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89-431: Prior to oil production from a new reservoir, volumetric methods are used to estimate oil-in-place. A series of test drills are used to map the rock conditions at and around the drilling site and to estimate the size of the oil-bearing rock field. The oil in place is calculated as the product of the volume of porous oil-bearing rock, the porosity of the rock, and its saturation. Correction factors have to be applied for

178-449: A day (bod). In other circumstances, it can be important to include gas in production and consumption figures. Normally, gas amount is measured in standard cubic feet or standard cubic metres (for volume at STP), as well as in kg or Btu (which do not depend on pressure or temperature). But when necessary, such volume is converted to a volume of oil of equivalent enthalpy of combustion. Production and consumption using this analogue

267-514: A different volume at different pressures and temperatures. A standard barrel in this context is thus not simply a measure of volume, but of volume under specific conditions. ( See also: Standard temperature and pressure#Molar volume of a gas . ) Oil companies that are publicly listed in the United States typically report their production using the unit multiples Mbbl (one thousand barrels) and MMbbl (one million barrels), derived from

356-520: A fluid resembling petroleum, which when treated in the same way as the seep oil gave similar products. Young found that by slow distillation he could obtain several useful liquids from it, one of which he named "paraffine oil" because at low temperatures it congealed into a substance resembling paraffin wax. The production of these oils and solid paraffin wax from coal formed the subject of his patent dated October 17, 1850. In 1850, Young & Meldrum and Edward William Binney entered into partnership under

445-512: A much shallower level. The Athabasca oil sands are one example of this. An alternative mechanism to the one described above was proposed by Russian scientists in the mid-1850s, the hypothesis of abiogenic petroleum origin (petroleum formed by inorganic means), but this is contradicted by geological and geochemical evidence. Abiogenic sources of oil have been found, but never in commercially profitable amounts. "The controversy isn't over whether abiogenic oil reserves exist," said Larry Nation of

534-545: A physical container rather than a known measure. In the international oil market context, however, prices in United States dollars per barrel are commonly used, and the term is variously translated, often to derivations of the Latin / Teutonic root fat (for example vat or Fass ). In other commercial connections, barrel sizes such as beer keg volumes also are standardised in many countries. Some products have

623-476: A process known as catagenesis . Formation of petroleum occurs from hydrocarbon pyrolysis in a variety of mainly endothermic reactions at high temperatures or pressures, or both. These phases are described in detail below. In the absence of plentiful oxygen, aerobic bacteria were prevented from decaying the organic matter after it was buried under a layer of sediment or water. However, anaerobic bacteria were able to reduce sulfates and nitrates among

712-430: A region or country. One common term is barrels per day (BPD, BOPD, bbl/d, bpd, bd, or b/d), where 1 BPD is equivalent to 0.0292  gallons per minute . One BPD also becomes 49.8 tonnes per year. At an oil refinery, production is sometimes reported as barrels per calendar day (b/cd or bcd), which is total production in a year divided by the days in that year. Likewise, barrels per stream day (BSD or BPSD)

801-449: A set of parallel reactions, and oil eventually breaks down to natural gas by another set of reactions. The latter set is regularly used in petrochemical plants and oil refineries . Barrel (unit)#Oil barrel A barrel is one of several units of volume applied in various contexts; there are dry barrels , fluid barrels (such as the U.K. beer barrel and U.S. beer barrel ), oil barrels , and so forth. For historical reasons

890-665: A significant amount of petroleum while drilling for lignite in Wietze , Germany. Wietze later provided about 80% of German consumption in the Wilhelminian Era. The production stopped in 1963, but Wietze has hosted a Petroleum Museum since 1970. Oil sands have been mined since the 18th century. In Wietze in lower Saxony, natural asphalt/bitumen has been explored since the 18th century. Both in Pechelbronn as in Wietze,

979-535: A similar volume of water to maintain reservoir pressure. Outside the United States, volumes of oil are usually reported in cubic metres (m ) instead of oil barrels. Cubic metre is the basic volume unit in the International System . In Canada, oil companies measure oil in cubic metres, but convert to barrels on export, since most of Canada's oil production is exported to the US. The nominal conversion factor

