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High Stile

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99-544: High Stile is a mountain in the western part of the Lake District in North West England . It is the eleventh-highest English Marilyn , standing 807 metres (2,648 ft) high, and has a relative height of 362 metres (1,188 ft). It is the highest in the range of fells extending north-west from Great Gable towards Loweswater , and together with its satellites, Red Pike and High Crag , forms

198-579: A Gilman reagent . These can undergo substitution with alkyl halides to form coupling products ; as such, they are important in the field of organic synthesis . Copper(I) acetylide is highly shock-sensitive but is an intermediate in reactions such as the Cadiot–Chodkiewicz coupling and the Sonogashira coupling . Conjugate addition to enones and carbocupration of alkynes can also be achieved with organocopper compounds. Copper(I) forms

297-696: A covalent character and are relatively weak. This observation explains the low hardness and high ductility of single crystals of copper. At the macroscopic scale, introduction of extended defects to the crystal lattice , such as grain boundaries, hinders flow of the material under applied stress, thereby increasing its hardness. For this reason, copper is usually supplied in a fine-grained polycrystalline form, which has greater strength than monocrystalline forms. The softness of copper partly explains its high electrical conductivity ( 59.6 × 10   S /m ) and high thermal conductivity, second highest (second only to silver) among pure metals at room temperature. This

396-643: A nickel ) consists of 75% copper and 25% nickel in homogeneous composition. Prior to the introduction of cupronickel, which was widely adopted by countries in the latter half of the 20th century, alloys of copper and silver were also used, with the United States using an alloy of 90% silver and 10% copper until 1965, when circulating silver was removed from all coins with the exception of the half dollar—these were debased to an alloy of 40% silver and 60% copper between 1965 and 1970. The alloy of 90% copper and 10% nickel, remarkable for its resistance to corrosion,

495-425: A spin of 3 ⁄ 2 . The other isotopes are radioactive , with the most stable being Cu with a half-life of 61.83 hours. Seven metastable isomers have been characterized; Cu is the longest-lived with a half-life of 3.8 minutes. Isotopes with a mass number above 64 decay by β , whereas those with a mass number below 64 decay by β . Cu , which has

594-428: A biotemperature below 1.5 °C (34.7 °F). Mountain environments are particularly sensitive to anthropogenic climate change and are currently undergoing alterations unprecedented in last 10,000 years. The effect of global warming on mountain regions (relative to lowlands) is still an active area of study. Observational studies show that highlands are warming faster than nearby lowlands, but when compared globally,

693-399: A blast furnace. A potential source of copper is polymetallic nodules, which have an estimated concentration 1.3%. Like aluminium , copper is recyclable without any loss of quality, both from raw state and from manufactured products. In volume, copper is the third most recycled metal after iron and aluminium. An estimated 80% of all copper ever mined is still in use today. According to

792-464: A blue crystalline penta hydrate , the most familiar copper compound in the laboratory. It is used in a fungicide called the Bordeaux mixture . Polyols , compounds containing more than one alcohol functional group , generally interact with cupric salts. For example, copper salts are used to test for reducing sugars . Specifically, using Benedict's reagent and Fehling's solution the presence of

891-457: A green patina of compounds called verdigris . Copper is sometimes used in decorative art , both in its elemental metal form and in compounds as pigments. Copper compounds are used as bacteriostatic agents , fungicides , and wood preservatives . Copper is essential to all living organisms as a trace dietary mineral because it is a key constituent of the respiratory enzyme complex cytochrome c oxidase . In molluscs and crustaceans , copper

990-505: A half-life of 12.7 hours, decays both ways. Cu and Cu have significant applications. Cu is used in Cu Cu-PTSM as a radioactive tracer for positron emission tomography . Copper is produced in massive stars and is present in the Earth's crust in a proportion of about 50 parts per million (ppm). In nature, copper occurs in

1089-687: A layer of brown-black copper oxide which, unlike the rust that forms on iron in moist air, protects the underlying metal from further corrosion ( passivation ). A green layer of verdigris (copper carbonate) can often be seen on old copper structures, such as the roofing of many older buildings and the Statue of Liberty . Copper tarnishes when exposed to some sulfur compounds, with which it reacts to form various copper sulfides . There are 29 isotopes of copper. Cu and Cu are stable, with Cu comprising approximately 69% of naturally occurring copper; both have

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1188-464: A mountain is roughly equivalent to moving 80 kilometres (45 miles or 0.75° of latitude ) towards the nearest pole. This relationship is only approximate, however, since local factors such as proximity to oceans (such as the Arctic Ocean) can drastically modify the climate. As the altitude increases, the main form of precipitation becomes snow and the winds increase. The effect of

1287-532: A natural color other than gray or silver. Pure copper is orange-red and acquires a reddish tarnish when exposed to air. This is due to the low plasma frequency of the metal, which lies in the red part of the visible spectrum, causing it to absorb the higher-frequency green and blue colors. As with other metals, if copper is put in contact with another metal in the presence of an electrolyte , galvanic corrosion will occur. Copper does not react with water, but it does slowly react with atmospheric oxygen to form

