in what

3172-424: Is also a net sink of methane (CH 4 ) but a net producer of methane (a strong heat-absorbing greenhouse gas ) when soils are depleted of oxygen and subject to elevated temperatures. Soil atmosphere is also the seat of emissions of volatiles other than carbon and nitrogen oxides from various soil organisms, e.g. roots, bacteria, fungi, animals. These volatiles are used as chemical cues, making soil atmosphere

3294-440: Is also important, acting to oxidize many minerals, as is carbon dioxide, whose weathering reactions are described as carbonation . The process of mountain block uplift is important in exposing new rock strata to the atmosphere and moisture, enabling important chemical weathering to occur; significant release occurs of Ca and other ions into surface waters. Dissolution (also called simple solution or congruent dissolution )

3416-715: Is also known as sheeting . As with thermal weathering, pressure release is most effective in buttressed rock. Here the differential stress directed toward the unbuttressed surface can be as high as 35 megapascals (5,100 psi), easily enough to shatter rock. This mechanism is also responsible for spalling in mines and quarries, and for the formation of joints in rock outcrops. Retreat of an overlying glacier can also lead to exfoliation due to pressure release. This can be enhanced by other physical wearing mechanisms. Salt crystallization (also known as salt weathering , salt wedging or haloclasty ) causes disintegration of rocks when saline solutions seep into cracks and joints in

3538-464: Is assumed acid-forming cations). Base saturation is almost in direct proportion to pH (it increases with increasing pH). It is of use in calculating the amount of lime needed to neutralise an acid soil (lime requirement). The amount of lime needed to neutralize a soil must take account of the amount of acid forming ions on the colloids (exchangeable acidity), not just those in the soil water solution (free acidity). The addition of enough lime to neutralize

3660-401: Is called the soil solution. Since soil water is never pure water, but contains hundreds of dissolved organic and mineral substances, it may be more accurately called the soil solution. Water is central to the dissolution , precipitation and leaching of minerals from the soil profile . Finally, water affects the type of vegetation that grows in a soil, which in turn affects the development of

3782-612: Is chemically weathered to iron(II) sulfate and gypsum , which then crystallize as salt lenses. Salt crystallization can take place wherever salts are concentrated by evaporation. It is thus most common in arid climates where strong heating causes strong evaporation and along coasts. Salt weathering is likely important in the formation of tafoni , a class of cavernous rock weathering structures. Living organisms may contribute to mechanical weathering, as well as chemical weathering (see § Biological weathering below). Lichens and mosses grow on essentially bare rock surfaces and create

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3904-421: Is dependent on the type of parent material , the processes that modify those parent materials, and the soil-forming factors that influence those processes. The biological influences on soil properties are strongest near the surface, though the geochemical influences on soil properties increase with depth. Mature soil profiles typically include three basic master horizons: A, B, and C. The solum normally includes

4026-469: Is highly susceptible to ultraviolet radiation from sunlight. This induces photochemical reactions that degrade its surface. These also significantly weather paint and plastics. Soil Soil , also commonly referred to as earth , is a mixture of organic matter , minerals , gases , liquids , and organisms that together support the life of plants and soil organisms . Some scientific definitions distinguish dirt from soil by restricting

4148-577: Is in equilibrium with kaolinite. Soil formation requires between 100 and 1,000 years, a brief interval in geologic time. As a result, some formations show numerous paleosol (fossil soil) beds. For example, the Willwood Formation of Wyoming contains over 1,000 paleosol layers in a 770 meters (2,530 ft) section representing 3.5 million years of geologic time. Paleosols have been identified in formations as old as Archean (over 2.5 billion years in age). They are difficult to recognize in

4270-649: Is included in the broader concept of regolith , which also includes other loose material that lies above the bedrock, as can be found on the Moon and other celestial objects . Soil is a major component of the Earth 's ecosystem . The world's ecosystems are impacted in far-reaching ways by the processes carried out in the soil, with effects ranging from ozone depletion and global warming to rainforest destruction and water pollution . With respect to Earth's carbon cycle , soil acts as an important carbon reservoir , and it

4392-401: Is induced. Capillary action is responsible for moving groundwater from wet regions of the soil to dry areas. Subirrigation designs (e.g., wicking beds , sub-irrigated planters ) rely on capillarity to supply water to plant roots. Capillary action can result in an evaporative concentration of salts, causing land degradation through salination . Soil moisture measurement —measuring

4514-531: Is likely home to 59 ± 15% of the species on Earth. Enchytraeidae (worms) have the greatest percentage of species in soil (98.6%), followed by fungi (90%), plants (85.5%), and termites ( Isoptera ) (84.2%). Many other groups of animals have substantial fractions of species living in soil, e.g. about 30% of insects , and close to 50% of arachnids . While most vertebrates live above ground (ignoring aquatic species), many species are fossorial , that is, they live in soil, such as most blind snakes . The chemistry of