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1068-574: A source of internal and inter-state conflict, leading to both state-led wars and other resource conflicts . Production of petroleum is estimated to reach peak oil before 2035 as global economies lower dependencies on petroleum as part of climate change mitigation and a transition towards renewable energy and electrification . The word petroleum comes from Medieval Latin petroleum (literally 'rock oil'), which comes from Latin petra 'rock' (from Greek pétra πέτρα ) and oleum 'oil' (from Greek élaion ἔλαιον ). The origin of

1157-469: A standard barrel of oil to a standard cubic metre of oil is complicated by the fact that the latter is defined by the API to mean the amount of oil that, at different reference conditions (101.325  kPa and 15 °C (59.0 °F)), occupies 1 cubic metre. The fact that the refence conditions are not exactly the same means that an exact conversion is impossible unless the exact expansion coefficient of

1246-481: A standard weight or volume that constitutes a barrel: Fluid barrels vary depending on what is being measured and where. In the UK a beer barrel is 36 imperial gallons (43  US gal ; 164  L ). In the US most fluid barrels (apart from oil) are 31.5 US gallons (26 imp gal; 119 L) (half a hogshead ), but a beer barrel is 31 US gallons (26 imp gal; 117 L). The size of beer kegs in

1335-413: A symbol for "blue barrels" delivered by Standard Oil in its early days. However, while Ida Tarbell's 1904 Standard Oil Company history acknowledged the "holy blue barrel", the abbreviation "bbl" had been in use well before the 1859 birth of the U.S. petroleum industry. Oil wells recover not just oil from the ground, but also natural gas and water. The term barrels of liquid per day (BLPD) refers to

1424-415: A variety of different containers was causing buyer distrust. They decided they needed a standard unit of measure to convince buyers that they were getting a fair volume for their money, and settled on the standard wine tierce , which was two gallons larger than the standard whisky barrel. The Weekly Register , an Oil City, Pennsylvania newspaper, stated on August 31, 1866 that "the oil producers have issued

1513-411: A variety of liquid, gaseous, and solid components. Lighter hydrocarbons are the gases methane , ethane , propane and butane . Otherwise, the bulk of the liquid and solids are largely heavier organic compounds, often hydrocarbons (C and H only). The proportion of light hydrocarbons in the petroleum mixture varies among oil fields . An oil well produces predominantly crude oil. Because the pressure

1602-526: A visit to Fort Duquesne in 1750. Early British explorers to Myanmar documented a flourishing oil extraction industry based in Yenangyaung that, in 1795, had hundreds of hand-dug wells under production. Merkwiller-Pechelbronn is said to be the first European site where petroleum has been explored and used. The still active Erdpechquelle, a spring where petroleum appears mixed with water has been used since 1498, notably for medical purposes. There

1691-530: A wine tierce as holding 42 wine gallons. Custom had made the 42 gallon watertight tierce a standard container for shipping eel, salmon, herring, molasses, wine, whale oil, and many other commodities in the English colonies by 1700. After the American Revolution in 1776, American merchants continued to use the same size barrels. In the oil industry , one barrel ( unit symbol bbl )

1780-554: A year before Drake's Pennsylvania operation and could be argued to be the first commercial oil well in North America. The discovery at Oil Springs touched off an oil boom which brought hundreds of speculators and workers to the area. Advances in drilling continued into 1862 when local driller Shaw reached a depth of 62 metres using the spring-pole drilling method. On January 16, 1862, after an explosion of natural gas , Canada's first oil gusher came into production, shooting into

1869-687: Is 1 cubic metre = 6.2898 oil barrels, but conversion is generally done by custody transfer meters on the border, since the volumes are specified at different temperatures, and the exact conversion factor depends on both density and temperature. Canadian companies operate internally and report to Canadian governments in cubic metres, but often convert to US barrels for the benefit of American investors and oil marketers. They generally quote prices in Canadian dollars per cubic metre to other Canadian companies, but use US dollars per barrel in financial reports and press statements, making it appear to

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1958-549: Is a unit of volume used for measuring oil defined as exactly 42 US gallons , approximately 159 liters, or 35 imperial gallons . According to the American Petroleum Institute (API), a standard barrel of oil is the amount of oil that would occupy a volume of exactly 1 barrel (158.99 L) at reference temperature and pressure conditions of 60 °F (15.6 °C) and 14.696  psi (1,013.25  hPa ). This standard barrel of oil will occupy