1386-407: A red-brown precipitate with copper(II) salts. Compounds that contain a carbon-copper bond are known as organocopper compounds. They are very reactive towards oxygen to form copper(I) oxide and have many uses in chemistry . They are synthesized by treating copper(I) compounds with Grignard reagents , terminal alkynes or organolithium reagents ; in particular, the last reaction described produces

1485-451: A rich variety of compounds, usually with oxidation states +1 and +2, which are often called cuprous and cupric , respectively. Copper compounds promote or catalyse numerous chemical and biological processes. As with other elements, the simplest compounds of copper are binary compounds, i.e. those containing only two elements, the principal examples being oxides, sulfides, and halides . Both cuprous and cupric oxides are known. Among

1584-648: A significant role in religion. There are for example a number of sacred mountains within Greece such as Mount Olympus which was held to be the home of the gods. In Japanese culture, the 3,776.24 m (12,389.2 ft) volcano of Mount Fuji is also held to be sacred with tens of thousands of Japanese ascending it each year. Mount Kailash , in the Tibet Autonomous Region of China, is considered to be sacred in four religions: Hinduism, Bon , Buddhism, and Jainism . In Ireland, pilgrimages are made up

1683-533: A trio of fells overlooking the lake and village of Buttermere . On this side are high crags, wild combes and a small tarn, Bleaberry Tarn . High Stile is most easily ascended as part of a traverse of the three fells. The Western Fells occupy a triangular sector of the Lake District, bordered by the River Cocker to the north east and Wasdale to the south east. Westwards the hills diminish toward

1782-424: A variety of minerals, including native copper , copper sulfides such as chalcopyrite , bornite , digenite , covellite , and chalcocite , copper sulfosalts such as tetrahedite-tennantite , and enargite , copper carbonates such as azurite and malachite , and as copper(I) or copper(II) oxides such as cuprite and tenorite , respectively. The largest mass of elemental copper discovered weighed 420 tonnes and

1881-436: A variety of weak complexes with alkenes and carbon monoxide , especially in the presence of amine ligands. Copper(III) is most often found in oxides. A simple example is potassium cuprate , KCuO 2 , a blue-black solid. The most extensively studied copper(III) compounds are the cuprate superconductors . Yttrium barium copper oxide (YBa 2 Cu 3 O 7 ) consists of both Cu(II) and Cu(III) centres. Like oxide, fluoride

1980-419: A whole, 24% of the Earth's land mass is mountainous. There are three main types of mountains: volcanic , fold , and block . All three types are formed from plate tectonics : when portions of the Earth's crust move, crumple, and dive. Compressional forces, isostatic uplift and intrusion of igneous matter forces surface rock upward, creating a landform higher than the surrounding features. The height of

2079-452: Is El Alto , Bolivia, at 4,150 metres (13,620 ft), which has a highly diverse service and manufacturing economy and a population of nearly 1 million. Traditional mountain societies rely on agriculture, with higher risk of crop failure than at lower elevations. Minerals often occur in mountains, with mining being an important component of the economics of some mountain-based societies. More recently, tourism has become more important to

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2178-571: Is Mount Everest in the Himalayas of Asia , whose summit is 8,850 m (29,035 ft) above mean sea level. The highest known mountain on any planet in the Solar System is Olympus Mons on Mars at 21,171 m (69,459 ft). The tallest mountain including submarine terrain is Mauna Kea in Hawaii from its underwater base at 9,330 m (30,610 ft) and some scientists consider it to be

2277-603: Is a chemical element ; it has symbol Cu (from Latin cuprum ) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity . A freshly exposed surface of pure copper has a pinkish-orange color . Copper is used as a conductor of heat and electricity, as a building material , and as a constituent of various metal alloys , such as sterling silver used in jewelry , cupronickel used to make marine hardware and coins , and constantan used in strain gauges and thermocouples for temperature measurement. Copper

2376-583: Is a constituent of the blood pigment hemocyanin , replaced by the iron-complexed hemoglobin in fish and other vertebrates . In humans, copper is found mainly in the liver, muscle, and bone. The adult body contains between 1.4 and 2.1 mg of copper per kilogram of body weight. In the Roman era , copper was mined principally on Cyprus , the origin of the name of the metal, from aes cyprium (metal of Cyprus), later corrupted to cuprum (Latin). Coper ( Old English ) and copper were derived from this,

2475-405: Is a highly basic anion and is known to stabilize metal ions in high oxidation states. Both copper(III) and even copper(IV) fluorides are known, K 3 CuF 6 and Cs 2 CuF 6 , respectively. Some copper proteins form oxo complexes , which, in extensively studied synthetic analog systems, feature copper(III). With tetrapeptides , purple-colored copper(III) complexes are stabilized by

