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48-643: Northeast of the Ifen plateau is the Gottesacker plateau , a karst landscape which has been designated a nature reserve and which has numerous caves and rare mountain plants. The most important caves are the Hölloch im Mahdtal and the Schneckenloch Cave near Schönenbach. On the eastern slopes of the massif a Stone Age dwelling site was discovered on the mountain pasture of Schneiderkürenalpe at

96-805: A height of about 1,500 m. On the southern side of the mountain an undisturbed wildlife area has been declared by the Bregenz district commission at the instigation of the Walser Hunting Club ( Walser Jägerschaft ), that has restricted the usual Austrian freedom of passage in accordance with § 33 of the Forestry Act. Mountaineering clubs, in particular the German Alpine Club , the Austrian Alpine Club and Allgäu Climbing Group ( IG Klettern Allgäu ) have criticised

144-519: A pioneer of the study of karst in Slovenia and a fellow of the Royal Society , London, introduced the word karst to European scholars in 1689 to describe the phenomenon of underground flows of rivers in his account of Lake Cerknica . Jovan Cvijić greatly advanced the knowledge of karst regions to the point where he became known as the "father of karst geomorphology". Primarily discussing

192-582: A proper noun, the Slovene form Grast was first attested in 1177. Ultimately, the word is of Mediterranean origin. It has also been suggested that the word may derive from the Proto-Indo-European root karra- 'rock'. The name may also be connected to the oronym Kar(u)sádios oros cited by Ptolemy , and perhaps also to Latin Carusardius . Johann Weikhard von Valvasor ,

240-476: A referendum was held. About 55% of the voters rejected the proposal to build the lift. Karst Karst ( / k ɑːr s t / ) is a topography formed from the dissolution of soluble carbonate rocks such as limestone and dolomite . It is characterized by features like poljes above and drainage systems with sinkholes and caves underground. There is some evidence that karst may occur in more weathering -resistant rocks such as quartzite given

288-401: A sport than a science and so the underground karst caves and their associated watercourses were, from a scientific perspective, understudied. Karst is most strongly developed in dense carbonate rock , such as limestone, that is thinly bedded and highly fractured . Karst is not typically well developed in chalk , because chalk is highly porous rather than dense, so the flow of groundwater

336-435: A variety of spatial and temporal scales in karst regions, with the purpose of understanding karst aquifers and ecosystems, and the development of the surface and underground structure, so that the environment can be protected and human activities planned effectively. Carbonate rock Carbonate rocks are a class of sedimentary rocks composed primarily of carbonate minerals . The two major types are limestone , which

384-529: A well in a fracture trace or intersection of fracture traces increases the likelihood to encounter good water production. Voids in karst aquifers can be large enough to cause destructive collapse or subsidence of the ground surface that can initiate a catastrophic release of contaminants. Groundwater flow rate in karst aquifers is much more rapid than in porous aquifers. For example, in the Barton Springs Edwards aquifer, dye traces measured

432-505: Is a UNESCO World Heritage Site. Many karst-related terms derive from South Slavic languages , entering scientific vocabulary through early research in the Western Balkan Dinaric Alpine karst. The study of the various aspects of karst regions is called karstology. This includes biological, chemical, ecological, geomorphological, hydrogeological, hydrological, political, socio-economical, and other processes over

480-562: Is a development of karst observed in geological history and preserved within the rock sequence, effectively a fossil karst. There are for example palaeokarst surfaces exposed within the Clydach Valley Subgroup of the Carboniferous Limestone sequence of South Wales which developed as sub-aerial weathering of recently formed limestones took place during periods of non-deposition within the early part of

528-538: Is a karst landscape which is developed beneath a cover of insoluble rocks. Typically this will involve a cover of sandstone overlying limestone strata undergoing solution. In the United Kingdom for example extensive doline fields have developed at Cefn yr Ystrad , Mynydd Llangatwg and Mynydd Llangynidr in South Wales across a cover of Twrch Sandstone which overlies concealed Carboniferous Limestone ,