2047-442: Is a naturally occurring yellowish-black liquid mixture. It consists mainly of hydrocarbons , and is found in geological formations . The term petroleum refers both to naturally occurring unprocessed crude oil, as well as to petroleum products that consist of refined crude oil. Conventional reserves of petroleum are primarily recovered by drilling , which is done after a study of the relevant structural geology , analysis of

2136-491: Is called diagenesis , a word that means a transformation of materials by dissolution and recombination of their constituents. Kerogen formation continued to a depth of about 1 km from the Earth's surface where temperatures may reach around 50 °C . Kerogen formation represents a halfway point between organic matter and fossil fuels : kerogen can be exposed to oxygen, oxidize and thus be lost, or it could be buried deeper inside

2225-726: Is considered a sticky, black, tar-like form of crude oil which is so thick and heavy that it must be heated or diluted before it will flow. Venezuela also has large amounts of oil in the Orinoco oil sands , although the hydrocarbons trapped in them are more fluid than in Canada and are usually called extra heavy oil . These oil sands resources are called unconventional oil to distinguish them from oil which can be extracted using traditional oil well methods. Between them, Canada and Venezuela contain an estimated 3.6 trillion barrels (570 × 10 ^  m ) of bitumen and extra-heavy oil, about twice

2314-487: Is converted to the associated volume at surface conditions. Oil in place must not be confused with oil reserves , that are the technically and economically recoverable portion of oil volume in the reservoir. Current recovery factors for oil fields around the world typically range between 10 and 60 percent; some are over 80 percent. The wide variance is due largely to the diversity of fluid and reservoir characteristics for different deposits. Petroleum Petroleum

2403-473: Is lower at the surface than underground, some of the gas will come out of solution and be recovered (or burned) as associated gas or solution gas . A gas well produces predominantly natural gas . However, because the underground temperature is higher than at the surface, the gas may contain heavier hydrocarbons such as pentane, hexane , and heptane (" natural-gas condensate ", often shortened to condensate. ) Condensate resembles gasoline in appearance and

2492-756: Is now called the Drake Well in Cherrytree Township, Pennsylvania .There also was a company associated with it, and it sparked a major oil drilling boom. The first commercial oil well in Canada became operational in 1858 at Oil Springs, Ontario (then Canada West ). Businessman James Miller Williams dug several wells between 1855 and 1858 before discovering a rich reserve of oil four metres below ground. Williams extracted 1.5 million litres of crude oil by 1860, refining much of it into kerosene lamp oil. Williams's well became commercially viable

2581-451: Is similar in composition to some volatile light crude oils . The hydrocarbons in crude oil are mostly alkanes , cycloalkanes and various aromatic hydrocarbons , while the other organic compounds contain nitrogen , oxygen , and sulfur , and traces of metals such as iron, nickel, copper and vanadium . Many oil reservoirs contain live bacteria. The exact molecular composition of crude oil varies widely from formation to formation but

2670-420: Is stated in barrels of oil equivalent per day (boed). In the case of water-injection wells, in the United States it is common to refer to the injectivity rate in barrels of water per day (bwd). In Canada, it is measured in cubic metres per day (m /d). In general, water injection rates will be stated in the same units as oil production rates, since the usual objective is to replace the volume of oil produced with

2759-492: Is the quantity of oil product produced by a single refining unit during continuous operation for 24 hours. Burning one tonne of light, synthetic, or heavy crude yields 38.51, 39.40, or 40.90 GJ (thermal) respectively (10.70, 10.94, or 11.36 MW·h), so 1 tonne per day of synthetic crude is about 456 kW of thermal power and 1 bpd of synthetic crude is about 378 kW (slightly less for light crude, slightly more for heavy crude). The task of converting

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2848-473: Is used in manufacturing a vast variety of materials essential for modern life, and it is estimated that the world consumes about 100 million barrels (16 million cubic metres ) each day. Petroleum production played a key role in industrialization and economic development. Some countries, known as petrostates , gained significant economic and international power over their control of oil production and trade. Petroleum exploitation can be damaging to

2937-407: Is used to disambiguate it from the capital M used for thousand. In an effort to avoid the ambiguity around Mbbl, the unit kbbl (one thousand barrels) is also sometimes used. The first "b" in "bbl" may have been doubled originally to indicate the plural (1 bl, 2 bbl), or possibly it was doubled to eliminate any confusion with bl as a symbol for the bale . Some sources assert that "bbl" originated as

