74-519: Lava is molten volcanic rock or the resulting solid rock after cooling. Lava or LAVA also refer to: Lava Lava is molten or partially molten rock ( magma ) that has been expelled from the interior of a terrestrial planet (such as Earth ) or a moon onto its surface. Lava may be erupted at a volcano or through a fracture in the crust , on land or underwater, usually at temperatures from 800 to 1,200 °C (1,470 to 2,190 °F). The volcanic rock resulting from subsequent cooling
148-419: A continued supply of lava and its pressure on a solidified crust. Most basaltic lavas are of ʻaʻā or pāhoehoe types, rather than block lavas. Underwater, they can form pillow lavas , which are rather similar to entrail-type pahoehoe lavas on land. Ultramafic lavas, such as komatiite and highly magnesian magmas that form boninite , take the composition and temperatures of eruptions to the extreme. All have
222-455: A darker groundmass , including amphibole or pyroxene phenocrysts. Mafic or basaltic lavas are typified by relatively high magnesium oxide and iron oxide content (whose molecular formulas provide the consonants in mafic) and have a silica content limited to a range of 52% to 45%. They generally erupt at temperatures of 1,100 to 1,200 °C (2,010 to 2,190 °F) and at relatively low viscosities, around 10 to 10 cP (10 to 100 Pa⋅s). This
296-420: A dome forms on an inclined surface it can flow in short thick flows called coulées (dome flows). These flows often travel only a few kilometres from the vent. Lava tubes are formed when a flow of relatively fluid lava cools on the upper surface sufficiently to form a crust. Beneath this crust, which being made of rock is an excellent insulator, the lava can continue to flow as a liquid. When this flow occurs over
370-407: A glass with no true melting point, can be used as a glass fibre for fibreglass. Silicon dioxide is mostly obtained by mining, including sand mining and purification of quartz . Quartz is suitable for many purposes, while chemical processing is required to make a purer or otherwise more suitable (e.g. more reactive or fine-grained) product. Precipitated silica or amorphous silica is produced by
444-494: A heat capacity minimum. Its density decreases from 2.08 g/cm at 1950 °C to 2.03 g/cm at 2200 °C. The molecular SiO 2 has a linear structure like CO 2 . It has been produced by combining silicon monoxide (SiO) with oxygen in an argon matrix. The dimeric silicon dioxide, (SiO 2 ) 2 has been obtained by reacting O 2 with matrix isolated dimeric silicon monoxide, (Si 2 O 2 ). In dimeric silicon dioxide there are two oxygen atoms bridging between
518-450: A low value of 140° in α-tridymite, up to 180° in β-tridymite. In α-quartz, the Si–O–Si angle is 144°. Alpha quartz is the most stable form of solid SiO 2 at room temperature. The high-temperature minerals, cristobalite and tridymite, have both lower densities and indices of refraction than quartz. The transformation from α-quartz to beta-quartz takes place abruptly at 573 °C. Since
592-465: A massive dense core, which is the most active part of the flow. As pasty lava in the core travels downslope, the clinkers are carried along at the surface. At the leading edge of an ʻaʻā flow, however, these cooled fragments tumble down the steep front and are buried by the advancing flow. This produces a layer of lava fragments both at the bottom and top of an ʻaʻā flow. Accretionary lava balls as large as 3 metres (10 feet) are common on ʻaʻā flows. ʻAʻā
666-616: A prolonged period of time the lava conduit can form a tunnel-like aperture or lava tube , which can conduct molten rock many kilometres from the vent without cooling appreciably. Often these lava tubes drain out once the supply of fresh lava has stopped, leaving a considerable length of open tunnel within the lava flow. Lava tubes are known from the modern day eruptions of Kīlauea, and significant, extensive and open lava tubes of Tertiary age are known from North Queensland , Australia , some extending for 15 kilometres (9 miles). Silicon dioxide Silicon dioxide , also known as silica ,
