Kéniéba is a rural commune , small town and seat of Kéniéba Cercle in Mali 's Kayes Region , near the Mali–Senegal border . As well as the main town, the commune includes 26 other villages. In the 2009 census the commune had a population of 39,557.
98-466: Kéniéba is located in the gold -rich region of Bambouk . Kéniéba is twinned with the following towns: This Kayes Region location article is a stub . You can help Misplaced Pages by expanding it . Gold Gold is a chemical element with the chemical symbol Au (from Latin aurum ) and atomic number 79. In its pure form, it is a bright , slightly orange-yellow, dense, soft, malleable , and ductile metal . Chemically, gold
196-399: A fault . Water often lubricates faults, filling in fractures and jogs. About 10 kilometres (6.2 mi) below the surface, under very high temperatures and pressures, the water carries high concentrations of carbon dioxide, silica, and gold. During an earthquake, the fault jog suddenly opens wider. The water inside the void instantly vaporizes, flashing to steam and forcing silica, which forms
294-408: A hermaphroditic connector . These connectors includes mating with both male and female aspects, involving complementary paired identical parts each containing both protrusions and indentations. These mating surfaces are mounted into identical fittings that freely mate with any other, without regard for gender (provided that the size and type match). Sometimes both ends of a cable are terminated with
392-532: A plug (denoted P), designed to attach to a wire, cable or removable electrical assembly. This convention is currently defined in ASME Y14.44-2008, which supersedes IEEE 200-1975 , which in turn derives from the long-withdrawn MIL-STD-16 (from the 1950s), highlighting the heritage of this connector naming convention. IEEE 315-1975 works alongside ASME Y14.44-2008 to define jacks and plugs. The term jack occurs in several related terms: Crimped connectors are
490-483: A barrel, a spring, and a plunger. They are in applications such as the MagSafe connector where a quick disconnect is desired for safety. Because they rely on spring pressure, not friction, they can be more durable and less damaging than traditional pin and socket design, leading to their use in in-circuit testing . Crown spring connectors are commonly used for higher current flows and industrial applications. They have
588-423: A cable, and screw terminals are generally not very well protected from contact with persons or foreign conducting materials. Terminal blocks (also called terminal boards or strips ) provide a convenient means of connecting individual electrical wires without a splice or physically joining the ends. Since terminal blocks are readily available for a wide range of wire sizes and terminal quantity, they are one of
686-553: A coating material with good conductivity, mechanical robustness and corrosion resistance helps to reduce the influence of passivating oxide layers and surface adsorbates, which limit metal-to-metal contact patches and contribute to contact resistance. For example, copper alloys have favorable mechanical properties for electrodes, but are hard to solder and prone to corrosion. Thus, copper pins are usually coated with gold to alleviate these pitfalls, especially for analog signals and high-reliability applications. Contact carriers that hold
784-563: A connector specifically because it is not compatible with those from other sources, allowing control of what may be connected. No single connector has all the ideal properties for every application; the proliferation of types is a result of the diverse yet specific requirements of manufacturers. Electrical connectors essentially consist of two classes of materials: conductors and insulators. Properties important to conductor materials are contact resistance, conductivity , mechanical strength , formability , and resilience . Insulators must have
882-440: A connector with hyperboloid contacts, each female contact has several equally spaced longitudinal wires twisted into a hyperbolic shape. These wires are highly resilient to strain, but still somewhat elastic, hence they essentially function as linear springs. As the male pin is inserted, axial wires in the socket half are deflected, wrapping themselves around the pin to provide a number of contact points. The internal wires that form
980-743: A cylindrical housing and circular contact interface geometries. This is in contrast to the rectangular design of some connectors, e.g. USB or blade connectors . They are commonly used for easier engagement and disengagement, tight environmental sealing, and rugged mechanical performance. They are widely used in military, aerospace, industrial machinery, and rail, where MIL-DTL-5015 and MIL-DTL-38999 are commonly specified. Fields such as sound engineering and radio communication also use circular connectors, such as XLR and BNC . AC power plugs are also commonly circular, for example, Schuko plugs and IEC 60309 . The M12 connector , specified in IEC 61076-2-101,
1078-443: A decrease in insulation resistance and increase in conductor resistance; this increase generates more heat, and the cycle repeats. Fretting (so-called dynamic corrosion ) is a common failure mode in electrical connectors that have not been specifically designed to prevent it, especially in those that are frequently mated and de-mated. Surface corrosion is a risk for many metal parts in connectors, and can cause contacts to form
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#17327801731591176-493: A different connection method – e.g. the solder tabs on a male phone connector , and the male phone connector itself. In this example, the solder tabs connected to the cable represent the permanent connection, whilst the male connector portion interfaces with a female socket forming a detachable connection. There are many ways of applying a connector to a cable or device. Some of these methods can be accomplished without specialized tools. Other methods, while requiring
