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40-513: Exxon donor solvent process (EDS) is a coal liquefaction process developed by Exxon Research and Engineering Company , starting in 1966. The process converts solid coal directly to liquid synthetic fuels which could be used as a substitute for petroleum products . The process does not involve an intermediate step of coal gasification . Exxon operated a pilot plant in Texas from 1980 until 1982. Exxon started to develop this process in 1966 and

80-646: A zeolite catalyst. This process, under the moniker MTG (MTG for "Methanol To Gasoline"), was developed by Mobil in the early 1970s, and is being tested at a demonstration plant by Jincheng Anthracite Mining Group (JAMG) in Shanxi, China. Based on this methanol synthesis, China has also developed a strong coal-to-chemicals industry, with outputs such as olefins , MEG , DME and aromatics . Methanation reaction converts syngas to substitute natural gas (SNG). The Great Plains Gasification Plant in Beulah, North Dakota

120-564: A Chinese coal mining company, decided in 2002 to build a direct liquefaction plant in Erdos, Inner Mongolia ( Erdos CTL ), with barrel capacity of 20 thousand barrels per day (3.2 × 10 ^  m /d) of liquid products including diesel oil, liquefied petroleum gas (LPG) and naphtha (petroleum ether). First tests were implemented at the end of 2008. A second and longer test campaign was started in October 2009. In 2011, Shenhua Group reported that

160-524: A fast reaction time, while the main disadvantages are high gas yield (this is basically a thermal cracking process), high hydrogen consumption, and limitation of oil usage only as a boiler oil because of impurities. The SRC-I and SRC-II (Solvent Refined Coal) processes were developed by Gulf Oil and implemented as pilot plants in the United States in the 1960s and 1970s. The Nuclear Utility Services Corporation developed hydrogenation process which

200-479: A high-pressure liquefaction reactor. Coal is cleaned, crushed and fed to the slurry dryer, where water is removed. The dry crushed coal is slurried with the hydrogen donor recycle solvent. The coal slurry is treated with hydrogen and heated in a liquefaction slurry furnace. The liquefaction occurs at 840 °F (449 °C) and 2,000 pounds per square inch (14,000 kPa). The process produces gas and liquids. After separation of gas from liquids and remaining solids,

240-529: A higher hydrogen-carbon molar ratio than coals, either hydrogenation or carbon-rejection processes must be employed in both ICL and DCL technologies. At industrial scales (i.e. thousands of barrels/day) a coal liquefaction plant typically requires multibillion-dollar capital investments. A number of carbonization processes exist. The carbonization conversion typically occurs through pyrolysis or destructive distillation . It produces condensable coal tar , oil and water vapor, non-condensable synthetic gas , and

280-537: A mixture of carbon monoxide and hydrogen , often known as synthesis gas or simply syngas . Using the Fischer–Tropsch process syngas is converted into liquid hydrocarbons. In contrast, direct liquefaction processes convert coal into liquids directly without having to rely on intermediate steps by breaking down the organic structure of coal with application of hydrogen-donor solvent , often at high pressures and temperatures. Since liquid hydrocarbons generally have

320-468: A researcher or developer in coal conversion is rewarded by the industry in receiving the World Carbon To X Award . The 2016 Award recipient is Mr. Jona Pillay, executive director for Gasification & CTL, Jindal Steel & Power Ltd (India). The 2017 Award recipient is Dr. Yao Min, Deputy General Manager of Shenhua Ningxia Coal Group (China). In terms of commercial development, coal conversion

360-459: A solid residue - char . One typical example of carbonization is the Karrick process . In this low-temperature carbonization process, coal is heated at 680 °F (360 °C) to 1,380 °F (750 °C) in the absence of air. These temperatures optimize the production of coal tars richer in lighter hydrocarbons than normal coal tar. However, any produced liquids are mostly a by-product and

400-441: A time when rising oil prices and concerns over peak oil made planners rethink existing supply chains for liquid fuels. Specific liquefaction technologies generally fall into two categories: direct liquefaction (DCL) and indirect liquefaction (ICL) processes. Direct processes are based on approaches such as carbonization , pyrolysis , and hydrogenation . Indirect liquefaction processes generally involve gasification of coal to