740-960: A silica content greater than 63%. They include rhyolite and dacite lavas. With such a high silica content, these lavas are extremely viscous, ranging from 10 cP (10 Pa⋅s) for hot rhyolite lava at 1,200 °C (2,190 °F) to 10 cP (10 Pa⋅s) for cool rhyolite lava at 800 °C (1,470 °F). For comparison, water has a viscosity of about 1 cP (0.001 Pa⋅s). Because of this very high viscosity, felsic lavas usually erupt explosively to produce pyroclastic (fragmental) deposits. However, rhyolite lavas occasionally erupt effusively to form lava spines , lava domes or "coulees" (which are thick, short lava flows). The lavas typically fragment as they extrude, producing block lava flows. These often contain obsidian . Felsic magmas can erupt at temperatures as low as 800 °C (1,470 °F). Unusually hot (>950 °C; >1,740 °F) rhyolite lavas, however, may flow for distances of many tens of kilometres, such as in
814-450: A silica content under 45%. Komatiites contain over 18% magnesium oxide and are thought to have erupted at temperatures of 1,600 °C (2,910 °F). At this temperature there is practically no polymerization of the mineral compounds, creating a highly mobile liquid. Viscosities of komatiite magmas are thought to have been as low as 100 to 1000 cP (0.1 to 1 Pa⋅s), similar to that of light motor oil. Most ultramafic lavas are no younger than
SECTION 10
#1732766190296888-410: A silicon wafer enables it to overcome the surface states that otherwise prevent electricity from reaching the semiconducting layer. The process of silicon surface passivation by thermal oxidation (silicon dioxide) is critical to the semiconductor industry . It is commonly used to manufacture metal–oxide–semiconductor field-effect transistors (MOSFETs) and silicon integrated circuit chips (with
962-441: A similar manner to ʻaʻā flows but their more viscous nature causes the surface to be covered in smooth-sided angular fragments (blocks) of solidified lava instead of clinkers. As with ʻaʻā flows, the molten interior of the flow, which is kept insulated by the solidified blocky surface, advances over the rubble that falls off the flow front. They also move much more slowly downhill and are thicker in depth than ʻaʻā flows. Pillow lava
1036-530: A solid crust that insulates the remaining liquid lava, helping to keep it hot and inviscid enough to continue flowing. The word lava comes from Italian and is probably derived from the Latin word labes , which means a fall or slide. An early use of the word in connection with extrusion of magma from below the surface is found in a short account of the 1737 eruption of Vesuvius , written by Francesco Serao , who described "a flow of fiery lava" as an analogy to
1110-575: A temperature of 1,100 to 1,200 °C (2,010 to 2,190 °F). On the Earth, most lava flows are less than 10 km (6.2 mi) long, but some pāhoehoe flows are more than 50 km (31 mi) long. Some flood basalt flows in the geologic record extend for hundreds of kilometres. The rounded texture makes pāhoehoe a poor radar reflector, and is difficult to see from an orbiting satellite (dark on Magellan picture). Block lava flows are typical of andesitic lavas from stratovolcanoes. They behave in
1184-477: A very shallow layer of about 1 nm or 10 Å of so-called native oxide. Higher temperatures and alternative environments are used to grow well-controlled layers of silicon dioxide on silicon, for example at temperatures between 600 and 1200 °C, using so-called dry oxidation with O 2 or wet oxidation with H 2 O. The native oxide layer is beneficial in microelectronics , where it acts as electric insulator with high chemical stability. It can protect
1258-501: A volcano extrudes silicic lava, it can form an inflation dome or endogenous dome , gradually building up a large, pillow-like structure which cracks, fissures, and may release cooled chunks of rock and rubble. The top and side margins of an inflating lava dome tend to be covered in fragments of rock, breccia and ash. Examples of lava dome eruptions include the Novarupta dome, and successive lava domes of Mount St Helens . When
1332-524: A white powder with extremely low bulk density (0.03-0.15 g/cm ) and thus high surface area. The particles act as a thixotropic thickening agent, or as an anti-caking agent, and can be treated to make them hydrophilic or hydrophobic for either water or organic liquid applications. Silica fume is an ultrafine powder collected as a by-product of the silicon and ferrosilicon alloy production. It consists of amorphous (non-crystalline) spherical particles with an average particle diameter of 150 nm, without
1406-402: Is a large subsidence crater, can form in a stratovolcano, if the magma chamber is partially or wholly emptied by large explosive eruptions; the summit cone no longer supports itself and thus collapses in on itself afterwards. Such features may include volcanic crater lakes and lava domes after the event. However, calderas can also form by non-explosive means such as gradual magma subsidence. This
