101-421: A crystallite is a small or even microscopic crystal which forms, for example, during the cooling of many materials. Crystallites are also referred to as grains . Bacillite is a type of crystallite. It is rodlike with parallel longulites . The orientation of crystallites can be random with no preferred direction, called random texture , or directed, possibly due to growth and processing conditions. While
202-930: A grain boundary . Like a grain boundary, a twin boundary has different crystal orientations on its two sides. But unlike a grain boundary, the orientations are not random, but related in a specific, mirror-image way. Mosaicity is a spread of crystal plane orientations. A mosaic crystal consists of smaller crystalline units that are somewhat misaligned with respect to each other. In general, solids can be held together by various types of chemical bonds , such as metallic bonds , ionic bonds , covalent bonds , van der Waals bonds , and others. None of these are necessarily crystalline or non-crystalline. However, there are some general trends as follows: Metals crystallize rapidly and are almost always polycrystalline, though there are exceptions like amorphous metal and single-crystal metals. The latter are grown synthetically, for example, fighter-jet turbines are typically made by first growing
303-515: A molten condition nor entirely in solution, but the high temperature and pressure conditions of metamorphism have acted on them by erasing their original structures and inducing recrystallization in the solid state. Other rock crystals have formed out of precipitation from fluids, commonly water, to form druses or quartz veins. Evaporites such as halite , gypsum and some limestones have been deposited from aqueous solution, mostly owing to evaporation in arid climates. Water-based ice in
404-619: A molten fluid, or by crystallization out of a solution. Some ionic compounds can be very hard, such as oxides like aluminium oxide found in many gemstones such as ruby and synthetic sapphire . Covalently bonded solids (sometimes called covalent network solids ) are typically formed from one or more non-metals, such as carbon or silicon and oxygen, and are often very hard, rigid, and brittle. These are also very common, notable examples being diamond and quartz respectively. Weak van der Waals forces also help hold together certain crystals, such as crystalline molecular solids , as well as
505-403: A moon onto its surface. Lava may be erupted at a volcano or through a fracture in the crust , on land or underwater, usually at temperatures from 800 to 1,200 °C (1,470 to 2,190 °F). The volcanic rock resulting from subsequent cooling is also often called lava . A lava flow is an outpouring of lava during an effusive eruption . (An explosive eruption , by contrast, produces
606-420: A transgranular fracture . There is an ambiguity with powder grains: a powder grain can be made of several crystallites. Thus, the (powder) "grain size" found by laser granulometry can be different from the "grain size" (rather, crystallite size) found by X-ray diffraction (e.g. Scherrer method), by optical microscopy under polarised light , or by scanning electron microscopy (backscattered electrons). If
707-416: A "crystal" is based on the microscopic arrangement of atoms inside it, called the crystal structure . A crystal is a solid where the atoms form a periodic arrangement. ( Quasicrystals are an exception, see below ). Not all solids are crystals. For example, when liquid water starts freezing, the phase change begins with small ice crystals that grow until they fuse, forming a polycrystalline structure. In
808-419: A continued supply of lava and its pressure on a solidified crust. Most basaltic lavas are of ʻaʻā or pāhoehoe types, rather than block lavas. Underwater, they can form pillow lavas , which are rather similar to entrail-type pahoehoe lavas on land. Ultramafic lavas, such as komatiite and highly magnesian magmas that form boninite , take the composition and temperatures of eruptions to the extreme. All have
909-443: A critical extent, the material could fracture . During grain boundary migration, the rate determining step depends on the angle between two adjacent grains. In a small angle dislocation boundary, the migration rate depends on vacancy diffusion between dislocations. In a high angle dislocation boundary, this depends on the atom transport by single atom jumps from the shrinking to the growing grains. Grain boundaries are generally only
1010-455: A darker groundmass , including amphibole or pyroxene phenocrysts. Mafic or basaltic lavas are typified by relatively high magnesium oxide and iron oxide content (whose molecular formulas provide the consonants in mafic) and have a silica content limited to a range of 52% to 45%. They generally erupt at temperatures of 1,100 to 1,200 °C (2,010 to 2,190 °F) and at relatively low viscosities, around 10 to 10 cP (10 to 100 Pa⋅s). This
1111-420: A dome forms on an inclined surface it can flow in short thick flows called coulées (dome flows). These flows often travel only a few kilometres from the vent. Lava tubes are formed when a flow of relatively fluid lava cools on the upper surface sufficiently to form a crust. Beneath this crust, which being made of rock is an excellent insulator, the lava can continue to flow as a liquid. When this flow occurs over
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#17327973042721212-404: A few nanometers wide. In common materials, crystallites are large enough that grain boundaries account for a small fraction of the material. However, very small grain sizes are achievable. In nanocrystalline solids, grain boundaries become a significant volume fraction of the material, with profound effects on such properties as diffusion and plasticity . In the limit of small crystallites, as
1313-555: A fraction of a millimetre to several centimetres across, although exceptionally large crystals are occasionally found. As of 1999 , the world's largest known naturally occurring crystal is a crystal of beryl from Malakialina, Madagascar , 18 m (59 ft) long and 3.5 m (11 ft) in diameter, and weighing 380,000 kg (840,000 lb). Some crystals have formed by magmatic and metamorphic processes, giving origin to large masses of crystalline rock . The vast majority of igneous rocks are formed from molten magma and
