An aquarium ( pl. : aquariums or aquaria ) is a vivarium of any size having at least one transparent side in which aquatic plants or animals are kept and displayed. Fishkeepers use aquaria to keep fish , invertebrates , amphibians , aquatic reptiles , such as turtles , and aquatic plants . The term aquarium , coined by English naturalist Philip Henry Gosse , combines the Latin root aqua , meaning 'water', with the suffix -arium , meaning 'a place for relating to'.
126-714: Sea Life Melbourne Aquarium is a Southern Ocean and Antarctic aquarium in central Melbourne , Australia . It is located on the banks of the Yarra River beside and under the Flinders Street Viaduct and the King Street Bridge . The attraction is a Sea Life Centre owned by Merlin Entertainments . The current building was built between February 1998 and December 1999, the building was designed by Peddle Thorp architects to resemble
252-583: A cascade method, Swiss chemist and physicist Raoul Pierre Pictet evaporated liquid sulfur dioxide in order to liquefy carbon dioxide, which in turn was evaporated to cool oxygen gas enough to liquefy it. He sent a telegram on December 22, 1877, to the French Academy of Sciences in Paris announcing his discovery of liquid oxygen . Just two days later, French physicist Louis Paul Cailletet announced his own method of liquefying molecular oxygen. Only
378-539: A legionnaires disease outbreak that resulted in 4 deaths and another 125 people being infected. Those affected had visited the aquarium between 11 and 27 April 2000. A damages action was brought in May 2000, ending in February 2004. On 28 November 2008 Melbourne Aquarium officially reopened after a significant expansion, also designed by Peddle Thorp, and now extends from the Yarra River to Flinders Street . A new entrance
504-472: A saltwater aquarium , though he did not use the term. In 1846, Anne Thynne maintained stony corals and seaweed for almost three years, and was credited as the creator of the first balanced marine aquarium in London. English chemist Robert Warington experimented with a 13-gallon container, which contained goldfish, eelgrass , and snails , creating one of the first stable aquaria. The aquarium principle
630-414: A 400-litre (110 US gal; 88 imp gal) tank with many other fish in it represents only a minor change. For this reason, hobbyists often favor larger tanks, as they require less attention. Several nutrient cycles are important in the aquarium. Dissolved oxygen enters the system at the surface water-air interface. Similarly, carbon dioxide escapes the system into the air. The phosphate cycle
756-1166: A challenge to recreate such environments, and most "true" biotopes will only have a few (if not only one) species of fish and invertebrates. Finally, an emerging concept for the home is that of a wall mounted aquarium, some of which are displayed at the Living Art Marine Center . An aquarium can range from a small glass bowl containing less than 1 litre (2.1 US pt) of water to immense public aquaria that house entire ecosystems such as kelp forests . Relatively large home aquaria resist rapid fluctuations of temperature and pH , allowing for greater system stability. Beginner aquarists are advised to consider larger tanks to begin with, as controlling water parameters in smaller tanks can prove difficult. Small, unfiltered bowl-shaped aquaria are now widely regarded as unsuitable for most fish. In order to keep water conditions at suitable levels, aquariums should contain at least two forms of filtration : biological and mechanical. Chemical filtration should also be considered under some circumstances for optimum water quality. Chemical filtration
882-420: A circular, submerged lid. Pseudokreisels are "U" or semicircle shaped, usually without a lid. Stretch kreisels are a "double gyre" kreisel design, where the tank length is at least twice the height. Using two downwelling inlets on both sides of the tank lets gravity create two gyres in the tank. A single downwelling inlet may be used in the middle as well. The top of a stretch kreisel may be open or closed with
1008-634: A colorless and odorless diatomic gas with the chemical formula O 2 . Dioxygen gas currently constitutes 20.95% molar fraction of the Earth's atmosphere , though this has changed considerably over long periods of time in Earth's history . Oxygen makes up almost half of the Earth's crust in the form of various oxides such as water , carbon dioxide , iron oxides and silicates . All eukaryotic organisms , including plants , animals , fungi , algae and most protists , need oxygen for cellular respiration , which extracts chemical energy by
1134-425: A cooler environment. Temperature consistency is more important than range. Most organisms are not accustomed to sudden changes in temperatures, which can cause shock and lead to disease. Water temperature can be regulated with a thermostat and heater (or cooler). Water movement can also be important in simulating a natural ecosystem. Aquarists may prefer anything from still water up to swift currents , depending on
1260-444: A dazzling aquarium is one of the last surefire ways to impress their peers." A kreisel tank ( kreisel being German for " spinning top " or " gyroscope ") is an aquarium shaped like a horizontal cylinder that is designed to hold delicate animals such as jellyfish and newborn seahorses. These aquariums provide slow, circular water flow with a bare minimum of interior hardware to prevent the inhabitants from becoming injured by pumps or
1386-434: A few drops of the liquid were produced in each case and no meaningful analysis could be conducted. Oxygen was liquefied in a stable state for the first time on March 29, 1883, by Polish scientists from Jagiellonian University , Zygmunt Wróblewski and Karol Olszewski . In 1891 Scottish chemist James Dewar was able to produce enough liquid oxygen for study. The first commercially viable process for producing liquid oxygen
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#17327901989081512-399: A lid. There may also be screens about midway down the sides of the tank, or at the top on the sides. It is possible to combine these designs; a circular shaped tank is used without a lid or cover, and the surface of the water acts as the continuation of circular flow. Another popular setup is the biotope aquarium. A biotope aquarium is a recreation of a specific natural environment. Some of
1638-481: A light sky-blue color caused by absorption in the red (in contrast with the blue color of the sky, which is due to Rayleigh scattering of blue light). High-purity liquid O 2 is usually obtained by the fractional distillation of liquefied air. Liquid oxygen may also be condensed from air using liquid nitrogen as a coolant. Liquid oxygen is a highly reactive substance and must be segregated from combustible materials. The spectroscopy of molecular oxygen
1764-564: A major role in absorbing energy from singlet oxygen and converting it to the unexcited ground state before it can cause harm to tissues. The common allotrope of elemental oxygen on Earth is called dioxygen , O 2 , the major part of the Earth's atmospheric oxygen (see Occurrence ). O 2 has a bond length of 121 pm and a bond energy of 498 kJ/mol . O 2 is used by complex forms of life, such as animals, in cellular respiration . Other aspects of O 2 are covered in
