81-687: An eraser (also known as a rubber in some Commonwealth countries, including South Africa from which the material first used got its name) is an article of stationery that is used for removing marks from paper or skin (e.g. parchment or vellum ). Erasers have a rubbery consistency and come in a variety of shapes, sizes, and colors. Some pencils have an eraser on one end. Erasers can come in various shapes and colors. Less expensive erasers are made from synthetic rubber and synthetic soy -based gum, but more expensive or specialized erasers are made from vinyl , plastic , or gum -like materials. At first, erasers were invented to erase mistakes made with
162-411: A pencil ; later, more abrasive ink erasers were introduced. The term is also used for things that remove marks from chalkboards and whiteboards . Before rubber erasers used today, tablets of wax were used to erase lead or charcoal marks from paper. Bits of rough stone such as sandstone or pumice were used to remove small errors from parchment or papyrus documents written in ink. Crustless bread
243-568: A plasticizer such as vegetable oil. They are relatively hard (in order to remain attached to the pencil) and frequently colored pink. They can also be permanently attached to the end of a pencil with a ferrule . The stylized word "Art gum" was first used in 1903 and trademarked in the United States in 1907. That type of eraser was originally made from oils such as corn oil vulcanized with sulfur dichloride although it may now be made from natural or synthetic rubber or vinyl compounds. It
324-409: A dark surface (e.g., white on black, or yellow on green); it can be rubbed off with a soft material, such as a rag. Erasers for chalkboards are made, with a block of plastic or wood, much larger than an eraser for pen or pencil, with a layer of felt on one side. The block is held in the hand and the felt rubbed against the writing, which it easily wipes off. Chalk dust is released, some of which sticks to
405-447: A fiber, sometimes called 'elastic', had significant value to the textile industry because of its excellent elongation and recovery properties. For these purposes, manufactured rubber fiber was made as either an extruded round fiber or rectangular fibers cut into strips from extruded film. Because of its low dye acceptance, feel and appearance, the rubber fiber was either covered by yarn of another fiber or directly woven with other yarns into
486-509: A footnote: "I have seen a substance excellently adapted to the purpose of wiping from paper the mark of black-lead-pencil. ... It is sold by Mr. Nairne, Mathematical Instrument-Maker, opposite the Royal-Exchange." In 1770 the word rubber was in general use for any object used for rubbing; the word became attached to the new material sometime between 1770 and 1778. However, raw rubber was perishable. In 1839 Charles Goodyear discovered
567-510: A form of assisted biological coagulation. Little care is taken to exclude twigs, leaves, and even bark from the lumps that are formed, which may also include tree lace. Earth scrap is material that gathers around the base of the tree. It arises from latex overflowing from the cut and running down the bark, from rain flooding a collection cup containing latex, and from spillage from tappers' buckets during collection. It contains soil and other contaminants, and has variable rubber content, depending on
648-752: A given strain, thereby increasing the elastic force constant and making the rubber harder and less extensible. Raw rubber storage depots and rubber processing can produce malodour that is serious enough to become a source of complaints and protest to those living in the vicinity. Microbial impurities originate during the processing of block rubber. These impurities break down during storage or thermal degradation and produce volatile organic compounds. Examination of these compounds using gas chromatography / mass spectrometry (GC/MS) and gas chromatography (GC) indicates that they contain sulfur, ammonia, alkenes , ketones , esters , hydrogen sulfide , nitrogen, and low-molecular-weight fatty acids (C2–C5). When latex concentrate
729-432: A petroleum refinery or other natural incineration processes, is sometimes used as an additive to rubber to improve its strength, especially in vehicle tires. During vulcanization, rubber's polyisoprene molecules (long chains of isoprene) are heated and cross-linked with molecular bonds to sulfur, forming a 3-D matrix. The optimal percentage of sulfur is approximately 10%. In this form, the polyisoprene molecules orientation
810-506: A piece of the material was extremely good for rubbing off pencil marks on paper, hence the name "rubber". It slowly made its way around England. In 1764, François Fresnau discovered that turpentine was a rubber solvent . Giovanni Fabbroni is credited with the discovery of naphtha as a rubber solvent in 1779. Charles Goodyear redeveloped vulcanization in 1839, although Mesoamericans had used stabilized rubber for balls and other objects as early as 1600 BC. South America remained