1414-405: A high enough temperature. This is because grain boundaries are amorphous, and serve as nucleation points for the liquid phase . By contrast, if no solid nucleus is present as a liquid cools, it tends to become supercooled . Since this is undesirable for mechanical materials, alloy designers often take steps against it (by grain refinement ). Material fractures can be either intergranular or
1515-513: A large number crystallites held together by thin layers of amorphous solid. Most inorganic solids are polycrystalline, including all common metals, many ceramics , rocks, and ice. The areas where crystallites meet are known as grain boundaries . Crystallite size in monodisperse microstructures is usually approximated from X-ray diffraction patterns and grain size by other experimental techniques like transmission electron microscopy. Solid objects large enough to see and handle are rarely composed of
1616-465: A massive dense core, which is the most active part of the flow. As pasty lava in the core travels downslope, the clinkers are carried along at the surface. At the leading edge of an ʻaʻā flow, however, these cooled fragments tumble down the steep front and are buried by the advancing flow. This produces a layer of lava fragments both at the bottom and top of an ʻaʻā flow. Accretionary lava balls as large as 3 metres (10 feet) are common on ʻaʻā flows. ʻAʻā
1717-471: A mixture of volcanic ash and other fragments called tephra , not lava flows.) The viscosity of most lava is about that of ketchup , roughly 10,000 to 100,000 times that of water. Even so, lava can flow great distances before cooling causes it to solidify, because lava exposed to air quickly develops a solid crust that insulates the remaining liquid lava, helping to keep it hot and inviscid enough to continue flowing. The word lava comes from Italian and
1818-608: A perfect, exactly repeating pattern. However, in reality, most crystalline materials have a variety of crystallographic defects : places where the crystal's pattern is interrupted. The types and structures of these defects may have a profound effect on the properties of the materials. A few examples of crystallographic defects include vacancy defects (an empty space where an atom should fit), interstitial defects (an extra atom squeezed in where it does not fit), and dislocations (see figure at right). Dislocations are especially important in materials science , because they help determine
1919-960: A silica content greater than 63%. They include rhyolite and dacite lavas. With such a high silica content, these lavas are extremely viscous, ranging from 10 cP (10 Pa⋅s) for hot rhyolite lava at 1,200 °C (2,190 °F) to 10 cP (10 Pa⋅s) for cool rhyolite lava at 800 °C (1,470 °F). For comparison, water has a viscosity of about 1 cP (0.001 Pa⋅s). Because of this very high viscosity, felsic lavas usually erupt explosively to produce pyroclastic (fragmental) deposits. However, rhyolite lavas occasionally erupt effusively to form lava spines , lava domes or "coulees" (which are thick, short lava flows). The lavas typically fragment as they extrude, producing block lava flows. These often contain obsidian . Felsic magmas can erupt at temperatures as low as 800 °C (1,470 °F). Unusually hot (>950 °C; >1,740 °F) rhyolite lavas, however, may flow for distances of many tens of kilometres, such as in
2020-450: A silica content under 45%. Komatiites contain over 18% magnesium oxide and are thought to have erupted at temperatures of 1,600 °C (2,910 °F). At this temperature there is practically no polymerization of the mineral compounds, creating a highly mobile liquid. Viscosities of komatiite magmas are thought to have been as low as 100 to 1000 cP (0.1 to 1 Pa⋅s), similar to that of light motor oil. Most ultramafic lavas are no younger than
2121-441: A similar manner to ʻaʻā flows but their more viscous nature causes the surface to be covered in smooth-sided angular fragments (blocks) of solidified lava instead of clinkers. As with ʻaʻā flows, the molten interior of the flow, which is kept insulated by the solidified blocky surface, advances over the rubble that falls off the flow front. They also move much more slowly downhill and are thicker in depth than ʻaʻā flows. Pillow lava
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#17327973042722222-410: A similar mean crystallite size. Coarse grained rocks are formed very slowly, while fine grained rocks are formed quickly, on geological time scales. If a rock forms very quickly, such as from the solidification of lava ejected from a volcano , there may be no crystals at all. This is how obsidian forms. Grain boundaries are interfaces where crystals of different orientations meet. A grain boundary
2323-417: A single crystal cut into two parts, one of which is rotated, we see that there are five variables required to define a grain boundary. The first two numbers come from the unit vector that specifies a rotation axis. The third number designates the angle of rotation of the grain. The final two numbers specify the plane of the grain boundary (or a unit vector that is normal to this plane). Grain boundaries disrupt
2424-434: A single crystal of titanium alloy, increasing its strength and melting point over polycrystalline titanium. A small piece of metal may naturally form into a single crystal, such as Type 2 telluric iron , but larger pieces generally do not unless extremely slow cooling occurs. For example, iron meteorites are often composed of single crystal, or many large crystals that may be several meters in size, due to very slow cooling in