1274-483: A dilute solution of gold(III) chloride or chlorauric acid . Unlike sulfur, phosphorus reacts directly with gold at elevated temperatures to produce gold phosphide (Au 2 P 3 ). Gold readily dissolves in mercury at room temperature to form an amalgam , and forms alloys with many other metals at higher temperatures. These alloys can be produced to modify the hardness and other metallurgical properties, to control melting point or to create exotic colors. Gold
1372-420: A few amperes are more reliably terminated with other means, though "hot tap" press-on connectors find some use in automotive applications for additions to existing wiring. A common example is the multi-conductor flat ribbon cable used in computer disk drives; to terminate each of the many (approximately 40) wires individually would be slow and error-prone, but an insulation displacement connector can terminate all
1470-579: A gold-from-seawater swindle in the United States in the 1890s, as did an English fraudster in the early 1900s. Fritz Haber did research on the extraction of gold from sea water in an effort to help pay Germany 's reparations following World War I . Based on the published values of 2 to 64 ppb of gold in seawater, a commercially successful extraction seemed possible. After analysis of 4,000 water samples yielding an average of 0.004 ppb, it became clear that extraction would not be possible, and he ended
1568-830: A golden hue to metallic caesium . Common colored gold alloys include the distinctive eighteen-karat rose gold created by the addition of copper. Alloys containing palladium or nickel are also important in commercial jewelry as these produce white gold alloys. Fourteen-karat gold-copper alloy is nearly identical in color to certain bronze alloys, and both may be used to produce police and other badges . Fourteen- and eighteen-karat gold alloys with silver alone appear greenish-yellow and are referred to as green gold . Blue gold can be made by alloying with iron , and purple gold can be made by alloying with aluminium . Less commonly, addition of manganese , indium , and other elements can produce more unusual colors of gold for various applications. Colloidal gold , used by electron-microscopists,
1666-426: A good electrical connection and complete the circuit. An alternative type of plug and socket connection uses hyperboloid contacts , which makes a more reliable electrical connection. When working with multi-pin connectors, it is helpful to have a pinout diagram to identify the wire or circuit node connected to each pin. Some connector styles may combine pin and socket connection types in a single unit, referred to as
1764-411: A high electrical resistance , withstand high temperatures, and be easy to manufacture for a precise fit Electrodes in connectors are usually made of copper alloys , due to their good conductivity and malleability . Alternatives include brass , phosphor bronze , and beryllium copper . The base electrode metal is often coated with another inert metal such as gold , nickel , or tin . The use of
1862-399: A high number of contact points, which provides a more electrically reliable connection than traditional pin and socket connectors. Whilst technically inaccurate, electrical connectors can be viewed as a type of adapter to convert between two connection methods, which are permanently connected at one end and (usually) detachable at the other end. By definition, each end of this "adapter" has
1960-567: A large alluvial deposit. The mines at Roşia Montană in Transylvania were also very large, and until very recently, still mined by opencast methods. They also exploited smaller deposits in Britain , such as placer and hard-rock deposits at Dolaucothi . The various methods they used are well described by Pliny the Elder in his encyclopedia Naturalis Historia written towards the end of
2058-657: A larger circuit. The connection may be removable (as for portable equipment), require a tool for assembly and removal, or serve as a permanent electrical joint between two points. An adapter can be used to join dissimilar connectors. Most electrical connectors have a gender – i.e. the male component, called a plug , connects to the female component, or socket . Thousands of configurations of connectors are manufactured for power , data , and audiovisual applications. Electrical connectors can be divided into four basic categories, differentiated by their function: In computing, electrical connectors are considered
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#17327801731592156-424: A male plug (typically pin contacts) and a female socket (typically receptacle contacts). Often, but not always, sockets are permanently fixed to a device as in a chassis connector (see above) , and plugs are attached to a cable. Plugs generally have one or more pins or prongs that are inserted into openings in the mating socket. The connection between the mating metal parts must be sufficiently tight to make
2254-418: A method for locking the connector into a receptacle. In some cases, this backshell provides a hermetic seal , or some degree of ingress protection , through the use of grommets , O-rings , or potting . Hybrid connectors allow the intermixing of many connector types, usually by way of a housing with inserts. These housings may also allow intermixing of electrical and non-electrical interfaces, examples of