891-697: A point for erasing small areas and tight detail erasing, molded into a textured surface and used as a reverse stamp to give texture, or used in a "blotting" manner to lighten lines or shading without completely erasing them. They gradually lose their efficacy and resilience as they become infused with particles picked up from erasing and from their environment. They are not suited to erase large areas because of their tendency to deform under vigorous erasing. Commonly sold in retail outlets with school supplies and home improvement products, this soft, malleable putty appears in many colors and under numerous brand names. Intended to adhere posters and prints to walls without damaging
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#1732787368481972-435: A point where it shares properties of both; i.e., if it is heated and cooled, it is degraded but not destroyed. The final properties of a rubber item depend not just on the polymer, but also on modifiers and fillers, such as carbon black , factice , whiting and others. Rubber particles are formed in the cytoplasm of specialized latex-producing cells called laticifers within rubber plants. Rubber particles are surrounded by
1053-474: A replaceable cylinder of eraser material held by a chuck driven on the axis of a motor. The speed of rotation allowed less pressure to be used, which minimized paper damage. Originally standard pencil-eraser rubber was used, later replaced by higher-performance vinyl. Dremel went on to develop an entire line of hand-held rotary power tools. A fiberglass eraser, a bundle of very fine glass fibers, can be used for erasing and other tasks requiring abrasion. Typically
1134-451: A significant amount of rubber. Gloves (medical, household, and industrial) and toy balloons were large consumers of rubber, although the type of rubber used is concentrated latex. Significant tonnage of rubber was used as adhesives in many manufacturing industries and products, although the two most noticeable were the paper and the carpet industries. Rubber was commonly used to make rubber bands and pencil erasers . Rubber produced as
1215-453: A single phospholipid membrane with hydrophobic tails pointed inward. The membrane allows biosynthetic proteins to be sequestered at the surface of the growing rubber particle, which allows new monomeric units to be added from outside the biomembrane, but within the lacticifer. The rubber particle is an enzymatically active entity that contains three layers of material, the rubber particle, a biomembrane and free monomeric units. The biomembrane
1296-516: A thermoplastic elastomer combines a styrene resin elastomer and an olefin resin. These erasers have better erasability for erasing pencil marks compared to conventional vinyl erasers. Elastomers can be formed into thin cylindrical or other shapes to be used as extendable erasers. Kneaded erasers (called putty rubbers outside the United States) have a plastic consistency and are common to most artists' standard toolkit. They can be pulled into
1377-414: A very hard and massive limestone. Because fiberglass erasers shed fiberglass dust when used, care must be taken during and after use to avoid accidental contamination with this abrasive dust in sensitive areas of the body, especially in the eyes. Felt chalkboard erasers or blackboard dusters are used to erase chalk markings on a chalkboard . Chalk writing leaves light-colored particles weakly adhering to
1458-401: A wire that encircles the tree. This wire incorporates a spring so it can stretch as the tree grows. The latex is led into the cup by a galvanised "spout" knocked into the bark. Rubber tapping normally takes place early in the morning, when the internal pressure of the tree is highest. A good tapper can tap a tree every 20 seconds on a standard half-spiral system, and a common daily "task" size
1539-442: Is 25 cm (vertical) bark consumption per year. The latex-containing tubes in the bark ascend in a spiral to the right. For this reason, tapping cuts usually ascend to the left to cut more tubes. The trees drip latex for about four hours, stopping as latex coagulates naturally on the tapping cut, thus blocking the latex tubes in the bark. Tappers usually rest and have a meal after finishing their tapping work and then start collecting
1620-418: Is a natural polymer of isoprene (polyisoprene), and an elastomer (a stretchy polymer). Polymers are simply chains of molecules that can be linked together. Rubber is one of the few naturally occurring polymers and prized for its high stretch ratio, resilience, and water-proof properties. Other examples of natural polymers include tortoise shell , amber , and animal horn . When harvested, latex rubber takes
