Beryllium oxide ( BeO ), also known as beryllia , is an inorganic compound with the formula BeO. This colourless solid is an electrical insulator with a higher thermal conductivity than any other non-metal except diamond , and exceeds that of most metals. As an amorphous solid , beryllium oxide is white. Its high melting point leads to its use as a refractory material. It occurs in nature as the mineral bromellite . Historically and in materials science , beryllium oxide was called glucina or glucinium oxide , owing to its sweet taste.
84-431: Beryllium oxide can be prepared by calcining (roasting) beryllium carbonate , dehydrating beryllium hydroxide , or igniting metallic beryllium : Igniting beryllium in air gives a mixture of BeO and the nitride Be 3 N 2 . Unlike the oxides formed by the other Group 2 elements ( alkaline earth metals ), beryllium oxide is amphoteric rather than basic. Beryllium oxide formed at high temperatures (>800 °C)
168-412: A thermionic tube or thermionic valve utilizes thermionic emission of electrons from a hot cathode for fundamental electronic functions such as signal amplification and current rectification . Non-thermionic types such as a vacuum phototube , however, achieve electron emission through the photoelectric effect , and are used for such purposes as the detection of light intensities. In both types,
252-404: A beam of electrons for display purposes (such as the television picture tube, in electron microscopy , and in electron beam lithography ); X-ray tubes ; phototubes and photomultipliers (which rely on electron flow through a vacuum where electron emission from the cathode depends on energy from photons rather than thermionic emission ). A vacuum tube consists of two or more electrodes in
336-550: A blower, or water-jacket. Klystrons and magnetrons often operate their anodes (called collectors in klystrons) at ground potential to facilitate cooling, particularly with water, without high-voltage insulation. These tubes instead operate with high negative voltages on the filament and cathode. Except for diodes, additional electrodes are positioned between the cathode and the plate (anode). These electrodes are referred to as grids as they are not solid electrodes but sparse elements through which electrons can pass on their way to
420-649: A blue glow. Finnish inventor Eric Tigerstedt significantly improved on the original triode design in 1914, while working on his sound-on-film process in Berlin, Germany. Tigerstedt's innovation was to make the electrodes concentric cylinders with the cathode at the centre, thus greatly increasing the collection of emitted electrons at the anode. Irving Langmuir at the General Electric research laboratory ( Schenectady, New York ) had improved Wolfgang Gaede 's high-vacuum diffusion pump and used it to settle
504-401: A certain sound or tone). Not all electronic circuit valves or electron tubes are vacuum tubes. Gas-filled tubes are similar devices, but containing a gas, typically at low pressure, which exploit phenomena related to electric discharge in gases , usually without a heater. One classification of thermionic vacuum tubes is by the number of active electrodes . A device with two active elements
588-524: A chronic allergic-type lung disease berylliosis . Once fired into solid form, it is safe to handle if not subjected to machining that generates dust. Clean breakage releases little dust, but crushing or grinding actions can pose a risk. Calcination Calcination is thermal treatment of a solid chemical compound (e.g. mixed carbonate ores ) whereby the compound is raised to high temperature without melting under restricted supply of ambient oxygen (i.e. gaseous O 2 fraction of air), generally for
672-501: A combination of a triode with a hexode and even an octode have been used for this purpose. The additional grids include control grids (at a low potential) and screen grids (at a high voltage). Many designs use such a screen grid as an additional anode to provide feedback for the oscillator function, whose current adds to that of the incoming radio frequency signal. The pentagrid converter thus became widely used in AM receivers, including
756-466: A common circuit (which can be AC without inducing hum) while allowing the cathodes in different tubes to operate at different voltages. H. J. Round invented the indirectly heated tube around 1913. The filaments require constant and often considerable power, even when amplifying signals at the microwatt level. Power is also dissipated when the electrons from the cathode slam into the anode (plate) and heat it; this can occur even in an idle amplifier due to