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576-856: Is composed of calcite or aragonite (different crystal forms of CaCO 3 ), and dolomite rock (also known as dolostone), which is composed of dolomite (CaMg(CO 3 ) 2 ). They are usually classified on the basis of texture and grain size . Importantly, carbonate rocks can exist as metamorphic and igneous rocks, too. When recrystallized carbonate rocks are metamorphosed , marble is created. Rare igneous carbonate rocks even exist as intrusive carbonatites and, even rarer, there exists volcanic carbonate lava . Carbonate rocks are also crucial components to understanding geologic history due to processes such as diagenesis in which carbonates undergo compositional changes based on kinetic effects . The correlation between this compositional change and temperature can be exploited to reconstruct past climate as

624-468: Is developed in areas where salt is undergoing solution underground. It can lead to surface depressions and collapses which present a geo-hazard. Karst areas tend to have unique types of forests. The karst terrain is difficult for humans to traverse, so that their ecosystems are often relatively undisturbed. The soil tends to have a high pH, which encourages growth of unusual species of orchids, palms, mangroves, and other plants. Paleokarst or palaeokarst

672-402: Is doloimite which contains significant trace levels of iron. Due to the similar ionic radii of iron(II) and magnesium , iron(II) can easily substitute magnesium to form ferroan dolomite; manganese can also substitute this atom. The result can be defined as ankerite . The exact delineation between which minerals are considered ferroan dolomite and which are ankerite is unclear. Ankerite with

720-433: Is dolomite which has more calcium than magnesium in its mineral form. This is the most common form of dolomite found naturally and artificially from synthesis . This dolomite, when formed in the oceans, can prove to be metastable . The resultant structure of this mineral presents minimal differences from regular dolomite likely as a result of formation after initial crystal growth. Iron-rich dolomite, or ferroan dolomite,

768-465: Is done in paleoclimatology . Carbonate rocks can also be used for understanding various other systems as described below. Limestone is the most common carbonate rock and is a sedimentary rock made of calcium carbonate with two main polymorphs : calcite and aragonite. While the chemical composition of these two minerals is the same, their physical properties differ significantly due to their different crystalline form . The most common form found in

816-636: Is frequently unseen until the roof of a cavern suddenly collapses. Such events have swallowed homes, cattle, cars, and farm machinery. In the United States, sudden collapse of such a cavern-sinkhole swallowed part of the collection of the National Corvette Museum in Bowling Green, Kentucky in 2014. The world's largest limestone karst is Australia's Nullarbor Plain . Slovenia has the world's highest risk of sinkholes, while

864-407: Is important in petroleum geology because as much as 50% of the world's hydrocarbon reserves are hosted in carbonate rock , and much of this is found in porous karst systems. The English word karst was borrowed from German Karst in the late 19th century, which entered German usage much earlier, to describe a number of geological, geomorphological, and hydrological features found within

912-399: Is not concentrated along fractures. Karst is also most strongly developed where the water table is relatively low, such as in uplands with entrenched valleys , and where rainfall is moderate to heavy. This contributes to rapid downward movement of groundwater, which promotes dissolution of the bedrock, whereas standing groundwater becomes saturated with carbonate minerals and ceases to dissolve

960-621: Is the following: In very rare conditions, oxidation can play a role. Oxidation played a major role in the formation of ancient Lechuguilla Cave in the US state of New Mexico and is presently active in the Frasassi Caves of Italy. The oxidation of sulfides leading to the formation of sulfuric acid can also be one of the corrosion factors in karst formation. As oxygen (O 2 )-rich surface waters seep into deep anoxic karst systems, they bring oxygen, which reacts with sulfide present in

