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82-552: The Makran Coastal Range is primarily made up of limestone and sandstone . It was formed when the northwestern Indian Plate collided with the Asian Plate. There are three main ranges in Balochistan: Limestone Limestone ( calcium carbonate CaCO 3 ) is a type of carbonate sedimentary rock which is the main source of the material lime . It is composed mostly of

164-659: A Hertzian cone when struck with sufficient force. This results in conchoidal fractures, a characteristic of all minerals with no cleavage planes. In this kind of fracture, a cone of force propagates through the material from the point of impact, eventually removing a full or partial cone, like when a plate-glass window is struck by a small object such as an air gun projectile. The partial Hertzian cones produced during lithic reduction are called flakes , and exhibit features characteristic of this sort of breakage, including striking platforms , bulbs of force , and occasionally eraillures , which are small secondary flakes detached from

246-463: A bloom of cyanobacteria or microalgae . However, stable isotope ratios in modern carbonate mud appear to be inconsistent with either of these mechanisms, and abrasion of carbonate grains in high-energy environments has been put forward as a third possibility. Formation of limestone has likely been dominated by biological processes throughout the Phanerozoic , the last 540 million years of

328-619: A carbonate mud matrix. Because limestones are often of biological origin and are usually composed of sediment that is deposited close to where it formed, classification of limestone is usually based on its grain type and mud content. Most grains in limestone are skeletal fragments of marine organisms such as coral or foraminifera . These organisms secrete structures made of aragonite or calcite, and leave these structures behind when they die. Other carbonate grains composing limestones are ooids , peloids , and limeclasts ( intraclasts and extraclasts  [ ca ] ). Skeletal grains have

410-434: A carbonate rock outcrop can be estimated in the field by etching the surface with dilute hydrochloric acid. This etches away the calcite and aragonite, leaving behind any silica or dolomite grains. The latter can be identified by their rhombohedral shape. Crystals of calcite, quartz , dolomite or barite may line small cavities ( vugs ) in the rock. Vugs are a form of secondary porosity, formed in existing limestone by

492-616: A central quartz grain or carbonate mineral fragment. These likely form by direct precipitation of calcium carbonate onto the ooid. Pisoliths are similar to ooids, but they are larger than 2 mm in diameter and tend to be more irregular in shape. Limestone composed mostly of ooids is called an oolite or sometimes an oolitic limestone . Ooids form in high-energy environments, such as the Bahama platform, and oolites typically show crossbedding and other features associated with deposition in strong currents. Oncoliths resemble ooids but show

574-449: A change in environment that increases the solubility of calcite. Dense, massive limestone is sometimes described as "marble". For example, the famous Portoro "marble" of Italy is actually a dense black limestone. True marble is produced by recrystallization of limestone during regional metamorphism that accompanies the mountain building process ( orogeny ). It is distinguished from dense limestone by its coarse crystalline texture and

656-407: A chemical feedstock for the production of lime used for cement (an essential component of concrete ), as aggregate for the base of roads, as white pigment or filler in products such as toothpaste or paint, as a soil conditioner , and as a popular decorative addition to rock gardens . Limestone formations contain about 30% of the world's petroleum reservoirs . Limestone is composed mostly of

738-949: A composition reflecting the organisms that produced them and the environment in which they were produced. Low-magnesium calcite skeletal grains are typical of articulate brachiopods , planktonic (free-floating) foraminifera, and coccoliths . High-magnesium calcite skeletal grains are typical of benthic (bottom-dwelling) foraminifera, echinoderms , and coralline algae . Aragonite skeletal grains are typical of molluscs , calcareous green algae , stromatoporoids , corals , and tube worms . The skeletal grains also reflect specific geological periods and environments. For example, coral grains are more common in high-energy environments (characterized by strong currents and turbulence) while bryozoan grains are more common in low-energy environments (characterized by quiet water). Ooids (sometimes called ooliths) are sand-sized grains (less than 2mm in diameter) consisting of one or more layers of calcite or aragonite around

820-412: A considerable fraction of the limestone bed. At depths greater than 1 km (0.62 miles), burial cementation completes the lithification process. Burial cementation does not produce stylolites. When overlying beds are eroded, bringing limestone closer to the surface, the final stage of diagenesis takes place. This produces secondary porosity as some of the cement is dissolved by rainwater infiltrating