1480-456: Is also often called lava . A lava flow is an outpouring of lava during an effusive eruption . (An explosive eruption , by contrast, produces a mixture of volcanic ash and other fragments called tephra , not lava flows.) The viscosity of most lava is about that of ketchup , roughly 10,000 to 100,000 times that of water. Even so, lava can flow great distances before cooling causes it to solidify, because lava exposed to air quickly develops
1554-439: Is also the primary component of rice husk ash , which is used, for example, in filtration and as supplementary cementitious material (SCM) in cement and concrete manufacturing. Silicification in and by cells has been common in the biological world and it occurs in bacteria, protists, plants, and animals (invertebrates and vertebrates). Prominent examples include: About 95% of the commercial use of silicon dioxide (sand)
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#17327661902961628-399: Is an oxide of silicon with the chemical formula SiO 2 , commonly found in nature as quartz . In many parts of the world, silica is the major constituent of sand . Silica is one of the most complex and abundant families of materials , existing as a compound of several minerals and as a synthetic product. Examples include fused quartz , fumed silica , opal , and aerogels . It
1702-415: Is basaltic lava that has a smooth, billowy, undulating, or ropy surface. These surface features are due to the movement of very fluid lava under a congealing surface crust. The Hawaiian word was introduced as a technical term in geology by Clarence Dutton . A pāhoehoe flow typically advances as a series of small lobes and toes that continually break out from a cooled crust. It also forms lava tubes where
1776-719: Is concentrated in a thin layer in the toothpaste next to the tube and only there does the toothpaste behave as a fluid. Thixotropic behavior also hinders crystals from settling out of the lava. Once the crystal content reaches about 60%, the lava ceases to behave like a fluid and begins to behave like a solid. Such a mixture of crystals with melted rock is sometimes described as crystal mush . Lava flow speeds vary based primarily on viscosity and slope. In general, lava flows slowly, with typical speeds for Hawaiian basaltic flows of 0.40 km/h (0.25 mph) and maximum speeds of 10 to 48 km/h (6 to 30 mph) on steep slopes. An exceptional speed of 32 to 97 km/h (20 to 60 mph)
1850-604: Is covalently bonded in a tetrahedral manner to 4 oxygen atoms. In contrast, CO 2 is a linear molecule. The starkly different structures of the dioxides of carbon and silicon are a manifestation of the double bond rule . Based on the crystal structural differences, silicon dioxide can be divided into two categories: crystalline and non-crystalline (amorphous). In crystalline form, this substance can be found naturally occurring as quartz , tridymite (high-temperature form), cristobalite (high-temperature form), stishovite (high-pressure form), and coesite (high-pressure form). On
1924-465: Is in the construction industry, e.g. in the production of concrete ( Portland cement concrete ). Certain deposits of silica sand, with desirable particle size and shape and desirable clay and other mineral content, were important for sand casting of metallic products. The high melting point of silica enables it to be used in such applications such as iron casting; modern sand casting sometimes uses other minerals for other reasons. Crystalline silica
1998-546: Is mostly determined by composition but also depends on temperature and shear rate. Lava viscosity determines the kind of volcanic activity that takes place when the lava is erupted. The greater the viscosity, the greater the tendency for eruptions to be explosive rather than effusive. As a result, most lava flows on Earth, Mars, and Venus are composed of basalt lava. On Earth, 90% of lava flows are mafic or ultramafic, with intermediate lava making up 8% of flows and felsic lava making up just 2% of flows. Viscosity also determines
