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47-410: Four major dacitic – rhyolitic eruptions occurred during the late Pleistocene and Holocene , producing pyroclastic flows and tephra that blanketed much of the country. The caldera collapsed most recently sometime between 410 and 535 CE (based on radiocarbon dating of plant life directly related to the eruption), which produced widespread pyroclastic flows and devastated Mayan cities ; however,

94-399: A polarizing microscope . The extinction angle is an optical characteristic and varies with the albite fraction (%Ab). The intermediate members of the plagioclase group are very similar to each other and normally cannot be distinguished except by their optical properties. The specific gravity in each member (albite 2.62) increases 0.02 per 10% increase in anorthite (2.75). Plagioclase is

141-534: A crushed grain mount can be obtained by the Tsuboi method, which yields an accurate measurement of the minimum refractive index that in turn gives an accurate composition. In thin section , the composition can be determined by either the Michel Lévy or Carlsbad-albite methods. The former relies on accurate measure of minimum index of refraction, while the latter relies on measuring the extinction angle under

188-491: A depth of at least 0.5 cm (0.20 in), which would have stopped all agricultural production in the most-severely affected area for decades. It is also theorized that the eruption and subsequent weather events and agricultural failures directly led to the abandonment of Teotihuacan by the original inhabitants. It was hypothesized that this eruption caused the extreme weather events of 535–536 in Europe and Asia, but this

235-400: A more calcium-rich rim on a more sodium-rich core. Plagioclase also sometimes shows oscillatory zoning, with the zones fluctuating between sodium-rich and calcium-rich compositions, though this is usually superimposed on an overall normal zoning trend. Plagioclase is very important for the classification of crystalline igneous rocks. Generally, the more silica is present in the rock, the fewer

282-583: A new rock type to separate calc-alkaline rocks with oligoclase phenocrysts (dacites) from rocks with orthoclase phenocrysts (rhyolites). Dacite consists mostly of plagioclase feldspar and quartz with biotite , hornblende , and pyroxene ( augite or enstatite ). The quartz appears as rounded, corroded phenocrysts , or as an element of the ground-mass. The plagioclase in dacite ranges from oligoclase to andesine and labradorite . Sanidine occurs, although in small proportions, in some dacites, and when abundant gives rise to rocks that form transitions to

329-535: A plagioclase feldspar is typically denoted by its overall fraction of anorthite (%An) or albite (%Ab). There are several named plagioclase feldspars that fall between albite and anorthite in the series. The following table shows their compositions in terms of constituent anorthite and albite percentages. The distinction between these minerals cannot easily be made in the field . The composition can be roughly determined by specific gravity, but accurate measurement requires chemical or optical tests. The composition in

376-537: A province of the Roman Empire which lay between the Danube River and Carpathian Mountains (now modern Romania and Moldova ) where the rock was first described. The term dacite was used for the first time in the scientific literature in the book Geologie Siebenbürgens ( The Geology of Transylvania ) by Austrian geologists Franz Ritter von Hauer and Guido Stache. Dacite was originally defined as

423-477: A silica content of 60.7 wt%; and 1,275 °C (2,327 °F) in dacite with a silica content of 69.9 wt%. These values are for dry magma. The liquidus is greatly lowered by the addition of water, and much more for plagioclase than for mafic minerals. The eutectic (minimum melting mixture) for a mixture of anorthite and diopside shifts from 40 wt% anorthite to 78 wt% anorthite as the water vapor pressure goes from 1 bar to 10 kbar. The presence of water also shifts

470-485: A team of scientists concluded that the volcanic eruption might have happened in 431 ± 2 CE , based on volcanic shards taken from ice cores in Greenland , levels of sulphur recorded in ice cores from Antarctica , and radiocarbon dating of a charred tree found in volcanic ash deposits. The eruption is estimated to have produced around 37–82 km (8.9–19.7 cu mi) of ejecta ( DRE —several times more than