1890-514: A natural water source (such as a river, lake, or ocean) to reduce the level of treatment. Some hobbyists use an algae scrubber to filter the water naturally. Water temperature determines the two most basic aquarium classifications: tropical versus cold water . Most fish and plant species tolerate only a limited temperature range; tropical aquaria, with an average temperature of about 25 °C (77 °F), are much more common. Temperate or coldwater aquaria are for fish that are better suited to
2016-438: A part of air that he called spiritus nitroaereus . In one experiment, he found that placing either a mouse or a lit candle in a closed container over water caused the water to rise and replace one-fourteenth of the air's volume before extinguishing the subjects. From this, he surmised that nitroaereus is consumed in both respiration and combustion. Mayow observed that antimony increased in weight when heated, and inferred that
2142-433: A popular choice for many home and hobbyist aquarists for many years. Once silicone sealant became strong enough to ensure a long-term water-tight seal, it eliminated the need for a structural frame. In addition to lower cost, glass aquaria are more scratch resistant than acrylic. Although the price is one of the main considerations for aquarists when deciding which of these two types of aquaria to purchase, for very large tanks,
2268-404: A process called eutrophication and the decay of these organisms and other biomaterials may reduce the O 2 content in eutrophic water bodies. Scientists assess this aspect of water quality by measuring the water's biochemical oxygen demand , or the amount of O 2 needed to restore it to a normal concentration. Paleoclimatologists measure the ratio of oxygen-18 and oxygen-16 in
2394-468: A ship moored to the river, and opened in January 2000. The depth of the building however was designed not to be imposing at street level, and extends 7 metres (23 ft) below the surface. At its centre is a world first 2,200,000-litre (580,000 US gal) 'oceanarium in the round' where the spectators become the spectacle to the marine life swimming around them. Soon after opening, the building had
2520-465: A small glass bowl, a few liters in volume, to immense public aquaria of thousands of liters. Specialized equipment maintains appropriate water quality and other characteristics suitable for the aquarium's residents. In 1369, the Hongwu Emperor of China established a porcelain company that produced large porcelain tubs for maintaining goldfish ; over time, people produced tubs that approached
2646-458: A small proportion of manganese dioxide. Oxygen levels in the atmosphere are trending slightly downward globally, possibly because of fossil-fuel burning. At standard temperature and pressure , oxygen is a colorless, odorless, and tasteless gas with the molecular formula O 2 , referred to as dioxygen. As dioxygen , two oxygen atoms are chemically bound to each other. The bond can be variously described based on level of theory, but
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#17327901989082772-401: A tank by diluting effects from death or contamination events that push an aquarium away from equilibrium. The bigger the tank, the easier such a systemic shock is to absorb, because the effects of that event are diluted. For example, the death of the only fish in an 11-litre (3 US gal; 2 imp gal) tank causes dramatic changes in the system, while the death of that same fish in
2898-449: A triplet electronic ground state . An electron configuration with two unpaired electrons, as is found in dioxygen orbitals (see the filled π* orbitals in the diagram) that are of equal energy—i.e., degenerate —is a configuration termed a spin triplet state. Hence, the ground state of the O 2 molecule is referred to as triplet oxygen . The highest-energy, partially filled orbitals are antibonding , and so their filling weakens
3024-449: A tropical temperature and requires less capacity from an aquarium heater. Acrylic-soluble cements are used to directly fuse acrylic together. Acrylic allows for the formation of unusual shapes, such as the hexagonal tank. Acrylics are easier to scratch than glass, but unlike glass, scratches in acrylic can be polished out. Large aquaria might instead use stronger materials such as fiberglass -reinforced plastics . However, this material
3150-532: Is a chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table , a highly reactive nonmetal , and a potent oxidizing agent that readily forms oxides with most elements as well as with other compounds . Oxygen is the most abundant element in Earth's crust , and the third-most abundant element in the universe after hydrogen and helium . At standard temperature and pressure , two oxygen atoms will bind covalently to form dioxygen ,
3276-431: Is an important, although often overlooked, nutrient cycle. Sulfur, iron, and micronutrients also cycle through the system, entering as food and exiting as waste. Appropriate handling of the nitrogen cycle , along with supplying an adequately balanced food supply and considered biological loading, is enough to keep these other nutrient cycles in approximate equilibrium. An aquarium must be maintained regularly to ensure that
3402-513: Is associated with the atmospheric processes of aurora and airglow . The absorption in the Herzberg continuum and Schumann–Runge bands in the ultraviolet produces atomic oxygen that is important in the chemistry of the middle atmosphere. Excited-state singlet molecular oxygen is responsible for red chemiluminescence in solution. Table of thermal and physical properties of oxygen (O 2 ) at atmospheric pressure: Naturally occurring oxygen
3528-472: Is composed of three stable isotopes , O , O , and O , with O being the most abundant (99.762% natural abundance ). Most O is synthesized at the end of the helium fusion process in massive stars but some is made in the neon burning process . O is primarily made by the burning of hydrogen into helium during the CNO cycle , making it a common isotope in the hydrogen burning zones of stars. Most O
3654-436: Is frequently achieved via activated carbon , to filter medications, tannins , and/or other known impurities from the water. Reef aquaria under 100 litres (26 US gal; 22 imp gal) have a special place in the aquarium hobby; these aquaria, termed nano reefs (when used in reefkeeping), have a small water volume, under 40 litres (11 US gal; 9 imp gal). Practical limitations, most notably
3780-614: Is keeping them in a wall. Here the use of plywood is hidden by sinking the aquarium inside the wall. Putting insulation between the two helps with the insulation of a heated tank. Objects used for aquariums include: coffee tables, sinks, and even toilets. Another such example is the MacQuarium , an aquarium made from the shell of an Apple Macintosh computer . In recent years, elaborate custom-designed home aquariums costing hundreds of thousands of dollars have become status symbols—according to The New York Times , "among people of means,
3906-409: Is most often addressed through two filtration solutions: Activated carbon filters absorb nitrogen compounds and other toxins , while biological filters provide a medium designed to enhance bacterial colonization . Activated carbon and other substances, such as ammonia absorbing resins, stop working when their pores fill, so these components have to be replaced regularly. Oxygen Oxygen