2352-710: A notch to ensure proper orientation, while Mini-DIN plugs have a plastic projection that fits into a corresponding hole in the socket (they also have a notched metal skirt to provide secondary keying). Some connector housings are designed with locking mechanisms to prevent inadvertent disconnection or poor environmental sealing. Locking mechanism designs include locking levers of various sorts, jackscrews , screw-in shells, push-pull connector , and toggle or bayonet systems. Some connectors, particularly those with large numbers of contacts, require high forces to connect and disconnect. Locking levers and jackscrews and screw-in shells for such connectors frequently serve both to retain
2450-462: A novel type of metal-halide perovskite material consisting of Au and Au cations in its crystal structure has been found. It has been shown to be unexpectedly stable at normal conditions. Gold pentafluoride , along with its derivative anion, AuF − 6 , and its difluorine complex , gold heptafluoride , is the sole example of gold(V), the highest verified oxidation state. Some gold compounds exhibit aurophilic bonding , which describes
2548-603: A physical interface and constitute part of the physical layer in the OSI model of networking. In addition to the classes mentioned above, connectors are characterised by their pinout , method of connection , materials, size, contact resistance , insulation , mechanical durability, ingress protection , lifetime (number of cycles), and ease of use. It is usually desirable for a connector to be easy to identify visually, rapid to assemble, inexpensive, and require only simple tooling. In some cases an equipment manufacturer might choose
2646-401: A sheet of 1 square metre (11 sq ft), and an avoirdupois ounce into 28 square metres (300 sq ft). Gold leaf can be beaten thin enough to become semi-transparent. The transmitted light appears greenish-blue because gold strongly reflects yellow and red. Such semi-transparent sheets also strongly reflect infrared light, making them useful as infrared (radiant heat) shields in
2744-520: A solution of Au(OH) 3 in concentrated H 2 SO 4 produces red crystals of gold(II) sulfate , Au 2 (SO 4 ) 2 . Originally thought to be a mixed-valence compound, it has been shown to contain Au 4+ 2 cations, analogous to the better-known mercury(I) ion, Hg 2+ 2 . A gold(II) complex, the tetraxenonogold(II) cation, which contains xenon as a ligand, occurs in [AuXe 4 ](Sb 2 F 11 ) 2 . In September 2023,
2842-468: A special tool, can assemble connectors much faster and more reliably, and make repairs easier. The number of times a connector can connect and disconnect with its counterpart while meeting all its specifications is termed as mating cycles and is an indirect measure of connector lifespan. The material used for connector contact, plating type and thickness is a major factor that determines the mating cycles. Plug and socket connectors are usually made up of
2940-427: A thin surface layer that increases resistance, thus contributing to heat buildup and intermittent connections. However, remating or reseating a connector can alleviate the issue of surface corrosion, since each cycle scrapes a microscopic layer off the surface of the contact(s), exposing a fresh, unoxidised surface. Many connectors used for industrial and high-reliability applications are circular in cross section, with
3038-486: A type of solderless connection, using mechanical friction and uniform deformation to secure a connector to a pre-stripped wire (usually stranded). Crimping is used in splice connectors, crimped multipin plugs and sockets, and crimped coaxial connectors. Crimping usually requires a specialised crimping tool, but the connectors are quick and easy to install and are a common alternative to solder connections or insulation displacement connectors. Effective crimp connections deform
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3136-470: Is Au with a half-life of 2.27 days. Gold's least stable isomer is Au with a half-life of only 7 ns. Au has three decay paths: β decay, isomeric transition , and alpha decay. No other isomer or isotope of gold has three decay paths. The possible production of gold from a more common element, such as lead , has long been a subject of human inquiry, and the ancient and medieval discipline of alchemy often focused on it; however,
3234-696: Is Au , which decays by proton emission with a half-life of 30 μs. Most of gold's radioisotopes with atomic masses below 197 decay by some combination of proton emission , α decay , and β decay . The exceptions are Au , which decays by electron capture, and Au , which decays most often by electron capture (93%) with a minor β decay path (7%). All of gold's radioisotopes with atomic masses above 197 decay by β decay. At least 32 nuclear isomers have also been characterized, ranging in atomic mass from 170 to 200. Within that range, only Au , Au , Au , Au , and Au do not have isomers. Gold's most stable isomer
3332-669: Is a transition metal , a group 11 element , and one of the noble metals . It is one of the least reactive chemical elements, being the second-lowest in the reactivity series . It is solid under standard conditions . Gold often occurs in free elemental ( native state ), as nuggets or grains, in rocks , veins , and alluvial deposits . It occurs in a solid solution series with the native element silver (as in electrum ), naturally alloyed with other metals like copper and palladium , and mineral inclusions such as within pyrite . Less commonly, it occurs in minerals as gold compounds, often with tellurium ( gold tellurides ). Gold
3430-489: Is a circular electrical plug/receptacle pair with 12mm OD mating threads, used in NMEA 2000 , DeviceNet , IO-Link , some kinds of Industrial Ethernet , etc. A disadvantage of the circular design is its inefficient use of panel space when used in arrays, when compared to rectangular connectors. Circular connectors commonly use backshells , which provide physical and electromagnetic protection, whilst sometimes also providing