2525-829: A single crystal, except for a few cases ( gems , silicon single crystals for the electronics industry, certain types of fiber , single crystals of a nickel -based superalloy for turbojet engines, and some ice crystals which can exceed 0.5 meters in diameter). The crystallite size can vary from a few nanometers to several millimeters. The extent to which a solid is crystalline ( crystallinity ) has important effects on its physical properties. Sulfur , while usually polycrystalline, may also occur in other allotropic forms with completely different properties. Although crystallites are referred to as grains, powder grains are different, as they can be composed of smaller polycrystalline grains themselves. Generally, polycrystals cannot be superheated ; they will melt promptly once they are brought to
2626-721: A single solid. Polycrystals include most metals , rocks, ceramics , and ice . A third category of solids is amorphous solids , where the atoms have no periodic structure whatsoever. Examples of amorphous solids include glass , wax , and many plastics . Despite the name, lead crystal, crystal glass , and related products are not crystals, but rather types of glass, i.e. amorphous solids. Crystals, or crystalline solids, are often used in pseudoscientific practices such as crystal therapy , and, along with gemstones , are sometimes associated with spellwork in Wiccan beliefs and related religious movements. The scientific definition of
2727-575: A temperature of 1,100 to 1,200 °C (2,010 to 2,190 °F). On the Earth, most lava flows are less than 10 km (6.2 mi) long, but some pāhoehoe flows are more than 50 km (31 mi) long. Some flood basalt flows in the geologic record extend for hundreds of kilometres. The rounded texture makes pāhoehoe a poor radar reflector, and is difficult to see from an orbiting satellite (dark on Magellan picture). Block lava flows are typical of andesitic lavas from stratovolcanoes. They behave in
2828-501: A volcano extrudes silicic lava, it can form an inflation dome or endogenous dome , gradually building up a large, pillow-like structure which cracks, fissures, and may release cooled chunks of rock and rubble. The top and side margins of an inflating lava dome tend to be covered in fragments of rock, breccia and ash. Examples of lava dome eruptions include the Novarupta dome, and successive lava domes of Mount St Helens . When
2929-435: A wide range of properties. Polyamorphism is a similar phenomenon where the same atoms can exist in more than one amorphous solid form. Crystallization is the process of forming a crystalline structure from a fluid or from materials dissolved in a fluid. (More rarely, crystals may be deposited directly from gas; see: epitaxy and frost .) Crystallization is a complex and extensively-studied field, because depending on
3030-402: Is a large subsidence crater, can form in a stratovolcano, if the magma chamber is partially or wholly emptied by large explosive eruptions; the summit cone no longer supports itself and thus collapses in on itself afterwards. Such features may include volcanic crater lakes and lava domes after the event. However, calderas can also form by non-explosive means such as gradual magma subsidence. This
3131-445: Is a noncrystalline form. Polymorphs, despite having the same atoms, may have very different properties. For example, diamond is the hardest substance known, while graphite is so soft that it is used as a lubricant. Chocolate can form six different types of crystals, but only one has the suitable hardness and melting point for candy bars and confections. Polymorphism in steel is responsible for its ability to be heat treated , giving it
Crystallite - Misplaced Pages Continue
3232-425: Is a single-phase interface, with crystals on each side of the boundary being identical except in orientation. The term "crystallite boundary" is sometimes, though rarely, used. Grain boundary areas contain those atoms that have been perturbed from their original lattice sites, dislocations , and impurities that have migrated to the lower energy grain boundary. Treating a grain boundary geometrically as an interface of
3333-415: Is basaltic lava that has a smooth, billowy, undulating, or ropy surface. These surface features are due to the movement of very fluid lava under a congealing surface crust. The Hawaiian word was introduced as a technical term in geology by Clarence Dutton . A pāhoehoe flow typically advances as a series of small lobes and toes that continually break out from a cooled crust. It also forms lava tubes where
3434-719: Is concentrated in a thin layer in the toothpaste next to the tube and only there does the toothpaste behave as a fluid. Thixotropic behavior also hinders crystals from settling out of the lava. Once the crystal content reaches about 60%, the lava ceases to behave like a fluid and begins to behave like a solid. Such a mixture of crystals with melted rock is sometimes described as crystal mush . Lava flow speeds vary based primarily on viscosity and slope. In general, lava flows slowly, with typical speeds for Hawaiian basaltic flows of 0.40 km/h (0.25 mph) and maximum speeds of 10 to 48 km/h (6 to 30 mph) on steep slopes. An exceptional speed of 32 to 97 km/h (20 to 60 mph)
3535-473: Is given by the Hall–Petch relationship . The high interfacial energy and relatively weak bonding in grain boundaries makes them preferred sites for the onset of corrosion and for the precipitation of new phases from the solid. Grain boundary migration plays an important role in many of the mechanisms of creep . Grain boundary migration occurs when a shear stress acts on the grain boundary plane and causes
3636-580: Is impossible for an ordinary periodic crystal (see crystallographic restriction theorem ). The International Union of Crystallography has redefined the term "crystal" to include both ordinary periodic crystals and quasicrystals ("any solid having an essentially discrete diffraction diagram" ). Quasicrystals, first discovered in 1982, are quite rare in practice. Only about 100 solids are known to form quasicrystals, compared to about 400,000 periodic crystals known in 2004. The 2011 Nobel Prize in Chemistry
3737-431: Is its visible external shape. This is determined by the crystal structure (which restricts the possible facet orientations), the specific crystal chemistry and bonding (which may favor some facet types over others), and the conditions under which the crystal formed. By volume and weight, the largest concentrations of crystals in the Earth are part of its solid bedrock . Crystals found in rocks typically range in size from