2072-651: Is obtained by the dealumination of a low-sodium, ultra-stable Y zeolite with combined acid and thermal treatment. The resulting product contains over 99% silica, and has high crystallinity and specific surface area (over 800 m /g). Faujasite-silica has very high thermal and acid stability. For example, it maintains a high degree of long-range molecular order or crystallinity even after boiling in concentrated hydrochloric acid . Molten silica exhibits several peculiar physical characteristics that are similar to those observed in liquid water : negative temperature expansion, density maximum at temperatures ~5000 °C, and
2146-444: Is one of three basic types of flow lava. ʻAʻā is basaltic lava characterized by a rough or rubbly surface composed of broken lava blocks called clinker. The word is Hawaiian meaning "stony rough lava", but also to "burn" or "blaze"; it was introduced as a technical term in geology by Clarence Dutton . The loose, broken, and sharp, spiny surface of an ʻaʻā flow makes hiking difficult and slow. The clinkery surface actually covers
2220-421: Is rapidly cooled, it does not crystallize, but solidifies as a glass. Because of this, most ceramic glazes have silica as the main ingredient. The structural geometry of silicon and oxygen in glass is similar to that in quartz and most other crystalline forms of silicon and oxygen, with silicon surrounded by regular tetrahedra of oxygen centres. The difference between the glass and crystalline forms arises from
2294-474: Is similar to the viscosity of ketchup , although it is still many orders of magnitude higher than that of water. Mafic lavas tend to produce low-profile shield volcanoes or flood basalts , because the less viscous lava can flow for long distances from the vent. The thickness of a solidified basaltic lava flow, particularly on a low slope, may be much greater than the thickness of the moving molten lava flow at any one time, because basaltic lavas may "inflate" by
Lava (disambiguation) - Misplaced Pages Continue
2368-454: Is the lava structure typically formed when lava emerges from an underwater volcanic vent or subglacial volcano or a lava flow enters the ocean. The viscous lava gains a solid crust on contact with the water, and this crust cracks and oozes additional large blobs or "pillows" as more lava emerges from the advancing flow. Since water covers the majority of Earth 's surface and most volcanoes are situated near or under bodies of water, pillow lava
2442-426: Is the major constituent of sand . Even though it is poorly soluble, silica occurs in many plants such as rice . Plant materials with high silica phytolith content appear to be of importance to grazing animals, from chewing insects to ungulates . Silica accelerates tooth wear, and high levels of silica in plants frequently eaten by herbivores may have developed as a defense mechanism against predation. Silica
2516-405: Is the only polymorph of silica stable at the Earth's surface. Metastable occurrences of the high-pressure forms coesite and stishovite have been found around impact structures and associated with eclogites formed during ultra-high-pressure metamorphism . The high-temperature forms of tridymite and cristobalite are known from silica-rich volcanic rocks . In many parts of the world, silica
2590-504: Is the process by which a semiconductor surface is rendered inert, and does not change semiconductor properties as a result of interaction with air or other materials in contact with the surface or edge of the crystal. The formation of a thermally grown silicon dioxide layer greatly reduces the concentration of electronic states at the silicon surface . SiO 2 films preserve the electrical characteristics of p–n junctions and prevent these electrical characteristics from deteriorating by
2664-422: Is typical of many shield volcanoes. Cinder cones and spatter cones are small-scale features formed by lava accumulation around a small vent on a volcanic edifice. Cinder cones are formed from tephra or ash and tuff which is thrown from an explosive vent. Spatter cones are formed by accumulation of molten volcanic slag and cinders ejected in a more liquid form. Another Hawaiian English term derived from
2738-436: Is used as a fining agent for wine, beer, and juice, with the E number reference E551 . In cosmetics, silica is useful for its light-diffusing properties and natural absorbency. Diatomaceous earth , a mined product, has been used in food and cosmetics for centuries. It consists of the silica shells of microscopic diatoms ; in a less processed form it was sold as "tooth powder". Manufactured or mined hydrated silica