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4032-471: Is not transparent. Reinforced concrete is used for aquaria where weight and space are not factors. Concrete must be coated with a waterproof layer to prevent the water from breaking down the concrete, as well as preventing contamination of the water by the concrete. Plywood can also be used when building aquaria. The benefits of using plywood include: lower construction costs, less weight, and better insulation. A popular positioning choice for plywood aquaria
4158-630: Is often given for Priestley because his work was published first. Priestley, however, called oxygen "dephlogisticated air", and did not recognize it as a chemical element. The name oxygen was coined in 1777 by Antoine Lavoisier , who first recognized oxygen as a chemical element and correctly characterized the role it plays in combustion. Common industrial uses of oxygen include production of steel , plastics and textiles , brazing, welding and cutting of steels and other metals , rocket propellant , oxygen therapy , and life support systems in aircraft , submarines , spaceflight and diving . One of
4284-478: Is only a portion of the complete cycle: nitrogen must be added to the system (usually through food provided to the tank inhabitants), and nitrates accumulate in the water at the end of the process, or become bound in the biomass of plants. The aquarium keeper must remove water once nitrate concentrations grow, or remove plants which have grown from the nitrates. Hobbyist aquaria often do not have sufficient bacteria populations to adequately denitrify waste. This problem
4410-441: Is produced when N (made abundant from CNO burning) captures a He nucleus, making O common in the helium-rich zones of evolved, massive stars . Fifteen radioisotopes have been characterized, ranging from O to O. The most stable are O with a half-life of 122.24 seconds and O with a half-life of 70.606 seconds. All of the remaining radioactive isotopes have half-lives that are less than 27 seconds and
4536-408: Is reasonably and simply described as a covalent double bond that results from the filling of molecular orbitals formed from the atomic orbitals of the individual oxygen atoms, the filling of which results in a bond order of two. More specifically, the double bond is the result of sequential, low-to-high energy, or Aufbau , filling of orbitals, and the resulting cancellation of contributions from
4662-459: Is released as a byproduct . Oxygen is too chemically reactive to remain a free element in air without being continuously replenished by the photosynthetic activities of autotrophs such as cyanobacteria , chloroplast -bearing algae and plants. A much rarer triatomic allotrope of oxygen , ozone ( O 3 ), strongly absorbs the UVB and UVC wavelengths and forms a protective ozone layer at
4788-712: Is temperature-dependent, and about twice as much ( 14.6 mg/L ) dissolves at 0 °C than at 20 °C ( 7.6 mg/L ). At 25 °C and 1 standard atmosphere (101.3 kPa ) of air, freshwater can dissolve about 6.04 milliliters (mL) of oxygen per liter , and seawater contains about 4.95 mL per liter. At 5 °C the solubility increases to 9.0 mL (50% more than at 25 °C) per liter for freshwater and 7.2 mL (45% more) per liter for sea water. Oxygen condenses at 90.20 K (−182.95 °C, −297.31 °F) and freezes at 54.36 K (−218.79 °C, −361.82 °F). Both liquid and solid O 2 are clear substances with
4914-518: Is the most basic measure of water conditions. An aquarium may have freshwater (salinity below 500 parts per million), simulating a lake or river environment; brackish water (a salt level of 500 to 30,000 PPM), simulating environments lying between fresh and salt, such as estuaries ; and salt water or seawater (a salt level of 30,000 to 40,000 PPM), simulating an ocean environment. Rarely, higher salt concentrations are maintained in specialized tanks for raising brine organisms. Saltwater
5040-435: Is the result of the oxygen cycle . This biogeochemical cycle describes the movement of oxygen within and between its three main reservoirs on Earth: the atmosphere, the biosphere, and the lithosphere . The main driving factor of the oxygen cycle is photosynthesis , which is responsible for modern Earth's atmosphere. Photosynthesis releases oxygen into the atmosphere, while respiration , decay , and combustion remove it from
5166-415: Is to have very small aquariums, termed mini aquariums (less than 150 litres or 40 gallons) or nano aquariums (less than 75 litres or 20 gallons). These can be either freshwater or saltwater, and are intended to display a tiny but self-contained ecosystem. The typical hobbyist aquarium includes a filtration system, an artificial lighting system, an air diffuser and pump, and a heater or chiller depending on
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5292-499: Is toxic to fish in high concentrations. Another type of bacteria (genus Nitrospira ) converts nitrite into nitrate , a less toxic substance. ( Nitrobacter bacteria were previously believed to fill this role. While biologically they could theoretically fill the same niche as Nitrospira , it has recently been found that Nitrobacter are not present in detectable levels in established aquaria, while Nitrospira are plentiful.) However, commercial products sold as kits to "jump start"
5418-463: Is unusual among the planets of the Solar System in having such a high concentration of oxygen gas in its atmosphere: Mars (with 0.1% O 2 by volume) and Venus have much less. The O 2 surrounding those planets is produced solely by the action of ultraviolet radiation on oxygen-containing molecules such as carbon dioxide. The unusually high concentration of oxygen gas on Earth
5544-541: Is usually alkaline, while the pH ( alkalinity or acidity ) of fresh water varies more. Hardness measures overall dissolved mineral content; hard or soft water may be preferred. Hard water is usually alkaline, while soft water is usually neutral to acidic. Dissolved organic content and dissolved gases content are also important factors. Home aquarists typically use tap water supplied through their local water supply network to fill their tanks. Straight tap water cannot be used in localities that pipe chlorinated water. In
5670-522: Is usually given priority in the discovery. The French chemist Antoine Laurent Lavoisier later claimed to have discovered the new substance independently. Priestley visited Lavoisier in October 1774 and told him about his experiment and how he liberated the new gas. Scheele had also dispatched a letter to Lavoisier on September 30, 1774, which described his discovery of the previously unknown substance, but Lavoisier never acknowledged receiving it (a copy of
5796-618: The Earth , the Moon , Mars , and meteorites , but were long unable to obtain reference values for the isotope ratios in the Sun , believed to be the same as those of the primordial solar nebula . Analysis of a silicon wafer exposed to the solar wind in space and returned by the crashed Genesis spacecraft has shown that the Sun has a higher proportion of oxygen-16 than does the Earth. The measurement implies that an unknown process depleted oxygen-16 from