1008-951: The Allgäuer Überlandwerk and the Raiffeisen Holding Kleinwalsertal . The Kleinwalsertaler Bergbahn AG plans to build a link lift to the Walmendinger Horn The expansion plans were sharply criticised by several associations because they were viewed as damaging to the environment and would promote mass tourism . The Austrian Alpine Club section in the Kleinwalsertal criticised the plans as follows: The construction of this lift cannot be done in harmony with nature as we would wish to remind those launching such an initiative! The Kleinwalsertal Landscape Protection Society ( Landschaftsschutz Kleinwalsertal ) expressed similar views. On October 21, 2012,

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1056-710: The Ifen-Bergbahn-Gesellschaft , emerged. For a long time it was mostly owned by Ruth Merckle, the wife of the pharmaceutical businessman Adolf Merckle . By taking over the Merckle family's 82% share and the 18% share of the family of Kleinwalsertal tourism pioneer, Alfons Herz, on 1 July 2009, the Ifen Bergbahn GmbH u. Co gained full ownership of the Kleinwalsertaler Bergbahn (KBB), Riezlern, whose main shareholders are

1104-544: The greenhouse effect . There is significant amount of research studying the ideal quantity of calcium carbonate (derived from limestone) in concrete and if other compounds can be used to provide the same economic and structural integrity benefits. Many forms of paleoclimatology exist whereby carbonate rocks can be used to determine past climate. Corals and sediments are well-known proxies for these reconstructions. Corals are marine organisms with calcium carbonate skeletons (rocks) which grow specific to oceanic conditions at

1152-636: The range of the Dinaric Alps , stretching from the northeastern corner of Italy above the city of Trieste , across the Balkan peninsula along the coast of the eastern Adriatic to Kosovo and North Macedonia , where the massif of the Šar Mountains begins. The karst zone is at the northwesternmost section, described in early topographical research as a plateau between Italy and Slovenia . Languages preserving this form include Italian : Carso , German : Karst , and Albanian : karsti . In

1200-503: The "pure" CaFe(CO 3 ) 2 chemical formula has yet to be found in nature . Carbonate rocks are significant for both human understanding of Earth's atmospheric and geologic history, in addition to providing humans with significant resources for current civilizational endeavors such as concrete . Limestone is often used in concrete as powder due to its cheap cost. During the formation of concrete, however, breakdown of limestone releases carbon dioxide and contributes significantly to

1248-469: The aragonite of coral skeleton can be used, alongside other proxies like oxygen isotopic ratios , to reconstruct climate variability when the coral was growing. This is because Strontium will sometimes substitute for Calcium in the calcium carbonate molecule depending on temperature effects. Similar to the concept for using compositional changes in coral skeletons as proxies for climate conditions, compositional changes in marine sediments can be used for

1296-511: The bedrock. The carbonic acid that causes karst features is formed as rain passes through Earth's atmosphere picking up carbon dioxide (CO 2 ), which readily dissolves in the water. Once the rain reaches the ground, it may pass through soil that provides additional CO 2 produced by soil respiration . Some of the dissolved carbon dioxide reacts with the water to form a weak carbonic acid solution, which dissolves calcium carbonate . The primary reaction sequence in limestone dissolution

1344-450: The complexity of karst aquifers, and need to be supplemented with dye traces , measurement of spring discharges, and analysis of water chemistry. U.S. Geological Survey dye tracing has determined that conventional groundwater models that assume a uniform distribution of porosity are not applicable for karst aquifers. Linear alignment of surface features such as straight stream segments and sinkholes develop along fracture traces . Locating

1392-529: The existing rock grains together or it can fill fractures. Compared to calcite, aragonite is less stable and more soluble , and can thus be converted to calcite under certain conditions. In solution, magnesium ions can act as promoters of aragonite growth as they inhibit calcite precipitation . Often this inhibited precipitation occurs in biology where organisms aim to precipitate calcium carbonate for their structural features such as for skeleton and shells . The discovery of dolomite rock, or dolostone ,