4636-420: Is likely the more important mechanism in nature. Geomorphologists have begun to reemphasize the importance of thermal stress weathering, particularly in cold climates. Pressure release or unloading is a form of physical weathering seen when deeply buried rock is exhumed . Intrusive igneous rocks, such as granite , are formed deep beneath the Earth's surface. They are under tremendous pressure because of

4758-477: Is more advanced. Most plant nutrients, with the exception of nitrogen , originate from the minerals that make up the soil parent material. Some nitrogen originates from rain as dilute nitric acid and ammonia , but most of the nitrogen is available in soils as a result of nitrogen fixation by bacteria . Once in the soil-plant system, most nutrients are recycled through living organisms, plant and microbial residues (soil organic matter), mineral-bound forms, and

4880-437: Is potentially one of the most reactive to human disturbance and climate change . As the planet warms, it has been predicted that soils will add carbon dioxide to the atmosphere due to increased biological activity at higher temperatures, a positive feedback (amplification). This prediction has, however, been questioned on consideration of more recent knowledge on soil carbon turnover. Soil acts as an engineering medium,

5002-409: Is referred to as cation exchange . Cation-exchange capacity is the amount of exchangeable cations per unit weight of dry soil and is expressed in terms of milliequivalents of positively charged ions per 100 grams of soil (or centimoles of positive charge per kilogram of soil; cmol c /kg ). Similarly, positively charged sites on colloids can attract and release anions in the soil, giving

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5124-484: Is relatively poor in potassium, the basalt weathers directly to potassium-poor montmorillonite , then to kaolinite . Where leaching is continuous and intense, as in rain forests, the final weathering product is bauxite , the principal ore of aluminium. Where rainfall is intense but seasonal, as in monsoon climates, the final weathering product is iron- and titanium-rich laterite . Conversion of kaolinite to bauxite occurs only with intense leaching, as ordinary river water

5246-449: Is shown in the following table: This table is only a rough guide to order of weathering. Some minerals, such as illite , are unusually stable, while silica is unusually unstable given the strength of the silicon–oxygen bond . Carbon dioxide that dissolves in water to form carbonic acid is the most important source of protons, but organic acids are also important natural sources of acidity. Acid hydrolysis from dissolved carbon dioxide

5368-421: Is sometimes described as carbonation , and can result in weathering of the primary minerals to secondary carbonate minerals. For example, weathering of forsterite can produce magnesite instead of brucite via the reaction: Carbonic acid is consumed by silicate weathering, resulting in more alkaline solutions because of the bicarbonate . This is an important reaction in controlling the amount of CO 2 in

5490-410: Is the class of processes that causes the disintegration of rocks without chemical change. Physical weathering involves the breakdown of rocks into smaller fragments through processes such as expansion and contraction, mainly due to temperature changes. Two types of physical breakdown are freeze-thaw weathering and thermal fracturing. Pressure release can also cause weathering without temperature change. It

5612-417: Is the process in which a mineral dissolves completely without producing any new solid substance. Rainwater easily dissolves soluble minerals, such as halite or gypsum , but can also dissolve highly resistant minerals such as quartz , given sufficient time. Water breaks the bonds between atoms in the crystal: [REDACTED] The overall reaction for dissolution of quartz is The dissolved quartz takes

5734-431: Is usually much less important than chemical weathering, but can be significant in subarctic or alpine environments. Furthermore, chemical and physical weathering often go hand in hand. For example, cracks extended by physical weathering will increase the surface area exposed to chemical action, thus amplifying the rate of disintegration. Frost weathering is the most important form of physical weathering. Next in importance

5856-545: Is very little organic material. Basaltic minerals commonly weather relatively quickly, according to the Goldich dissolution series . The plants are supported by the porous rock as it is filled with nutrient-bearing water that carries minerals dissolved from the rocks. Crevasses and pockets, local topography of the rocks, would hold fine materials and harbour plant roots. The developing plant roots are associated with mineral-weathering mycorrhizal fungi that assist in breaking up

5978-426: Is wedging by plant roots, which sometimes enter cracks in rocks and pry them apart. The burrowing of worms or other animals may also help disintegrate rock, as can "plucking" by lichens. Frost weathering is the collective name for those forms of physical weathering that are caused by the formation of ice within rock outcrops. It was long believed that the most important of these is frost wedging , which results from