840-586: A far superior and versatile technology for use in radio transmitters and receivers. At the end of the 19th century, radio or wireless technology was in an early stage of development and the Marconi Company was engaged in development and construction of radio communication systems. Guglielmo Marconi appointed English physicist John Ambrose Fleming as scientific advisor in 1899. Fleming had been engaged as scientific advisor to Edison Telephone (1879), as scientific advisor at Edison Electric Light (1882), and
924-432: A good electrical insulator. It is used as a filler in some thermal interface materials such as thermal grease . It is also employed in heat sinks and spreaders that cool electronic devices, such as CPUs , lasers, and power amplifiers. Some power semiconductor devices have used beryllium oxide ceramic between the silicon chip and the metal mounting base of the package to achieve a lower value of thermal resistance than
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#17327929492571008-400: A low potential space charge region between the anode and screen grid to return anode secondary emission electrons to the anode when the anode potential is less than that of the screen grid. Formation of beams also reduces screen grid current. In some cylindrically symmetrical beam power tubes, the cathode is formed of narrow strips of emitting material that are aligned with the apertures of
1092-414: A pair of beam deflection electrodes which deflected the current towards either of two anodes. They were sometimes known as the 'sheet beam' tubes and used in some color TV sets for color demodulation . The similar 7360 was popular as a balanced SSB (de)modulator . A beam tetrode (or "beam power tube") forms the electron stream from the cathode into multiple partially collimated beams to produce
1176-412: A printing instrument was needed. As a result of experiments conducted on Edison effect bulbs, Fleming developed a vacuum tube that he termed the oscillation valve because it passed current in only one direction. The cathode was a carbon lamp filament, heated by passing current through it, that produced thermionic emission of electrons. Electrons that had been emitted from the cathode were attracted to
1260-509: A relatively low-value resistor is connected between the cathode and ground. This makes the cathode positive with respect to the grid, which is at ground potential for DC. However C batteries continued to be included in some equipment even when the "A" and "B" batteries had been replaced by power from the AC mains. That was possible because there was essentially no current draw on these batteries; they could thus last for many years (often longer than all
1344-422: A similar construction of aluminium oxide . It is also used as a structural ceramic for high-performance microwave devices, vacuum tubes , cavity magnetrons , and gas lasers . BeO has been proposed as a neutron moderator for naval marine high-temperature gas-cooled reactors (MGCR), as well as NASA 's Kilopower nuclear reactor for space applications. BeO is carcinogenic in powdered form and may cause
1428-407: A simple oscillator only requiring connection of the plate to a resonant LC circuit to oscillate. The dynatron oscillator operated on the same principle of negative resistance as the tunnel diode oscillator many years later. The dynatron region of the screen grid tube was eliminated by adding a grid between the screen grid and the plate to create the pentode . The suppressor grid of the pentode
1512-419: A small-signal vacuum tube are 1 to 10 millisiemens. It is one of the three 'constants' of a vacuum tube, the other two being its gain μ and plate resistance R p or R a . The Van der Bijl equation defines their relationship as follows: g m = μ R p {\displaystyle g_{m}={\mu \over R_{p}}} The non-linear operating characteristic of
1596-464: A vacuum inside an airtight envelope. Most tubes have glass envelopes with a glass-to-metal seal based on kovar sealable borosilicate glasses , although ceramic and metal envelopes (atop insulating bases) have been used. The electrodes are attached to leads which pass through the envelope via an airtight seal. Most vacuum tubes have a limited lifetime, due to the filament or heater burning out or other failure modes, so they are made as replaceable units;
1680-519: A variety of colours to the otherwise colourless host crystals. Sintered beryllium oxide is a very stable ceramic . Beryllium oxide is used in rocket engines and as a transparent protective over-coating on aluminised telescope mirrors . Metal-coated beryllium oxide (BeO) plates are used in the control systems of aircraft drive devices. Beryllium oxide is used in many high-performance semiconductor parts for applications such as radio equipment because it has good thermal conductivity while also being