902-483: A drop of dilute hydrochloric acid is dropped on it. Dolomite is also soft but reacts only feebly with dilute hydrochloric acid, and it usually weathers to a characteristic dull yellow-brown color due to the presence of ferrous iron. This is released and oxidized as the dolomite weathers. Impurities (such as clay , sand, organic remains, iron oxide , and other materials) will cause limestones to exhibit different colors, especially with weathered surfaces. The makeup of

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984-637: A few million years, as this is the most stable form of calcium carbonate. Ancient carbonate formations of the Precambrian and Paleozoic contain abundant dolomite, but limestone dominates the carbonate beds of the Mesozoic and Cenozoic . Modern dolomite is quite rare. There is evidence that, while the modern ocean favors precipitation of aragonite, the oceans of the Paleozoic and middle to late Cenozoic favored precipitation of calcite. This may indicate

1066-455: A few thousand years. As rainwater mixes with groundwater, aragonite and high-magnesium calcite are converted to low-calcium calcite. Cementing of thick carbonate deposits by rainwater may commence even before the retreat of the sea, as rainwater can infiltrate over 100 km (60 miles) into sediments beneath the continental shelf. As carbonate sediments are increasingly deeply buried under younger sediments, chemical and mechanical compaction of

1148-448: A fraction of a micron to 20 microns, but most typically 8 to 10 microns. Chalcedony is a microfibrous variety of quartz, consisting of radiating bundles of very thin crystals about 100 microns long. Megaquartz is composed of equidimensional grains over 20 microns in size. Most chert is microcrystalline quartz with minor chalcedony and sometimes opal , but cherts range from nearly pure opal to nearly pure quartz chert. However, little opal

1230-547: A limestone and rarely exceeds 1%. Limestone often contains variable amounts of silica in the form of chert or siliceous skeletal fragments (such as sponge spicules, diatoms , or radiolarians ). Fossils are also common in limestone. Limestone is commonly white to gray in color. Limestone that is unusually rich in organic matter can be almost black in color, while traces of iron or manganese can give limestone an off-white to yellow to red color. The density of limestone depends on its porosity, which varies from 0.1% for

1312-435: A limestone sample except in thin section and are less common in ancient limestones, possibly because compaction of carbonate sediments disrupts them. Limeclasts are fragments of existing limestone or partially lithified carbonate sediments. Intraclasts are limeclasts that originate close to where they are deposited in limestone, while extraclasts come from outside the depositional area. Intraclasts include grapestone , which

1394-471: A lower Mg/Ca ratio in the ocean water of those times. This magnesium depletion may be a consequence of more rapid sea floor spreading , which removes magnesium from ocean water. The modern ocean and the ocean of the Mesozoic have been described as "aragonite seas". Most limestone was formed in shallow marine environments, such as continental shelves or platforms . Such environments form only about 5% of

1476-525: A lower diversity of organisms and a greater fraction of silica and clay minerals characteristic of marls . The Green River Formation is an example of a prominent freshwater sedimentary formation containing numerous limestone beds. Freshwater limestone is typically micritic. Fossils of charophyte (stonewort), a form of freshwater green algae, are characteristic of these environments, where the charophytes produce and trap carbonates. Limestones may also form in evaporite depositional environments . Calcite

1558-523: A mechanism for dolomitization, with one 2004 review paper describing it bluntly as "a myth". Ordinary seawater is capable of converting calcite to dolomite, if the seawater is regularly flushed through the rock, as by the ebb and flow of tides (tidal pumping). Once dolomitization begins, it proceeds rapidly, so that there is very little carbonate rock containing mixed calcite and dolomite. Carbonate rock tends to be either almost all calcite/aragonite or almost all dolomite. About 20% to 25% of sedimentary rock

1640-413: A microcrystalline form of silica composed mostly of bladed crystals of cristobalite and tridymite . Much opal-CT takes the form of lepispheres , which are clusters of bladed crystals about 10 microns in diameter. Opal-CT in turn transforms to microquartz. In deep ocean water, the transition to opal-CT occurs at a temperature of about 45 °C (113 °F) while the transition to microquartz occurs at