2812-489: Is used as the hard abrasive in toothpaste . Silicon dioxide is widely used in the semiconductor technology: Because silicon dioxide is a native oxide of silicon it is more widely used compared to other semiconductors like gallium arsenide or indium phosphide . Silicon dioxide could be grown on a silicon semiconductor surface. Silicon oxide layers could protect silicon surfaces during diffusion processes , and could be used for diffusion masking. Surface passivation
2886-418: Is used in hydraulic fracturing of formations which contain tight oil and shale gas . Silica is the primary ingredient in the production of most glass . As other minerals are melted with silica, the principle of freezing point depression lowers the melting point of the mixture and increases fluidity. The glass transition temperature of pure SiO 2 is about 1475 K. When molten silicon dioxide SiO 2
2960-498: Is used in structural materials , microelectronics , and as components in the food and pharmaceutical industries. All forms are white or colorless, although impure samples can be colored. Silicon dioxide is a common fundamental constituent of glass . In the majority of silicon dioxides, the silicon atom shows tetrahedral coordination , with four oxygen atoms surrounding a central Si atom ( see 3-D Unit Cell ). Thus, SiO 2 forms 3-dimensional network solids in which each silicon atom
3034-538: Is used to produce elemental silicon . The process involves carbothermic reduction in an electric arc furnace : Fumed silica , also known as pyrogenic silica, is prepared by burning SiCl 4 in an oxygen-rich hydrogen flame to produce a "smoke" of SiO 2 . It can also be produced by vaporizing quartz sand in a 3000 °C electric arc. Both processes result in microscopic droplets of amorphous silica fused into branched, chainlike, three-dimensional secondary particles which then agglomerate into tertiary particles,
Lava (disambiguation) - Misplaced Pages Continue
3108-516: Is usually of higher viscosity than pāhoehoe. Pāhoehoe can turn into ʻaʻā if it becomes turbulent from meeting impediments or steep slopes. The sharp, angled texture makes ʻaʻā a strong radar reflector, and can easily be seen from an orbiting satellite (bright on Magellan pictures). ʻAʻā lavas typically erupt at temperatures of 1,050 to 1,150 °C (1,920 to 2,100 °F) or greater. Pāhoehoe (also spelled pahoehoe , from Hawaiian [paːˈhoweˈhowe] meaning "smooth, unbroken lava")
3182-646: Is very common. Because it is formed from viscous molten rock, lava flows and eruptions create distinctive formations, landforms and topographical features from the macroscopic to the microscopic. Volcanoes are the primary landforms built by repeated eruptions of lava and ash over time. They range in shape from shield volcanoes with broad, shallow slopes formed from predominantly effusive eruptions of relatively fluid basaltic lava flows, to steeply-sided stratovolcanoes (also known as composite volcanoes) made of alternating layers of ash and more viscous lava flows typical of intermediate and felsic lavas. A caldera , which
3256-494: The Hawaiian language , a kīpuka denotes an elevated area such as a hill, ridge or old lava dome inside or downslope from an area of active volcanism. New lava flows will cover the surrounding land, isolating the kīpuka so that it appears as a (usually) forested island in a barren lava flow. Lava domes are formed by the extrusion of viscous felsic magma. They can form prominent rounded protuberances, such as at Valles Caldera . As
3330-889: The Proterozoic , with a few ultramafic magmas known from the Phanerozoic in Central America that are attributed to a hot mantle plume . No modern komatiite lavas are known, as the Earth's mantle has cooled too much to produce highly magnesian magmas. Some silicate lavas have an elevated content of alkali metal oxides (sodium and potassium), particularly in regions of continental rifting , areas overlying deeply subducted plates , or at intraplate hotspots . Their silica content can range from ultramafic ( nephelinites , basanites and tephrites ) to felsic ( trachytes ). They are more likely to be generated at greater depths in
3404-520: The Snake River Plain of the northwestern United States. Intermediate or andesitic lavas contain 52% to 63% silica, and are lower in aluminium and usually somewhat richer in magnesium and iron than felsic lavas. Intermediate lavas form andesite domes and block lavas and may occur on steep composite volcanoes , such as in the Andes . They are also commonly hotter than felsic lavas, in