1701-415: Is between 450 and 650 trees. Trees are usually tapped on alternate or third days, although many variations in timing, length and number of cuts are used. "Tappers would make a slash in the bark with a small hatchet. These slanting cuts allowed latex to flow from ducts located on the exterior or the inner layer of bark ( cambium ) of the tree. Since the cambium controls the growth of the tree, growth stops if it
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#17327873684811782-496: Is cut. Thus, rubber tapping demanded accuracy, so that the incisions would not be too many given the size of the tree, or too deep, which could stunt its growth or kill it." It is usual to tap a panel at least twice, sometimes three times, during the tree's life. The economic life of the tree depends on how well the tapping is carried out, as the critical factor is bark consumption. A standard in Malaysia for alternate daily tapping
1863-555: Is harvested mainly in the form of the latex from the Pará rubber tree ( Hevea brasiliensis ) or others. The latex is a sticky, milky and white colloid drawn off by making incisions in the bark and collecting the fluid in vessels in a process called "tapping". The latex then is refined into the rubber that is ready for commercial processing. In major areas, latex is allowed to coagulate in the collection cup. The coagulated lumps are collected and processed into dry forms for sale. Natural rubber
1944-438: Is held tightly to the rubber core by the high negative charge along the double bonds of the rubber polymer backbone. Free monomeric units and conjugated proteins make up the outer layer. The rubber precursor is isopentenyl pyrophosphate (an allylic compound), which elongates by Mg -dependent condensation by the action of rubber transferase. The monomer adds to the pyrophosphate end of the growing polymer. The process displaces
2025-449: Is in cooking, where its high smoke point makes refined corn oil a valuable frying oil. It is also a key ingredient in some margarines . Corn oil is generally less expensive than most other types of vegetable oils . Corn oil is also a feedstock used for biodiesel . Other industrial uses for corn oil include soap , salve , paint , erasers , rustproofing for metal surfaces, inks , textiles , nitroglycerin , and insecticides . It
2106-484: Is instead absorbed into the discarded vinyl scraps. Being softer and non-abrasive, they are less likely to damage canvas or paper. Engineers favor this type of eraser for work on technical drawings due to their gentleness on paper with less smearing to surrounding areas. They often come in white and can be found in a variety of shapes. More recently, very low-cost erasers are manufactured from highly plasticized vinyl compounds and made in decorative shapes. In these types,
2187-572: Is low and strain results from small changes of bond lengths and angles: this caused the Challenger disaster , when the American Space Shuttle 's flattened o-rings failed to relax to fill a widening gap. The glass transition is fast and reversible: the force resumes on heating. The parallel chains of stretched rubber are susceptible to crystallization. This takes some time because turns of twisted chains have to move out of
2268-899: Is not cultivated widely in its native continent of South America because of the South American leaf blight , and other natural predators there. Rubber latex is extracted from rubber trees. The economic life of rubber trees in plantations is around 32 years, with up to 7 years being an immature phase and about 25 years of productive phase. The soil requirement is well-drained, weathered soil consisting of laterite , lateritic types, sedimentary types, nonlateritic red or alluvial soils. The climatic conditions for optimum growth of rubber trees are: Many high-yielding clones have been developed for commercial planting. These clones yield more than 2,000 kilograms per hectare (1,800 lb/acre) of dry rubber per year, under ideal conditions. Rubber production has been linked to deforestation. Rubber therefore
2349-588: Is one of seven commodities included in the 2023 EU Regulation on Deforestation-free products (EUDR), which aims to guarantee that the products European Union (EU) citizens consume do not contribute to deforestation or forest degradation worldwide. In places such as Kerala and Sri Lanka, where coconuts are in abundance, the half shell of coconut was used as the latex collection container. Glazed pottery or aluminium or plastic cups became more common in Kerala-India and other countries. The cups are supported by