3026-480: Is used to refer to the total natural gas in a reservoir. Furthermore, there is a term called Hydrocarbons Initially in Place (HCIIP) that is used for either oil or gas. Similar to OIP, HCIIP is calculated using measures of the total reservoirs volume correcting for the non reservoir rock, the porosity and the water saturation in this pore space. Lastly the volume at reservoir conditions (high pressures and temperatures)

3115-674: The Earth's crust and be subjected to conditions which allow it to slowly transform into fossil fuels like petroleum. The latter happened through catagenesis in which the reactions were mostly radical rearrangements of kerogen. These reactions took thousands to millions of years and no external reactants were involved. Due to the radical nature of these reactions, kerogen reacted towards two classes of products: those with low H/C ratio ( anthracene or products similar to it) and those with high H/C ratio ( methane or products similar to it); i.e., carbon-rich or hydrogen-rich products. Because catagenesis

3204-490: The Orinoco Belt . While significant volumes of oil are extracted from oil sands, particularly in Canada, logistical and technical hurdles remain, as oil extraction requires large amounts of heat and water, making its net energy content quite low relative to conventional crude oil. Thus, Canada's oil sands are not expected to provide more than a few million barrels per day in the foreseeable future. Petroleum consists of

3293-745: The Soviet Union in total output. In 1973 , Saudi Arabia and other Arab nations imposed an oil embargo against the United States, United Kingdom, Japan and other Western nations which supported Israel in the Yom Kippur War of October 1973. The embargo caused an oil crisis . This was followed by the 1979 oil crisis , which was caused by a drop in oil production in the wake of the Iranian Revolution and caused oil prices to more than double. The two oil price shocks had many short- and long-term effects on global politics and

3382-478: The United States , but is responsible for only one percent of electricity generation. Petroleum's worth as a portable, dense energy source powering the vast majority of vehicles and as the base of many industrial chemicals makes it one of the world's most important commodities . The top three oil-producing countries as of 2018 are the United States, Russia , and Saudi Arabia . In 2018, due in part to developments in hydraulic fracturing and horizontal drilling ,

3471-455: The actinomycetales order of bacteria also produced antibiotic compounds (e.g., streptomycin ). Thus the action of anaerobic bacteria ceased at about 10 m below the water or sediment. The mixture at this depth contained fulvic acids, unreacted and partially reacted fats and waxes, slightly modified lignin , resins and other hydrocarbons. As more layers of organic matter settled into the sea or lake bed, intense heat and pressure built up in

3560-585: The 12th century. It has also been present in Romania since the 13th century, being recorded as păcură. Sophisticated oil pits, 4.5 to 6 metres (15 to 20 ft) deep, were dug by the Seneca people and other Iroquois in Western Pennsylvania as early as 1415–1450. The French General Louis-Joseph de Montcalm encountered Seneca using petroleum for ceremonial fires and as a healing lotion during

3649-510: The 42-US-gallon (159 L) barrels (based on the old English wine measure), the tierce (159 litres) and the 40-US-gallon (150 L) whiskey barrels were used. Also, 45-US-gallon (170 L) barrels were in common use. The 40 gallon whiskey barrel was the most common size used by early oil producers, since they were readily available at the time. Around 1866, early oil producers in Pennsylvania concluded that shipping oil in

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3738-503: The American Association of Petroleum Geologists. "The controversy is over how much they contribute to Earth's overall reserves and how much time and effort geologists should devote to seeking them out." Three conditions must be present for oil reservoirs to form: The reactions that produce oil and natural gas are often modeled as first order breakdown reactions, where hydrocarbons are broken down to oil and natural gas by

3827-455: The Earth's surface. Unusual magma intrusions, however, could have created greater localized heating. Geologists often refer to the temperature range in which oil forms as an "oil window" . Below the minimum temperature oil remains trapped in the form of kerogen. Above the maximum temperature the oil is converted to natural gas through the process of thermal cracking . Sometimes, oil formed at extreme depths may migrate and become trapped at

3916-701: The Latin word "mille" and Roman Numeral M, meaning "thousand", which is similar to how the US finance industry commonly refers to one million dollars as $ 1MM. This is different from the SI convention where "M" stands for "mega" representing million, from the Greek for "large". Some international companies, particularly those based in Europe, use kb (kilobarrels, one thousand barrels), mb (megabarrels, one million barrels), and gb (gigabarrels, one billion barrels). The lower case m