3528-471: Is a connector that installs on the surface of a bulkhead or enclosure, and mates with its reciprocal, the plug . According to the American Society of Mechanical Engineers , the stationary (more fixed) connector of a pair is classified as a jack (denoted J), usually attached to a piece of equipment as in a chassis-mount or panel-mount connector. The movable (less fixed) connector is classified as
3626-648: Is also known, an example of a mixed-valence complex . Gold does not react with oxygen at any temperature and, up to 100 °C, is resistant to attack from ozone: Au + O 2 ⟶ ( no reaction ) {\displaystyle {\ce {Au + O2 ->}}({\text{no reaction}})} Au + O 3 → t < 100 ∘ C ( no reaction ) {\displaystyle {\ce {Au{}+O3->[{} \atop {t<100^{\circ }{\text{C}}}]}}({\text{no reaction}})} Some free halogens react to form
3724-520: Is also used in infrared shielding, the production of colored glass , gold leafing , and tooth restoration . Certain gold salts are still used as anti-inflammatory agents in medicine. Gold is the most malleable of all metals. It can be drawn into a wire of single-atom width, and then stretched considerably before it breaks. Such nanowires distort via the formation, reorientation, and migration of dislocations and crystal twins without noticeable hardening. A single gram of gold can be beaten into
3822-427: Is always richer at the exposed surface of gold-bearing veins, owing to the oxidation of accompanying minerals followed by weathering; and by washing of the dust into streams and rivers, where it collects and can be welded by water action to form nuggets. Gold sometimes occurs combined with tellurium as the minerals calaverite , krennerite , nagyagite , petzite and sylvanite (see telluride minerals ), and as
3920-517: Is attributed to wind-blown dust or rivers. At 10 parts per quadrillion, the Earth's oceans would hold 15,000 tonnes of gold. These figures are three orders of magnitude less than reported in the literature prior to 1988, indicating contamination problems with the earlier data. A number of people have claimed to be able to economically recover gold from sea water , but they were either mistaken or acted in an intentional deception. Prescott Jernegan ran
4018-470: Is found in ores in rock formed from the Precambrian time onward. It most often occurs as a native metal , typically in a metal solid solution with silver (i.e. as a gold/silver alloy ). Such alloys usually have a silver content of 8–10%. Electrum is elemental gold with more than 20% silver, and is commonly known as white gold . Electrum's color runs from golden-silvery to silvery, dependent upon
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4116-472: Is most often called the oldest since this treasure is the largest and most diverse. Gold artifacts probably made their first appearance in Ancient Egypt at the very beginning of the pre-dynastic period, at the end of the fifth millennium BC and the start of the fourth, and smelting was developed during the course of the 4th millennium; gold artifacts appear in the archeology of Lower Mesopotamia during
4214-542: Is now questioned. The gold-bearing Witwatersrand rocks were laid down between 700 and 950 million years before the Vredefort impact. These gold-bearing rocks had furthermore been covered by a thick layer of Ventersdorp lavas and the Transvaal Supergroup of rocks before the meteor struck, and thus the gold did not actually arrive in the asteroid/meteorite. What the Vredefort impact achieved, however,
4312-430: Is often used in power connectors to protect equipment, e.g. connecting safety ground first. It is also employed for digital signals, as a method to sequence connections properly in hot swapping . Many connectors are keyed with some mechanical component (sometimes called a keyway ), which prevents mating in an incorrect orientation. This can be used to prevent mechanical damage to connectors, from being jammed in at
4410-427: Is red if the particles are small; larger particles of colloidal gold are blue. Gold has only one stable isotope , Au , which is also its only naturally occurring isotope, so gold is both a mononuclidic and monoisotopic element . Thirty-six radioisotopes have been synthesized, ranging in atomic mass from 169 to 205. The most stable of these is Au with a half-life of 186.1 days. The least stable
4508-553: Is resistant to most acids, though it does dissolve in aqua regia (a mixture of nitric acid and hydrochloric acid ), forming a soluble tetrachloroaurate anion . Gold is insoluble in nitric acid alone, which dissolves silver and base metals , a property long used to refine gold and confirm the presence of gold in metallic substances, giving rise to the term ' acid test '. Gold dissolves in alkaline solutions of cyanide , which are used in mining and electroplating . Gold also dissolves in mercury , forming amalgam alloys, and as
4606-484: Is similarly unaffected by most bases. It does not react with aqueous , solid , or molten sodium or potassium hydroxide . It does however, react with sodium or potassium cyanide under alkaline conditions when oxygen is present to form soluble complexes. Common oxidation states of gold include +1 (gold(I) or aurous compounds) and +3 (gold(III) or auric compounds). Gold ions in solution are readily reduced and precipitated as metal by adding any other metal as
4704-589: Is the soluble form of gold encountered in mining. The binary gold halides , such as AuCl , form zigzag polymeric chains, again featuring linear coordination at Au. Most drugs based on gold are Au(I) derivatives. Au(III) (referred to as auric) is a common oxidation state, and is illustrated by gold(III) chloride , Au 2 Cl 6 . The gold atom centers in Au(III) complexes, like other d compounds, are typically square planar , with chemical bonds that have both covalent and ionic character. Gold(I,III) chloride