5922-826: The Great Exhibition of 1851. In 1853, the aquarium craze was launched in England by Philip Henry Gosse who created and stocked the first public aquarium in the London Zoo which came to be known as the Fish House. Gosse coined the word "aquarium", opting for this term (instead of "aquatic vivarium" or "aqua-vivarium") in 1854 in his book The Aquariums: An Unveiling of the Wonders of the Deep Water . In this book, Gosse primarily discussed saltwater aquaria. In
6048-565: The Greek roots ὀξύς (oxys) ( acid , literally 'sharp', from the taste of acids) and -γενής (-genēs) (producer, literally begetter), because he mistakenly believed that oxygen was a constituent of all acids. Chemists (such as Sir Humphry Davy in 1812) eventually determined that Lavoisier was wrong in this regard, but by then the name was too well established. Oxygen entered the English language despite opposition by English scientists and
6174-680: The Sea Life Centres brand as well as iconic brands such as Legoland and Madame Tussauds , purchased the Living and Leisure Group, then the owner-operators of the Melbourne Aquarium. In late 2013, after an extensive $ 8 million investment and redevelopment by Merlin Entertainments, the aquarium relaunched under the Sea Life brand, joining up to 100 Merlin-owned attractions worldwide. Aquarium The aquarium principle
6300-554: The Victorian era in the United Kingdom, a common design for the home aquarium was a glass front with the other sides made of wood (made watertight with a pitch coating). The bottom would be made of slate and heated from below. More advanced systems soon began to be introduced, along with tanks of glass in metal frames. During the latter half of the 19th century, a variety of aquarium designs were explored, such as hanging
6426-611: The aquascaping designs of Takashi Amano influencing fishkeepers to treat home aquariums as aesthetically pleasing compositions, rather than simply as a way of displaying fish specimens. In the United States, as of 1996, aquarium keeping is the second-most popular hobby after stamp collecting . In 1999, an estimated 9.6 million US households owned an aquarium. Figures from the 2005/2006 APPMA National Pet Owners Survey report that Americans own approximately 139 million freshwater fish and 9.6 million saltwater fish. Estimates of
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#17327901989086552-484: The blood and carbon dioxide out, and the body's circulatory system then transports the oxygen to other tissues where cellular respiration takes place. However in insects , the most successful and biodiverse terrestrial clade , oxygen is directly conducted to the internal tissues via a deep network of airways . Many major classes of organic molecules in living organisms contain oxygen atoms, such as proteins , nucleic acids , carbohydrates and fats , as do
6678-447: The gravel , or other substrate if the aquarium has one; however some manage to avoid this entirely by keeping it somewhat self-sufficient. A good habit is to remove the water being replaced by "vacuuming" the gravel with suitable implements, as this will eliminate uneaten foods and other residues that settle on the substrate . In many areas tap water is not considered to be safe for fish to live in because it contains chemicals that harm
6804-481: The nitrogen cycle or be removed by passing through zeolite . Ammonia is also produced through the decomposition of plant and animal matter, including fecal matter and other detritus . Nitrogen waste products become toxic to fish and other aquarium inhabitants at high concentrations. In the wild, the vast amount of water surrounding the fish dilutes ammonia and other waste materials. When fish are put into an aquarium, waste can quickly reach toxic concentrations in
6930-465: The reaction of oxygen with organic molecules derived from food and releases carbon dioxide as a waste product. In aquatic animals , dissolved oxygen in water is absorbed by specialized respiratory organs called gills , through the skin or via the gut ; in terrestrial animals such as tetrapods , oxygen in air is actively taken into the body via specialized organs known as lungs , where gas exchange takes place to diffuse oxygen into
7056-470: The shells and skeletons of marine organisms to determine the climate millions of years ago (see oxygen isotope ratio cycle ). Seawater molecules that contain the lighter isotope , oxygen-16, evaporate at a slightly faster rate than water molecules containing the 12% heavier oxygen-18, and this disparity increases at lower temperatures. During periods of lower global temperatures, snow and rain from that evaporated water tends to be higher in oxygen-16, and
7182-430: The thermal decomposition of potassium nitrate . In Bugaj's view, the isolation of oxygen and the proper association of the substance to that part of air which is required for life, provides sufficient evidence for the discovery of oxygen by Sendivogius. This discovery of Sendivogius was however frequently denied by the generations of scientists and chemists which succeeded him. It is also commonly claimed that oxygen
7308-661: The weight of water (1 kilogram per litre (8.345 lb/U.S. gal; 10.022 lb/imp gal)) and internal water pressure (requiring thick glass siding) of a large aquarium, restrict most home aquaria to a maximum of around 1 cubic metre in volume (1000 L, weighing 1,000 kg or 2,200 lb ). Some aquarists, however, have constructed aquaria of many thousands of litres. Public aquariums and oceanariums designed for exhibition of large species or environments can be dramatically larger than any home aquarium. The Georgia Aquarium , for example, features an individual aquarium of 6,300,000 US gallons (24,000,000 L). A new trend
7434-557: The 17th and the 18th century but none of them recognized it as a chemical element . This may have been in part due to the prevalence of the philosophy of combustion and corrosion called the phlogiston theory , which was then the favored explanation of those processes. Established in 1667 by the German alchemist J. J. Becher , and modified by the chemist Georg Ernst Stahl by 1731, phlogiston theory stated that all combustible materials were made of two parts. One part, called phlogiston,
7560-429: The 1850s, the aquarium became a fad in the United Kingdom. Tank designs and techniques for maintaining water quality were developed by Warington, later cooperating with Gosse until his critical review of the tank water composition. Edward Edwards developed these glass-fronted aquaria in his 1858 patent for a "dark-water-chamber slope-back tank", with water slowly circulating to a reservoir beneath. Germans soon rivaled
7686-520: The 1960s, metal frames made marine aquaria almost impossible due to corrosion, but the development of tar and silicone sealant allowed the first all-glass aquaria made by Martin Horowitz in Los Angeles, CA. The frames remained, however, though purely for aesthetic reasons. Japan played an increasingly important role in shaping aquarium design in the latter part of the twentieth century, with
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#17327901989087812-531: The 2.2 million litre Mermaid Garden oceanarium, which features a grey nurse shark and sandbar whaler sharks, along with up to 2,000 marine creatures of diverse species. Sea Life Melbourne Aquarium conducts extensive research into marine species, with the Aquarium's conservation efforts overseen by the Turtle Rehabilitation and Conservation of Keystone Species (T.R.A.C.K.S.) group, a subsidiary of