1722-448: A plausible source of mud. Another possibility is direct precipitation from the water. A phenomenon known as whitings occurs in shallow waters, in which white streaks containing dispersed micrite appear on the surface of the water. It is uncertain whether this is freshly precipitated aragonite or simply material stirred up from the bottom, but there is some evidence that whitings are caused by biological precipitation of aragonite as part of

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1804-449: A radial rather than layered internal structure, indicating that they were formed by algae in a normal marine environment. Peloids are structureless grains of microcrystalline carbonate likely produced by a variety of processes. Many are thought to be fecal pellets produced by marine organisms. Others may be produced by endolithic (boring) algae or other microorganisms or through breakdown of mollusc shells. They are difficult to see in

1886-614: A significant percentage of magnesium . Most limestone was formed in shallow marine environments, such as continental shelves or platforms , though smaller amounts were formed in many other environments. Much dolomite is secondary dolomite, formed by chemical alteration of limestone. Limestone is exposed over large regions of the Earth's surface, and because limestone is slightly soluble in rainwater, these exposures often are eroded to become karst landscapes. Most cave systems are found in limestone bedrock. Limestone has numerous uses: as

1968-418: A source of dissolved silica, but they are sometimes found cutting across bedding surfaces, where the chert fills fossil burrows , fluid escape structures , or fractures. Nodules under a few centimeters in size tend to be egg-shaped, while larger nodules form irregular bodies with knobby surfaces. The outer few centimeters of large nodules may show desiccation cracks with secondary chert, which likely formed at

2050-506: A spark that ignites a small reservoir containing black powder , discharging the firearm. Cherts can cause several problems when used as concrete aggregates. Deeply weathered chert develops surface pop-outs when used in concrete that undergoes freezing and thawing because of the high porosity of weathered chert. The other concern is that certain cherts undergo an alkali-silica reaction with high-alkali cements. This reaction leads to cracking and expansion of concrete and ultimately to failure of

2132-870: A temperature of about 80 °C (176 °F). However, the transition temperature varies considerably, and the transition is hastened by the presence of magnesium hydroxide , which provides a nucleus for the recrystallization. Megaquartz forms at elevated temperatures typical of metamorphism . There is evidence that the variety of chert called porcelainite , which is characterized by a high content of opal-CT, recrystallizes at very shallow depths. The Caballos Novaculite of Texas also shows signs of very shallow water deposition, including shallow water sedimentary structures and evaporite pseudomorphs , which are casts of crystals of soluble minerals that could have formed only in near-surface conditions. This novaculate appears to have formed by replacement of carbonate fecal pellets by chert. Bedded cherts can be further subdivided by

2214-401: Is a hard, fine-grained sedimentary rock composed of microcrystalline or cryptocrystalline quartz , the mineral form of silicon dioxide (SiO 2 ). Chert is characteristically of biological origin, but may also occur inorganically as a chemical precipitate or a diagenetic replacement, as in petrified wood . Chert is typically composed of the petrified remains of siliceous ooze ,

2296-560: Is also favored on the seaward margin of shelves and platforms, where there is upwelling deep ocean water rich in nutrients that increase organic productivity. Reefs are common here, but when lacking, ooid shoals are found instead. Finer sediments are deposited close to shore. The lack of deep sea limestones is due in part to rapid subduction of oceanic crust, but is more a result of dissolution of calcium carbonate at depth. The solubility of calcium carbonate increases with pressure and even more with higher concentrations of carbon dioxide, which

2378-402: Is carbonate rock, and most of this is limestone. Limestone is found in sedimentary sequences as old as 2.7 billion years. However, the compositions of carbonate rocks show an uneven distribution in time in the geologic record. About 95% of modern carbonates are composed of high-magnesium calcite and aragonite. The aragonite needles in carbonate mud are converted to low-magnesium calcite within

2460-474: Is clusters of peloids cemented together by organic material or mineral cement. Extraclasts are uncommon, are usually accompanied by other clastic sediments, and indicate deposition in a tectonically active area or as part of a turbidity current . The grains of most limestones are embedded in a matrix of carbonate mud. This is typically the largest fraction of an ancient carbonate rock. Mud consisting of individual crystals less than 5 μm (0.20 mils) in length