3478-418: The most abundant elements of the Earth's crust , with smaller quantities of aluminium , calcium , magnesium , iron , sodium , and potassium and minor amounts of many other elements. Petrologists routinely express the composition of a silicate lava in terms of the weight or molar mass fraction of the oxides of the major elements (other than oxygen) present in the lava. The silica component dominates
3552-555: The planar process ). Hydrophobic silica is used as a defoamer component . In its capacity as a refractory , it is useful in fiber form as a high-temperature thermal protection fabric. Silica is used in the extraction of DNA and RNA due to its ability to bind to the nucleic acids under the presence of chaotropes . Silica aerogel was used in the Stardust spacecraft to collect extraterrestrial particles. Pure silica (silicon dioxide), when cooled as fused quartz into
3626-496: The acidification of solutions of sodium silicate . The gelatinous precipitate or silica gel , is first washed and then dehydrated to produce colorless microporous silica. The idealized equation involving a trisilicate and sulfuric acid is: Approximately one billion kilograms/year (1999) of silica were produced in this manner, mainly for use for polymer composites – tires and shoe soles. Thin films of silica grow spontaneously on silicon wafers via thermal oxidation , producing
3700-989: The aspect (thickness relative to lateral extent) of flows, the speed with which flows move, and the surface character of the flows. When highly viscous lavas erupt effusively rather than in their more common explosive form, they almost always erupt as high-aspect flows or domes. These flows take the form of block lava rather than ʻaʻā or pāhoehoe. Obsidian flows are common. Intermediate lavas tend to form steep stratovolcanoes, with alternating beds of lava from effusive eruptions and tephra from explosive eruptions. Mafic lavas form relatively thin flows that can move great distances, forming shield volcanoes with gentle slopes. In addition to melted rock, most lavas contain solid crystals of various minerals, fragments of exotic rocks known as xenoliths , and fragments of previously solidified lava. The crystal content of most lavas gives them thixotropic and shear thinning properties. In other words, most lavas do not behave like Newtonian fluids, in which
3774-552: The branching of the pyrogenic product. The main use is as pozzolanic material for high performance concrete. Fumed silica nanoparticles can be successfully used as an anti-aging agent in asphalt binders. Silica, either colloidal, precipitated, or pyrogenic fumed, is a common additive in food production. It is used primarily as a flow or anti- caking agent in powdered foods such as spices and non-dairy coffee creamer, or powders to be formed into pharmaceutical tablets. It can adsorb water in hygroscopic applications. Colloidal silica
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#17327661902963848-509: The connectivity of the tetrahedral units: Although there is no long-range periodicity in the glassy network, ordering remains at length scales well beyond the SiO bond length. One example of this ordering is the preference to form rings of 6-tetrahedra. The majority of optical fibers for telecommunications are also made from silica. It is a primary raw material for many ceramics such as earthenware , stoneware , and porcelain . Silicon dioxide
3922-488: The densest of the low-pressure forms, which has a density of 2.648 g/cm . The difference in density can be ascribed to the increase in coordination as the six shortest Si–O bond lengths in stishovite (four Si–O bond lengths of 176 pm and two others of 181 pm) are greater than the Si–O bond length (161 pm) in α-quartz. The change in the coordination increases the ionicity of the Si–O bond. Faujasite silica, another polymorph,
3996-418: The eruption. A cooling lava flow shrinks, and this fractures the flow. Basalt flows show a characteristic pattern of fractures. The uppermost parts of the flow show irregular downward-splaying fractures, while the lower part of the flow shows a very regular pattern of fractures that break the flow into five- or six-sided columns. The irregular upper part of the solidified flow is called the entablature , while