7938-531: The 2s electrons, after sequential filling of the low σ and σ orbitals; σ overlap of the two atomic 2p orbitals that lie along the O–O molecular axis and π overlap of two pairs of atomic 2p orbitals perpendicular to the O–O molecular axis, and then cancellation of contributions from the remaining two 2p electrons after their partial filling of the π orbitals. This combination of cancellations and σ and π overlaps results in dioxygen's double-bond character and reactivity, and
8064-536: The American scientist Robert H. Goddard became the first person to develop a rocket engine that burned liquid fuel; the engine used gasoline for fuel and liquid oxygen as the oxidizer . Goddard successfully flew a small liquid-fueled rocket 56 m at 97 km/h on March 16, 1926, in Auburn, Massachusetts , US. In academic laboratories, oxygen can be prepared by heating together potassium chlorate mixed with
8190-649: The British in their interest. In 1854, an anonymous author had two articles published about the saltwater aquaria of the United Kingdom: Die Gartenlaube (The Garden House) entitled Der Ocean auf dem Tische (The Ocean on the Table). However, in 1856, Der See im Glase (The Lake in a Glass) was published, discussing freshwater aquaria, which were much easier to maintain in landlocked areas. In 1862 William Alford Lloyd , then bankrupt because of
8316-484: The Philosopher's Stone drawn from the source of nature and manual experience"] (1604) described a substance contained in air, referring to it as 'cibus vitae' (food of life, ) and according to Polish historian Roman Bugaj, this substance is identical with oxygen. Sendivogius, during his experiments performed between 1598 and 1604, properly recognized that the substance is equivalent to the gaseous byproduct released by
8442-606: The Sea Life Conservation Trust. Sea Life Melbourne Aquarium formerly had a giant squid exhibit (frozen, not alive), which was moved to UnderWater World in Queensland. The Aquarium was also home to angler fish , the Japanese spider crab , jellyfish , blood sucking leeches , horseshoe crabs , venomous scorpions and tarantulas . In 2012, Merlin Entertainments , the global owner and operator of
8568-438: The Sun's disk of protoplanetary material prior to the coalescence of dust grains that formed the Earth. Oxygen presents two spectrophotometric absorption bands peaking at the wavelengths 687 and 760 nm . Some remote sensing scientists have proposed using the measurement of the radiance coming from vegetation canopies in those bands to characterize plant health status from a satellite platform. This approach exploits
8694-659: The Wonders of the Deep Sea in 1854. Small aquariums are kept in the home by hobbyists . There are large public aquariums in many cities. Public aquariums keep fish and other aquatic animals in large tanks. A large aquarium may have otters , dolphins , sharks , penguins , seals , and whales . Many aquarium tanks also have plants. An aquarist owns fish or maintains an aquarium, typically constructed of glass or high-strength acrylic . Aquaria with flat walls are known as fish tanks or simply tanks, while those with rounded walls are known as fish bowls . Size can range from
8820-482: The addition of a commercially available mixture of salts and other minerals. Some aquarists modify water's alkalinity, hardness, or dissolved content of organics and gases, before adding it to their aquaria. This can be accomplished by additives, such as sodium bicarbonate, to raise pH. Some aquarists filter or purify their water through deionization or reverse osmosis prior to using it. In contrast, public aquaria with large water needs often locate themselves near
8946-548: The aquarium on a wall, mounting it as part of a window , or even combining it with a birdcage . Around 1908, the first mechanical aquarium air pump was invented, powered by running water, instead of electricity. The introduction of the air pump into the hobby is considered by several historians of the hobby to be a pivotal moment in its development. Aquaria became more widely popular as houses had an electricity supply after World War I . Electricity allowed artificial lighting, as well as aeration , filtration , and heating of
9072-505: The aquarium's inhabitants. Many aquaria incorporate a hood, containing the lights, to decrease evaporation and prevent fish from leaving the aquarium (and anything else from entering the aquarium). Combined biological and mechanical aquarium filtration systems are common. These either convert ammonia to nitrate (removing nitrogen at the expense of aquatic plants), or to sometimes remove phosphate . Filter media can house microbes that mediate nitrification . Filtration systems are sometimes
9198-491: The aquarium's inhabitants. Water movement can be controlled via aeration from air pumps, powerheads, and careful design of internal water flow (such as location of filtration system points of inflow and outflow). Of primary concern to the aquarist is management of the waste produced by an aquarium's inhabitants. Fish, invertebrates, fungi , and some bacteria excrete nitrogen waste in the form of ammonia (which converts to ammonium , in water) and must then either pass through
9324-547: The aquarium. According to the July issue of The North American Review of the same year, William Stimson may have owned some of the first functional aquaria, and had as many as seven or eight. The first aquarist society in the United States was founded in New York City in 1893, followed by others. The New York Aquarium Journal , first published in October 1876, is considered to be the world's first aquarium magazine. In
9450-493: The atmosphere. In the present equilibrium, production and consumption occur at the same rate. Free oxygen also occurs in solution in the world's water bodies. The increased solubility of O 2 at lower temperatures (see Physical properties ) has important implications for ocean life, as polar oceans support a much higher density of life due to their higher oxygen content. Water polluted with plant nutrients such as nitrates or phosphates may stimulate growth of algae by
9576-460: The behavior and survival of tank inhabitants. An aquarium can be placed on an aquarium stand. Because of the weight of the aquarium, a stand must be strong as well as level. A tank that is not level may distort, leak, or crack. These are often built with cabinets to allow storage, available in many styles to match room decor . Simple metal tank stands are also available. Most aquaria should be placed on polystyrene to cushion any irregularities on
9702-412: The bond order from three to two. Because of its unpaired electrons, triplet oxygen reacts only slowly with most organic molecules, which have paired electron spins; this prevents spontaneous combustion. In the triplet form, O 2 molecules are paramagnetic . That is, they impart magnetic character to oxygen when it is in the presence of a magnetic field, because of the spin magnetic moments of