2574-478: Is a poor conductor of heat, so a parcel of air will rise and fall without exchanging heat. This is known as an adiabatic process , which has a characteristic pressure-temperature dependence. As the pressure gets lower, the temperature decreases. The rate of decrease of temperature with elevation is known as the adiabatic lapse rate , which is approximately 9.8 °C per kilometre (or 5.4 °F (3.0 °C) per 1000 feet) of altitude. The presence of water in

2673-419: Is a set of outdoor activities that involves ascending mountains . Mountaineering-related activities include traditional outdoor climbing , skiing , and traversing via ferratas that have become sports in their own right. Indoor climbing , sport climbing , and bouldering are also considered variants of mountaineering by some, but are part of a wide group of mountain sports . Mountains often play

2772-401: Is because the resistivity to electron transport in metals at room temperature originates primarily from scattering of electrons on thermal vibrations of the lattice, which are relatively weak in a soft metal. The maximum possible current density of copper in open air is approximately 3.1 × 10  A/m , above which it begins to heat excessively. Copper is one of a few metallic elements with

2871-533: Is melted in a furnace and then reduced and cast into billets and ingots ; lower-purity scrap is refined by electroplating in a bath of sulfuric acid . The environmental cost of copper mining was estimated at 3.7 kg CO2eq per kg of copper in 2019. Codelco, a major producer in Chile, reported that in 2020 the company emitted 2.8t CO2eq per ton (2.8 kg CO2eq per kg) of fine copper. Greenhouse gas emissions primarily arise from electricity consumed by

2970-556: Is not enough oxygen to support human life. This is sometimes referred to as the " death zone ". The summits of Mount Everest and K2 are in the death zone. Mountains are generally less preferable for human habitation than lowlands, because of harsh weather and little level ground suitable for agriculture . While 7% of the land area of Earth is above 2,500 metres (8,200 ft), only 140 million people live above that altitude and only 20-30 million people above 3,000 metres (9,800 ft) elevation. About half of mountain dwellers live in

3069-499: Is not found in guidebooks. The fell is climbed as part of Variation 1 on the Coast to Coast Walk . Direct ascents can be made if desired via either of the northern combs. From the shore of Buttermere a path runs up into Birkness Comb from where the northern spur can be gained. From Buttermere village the path to Bleaberry Tarn can be used, branching off to find a line around the eastern end of Chapel Crags. If climbing from Ennerdale

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3168-762: Is one of the few metals that can occur in nature in a directly usable metallic form ( native metals ). This led to very early human use in several regions, from c.  8000 BC . Thousands of years later, it was the first metal to be smelted from sulfide ores, c.  5000 BC ; the first metal to be cast into a shape in a mold, c.  4000 BC ; and the first metal to be purposely alloyed with another metal, tin , to create bronze , c.  3500 BC . Commonly encountered compounds are copper(II) salts, which often impart blue or green colors to such minerals as azurite , malachite , and turquoise , and have been used widely and historically as pigments. Copper used in buildings, usually for roofing, oxidizes to form

3267-444: Is one of the most important constituents of silver and karat gold solders used in the jewelry industry, modifying the color, hardness and melting point of the resulting alloys. Some lead-free solders consist of tin alloyed with a small proportion of copper and other metals. The alloy of copper and nickel , called cupronickel , is used in low-denomination coins, often for the outer cladding. The US five-cent coin (currently called

3366-437: Is recovered from mine tailings and heaps. A variety of methods are used including leaching with sulfuric acid, ammonia, ferric chloride. Biological methods are also used. A significant source of copper is from recycling. Recycling is facilitated because copper is usually deployed in its metallic state. In 2001, a typical automobile contained 20–30 kg of copper. Recycling usually begins with some melting process using

3465-457: Is the highest mountain on Earth, at 8,848 metres (29,029 ft). There are at least 100 mountains with heights of over 7,200 metres (23,622 ft) above sea level, all of which are located in central and southern Asia. The highest mountains above sea level are generally not the highest above the surrounding terrain. There is no precise definition of surrounding base, but Denali , Mount Kilimanjaro and Nanga Parbat are possible candidates for

3564-525: Is the largest mountain on Earth in terms of base area (about 2,000 sq mi or 5,200 km ) and volume (about 18,000 cu mi or 75,000 km ). Mount Kilimanjaro is the largest non-shield volcano in terms of both base area (245 sq mi or 635 km ) and volume (1,150 cu mi or 4,793 km ). Mount Logan is the largest non-volcanic mountain in base area (120 sq mi or 311 km ). The highest mountains above sea level are also not those with peaks farthest from

3663-411: Is used for various objects exposed to seawater, though it is vulnerable to the sulfides sometimes found in polluted harbors and estuaries. Alloys of copper with aluminium (about 7%) have a golden color and are used in decorations. Shakudō is a Japanese decorative alloy of copper containing a low percentage of gold, typically 4–10%, that can be patinated to a dark blue or black color. Copper forms