1764-440: A white calx". He claimed "That this increase in weight comes from the air, which in the vessel has been rendered denser, heavier, and in some measure adhesive, by the vehement and long-continued heat of the furnace: which air mixes with the calx (frequent agitation aiding) and becomes attached to its most minute particles: not otherwise than water makes heavier sand which you throw into it and agitate, by moistening it and adhering to
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#17327929492571848-429: A wide range of frequencies. To combat the stability problems of the triode as a radio frequency amplifier due to grid-to-plate capacitance, the physicist Walter H. Schottky invented the tetrode or screen grid tube in 1919. He showed that the addition of an electrostatic shield between the control grid and the plate could solve the problem. This design was refined by Hull and Williams. The added grid became known as
1932-445: Is a current . Compare this to the behavior of the bipolar junction transistor , in which the controlling signal is a current and the output is also a current. For vacuum tubes, transconductance or mutual conductance ( g m ) is defined as the change in the plate(anode)/cathode current divided by the corresponding change in the grid to cathode voltage, with a constant plate(anode) to cathode voltage. Typical values of g m for
2016-489: Is a diode , usually used for rectification . Devices with three elements are triodes used for amplification and switching . Additional electrodes create tetrodes , pentodes , and so forth, which have multiple additional functions made possible by the additional controllable electrodes. Other classifications are: Vacuum tubes may have other components and functions than those described above, and are described elsewhere. These include as cathode-ray tubes , which create
2100-489: Is also used as a chemical flux in smelting . Industrial calcination generally emits carbon dioxide (CO 2 ). A calciner is a steel cylinder that rotates inside a heated furnace and performs indirect high-temperature processing (550–1150 °C, or 1000–2100 °F) within a controlled atmosphere. The process of calcination derives its name from the Latin calcinare 'to burn lime' due to its most common application,
2184-474: Is inert, but dissolves easily in hot aqueous ammonium bifluoride (NH 4 HF 2 ) or a solution of hot concentrated sulfuric acid (H 2 SO 4 ) and ammonium sulfate ((NH 4 ) 2 SO 4 ). BeO crystallizes in the hexagonal wurtzite structure, featuring tetrahedral Be and O centres, like lonsdaleite and w- BN (with both of which it is isoelectronic ). In contrast, the oxides of the larger group-2 metals, i.e., MgO , CaO , SrO , BaO , crystallize in
2268-410: Is not important since they are simply re-captured by the plate. But in a tetrode they can be captured by the screen grid since it is also at a positive voltage, robbing them from the plate current and reducing the amplification of the tube. Since secondary electrons can outnumber the primary electrons over a certain range of plate voltages, the plate current can decrease with increasing plate voltage. This
2352-564: Is the Loewe 3NF . This 1920s device has three triodes in a single glass envelope together with all the fixed capacitors and resistors required to make a complete radio receiver. As the Loewe set had only one tube socket, it was able to substantially undercut the competition, since, in Germany, state tax was levied by the number of sockets. However, reliability was compromised, and production costs for
2436-416: Is the dynatron region or tetrode kink and is an example of negative resistance which can itself cause instability. Another undesirable consequence of secondary emission is that screen current is increased, which may cause the screen to exceed its power rating. The otherwise undesirable negative resistance region of the plate characteristic was exploited with the dynatron oscillator circuit to produce
2520-564: The Edison effect , that became well known. Although Edison was aware of the unidirectional property of current flow between the filament and the anode, his interest (and patent ) concentrated on the sensitivity of the anode current to the current through the filament (and thus filament temperature). It was years later that John Ambrose Fleming applied the rectifying property of the Edison effect to detection of radio signals, as an improvement over
2604-684: The plate ( anode ) when the plate was at a positive voltage with respect to the cathode. Electrons could not pass in the reverse direction because the plate was not heated and not capable of thermionic emission of electrons. Fleming filed a patent for these tubes, assigned to the Marconi company, in the UK in November 1904 and this patent was issued in September 1905. Later known as the Fleming valve ,