2542-420: Is controlled largely by the amount of dissolved carbon dioxide ( CO 2 ) in the water. This is summarized in the reaction: Increases in temperature or decreases in pressure tend to reduce the amount of dissolved CO 2 and precipitate CaCO 3 . Reduction in salinity also reduces the solubility of CaCO 3 , by several orders of magnitude for fresh water versus seawater. Near-surface water of

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2624-545: Is converted to low-magnesium calcite. Diagenesis is the likely origin of pisoliths , concentrically layered particles ranging from 1 to 10 mm (0.039 to 0.394 inches) in diameter found in some limestones. Pisoliths superficially resemble ooids but have no nucleus of foreign matter, fit together tightly, and show other signs that they formed after the original deposition of the sediments. Silicification occurs early in diagenesis, at low pH and temperature, and contributes to fossil preservation. Silicification takes place through

2706-460: Is described as coquinite . Chalk is a soft, earthy, fine-textured limestone composed of the tests of planktonic microorganisms such as foraminifera, while marl is an earthy mixture of carbonates and silicate sediments. Limestone forms when calcite or aragonite precipitate out of water containing dissolved calcium, which can take place through both biological and nonbiological processes. The solubility of calcium carbonate ( CaCO 3 )

2788-617: Is described as micrite . In fresh carbonate mud, micrite is mostly small aragonite needles, which may precipitate directly from seawater, be secreted by algae, or be produced by abrasion of carbonate grains in a high-energy environment. This is converted to calcite within a few million years of deposition. Further recrystallization of micrite produces microspar , with grains from 5 to 15 μm (0.20 to 0.59 mils) in diameter. Limestone often contains larger crystals of calcite, ranging in size from 0.02 to 0.1 mm (0.79 to 3.94 mils), that are described as sparry calcite or sparite . Sparite

2870-462: Is distinguished from micrite by a grain size of over 20 μm (0.79 mils) and because sparite stands out under a hand lens or in thin section as white or transparent crystals. Sparite is distinguished from carbonate grains by its lack of internal structure and its characteristic crystal shapes. Geologists are careful to distinguish between sparite deposited as cement and sparite formed by recrystallization of micrite or carbonate grains. Sparite cement

2952-418: Is far below saturation, indicating that silica cannot normally be precipitated from seawater through inorganic processes. The silica is instead extracted from seawater by living organisms, such as diatoms, radiolarians, and glass sponges, which can efficiently extract silica even from very unsaturated water, and which are estimated to presently produce 12 cubic kilometers (2.9 cu mi) of opal per year in

3034-885: Is little in the carbonate buildup zone itself. This may reflect dissolution of opal where carbonate is being actively deposited, a lack of siliceous organisms in these environments, or removal of siliceous skeletons by strong currents that redeposit the siliceous material in the deep basin. The silica in nodular chert likely precipitates as opal-A, based on internal banding in nodules, and may recrystallize directly to microquartz without first recrystallizing to opal-CT. Some nodular chert may precipitate directly as microquartz, due to low levels of supersaturation of silica. The banded iron formations of Precambrian age are composed of alternating layers of chert and iron oxides . Nonmarine cherts may form in saline alkaline lakes as thin lenses or nodules showing sedimentary structures suggestive of evaporite origin. Such cherts are forming today in

3116-780: Is most often found as gray, brown, grayish brown and light green to rusty red and occasionally as dark green. Its color is an expression of trace elements present in the rock. Both red and green are most often related to traces of iron in its oxidized and reduced forms, respectively. In petrology , the term "chert" refers generally to all chemically precipitated sedimentary rocks composed primarily of microcrystalline , cryptocrystalline and microfibrous silica . Most cherts are nearly pure silica, with less than 5% other minerals (mostly calcite , dolomite , clay minerals , hematite , and organic matter.) However, cherts range from very pure cherts with over 99% silica content to impure nodular cherts with less than 65% silica content. Aluminium

3198-485: Is of only modest economic importance today as a source of silica (quartz sand being much more important.) However, chert deposits may be associated with valuable deposits of iron , uranium , manganese , phosphorite , and petroleum . In prehistoric times, chert was often used as a raw material for the construction of stone tools . Like obsidian , as well as some rhyolites , felsites , quartzites , and other tool stones used in lithic reduction , chert fractures in