4005-487: The Petroleum Producers Association in 1872 and by the U.S. Geological Survey and the U.S. Bureau of Mines in 1882. In modern times, many different types of oil, chemicals, and other products are transported in steel drums . In the United States, these commonly have a capacity of 55 US gallons (208 L) and are referred to as such. They are called 200 litre or 200 kg drums outside

4094-586: The Soviet Union included the goal to capture the Baku oilfields , as it would provide much-needed oil supplies for the German military which was suffering from blockades. Oil exploration in North America during the early 20th century later led to the U.S. becoming the leading producer by mid-century. As petroleum production in the U.S. peaked during the 1960s, the United States was surpassed by Saudi Arabia and

4183-438: The US is based loosely on fractions of the US beer barrel. When referring to beer barrels or kegs in many countries, the term may be used for the commercial package units independent of actual volume, where common range for professional use is 20–60  L , typically a DIN or Euro keg of 50 L. Richard III , King of England from 1483 until 1485, had defined the wine puncheon as a cask holding 84  wine gallons and

4272-576: The United States became the world's largest producer. About 80 percent of the world's readily accessible reserves are located in the Middle East , with 62.5 percent coming from the Arab five: Saudi Arabia , United Arab Emirates , Iraq , Qatar , and Kuwait . A large portion of the world's total oil exists as unconventional sources, such as bitumen in Athabasca oil sands and extra heavy oil in

4361-500: The United States. In the United Kingdom and its former dependencies, a 44-imperial-gallon (200 L) drum was used, even though all those countries now officially use the metric system and the drums are filled to 200 litres. In the United States, the 42 US-gallon size as a unit of measure is largely confined to the oil industry, while different sizes of barrel are used in other industries. Nearly all other countries use

4450-627: The air at a recorded rate of 480 cubic metres (3,000 bbl) per day. By the end of the 19th century the Russian Empire, particularly the Branobel company in Azerbaijan , had taken the lead in production. Access to oil was and still is a major factor in several military conflicts of the 20th century, including World War II , during which oil facilities were a major strategic asset and were extensively bombed . The German invasion of

4539-551: The area around modern Baku , Azerbaijan . These fields were described by the Persian geographer Abu Bakr al-Razi in the 10th century, and by Marco Polo in the 13th century, who described the output of those wells as hundreds of shiploads. Arab and Persian chemists also distilled crude oil to produce flammable products for military purposes. Through Islamic Spain , distillation became available in Western Europe by

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4628-466: The barrel or package, but by the gallon only. An allowance of two gallons will be made on the gauge of each and every 40 gallons in favor of the buyer. And by that means, King Richard III's English wine tierce became the American standard oil barrel. By 1872, the standard oil barrel was firmly established as 42 US-gallons. The 42 gallon standard oil barrel was officially adopted by

4717-474: The coal industry dominated the petroleum technologies. Chemist James Young in 1847 noticed a natural petroleum seepage in the coal mine at riddings Alfreton , Derbyshire from which he distilled a light thin oil suitable for use as lamp oil, at the same time obtaining a more viscous oil suitable for lubricating machinery. In 1848, Young set up a small business refining crude oil. Young eventually succeeded, by distilling cannel coal at low heat, in creating

4806-613: The conversion is usually between 6 and 8 barrels (954 and 1,270 litres; 252 and 336 US gallons) per tonne. The measurement of an "oil barrel" originated in the early Pennsylvania oil fields . The Drake Well , the first oil well in the US, was drilled in Pennsylvania in 1859, and an oil boom followed in the 1860s. When oil production began, there was no standard container for oil, so oil and petroleum products were stored and transported in barrels of different shapes and sizes. Some of these barrels would originally have been used for other products, such as beer, fish, molasses, or turpentine. Both

4895-418: The crude is known, and this will vary from one crude oil to another. For a light oil with density of 850 kilogram per cubic metre ( API gravity of 35), warming the oil from 59 °F (15 °C) to 60 °F (16 °C) might increase its volume by about 0.047%. Conversely, a heavy oil with a density of 934 kg/m (API gravity of 20) might only increase in volume by 0.039%. If physically measuring