9828-529: The craze in England being over, moved to Grindel Dammthor, Hamburg, to supervise the installation of the circulating system and tanks at the Hamburg Aquarium . During the 1870s, some of the first aquarist societies were appearing in Germany. The United States soon followed. Published in 1858, Henry D. Butler's The Family Aquarium was one of the first books written in the United States solely about
9954-444: The diatomic elemental molecules in those gases. The first commercial method of producing oxygen was chemical, the so-called Brin process involving a reversible reaction of barium oxide . It was invented in 1852 and commercialized in 1884, but was displaced by newer methods in early 20th century. By the late 19th century scientists realized that air could be liquefied and its components isolated by compressing and cooling it. Using
10080-466: The electron spins are paired. It is much more reactive with common organic molecules than is normal (triplet) molecular oxygen. In nature, singlet oxygen is commonly formed from water during photosynthesis, using the energy of sunlight. It is also produced in the troposphere by the photolysis of ozone by light of short wavelength and by the immune system as a source of active oxygen. Carotenoids in photosynthetic organisms (and possibly animals) play
10206-421: The enclosed environment unless the tank is cycled to remove waste. A well-balanced tank contains organisms that are able to metabolize the waste products of other aquarium residents, recreating a portion of the nitrogen cycle . Bacteria known as nitrifiers (genus Nitrosomonas ) metabolize nitrogen waste. Nitrifying bacteria capture ammonia from the water and metabolize it to produce nitrite . Nitrite
10332-572: The fact that the Englishman Priestley had first isolated the gas and written about it. This is partly due to a poem praising the gas titled "Oxygen" in the popular book The Botanic Garden (1791) by Erasmus Darwin , grandfather of Charles Darwin . John Dalton 's original atomic hypothesis presumed that all elements were monatomic and that the atoms in compounds would normally have the simplest atomic ratios with respect to one another. For example, Dalton assumed that water's formula
10458-399: The first known experiments on the relationship between combustion and air was conducted by the 2nd century BCE Greek writer on mechanics, Philo of Byzantium . In his work Pneumatica , Philo observed that inverting a vessel over a burning candle and surrounding the vessel's neck with water resulted in some water rising into the neck. Philo incorrectly surmised that parts of the air in
10584-557: The first person to create aquaria for experimenting with aquatic organisms. This experimentation lead to several discoveries, including the first direct evidence that argonauts , a marine cephalopod, create their own shells. In 1836, soon after his invention of the Wardian case , Dr. Nathaniel Bagshaw Ward proposed to use his tanks for tropical animals. In 1841 he did so, though only with aquatic plants and toy fish. However, he soon housed real animals. In 1838, Félix Dujardin noted owning
10710-416: The fish are kept healthy. Daily maintenance consists of checking the fish for signs of stress and disease . Also, aquarists must make sure that the water has a good quality and it is not cloudy or foamy and the temperature of the water is appropriate for the particular species of fish that live in the aquarium. Typical weekly maintenance includes changing around 10–30% or more of the water while cleaning
10836-594: The fish. Tap water from those areas must be treated with a suitable water conditioner, such as a product which removes chlorine and chloramine and neutralizes any heavy metals present. The water conditions must be checked both in the tank and in the replacement water, to make sure they are suitable for the species. The solute content of water is perhaps the most important aspect of water conditions, as total dissolved solids and other constituents dramatically impact basic water chemistry, and therefore how organisms interact with their environment. Salt content, or salinity ,
10962-473: The glass panels attached with metal frames and sealed with putty. Metal-framed aquariums were still available until the mid-1960s, when the modern, silicone-sealed style replaced them. Acrylic aquariums first became available to the public in the 1970s. Laminated glass is sometimes used, which combines the advantages of both glass and acrylic. Today, most aquaria consist of glass panes bonded together by 100% silicone sealant, with plastic frames attached to
11088-399: The idea; instead, it was based on observations of what happens when something burns, that most common objects appear to become lighter and seem to lose something in the process. Polish alchemist , philosopher , and physician Michael Sendivogius (Michał Sędziwój) in his work De Lapide Philosophorum Tractatus duodecim e naturae fonte et manuali experientia depromti ["Twelve Treatises on
11214-504: The letter was found in Scheele's belongings after his death). Lavoisier conducted the first adequate quantitative experiments on oxidation and gave the first correct explanation of how combustion works. He used these and similar experiments, all started in 1774, to discredit the phlogiston theory and to prove that the substance discovered by Priestley and Scheele was a chemical element . In one experiment, Lavoisier observed that there
11340-562: The lower stratosphere , which shields the biosphere from ionizing ultraviolet radiation . However, ozone present at the surface is a corrosive byproduct of smog and thus an air pollutant . Oxygen was isolated by Michael Sendivogius before 1604, but it is commonly believed that the element was discovered independently by Carl Wilhelm Scheele , in Uppsala , in 1773 or earlier, and Joseph Priestley in Wiltshire , in 1774. Priority
11466-423: The major constituent inorganic compounds of animal shells, teeth, and bone. Most of the mass of living organisms is oxygen as a component of water, the major constituent of lifeforms. Oxygen in Earth's atmosphere is produced by biotic photosynthesis , in which photon energy in sunlight is captured by chlorophyll to split water molecules and then react with carbon dioxide to produce carbohydrates and oxygen
11592-428: The majority of these have half-lives that are less than 83 milliseconds. The most common decay mode of the isotopes lighter than O is β decay to yield nitrogen, and the most common mode for the isotopes heavier than O is beta decay to yield fluorine . Oxygen is the most abundant chemical element by mass in the Earth's biosphere , air, sea and land. Oxygen is the third most abundant chemical element in
11718-678: The most complex component of home aquaria. Aquarium heaters combine a heating element with a thermostat , allowing the aquarist to regulate water temperature at a level above that of the surrounding air, whereas coolers and chillers (refrigeration devices) are for use anywhere, such as cold water aquaria, where the ambient room temperature is above the desired tank temperature. Thermometers used include glass alcohol thermometers, adhesive external plastic strip thermometers , and battery-powered LCD thermometers. In addition, some aquarists use air pumps attached to airstones or water pumps to increase water circulation and supply adequate gas exchange at