6100-490: The aeration of the soil and the ability of water to infiltrate and to be held within the soil. Soil water content can be measured as volume or weight . Soil moisture levels, in order of decreasing water content, are saturation, field capacity , wilting point , air dry, and oven dry. Field capacity describes a drained wet soil at the point water content reaches equilibrium with gravity. Irrigating soil above field capacity risks percolation losses. Wilting point describes

6222-444: The atmosphere , and the biosphere . Soil has four important functions : All of these functions, in their turn, modify the soil and its properties. Soil science has two basic branches of study: edaphology and pedology . Edaphology studies the influence of soils on living things. Pedology focuses on the formation, description (morphology), and classification of soils in their natural environment. In engineering terms, soil

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6344-561: The humus form ), the copedon (in intermediary position, where most weathering of minerals takes place) and the lithopedon (in contact with the subsoil). The soil texture is determined by the relative proportions of the individual particles of sand , silt , and clay that make up the soil. The interaction of the individual mineral particles with organic matter, water, gases via biotic and abiotic processes causes those particles to flocculate (stick together) to form aggregates or peds . Where these aggregates can be identified,

6466-425: The mineralogy of those particles can strongly modify those properties. The mineralogy of the finest soil particles, clay, is especially important. Large numbers of microbes , animals , plants and fungi are living in soil. However, biodiversity in soil is much harder to study as most of this life is invisible, hence estimates about soil biodiversity have been unsatisfactory. A recent study suggested that soil

6588-613: The water-holding capacity of soils is vital for plant survival. Soils can effectively remove impurities, kill disease agents, and degrade contaminants , this latter property being called natural attenuation . Typically, soils maintain a net absorption of oxygen and methane and undergo a net release of carbon dioxide and nitrous oxide . Soils offer plants physical support, air, water, temperature moderation, nutrients, and protection from toxins. Soils provide readily available nutrients to plants and animals by converting dead organic matter into various nutrient forms. Components of

6710-448: The A and B horizons. The living component of the soil is largely confined to the solum, and is generally more prominent in the A horizon. It has been suggested that the pedon , a column of soil extending vertically from the surface to the underlying parent material and large enough to show the characteristics of all its horizons, could be subdivided in the humipedon (the living part, where most soil organisms are dwelling, corresponding to

6832-516: The Chimney Tops area. The trail reopened in October 2017, with a new observation area that offers a place to view both of the bare rock points of the summit. However, the extreme heat of the fires resulted in accelerated weathering and potential mass wasting of the exposed rock, and therefore access to the summit is no longer permitted for safety reasons. Weathering Weathering is

6954-408: The Earth's surface, begins weathering with the destruction of hornblende . Biotite then weathers to vermiculite , and finally oligoclase and microcline are destroyed. All are converted into a mixture of clay minerals and iron oxides. The resulting soil is depleted in calcium, sodium, and ferrous iron compared with the bedrock, and magnesium is reduced by 40% and silicon by 15%. At the same time,

7076-411: The Earth's surface. Chemical weathering takes place when water, oxygen, carbon dioxide, and other chemical substances react with rock to change its composition. These reactions convert some of the original primary minerals in the rock to secondary minerals, remove other substances as solutes, and leave the most stable minerals as a chemically unchanged resistate . In effect, chemical weathering changes

7198-673: The Gap of the Forked Antler, and to the lake of Atagahi, and at each found monstrous reptiles. The Road Prong Trail, which follows the stream of the same name at the base of Chimney Tops, is one of the oldest trails in the Smokies. In the 18th and 19th centuries, the ancient path was known commonly as the Indian Gap Trail. In 1832, the Oconaluftee Turnpike was constructed between Indian Gap and Smokemont . The road

7320-406: The acronym CROPT. The physical properties of soils, in order of decreasing importance for ecosystem services such as crop production , are texture , structure , bulk density , porosity , consistency, temperature , colour and resistivity . Soil texture is determined by the relative proportion of the three kinds of soil mineral particles, called soil separates: sand , silt , and clay . At

7442-446: The addition of any more hydronium ions or aluminum hydroxyl cations drives the pH even lower (more acidic) as the soil has been left with no buffering capacity. In areas of extreme rainfall and high temperatures, the clay and humus may be washed out, further reducing the buffering capacity of the soil. In low rainfall areas, unleached calcium pushes pH to 8.5 and with the addition of exchangeable sodium, soils may reach pH 10. Beyond

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7564-409: The affected rocks a reddish-brown coloration on the surface which crumbles easily and weakens the rock. Many other metallic ores and minerals oxidize and hydrate to produce colored deposits, as does sulfur during the weathering of sulfide minerals such as chalcopyrites or CuFeS 2 oxidizing to copper hydroxide and iron oxides . Mineral hydration is a form of chemical weathering that involves