Beryllium oxide - Misplaced Pages Continue
2688-429: The screen grid or shield grid . The screen grid is operated at a positive voltage significantly less than the plate voltage and it is bypassed to ground with a capacitor of low impedance at the frequencies to be amplified. This arrangement substantially decouples the plate and the control grid , eliminating the need for neutralizing circuitry at medium wave broadcast frequencies. The screen grid also largely reduces
2772-480: The 6GH8 /ECF82 triode-pentode, quite popular in television receivers. The desire to include even more functions in one envelope resulted in the General Electric Compactron which has 12 pins. A typical example, the 6AG11, contains two triodes and two diodes. Some otherwise conventional tubes do not fall into standard categories; the 6AR8, 6JH8 and 6ME8 have several common grids, followed by
2856-482: The 6SN7 , is a "dual triode" which performs the functions of two triode tubes while taking up half as much space and costing less. The 12AX7 is a dual "high mu" (high voltage gain ) triode in a miniature enclosure, and became widely used in audio signal amplifiers, instruments, and guitar amplifiers . The introduction of the miniature tube base (see below) which can have 9 pins, more than previously available, allowed other multi-section tubes to be introduced, such as
2940-467: The magnetic detector . Amplification by vacuum tube became practical only with Lee de Forest 's 1907 invention of the three-terminal " audion " tube, a crude form of what was to become the triode . Being essentially the first electronic amplifier , such tubes were instrumental in long-distance telephony (such as the first coast-to-coast telephone line in the US) and public address systems , and introduced
3024-468: The quiescent current necessary to ensure linearity and low distortion. In a power amplifier, this heating can be considerable and can destroy the tube if driven beyond its safe limits. Since the tube contains a vacuum, the anodes in most small and medium power tubes are cooled by radiation through the glass envelope. In some special high power applications, the anode forms part of the vacuum envelope to conduct heat to an external heat sink, usually cooled by
3108-462: The spark gap transmitter for radio or mechanical computers for computing, it was the invention of the thermionic vacuum tube that made these technologies widespread and practical, and created the discipline of electronics . In the 1940s, the invention of semiconductor devices made it possible to produce solid-state devices, which are smaller, safer, cooler, and more efficient, reliable, durable, and economical than thermionic tubes. Beginning in
3192-413: The 19th century, telegraph and telephone engineers had recognized the need to extend the distance that signals could be transmitted. In 1906, Robert von Lieben filed for a patent for a cathode-ray tube which used an external magnetic deflection coil and was intended for use as an amplifier in telephony equipment. This von Lieben magnetic deflection tube was not a successful amplifier, however, because of
3276-485: The Audion for demonstration to AT&T's engineering department. Dr. Harold D. Arnold of AT&T recognized that the blue glow was caused by ionized gas. Arnold recommended that AT&T purchase the patent, and AT&T followed his recommendation. Arnold developed high-vacuum tubes which were tested in the summer of 1913 on AT&T's long-distance network. The high-vacuum tubes could operate at high plate voltages without
3360-400: The allied military by 1916. Historically, vacuum levels in production vacuum tubes typically ranged from 10 μPa down to 10 nPa (8 × 10 Torr down to 8 × 10 Torr). The triode and its derivatives (tetrodes and pentodes) are transconductance devices, in which the controlling signal applied to the grid is a voltage , and the resulting amplified signal appearing at the anode
3444-409: The base. There was even an occasional design that had two top cap connections. The earliest vacuum tubes evolved from incandescent light bulbs , containing a filament sealed in an evacuated glass envelope. When hot, the filament in a vacuum tube (a cathode ) releases electrons into the vacuum, a process called thermionic emission . This can produce a controllable unidirectional current though
Beryllium oxide - Misplaced Pages Continue
3528-536: The cathode, no direct current could pass from the cathode to the grid. Thus a change of voltage applied to the grid, requiring very little power input to the grid, could make a change in the plate current and could lead to a much larger voltage change at the plate; the result was voltage and power amplification . In 1908, de Forest was granted a patent ( U.S. patent 879,532 ) for such a three-electrode version of his original Audion for use as an electronic amplifier in radio communications. This eventually became known as