4070-654: The flood basalts of South America formed in this manner. Flood basalts typically crystallize little before they cease flowing, and, as a result, flow textures are uncommon in less silicic flows. On the other hand, flow banding is common in felsic flows. The morphology of lava describes its surface form or texture. More fluid basaltic lava flows tend to form flat sheet-like bodies, whereas viscous rhyolite lava flows form knobbly, blocky masses of rock. Lava erupted underwater has its own distinctive characteristics. ʻAʻā (also spelled aa , aʻa , ʻaʻa , and a-aa , and pronounced [ʔəˈʔaː] or / ˈ ɑː ( ʔ ) ɑː / )
4144-517: The flow of water and mud down the flanks of the volcano (a lahar ) after heavy rain . Solidified lava on the Earth's crust is predominantly silicate minerals : mostly feldspars , feldspathoids , olivine , pyroxenes , amphiboles , micas and quartz . Rare nonsilicate lavas can be formed by local melting of nonsilicate mineral deposits or by separation of a magma into immiscible silicate and nonsilicate liquid phases . Silicate lavas are molten mixtures dominated by oxygen and silicon ,
4218-411: The gaseous ambient environment. Silicon oxide layers could be used to electrically stabilize silicon surfaces. The surface passivation process is an important method of semiconductor device fabrication that involves coating a silicon wafer with an insulating layer of silicon oxide so that electricity could reliably penetrate to the conducting silicon below. Growing a layer of silicon dioxide on top of
4292-497: The icy satellites of the Solar System 's giant planets . The lava's viscosity mostly determines the behavior of lava flows. While the temperature of common silicate lava ranges from about 800 °C (1,470 °F) for felsic lavas to 1,200 °C (2,190 °F) for mafic lavas, its viscosity ranges over seven orders of magnitude, from 10 cP (10 Pa⋅s) for felsic lavas to 10 cP (10 Pa⋅s) for mafic lavas. Lava viscosity
4366-404: The lava's chemical composition. This temperature range is similar to the hottest temperatures achievable with a forced air charcoal forge. Lava is most fluid when first erupted, becoming much more viscous as its temperature drops. Lava flows quickly develop an insulating crust of solid rock as a result of radiative loss of heat. Thereafter, the lava cools by a very slow conduction of heat through
4440-610: The lava. Other cations , such as ferrous iron, calcium, and magnesium, bond much more weakly to oxygen and reduce the tendency to polymerize. Partial polymerization makes the lava viscous, so lava high in silica is much more viscous than lava low in silica. Because of the role of silica in determining viscosity and because many other properties of a lava (such as its temperature) are observed to correlate with silica content, silicate lavas are divided into four chemical types based on silica content: felsic , intermediate , mafic , and ultramafic . Felsic or silicic lavas have
4514-464: The lower and upper boundaries. These are described as pipe-stem vesicles or pipe-stem amygdales . Liquids expelled from the cooling crystal mush rise upwards into the still-fluid center of the cooling flow and produce vertical vesicle cylinders . Where these merge towards the top of the flow, they form sheets of vesicular basalt and are sometimes capped with gas cavities that sometimes fill with secondary minerals. The beautiful amethyst geodes found in
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#17327661902964588-467: The lower part that shows columnar jointing is called the colonnade . (The terms are borrowed from Greek temple architecture.) Likewise, regular vertical patterns on the sides of columns, produced by cooling with periodic fracturing, are described as chisel marks . Despite their names, these are natural features produced by cooling, thermal contraction, and fracturing. As lava cools, crystallizing inwards from its edges, it expels gases to form vesicles at
4662-422: The mantle than subalkaline magmas. Olivine nephelinite lavas are both ultramafic and highly alkaline, and are thought to have come from much deeper in the mantle of the Earth than other lavas. Tholeiitic basalt lava Rhyolite lava Some lavas of unusual composition have erupted onto the surface of the Earth. These include: The term "lava" can also be used to refer to molten "ice mixtures" in eruptions on
4736-521: The minimal heat loss maintains a low viscosity. The surface texture of pāhoehoe flows varies widely, displaying all kinds of bizarre shapes often referred to as lava sculpture. With increasing distance from the source, pāhoehoe flows may change into ʻaʻā flows in response to heat loss and consequent increase in viscosity. Experiments suggest that the transition takes place at a temperature between 1,200 and 1,170 °C (2,190 and 2,140 °F), with some dependence on shear rate. Pahoehoe lavas typically have