4984-421: The density at a new temperature is not possible, then tables of empirical data can be used to accurately predict the change in density. In turn, this allows maximum accuracy when converting between standard barrel and standard cubic metre. The logic above also implies the same level of accuracy in measurements for barrels if there is a 1 °F (0.56 °C) error in measuring the temperature at time of measuring

5073-444: The difference between the volume of the same mass of oil in the reservoir to its volume when brought to the surface, which is caused by the different physical conditions (temperature, pressure) there. Oil-in-place is also known as stock tank original oil-in-place ( STOOIP ) or stock tank oil-initially-in-place ( STOIIP ), referring to the oil in place before the commencement of production. In this case, stock tank barrels refers to

5162-573: The earliest Chinese writings, cites that oil in its raw state, without refining, was first discovered, extracted, and used in China in the first century BCE. In addition, the Chinese were the first to record the use of petroleum as fuel as early as the fourth century BCE. By 347 CE, oil was produced from bamboo-drilled wells in China. In the 7th century, petroleum was among the essential ingredients for Greek fire , an incendiary projectile weapon that

5251-469: The environment and human health. Extraction , refining and burning of petroleum fuels all release large quantities of greenhouse gases , so petroleum is one of the major contributors to climate change . Other negative environmental effects include direct releases, such as oil spills , as well as air and water pollution at almost all stages of use. These environmental effects have direct and indirect health consequences for humans. Oil has also been

5340-425: The fact that it happened at relatively low temperatures (when compared to commercial pyrolysis plants) of 60 to several hundred °C. Pyrolysis was possible because of the long reaction times involved. Heat for catagenesis came from the decomposition of radioactive materials of the crust, especially K , Th , U and U . The heat varied with geothermal gradient and was typically 10–30 °C per km of depth from

5429-464: The fluids being measured varies along the stream, sometimes qualifiers are used to clarify what is being specified. In the oil field, it is often important to differentiate between rates of production of fluids, which may be a mix of oil and water, and rates of production of the oil itself. If a well is producing 10 MBD (millions of barrels per day) of fluids with a 20% water cut, then the well would also be said to be producing 8,000 barrels of oil

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5518-428: The following circular": Whereas, It is conceded by all producers of crude petroleum on Oil Creek that the present system of selling crude oil by the barrel, without regard to the size, is injurious to the oil trade, alike to the buyer and seller, as buyers, with an ordinary sized barrel cannot compete with those with large ones. We, therefore, mutually agree and bind ourselves that from this date we will sell no crude by

5607-751: The global economy. They led to sustained reductions in demand as a result of substitution to other fuels, especially coal and nuclear, and improvements in energy efficiency , facilitated by government policies. High oil prices also induced investment in oil production by non-OPEC countries, including Prudhoe Bay in Alaska, the North Sea offshore fields of the United Kingdom and Norway, the Cantarell offshore field of Mexico, and oil sands in Canada. About 90 percent of vehicular fuel needs are met by oil. Petroleum also makes up 40 percent of total energy consumption in

5696-408: The heavier end of the range, paraffin wax is an alkane with approximately 25 carbon atoms, while asphalt has 35 and up, although these are usually cracked in modern refineries into more valuable products. The lightest fraction, the so-called petroleum gases are subjected to diverse processing depending on cost. These gases are either flared off , sold as liquefied petroleum gas , or used to power

5785-605: The invention of the modern kerosene lamp (1853), the introduction of the first modern street lamp in Europe (1853), and the construction of the world's first modern oil "mine" (1854). at Bóbrka , near Krosno (still operational as of 2020). The demand for petroleum as a fuel for lighting in North America and around the world quickly grew. The first oil well in the Americas was drilled in 1859 by Edwin Drake at what

5874-446: The large number of co-eluted hydrocarbons within oil, many cannot be resolved by traditional gas chromatography. This unresolved complex mixture (UCM) of hydrocarbons is particularly apparent when analysing weathered oils and extracts from tissues of organisms exposed to oil. Crude oil varies greatly in appearance depending on its composition. It is usually black or dark brown (although it may be yellowish, reddish, or even greenish). In

5963-411: The lower regions. As a consequence, compounds of this mixture began to combine in poorly understood ways to kerogen . Combination happened in a similar fashion as phenol and formaldehyde molecules react to urea-formaldehyde resins, but kerogen formation occurred in a more complex manner due to a bigger variety of reactants. The total process of kerogen formation from the beginning of anaerobic decay