1440-557: The fissures. The enlarged fissures allow a larger quantity of water to enter which leads to a progressive enlargement of openings. Abundant small openings store a large quantity of water. The larger openings form a conduit system that drains the aquifer to springs. Characterization of karst aquifers requires field exploration to locate sinkholes, swallets , sinking streams , and springs in addition to studying geologic maps . Conventional hydrogeologic methods such as aquifer tests and potentiometric mapping are insufficient to characterize

1488-466: The global demand for drinkable water. Farming in karst areas must take into account the lack of surface water. The soils may be fertile enough, and rainfall may be adequate, but rainwater quickly moves through the crevices into the ground, sometimes leaving the surface soil parched between rains. The karst topography also poses peculiar difficulties for human inhabitants. Sinkholes can develop gradually as surface openings enlarge, but progressive erosion

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1536-456: The karst groundwater flow rates from 0.5 to 7 miles per day (0.8 to 11.3 km/d). The rapid groundwater flow rates make karst aquifers much more sensitive to groundwater contamination than porous aquifers. Groundwater in karst areas is also just as easily polluted as surface streams, because Karst formations are cavernous and highly permeable, resulting in reduced opportunity for contaminant filtration. Well water may also be unsafe as

1584-534: The karst regions of the Balkans, Cvijić's 1893 publication Das Karstphänomen describes landforms such as karren, dolines and poljes . In a 1918 publication, Cvijić proposed a cyclical model for karst landscape development. Karst hydrology emerged as a discipline in the late 1950s and the early 1960s in France. Previously, the activities of cave explorers, called speleologists , had been dismissed as more of

1632-562: The last-named locality having been declared a site of special scientific interest in respect of it. Kegelkarst is a type of tropical karst terrain with numerous cone-like hills, formed by cockpits, mogotes , and poljes and without strong fluvial erosion processes. This terrain is found in Cuba, Jamaica, Indonesia, Malaysia, the Philippines, Puerto Rico, southern China, Myanmar, Thailand, Laos and Vietnam. Salt karst (or 'halite karst')

1680-412: The local South Slavic languages , all variations of the word are derived from a Romanized Illyrian base (yielding Latin : carsus , Dalmatian : carsus ), later metathesized from the reconstructed form * korsъ into forms such as Slovene : kras and Serbo-Croatian : krš , kras , first attested in the 18th century, and the adjective form kraški in the 16th century. As

1728-647: The most dramatic of these formations can be seen in Thailand 's Phangnga Bay and at Halong Bay in Vietnam . Calcium carbonate dissolved into water may precipitate out where the water discharges some of its dissolved carbon dioxide. Rivers which emerge from springs may produce tufa terraces, consisting of layers of calcite deposited over extended periods of time. In caves, a variety of features collectively called speleothems are formed by deposition of calcium carbonate and other dissolved minerals. Interstratal karst

1776-709: The period. Sedimentation resumed and further limestone strata were deposited on an irregular karst surface, the cycle recurring several times in connection with fluctuating sea levels over prolonged periods. Pseudokarsts are similar in form or appearance to karst features but are created by different mechanisms. Examples include lava caves and granite tors —for example, Labertouche Cave in Victoria, Australia —and paleocollapse features. Mud Caves are an example of pseudokarst. Karst formations have unique hydrology, resulting in many unusual features. A karst fenster (karst window) occurs when an underground stream emerges onto

1824-613: The regulation by the Bregenz district commission, because, within its boundaries, on the southern edge of the plateau and at Bärenköpfe is one of the best sport climbing areas in the Alps. The south faces are called the Céüse of the Allgäu, a comparison to the most famous climbing area in Europe. At the beginning of the 1970s the first ski lifts appeared on the Ifen, from which today's company,

1872-418: The right conditions. Subterranean drainage may limit surface water, with few to no rivers or lakes. In regions where the dissolved bedrock is covered (perhaps by debris) or confined by one or more superimposed non-soluble rock strata, distinctive karst features may occur only at subsurface levels and can be totally missing above ground. The study of paleokarst (buried karst in the stratigraphic column )