4810-400: The other hand, amorphous silica can be found in nature as opal and diatomaceous earth . Quartz glass is a form of intermediate state between these structures. All of these distinct crystalline forms always have the same local structure around Si and O. In α-quartz the Si–O bond length is 161 pm, whereas in α-tridymite it is in the range 154–171 pm. The Si–O–Si angle also varies between
4884-446: The physical behavior of silicate magmas. Silicon ions in lava strongly bind to four oxygen ions in a tetrahedral arrangement. If an oxygen ion is bound to two silicon ions in the melt, it is described as a bridging oxygen, and lava with many clumps or chains of silicon ions connected by bridging oxygen ions is described as partially polymerized. Aluminium in combination with alkali metal oxides (sodium and potassium) also tends to polymerize
4958-440: The range of 850 to 1,100 °C (1,560 to 2,010 °F). Because of their lower silica content and higher eruptive temperatures, they tend to be much less viscous, with a typical viscosity of 3.5 × 10 cP (3,500 Pa⋅s) at 1,200 °C (2,190 °F). This is slightly greater than the viscosity of smooth peanut butter . Intermediate lavas show a greater tendency to form phenocrysts . Higher iron and magnesium tends to manifest as
5032-409: The rate of flow is proportional to the shear stress . Instead, a typical lava is a Bingham fluid , which shows considerable resistance to flow until a stress threshold, called the yield stress, is crossed. This results in plug flow of partially crystalline lava. A familiar example of plug flow is toothpaste squeezed out of a toothpaste tube. The toothpaste comes out as a semisolid plug, because shear
5106-625: The rocky crust. For instance, geologists of the United States Geological Survey regularly drilled into the Kilauea Iki lava lake, formed in an eruption in 1959. After three years, the solid surface crust, whose base was at a temperature of 1,065 °C (1,949 °F), was still only 14 m (46 ft) thick, even though the lake was about 100 m (330 ft) deep. Residual liquid was still present at depths of around 80 m (260 ft) nineteen years after
5180-401: The silicon atoms with an Si–O–Si angle of 94° and bond length of 164.6 pm and the terminal Si–O bond length is 150.2 pm. The Si–O bond length is 148.3 pm, which compares with the length of 161 pm in α-quartz. The bond energy is estimated at 621.7 kJ/mol. SiO 2 is most commonly encountered in nature as quartz , which comprises more than 10% by mass of the Earth's crust. Quartz
5254-418: The silicon, store charge, block current, and even act as a controlled pathway to limit current flow. Many routes to silicon dioxide start with an organosilicon compound, e.g., HMDSO, TEOS. Synthesis of silica is illustrated below using tetraethyl orthosilicate (TEOS). Simply heating TEOS at 680–730 °C results in the oxide: Similarly TEOS combusts around 400 °C: TEOS undergoes hydrolysis via
5328-492: The so-called sol-gel process . The course of the reaction and nature of the product are affected by catalysts, but the idealized equation is: Being highly stable, silicon dioxide arises from many methods. Conceptually simple, but of little practical value, combustion of silane gives silicon dioxide. This reaction is analogous to the combustion of methane: However the chemical vapor deposition of silicon dioxide onto crystal surface from silane had been used using nitrogen as
5402-446: The transformation is accompanied by a significant change in volume, it can easily induce fracturing of ceramics or rocks passing through this temperature limit. The high-pressure minerals, seifertite , stishovite, and coesite, though, have higher densities and indices of refraction than quartz. Stishovite has a rutile -like structure where silicon is 6-coordinate. The density of stishovite is 4.287 g/cm , which compares to α-quartz,
5476-480: Was recorded following the collapse of a lava lake at Mount Nyiragongo . The scaling relationship for lavas is that the average speed of a flow scales as the square of its thickness divided by its viscosity. This implies that a rhyolite flow would have to be about a thousand times thicker than a basalt flow to flow at a similar speed. The temperature of most types of molten lava ranges from about 800 °C (1,470 °F) to 1,200 °C (2,190 °F) depending on
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