3838-589: Is known as crystallography . The process of crystal formation via mechanisms of crystal growth is called crystallization or solidification . The word crystal derives from the Ancient Greek word κρύσταλλος ( krustallos ), meaning both " ice " and " rock crystal ", from κρύος ( kruos ), "icy cold, frost". Examples of large crystals include snowflakes , diamonds , and table salt . Most inorganic solids are not crystals but polycrystals , i.e. many microscopic crystals fused together into
3939-473: Is mechanically very strong, the sheets are rather loosely bound to each other. Therefore, the mechanical strength of the material is quite different depending on the direction of stress. Not all crystals have all of these properties. Conversely, these properties are not quite exclusive to crystals. They can appear in glasses or polycrystals that have been made anisotropic by working or stress —for example, stress-induced birefringence . Crystallography
4040-546: Is mostly determined by composition but also depends on temperature and shear rate. Lava viscosity determines the kind of volcanic activity that takes place when the lava is erupted. The greater the viscosity, the greater the tendency for eruptions to be explosive rather than effusive. As a result, most lava flows on Earth, Mars, and Venus are composed of basalt lava. On Earth, 90% of lava flows are mafic or ultramafic, with intermediate lava making up 8% of flows and felsic lava making up just 2% of flows. Viscosity also determines
4141-444: Is one of three basic types of flow lava. ʻAʻā is basaltic lava characterized by a rough or rubbly surface composed of broken lava blocks called clinker. The word is Hawaiian meaning "stony rough lava", but also to "burn" or "blaze"; it was introduced as a technical term in geology by Clarence Dutton . The loose, broken, and sharp, spiny surface of an ʻaʻā flow makes hiking difficult and slow. The clinkery surface actually covers
Crystallite - Misplaced Pages Continue
4242-478: Is probably derived from the Latin word labes , which means a fall or slide. An early use of the word in connection with extrusion of magma from below the surface is found in a short account of the 1737 eruption of Vesuvius , written by Francesco Serao , who described "a flow of fiery lava" as an analogy to the flow of water and mud down the flanks of the volcano (a lahar ) after heavy rain . Solidified lava on
4343-474: Is similar to the viscosity of ketchup , although it is still many orders of magnitude higher than that of water. Mafic lavas tend to produce low-profile shield volcanoes or flood basalts , because the less viscous lava can flow for long distances from the vent. The thickness of a solidified basaltic lava flow, particularly on a low slope, may be much greater than the thickness of the moving molten lava flow at any one time, because basaltic lavas may "inflate" by
4444-454: Is the lava structure typically formed when lava emerges from an underwater volcanic vent or subglacial volcano or a lava flow enters the ocean. The viscous lava gains a solid crust on contact with the water, and this crust cracks and oozes additional large blobs or "pillows" as more lava emerges from the advancing flow. Since water covers the majority of Earth 's surface and most volcanoes are situated near or under bodies of water, pillow lava
4545-414: Is the science of measuring the crystal structure (in other words, the atomic arrangement) of a crystal. One widely used crystallography technique is X-ray diffraction . Large numbers of known crystal structures are stored in crystallographic databases . Lava Lava is molten or partially molten rock ( magma ) that has been expelled from the interior of a terrestrial planet (such as Earth ) or
4646-424: Is the type of impurities present in a corundum crystal. In semiconductors , a special type of impurity, called a dopant , drastically changes the crystal's electrical properties. Semiconductor devices , such as transistors , are made possible largely by putting different semiconductor dopants into different places, in specific patterns. Twinning is a phenomenon somewhere between a crystallographic defect and
4747-422: Is typical of many shield volcanoes. Cinder cones and spatter cones are small-scale features formed by lava accumulation around a small vent on a volcanic edifice. Cinder cones are formed from tephra or ash and tuff which is thrown from an explosive vent. Spatter cones are formed by accumulation of molten volcanic slag and cinders ejected in a more liquid form. Another Hawaiian English term derived from
4848-516: Is usually of higher viscosity than pāhoehoe. Pāhoehoe can turn into ʻaʻā if it becomes turbulent from meeting impediments or steep slopes. The sharp, angled texture makes ʻaʻā a strong radar reflector, and can easily be seen from an orbiting satellite (bright on Magellan pictures). ʻAʻā lavas typically erupt at temperatures of 1,050 to 1,150 °C (1,920 to 2,100 °F) or greater. Pāhoehoe (also spelled pahoehoe , from Hawaiian [paːˈhoweˈhowe] meaning "smooth, unbroken lava")
4949-646: Is very common. Because it is formed from viscous molten rock, lava flows and eruptions create distinctive formations, landforms and topographical features from the macroscopic to the microscopic. Volcanoes are the primary landforms built by repeated eruptions of lava and ash over time. They range in shape from shield volcanoes with broad, shallow slopes formed from predominantly effusive eruptions of relatively fluid basaltic lava flows, to steeply-sided stratovolcanoes (also known as composite volcanoes) made of alternating layers of ash and more viscous lava flows typical of intermediate and felsic lavas. A caldera , which
5050-456: The Earth's crust is predominantly silicate minerals : mostly feldspars , feldspathoids , olivine , pyroxenes , amphiboles , micas and quartz . Rare nonsilicate lavas can be formed by local melting of nonsilicate mineral deposits or by separation of a magma into immiscible silicate and nonsilicate liquid phases . Silicate lavas are molten mixtures dominated by oxygen and silicon ,