440-643: Is a coal-to-SNG facility producing 160 million cubic feet per day of SNG, and has been in operation since 1984. Several coal-to-SNG plants are in operation or in project in China, South Korea and India. In another application of gasification, hydrogen extracted from synthetic gas reacts with nitrogen to form ammonia . Ammonia then reacts with carbon dioxide to produce urea . The above instances of commercial plants based on indirect coal liquefaction processes, as well as many others not listed here including those in planning stages and under construction, are tabulated in

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480-432: Is conducted without any carbon capture and storage technologies. There are technically feasible low-emission configurations of CTL plants. High water consumption in the water-gas shift reaction or steam methane reforming is another adverse environmental effect. CO 2 emission control at Erdos CTL , an Inner Mongolian plant with a carbon capture and storage demonstration project, involves injecting CO 2 into

520-704: The TOSCO II oil shale retorting process and Lurgi–Ruhrgas process , which is also used for the shale oil extraction , uses hot recycled solids for the heat transfer. Liquid yields of pyrolysis and the Karrick process are generally considered too low for practical use for synthetic liquid fuel production. The resulting coal tars and oils from pyrolysis generally require further treatment before they can be usable as motor fuels; they are processed by hydrotreating to remove sulfur and nitrogen species, after which they are finally processed into liquid fuels. In summary,

560-399: The 1940s. The DCL and ICL plants effectively complemented each other rather than competed. The reason for this is that coal hydrogenation yields high quality gasoline for aviation and motors, while FT synthesis chiefly produced high-quality diesel, lubrication oil, and waxes together with some smaller amounts of lower-quality motor gasoline. The DCL plants were also more developed, as lignite –

600-1016: The Exxon Donor Solvent Process, the Imhausen High-pressure Process, and the Conoco Zinc Chloride Process. There are also a number of two-stage direct liquefaction processes; however, after the 1980s only the Catalytic Two-stage Liquefaction Process, modified from the H-Coal Process; the Liquid Solvent Extraction Process by British Coal ; and the Brown Coal Liquefaction Process of Japan have been developed. Shenhua ,

640-522: The Gasification Technologies Council's World Gasification Database. Typically coal liquefaction processes are associated with significant CO 2 emissions from the gasification process or as well as from generation of necessary process heat and electricity inputs to the liquefaction reactors, thus releasing greenhouse gases that can contribute to anthropogenic global warming . This is especially true if coal liquefaction

680-561: The Second World War. Technical development has resulted in a variety of systems capable of handling a wide array of coal types. However, only a few enterprises based on generating liquid fuels from coal have been undertaken, most of them based on ICL technology; the most successful one has been Sasol in South Africa. CTL also received new interest in the early 2000s as a possible mitigation option for reducing oil dependence, at

720-514: The South African government considered essential for continued economic development and autonomy. South Africa had no known domestic oil reserves at the time, and this made the country very vulnerable to disruption of supplies coming from outside, albeit for different reasons at different times. Sasol was a successful way to protect the country's balance of payment against the increasing dependence on foreign oil. For years its principal product

760-681: The United States has restricted the military's use of alternative liquid fuels to only those demonstrated to have life-cycle GHG emissions less than or equal to those of their conventional petroleum-based equivalent, as required by Section 526 of the Energy Independence and Security Act (EISA) of 2007. The United States military has an active program to promote alternative fuels use, and utilizing vast domestic U.S. coal reserves to produce fuels through coal liquefaction would have obvious economic and security advantages. But with their higher carbon footprint, fuels from coal liquefaction face

800-459: The area of coal liquefaction to produce military-specification liquid fuels, with an emphasis on jet fuel, which would be both cost-effective and in accordance with EISA Section 526. Projects underway in this area are described under the U.S. Department of Energy National Energy Technology Laboratory's Advanced Fuels Synthesis R&D area in the Coal and Coal-Biomass to Liquids Program . Every year,