4802-657: Is thought to have been delivered to Earth by asteroid impacts during the Late Heavy Bombardment , about 4 billion years ago. Gold which is reachable by humans has, in one case, been associated with a particular asteroid impact. The asteroid that formed Vredefort impact structure 2.020 billion years ago is often credited with seeding the Witwatersrand basin in South Africa with the richest gold deposits on earth. However, this scenario
4900-511: Is thought to have been produced in supernova nucleosynthesis , and from the collision of neutron stars , and to have been present in the dust from which the Solar System formed. Traditionally, gold in the universe is thought to have formed by the r-process (rapid neutron capture) in supernova nucleosynthesis , but more recently it has been suggested that gold and other elements heavier than iron may also be produced in quantity by
4998-416: Is unaffected by most acids. It does not react with hydrofluoric , hydrochloric , hydrobromic , hydriodic , sulfuric , or nitric acid . It does react with selenic acid , and is dissolved by aqua regia , a 1:3 mixture of nitric acid and hydrochloric acid . Nitric acid oxidizes the metal to +3 ions, but only in minute amounts, typically undetectable in the pure acid because of the chemical equilibrium of
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#17327801731595096-666: The Chu (state) circulated the Ying Yuan , one kind of square gold coin. In Roman metallurgy , new methods for extracting gold on a large scale were developed by introducing hydraulic mining methods, especially in Hispania from 25 BC onwards and in Dacia from 106 AD onwards. One of their largest mines was at Las Medulas in León , where seven long aqueducts enabled them to sluice most of
5194-602: The Old Testament , starting with Genesis 2:11 (at Havilah ), the story of the golden calf , and many parts of the temple including the Menorah and the golden altar. In the New Testament , it is included with the gifts of the magi in the first chapters of Matthew. The Book of Revelation 21:21 describes the city of New Jerusalem as having streets "made of pure gold, clear as crystal". Exploitation of gold in
5292-658: The Varna Necropolis near Lake Varna and the Black Sea coast, thought to be the earliest "well-dated" finding of gold artifacts in history. Several prehistoric Bulgarian finds are considered no less old – the golden treasures of Hotnitsa, Durankulak , artifacts from the Kurgan settlement of Yunatsite near Pazardzhik , the golden treasure Sakar, as well as beads and gold jewelry found in the Kurgan settlement of Provadia – Solnitsata ("salt pit"). However, Varna gold
5390-470: The reducing agent . The added metal is oxidized and dissolves, allowing the gold to be displaced from solution and be recovered as a solid precipitate. Less common oxidation states of gold include −1, +2, and +5. The −1 oxidation state occurs in aurides, compounds containing the Au anion . Caesium auride (CsAu), for example, crystallizes in the caesium chloride motif; rubidium, potassium, and tetramethylammonium aurides are also known. Gold has
5488-611: The 1920s by Wilhelm Harold Frederick. In the 1950s, Francois Bonhomme popularised hyperboloid contacts with his "Hypertac" connector, which was later acquired by Smiths Group . During the following decades, the connectors steadily gained popularity, and are still used for medical, industrial, military, aerospace, and rail applications (particularly trains in Europe). Pogo pin or spring loaded connectors are commonly used in consumer and industrial products, where mechanical resilience and ease of use are priorities. The connector consists of
5586-538: The USA. To deliver ensured signal stability in extreme environments, traditional pin and socket design may become inadequate. Hyperboloid contacts are designed to withstand more extreme physical demands, such as vibration and shock. They also require around 40% less insertion force – as low as 0.3 newtons (1 oz f ) per contact, – which extends the lifespan, and in some cases offers an alternative to zero insertion force connectors. In
5684-418: The board. The connectors in the top row of the image are known as ring terminals and spade terminals (sometimes called fork or split ring terminals). Electrical contact is made by the flat surface of the ring or spade, while mechanically they are attached by passing a screw or bolt through them. The spade terminal form factor facilitates connections since the screw or bolt can be left partially screwed in as
5782-410: The cable and connector, and when this heat melts plastic dielectric, it can cause short circuits or "flared" (conical) insulation. Solder joints are also more prone to mechanical failure than crimped joints when subjected to vibration and compression. Since stripping insulation from wires is time-consuming, many connectors intended for rapid assembly use insulation-displacement connectors which cut
5880-403: The connection and add strain relief. Metal solder buckets or solder cups are provided, which consist of a cylindrical cavity that an installer fills with solder before inserting the wire. When creating soldered connections, it is possible to melt the dielectric between pins or wires. This can cause problems because the thermal conductivity of metals causes heat to quickly distribute through
5978-458: The connector and/or cable from environmental or mechanical stress, or shield it from electromagnetic interference . Many types of backshells are available for different purposes, including various sizes, shapes, materials, and levels of protection. Backshells usually lock onto the cable with a clamp or moulded boot, and may be threaded for attachment to a mating receptacle. Backshells for military and aerospace use are regulated by SAE AS85049 within