2430-449: Is produced by smallholders, who collect rubber from trees far from the nearest factory. Many Indonesian smallholders, who farm paddies in remote areas, tap dispersed trees on their way to work in the paddy fields and collect the latex (or the coagulated latex) on their way home. As it is often impossible to preserve the latex sufficiently to get it to a factory that processes latex in time for it to be used to make high quality products, and as
2511-529: Is produced from rubber, sulfuric acid is used for coagulation. This produces malodourous hydrogen sulfide. The industry can mitigate these bad odours with scrubber systems . Rubber is the polymer cis-1,4-polyisoprene – with a molecular weight of 100,000 to 1,000,000 daltons . Typically, a small percentage (up to 5% of dry mass) of other materials, such as proteins , fatty acids , resins , and inorganic materials (salts) are found in natural rubber. Polyisoprene can also be created synthetically, producing what
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2592-402: Is sometimes referred to as "synthetic natural rubber", but the synthetic and natural routes are distinct. Some natural rubber sources, such as gutta-percha , are composed of trans-1,4-polyisoprene, a structural isomer that has similar properties. Natural rubber is an elastomer and a thermoplastic . Once the rubber is vulcanized, it is a thermoset . Most rubber in everyday use is vulcanized to
2673-589: Is sometimes used as a carrier for drug molecules in pharmaceutical preparations. Almost all corn oil is expeller-pressed , then solvent-extracted using hexane or 2-methylpentane (isohexane). The solvent is evaporated from the corn oil, recovered, and re-used. After extraction, the corn oil is then refined by degumming and/or alkali treatment, both of which remove phosphatides . Alkali treatment also neutralizes free fatty acids and removes color (bleaching). Final steps in refining include winterization (the removal of waxes), and deodorization by steam distillation of
2754-479: Is still random but they become aligned when the rubber is stretched. This sulfur vulcanization makes the rubber stronger and more rigid, but still very elastic. And through the vulcanization process, the sulfur and latex are meant to be totally used up in individual form. Natural rubber latex is shipped from factories in Southeast Asia , South America , and West and Central Africa to destinations around
2835-467: Is the Amazonian rubber tree ( Hevea brasiliensis ), a member of the spurge family , Euphorbiaceae . Once native to Brazil, the species is now pan-tropical. This species is preferred because it grows well under cultivation. A properly managed tree responds to wounding by producing more latex for several years. Congo rubber , formerly a major source of rubber, which motivated the atrocities in
2916-474: Is used extensively in many applications and products, either alone or in combination with other materials. In most of its useful forms, it has a large stretch ratio and high resilience and also is buoyant and water-proof. Industrial demand for rubber-like materials began to outstrip natural rubber supplies by the end of the 19th century, leading to the synthesis of synthetic rubber in 1909 by chemical means. The major commercial source of natural rubber latex
2997-399: Is very soft yet retains its shape and is not mechanically plastic, but crumbles as it is used. It is especially suited to cleaning large areas without damaging the paper. However, they are so soft as to be imprecise in use. The removed graphite is carried away in the crumbles, leaving the eraser clean, but resulting in a lot of eraser residue. This residue must then be brushed away with care, as
3078-601: The Fraunhofer Institute for Molecular Biology and Applied Ecology (IME) in Germany developed a cultivar of the Kazakh dandelion ( Taraxacum kok-saghyz ) that is suitable for commercial production of natural rubber. In collaboration with Continental Tires , IME began a pilot facility. Many other plants produce forms of latex rich in isoprene polymers, though not all produce usable forms of polymer as easily as
3159-505: The Mullins effect and the Payne effect and is often modeled as hyperelastic . Rubber strain crystallizes . Because there are weakened allylic C-H bonds in each repeat unit , natural rubber is susceptible to vulcanisation as well as being sensitive to ozone cracking . The two main solvents for rubber are turpentine and naphtha (petroleum). Because rubber does not dissolve easily,
3240-728: The Putumayo genocide . Between the 1880s–1913 Julio César Arana and his company that would become the Peruvian Amazon Company controlled the Putumayo river. W.E. Hardenburg, Benjamin Saldaña Rocca and Roger Casement were influential figures in exposing these atrocities. Roger Casement was also prominent in revealing the Congo atrocities to the world. Days before entering Iquitos by boat Casement wrote "'Caoutchouc