6052-899: The matter to H 2 S and N 2 respectively by using the matter as a source for other reactants. Due to such anaerobic bacteria, at first, this matter began to break apart mostly via hydrolysis : polysaccharides and proteins were hydrolyzed to simple sugars and amino acids respectively. These were further anaerobically oxidized at an accelerated rate by the enzymes of the bacteria: e.g., amino acids went through oxidative deamination to imino acids , which in turn reacted further to ammonia and α-keto acids . Monosaccharides in turn ultimately decayed to CO 2 and methane . The anaerobic decay products of amino acids, monosaccharides, phenols and aldehydes combined into fulvic acids . Fats and waxes were not extensively hydrolyzed under these mild conditions. Some phenolic compounds produced from previous reactions worked as bactericides and

6141-618: The outside world that they operate in barrels. Companies on the European stock exchanges report the mass of oil in tonnes . Since different varieties of petroleum have different densities, however, there is not a single conversion between mass and volume. For example, one tonne of heavy distillates might occupy a volume of 6.1 barrels (970 litres ; 256 US gallons ). In contrast, one tonne of crude oil might occupy 6.5 barrels (1,030 litres; 273 US gallons), and one tonne of gasoline will require 7.9 barrels (1,260 litres; 332 US gallons). Overall,

6230-556: The proportion of chemical elements varies over fairly narrow limits as follows: Four different types of hydrocarbon appear in crude oil. The relative percentage of each varies from oil to oil, determining the properties of each oil. The alkanes from pentane (C 5 H 12 ) to octane (C 8 H 18 ) are refined into gasoline, the ones from nonane (C 9 H 20 ) to hexadecane (C 16 H 34 ) into diesel fuel , kerosene and jet fuel . Alkanes with more than 16 carbon atoms can be refined into fuel oil and lubricating oil . At

6319-644: The refinery's own burners. During the winter, butane (C 4 H 10 ), is blended into the gasoline pool at high rates, because its high vapour pressure assists with cold starts. The aromatic hydrocarbons are unsaturated hydrocarbons that have one or more benzene rings . They tend to burn with a sooty flame, and many have a sweet aroma. Some are carcinogenic . These different components are separated by fractional distillation at an oil refinery to produce gasoline, jet fuel, kerosene, and other hydrocarbon fractions. The components in an oil sample can be determined by gas chromatography and mass spectrometry . Due to

6408-412: The reservoir it is usually found in association with natural gas, which being lighter forms a "gas cap" over the petroleum, and saline water which, being heavier than most forms of crude oil, generally sinks beneath it. Crude oil may also be found in a semi-solid form mixed with sand and water, as in the Athabasca oil sands in Canada, where it is usually referred to as crude bitumen . In Canada, bitumen

6497-518: The same time the world's first, small, oil refinery was opened at Jasło in Poland (then Austria), with a larger one opened at Ploiești in Romania shortly after. Romania (then being a vassal of the Ottoman empire) is the first country in the world to have had its annual crude oil output officially recorded in international statistics: 275 tonnes for 1857. In 1858, Georg Christian Konrad Hunäus found

6586-523: The second half of the 19th century, the term became commonly known for the liquid form of hydrocarbons. Petroleum, in one form or another, has been used since ancient times. More than 4300 years ago, bitumen was mentioned when the Sumerians used it to make boats. A tablet of the legend of the birth of Sargon of Akkad mentions a basket which was closed by straw and bitumen. More than 4000 years ago, according to Herodotus and Diodorus Siculus , asphalt

6675-665: The sedimentary basin , and characterization of the petroleum reservoir . There are also unconventional reserves such as oil sands and oil shale which are recovered by other means such as fracking . Once extracted, oil is refined and separated, most easily by distillation , into innumerable products for direct use or use in manufacturing. Products include fuels such as gasoline (petrol), diesel , kerosene and jet fuel ; asphalt and lubricants ; chemical reagents used to make plastics ; solvents , textiles , refrigerants , paint , synthetic rubber , fertilizers , pesticides , pharmaceuticals , and thousands of others. Petroleum