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#17327801731596076-510: The connector when connected and to provide the force needed for connection and disconnection. Depending on application requirements, housings with locking mechanisms may be tested under various environmental simulations that include physical shock and vibration, water spray, dust, etc. to ensure the integrity of the electrical connection and housing seals. Backshells are a common accessory for industrial and high-reliability connectors, especially circular connectors . Backshells typically protect
6174-1409: The corresponding gold halides. Gold is strongly attacked by fluorine at dull-red heat to form gold(III) fluoride AuF 3 . Powdered gold reacts with chlorine at 180 °C to form gold(III) chloride AuCl 3 . Gold reacts with bromine at 140 °C to form a combination of gold(III) bromide AuBr 3 and gold(I) bromide AuBr, but reacts very slowly with iodine to form gold(I) iodide AuI: 2 Au + 3 F 2 → Δ 2 AuF 3 {\displaystyle {\ce {2Au{}+3F2->[{} \atop \Delta ]2AuF3}}} 2 Au + 3 Cl 2 → Δ 2 AuCl 3 {\displaystyle {\ce {2Au{}+3Cl2->[{} \atop \Delta ]2AuCl3}}} 2 Au + 2 Br 2 → Δ AuBr 3 + AuBr {\displaystyle {\ce {2Au{}+2Br2->[{} \atop \Delta ]AuBr3{}+AuBr}}} 2 Au + I 2 → Δ 2 AuI {\displaystyle {\ce {2Au{}+I2->[{} \atop \Delta ]2AuI}}} Gold does not react with sulfur directly, but gold(III) sulfide can be made by passing hydrogen sulfide through
6272-424: The densest element, osmium , is 22.588 ± 0.015 g/cm . Whereas most metals are gray or silvery white, gold is slightly reddish-yellow. This color is determined by the frequency of plasma oscillations among the metal's valence electrons, in the ultraviolet range for most metals but in the visible range for gold due to relativistic effects affecting the orbitals around gold atoms. Similar effects impart
6370-689: The early 4th millennium. As of 1990, gold artifacts found at the Wadi Qana cave cemetery of the 4th millennium BC in West Bank were the earliest from the Levant. Gold artifacts such as the golden hats and the Nebra disk appeared in Central Europe from the 2nd millennium BC Bronze Age . The oldest known map of a gold mine was drawn in the 19th Dynasty of Ancient Egypt (1320–1200 BC), whereas
6468-408: The first century AD. Electrical connector Components of an electrical circuit are electrically connected if an electric current can run between them through an electrical conductor . An electrical connector is an electromechanical device used to create an electrical connection between parts of an electrical circuit, or between different electrical circuits, thereby joining them into
6566-591: The first written reference to gold was recorded in the 12th Dynasty around 1900 BC. Egyptian hieroglyphs from as early as 2600 BC describe gold, which King Tushratta of the Mitanni claimed was "more plentiful than dirt" in Egypt. Egypt and especially Nubia had the resources to make them major gold-producing areas for much of history. One of the earliest known maps, known as the Turin Papyrus Map , shows
6664-641: The function of a circuit – so connectors should affect the function of a circuit as little as possible. Insecure mounting of connectors (primarily chassis-mounted) can contribute significantly to the risk of failure, especially when subjected to extreme shock or vibration. Other causes of failure are connectors inadequately rated for the applied current and voltage, connectors with inadequate ingress protection, and threaded backshells that are worn or damaged. High temperatures can also cause failure in connectors, resulting in an "avalanche" of failures – ambient temperature increases, leading to
6762-403: The gold acts simply as a solute, this is not a chemical reaction . A relatively rare element, gold is a precious metal that has been used for coinage , jewelry , and other works of art throughout recorded history . In the past, a gold standard was often implemented as a monetary policy . Gold coins ceased to be minted as a circulating currency in the 1930s, and the world gold standard
6860-563: The highest electron affinity of any metal, at 222.8 kJ/mol, making Au a stable species, analogous to the halides . Gold also has a –1 oxidation state in covalent complexes with the group 4 transition metals, such as in titanium tetraauride and the analogous zirconium and hafnium compounds. These chemicals are expected to form gold-bridged dimers in a manner similar to titanium(IV) hydride . Gold(II) compounds are usually diamagnetic with Au–Au bonds such as [ Au(CH 2 ) 2 P(C 6 H 5 ) 2 ] 2 Cl 2 . The evaporation of
6958-490: The hyperboloid structure are usually anchored at each end by bending the tip into a groove or notch in the housing. Whilst hyperboloid contacts may be the only option to make a reliable connection in some circumstances, they have the disadvantage of taking up greater volume in a connector, which can cause problems for high-density connectors. They are also significantly more expensive than traditional pin and socket contacts, which has limited their uptake since their invention in
7056-574: The insulation as the wire is inserted. These generally take the form of a fork-shaped opening in the terminal, into which the insulated wire is pressed, which cut through the insulation to contact the conductor. To make these connections reliably on a production line, special tools accurately control the forces applied during assembly. On small scales, these tools tend to cost more than tools for crimped connections. Insulation displacement connectors are usually used with small conductors for signal purposes and at low voltage. Power conductors carrying more than
7154-498: The latter being pneumatic line connectors, and optical fiber connectors . Because hybrid connectors are modular in nature, they tend to simplify assembly, repair, and future modifications. They also allow the creation of composite cable assemblies that can reduce equipment installation time by reducing the number of individual cable and connector assemblies. Some connectors are designed such that certain pins make contact before others when inserted, and break first on disconnection. This