7686-452: The apparent sterility of tropical soils. Live plant roots also have some CEC, linked to their specific surface area. Anion exchange capacity is the soil's ability to remove anions (such as nitrate , phosphate ) from the soil water solution and sequester those for later exchange as the plant roots release carbonate anions to the soil water solution. Those colloids which have low CEC tend to have some AEC. Amorphous and sesquioxide clays have

7808-466: The atmosphere and can affect climate. Aluminosilicates containing highly soluble cations, such as sodium or potassium ions, will release the cations as dissolved bicarbonates during acid hydrolysis: Within the weathering environment, chemical oxidation of a variety of metals occurs. The most commonly observed is the oxidation of Fe ( iron ) by oxygen and water to form Fe oxides and hydroxides such as goethite , limonite , and hematite . This gives

7930-426: The basic cations are forced off the soil colloids by the mass action of hydronium ions from usual or unusual rain acidity against those attached to the colloids. High rainfall rates can then wash the nutrients out, leaving the soil inhabited only by those organisms which are particularly efficient to uptake nutrients in very acid conditions, like in tropical rainforests . Once the colloids are saturated with H 3 O ,

8052-463: The breakdown of rocks and soils through such mechanical effects as heat, water, ice and wind. The latter covers reactions to water, atmospheric gases and biologically produced chemicals with rocks and soils. Water is the principal agent behind both kinds, though atmospheric oxygen and carbon dioxide and the activities of biological organisms are also important. Biological chemical weathering is also called biological weathering. The materials left after

8174-819: The carbon dioxide level to 30% of all soil gases, aided by adsorption of CO 2 on clay minerals and the very slow diffusion rate of CO 2 out of the soil. The CO 2 and organic acids help break down aluminium - and iron -containing compounds in the soils beneath them. Roots have a negative electrical charge balanced by protons in the soil next to the roots, and these can be exchanged for essential nutrient cations such as potassium. Decaying remains of dead plants in soil may form organic acids which, when dissolved in water, cause chemical weathering. Chelating compounds, mostly low molecular weight organic acids, are capable of removing metal ions from bare rock surfaces, with aluminium and silicon being particularly susceptible. The ability to break down bare rock allows lichens to be among

8296-480: The deterioration of rocks , soils and minerals (as well as wood and artificial materials) through contact with water, atmospheric gases , sunlight , and biological organisms. It occurs in situ (on-site, with little or no movement), and so is distinct from erosion , which involves the transport of rocks and minerals by agents such as water , ice , snow , wind , waves and gravity . Weathering processes are either physical or chemical. The former involves

8418-436: The dry limit for growing plants. During growing season, soil moisture is unaffected by functional groups or specie richness. Available water capacity is the amount of water held in a soil profile available to plants. As water content drops, plants have to work against increasing forces of adhesion and sorptivity to withdraw water. Irrigation scheduling avoids moisture stress by replenishing depleted water before stress

8540-530: The early 20th century that seemed to show that its effects were unimportant. These experiments have since been criticized as unrealistic, since the rock samples were small, were polished (which reduces nucleation of fractures), and were not buttressed. These small samples were thus able to expand freely in all directions when heated in experimental ovens, which failed to produce the kinds of stress likely in natural settings. The experiments were also more sensitive to thermal shock than thermal fatigue, but thermal fatigue

8662-427: The expansion of pore water when it freezes. A growing body of theoretical and experimental work suggests that ice segregation, whereby supercooled water migrates to lenses of ice forming within the rock, is the more important mechanism. When water freezes, its volume increases by 9.2%. This expansion can theoretically generate pressures greater than 200 megapascals (29,000 psi), though a more realistic upper limit

8784-404: The expense of silica, titanium, aluminum, ferrous iron, and calcium. Buildings made of any stone, brick or concrete are susceptible to the same weathering agents as any exposed rock surface. Also statues , monuments and ornamental stonework can be badly damaged by natural weathering processes. This is accelerated in areas severely affected by acid rain . Accelerated building weathering may be

8906-488: The first colonizers of dry land. The accumulation of chelating compounds can easily affect surrounding rocks and soils, and may lead to podsolisation of soils. The symbiotic mycorrhizal fungi associated with tree root systems can release inorganic nutrients from minerals such as apatite or biotite and transfer these nutrients to the trees, thus contributing to tree nutrition. It was also recently evidenced that bacterial communities can impact mineral stability leading to

9028-463: The form of silicic acid . A particularly important form of dissolution is carbonate dissolution, in which atmospheric carbon dioxide enhances solution weathering. Carbonate dissolution affects rocks containing calcium carbonate , such as limestone and chalk . It takes place when rainwater combines with carbon dioxide to form carbonic acid , a weak acid , which dissolves calcium carbonate (limestone) and forms soluble calcium bicarbonate . Despite