517-401: A thick felsic continental plate. Oceanic crust is hydrothermally altered causing addition of quartz and sodium. As the young, hot oceanic plate is subducted under continental crust, the subducted slab partially melts and interacts with the upper mantle through convection and dehydration reactions. The process of subduction creates metamorphism in the subducting slab. When this slab reaches

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564-502: A useful estimate of composition if measured accurately. The index of refraction likewise varies smoothly from 1.53 to 1.58, and, if measured carefully, this also gives a useful composition estimate. Plagioclase almost universally shows a characteristic polysynthetic twinning that produces twinning striations on [010]. These striations allow plagioclase to be distinguished from alkali feldspar. Plagioclase often also displays Carlsbad, Baveno, and Manebach Law twinning. The composition of

611-444: Is 6 to 6.5, and cleavage is perfect on [001] and good on [010], with the cleavage planes meeting at an angle of 93 to 94 degrees. It is from this slightly oblique cleavage angle that plagioclase gets its name, Ancient Greek plágios ( πλάγιος 'oblique') + klásis ( κλάσις 'fracture'). The name was introduced by August Breithaupt in 1847. There is also a poor cleavage on [110] rarely seen in hand samples. The luster

658-652: Is a series of tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continuous solid solution series, more properly known as the plagioclase feldspar series. This was first shown by the German mineralogist Johann Friedrich Christian Hessel (1796–1872) in 1826. The series ranges from albite to anorthite endmembers (with respective compositions NaAlSi 3 O 8 to CaAl 2 Si 2 O 8 ), where sodium and calcium atoms can substitute for each other in

705-594: Is an intrusive rock composed of at least 90% plagioclase. Albite is an end member of both the alkali and plagioclase series. However, it is included in the alkali feldspar fraction of the rock in the QAPF classification. Plagioclase is also common in metamorphic rock. Plagioclase tends to be albite in low-grade metamorphic rock, while oligoclase to andesine are more common in medium- to high-grade metamorphic rock. Metacarbonate rock sometimes contains fairly pure anorthite. Feldspar makes up between 10 and 20 percent of

752-558: Is found extraterrestrially at Nili Patera caldera of Syrtis Major Planum on Mars . Volcanic rocks : Subvolcanic rocks : Plutonic rocks : Picrite basalt Peridotite Basalt Diabase (Dolerite) Gabbro Andesite Microdiorite Diorite Dacite Microgranodiorite Granodiorite Rhyolite Microgranite Granite Plagioclase Plagioclase ( / ˈ p l æ dʒ ( i ) ə ˌ k l eɪ s , ˈ p l eɪ dʒ -, - ˌ k l eɪ z / PLAJ -(ee)-ə-klayss, PLAYJ -, -⁠klayz )

799-483: Is high in silica and low in alkali metal oxides . It has a fine-grained ( aphanitic ) to porphyritic texture and is intermediate in composition between andesite and rhyolite . It is composed predominantly of plagioclase feldspar and quartz . Dacite is relatively common, occurring in many tectonic settings. It is associated with andesite and rhyolite as part of the subalkaline tholeiitic and calc-alkaline magma series . The word dacite comes from Dacia ,

846-866: Is impractical. The rock must then be classified chemically based on its content of silica and alkali metal oxides ( K 2 O plus Na 2 O ). The TAS classification puts dacite in the O3 sector. In hand specimen, many of the hornblende and biotite dacites are grey or pale brown and yellow rocks with white feldspars, and black crystals of biotite and hornblende. Other dacites, especially pyroxene-bearing dacites, are darker colored. In thin section, dacites may have an aphanitic to porphyritic texture. Porphyritic dacites contain blocky highly zoned plagioclase phenocrysts and/or rounded corroded quartz phenocrysts. Subhedral hornblende and elongated biotite grains are present. Sanidine phenocrysts and augite (or enstatite ) are found in some samples. The groundmass of these rocks