3321-557: The cytosol . In plants, isoprene pyrophosphate can also be obtained from the 1-deox-D-xyulose-5-phosphate/2-C-methyl-D-erythritol-4-phosphate pathway within plasmids. The relative ratio of the farnesyl pyrophosphate initiator unit and isoprenyl pyrophosphate elongation monomer determines the rate of new particle synthesis versus elongation of existing particles. Though rubber is known to be produced by only one enzyme, extracts of latex host numerous small molecular weight proteins with unknown function. The proteins possibly serve as cofactors, as
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3402-673: The Congo Free State for more information on the rubber trade in the Congo Free State in the late 1800s and early 1900s.) The rubber boom in the Amazon also similarly affected indigenous populations to varying degrees. Correrias, or slave raids were frequent in Colombia, Peru and Bolivia where many were either captured or killed. The most well known case of atrocities generated from rubber extraction in South America came from
3483-534: The Congo Free State , came from vines in the genus Landolphia ( L. kirkii , L. heudelotis , and L. owariensis ). Dandelion milk contains latex. The latex exhibits the same quality as the natural rubber from rubber trees . In the wild types of dandelion, latex content is low and varies greatly. In Nazi Germany , research projects tried to use dandelions as a base for rubber production, but failed. In 2013, by inhibiting one key enzyme and using modern cultivation methods and optimization techniques, scientists in
3564-565: The Pará. Some of them require more elaborate processing to produce anything like usable rubber, and most are more difficult to tap. Some produce other desirable materials, for example gutta-percha ( Palaquium gutta ) and chicle from Manilkara species. Others that have been commercially exploited, or at least showed promise as rubber sources, include the rubber fig ( Ficus elastica ), Panama rubber tree ( Castilla elastica ), various spurges ( Euphorbia spp.), lettuce ( Lactuca species),
3645-409: The amount of contaminants. Earth scrap is collected by field workers two or three times a year and may be cleaned in a scrap-washer to recover the rubber, or sold to a contractor who cleans it and recovers the rubber. It is of low quality. Latex coagulates in the cups if kept for long and must be collected before this happens. The collected latex, "field latex", is transferred into coagulation tanks for
3726-407: The dry rubber produced. Latex that drips onto the ground, "earth scrap", is also collected periodically for processing of low-grade product. Cup lump is the coagulated material found in the collection cup when the tapper next visits the tree to tap it again. It arises from latex clinging to the walls of the cup after the latex was last poured into the bucket, and from late-dripping latex exuded before
3807-594: The end of a pencil ( cap eraser ). A barrel or click eraser is a device shaped like a pencil, but instead of being filled with pencil lead , its barrel contains a retractable cylinder of eraser material (most commonly soft vinyl). Many, but not all, wooden pencils are made with attached erasers. Novelty erasers made in shapes intended to be amusing are often made of hard vinyl, which tends to smear heavy markings when used as an eraser. Originally made from natural rubber, but now usually from cheaper SBR , this type contains mineral fillers and an abrasive such as pumice with
3888-428: The eraser is a pen-shaped device with a replaceable insert with glass fibers, which wear down in use. The fibers are very hard; in addition to removing pencil and pen markings, such erasers are used for cleaning traces on electronic circuit boards to facilitate soldering, removing rust, and many other applications. As an example of an unusual use, a fiberglass eraser was used for preparing a Pterosaur fossil embedded in
3969-432: The eraser particles are coated with the graphite and can make new marks. Art gum erasers are traditionally tan or brown, but some are blue. High-quality plasticized vinyl or other "plastic" erasers, originally trademarked Mylar in the mid-20th century, are softer, non-abrasive, and erase cleaner than standard rubber erasers. This is because the removed graphite does not remain on the eraser as much as rubber erasers, but
4050-415: The eraser until it is cleaned, usually by hitting it against a hard surface. Various types of eraser, depending upon the board and the type of ink used, are used to erase a whiteboard . Dedicated erasers that are supplied with some ballpens and permanent markers are intended only to erase the ink of the writing instrument they are made for; sometimes this is done by making the ink bond more strongly to