9150-448: The former term specifically to displaced soil. Soil consists of a solid phase of minerals and organic matter (the soil matrix), as well as a porous phase that holds gases (the soil atmosphere) and water (the soil solution). Accordingly, soil is a three- state system of solids, liquids, and gases. Soil is a product of several factors: the influence of climate , relief (elevation, orientation, and slope of terrain), organisms, and

9272-669: The geologic record. Indications that a sedimentary bed is a paleosol include a gradational lower boundary and sharp upper boundary, the presence of much clay, poor sorting with few sedimentary structures, rip-up clasts in overlying beds, and desiccation cracks containing material from higher beds. The degree of weathering of soil can be expressed as the chemical index of alteration , defined as 100 Al 2 O 3 /(Al 2 O 3 + CaO + Na 2 O + K 2 O) . This varies from 47 for unweathered upper crust rock to 100 for fully weathered material. Wood can be physically and chemically weathered by hydrolysis and other processes relevant to minerals and

9394-419: The highest AEC, followed by the iron oxides. Levels of AEC are much lower than for CEC, because of the generally higher rate of positively (versus negatively) charged surfaces on soil colloids, to the exception of variable-charge soils. Phosphates tend to be held at anion exchange sites. Iron and aluminum hydroxide clays are able to exchange their hydroxide anions (OH ) for other anions. The order reflecting

9516-439: The ice will simply expand into the air spaces in the unsaturated rock without generating much pressure. These conditions are unusual enough that frost wedging is unlikely to be the dominant process of frost weathering. Frost wedging is most effective where there are daily cycles of melting and freezing of water-saturated rock, so it is unlikely to be significant in the tropics, in polar regions or in arid climates. Ice segregation

9638-546: The most effective biological agents of chemical weathering. For example, an experimental study on hornblende granite in New Jersey, US, demonstrated a 3x – 4x increase in weathering rate under lichen covered surfaces compared to recently exposed bare rock surfaces. The most common forms of biological weathering result from the release of chelating compounds (such as certain organic acids and siderophores ) and of carbon dioxide and organic acids by plants. Roots can build up

9760-429: The negatively charged colloids resist being washed downward by water and are out of reach of plant roots, thereby preserving the soil fertility in areas of moderate rainfall and low temperatures. There is a hierarchy in the process of cation exchange on colloids, as cations differ in the strength of adsorption by the colloid and hence their ability to replace one another ( ion exchange ). If present in equal amounts in

9882-412: The negatively-charged soil colloid exchange sites (CEC) that are occupied by base-forming cations is called base saturation . If a soil has a CEC of 20 meq and 5 meq are aluminium and hydronium cations (acid-forming), the remainder of positions on the colloids ( 20 − 5 = 15 meq ) are assumed occupied by base-forming cations, so that the base saturation is 15 ÷ 20 × 100% = 75% (the compliment 25%

10004-419: The next larger scale, soil structures called peds or more commonly soil aggregates are created from the soil separates when iron oxides , carbonates , clay, silica and humus , coat particles and cause them to adhere into larger, relatively stable secondary structures. Soil bulk density , when determined at standardized moisture conditions, is an estimate of soil compaction . Soil porosity consists of

10126-551: The original set of minerals in the rock into a new set of minerals that is in closer equilibrium with surface conditions. True equilibrium is rarely reached, because weathering is a slow process, and leaching carries away solutes produced by weathering reactions before they can accumulate to equilibrium levels. This is particularly true in tropical environments. Water is the principal agent of chemical weathering, converting many primary minerals to clay minerals or hydrated oxides via reactions collectively described as hydrolysis . Oxygen

10248-635: The other cations more weakly bound to colloids are pushed into solution as hydrogen ions occupy exchange sites ( protonation ). A low pH may cause the hydrogen of hydroxyl groups to be pulled into solution, leaving charged sites on the colloid available to be occupied by other cations. This ionisation of hydroxy groups on the surface of soil colloids creates what is described as pH-dependent surface charges. Unlike permanent charges developed by isomorphous substitution , pH-dependent charges are variable and increase with increasing pH. Freed cations can be made available to plants but are also prone to be leached from

10370-443: The overlying rock material. When erosion removes the overlying rock material, these intrusive rocks are exposed and the pressure on them is released. The outer parts of the rocks then tend to expand. The expansion sets up stresses which cause fractures parallel to the rock surface to form. Over time, sheets of rock break away from the exposed rocks along the fractures, a process known as exfoliation . Exfoliation due to pressure release