11844-716: The most popular biotopes are the freshwater habitats of the Amazon River , the Rio Negro River, the African rift lake environments of Lake Malawi and Lake Tanganyika , and saltwater coral reefs of Australia , the Red Sea , and the Caribbean Sea . The fish, plants, substrate, rocks, wood, coral, and any other component of the display should completely match that of the local natural environment. It can be
11970-494: The nitroaereus must have combined with it. He also thought that the lungs separate nitroaereus from air and pass it into the blood and that animal heat and muscle movement result from the reaction of nitroaereus with certain substances in the body. Accounts of these and other experiments and ideas were published in 1668 in his work Tractatus duo in the tract "De respiratione". Robert Hooke , Ole Borch , Mikhail Lomonosov , and Pierre Bayen all produced oxygen in experiments in
12096-539: The nitrogen cycle often still contain Nitrobacter . Aquatic plants also eliminate nitrogen waste by metabolizing ammonia and nitrate. When plants metabolize nitrogen compounds, they remove nitrogen from the water by using it to build biomass that decays more slowly than ammonia-driven plankton already dissolved in the water. Some hobbyists also use "anoxic filtration," which relies on bacteria that live in low-oxygen environments. The nitrogen cycle in an aquarium
12222-484: The numbers of fish kept in aquaria in Germany suggest at least 36 million. The hobby has the strongest following in Europe, Asia, and North America. In the United States, 40% of aquarists maintain two or more tanks. Over time, there has been an increasing appreciation of the usefulness of access to an aquarium to provide potential stress reduction and improvement of mood in people observing aquatic life. According to
12348-410: The past, it was possible to "condition" the water by simply letting the water stand for a day or two, which allows the chlorine time to dissipate. However, chloramine is now used more often and does not leave the water as readily. Water conditioners formulated to remove chlorine or chloramine are often all that is needed to make the water ready for aquarium use. Brackish or saltwater aquaria require
12474-428: The price difference tends to disappear. Acrylic aquaria are now the primary competitor with glass. Prior to the invention of UV stabilization , early acrylic aquaria discolored over time with exposure to light; this is no longer the case. Acrylic is generally stronger than glass, weighs less, and provides a certain amount of temperature insulation. In colder climates or environments, it is easier to achieve and maintain
12600-594: The refurbishment of the facilities. As part of the process, the aquarium was rebranded as a Sea Life Centre and relaunched in September 2013. The current Aquarium succeeded an earlier site in the Eastern annex of the Royal Exhibition Building , which burned down in 1953. The Aquarium has a one-way self-guided tour, which is spread over four levels: The aquarium is known for its main exhibit,
12726-458: The remainder of this article. Trioxygen ( O 3 ) is usually known as ozone and is a very reactive allotrope of oxygen that is damaging to lung tissue. Ozone is produced in the upper atmosphere when O 2 combines with atomic oxygen made by the splitting of O 2 by ultraviolet (UV) radiation. Since ozone absorbs strongly in the UV region of the spectrum , the ozone layer of
12852-532: The research of having an aquarium is many health benefits like reduce stress, blood pressure and heart rate improvement, better quality sleep , reduce anxiety and pain , therapy of excited children, Alzheimer's therapy and improve productivity . The first modern aquarium made of glass was developed in the 19th century by Robert Warrington. During the Victorian age , glass aquariums commonly had slate or steel bottoms, which allowed them to be heated underneath by an open-flame heat source. These aquariums had
12978-414: The seawater left behind tends to be higher in oxygen-18. Marine organisms then incorporate more oxygen-18 into their skeletons and shells than they would in a warmer climate. Paleoclimatologists also directly measure this ratio in the water molecules of ice core samples as old as hundreds of thousands of years. Planetary geologists have measured the relative quantities of oxygen isotopes in samples from
13104-486: The shape of modern fish bowls. Leonhard Baldner , who wrote Vogel-, Fisch- und Tierbuch (Bird, Fish, and Animal Book) in 1666, maintained weather loaches and newts . It is sometimes held that the aquarium was invented by the Romans, who are said to have kept sea barbels in marble-and-glass tanks, but scholars doubt the veracity of this. In 1832, Jeanne Villepreux-Power , a pioneering French marine biologist, became
13230-399: The tank itself. The tank has no sharp angles around its sides and keeps the housed animals away from plumbing. Water moving into the tank gives a gentle flow that keeps the inhabitants suspended. Water leaves the tank through a screen which prevents animals from being drawn into the pump intake or overflow line. There are several types of kreisel tanks. In a true kreisel, a circular tank has
13356-579: The underlying surface or the bottom of the tank itself that may cause cracks. However, some tanks have an underframe making this unnecessary. Another important consideration for aquariums is their electrical usage. Water is expensive to keep heated, along with the lights that many aquariums, especially those with live plants have. New aquarists should also pay close attention to their electrical setup for their aquarium, taking care to set up power connections with drip loops to prevent water from getting to outlets. Large volumes of water enable more stability in
13482-486: The universe, after hydrogen and helium. About 0.9% of the Sun 's mass is oxygen. Oxygen constitutes 49.2% of the Earth's crust by mass as part of oxide compounds such as silicon dioxide and is the most abundant element by mass in the Earth's crust . It is also the major component of the world's oceans (88.8% by mass). Oxygen gas is the second most common component of the Earth's atmosphere , taking up 20.8% of its volume and 23.1% of its mass (some 10 tonnes). Earth
13608-401: The unpaired electrons in the molecule, and the negative exchange energy between neighboring O 2 molecules. Liquid oxygen is so magnetic that, in laboratory demonstrations, a bridge of liquid oxygen may be supported against its own weight between the poles of a powerful magnet. Singlet oxygen is a name given to several higher-energy species of molecular O 2 in which all
13734-580: The upper and lower edges for decoration. The glass aquarium is standard for sizes up to about 1,000 litres (260 US gal; 220 imp gal). However, glass is brittle and has very little give before fracturing, though generally the sealant fails first. Aquaria are made in a variety of shapes, such as cuboid , hexagonal , angled to fit in a corner (L-shaped), and bow-front (the front side curves outwards). Fish bowls are generally either made of plastic or glass, and are either spherical or some other round configuration in shape. Glass aquaria have been
13860-435: The upper atmosphere functions as a protective radiation shield for the planet. Near the Earth's surface, it is a pollutant formed as a by-product of automobile exhaust . At low earth orbit altitudes, sufficient atomic oxygen is present to cause corrosion of spacecraft . The metastable molecule tetraoxygen ( O 4 ) was discovered in 2001, and was assumed to exist in one of the six phases of solid oxygen . It