840-426: The catalytic hydroprocessing unit. The oil produced had properties that were unique when compared to other coal oils; it was lighter and had far fewer heteroatom impurities. The process was scaled-up to the 6 ton per day level, but not proven commercially. Indirect coal liquefaction (ICL) processes operate in two stages. In the first stage, coal is converted into syngas (a purified mixture of CO and H 2 gas). In

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880-603: The development process continued until 1976. By 1975, the process was used in 1/2-tons per day pilot plant. In 1977, preparations to build the demonstration-scale 250-tons per day plant in Baytown, Texas . The plant was opened in April 1980. The plant was built by Carter Oil , an affiliate of Exxon Corporation later renamed Exxon Coal, U.S.A. The plant was financed by the United States Department of Energy and by

920-518: The direct liquefaction plant had been in continuous and stable operations since November 2010, and that Shenhua had made 800 million yuan ($ 125.1 million) in earnings before taxes in the first six months of 2011 on the project. Chevron Corporation developed a process invented by Joel W. Rosenthal called the Chevron Coal Liquefaction Process (CCLP). It is unique due to the close-coupling of the non-catalytic dissolver and

960-882: The economic viability of this technology is questionable. One of the main methods of direct conversion of coal to liquids by hydrogenation process is the Bergius process , developed by Friedrich Bergius in 1913. In this process, dry coal is mixed with heavy oil recycled from the process. A catalyst is typically added to the mixture. The reaction occurs at between 400 °C (752 °F) to 500 °C (932 °F) and 20 to 70  MPa hydrogen pressure. The reaction can be summarized as follows: After World War I several plants based on this technology were built in Germany; these plants were extensively used during World War II to supply Germany with fuel and lubricants. The Kohleoel Process, developed in Germany by Ruhrkohle and VEBA ,

1000-469: The gas is cooled to separate vaporized naptha , and scrubbed to remove ammonia , hydrogen gas , and carbon monoxide . The remaining gas is treated with hydrogen, and reused in the liquefaction reactor. Liquids, remaining solids, and condensate from the process gas are treated in fractionators for separating naptha, a spent solvent, and vacuum gas oil . Naptha is processed into different hydrocarbon products while spent solvent hydrogenated before reusing in

1040-513: The main product is semi-coke - a solid and smokeless fuel. The COED Process, developed by FMC Corporation , uses a fluidized bed for processing, in combination with increasing temperature, through four stages of pyrolysis. Heat is transferred by hot gases produced by combustion of part of the produced char. A modification of this process, the COGAS Process, involves the addition of gasification of char. The TOSCOAL Process, an analogue to

1080-470: The only coal available in many parts of Germany – worked better with hydrogenation than with FT synthesis. After the war, Germany had to abandon its synthetic fuel production as it was prohibited by the Potsdam conference in 1945. South Africa developed its own CTL technology in the 1950s. The South African Coal, Oil and Gas Corporation ( Sasol ) was founded in 1950 as part of industrialization process that

1120-403: The pressure 150-200 bar. The produced oil has low quality and requires intensive upgrading. H-Coal process, developed by Hydrocarbon Research, Inc., in 1963, mixes pulverized coal with recycled liquids, hydrogen and catalyst in the ebullated bed reactor . Advantages of this process are that dissolution and oil upgrading are taking place in the single reactor, products have high H/C ratio, and

1160-429: The private investors Carter Oil, Electric Power Research Institute , Japan Coal Liquefaction Development Company, Phillips Coal Company, ARCO Coal Company, Ruhrkohle and Agip . The plant was closed and dismantled in 1982. Originally Exxon planned to open its first commercial scale plant in 1997; however, this plan was abandoned. The Exxon donor solvent process is a non-catalytic processing of solvent-slurried coal in

1200-567: The saline aquifer of Erdos Basin, at a rate of 100,000 tonnes per year. As of late October 2013, an accumulated amount of 154,000 tonnes of CO 2 had been injected since 2010, which reached or exceeded the design value. In the United States, the Renewable Fuel Standard and low-carbon fuel standard , such as enacted in the State of California, reflect an increasing demand for low carbon footprint fuels. Also, legislation in