7252-519: The metal of the connector past its yield point so that the compressed wire causes tension in the surrounding connector, and these forces counter each other to create a high degree of static friction . Due to the elastic element in crimped connections, they are highly resistant to vibration and thermal shock . Crimped contacts are permanent (i.e. the connectors and wire ends cannot be reused). Crimped plug-and-socket connectors can be classified as rear release or front release . This relates to
7350-547: The mineral quartz, and gold out of the fluids and onto nearby surfaces. The world's oceans contain gold. Measured concentrations of gold in the Atlantic and Northeast Pacific are 50–150 femtomol /L or 10–30 parts per quadrillion (about 10–30 g/km ). In general, gold concentrations for south Atlantic and central Pacific samples are the same (~50 femtomol/L) but less certain. Mediterranean deep waters contain slightly higher concentrations of gold (100–150 femtomol/L), which
7448-425: The most flexible types of electrical connector available. One type of terminal block accepts wires that are prepared only by stripping a short length of insulation from the end. Another type, often called barrier strips , accepts wires that have ring or spade terminal lugs crimped onto the wires. Printed circuit board (PCB) mounted screw terminals let individual wires connect to a PCB through leads soldered to
7546-411: The noble metals, it still forms many diverse compounds. The oxidation state of gold in its compounds ranges from −1 to +5, but Au(I) and Au(III) dominate its chemistry. Au(I), referred to as the aurous ion, is the most common oxidation state with soft ligands such as thioethers , thiolates , and organophosphines . Au(I) compounds are typically linear. A good example is Au(CN) − 2 , which
7644-504: The parts of a connector together are usually made of plastic, due to its insulating properties. Housings or backshells can be made of molded plastic and metal. Connector bodies for high-temperature use, such as thermocouples or associated with large incandescent lamps , may be made of fired ceramic material. The majority of connector failures result in intermittent connections or open contacts: Connectors are purely passive components – that is, they do not enhance
7742-576: The plan of a gold mine in Nubia together with indications of the local geology . The primitive working methods are described by both Strabo and Diodorus Siculus , and included fire-setting . Large mines were also present across the Red Sea in what is now Saudi Arabia . Gold is mentioned in the Amarna letters numbered 19 and 26 from around the 14th century BC. Gold is mentioned frequently in
7840-464: The project. The earliest recorded metal employed by humans appears to be gold, which can be found free or " native ". Small amounts of natural gold have been found in Spanish caves used during the late Paleolithic period, c. 40,000 BC . The oldest gold artifacts in the world are from Bulgaria and are dating back to the 5th millennium BC (4,600 BC to 4,200 BC), such as those found in
7938-690: The r-process in the collision of neutron stars . In both cases, satellite spectrometers at first only indirectly detected the resulting gold. However, in August 2017, the spectroscopic signatures of heavy elements, including gold, were observed by electromagnetic observatories in the GW170817 neutron star merger event, after gravitational wave detectors confirmed the event as a neutron star merger. Current astrophysical models suggest that this single neutron star merger event generated between 3 and 13 Earth masses of gold. This amount, along with estimations of
8036-620: The rare bismuthide maldonite ( Au 2 Bi ) and antimonide aurostibite ( AuSb 2 ). Gold also occurs in rare alloys with copper , lead , and mercury : the minerals auricupride ( Cu 3 Au ), novodneprite ( AuPb 3 ) and weishanite ( (Au,Ag) 3 Hg 2 ). A 2004 research paper suggests that microbes can sometimes play an important role in forming gold deposits, transporting and precipitating gold to form grains and nuggets that collect in alluvial deposits. A 2013 study has claimed water in faults vaporizes during an earthquake, depositing gold. When an earthquake strikes, it moves along
8134-420: The rate of occurrence of these neutron star merger events, suggests that such mergers may produce enough gold to account for most of the abundance of this element in the universe. Because the Earth was molten when it was formed , almost all of the gold present in the early Earth probably sank into the planetary core . Therefore, as hypothesized in one model, most of the gold in the Earth's crust and mantle
8232-935: The reaction. However, the ions are removed from the equilibrium by hydrochloric acid, forming AuCl − 4 ions, or chloroauric acid , thereby enabling further oxidation: 2 Au + 6 H 2 SeO 4 → 200 ∘ C Au 2 ( SeO 4 ) 3 + 3 H 2 SeO 3 + 3 H 2 O {\displaystyle {\ce {2Au{}+6H2SeO4->[{} \atop {200^{\circ }{\text{C}}}]Au2(SeO4)3{}+3H2SeO3{}+3H2O}}} Au + 4 HCl + HNO 3 ⟶ HAuCl 4 + NO ↑ + 2 H 2 O {\displaystyle {\ce {Au{}+4HCl{}+HNO3->HAuCl4{}+NO\uparrow +2H2O}}} Gold
8330-473: The rest of the gold on Earth is thought to have been incorporated into the planet since its very beginning, as planetesimals formed the mantle . In 2017, an international group of scientists established that gold "came to the Earth's surface from the deepest regions of our planet", the mantle, as evidenced by their findings at Deseado Massif in the Argentinian Patagonia . On Earth, gold