893-559: Is known as the alkali feldspar series. Thus, almost all feldspar found on Earth is either plagioclase or alkali feldspar, with the two series overlapping for pure albite. When a plagioclase composition is described by its anorthite mol% (such as An40 in the previous example) it is assumed that the remainder is albite, with only a minor component of potassium feldspar. Plagioclase of any composition shares many basic physical characteristics, while other characteristics vary smoothly with composition. The Mohs hardness of all plagioclase species

940-452: Is known as the plagioclase series. The composition of a particular sample of plagioclase is customarily expressed as the mol% of anorthite in the sample. For example, plagioclase that is 40 mol% anorthite would be described as An40 plagioclase. The ability of albite and anorthite to form solid solutions in any proportions at elevated temperature reflects the ease with which calcium and aluminium can substitute for sodium and silicon in

987-425: Is often aphanitic microcrystalline , with a web of minute feldspars mixed with interstitial grains of quartz or tridymite; but in many dacites it is largely vitreous, while in others it is felsitic or cryptocrystalline. Dacite usually forms as an intrusive rock such as a dike or sill . Examples of this type of dacite outcrop are found in northwestern Montana and northeastern Bulgaria . Nevertheless, because of

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1034-413: Is unlikely given the research published in 2020 that dates the eruption to 431 CE. Later eruptions formed several lava domes within the lake and near its shore. The only historical eruption, which occurred from December 31, 1879, up to March 26, 1880, produced a lava dome and had a VEI of 3. The lava dome reached the surface of the lake, forming the islets known as Islas Quemadas. On July 5, 2004

1081-428: Is usually white to greyish-white in color, with a slight tendency for more calcium-rich samples to be darker. Impurities can infrequently tint the mineral greenish, yellowish, or flesh-red. Ferric iron (Fe ) gives a pale yellow color in plagioclase feldspar from Lake County, Oregon . The specific gravity increases smoothly with calcium content, from 2.62 for pure albite to 2.76 for pure anorthite, and this can provide

1128-566: Is vitreous to pearly and the diaphaneity is transparent to translucent. The tenacity is brittle, and the fracture is uneven or conchoidal, but the fracture is rarely observed due to the strong tendency of the mineral to cleave instead. At low temperature, the crystal structure belongs to the triclinic system , space group P 1 Well-formed crystals are rare and are most commonly sodic in composition. Well-shaped samples are instead typically cleavage fragments. Well-formed crystals are typically bladed or tabular parallel to [010]. Plagioclase

1175-514: The 1980 eruption of Mount St. Helens ), which puts it at a rating of 6 on the Volcanic Explosivity Index (VEI) and makes it one of the biggest volcanic events on Earth in the last 7,000 years. Fallout from the eruption column blanketed an area of at least 10,000 km (3,900 sq mi) with pumice and ash to a depth of at least 50 cm (20 in), and an area of nearly 2,000,000 km (770,000 sq mi) to

1222-482: The Earth's crust and the upper mantle , is thought to be the depth where feldspar disappears from the rock. While plagioclase is the most important aluminium-bearing mineral in the crust, it breaks down at the high pressure of the upper mantle, with the aluminium tending to be incorporated into clinopyroxene as Tschermak's molecule ( CaAl 2 SiO 6 ) or in jadeite NaAlSi 2 O 6 . At still higher pressure,

1269-663: The Earth's crust . Part of the feldspar family of minerals, it is abundant in igneous and metamorphic rock , and it is also common as a detrital mineral in sedimentary rock . It is not a single mineral , but is a solid solution of two end members , albite or sodium feldspar ( NaAlSi 3 O 8 ) and anorthite or calcium feldspar ( CaAl 2 Si 2 O 8 ). These can be present in plagioclase in any proportion from pure anorthite to pure albite. The composition of plagioclase can thus be written as Na 1−x Ca x Al 1+x Si 3−x O 8 where x ranges from 0 for pure albite to 1 for pure anorthite. This solid solution series