3612-408: The chemical reaction is Today, this reaction largely occurs in a cement kiln . The standard Gibbs free energy of reaction in [J/mol] is approximated as Δ G ° r ≈ 177,100 J/mol − 158 J/(mol*K) * T . The standard free energy of reaction is 0 in this case when the temperature, T , is equal to 1121 K, or 848 °C. In some cases, calcination of a metal results in oxidation of
3696-517: The cubic rock salt motif with octahedral geometry about the dications and dianions. At high temperature the structure transforms to a tetragonal form. In the vapour phase, beryllium oxide is present as discrete diatomic molecules . In the language of valence bond theory , these molecules can be described as adopting sp orbital hybridisation on both atoms, featuring one σ bond (between one sp orbital on each atom) and one π bond (between aligned p orbitals on each atom oriented perpendicular to
3780-537: The decomposition of calcium carbonate ( limestone ) to calcium oxide ( lime ) and carbon dioxide , in order to create cement . The product of calcination is usually referred to in general as "calcine", regardless of the actual minerals undergoing thermal treatment. Calcination is carried out in furnaces or reactors (sometimes referred to as kilns or calciners) of various designs including shaft furnaces, rotary kilns , multiple hearth furnaces , and fluidized bed reactors . Examples of calcination processes include
3864-418: The electrode leads connect to pins on the tube's base which plug into a tube socket . Tubes were a frequent cause of failure in electronic equipment, and consumers were expected to be able to replace tubes themselves. In addition to the base terminals, some tubes had an electrode terminating at a top cap . The principal reason for doing this was to avoid leakage resistance through the tube base, particularly for
3948-426: The electrons are accelerated from the cathode to the anode by the electric field in the tube. The simplest vacuum tube, the diode (i.e. Fleming valve ), was invented in 1904 by John Ambrose Fleming . It contains only a heated electron-emitting cathode and an anode. Electrons can flow in only one direction through the device – from the cathode to the anode. Adding one or more control grids within
4032-425: The exception of early light bulbs , such tubes were only used in scientific research or as novelties. The groundwork laid by these scientists and inventors, however, was critical to the development of subsequent vacuum tube technology. Although thermionic emission was originally reported in 1873 by Frederick Guthrie , it was Thomas Edison's apparently independent discovery of the phenomenon in 1883, referred to as
4116-403: The filament as the cathode; this is called a "directly heated" tube. Most modern tubes are "indirectly heated" by a "heater" element inside a metal tube that is the cathode. The heater is electrically isolated from the surrounding cathode and simply serves to heat the cathode sufficiently for thermionic emission of electrons. The electrical isolation allows all the tubes' heaters to be supplied from
4200-457: The following: Calcination reactions usually take place at or above the thermal decomposition temperature (for decomposition and volatilization reactions) or the transition temperature (for phase transitions ). This temperature is usually defined as the temperature at which the standard Gibbs free energy for a particular calcination reaction is equal to zero. In limestone calcination, a decomposition process that occurs at 900 to 1050 °C,
4284-400: The high impedance grid input. The bases were commonly made with phenolic insulation which performs poorly as an insulator in humid conditions. Other reasons for using a top cap include improving stability by reducing grid-to-anode capacitance, improved high-frequency performance, keeping a very high plate voltage away from lower voltages, and accommodating one more electrode than allowed by
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#17327929492574368-411: The influence of the plate voltage on the space charge near the cathode, permitting the tetrode to produce greater voltage gain than the triode in amplifier circuits. While the amplification factors of typical triodes commonly range from below ten to around 100, tetrode amplification factors of 500 are common. Consequently, higher voltage gains from a single tube amplification stage became possible, reducing