3280-560: Is one of the first minerals to precipitate in marine evaporites. Most limestone is formed by the activities of living organisms near reefs, but the organisms responsible for reef formation have changed over geologic time. For example, stromatolites are mound-shaped structures in ancient limestones, interpreted as colonies of cyanobacteria that accumulated carbonate sediments, but stromatolites are rare in younger limestones. Organisms precipitate limestone both directly as part of their skeletons, and indirectly by removing carbon dioxide from

3362-459: Is over 60 million years old. Opaline chert often contains visible fossils of diatoms , radiolarians , and glass sponge spicules . Chert is found in settings as diverse as hot spring deposits ( siliceous sinter ), banded iron formation ( jaspilite ), or alkaline lakes . However, most chert is found either as bedded chert or as nodular chert . Bedded chert is more common in Precambrian beds, but nodular chert became more common in

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3444-472: Is produced by decaying organic matter settling into the deep ocean that is not removed by photosynthesis in the dark depths. As a result, there is a fairly sharp transition from water saturated with calcium carbonate to water unsaturated with calcium carbonate, the lysocline , which occurs at the calcite compensation depth of 4,000 to 7,000 m (13,000 to 23,000 feet). Below this depth, foraminifera tests and other skeletal particles rapidly dissolve, and

3526-435: Is the most abundant minor element, followed by iron and manganese or potassium , sodium , and calcium . Extracrystalline water (tiny inclusions of water within and around the quartz grains) make up less than 1% of most cherts. The Folk classification divides chert into three textural categories. Granular microquartz is the component of chert consisting of roughly equidimensional quartz grains, ranging in size from

3608-419: Is uncertain, but they may form from fossil remains that are completely dissolved in fluids that then migrate to precipitate their silica load in a nearby bed. Eolian quartz has also been suggested as a source of silica for chert beds. Precambrian bedded cherts are common, making up 15% of middle Precambrian sedimentary rock, and may have been deposited nonbiologically in oceans more saturated in silica than

3690-506: Is usually black to green in color, and the full sequence of beds may be several hundred meters thick. The shale is typically black shale, sometimes with pyrite , indicating deposition in an anoxic environment. Bedded chert is most often found in association with turbidites , deep water limestone , submarine volcanic rock , ophiolites , and mélanges on active margins of tectonic plates . Sedimentary structures are rare in bedded cherts. The typically high purity of bedded chert, like

3772-659: The Cretaceous . Diatoms were the dominant siliceous organism responsible for extracting silica from seawater from the Jurassic and later. Radiolarite consists mostly of remains of radiolarians. When the remains are well-cemented with silica, it is known as radiolarian chert . Many show evidence of a deep-water origin, but some appear to have formed in water as shallow as 200 meters (660 ft), perhaps in shelf seas where upwelling of nutrient-rich deep ocean water support high organic productivity. Radiolarians dominated

3854-541: The Phanerozoic as the total volume of chert in the rock record diminished. Bedded chert is rare after the early Mesozoic . Chert became moderately abundant during the Devonian and Carboniferous and again became moderately abundant from the Jurassic to the present. Bedded chert, also known as ribbon chert, takes the form of thinly bedded layers (a few centimeters to a meter in thickness ) of nearly pure chert separated by very thin layers of silica-rich shale . It

3936-474: The evolution of life. About 20% to 25% of sedimentary rock is carbonate rock, and most of this is limestone. The remaining carbonate rock is mostly dolomite , a closely related rock, which contains a high percentage of the mineral dolomite , CaMg(CO 3 ) 2 . Magnesian limestone is an obsolete and poorly-defined term used variously for dolomite, for limestone containing significant dolomite ( dolomitic limestone ), or for any other limestone containing

4018-522: The minerals calcite and aragonite , which are different crystal forms of CaCO 3 . Limestone forms when these minerals precipitate out of water containing dissolved calcium. This can take place through both biological and nonbiological processes, though biological processes, such as the accumulation of corals and shells in the sea, have likely been more important for the last 540 million years. Limestone often contains fossils which provide scientists with information on ancient environments and on