13986-451: The vessel were converted into the classical element fire and thus were able to escape through pores in the glass. Many centuries later Leonardo da Vinci built on Philo's work by observing that a portion of air is consumed during combustion and respiration . In the late 17th century, Robert Boyle proved that air is necessary for combustion. English chemist John Mayow (1641–1679) refined this work by showing that fire requires only
14112-400: The water surface. Wave-making devices have also been constructed to provide wave action. An aquarium's physical characteristics form another aspect of aquarium design. Size, lighting conditions, density of floating and rooted plants, placement of bog-wood , creation of caves or overhangs, type of substrate , and other factors (including an aquarium's positioning within a room) can all affect
14238-611: The water. Initially, amateur aquarists kept native fish (with the exception of goldfish); the availability of exotic species from overseas further increased the popularity of the aquarium. Jugs made from a variety of materials were used to import fish from overseas, with a bicycle foot pump for aeration. Plastic shipping bags were introduced in the 1950s, making it easier to ship fish. The eventual availability of air freight allowed fish to be successfully imported from distant regions. Popular publications started by Herbert R. Axelrod influenced many more hobbyists to start keeping fish. In
14364-428: Was HO, leading to the conclusion that the atomic mass of oxygen was 8 times that of hydrogen, instead of the modern value of about 16. In 1805, Joseph Louis Gay-Lussac and Alexander von Humboldt showed that water is formed of two volumes of hydrogen and one volume of oxygen; and by 1811 Amedeo Avogadro had arrived at the correct interpretation of water's composition, based on what is now called Avogadro's law and
14490-580: Was built on the corner of Flinders and King Streets. The expansion features exhibits with king penguins and gentoo penguins , as well as many Antarctic fish, a first for Australia. The exhibits also feature real ice and snow to simulate Antarctic conditions, and take visitors on an expedition to Antarctica. The penguins were sourced from Kelly Tarlton's Underwater World in New Zealand . In April 2013, Melbourne Aquarium's owners, Merlin Entertainments , announced that they would be spending $ 8 million on
14616-408: Was first discovered by Swedish pharmacist Carl Wilhelm Scheele . He had produced oxygen gas by heating mercuric oxide (HgO) and various nitrates in 1771–72. Scheele called the gas "fire air" because it was then the only known agent to support combustion. He wrote an account of this discovery in a manuscript titled Treatise on Air and Fire , which he sent to his publisher in 1775. That document
14742-505: Was fully developed by Warington, explaining that plants added to water in a container would give off enough oxygen to support animals, so long as their numbers do not grow too large. He published his findings in 1850 in the Chemical Society's journal . The keeping of fish in an aquarium became a popular hobby and spread quickly. In the United Kingdom, it became popular after ornate aquaria in cast-iron frames were featured at
14868-443: Was fully developed in 1850 by the chemist Robert Warington , who explained that plants added to water in a container would give off enough oxygen to support animals, so long as the numbers of animals did not grow too large. The aquarium craze was launched in early Victorian England by Gosse, who created and stocked the first public aquarium at the London Zoo in 1853, and published the first manual, The Aquarium: An Unveiling of
14994-451: Was given off when the substance containing it was burned, while the dephlogisticated part was thought to be its true form, or calx . Highly combustible materials that leave little residue , such as wood or coal, were thought to be made mostly of phlogiston; non-combustible substances that corrode, such as iron, contained very little. Air did not play a role in phlogiston theory, nor were any initial quantitative experiments conducted to test
15120-491: Was independently developed in 1895 by German engineer Carl von Linde and British engineer William Hampson . Both men lowered the temperature of air until it liquefied and then distilled the component gases by boiling them off one at a time and capturing them separately. Later, in 1901, oxyacetylene welding was demonstrated for the first time by burning a mixture of acetylene and compressed O 2 . This method of welding and cutting metal later became common. In 1923,
15246-445: Was no overall increase in weight when tin and air were heated in a closed container. He noted that air rushed in when he opened the container, which indicated that part of the trapped air had been consumed. He also noted that the tin had increased in weight and that increase was the same as the weight of the air that rushed back in. This and other experiments on combustion were documented in his book Sur la combustion en général , which
15372-465: Was not sensibly different from that of common air , but I fancied that my breast felt peculiarly light and easy for some time afterwards." Priestley published his findings in 1775 in a paper titled "An Account of Further Discoveries in Air", which was included in the second volume of his book titled Experiments and Observations on Different Kinds of Air . Because he published his findings first, Priestley
15498-408: Was proven in 2006 that this phase, created by pressurizing O 2 to 20 GPa , is in fact a rhombohedral O 8 cluster . This cluster has the potential to be a much more powerful oxidizer than either O 2 or O 3 and may therefore be used in rocket fuel . A metallic phase was discovered in 1990 when solid oxygen is subjected to a pressure of above 96 GPa and it
15624-449: Was published in 1777. In the meantime, on August 1, 1774, an experiment conducted by the British clergyman Joseph Priestley focused sunlight on mercuric oxide contained in a glass tube, which liberated a gas he named "dephlogisticated air". He noted that candles burned brighter in the gas and that a mouse was more active and lived longer while breathing it. After breathing the gas himself, Priestley wrote: "The feeling of it to my lungs
15750-462: Was published in 1777. In that work, he proved that air is a mixture of two gases; 'vital air', which is essential to combustion and respiration, and azote (Gk. ἄζωτον "lifeless"), which did not support either. Azote later became nitrogen in English, although it has kept the earlier name in French and several other European languages. Lavoisier renamed 'vital air' to oxygène in 1777 from
15876-420: Was shown in 1998 that at very low temperatures, this phase becomes superconducting . Oxygen dissolves more readily in water than nitrogen, and in freshwater more readily than in seawater. Water in equilibrium with air contains approximately 1 molecule of dissolved O 2 for every 2 molecules of N 2 (1:2), compared with an atmospheric ratio of approximately 1:4. The solubility of oxygen in water
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