4452-423: The metal to produce a metal oxide . In his essay " Formal response to the question, why Tin and Lead increase in weight when they are calcined " (1630), Jean Rey notes that "having placed two pounds six ounces of fine English tin in an iron vessel and heated it strongly on an open furnace for the space of six hours with continual agitation and without adding anything to it, he recovered two pounds thirteen ounces of
4536-573: The mid-1960s, thermionic tubes were being replaced by the transistor . However, the cathode-ray tube (CRT) remained the basis for television monitors and oscilloscopes until the early 21st century. Thermionic tubes are still employed in some applications, such as the magnetron used in microwave ovens, certain high-frequency amplifiers , and high end audio amplifiers, which many audio enthusiasts prefer for their "warmer" tube sound , and amplifiers for electric musical instruments such as guitars (for desired effects, such as "overdriving" them to achieve
4620-561: The miniature tube version of the " All American Five ". Octodes, such as the 7A8, were rarely used in the United States, but much more common in Europe, particularly in battery operated radios where the lower power consumption was an advantage. To further reduce the cost and complexity of radio equipment, two separate structures (triode and pentode for instance) can be combined in the bulb of a single multisection tube . An early example
4704-512: The molecular axis is unfilled. The corresponding ground state is ...(2sσ)(2sσ*)(2pπ) (as in the isoelectronic C 2 molecule), where both bonds can be considered as dative bonds from oxygen towards beryllium. High-quality crystals may be grown hydrothermally , or otherwise by the Verneuil method . For the most part, beryllium oxide is produced as a white amorphous powder, sintered into larger shapes. Impurities, like carbon, can give rise to
4788-405: The molecular axis). Molecular orbital theory provides a slightly different picture with no net σ bonding (because the 2 s orbitals of the two atoms combine to form a filled sigma bonding orbital and a filled sigma* anti-bonding orbital) and two π bonds formed between both pairs of p orbitals oriented perpendicular to the molecular axis. The sigma orbital formed by the p orbitals aligned along
4872-431: The number of external pins (leads) often forced the functions to share some of those external connections such as their cathode connections (in addition to the heater connection). The RCA Type 55 is a double diode triode used as a detector, automatic gain control rectifier and audio preamplifier in early AC powered radios. These sets often include the 53 Dual Triode Audio Output. Another early type of multi-section tube,
4956-435: The number of tubes required. Screen grid tubes were marketed by late 1927. However, the useful region of operation of the screen grid tube as an amplifier was limited to plate voltages greater than the screen grid voltage, due to secondary emission from the plate. In any tube, electrons strike the plate with sufficient energy to cause the emission of electrons from its surface. In a triode this secondary emission of electrons
5040-451: The obsolete phlogiston theory , the ' calx ' was the true elemental substance that was left after phlogiston was driven out of it in the process of combustion . Vacuum tube A vacuum tube , electron tube , valve (British usage), or tube (North America) is a device that controls electric current flow in a high vacuum between electrodes to which an electric potential difference has been applied. The type known as
5124-528: The oscillation valve was developed for the purpose of rectifying radio frequency current as the detector component of radio receiver circuits. While offering no advantage over the electrical sensitivity of crystal detectors , the Fleming valve offered advantage, particularly in shipboard use, over the difficulty of adjustment of the crystal detector and the susceptibility of the crystal detector to being dislodged from adjustment by vibration or bumping. In
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#17327929492575208-652: The plate current, possibly changing the output by hundreds of volts (depending on the circuit). The solid-state device which operates most like the pentode tube is the junction field-effect transistor (JFET), although vacuum tubes typically operate at over a hundred volts, unlike most semiconductors in most applications. The 19th century saw increasing research with evacuated tubes, such as the Geissler and Crookes tubes . The many scientists and inventors who experimented with such tubes include Thomas Edison , Eugen Goldstein , Nikola Tesla , and Johann Wilhelm Hittorf . With