10492-492: The plant roots release hydrogen ions to the solution. CEC is the amount of exchangeable hydrogen cation (H ) that will combine with 100 grams dry weight of soil and whose measure is one milliequivalents per 100 grams of soil (1 meq/100 g). Hydrogen ions have a single charge and one-thousandth of a gram of hydrogen ions per 100 grams dry soil gives a measure of one milliequivalent of hydrogen ion. Calcium, with an atomic weight 40 times that of hydrogen and with

10614-486: The porous lava, and by these means organic matter and a finer mineral soil accumulate with time. Such initial stages of soil development have been described on volcanoes, inselbergs, and glacial moraines. How soil formation proceeds is influenced by at least five classic factors that are intertwined in the evolution of a soil: parent material, climate, topography (relief), organisms, and time. When reordered to climate, relief, organisms, parent material, and time, they form

10736-402: The production of weathering agents, such as protons, organic acids and chelating molecules. Weathering of basaltic oceanic crust differs in important respects from weathering in the atmosphere. Weathering is relatively slow, with basalt becoming less dense, at a rate of about 15% per 100 million years. The basalt becomes hydrated, and is enriched in total and ferric iron, magnesium, and sodium at

10858-434: The rate of soil respiration , leading to the depletion of soil organic matter. Since plant roots need oxygen, aeration is an important characteristic of soil. This ventilation can be accomplished via networks of interconnected soil pores , which also absorb and hold rainwater making it readily available for uptake by plants. Since plants require a nearly continuous supply of water, but most regions receive sporadic rainfall,

10980-414: The rate of diffusion of gases into and out of soil. Platy soil structure and soil compaction (low porosity) impede gas flow, and a deficiency of oxygen may encourage anaerobic bacteria to reduce (strip oxygen) from nitrate NO 3 to the gases N 2 , N 2 O, and NO, which are then lost to the atmosphere, thereby depleting the soil of nitrogen, a detrimental process called denitrification . Aerated soil

11102-416: The release of inorganic nutrients. A large range of bacterial strains or communities from diverse genera have been reported to be able to colonize mineral surfaces or to weather minerals, and for some of them a plant growth promoting effect has been demonstrated. The demonstrated or hypothesised mechanisms used by bacteria to weather minerals include several oxidoreduction and dissolution reactions as well as

11224-448: The rigid attachment of water molecules or H+ and OH- ions to the atoms and molecules of a mineral. No significant dissolution takes place. For example, iron oxides are converted to iron hydroxides and the hydration of anhydrite forms gypsum . Bulk hydration of minerals is secondary in importance to dissolution, hydrolysis, and oxidation, but hydration of the crystal surface is the crucial first step in hydrolysis. A fresh surface of

11346-421: The rock breaks down combine with organic material to create soil . Many of Earth's landforms and landscapes are the result of weathering, erosion and redeposition. Weathering is a crucial part of the rock cycle ; sedimentary rock , the product of weathered rock, covers 66% of the Earth's continents and much of the ocean floor . Physical weathering , also called mechanical weathering or disaggregation ,

11468-455: The rock surface, which gradually pry the rock apart. Thermal stress weathering results from the expansion and contraction of rock due to temperature changes. Thermal stress weathering is most effective when the heated portion of the rock is buttressed by surrounding rock, so that it is free to expand in only one direction. Thermal stress weathering comprises two main types, thermal shock and thermal fatigue . Thermal shock takes place when

11590-413: The rock. This results in growth of the ice grain that puts considerable pressure on the surrounding rock, up to ten times greater than is likely with frost wedging. This mechanism is most effective in rock whose temperature averages just below the freezing point, −4 to −15 °C (25 to 5 °F). Ice segregation results in growth of ice needles and ice lenses within fractures in the rock and parallel to

11712-408: The rocks and evaporate, leaving salt crystals behind. As with ice segregation, the surfaces of the salt grains draw in additional dissolved salts through capillary action, causing the growth of salt lenses that exert high pressure on the surrounding rock. Sodium and magnesium salts are the most effective at producing salt weathering. Salt weathering can also take place when pyrite in sedimentary rock

11834-425: The rocks on which it falls. Hydrolysis (also called incongruent dissolution ) is a form of chemical weathering in which only part of a mineral is taken into solution. The rest of the mineral is transformed into a new solid material, such as a clay mineral . For example, forsterite (magnesium olivine ) is hydrolyzed into solid brucite and dissolved silicic acid: Most hydrolysis during weathering of minerals

11956-442: The seat of interaction networks playing a decisive role in the stability, dynamics and evolution of soil ecosystems. Biogenic soil volatile organic compounds are exchanged with the aboveground atmosphere, in which they are just 1–2 orders of magnitude lower than those from aboveground vegetation. Humans can get some idea of the soil atmosphere through the well-known 'after-the-rain' scent, when infiltering rainwater flushes out