1316-518: The aluminium is incorporated into garnet . At very high temperatures, plagioclase forms a solid solution with potassium feldspar, but this becomes highly unstable on cooling. The plagioclase separates from the potassium feldspar, a process called exsolution . The resulting rock, in which fine streaks of plagioclase ( lamellae ) are present in potassium feldspar, is called perthite . The solid solution between anorthite and albite remains stable to lower temperatures, but ultimately becomes unstable as

1363-401: The beautiful play of colors known as chatoyance . In addition to its importance to geologists in classifying igneous rocks, plagioclase finds practical use as construction aggregate , as dimension stone , and in powdered form as a filler in paint, plastics, and rubber. Sodium-rich plagioclase finds use in the manufacture of glass and ceramics. Anorthosite could someday be important as

1410-481: The composition of the crystallizing plagioclase towards anorthite. The eutectic for this wet mixture drops to about 1,010 °C (1,850 °F). Crystallizing plagioclase is always richer in anorthite than the melt from which it crystallizes. This plagioclase effect causes the residual melt to be enriched in sodium and silicon and depleted in aluminium and calcium. However, the simultaneous crystallization of mafic minerals not containing aluminium can partially offset

1457-401: The composition with which plagioclase crystallizes also depends on the other components of the melt, so it is not by itself a reliable thermometer. The liquidus of plagioclase (the temperature at which the plagioclase first begins to crystallize) is about 1,215 °C (2,219 °F) for olivine basalt , with a composition of 50.5 wt% silica; 1,255 °C (2,291 °F) in andesite with

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1504-565: The depletion in aluminium. In volcanic rock, the crystallized plagioclase incorporates most of the potassium in the melt as a trace element. New plagioclase crystals nucleate only with difficulty, and diffusion is very slow within the solid crystals. As a result, as a magma cools, increasingly sodium-rich plagioclase is usually crystallized onto the rims of existing plagioclase crystals, which retain their more calcium-rich cores. This results in compositional zoning of plagioclase in igneous rocks. In rare cases, plagioclase shows reverse zoning, with

1551-419: The framework grains in typical sandstones . Alkali feldspar is usually more abundant than plagioclase in sandstone because Alkali feldspars are more resistant to chemical weathering and more stable, but sandstone derived from volcanic rock contains more plagioclase. Plagioclase weathers relatively rapidly to clay minerals such as smectite . The Mohorovičić discontinuity , which defines the boundary between

1598-482: The highlands of the Moon . Analysis of thermal emission spectra from the surface of Mars suggests that plagioclase is the most abundant mineral in the crust of Mars. Its name comes from Ancient Greek πλάγιος ( plágios )  'oblique' and κλάσις ( klásis )  'fracture', in reference to its two cleavage angles. Plagioclase is the most common and abundant mineral group in

1645-457: The history of the magma. The formation of dacite provides a great deal of information about the connection between oceanic crust and continental crust. It provides a model for the generation of felsic, buoyant, perennial rock from a mafic, dense, short-lived one. The process by which dacite forms has been used to explain the generation of continental crust during the Archean eon . At that time,

1692-427: The illusionist, Francis Fanci was tagged and submerged inside a trunk from which he emerged after thirty seconds. On the other hand, in 2004 Matthew Hatfield Knight, eldest son of the owner of the international consortium of Nike sports shoes, died of a heart attack while diving with his colleagues. Dacite Dacite ( / ˈ d eɪ s aɪ t / ) is a volcanic rock formed by rapid solidification of lava that

1739-535: The mafic minerals, and the more sodium-rich the plagioclase. Alkali feldspar appears as the silica content becomes high. Under the QAPF classification , plagioclase is one of the three key minerals, along with quartz and alkali feldspar, used to make the initial classification of the rock type. Low-silica igneous rocks are further divided into dioritic rocks having sodium-rich plagioclase (An<50) and gabbroic rocks having calcium-rich plagioclase (An>50). Anorthosite