5292-471: The plate, it creates an electric field due to the potential difference between them. Such a tube with only two electrodes is termed a diode , and is used for rectification . Since current can only pass in one direction, such a diode (or rectifier ) will convert alternating current (AC) to pulsating DC. Diodes can therefore be used in a DC power supply , as a demodulator of amplitude modulated (AM) radio signals and for similar functions. Early tubes used
5376-405: The plate. The vacuum tube is then known as a triode , tetrode , pentode , etc., depending on the number of grids. A triode has three electrodes: the anode, cathode, and one grid, and so on. The first grid, known as the control grid, (and sometimes other grids) transforms the diode into a voltage-controlled device : the voltage applied to the control grid affects the current between the cathode and
5460-414: The plate. When held negative with respect to the cathode, the control grid creates an electric field that repels electrons emitted by the cathode, thus reducing or even stopping the current between cathode and anode. As long as the control grid is negative relative to the cathode, essentially no current flows into it, yet a change of several volts on the control grid is sufficient to make a large difference in
5544-399: The power used by the deflection coil. Von Lieben would later make refinements to triode vacuum tubes. Lee de Forest is credited with inventing the triode tube in 1907 while experimenting to improve his original (diode) Audion . By placing an additional electrode between the filament ( cathode ) and plate (anode), he discovered the ability of the resulting device to amplify signals. As
5628-448: The present-day C cell , for which the letter denotes its size and shape). The C battery's positive terminal was connected to the cathode of the tubes (or "ground" in most circuits) and whose negative terminal supplied this bias voltage to the grids of the tubes. Later circuits, after tubes were made with heaters isolated from their cathodes, used cathode biasing , avoiding the need for a separate negative power supply. For cathode biasing,
5712-419: The purpose of removing impurities or volatile substances and/or to incur thermal decomposition . The root of the word calcination refers to its most prominent use, which is to remove carbon from limestone (calcium carbonate) through combustion to yield calcium oxide (quicklime) . This calcination reaction is CaCO 3 (s) → CaO(s) + CO 2 (g). Calcium oxide is a crucial ingredient in modern cement , and
5796-532: The question of thermionic emission and conduction in a vacuum. Consequently, General Electric started producing hard vacuum triodes (which were branded Pliotrons) in 1915. Langmuir patented the hard vacuum triode, but de Forest and AT&T successfully asserted priority and invalidated the patent. Pliotrons were closely followed by the French type ' TM ' and later the English type 'R' which were in widespread use by
5880-425: The smallest of its grains", presumably the metal gained weight as it was being oxidized. At room temperature, tin is quite resistant to the impact of air or water, as a thin oxide film forms on the surface of the metal. In air, tin starts to oxidize at a temperature of over 150 °C: Sn + O 2 → SnO 2 . Antoine Lavoisier explored this experiment with similar results time later. In alchemy , calcination
5964-440: The suppressor grid wired internally to the cathode (e.g. EL84/6BQ5) and those with the suppressor grid wired to a separate pin for user access (e.g. 803, 837). An alternative solution for power applications is the beam tetrode or beam power tube , discussed below. Superheterodyne receivers require a local oscillator and mixer , combined in the function of a single pentagrid converter tube. Various alternatives such as using
6048-458: The triode caused early tube audio amplifiers to exhibit harmonic distortion at low volumes. Plotting plate current as a function of applied grid voltage, it was seen that there was a range of grid voltages for which the transfer characteristics were approximately linear. To use this range, a negative bias voltage had to be applied to the grid to position the DC operating point in the linear region. This
6132-407: The triode. De Forest's original device was made with conventional vacuum technology. The vacuum was not a "hard vacuum" but rather left a very small amount of residual gas. The physics behind the device's operation was also not settled. The residual gas would cause a blue glow (visible ionization) when the plate voltage was high (above about 60 volts). In 1912, de Forest and John Stone Stone brought
6216-464: The tube allows the current between the cathode and anode to be controlled by the voltage on the grids. These devices became a key component of electronic circuits for the first half of the twentieth century. They were crucial to the development of radio , television , radar , sound recording and reproduction , long-distance telephone networks, and analog and early digital computers . Although some applications had used earlier technologies such as