5151-494: The Hawaiian language , a kīpuka denotes an elevated area such as a hill, ridge or old lava dome inside or downslope from an area of active volcanism. New lava flows will cover the surrounding land, isolating the kīpuka so that it appears as a (usually) forested island in a barren lava flow. Lava domes are formed by the extrusion of viscous felsic magma. They can form prominent rounded protuberances, such as at Valles Caldera . As
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#17327973042725252-838: The Proterozoic , with a few ultramafic magmas known from the Phanerozoic in Central America that are attributed to a hot mantle plume . No modern komatiite lavas are known, as the Earth's mantle has cooled too much to produce highly magnesian magmas. Some silicate lavas have an elevated content of alkali metal oxides (sodium and potassium), particularly in regions of continental rifting , areas overlying deeply subducted plates , or at intraplate hotspots . Their silica content can range from ultramafic ( nephelinites , basanites and tephrites ) to felsic ( trachytes ). They are more likely to be generated at greater depths in
5353-520: The Snake River Plain of the northwestern United States. Intermediate or andesitic lavas contain 52% to 63% silica, and are lower in aluminium and usually somewhat richer in magnesium and iron than felsic lavas. Intermediate lavas form andesite domes and block lavas and may occur on steep composite volcanoes , such as in the Andes . They are also commonly hotter than felsic lavas, in
5454-447: The mechanical strength of materials . Another common type of crystallographic defect is an impurity , meaning that the "wrong" type of atom is present in a crystal. For example, a perfect crystal of diamond would only contain carbon atoms, but a real crystal might perhaps contain a few boron atoms as well. These boron impurities change the diamond's color to slightly blue. Likewise, the only difference between ruby and sapphire
5555-418: The most abundant elements of the Earth's crust , with smaller quantities of aluminium , calcium , magnesium , iron , sodium , and potassium and minor amounts of many other elements. Petrologists routinely express the composition of a silicate lava in terms of the weight or molar mass fraction of the oxides of the major elements (other than oxygen) present in the lava. The silica component dominates
5656-429: The air ( ice fog ) more often grow from a supersaturated gaseous-solution of water vapor and air, when the temperature of the air drops below its dew point , without passing through a liquid state. Another unusual property of water is that it expands rather than contracts when it crystallizes. Many living organisms are able to produce crystals grown from an aqueous solution , for example calcite and aragonite in
5757-989: The aspect (thickness relative to lateral extent) of flows, the speed with which flows move, and the surface character of the flows. When highly viscous lavas erupt effusively rather than in their more common explosive form, they almost always erupt as high-aspect flows or domes. These flows take the form of block lava rather than ʻaʻā or pāhoehoe. Obsidian flows are common. Intermediate lavas tend to form steep stratovolcanoes, with alternating beds of lava from effusive eruptions and tephra from explosive eruptions. Mafic lavas form relatively thin flows that can move great distances, forming shield volcanoes with gentle slopes. In addition to melted rock, most lavas contain solid crystals of various minerals, fragments of exotic rocks known as xenoliths , and fragments of previously solidified lava. The crystal content of most lavas gives them thixotropic and shear thinning properties. In other words, most lavas do not behave like Newtonian fluids, in which
5858-510: The case of most molluscs or hydroxylapatite in the case of bones and teeth in vertebrates . The same group of atoms can often solidify in many different ways. Polymorphism is the ability of a solid to exist in more than one crystal form. For example, water ice is ordinarily found in the hexagonal form Ice I h , but can also exist as the cubic Ice I c , the rhombohedral ice II , and many other forms. The different polymorphs are usually called different phases . In addition,
5959-404: The conditions, a single fluid can solidify into many different possible forms. It can form a single crystal , perhaps with various possible phases , stoichiometries , impurities, defects , and habits . Or, it can form a polycrystal , with various possibilities for the size, arrangement, orientation, and phase of its grains. The final form of the solid is determined by the conditions under which
6060-409: The crystal can shrink or stretch it. Another is birefringence , where a double image appears when looking through a crystal. Moreover, various properties of a crystal, including electrical conductivity , electrical permittivity , and Young's modulus , may be different in different directions in a crystal. For example, graphite crystals consist of a stack of sheets, and although each individual sheet
6161-411: The crystal is one grain in a polycrystalline solid. The flat faces (also called facets ) of a euhedral crystal are oriented in a specific way relative to the underlying atomic arrangement of the crystal : they are planes of relatively low Miller index . This occurs because some surface orientations are more stable than others (lower surface energy ). As a crystal grows, new atoms attach easily to
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#17327973042726262-421: The crystallites are mostly ordered with a random spread of orientations, one has a mosaic crystal . Abnormal grain growth , where a small number of crystallites are significantly larger than the mean crystallite size, is commonly observed in diverse polycrystalline materials, and results in mechanical and optical properties that diverge from similar materials having a monodisperse crystallite size distribution with