4100-408: The minerals calcite and aragonite , which are different crystal forms of calcium carbonate ( CaCO 3 ). Dolomite , CaMg(CO 3 ) 2 , is an uncommon mineral in limestone, and siderite or other carbonate minerals are rare. However, the calcite in limestone often contains a few percent of magnesium . Calcite in limestone is divided into low-magnesium and high-magnesium calcite, with

4182-496: The Earth's history. Limestone may have been deposited by microorganisms in the Precambrian , prior to 540 million years ago, but inorganic processes were probably more important and likely took place in an ocean more highly oversaturated in calcium carbonate than the modern ocean. Diagenesis is the process in which sediments are compacted and turned into solid rock . During diagenesis of carbonate sediments, significant chemical and textural changes take place. For example, aragonite

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4264-403: The alkaline Lake T'oo'dichi'. Chert may also form from replacement of calcrete in fossil soils ( paleosols ) by silica dissolved from overlying volcanic ash beds. The cryptocrystalline nature of chert, combined with its above average ability to resist weathering, recrystallization and metamorphism has made it an ideal rock for preservation of early life forms. For example: Chert

4346-548: The alkaline lakes of the East African Rift Valley . These lakes are characterized by sodium carbonate brines with very high pH that can contain as much as 2700 ppm silica. Episodes of runoff of fresh water into the lakes lowers the pH and precipitates the unusual sodium silicate minerals magadiite or kenyaite , After burial and diagenesis , these are altered to Magadi-type chert. The Morrison Formation contains Magadi-type chert that may have formed in

4428-657: The beds. This may include the formation of vugs , which are crystal-lined cavities within the limestone. Diagenesis may include conversion of limestone to dolomite by magnesium-rich fluids. There is considerable evidence of replacement of limestone by dolomite, including sharp replacement boundaries that cut across bedding. The process of dolomitization remains an area of active research, but possible mechanisms include exposure to concentrated brines in hot environments ( evaporative reflux ) or exposure to diluted seawater in delta or estuary environments ( Dorag dolomitization ). However, Dorag dolomitization has fallen into disfavor as

4510-435: The biogenic sediment that covers large areas of the deep ocean floor, and which contains the silicon skeletal remains of diatoms , silicoflagellates , and radiolarians . Precambrian cherts are notable for the presence of fossil cyanobacteria . In addition to microfossils , chert occasionally contains macrofossils . However, some chert is devoid of any fossils. Chert varies greatly in color, from white to black, but

4592-480: The bottom with the concave face downwards. This traps a void space that can later be filled by sparite. Geologists use geopetal structures to determine which direction was up at the time of deposition, which is not always obvious with highly deformed limestone formations. The cyanobacterium Hyella balani can bore through limestone; as can the green alga Eugamantia sacculata and the fungus Ostracolaba implexa . Chert Chert ( / tʃ ɜːr t / )

4674-468: The densest limestone to 40% for chalk. The density correspondingly ranges from 1.5 to 2.7 g/cm . Although relatively soft, with a Mohs hardness of 2 to 4, dense limestone can have a crushing strength of up to 180 MPa . For comparison, concrete typically has a crushing strength of about 40 MPa. Although limestones show little variability in mineral composition, they show great diversity in texture. However, most limestone consists of sand-sized grains in

4756-466: The depositional fabric of carbonate rocks. Dunham divides the rocks into four main groups based on relative proportions of coarser clastic particles, based on criteria such as whether the grains were originally in mutual contact, and therefore self-supporting, or whether the rock is characterized by the presence of frame builders and algal mats. Unlike the Folk scheme, Dunham deals with the original porosity of

4838-469: The deposits are highly porous, so that they have a spongelike texture, they are typically described as tufa . Secondary calcite deposited by supersaturated meteoric waters ( groundwater ) in caves is also sometimes described as travertine. This produces speleothems , such as stalagmites and stalactites . Coquina is a poorly consolidated limestone composed of abraded pieces of coral , shells , or other fossil debris. When better consolidated, it

4920-441: The dividing line placed at a composition of 4% magnesium. High-magnesium calcite retains the calcite mineral structure, which is distinct from dolomite. Aragonite does not usually contain significant magnesium. Most limestone is otherwise chemically fairly pure, with clastic sediments (mainly fine-grained quartz and clay minerals ) making up less than 5% to 10% of the composition. Organic matter typically makes up around 0.2% of