4131-636: The fabric. Rubber yarns were used in foundation garments. While rubber is still used in textile manufacturing, its low tenacity limits its use in lightweight garments because latex lacks resistance to oxidizing agents and is damaged by aging, sunlight, oil and perspiration. The textile industry turned to neoprene (polymer of chloroprene ), a type of synthetic rubber, as well as another more commonly used elastomer fiber, spandex (also known as elastane), because of their superiority to rubber in both strength and durability. Rubber exhibits unique physical and chemical properties. Rubber's stress–strain behavior exhibits
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#17327873684814212-477: The first technique for tapping trees for latex without causing serious harm to the tree. Because of his fervent promotion of this crop, he is popularly remembered by the nickname "Mad Ridley". Before World War II significant uses included door and window profiles, hoses, belts, gaskets, matting , flooring, and dampeners (antivibration mounts) for the automotive industry. The use of rubber in car tires (initially solid rather than pneumatic) in particular consumed
4293-544: The form of latex, an opaque, white, milky suspension of rubber particles in water. It is then transformed through industrial processes to the solid form widely seen in manufactured goods. Natural rubber is reactive and vulnerable to oxidization, but it can be stabilized through a heating process called vulcanization. Vulcanization is a process by which the rubber is heated and sulfur , peroxide , or bisphenol are added to improve resistance and elasticity and to prevent it from oxidizing. Carbon black , which can be derived from
4374-459: The higher-grade, technically specified block rubbers such as SVR 3L or SVR CV or used to produce Ribbed Smoke Sheet grades. Naturally coagulated rubber (cup lump) is used in the manufacture of TSR10 and TSR20 grade rubbers. Processing for these grades is a size reduction and cleaning process to remove contamination and prepare the material for the final stage of drying. The dried material is then baled and palletized for storage and shipment. Rubber
4455-431: The international market spot price of a seemingly more profitable crop (for example palm oil ) surges in relation to rubber. For instance, during the 2020 and 2021 international COVID-19 pandemic , demand for rubber gloves surged, leading to a spike in rubber prices of about 30%. In addition to the pandemic, demand exceeded supply in part because long term plantations had been torn out and replaced with other crops over
4536-532: The latex sap. Charles Marie de La Condamine is credited with introducing samples of rubber to the Académie Royale des Sciences of France in 1736. In 1751, he presented a paper by François Fresneau to the Académie (published in 1755) that described many of rubber's properties. This has been referred to as the first scientific paper on rubber. In England, Joseph Priestley , in 1770, observed that
4617-402: The latex would anyway have coagulated by the time it reached the factory, the smallholder will coagulate it by any means available, in any container available. Some smallholders use small containers, buckets etc., but often the latex is coagulated in holes in the ground, which are usually lined with plastic sheeting. Acidic materials and fermented fruit juices are used to coagulate the latex –
4698-434: The latex-carrying vessels of the tree become blocked. It is of higher purity and of greater value than the other three types. 'Cup lumps' can also be used to describe a completely different type of coagulate that has collected in smallholder plantations over a period of 1–2 weeks. After tapping all of the trees, the tapper will return to each tree and stir in some type of acid, which allows the newly harvested latex to mix with
4779-416: The latex. There is growing concern for the future supply of rubber due to various factors, including plant disease, climate change, and the volatile market price of rubber. Producers of natural rubber are mostly small family-held plantations, often serving large industrial aggregators. High volatility in the price of rubber affects rubber plantation investment, and farmers may remove their rubber trees if
4860-443: The liquid "field latex" at about midday. The four types of field coagula are "cuplump", "treelace", "smallholders' lump", and "earth scrap". Each has significantly different properties. Some trees continue to drip after the collection leading to a small amount of "cup lump" that is collected at the next tapping. The latex that coagulates on the cut is also collected as "tree lace". Tree lace and cup lump together account for 10%–20% of