6363-532: The crystals may form hexagons, such as ordinary water ice ). Crystals are commonly recognized, macroscopically, by their shape, consisting of flat faces with sharp angles. These shape characteristics are not necessary for a crystal—a crystal is scientifically defined by its microscopic atomic arrangement, not its macroscopic shape—but the characteristic macroscopic shape is often present and easy to see. Euhedral crystals are those that have obvious, well-formed flat faces. Anhedral crystals do not, usually because
6464-404: The dangers of grain boundaries in certain materials such as superalloy turbine blades, great technological leaps were made to minimize as much as possible the effect of grain boundaries in the blades. The result was directional solidification processing in which grain boundaries were eliminated by producing columnar grain structures aligned parallel to the axis of the blade, since this is usually
6565-606: The degree of crystallization depends primarily on the conditions under which they solidified. Such rocks as granite , which have cooled very slowly and under great pressures, have completely crystallized; but many kinds of lava were poured out at the surface and cooled very rapidly, and in this latter group a small amount of amorphous or glassy matter is common. Other crystalline rocks, the metamorphic rocks such as marbles , mica-schists and quartzites , are recrystallized. This means that they were at first fragmental rocks like limestone , shale and sandstone and have never been in
6666-652: The direction of maximum tensile stress felt by a blade during its rotation in an airplane. The resulting turbine blades consisted of a single grain, improving reliability. Crystal A crystal or crystalline solid is a solid material whose constituents (such as atoms , molecules , or ions ) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macroscopic single crystals are usually identifiable by their geometrical shape , consisting of flat faces with specific, characteristic orientations. The scientific study of crystals and crystal formation
6767-453: The eight faces of the octahedron belong to another crystallographic form reflecting a different symmetry of the isometric system. A crystallographic form is described by placing the Miller indices of one of its faces within brackets. For example, the octahedral form is written as {111}, and the other faces in the form are implied by the symmetry of the crystal. Forms may be closed, meaning that
6868-418: The eruption. A cooling lava flow shrinks, and this fractures the flow. Basalt flows show a characteristic pattern of fractures. The uppermost parts of the flow show irregular downward-splaying fractures, while the lower part of the flow shows a very regular pattern of fractures that break the flow into five- or six-sided columns. The irregular upper part of the solidified flow is called the entablature , while
6969-710: The final block of ice, each of the small crystals (called " crystallites " or "grains") is a true crystal with a periodic arrangement of atoms, but the whole polycrystal does not have a periodic arrangement of atoms, because the periodic pattern is broken at the grain boundaries . Most macroscopic inorganic solids are polycrystalline, including almost all metals , ceramics , ice , rocks , etc. Solids that are neither crystalline nor polycrystalline, such as glass , are called amorphous solids , also called glassy , vitreous, or noncrystalline. These have no periodic order, even microscopically. There are distinct differences between crystalline solids and amorphous solids: most notably,
7070-654: The flood basalts of South America formed in this manner. Flood basalts typically crystallize little before they cease flowing, and, as a result, flow textures are uncommon in less silicic flows. On the other hand, flow banding is common in felsic flows. The morphology of lava describes its surface form or texture. More fluid basaltic lava flows tend to form flat sheet-like bodies, whereas viscous rhyolite lava flows form knobbly, blocky masses of rock. Lava erupted underwater has its own distinctive characteristics. ʻAʻā (also spelled aa , aʻa , ʻaʻa , and a-aa , and pronounced [ʔəˈʔaː] or / ˈ ɑː ( ʔ ) ɑː / )
7171-531: The fluid is being solidified, such as the chemistry of the fluid, the ambient pressure , the temperature , and the speed with which all these parameters are changing. Specific industrial techniques to produce large single crystals (called boules ) include the Czochralski process and the Bridgman technique . Other less exotic methods of crystallization may be used, depending on the physical properties of
7272-415: The form can completely enclose a volume of space, or open, meaning that it cannot. The cubic and octahedral forms are examples of closed forms. All the forms of the isometric system are closed, while all the forms of the monoclinic and triclinic crystal systems are open. A crystal's faces may all belong to the same closed form, or they may be a combination of multiple open or closed forms. A crystal's habit
7373-402: The form of snow , sea ice , and glaciers are common crystalline/polycrystalline structures on Earth and other planets. A single snowflake is a single crystal or a collection of crystals, while an ice cube is a polycrystal . Ice crystals may form from cooling liquid water below its freezing point, such as ice cubes or a frozen lake. Frost , snowflakes, or small ice crystals suspended in
7474-400: The grains to slide. This means that fine-grained materials actually have a poor resistance to creep relative to coarser grains, especially at high temperatures, because smaller grains contain more atoms in grain boundary sites. Grain boundaries also cause deformation in that they are sources and sinks of point defects. Voids in a material tend to gather in a grain boundary, and if this happens to
7575-497: The icy satellites of the Solar System 's giant planets . The lava's viscosity mostly determines the behavior of lava flows. While the temperature of common silicate lava ranges from about 800 °C (1,470 °F) for felsic lavas to 1,200 °C (2,190 °F) for mafic lavas, its viscosity ranges over seven orders of magnitude, from 10 cP (10 Pa⋅s) for felsic lavas to 10 cP (10 Pa⋅s) for mafic lavas. Lava viscosity