3762-444: Is well stocked with trout. Bleaberry Tarn is drained into Buttermere by Sourmilk Gill, reaching the lake mere yards from its outlet. A belt of trees has been planted along the shoreline. Birkness Comb, also called Burtness Comb on Ordnance Survey maps, lies between the truncated and unnamed northern ridges of High Crag and High Stile. The lack of a retaining moraine means that this hollow has no tarn, Comb Beck running uninterrupted to

3861-526: The Andes , Central Asia, and Africa. With limited access to infrastructure, only a handful of human communities exist above 4,000 metres (13,000 ft) of elevation. Many are small and have heavily specialized economies, often relying on industries such as agriculture, mining, and tourism. An example of such a specialized town is La Rinconada, Peru , a gold-mining town and the highest elevation human habitation at 5,100 metres (16,700 ft). A counterexample

3960-649: The Basin and Range Province of Western North America. These areas often occur when the regional stress is extensional and the crust is thinned. During and following uplift, mountains are subjected to the agents of erosion (water, wind, ice, and gravity) which gradually wear the uplifted area down. Erosion causes the surface of mountains to be younger than the rocks that form the mountains themselves. Glacial processes produce characteristic landforms, such as pyramidal peaks , knife-edge arêtes , and bowl-shaped cirques that can contain lakes. Plateau mountains, such as

4059-686: The British Geological Survey , in 2005, Chile was the top producer of copper with at least one-third of the world share followed by the United States, Indonesia and Peru. Copper can also be recovered through the in-situ leach process. Several sites in the state of Arizona are considered prime candidates for this method. The amount of copper in use is increasing and the quantity available is barely sufficient to allow all countries to reach developed world levels of usage. An alternative source of copper for collection currently being researched are polymetallic nodules , which are located at

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4158-468: The Catskills , are formed from the erosion of an uplifted plateau. Climate in the mountains becomes colder at high elevations , due to an interaction between radiation and convection. Sunlight in the visible spectrum hits the ground and heats it. The ground then heats the air at the surface. If radiation were the only way to transfer heat from the ground to space, the greenhouse effect of gases in

4257-607: The Great Lakes may have also been mining copper during this time, making it one of the oldest known examples of copper extraction in the world. There is evidence from prehistoric lead pollution from lakes in Michigan that people in the region began mining copper c.  6000 BC . Evidence suggests that utilitarian copper objects fell increasingly out of use in the Old Copper Complex of North America during

4356-553: The International Resource Panel 's Metal Stocks in Society report , the global per capita stock of copper in use in society is 35–55 kg. Much of this is in more-developed countries (140–300 kg per capita) rather than less-developed countries (30–40 kg per capita). The process of recycling copper is roughly the same as is used to extract copper but requires fewer steps. High-purity scrap copper

4455-489: The Loweswater Fells . All three Buttermere Fells throw out a short spur towards the lake with deep combs hollowed out between them. North west of High Stile is Bleaberry Comb, backed by the wall of Chapel Crags. Nestled deep within is Bleaberry Tarn, a pool which is on continual shadow from November to March. Despite the steep contours of the rock walls above, the tarn is only about 15 ft (4.6 m) deep, and

4554-726: The Neolithic period and the Bronze Age was formerly termed the Chalcolithic period (copper-stone), when copper tools were used with stone tools. The term has gradually fallen out of favor because in some parts of the world, the Chalcolithic and Neolithic are coterminous at both ends. Brass, an alloy of copper and zinc, is of much more recent origin. It was known to the Greeks, but became a significant supplement to bronze during

4653-525: The Vinča culture date to 4500 BC. Sumerian and Egyptian artifacts of copper and bronze alloys date to 3000 BC. Egyptian Blue , or cuprorivaite (calcium copper silicate) is a synthetic pigment that contains copper and started being used in ancient Egypt around 3250 BC. The manufacturing process of Egyptian blue was known to the Romans, but by the fourth century AD the pigment fell out of use and

4752-621: The 952 metres (3,123 ft) Mount Brandon by Irish Catholics . The Himalayan peak of Nanda Devi is associated with the Hindu goddesses Nanda and Sunanda; it has been off-limits to climbers since 1983. Mount Ararat is a sacred mountain, as it is believed to be the landing place of Noah's Ark . In Europe and especially in the Alps , summit crosses are often erected on the tops of prominent mountains. Heights of mountains are typically measured above sea level . Using this metric, Mount Everest

4851-548: The 9th or 10th century AD. Carbon dating has established mining at Alderley Edge in Cheshire , UK, at 2280 to 1890 BC. Ötzi the Iceman , a male dated from 3300 to 3200 BC, was found with an axe with a copper head 99.7% pure; high levels of arsenic in his hair suggest an involvement in copper smelting. Experience with copper has assisted the development of other metals; in particular, copper smelting likely led to