12078-575: The soil particle density is much higher, in the range of 2.6 to 2.7 g/cm . Little of the soil of planet Earth is older than the Pleistocene and none is older than the Cenozoic , although fossilized soils are preserved from as far back as the Archean . Collectively the Earth's body of soil is called the pedosphere . The pedosphere interfaces with the lithosphere , the hydrosphere ,

12200-441: The soil anion exchange capacity. The cation exchange, that takes place between colloids and soil water, buffers (moderates) soil pH, alters soil structure, and purifies percolating water by adsorbing cations of all types, both useful and harmful. The negative or positive charges on colloid particles make them able to hold cations or anions, respectively, to their surfaces. The charges result from four sources. Cations held to

12322-538: The soil by volatilisation (loss to the atmosphere as gases) or leaching. Soil is said to be formed when organic matter has accumulated and colloids are washed downward, leaving deposits of clay, humus , iron oxide , carbonate , and gypsum , producing a distinct layer called the B horizon. This is a somewhat arbitrary definition as mixtures of sand, silt, clay and humus will support biological and agricultural activity before that time. These constituents are moved from one level to another by water and animal activity. As

12444-536: The soil is enriched in aluminium and potassium by at least 50%; by titanium, whose abundance triples, and ferric iron, whose abundance increases by an order of magnitude compared with the bedrock. Basaltic rock is more easily weathered than granitic rock due to its formation at higher temperatures and drier conditions. The fine grain size and presence of volcanic glass also hasten weathering. In tropical settings, it rapidly weathers to clay minerals, aluminium hydroxides, and titanium-enriched iron oxides. Because most basalt

12566-420: The soil solution composition (attenuate changes in the soil solution) as soils wet up or dry out, as plants take up nutrients, as salts are leached, or as acids or alkalis are added. Plant nutrient availability is affected by soil pH , which is a measure of the hydrogen ion activity in the soil solution. Soil pH is a function of many soil forming factors, and is generally lower (more acidic) where weathering

12688-402: The soil solution. Both living soil organisms (microbes, animals and plant roots) and soil organic matter are of critical importance to this recycling, and thereby to soil formation and soil fertility . Microbial soil enzymes may release nutrients from minerals or organic matter for use by plants and other microorganisms, sequester (incorporate) them into living cells, or cause their loss from

12810-473: The soil voids are saturated with water vapour, at least until the point of maximal hygroscopicity , beyond which a vapour-pressure deficit occurs in the soil pore space. Adequate porosity is necessary, not just to allow the penetration of water, but also to allow gases to diffuse in and out. Movement of gases is by diffusion from high concentrations to lower, the diffusion coefficient decreasing with soil compaction . Oxygen from above atmosphere diffuses in

12932-430: The soil water solution will be insufficient to change the pH, as the acid forming cations stored on the soil colloids will tend to restore the original pH condition as they are pushed off those colloids by the calcium of the added lime. The resistance of soil to change in pH, as a result of the addition of acid or basic material, is a measure of the buffering capacity of a soil and (for a particular soil type) increases as

13054-433: The soil water solution: Al replaces H replaces Ca replaces Mg replaces K same as NH 4 replaces Na If one cation is added in large amounts, it may replace the others by the sheer force of its numbers. This is called law of mass action . This is largely what occurs with the addition of cationic fertilisers ( potash , lime ). As the soil solution becomes more acidic (low pH , meaning an abundance of H ),

13176-462: The soil where it is consumed and levels of carbon dioxide in excess of above atmosphere diffuse out with other gases (including greenhouse gases ) as well as water. Soil texture and structure strongly affect soil porosity and gas diffusion. It is the total pore space ( porosity ) of soil, not the pore size, and the degree of pore interconnection (or conversely pore sealing), together with water content, air turbulence and temperature, that determine

13298-468: The soil's parent materials (original minerals) interacting over time. It continually undergoes development by way of numerous physical, chemical and biological processes, which include weathering with associated erosion . Given its complexity and strong internal connectedness , soil ecologists regard soil as an ecosystem . Most soils have a dry bulk density (density of soil taking into account voids when dry) between 1.1 and 1.6 g/cm , though

13420-502: The soil, a complex feedback which is exemplified in the dynamics of banded vegetation patterns in semi-arid regions. Soils supply plants with nutrients , most of which are held in place by particles of clay and organic matter ( colloids ) The nutrients may be adsorbed on clay mineral surfaces, bound within clay minerals ( absorbed ), or bound within organic compounds as part of the living organisms or dead soil organic matter. These bound nutrients interact with soil water to buffer