7676-457: The individual crystallites are oriented completely at random, a large enough volume of polycrystalline material will be approximately isotropic . This property helps the simplifying assumptions of continuum mechanics to apply to real-world solids. However, most manufactured materials have some alignment to their crystallites, resulting in texture that must be taken into account for accurate predictions of their behavior and characteristics. When
7777-458: The interlayer bonding in graphite . Substances such as fats , lipids and wax form molecular bonds because the large molecules do not pack as tightly as atomic bonds. This leads to crystals that are much softer and more easily pulled apart or broken. Common examples include chocolates, candles, or viruses. Water ice and dry ice are examples of other materials with molecular bonding. Polymer materials generally will form crystalline regions, but
7878-404: The lava's chemical composition. This temperature range is similar to the hottest temperatures achievable with a forced air charcoal forge. Lava is most fluid when first erupted, becoming much more viscous as its temperature drops. Lava flows quickly develop an insulating crust of solid rock as a result of radiative loss of heat. Thereafter, the lava cools by a very slow conduction of heat through
7979-610: The lava. Other cations , such as ferrous iron, calcium, and magnesium, bond much more weakly to oxygen and reduce the tendency to polymerize. Partial polymerization makes the lava viscous, so lava high in silica is much more viscous than lava low in silica. Because of the role of silica in determining viscosity and because many other properties of a lava (such as its temperature) are observed to correlate with silica content, silicate lavas are divided into four chemical types based on silica content: felsic , intermediate , mafic , and ultramafic . Felsic or silicic lavas have
8080-471: The lengths of the molecules usually prevent complete crystallization—and sometimes polymers are completely amorphous. A quasicrystal consists of arrays of atoms that are ordered but not strictly periodic. They have many attributes in common with ordinary crystals, such as displaying a discrete pattern in x-ray diffraction , and the ability to form shapes with smooth, flat faces. Quasicrystals are most famous for their ability to show five-fold symmetry, which
8181-464: The lower and upper boundaries. These are described as pipe-stem vesicles or pipe-stem amygdales . Liquids expelled from the cooling crystal mush rise upwards into the still-fluid center of the cooling flow and produce vertical vesicle cylinders . Where these merge towards the top of the flow, they form sheets of vesicular basalt and are sometimes capped with gas cavities that sometimes fill with secondary minerals. The beautiful amethyst geodes found in
8282-467: The lower part that shows columnar jointing is called the colonnade . (The terms are borrowed from Greek temple architecture.) Likewise, regular vertical patterns on the sides of columns, produced by cooling with periodic fracturing, are described as chisel marks . Despite their names, these are natural features produced by cooling, thermal contraction, and fracturing. As lava cools, crystallizing inwards from its edges, it expels gases to form vesicles at
8383-422: The mantle than subalkaline magmas. Olivine nephelinite lavas are both ultramafic and highly alkaline, and are thought to have come from much deeper in the mantle of the Earth than other lavas. Tholeiitic basalt lava Rhyolite lava Some lavas of unusual composition have erupted onto the surface of the Earth. These include: The term "lava" can also be used to refer to molten "ice mixtures" in eruptions on
8484-521: The minimal heat loss maintains a low viscosity. The surface texture of pāhoehoe flows varies widely, displaying all kinds of bizarre shapes often referred to as lava sculpture. With increasing distance from the source, pāhoehoe flows may change into ʻaʻā flows in response to heat loss and consequent increase in viscosity. Experiments suggest that the transition takes place at a temperature between 1,200 and 1,170 °C (2,190 and 2,140 °F), with some dependence on shear rate. Pahoehoe lavas typically have
8585-437: The misalignment between these regions forms boundaries that are key to data storage. The inductive head measures the orientation of the magnetic moments of these domain regions and reads out either a “1” or “0”. These bits are the data being read. Grain size is important in this technology because it limits the number of bits that can fit on one hard disk. The smaller the grain sizes, the more data that can be stored. Because of
8686-472: The motion of dislocations through a material. Dislocation propagation is impeded because of the stress field of the grain boundary defect region and the lack of slip planes and slip directions and overall alignment across the boundaries. Reducing grain size is therefore a common way to improve strength , often without any sacrifice in toughness because the smaller grains create more obstacles per unit area of slip plane. This crystallite size-strength relationship
8787-446: The physical behavior of silicate magmas. Silicon ions in lava strongly bind to four oxygen ions in a tetrahedral arrangement. If an oxygen ion is bound to two silicon ions in the melt, it is described as a bridging oxygen, and lava with many clumps or chains of silicon ions connected by bridging oxygen ions is described as partially polymerized. Aluminium in combination with alkali metal oxides (sodium and potassium) also tends to polymerize
8888-413: The process of forming a glass does not release the latent heat of fusion , but forming a crystal does. A crystal structure (an arrangement of atoms in a crystal) is characterized by its unit cell , a small imaginary box containing one or more atoms in a specific spatial arrangement. The unit cells are stacked in three-dimensional space to form the crystal. The symmetry of a crystal is constrained by