4941-528: The main source of latex rubber used during much of the 19th century. The rubber trade was heavily controlled by business interests but no laws expressly prohibited the export of seeds or plants. In 1876, Henry Wickham smuggled 70,000 Amazonian rubber tree seeds from Brazil and delivered them to Kew Gardens , England. Only 2,400 of these germinated. Seedlings were then sent to India , British Ceylon ( Sri Lanka ), Dutch East Indies ( Indonesia ), Singapore , and British Malaya . Malaya (now Peninsular Malaysia )
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#17327873684815022-399: The material is finely divided by shredding prior to its immersion. An ammonia solution can be used to prevent the coagulation of raw latex. Rubber begins to melt at approximately 180 °C (356 °F). On a microscopic scale, relaxed rubber is a disorganized cluster of erratically changing wrinkled chains. In stretched rubber, the chains are almost linear. The restoring force is due to
5103-528: The material of an eraser than the surface it was applied to. Natural rubber Rubber , also called India rubber , latex , Amazonian rubber , caucho , or caoutchouc , as initially produced, consists of polymers of the organic compound isoprene , with minor impurities of other organic compounds. Thailand , Malaysia , Indonesia , and Cambodia are four of the leading rubber producers. Types of polyisoprene that are used as natural rubbers are classified as elastomers . Currently, rubber
5184-420: The material was known as gum elastic or by its Quechua name (via French) caoutchouc . Nairne sold natural rubber erasers for the high price of three shillings per half-inch cube. According to Nairne, he inadvertently picked up a piece of rubber instead of breadcrumbs, discovered rubber's erasing properties, and began selling rubber erasers. The invention was described by Joseph Priestley on April 15, 1770, in
5265-577: The plantation expanded to Karnataka , Tamil Nadu and the Andaman and Nicobar Islands of India. Today, India is the world's 3rd largest producer and 4th largest consumer of rubber. In Singapore and Malaya, commercial production was heavily promoted by Sir Henry Nicholas Ridley , who served as the first Scientific Director of the Singapore Botanic Gardens from 1888 to 1911. He distributed rubber seeds to many planters and developed
5346-606: The preparation of dry rubber or transferred into air-tight containers with sieving for ammoniation. Ammoniation, invented by patent lawyer and vice-president of the United States Rubber Company Ernest Hopkinson around 1920, preserves the latex in a colloidal state for longer periods of time. Latex is generally processed into either latex concentrate for manufacture of dipped goods or coagulated under controlled, clean conditions using formic acid. The coagulated latex can then be processed into
5427-400: The preponderance of wrinkled conformations over more linear ones. For the quantitative treatment see ideal chain , for more examples see entropic force . Cooling below the glass transition temperature permits local conformational changes but a reordering is practically impossible because of the larger energy barrier for the concerted movement of longer chains. "Frozen" rubber's elasticity
5508-401: The previous 5–10 years, and other areas were affected by climate-fueled natural disasters. In this environment, producers did increase their prices in keeping with supply and demand dynamics, putting upward price pressure on the whole downstream supply chain. Corn oil Corn oil (North American) or maize oil (British) is oil extracted from the germ of corn (maize). Its main use
5589-422: The previously coagulated material. The rubber/acid mixture is what gives rubber plantations, markets, and factories a strong odor. Tree lace is the coagulum strip that the tapper peels off the previous cut before making a new cut. It usually has higher copper and manganese contents than cup lump. Both copper and manganese are pro-oxidants and can damage the physical properties of the dry rubber. Smallholders' lump
5670-525: The process of vulcanization , a method that would cure rubber, making it durable. Rubber erasers became common with the advent of vulcanization. On March 30, 1858, Hymen Lipman of Philadelphia , United States, received the first patent for attaching an eraser to the end of a pencil. It was later invalidated because it was determined to be simply a composite of two devices rather than an entirely new product. Erasers may be free-standing blocks ( block and wedge eraser ), or conical caps that can slip onto
5751-419: The related Scorzonera tau-saghyz , various Taraxacum species, including common dandelion ( Taraxacum officinale ) and Kazakh dandelion, and, perhaps most importantly for its hypoallergenic properties, guayule ( Parthenium argentatum ). The term gum rubber is sometimes applied to the tree-obtained version of natural rubber in order to distinguish it from the synthetic version. The first use of rubber