4950-517: The Bronze Age and a shift towards an increased production of ornamental copper objects occurred. Natural bronze, a type of copper made from ores rich in silicon, arsenic, and (rarely) tin, came into general use in the Balkans around 5500 BC. Alloying copper with tin to make bronze was first practiced about 4000 years after the discovery of copper smelting, and about 2000 years after "natural bronze" had come into general use. Bronze artifacts from

5049-472: The Buttermere Formation. In the direction of Red Pike are intrusions of the granophyric granite . In Burtness Comb, a prominent bank of debris runs along the outer flank of the upper cirque, then turns down into the lower cirque, ending in a block strew at the intake wall. It marks the course of a rock avalanche which fell from Grey Crag on the summit rim of High Stile, and was channeled along

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5148-537: The Ennerdale Forest, all contributing to the difficulty of access. There are no paths on the southern flank of High Stile. The summit area is formed of the siltstone , sandstone , conglomerate, tuff , lapilli -tuff and andesite sills of the Eagle Crag Member. The northern slopes display the underlying olistostrome of disrupted, sheared and folded mudstone , siltstone and sandstone of

5247-451: The Lake. Grey Crag and Eagle Crag are the main faces on High Stile. These corries being scooped out of the northern face result in the connecting ridges between the three Buttermere Fells being fine and narrow. The Ennerdale flanks have a tier of crag at around 2,000 ft (610 m), The Knors and Raven Crag being the principal features. At the foot of the slopes are the massed conifers of

5346-541: The Middle East; a copper pendant was found in northern Iraq that dates to 8700 BC. Evidence suggests that gold and meteoric iron (but not smelted iron) were the only metals used by humans before copper. The history of copper metallurgy is thought to follow this sequence: first, cold working of native copper, then annealing , smelting , and, finally, lost-wax casting . In southeastern Anatolia , all four of these techniques appear more or less simultaneously at

5445-455: The US. Fold mountains occur when two plates collide: shortening occurs along thrust faults and the crust is overthickened. Since the less dense continental crust "floats" on the denser mantle rocks beneath, the weight of any crustal material forced upward to form hills, plateaus or mountains must be balanced by the buoyancy force of a much greater volume forced downward into the mantle. Thus

5544-622: The action of weathering , through slumping and other forms of mass wasting , as well as through erosion by rivers and glaciers . High elevations on mountains produce colder climates than at sea level at similar latitude. These colder climates strongly affect the ecosystems of mountains: different elevations have different plants and animals. Because of the less hospitable terrain and climate, mountains tend to be used less for agriculture and more for resource extraction, such as mining and logging , along with recreation, such as mountain climbing and skiing . The highest mountain on Earth

5643-581: The adjacent elevation, is impressive or notable." Whether a landform is called a mountain may depend on local usage. John Whittow's Dictionary of Physical Geography states "Some authorities regard eminences above 600 metres (1,969 ft) as mountains, those below being referred to as hills." In the United Kingdom and the Republic of Ireland, a mountain is usually defined as any summit at least 2,000 feet (610 m) high, which accords with

5742-521: The affected areas is highly acidic, with a pH range of 2.1–4.9, and shows elevated electrical conductivity levels between 280 and 1561 mS/cm. These changes in water chemistry make the environment inhospitable for fish, essentially rendering the water uninhabitable for aquatic life. Numerous copper alloys have been formulated, many with important uses. Brass is an alloy of copper and zinc . Bronze usually refers to copper- tin alloys, but can refer to any alloy of copper such as aluminium bronze . Copper

5841-553: The atmosphere complicates the process of convection. Water vapor contains latent heat of vaporization . As air rises and cools, it eventually becomes saturated and cannot hold its quantity of water vapor. The water vapor condenses to form clouds and releases heat, which changes the lapse rate from the dry adiabatic lapse rate to the moist adiabatic lapse rate (5.5 °C per kilometre or 3 °F (1.7 °C) per 1000 feet) The actual lapse rate can vary by altitude and by location. Therefore, moving up 100 m (330 ft) on

5940-429: The atmosphere would keep the ground at roughly 333 K (60 °C; 140 °F), and the temperature would decay exponentially with height. However, when air is hot, it tends to expand, which lowers its density. Thus, hot air tends to rise and transfer heat upward. This is the process of convection . Convection comes to equilibrium when a parcel of air at a given altitude has the same density as its surroundings. Air

6039-541: The atmosphere; 150 mg/kg in soil; 30 mg/kg in vegetation; 2 μg/L in freshwater and 0.5 μg/L in seawater. Most copper is mined or extracted as copper sulfides from large open pit mines in porphyry copper deposits that contain 0.4 to 1.0% copper. Sites include Chuquicamata , in Chile, Bingham Canyon Mine , in Utah, United States, and El Chino Mine , in New Mexico, United States. According to