8428-490: The same gender of connector, as in many Ethernet patch cables. In other applications the two ends are terminated differently, either with male and female of the same connector (as in an extension cord ), or with incompatible connectors, which is sometimes called an adapter cable . Plugs and sockets are widely used in various connector systems including blade connectors, breadboards , XLR connectors , car power outlets , banana connectors , and phone connectors . A jack
8526-486: The same result and showing that the isotopes of gold produced by it were all radioactive . In 1980, Glenn Seaborg transmuted several thousand atoms of bismuth into gold at the Lawrence Berkeley Laboratory. Gold can be manufactured in a nuclear reactor, but doing so is highly impractical and would cost far more than the value of the gold that is produced. Although gold is the most noble of
8624-423: The side of the connector where the pins are anchored: Many plug and socket connectors are attached to a wire or cable by soldering conductors to electrodes on the back of the connector. Soldered joints in connectors are robust and reliable if executed correctly, but are usually slower to make than crimped connections. When wires are to be soldered to the back of a connector, a backshell is often used to protect
8722-486: The silver content. The more silver, the lower the specific gravity . Native gold occurs as very small to microscopic particles embedded in rock, often together with quartz or sulfide minerals such as " fool's gold ", which is a pyrite . These are called lode deposits. The metal in a native state is also found in the form of free flakes, grains or larger nuggets that have been eroded from rocks and end up in alluvial deposits called placer deposits . Such free gold
8820-450: The south-east corner of the Black Sea is said to date from the time of Midas , and this gold was important in the establishment of what is probably the world's earliest coinage in Lydia around 610 BC. The legend of the golden fleece dating from eighth century BCE may refer to the use of fleeces to trap gold dust from placer deposits in the ancient world. From the 6th or 5th century BC,
8918-436: The tendency of gold ions to interact at distances that are too long to be a conventional Au–Au bond but shorter than van der Waals bonding . The interaction is estimated to be comparable in strength to that of a hydrogen bond . Well-defined cluster compounds are numerous. In some cases, gold has a fractional oxidation state. A representative example is the octahedral species {Au( P(C 6 H 5 ) 3 )} 2+ 6 . Gold
9016-419: The tip of a bolt clamping onto a stripped conductor. They can be used to join multiple conductors, to connect wires to a printed circuit board , or to terminate a cable into a plug or socket. The clamping screw may act in the longitudinal axis (parallel to the wire) or the transverse axis (perpendicular to the wire), or both. Some disadvantages are that connecting wires is more difficult than simply plugging in
9114-403: The transmutation of the chemical elements did not become possible until the understanding of nuclear physics in the 20th century. The first synthesis of gold was conducted by Japanese physicist Hantaro Nagaoka , who synthesized gold from mercury in 1924 by neutron bombardment. An American team, working without knowledge of Nagaoka's prior study, conducted the same experiment in 1941, achieving
9212-417: The visors of heat-resistant suits and in sun visors for spacesuits . Gold is a good conductor of heat and electricity . Gold has a density of 19.3 g/cm , almost identical to that of tungsten at 19.25 g/cm ; as such, tungsten has been used in the counterfeiting of gold bars , such as by plating a tungsten bar with gold. By comparison, the density of lead is 11.34 g/cm , and that of
9310-581: The wires in a single action. Another very common use is so-called punch-down blocks used for terminating unshielded twisted pair wiring. Binding posts are a single-wire connection method, where stripped wire is screwed or clamped to a metal electrode. Such connectors are frequently used in electronic test equipment and audio. Many binding posts also accept a banana plug . Screw connections are frequently used for semi-permanent wiring and connections inside devices, due to their simple but reliable construction. The basic principle of all screw terminals involves
9408-435: The wrong angle or into the wrong connector, or to prevent incompatible or dangerous electrical connections, such as plugging an audio cable into a power outlet. Keying also prevents otherwise symmetrical connectors from being connected in the wrong orientation or polarity . Keying is particularly important for situations where there are many similar connectors, such as in signal electronics. For instance, XLR connectors have
9506-787: Was abandoned for a fiat currency system after the Nixon shock measures of 1971. In 2020, the world's largest gold producer was China, followed by Russia and Australia. As of 2020 , a total of around 201,296 tonnes of gold exist above ground. This is equal to a cube, with each side measuring roughly 21.7 meters (71 ft). The world's consumption of new gold produced is about 50% in jewelry, 40% in investments , and 10% in industry . Gold's high malleability, ductility, resistance to corrosion and most other chemical reactions, as well as conductivity of electricity have led to its continued use in corrosion-resistant electrical connectors in all types of computerized devices (its chief industrial use). Gold
9604-621: Was to distort the Witwatersrand basin in such a way that the gold-bearing rocks were brought to the present erosion surface in Johannesburg , on the Witwatersrand , just inside the rim of the original 300 km (190 mi) diameter crater caused by the meteor strike. The discovery of the deposit in 1886 launched the Witwatersrand Gold Rush . Some 22% of all the gold that is ascertained to exist today on Earth has been extracted from these Witwatersrand rocks. Much of
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