6300-646: The tube were much greater. In a sense, these were akin to integrated circuits. In the United States, Cleartron briefly produced the "Multivalve" triple triode for use in the Emerson Baby Grand receiver. This Emerson set also has a single tube socket, but because it uses a four-pin base, the additional element connections are made on a "mezzanine" platform at the top of the tube base. By 1940 multisection tubes had become commonplace. There were constraints, however, due to patents and other licensing considerations (see British Valve Association ). Constraints due to
6384-482: The tubes) without requiring replacement. When triodes were first used in radio transmitters and receivers, it was found that tuned amplification stages had a tendency to oscillate unless their gain was very limited. This was due to the parasitic capacitance between the plate (the amplifier's output) and the control grid (the amplifier's input), known as the Miller capacitance . Eventually the technique of neutralization
6468-420: The vacuum known as the Edison effect . A second electrode, the anode or plate , will attract those electrons if it is at a more positive voltage. The result is a net flow of electrons from the filament to plate. However, electrons cannot flow in the reverse direction because the plate is not heated and does not emit electrons. The filament has a dual function: it emits electrons when heated; and, together with
6552-421: The voltage applied to the control grid (or simply "grid") was lowered from the cathode's voltage to somewhat more negative voltages, the amount of current from the filament to the plate would be reduced. The negative electrostatic field created by the grid in the vicinity of the cathode would inhibit the passage of emitted electrons and reduce the current to the plate. With the voltage of the grid less than that of
6636-449: Was also technical consultant to Edison-Swan . One of Marconi's needs was for improvement of the detector , a device that extracts information from a modulated radio frequency. Marconi had developed a magnetic detector , which was less responsive to natural sources of radio frequency interference than the coherer , but the magnetic detector only provided an audio frequency signal to a telephone receiver. A reliable detector that could drive
6720-412: Was believed to be one of the 12 vital processes required for the transformation of a substance. Alchemists distinguished two kinds of calcination, actual and potential . Actual calcination is that brought about by actual fire, from wood, coals, or other fuel, raised to a certain temperature. Potential calcination is that brought about by potential fire, such as corrosive chemicals; for example, gold
6804-498: Was calcined in a reverberatory furnace with mercury and salammoniac ; silver with common salt and alkali salt ; copper with salt and sulfur ; iron with salammoniac and vinegar ; tin with antimony ; lead with sulfur; and mercury with nitric acid . There was also philosophical calcination , which was said to occur when horns, hooves, etc., were hung over boiling water, or other liquor, until they had lost their mucilage , and were easily reducible into powder. According to
6888-405: Was called the idle condition, and the plate current at this point the "idle current". The controlling voltage was superimposed onto the bias voltage, resulting in a linear variation of plate current in response to positive and negative variation of the input voltage around that point. This concept is called grid bias . Many early radio sets had a third battery called the "C battery" (unrelated to
6972-617: Was developed whereby the RF transformer connected to the plate (anode) would include an additional winding in the opposite phase. This winding would be connected back to the grid through a small capacitor, and when properly adjusted would cancel the Miller capacitance. This technique was employed and led to the success of the Neutrodyne radio during the 1920s. However, neutralization required careful adjustment and proved unsatisfactory when used over
7056-401: Was usually connected to the cathode and its negative voltage relative to the anode repelled secondary electrons so that they would be collected by the anode instead of the screen grid. The term pentode means the tube has five electrodes. The pentode was invented in 1926 by Bernard D. H. Tellegen and became generally favored over the simple tetrode. Pentodes are made in two classes: those with
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