1786-428: The mantle and initiates the dehydration reactions, minerals such as talc , serpentine , mica and amphiboles break down generating a more sodic melt. The magma then continues to migrate upwards causing differentiation and becomes even more sodic and silicic as it rises. Once at the cold surface, the sodium rich magma crystallizes plagioclase, quartz and hornblende. Accessory minerals like pyroxenes provide insight to

1833-413: The mineral's crystal lattice structure. Plagioclase in hand samples is often identified by its polysynthetic crystal twinning or " record -groove" effect. Plagioclase is a major constituent mineral in Earth's crust and is consequently an important diagnostic tool in petrology for identifying the composition, origin and evolution of igneous rocks . Plagioclase is also a major constituent of rock in

1880-478: The moderately high silica content, dacitic magma is quite viscous and therefore prone to explosive eruption. A notorious example of this is Mount St. Helens in which dacite domes formed from previous eruptions. Pyroclastic flows may also be of dacitic composition as is the case with the Fish Canyon Tuff of La Garita Caldera . Dacitic magma is formed by the subduction of young oceanic crust under

1927-399: The plagioclase crystal structure. Although a calcium ion has a charge of +2, versus +1 for a sodium ion, the two ions have very nearly the same effective radius. The difference in charge is accommodated by the coupled substitution of aluminium (charge +3) for silicon (charge +4), both of which can occupy tetrahedral sites (surrounded by four oxygen ions). This contrasts with potassium, which has

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1974-438: The primary aluminium-bearing mineral in mafic rocks formed at low pressure. It is normally the first and most abundant feldspar to crystallize from a cooling primitive magma . Anorthite has a much higher melting point than albite, and, as a result, calcium-rich plagioclase is the first to crystallize. The plagioclase becomes more enriched in sodium as the temperature drops, forming Bowen's continuous reaction series . However,

2021-507: The production of dacitic magma was more ubiquitous, due to the availability of young, hot oceanic crust. Today, the colder oceanic crust that subducts under most plates is not able to melt prior to the dehydration reactions, thus inhibiting the process. Dacitic magma was encountered in a drillhole during geothermal exploration on Kīlauea in 2005. At a depth of 2488 m, the magma flowed up the wellbore. This produced several kilograms of clear, colorless vitric (glassy, non-crystalline) cuttings at

2068-521: The rhyolites. The relative proportions of feldspars and quartz in dacite, and in many other volcanic rocks, are illustrated in the QAPF diagram . This defines dacite as having a content of 20% to 60% quartz, with plagioclase making up 65% or more of its feldspar content. However, while the IUGS recommends classifying volcanic rocks on the basis of their mineral composition whenever possible, dacites are often so fine-grained that mineral identification

2115-411: The rock approaches ambient surface temperatures. The resulting exsolution results in very fine lamellar and other intergrowths, normally detected only by sophisticated means. However, exsolution in the andesine to labradorite compositional range sometimes produces lamellae with thicknesses comparable to the wavelength of visible light. This acts like a diffraction grating , causing the labradorite to show

2162-429: The same charge as sodium, but is a significantly larger ion. As a result of the size and charge difference between potassium and calcium, there is a very wide miscibility gap between anorthite and potassium feldspar , ( KAlSi 3 O 8 ), the third common rock-forming feldspar end member. Potassium feldspar does form a solid solution series with albite , due to the identical charges of sodium and potassium ions, which

2209-813: The surface. The dacite magma is a residual melt of the typical basalt magma of Kīlauea. Dacite is relatively common and occurs in various tectonic and magmatic contexts: The type locality of dacite is Gizella quarry near Poieni, Cluj in Romania . Other occurrences of dacite in Europe are Germany ( Weiselberg ), Greece ( Nisyros and Thera ), Italy (in Bozen quartz porphyry, and Sardinia ), Austria (Styrian Volcano Arc), Scotland ( Argyll ), Slovakia , Spain (El Hoyazo near Almería ), France ( Massif de l'Esterel ) and Hungary (Csódi Hill). Sites outside Europe include Iran , Morocco , New Zealand (volcanic region of Taupo ), Turkey , USA and Zambia . Dacite

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