13542-414: The soil, possibly making the soil less fertile. Plants are able to excrete H into the soil through the synthesis of organic acids and by that means, change the pH of the soil near the root and push cations off the colloids, thus making those available to the plant. Cation exchange capacity is the soil's ability to remove cations from the soil water solution and sequester those to be exchanged later as

13664-699: The stream at the base of the mountain, connects the Appalachian Trail with the Chimney Tops Trail. This route is twice as long as the route from the Chimney Tops parking lot. From the summit, Mount Le Conte and Mount Kephart can be seen in the east, Sugarland Mountain in the west, and the Sugarlands valley in the north. A severe fire in 2016 led to closure of many trails in the Great Smoky Mountains, including in

13786-409: The strength of anion adhesion is as follows: The amount of exchangeable anions is of a magnitude of tenths to a few milliequivalents per 100 g dry soil. As pH rises, there are relatively more hydroxyls, which will displace anions from the colloids and force them into solution and out of storage; hence AEC decreases with increasing pH (alkalinity). Soil reactivity is expressed in terms of pH and

13908-419: The stresses are so great that the rock cracks immediately, but this is uncommon. More typical is thermal fatigue, in which the stresses are not great enough to cause immediate rock failure, but repeated cycles of stress and release gradually weaken the rock. Thermal stress weathering is an important mechanism in deserts , where there is a large diurnal temperature range, hot in the day and cold at night. As

14030-454: The surface of the crystal, and that the weathering layer is only a few atoms thick. Diffusion within the mineral grain does not appear to be significant. Mineral weathering can also be initiated or accelerated by soil microorganisms. Soil organisms make up about 10 mg/cm of typical soils, and laboratory experiments have demonstrated that albite and muscovite weather twice as fast in live versus sterile soil. Lichens on rocks are among

14152-491: The two concentrations are equal, they are said to neutralise each other. A pH of 9.5 has 10 moles hydronium ions per litre of solution (and also 10 moles per litre OH ). A pH of 3.5 has one million times more hydronium ions per litre than a solution with pH of 9.5 ( 9.5 − 3.5 = 6 or 10 ) and is more acidic. The effect of pH on a soil is to remove from the soil or to make available certain ions. Soils with high acidity tend to have toxic amounts of aluminium and manganese . As

14274-473: The void part of the soil volume and is occupied by gases or water. Soil consistency is the ability of soil materials to stick together. Soil temperature and colour are self-defining. Resistivity refers to the resistance to conduction of electric currents and affects the rate of corrosion of metal and concrete structures which are buried in soil. These properties vary through the depth of a soil profile, i.e. through soil horizons . Most of these properties determine

14396-553: The water content of the soil, as can be expressed in terms of volume or weight—can be based on in situ probes (e.g., capacitance probes , neutron probes ), or remote sensing methods. Soil moisture measurement is an important factor in determining changes in soil activity. The atmosphere of soil, or soil gas , is very different from the atmosphere above. The consumption of oxygen by microbes and plant roots, and their release of carbon dioxide, decreases oxygen and increases carbon dioxide concentration. Atmospheric CO 2 concentration

14518-461: The weathering of lava flow bedrock, which would produce the purely mineral-based parent material from which the soil texture forms. Soil development would proceed most rapidly from bare rock of recent flows in a warm climate, under heavy and frequent rainfall. Under such conditions, plants (in a first stage nitrogen-fixing lichens and cyanobacteria then epilithic higher plants ) become established very quickly on basaltic lava, even though there

14640-476: The whole soil atmosphere after a drought period, or when soil is excavated, a bulk property attributed in a reductionist manner to particular biochemical compounds such as petrichor or geosmin . Soil particles can be classified by their chemical composition ( mineralogy ) as well as their size. The particle size distribution of a soil, its texture, determines many of the properties of that soil, in particular hydraulic conductivity and water potential , but

14762-635: Was clearly visible from most of the valley. Local legend even suggested that the top of the mountain was covered in soot. A common route to closely see the peaks is the Chimney Tops Trail, which can be accessed about 6.9 miles southeast of the Sugarlands Visitor Center on Newfound Gap Road. Another route follows the Appalachian Trail west from Newfound Gap to the Road Prong Trail. The Road Prong Trail, following

14884-547: Was expanded during the Civil War by Cherokee leader Col. Will Thomas , running parallel to the modern trail. The mountain's current name was probably given to it by residents of the Sugarlands , a valley to the north of the mountain that was home to a small Appalachian community before the Great Smoky Mountains National Park was formed. Before the Sugarlands was reforested, Chimney Tops

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