8989-440: The range of 850 to 1,100 °C (1,560 to 2,010 °F). Because of their lower silica content and higher eruptive temperatures, they tend to be much less viscous, with a typical viscosity of 3.5 × 10 cP (3,500 Pa⋅s) at 1,200 °C (2,190 °F). This is slightly greater than the viscosity of smooth peanut butter . Intermediate lavas show a greater tendency to form phenocrysts . Higher iron and magnesium tends to manifest as
9090-409: The rate of flow is proportional to the shear stress . Instead, a typical lava is a Bingham fluid , which shows considerable resistance to flow until a stress threshold, called the yield stress, is crossed. This results in plug flow of partially crystalline lava. A familiar example of plug flow is toothpaste squeezed out of a toothpaste tube. The toothpaste comes out as a semisolid plug, because shear
9191-432: The requirement that the unit cells stack perfectly with no gaps. There are 219 possible crystal symmetries (230 is commonly cited, but this treats chiral equivalents as separate entities), called crystallographic space groups . These are grouped into 7 crystal systems , such as cubic crystal system (where the crystals may form cubes or rectangular boxes, such as halite shown at right) or hexagonal crystal system (where
9292-625: The rocky crust. For instance, geologists of the United States Geological Survey regularly drilled into the Kilauea Iki lava lake, formed in an eruption in 1959. After three years, the solid surface crust, whose base was at a temperature of 1,065 °C (1,949 °F), was still only 14 m (46 ft) thick, even though the lake was about 100 m (330 ft) deep. Residual liquid was still present at depths of around 80 m (260 ft) nineteen years after
9393-423: The rougher and less stable parts of the surface, but less easily to the flat, stable surfaces. Therefore, the flat surfaces tend to grow larger and smoother, until the whole crystal surface consists of these plane surfaces. (See diagram on right.) One of the oldest techniques in the science of crystallography consists of measuring the three-dimensional orientations of the faces of a crystal, and using them to infer
9494-444: The same atoms may be able to form noncrystalline phases . For example, water can also form amorphous ice , while SiO 2 can form both fused silica (an amorphous glass) and quartz (a crystal). Likewise, if a substance can form crystals, it can also form polycrystals. For pure chemical elements, polymorphism is known as allotropy . For example, diamond and graphite are two crystalline forms of carbon , while amorphous carbon
9595-533: The structure of a single crystal is highly ordered and its lattice is continuous and unbroken, amorphous materials, such as glass and many polymers, are non-crystalline and do not display any structures, as their constituents are not arranged in an ordered manner. Polycrystalline structures and paracrystalline phases are in between these two extremes. Polycrystalline materials, or polycrystals, are solids that are composed of many crystallites of varying size and orientation. Most materials are polycrystalline, made of
9696-744: The substance, including hydrothermal synthesis , sublimation , or simply solvent-based crystallization . Large single crystals can be created by geological processes. For example, selenite crystals in excess of 10 m are found in the Cave of the Crystals in Naica, Mexico. For more details on geological crystal formation, see above . Crystals can also be formed by biological processes, see above . Conversely, some organisms have special techniques to prevent crystallization from occurring, such as antifreeze proteins . An ideal crystal has every atom in
9797-429: The underlying crystal symmetry . A crystal's crystallographic forms are sets of possible faces of the crystal that are related by one of the symmetries of the crystal. For example, crystals of galena often take the shape of cubes, and the six faces of the cube belong to a crystallographic form that displays one of the symmetries of the isometric crystal system . Galena also sometimes crystallizes as octahedrons, and
9898-620: The vacuum of space. The slow cooling may allow the precipitation of a separate phase within the crystal lattice, which form at specific angles determined by the lattice, called Widmanstatten patterns . Ionic compounds typically form when a metal reacts with a non-metal, such as sodium with chlorine. These often form substances called salts, such as sodium chloride (table salt) or potassium nitrate ( saltpeter ), with crystals that are often brittle and cleave relatively easily. Ionic materials are usually crystalline or polycrystalline. In practice, large salt crystals can be created by solidification of
9999-454: The volume fraction of grain boundaries approaches 100%, the material ceases to have any crystalline character, and thus becomes an amorphous solid . Grain boundaries are also present in magnetic domains in magnetic materials. A computer hard disk, for example, is made of a hard ferromagnetic material that contains regions of atoms whose magnetic moments can be realigned by an inductive head. The magnetization varies from region to region, and
10100-400: Was awarded to Dan Shechtman for the discovery of quasicrystals. Crystals can have certain special electrical, optical, and mechanical properties that glass and polycrystals normally cannot. These properties are related to the anisotropy of the crystal, i.e. the lack of rotational symmetry in its atomic arrangement. One such property is the piezoelectric effect , where a voltage across
10201-480: Was recorded following the collapse of a lava lake at Mount Nyiragongo . The scaling relationship for lavas is that the average speed of a flow scales as the square of its thickness divided by its viscosity. This implies that a rhyolite flow would have to be about a thousand times thicker than a basalt flow to flow at a similar speed. The temperature of most types of molten lava ranges from about 800 °C (1,470 °F) to 1,200 °C (2,190 °F) depending on
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