5002-406: The earth's oceans are oversaturated with CaCO 3 by a factor of more than six. The failure of CaCO 3 to rapidly precipitate out of these waters is likely due to interference by dissolved magnesium ions with nucleation of calcite crystals, the necessary first step in precipitation. Precipitation of aragonite may be suppressed by the presence of naturally occurring organic phosphates in

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5084-558: The extraction of silica from seawater prior to the Jurassic. Spicularite is chert composed of spicules of glass sponges and other invertebrates. When densely cemented, it is known as spicular chert . They are found in association with glauconite -rich sandstone , black shale , clay -rich limestone , phosphorites , and other nonvolcanic rocks typical of water a few hundred meters deep. Some bedded cherts appear devoid of fossils even under close microscopic examination. Their origin

5166-399: The first refers to the grains and the second to the cement. For example, a limestone consisting mainly of ooids, with a crystalline matrix, would be termed an oosparite. It is helpful to have a petrographic microscope when using the Folk scheme, because it is easier to determine the components present in each sample. Robert J. Dunham published his system for limestone in 1962. It focuses on

5248-419: The flake's bulb of force. When a chert stone is struck against an iron-bearing surface, sparks result. This makes chert an excellent tool for starting fires, and both flint and common chert were used in various types of fire-starting tools, such as tinderboxes , throughout history. A primary historic use of common chert and flint was for flintlock firearms , in which the chert striking a metal plate produces

5330-572: The formation of distinctive minerals from the silica and clay present in the original limestone. Two major classification schemes, the Folk and Dunham, are used for identifying the types of carbonate rocks collectively known as limestone. Robert L. Folk developed a classification system that places primary emphasis on the detailed composition of grains and interstitial material in carbonate rocks . Based on composition, there are three main components: allochems (grains), matrix (mostly micrite), and cement (sparite). The Folk system uses two-part names;

5412-429: The geologic record are called bioherms . Many are rich in fossils, but most lack any connected organic framework like that seen in modern reefs. The fossil remains are present as separate fragments embedded in ample mud matrix. Much of the sedimentation shows indications of occurring in the intertidal or supratidal zones, suggesting sediments rapidly fill available accommodation space in the shelf or platform. Deposition

5494-490: The high purity of other chemically precipitated rock, points to deposition in areas where there is little influx of detrital sediments (such as river water laden with silt and clay particles.) Such impurities as are present include authigenic pyrite and hematite, formed in the sediments after they were deposited, in addition to traces of detrital minerals. Seawater typically contains between 0.01 and 11 parts per million (ppm) of silica, with around 1 ppm being typical. This

5576-484: The kinds of organisms that produced the silica skeletons. Diatomaceous chert consists of beds and lenses of diatomite which were converted during diagenesis into dense, hard chert. Beds of marine diatomaceous chert comprising strata several hundred meters thick have been reported from sedimentary sequences such as the Miocene Monterey Formation of California and occur in rocks as old as

5658-606: The modern ocean. The high degree of silica saturation was due either to intense volcanic activity or to the lack of modern organisms that remove silica from seawater. Nodular chert is most common in limestone but may also be found in shales and sandstones. It is less common in dolomite . Nodular chert in carbonate rocks is found as oval to irregular nodules . These vary in size from powdery quartz particles to nodules several meters in size. The nodules are most typically along bedding planes or stylolite (dissolution) surfaces, where fossil organisms tended to accumulate and provided

5740-410: The ocean basins, but limestone is rarely preserved in continental slope and deep sea environments. The best environments for deposition are warm waters, which have both a high organic productivity and increased saturation of calcium carbonate due to lower concentrations of dissolved carbon dioxide. Modern limestone deposits are almost always in areas with very little silica-rich sedimentation, reflected in

5822-424: The ocean bottom and are buried, forming siliceous ooze that is 30% to 60% silica. Thus, bedded cherts are typically composed mostly of fossil remains of organisms that secrete silica skeletons, which are usually altered by solution and recrystallization. The skeletons of these organisms are composed of opal-A, an amorphous form of silica, lacking long-range crystal structure. This is gradually transformed to opal-CT,