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6138-766: The beginning of the Neolithic c.  7500 BC . Copper smelting was independently invented in different places. The earliest evidence of lost-wax casting copper comes from an amulet found in Mehrgarh , Pakistan, and is dated to 4000 BC. Investment casting was invented in 4500–4000 BC in Southeast Asia Smelting was probably discovered in China before 2800 BC, in Central America around 600 AD, and in West Africa about

6237-422: The brink can also add Bleaberry Tarn to the picture. Fine views of the crags of the surrounding combs complete the foreground. The fell is usually ascended as a traverse of the ‘Buttermere Three’, as the north eastern flank is very steep and rough. Strong walkers may continue the walk towards Haystacks , four miles (six kilometres) southeast. The direct ascent from Ennerdale (through forest and steep bracken )

6336-513: The centre of the Earth, because the figure of the Earth is not spherical. Sea level closer to the equator is several miles farther from the centre of the Earth. The summit of Chimborazo , Ecuador's tallest mountain, is usually considered to be the farthest point from the Earth's centre, although the southern summit of Peru's tallest mountain, Huascarán , is another contender. Both have elevations above sea level more than 2 kilometres (6,600 ft) less than that of Everest. Copper Copper

6435-459: The climate on the ecology at an elevation can be largely captured through a combination of amount of precipitation, and the biotemperature , as described by Leslie Holdridge in 1947. Biotemperature is the mean temperature; all temperatures below 0 °C (32 °F) are considered to be 0 °C. When the temperature is below 0 °C, plants are dormant, so the exact temperature is unimportant. The peaks of mountains with permanent snow can have

6534-446: The coastal plain of Cumberland. At the central hub of the high country are Great Gable and its satellites, while two principal ridges fan out on either flank of Ennerdale , the western fells in effect being a great horseshoe around this long wild valley. The highest section of the northern branch is formed by the trio of Buttermere fells, High Crag , High Stile and Red Pike . The Buttermere Fells, also known as Buttermere Edge, form

6633-531: The company, especially when sourced from fossil fuels, and from engines required for copper extraction and refinement. Companies that mine land often mismanage waste, rendering the area sterile for life. Additionally, nearby rivers and forests are also negatively impacted. The Philippines is an example of a region where land is overexploited by mining companies. Copper mining waste in Valea Şesei, Romania, has significantly altered nearby water properties. The water in

6732-534: The conditions above and below a particular zone will be inhospitable and thus constrain their movements or dispersal . These isolated ecological systems are known as sky islands . Altitudinal zones tend to follow a typical pattern. At the highest elevations, trees cannot grow, and whatever life may be present will be of the alpine type, resembling tundra . Just below the tree line , one may find subalpine forests of needleleaf trees, which can withstand cold, dry conditions. Below that, montane forests grow. In

6831-476: The continental crust is normally much thicker under mountains, compared to lower lying areas. Rock can fold either symmetrically or asymmetrically. The upfolds are anticlines and the downfolds are synclines : in asymmetric folding there may also be recumbent and overturned folds. The Balkan Mountains and the Jura Mountains are examples of fold mountains. Block mountains are caused by faults in

6930-513: The crust: a plane where rocks have moved past each other. When rocks on one side of a fault rise relative to the other, it can form a mountain. The uplifted blocks are block mountains or horsts . The intervening dropped blocks are termed graben : these can be small or form extensive rift valley systems. This kind of landscape can be seen in East Africa , the Vosges and Rhine valley, and

7029-548: The definition since the 1970s. Any similar landform lower than this height was considered a hill. However, today, the United States Geological Survey concludes that these terms do not have technical definitions in the US. The UN Environmental Programme 's definition of "mountainous environment" includes any of the following: Using these definitions, mountains cover 33% of Eurasia, 19% of South America, 24% of North America, and 14% of Africa. As

7128-522: The deprotonated amide ligands. Complexes of copper(III) are also found as intermediates in reactions of organocopper compounds, for example in the Kharasch–Sosnovsky reaction . A timeline of copper illustrates how this metal has advanced human civilization for the past 11,000 years. Copper occurs naturally as native metallic copper and was known to some of the oldest civilizations on record. The history of copper use dates to 9000 BC in

7227-461: The depths of the Pacific Ocean approximately 3000–6500 meters below sea level. These nodules contain other valuable metals such as cobalt and nickel . Copper has been in use for at least 10,000 years, but more than 95% of all copper ever mined and smelted has been extracted since 1900. As with many natural resources, the total amount of copper on Earth is vast, with around 10 tons in

7326-563: The discovery of iron smelting . Production in the Old Copper Complex in Michigan and Wisconsin is dated between 6500 and 3000 BC. A copper spearpoint found in Wisconsin has been dated to 6500 BC. Copper usage by the indigenous peoples of the Old Copper Complex from the Great Lakes region of North America has been radiometrically dated to as far back as 7500 BC. Indigenous peoples of North America around