5832-564: The synthetic rate decreases with complete removal. More than 28 million tons of rubber were produced in 2017, of which approximately 47% was natural. Since the bulk is synthetic, which is derived from petroleum, the price of natural rubber is determined, to a large extent, by the prevailing global price of crude oil. Asia was the main source of natural rubber, accounting for about 90% of output in 2021. The three largest producers, Thailand , Indonesia, and Malaysia, together account for around 72% of all natural rubber production. Natural rubber
5913-435: The terminal high-energy pyrophosphate. The reaction produces a cis polymer. The initiation step is catalyzed by prenyltransferase , which converts three monomers of isopentenyl pyrophosphate into farnesyl pyrophosphate . The farnesyl pyrophosphate can bind to rubber transferase to elongate a new rubber polymer. The required isopentenyl pyrophosphate is obtained from the mevalonate pathway, which derives from acetyl-CoA in
5994-456: The underlying wall surface, poster putty works much the same as traditional kneaded erasers, but with a greater tack and in some circumstances, lifting strength. Poster putty does not erase so much as lighten by directly pulling particles of graphite, charcoal or pastel from a drawing. In this regard, poster putty does not smudge or damage work in the process. Repeatedly touching the putty to a drawing pulls ever more medium free, gradually lightening
6075-453: The way of the growing crystallites . Crystallization has occurred, for example, when, after days, an inflated toy balloon is found withered at a relatively large remaining volume. Where it is touched, it shrinks because the temperature of the hand is enough to melt the crystals. Vulcanization of rubber creates di- and polysulfide bonds between chains, which limits the degrees of freedom and results in chains that tighten more quickly for
6156-457: The work in a controlled fashion. Poster putty can be shaped into fine points or knife edges, making it ideal for detailed or small areas of work. It can be rolled across a surface to create visual textures. Poster putty loses its efficacy with use, becoming less tacky as the material grows polluted with debris and oils from the user's skin. The electric eraser was invented in 1932 by Albert J. Dremel of Racine , Wisconsin , United States. It used
6237-442: The world. As the cost of natural rubber has risen significantly and rubber products are dense, the shipping methods offering the lowest cost per unit weight are preferred. Depending on destination, warehouse availability, and transportation conditions, some methods are preferred by certain buyers. In international trade, latex rubber is mostly shipped in 20-foot ocean containers. Inside the container, smaller containers are used to store
6318-670: Was by the indigenous cultures of Mesoamerica . The earliest archeological evidence of the use of natural latex from the Hevea tree comes from the Olmec culture, in which rubber was first used for making balls for the Mesoamerican ballgame . Rubber was later used by the Maya and Aztec cultures: in addition to making balls, Aztecs used rubber for other purposes, such as making containers and to make textiles waterproof by impregnating them with
6399-760: Was first called 'india rubber,' because it came from the Indies, and the earliest European use of it was to rub out or erase. It is now called India rubber because it rubs out or erases the Indians." In India , commercial cultivation was introduced by British planters, although the experimental efforts to grow rubber on a commercial scale were initiated as early as 1873 at the Calcutta Botanical Garden . The first commercial Hevea plantations were established at Thattekadu in Kerala in 1902. In later years
6480-724: Was later to become the biggest producer of rubber. In the early 1900s, the Congo Free State in Africa was also a significant source of natural rubber latex, mostly gathered by forced labor . King Leopold II's colonial state brutally enforced production quotas due to the high price of natural rubber at the time. Tactics to enforce the rubber quotas included removing the hands of victims to prove they had been killed. Soldiers often came back from raids with baskets full of chopped-off hands. Villages that resisted were razed to encourage better compliance locally. (See Atrocities in
6561-441: Was used; a Meiji period (1868–1912) Tokyo student said: "Bread erasers were used in place of rubber erasers, and so they would give them to us with no restriction on amount. So we thought nothing of taking these and eating a firm part to at least slightly satisfy our hunger." In 1770 English engineer Edward Nairne is reported to have developed the first widely marketed rubber eraser, for an inventions competition. Until that time
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