1240-455: The second stage, the syngas is converted into light hydrocarbons using one of three main processes: Fischer–Tropsch synthesis, methanol synthesis with subsequent conversion to gasoline or petrochemicals , and methanation . Fischer–Tropsch is the oldest of the ICL processes. In methanol synthesis processes syngas is converted to methanol , which is subsequently polymerized into alkanes over

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1280-495: The significant challenge of reducing life-cycle GHG emissions to competitive levels, which demands continued research and development of liquefaction technology to increase efficiency and reduce emissions. A number of avenues of research & development will need to be pursued, including: Since 2014, the U.S. Department of Energy and the Department of Defense have been collaborating on supporting new research and development in

1320-485: The slurry drier. By this process from one short ton (0.907 t) of dry, high volatile coal can be produced more than 2.6 barrels (0.41 m) of a synthetic fuel. Initially, the process was focused to be used for bituminous coals but it was tested also for lower grade coals, such as lignite . Pilot testings show that lignite was harder to process than bituminous coals and it resulted a lower oil yield. Coal liquefaction process Coal liquefactions originally

1360-512: Was also explored by SASOL in South Africa. During the 1970s and 1980s, Japanese companies Nippon Kokan , Sumitomo Metal Industries , and Mitsubishi Heavy Industries developed the NEDOL process. In this process, coal is mixed with a recycled solvent and a synthetic iron-based catalyst; after preheating, H 2 is added. The reaction takes place in a tubular reactor at a temperature between 430 °C (810 °F) and 465 °C (870 °F) at

1400-511: Was an important part of Adolf Hitler 's four-year plan of 1936, and became an integral part of German industry during World War II . During the mid-1930s, companies like IG Farben and Ruhrchemie initiated industrial production of synthetic fuels derived from coal. This led to the construction of twelve DCL plants using hydrogenation and nine ICL plants using Fischer–Tropsch synthesis by the end of World War II. In total, CTL provided 92% of Germany's air fuel and over 50% of its petroleum supply in

1440-545: Was developed at the beginning of the 20th century. The best-known CTL process is Fischer–Tropsch synthesis (FT), named after the inventors Franz Fischer and Hans Tropsch from the Kaiser Wilhelm Institute in the 1920s. The FT synthesis is the basis for indirect coal liquefaction (ICL) technology. Friedrich Bergius , also a German chemist, invented direct coal liquefaction (DCL) as a way to convert lignite into synthetic oil in 1913. Coal liquefaction

1480-646: Was only with state support that the coal liquefaction could start. CTL continued to play a vital part in South Africa's national economy, providing around 30% of its domestic fuel demand. The democratization of South Africa in the 1990s made Sasol search for products that could prove more competitive in the global marketplace; as of the new millennium the company was focusing primarily on its petrochemical business, as well as on efforts to convert natural gas into crude oil ( GTL ) using its expertise in Fischer–Tropsch synthesis. CTL technologies have steadily improved since

1520-539: Was patented by Wilburn C. Schroeder in 1976. The process involved dried, pulverized coal mixed with roughly 1wt% molybdenum catalysts. Hydrogenation occurred by use of high temperature and pressure synthesis gas produced in a separate gasifier. The process ultimately yielded a synthetic crude product, naphtha , a limited amount of C 3 /C 4 gas, light-medium weight liquids (C 5 -C 10 ) suitable for use as fuels, small amounts of NH 3 and significant amounts of CO 2 . Other single-stage hydrogenation processes are

1560-516: Was synthetic fuel, and this business enjoyed significant government protection in South Africa during the apartheid years for its contribution to domestic energy security . Although it was generally much more expensive to produce oil from coal than from natural petroleum, the political as well as economic importance of achieving as much independence as possible in this sphere was sufficient to overcome any objections. Early attempts to attract private capital, foreign or domestic, were unsuccessful, and it

1600-489: Was used in the demonstration plant with the capacity of 200 ton of lignite per day, built in Bottrop , Germany. This plant operated from 1981 to 1987. In this process, coal is mixed with a recycle solvent and iron catalyst. After preheating and pressurizing, H 2 is added. The process takes place in a tubular reactor at the pressure of 300 bar (30 MPa) and at the temperature of 470 °C (880 °F). This process

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