5904-426: The reaction: Fossils are often preserved in exquisite detail as chert. Cementing takes place rapidly in carbonate sediments, typically within less than a million years of deposition. Some cementing occurs while the sediments are still under water, forming hardgrounds . Cementing accelerates after the retreat of the sea from the depositional environment, as rainwater infiltrates the sediment beds, often within just

5986-482: The relative purity of most limestones. Reef organisms are destroyed by muddy, brackish river water, and carbonate grains are ground down by much harder silicate grains. Unlike clastic sedimentary rock, limestone is produced almost entirely from sediments originating at or near the place of deposition. Limestone formations tend to show abrupt changes in thickness. Large moundlike features in a limestone formation are interpreted as ancient reefs , which when they appear in

6068-460: The rock. The Dunham scheme is more useful for hand samples because it is based on texture, not the grains in the sample. A revised classification was proposed by Wright (1992). It adds some diagenetic patterns to the classification scheme. Travertine is a term applied to calcium carbonate deposits formed in freshwater environments, particularly waterfalls , cascades and hot springs . Such deposits are typically massive, dense, and banded. When

6150-411: The same time as the nodule. Calcareous fossils are occasionally present that have been completely silicified. Where chert occurs in chalk or marl , it is usually called flint . Nodular chert is often dark in color. It can have a white weathering rind that is known in archaeology as cortex . Most chert nodules have textures suggesting they were formed by diagenetic replacement, where silica

6232-479: The sediments increases. Chemical compaction takes place by pressure solution of the sediments. This process dissolves minerals from points of contact between grains and redeposits it in pore space, reducing the porosity of the limestone from an initial high value of 40% to 80% to less than 10%. Pressure solution produces distinctive stylolites , irregular surfaces within the limestone at which silica-rich sediments accumulate. These may reflect dissolution and loss of

6314-662: The sediments of the ocean floor abruptly transition from carbonate ooze rich in foraminifera and coccolith remains ( Globigerina ooze) to silicic mud lacking carbonates. In rare cases, turbidites or other silica-rich sediments bury and preserve benthic (deep ocean) carbonate deposits. Ancient benthic limestones are microcrystalline and are identified by their tectonic setting. Fossils typically are foraminifera and coccoliths. No pre-Jurassic benthic limestones are known, probably because carbonate-shelled plankton had not yet evolved. Limestones also form in freshwater environments. These limestones are not unlike marine limestone, but have

6396-533: The water by photosynthesis and thereby decreasing the solubility of calcium carbonate. Limestone shows the same range of sedimentary structures found in other sedimentary rocks. However, finer structures, such as lamination , are often destroyed by the burrowing activities of organisms ( bioturbation ). Fine lamination is characteristic of limestone formed in playa lakes , which lack the burrowing organisms. Limestones also show distinctive features such as geopetal structures , which form when curved shells settle to

6478-553: The water. Although ooids likely form through purely inorganic processes, the bulk of CaCO 3 precipitation in the oceans is the result of biological activity. Much of this takes place on carbonate platforms . The origin of carbonate mud, and the processes by which it is converted to micrite, continue to be a subject of research. Modern carbonate mud is composed mostly of aragonite needles around 5 μm (0.20 mils) in length. Needles of this shape and composition are produced by calcareous algae such as Penicillus , making this

6560-408: The world's oceans. Diatoms can double their numbers eight times a day under ideal conditions (though doubling once per day is more typical in normal seawater) and can extract silica from water with as little as 0.1 ppm silica. The organisms protect their skeletons from dissolution by "armoring" them with metal ions. Once the organisms die, their skeletons will quickly dissolve unless they accumulate on

6642-578: Was deposited in place of calcium carbonate or clay minerals . This may have taken place where meteoric water (water derived from snow or rain) mixed with saltwater in the sediment beds, where carbon dioxide was trapped, producing an environment supersaturated with silica and undersaturated with calcium carbonate. Nodular chert is particularly common in continental shelf environments. In the Permian Basin (North America) , chert nodules and chertified fossils are abundant in basin limestones, but there

6724-416: Was likely deposited in pore space between grains, suggesting a high-energy depositional environment that removed carbonate mud. Recrystallized sparite is not diagnostic of depositional environment. Limestone outcrops are recognized in the field by their softness (calcite and aragonite both have a Mohs hardness of less than 4, well below common silicate minerals) and because limestone bubbles vigorously when

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