1920-780: The river flows into a cave in a formation known as the Madison Limestone and then rises again 800 m ( 1 ⁄ 2  mi) down the canyon in a placid pool. A turlough is a unique type of seasonal lake found in Irish karst areas which are formed through the annual welling-up of water from the underground water system. Main Article Aquifer#Karst Karst aquifers typically develop in limestone . Surface water containing natural carbonic acid moves down into small fissures in limestone. This carbonic acid gradually dissolves limestone thereby enlarging

1968-512: The seafloor is calcite, while aragonite is more found in biological organisms. Calcite can be either dissolved by groundwater or precipitated by groundwater, depending on several factors including the water temperature , pH , and dissolved ion concentrations. Calcite exhibits an unusual characteristic called retrograde solubility in which it becomes less soluble in water as the temperature increases. When conditions are right for precipitation, calcite forms mineral coatings that cement

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2016-649: The surface between layers of rock, cascades some distance, and then disappears back down, often into a sinkhole. Rivers in karst areas may disappear underground a number of times and spring up again in different places, even under a different name, like Ljubljanica , the "river of seven names". Another example of this is the Popo Agie River in Fremont County, Wyoming , where, at a site named "The Sinks" in Sinks Canyon State Park ,

2064-415: The surface, complex underground drainage systems (such as karst aquifers ) and extensive caves and cavern systems may form. Erosion along limestone shores, notably in the tropics , produces karst topography that includes a sharp makatea surface above the normal reach of the sea, and undercuts that are mostly the result of biological activity or bioerosion at or a little above mean sea level . Some of

2112-1002: The system ( pyrite or hydrogen sulfide ) to form sulfuric acid (H 2 SO 4 ). Sulfuric acid then reacts with calcium carbonate, causing increased erosion within the limestone formation. This chain of reactions is: This reaction chain forms gypsum . The karstification of a landscape may result in a variety of large- or small-scale features both on the surface and beneath. On exposed surfaces, small features may include solution flutes (or rillenkarren), runnels , limestone pavement (clints and grikes), kamenitzas collectively called karren or lapiez. Medium-sized surface features may include sinkholes or cenotes (closed basins), vertical shafts, foibe (inverted funnel shaped sinkholes), disappearing streams, and reappearing springs . Large-scale features may include limestone pavements , poljes , and karst valleys. Mature karst landscapes, where more bedrock has been removed than remains, may result in karst towers , or haystack/eggbox landscapes. Beneath

2160-404: The time of growth. Diagenesis refers to the process whereby sediments are being converted to sedimentary rock. This includes biological activity, erosion, and other chemical reactions. Due to the strong correlation between diagenesis and seawater temperature , coral skeletons can be used as proxies for understanding past climate effects. Specifically, the ratio of Strontium to Calcium in

2208-461: The water may have run unimpeded from a sinkhole in a cattle pasture, bypassing the normal filtering that occurs in a porous aquifer . Sinkholes have often been used as farmstead or community trash dumps . Overloaded or malfunctioning septic tanks in karst landscapes may dump raw sewage directly into underground channels. Geologists are concerned with these negative effects of human activity on karst hydrology which, as of 2007 , supplied about 25% of

2256-515: The western Highland Rim in the eastern United States is at the second-highest risk of karst sinkholes. In Canada, Wood Buffalo National Park , Northwest Territories contains areas of karst sinkholes. Mexico hosts important karst regions in the Yucatán Peninsula and Chiapas . The West of Ireland is home to The Burren , a karst limestone area. The South China Karst in the provinces of Guizhou , Guangxi , and Yunnan provinces

2304-528: Was first published in 1791 and has been found across the Earth's crust from various different time periods . Because the rock is made of calcium , magnesium , and carbonate ions, the mineral crystalline structure can be visualized similar to calcite and magnesite . Due to this composition, the dolomite mineral present in dolostone can be classified by varying degree of calcium inclusion, and occasionally iron, too. Calcium-rich dolomite, or calcian dolomite,

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