7425-460: The dry season and in semiarid areas such as in central Asia. Alpine ecosystems can be particularly climatically sensitive. Many mid-latitude mountains act as cold climate refugia, with the ecosystems occupying small environmental niches. As well as the direct influence that the change in climate can have on an ecosystem, there is also the indirect one on the soils from changes in stability and soil development. The colder climate on mountains affects

7524-523: The economies of mountain communities, with developments focused around attractions such as national parks and ski resorts . Approximately 80% of mountain people live below the poverty line. Most of the world's rivers are fed from mountain sources, with snow acting as a storage mechanism for downstream users. More than half of humanity depends on mountains for water. In geopolitics , mountains are often seen as natural boundaries between polities. Mountaineering , mountain climbing, or alpinism

7623-428: The effect disappears. Precipitation in highland areas is not increasing as quickly as in lowland areas. Climate modeling give mixed signals about whether a particular highland area will have increased or decreased precipitation. Climate change has started to affect the physical and ecological systems of mountains. In recent decades mountain ice caps and glaciers have experienced accelerating ice loss. The melting of

7722-545: The fastest water exchange rate (speed of water ligands attaching and detaching) for any transition metal aquo complex . Adding aqueous sodium hydroxide causes the precipitation of light blue solid copper(II) hydroxide . A simplified equation is: Aqueous ammonia results in the same precipitate. Upon adding excess ammonia, the precipitate dissolves, forming tetraamminecopper(II) : Many other oxyanions form complexes; these include copper(II) acetate , copper(II) nitrate , and copper(II) carbonate . Copper(II) sulfate forms

7821-433: The feature makes it either a hill or, if higher and steeper, a mountain. Major mountains tend to occur in long linear arcs, indicating tectonic plate boundaries and activity. Volcanoes are formed when a plate is pushed below another plate , or at a mid-ocean ridge or hotspot . At a depth of around 100 km (60 mi), melting occurs in rock above the slab (due to the addition of water), and forms magma that reaches

7920-407: The foot of the glacier some 11,000 years ago. It is unique in the Lake District. There are the remains of a small copper -mine near the shore of Buttermere. This was worked from 1569 to 1570 and again in the 1820s. The highest point lies a little way out onto the northern spur at the top of Grey Crag, marked by a cairn . The highest point on the main ridge is only three feet (0.9 m) lower and

8019-498: The glaciers, permafrost and snow has caused underlying surfaces to become increasingly unstable. Landslip hazards have increased in both number and magnitude due to climate change. Patterns of river discharge will also be significantly affected by climate change, which in turn will have significant impacts on communities that rely on water fed from alpine sources. Nearly half of mountain areas provide essential or supportive water resources for mainly urban populations, in particular during

8118-511: The later spelling first used around 1530. Copper, silver , and gold are in group 11 of the periodic table; these three metals have one s-orbital electron on top of a filled d- electron shell and are characterized by high ductility , and electrical and thermal conductivity. The filled d-shells in these elements contribute little to interatomic interactions, which are dominated by the s-electrons through metallic bonds . Unlike metals with incomplete d-shells, metallic bonds in copper are lacking

8217-419: The level of <1% Cu. Concentration of the ore is required, which begins with comminution followed by froth flotation . The remaining concentrate is the smelted, which can be described with two simplified equations: Cuprous oxide reacts with cuprous sulfide to convert to blister copper upon heating This roasting gives matte copper, roughly 50% Cu by weight, which is purified by electrolysis. Depending on

8316-472: The modern world. The price of copper is volatile . After a peak in 2022 the price unexpectedly fell. The global market for copper is one of the most commodified and financialized of the commodity markets , and has been so for decades. The great majority of copper ores are sulfides. Common ores are the sulfides chalcopyrite (CuFeS 2 ), bornite (Cu 5 FeS 4 ) and, to a lesser extent, covellite (CuS) and chalcocite (Cu 2 S). These ores occur at

8415-516: The numerous copper sulfides , important examples include copper(I) sulfide ( Cu 2 S ) and copper monosulfide ( CuS ). Cuprous halides with fluorine , chlorine , bromine , and iodine are known, as are cupric halides with fluorine , chlorine , and bromine . Attempts to prepare copper(II) iodide yield only copper(I) iodide and iodine. Copper forms coordination complexes with ligands . In aqueous solution, copper(II) exists as [Cu(H 2 O) 6 ] . This complex exhibits

8514-520: The official UK government's definition that a mountain, for the purposes of access, is a summit of 2,000 feet (610 m) or higher. In addition, some definitions also include a topographical prominence requirement, such as that the mountain rises 300 metres (984 ft) above the surrounding terrain. At one time, the United States Board on Geographic Names defined a mountain as being 1,000 feet (305 m) or taller, but has abandoned

8613-428: The ore, sometimes other metals are obtained during the electrolysis including platinum and gold. Aside from sulfides, another family of ores are oxides. Approximately 15% of the world's copper supply derives from these oxides. The beneficiation process for oxides involves extraction with sulfuric acid solutions followed by electrolysis. In parallel with the above method for "concentrated" sulfide and oxide ores, copper

8712-527: The plants and animals residing on mountains. A particular set of plants and animals tend to be adapted to a relatively narrow range of climate. Thus, ecosystems tend to lie along elevation bands of roughly constant climate. This is called altitudinal zonation . In regions with dry climates, the tendency of mountains to have higher precipitation as well as lower temperatures also provides for varying conditions, which enhances zonation. Some plants and animals found in altitudinal zones tend to become isolated since

8811-743: The route up Red Pike may be used. Mountain A mountain is an elevated portion of the Earth's crust , generally with steep sides that show significant exposed bedrock . Although definitions vary, a mountain may differ from a plateau in having a limited summit area, and is usually higher than a hill , typically rising at least 300 metres (980  ft ) above the surrounding land. A few mountains are isolated summits , but most occur in mountain ranges . Mountains are formed through tectonic forces , erosion , or volcanism , which act on time scales of up to tens of millions of years. Once mountain building ceases, mountains are slowly leveled through

8910-750: The secret to its manufacturing process became lost. The Romans said the blue pigment was made from copper, silica, lime and natron and was known to them as caeruleum . The Bronze Age began in Southeastern Europe around 3700–3300 BC, in Northwestern Europe about 2500 BC. It ended with the beginning of the Iron Age, 2000–1000 BC in the Near East, and 600 BC in Northern Europe. The transition between

9009-438: The sugar is signaled by a color change from blue Cu(II) to reddish copper(I) oxide. Schweizer's reagent and related complexes with ethylenediamine and other amines dissolve cellulose . Amino acids such as cystine form very stable chelate complexes with copper(II) including in the form of metal-organic biohybrids (MOBs). Many wet-chemical tests for copper ions exist, one involving potassium ferricyanide , which gives

9108-514: The surface. When the magma reaches the surface, it often builds a volcanic mountain, such as a shield volcano or a stratovolcano . Examples of volcanoes include Mount Fuji in Japan and Mount Pinatubo in the Philippines. The magma does not have to reach the surface in order to create a mountain: magma that solidifies below ground can still form dome mountains , such as Navajo Mountain in

9207-415: The tallest mountain on land by this measure. The bases of mountain islands are below sea level, and given this consideration Mauna Kea (4,207 m (13,802 ft) above sea level) is the world's tallest mountain and volcano, rising about 10,203 m (33,474 ft) from the Pacific Ocean floor. The highest mountains are not generally the most voluminous. Mauna Loa (4,169 m or 13,678 ft)

9306-481: The tallest on earth. There is no universally accepted definition of a mountain. Elevation, volume, relief, steepness, spacing and continuity have been used as criteria for defining a mountain. In the Oxford English Dictionary a mountain is defined as "a natural elevation of the earth surface rising more or less abruptly from the surrounding level and attaining an altitude which, relatively to

9405-473: The temperate portions of the earth, those forests tend to be needleleaf trees, while in the tropics, they can be broadleaf trees growing in a rainforest . The highest known permanently tolerable altitude is at 5,950 metres (19,520 ft). At very high altitudes, the decreasing atmospheric pressure means that less oxygen is available for breathing, and there is less protection against solar radiation ( UV ). Above 8,000 metres (26,000 ft) elevation, there

9504-399: The top kilometer of Earth's crust, which is about 5 million years' worth at the current rate of extraction. However, only a tiny fraction of these reserves is economically viable with present-day prices and technologies. Estimates of copper reserves available for mining vary from 25 to 60 years, depending on core assumptions such as the growth rate. Recycling is a major source of copper in

9603-490: The watershed between Buttermere and Upper Ennerdale . The Ennerdale flanks are steep and rough with areas of crag, the lower slopes being planted with a ribbon of conifers. Across the narrow ridge-top to the north are deep corries and dark walls of crag, glowering down over the lake. The ridge continues south east to Haystacks and the Great Gable group. Beyond Red Pike to the west are Starling Dodd , Great Borne and

9702-476: Was found in 1857 on the Keweenaw Peninsula in Michigan, US. Native copper is a polycrystal , with the largest single crystal ever described measuring 4.4 × 3.2 × 3.2 cm . Copper is the 26th most abundant element in Earth's crust , representing 50 ppm compared with 75 ppm for zinc , and 14 ppm for lead . Typical background concentrations of copper do not exceed 1 ng/m in

9801-584: Was regarded as the summit by Alfred Wainwright , the maps available at the time not deciding the issue. This top has two main cairns side by side. In an attempt to avoid confusion some guidebooks refer to the summit as Grey Crag and the top on the ridge as High Stile. The view is extensive, the highlight perhaps being the North Western Fells across the Buttermere valley. Ennerdale Water and Crummock Water are in view and careful steps toward

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