6764-408: The term stems from monasteries in southern Italy where it was in use by the end of the first millennium as an alternative for the older term " naphtha ". After that, the term was used in numerous manuscripts and books, such as in the treatise De Natura Fossilium , published in 1546 by the German mineralogist Georg Bauer , also known as Georgius Agricola. After the advent of the oil industry, during

6853-539: The title of E.W. Binney & Co. at Bathgate in West Lothian and E. Meldrum & Co. at Glasgow; their works at Bathgate were completed in 1851 and became the first truly commercial oil-works in the world with the first modern oil refinery. The world's first oil refinery was built in 1856 by Ignacy Łukasiewicz in Austria. His achievements also included the discovery of how to distill kerosene from seep oil,

6942-420: The total volume of liquid that is recovered. Similarly, barrels of oil equivalent or BOE is a value that accounts for both oil and natural gas while ignoring any water that is recovered. Other terms are used when discussing only oil. These terms can refer to either the production of crude oil at an oil well, the conversion of crude oil to other products at an oil refinery , or the overall consumption of oil by

7031-405: The uncertainty in converting the volume for crude oil. Regulatory authorities in producing countries set standards for measurement accuracy of produced hydrocarbons, where such measurements affect taxes or royalties to the government. In the United Kingdom, for instance, the measurement accuracy required is ±0.25%. A barrel can technically be used to specify any volume. Since the actual nature of

7120-493: The volume of oil after production, at surface pressure and temperature (as opposed to reservoir conditions). After production has begun, the change in reservoir pressure over time and the history of production from that reservoir can be used to estimate the total oil-in-place using the materials balance method. Alternatively, the production history can be fitted to a curve to estimate future oil production ( decline curve method ). The analogous term original gas-in-place (OGIP)

7209-468: The volume of the world's reserves of conventional oil. Petroleum is a fossil fuel derived from fossilized organic materials , such as zooplankton and algae . Vast amounts of these remains settled to sea or lake bottoms where they were covered in stagnant water (water with no dissolved oxygen ) or sediments such as mud and silt faster than they could decompose aerobically . Approximately 1 m below this sediment, water oxygen concentration

7298-481: The volume. For ease of trading, communication and financial accounting , international commodity exchanges often set a conversion factor for benchmark crude oils. For instance the conversion factor set by the New York Mercantile Exchange (NYMEX) for Western Canadian Select (WCS) crude oil traded at Hardisty, Alberta , Canada is 6.29287 U.S. barrels per standard cubic metre, despite

7387-466: The volumes of some barrel units are roughly double the volumes of others; volumes in common use range approximately from 100 to 200 litres (22 to 44 imp gal; 26 to 53 US gal). In many connections the term drum is used almost interchangeably with barrel . Since medieval times the term barrel as a unit of measure has had various meanings throughout Europe, ranging from about 100 litres to about 1,000 litres. The name

7476-634: Was activity in various parts of the world in the mid-19th century. A group directed by Major Alexeyev of the Bakinskii Corps of Mining Engineers hand-drilled a well in the Baku region of Bibi-Heybat in 1846. There were engine-drilled wells in West Virginia in the same year as Drake's well. An early commercial well was hand dug in Poland in 1853, and another in nearby Romania in 1857. At around

7565-414: Was closed off from external reactants, the resulting composition of the fuel mixture was dependent on the composition of the kerogen via reaction stoichiometry . Three types of kerogen exist: type I (algal), II (liptinic) and III (humic), which were formed mainly from algae , plankton and woody plants (this term includes trees , shrubs and lianas ) respectively. Catagenesis was pyrolytic despite

7654-513: Was derived in medieval times from the French baril , of unknown origin, but still in use, both in French and as derivations in many other languages such as Italian , Polish , and Spanish . In most countries such usage is obsolescent, increasingly superseded by SI units . As a result, the meaning of corresponding words and related concepts (vat, cask, keg etc.) in other languages often refers to

7743-423: Was low, below 0.1 mg/L, and anoxic conditions existed. Temperatures also remained constant. As further layers settled into the sea or lake bed, intense heat and pressure built up in the lower regions. This process caused the organic matter to change, first into a waxy material known as kerogen , found in various oil shales around the world, and then with more heat into liquid and gaseous hydrocarbons via

7832-479: Was used by Byzantine Greeks against Arab ships, which were then attacking Constantinople . Crude oil was also distilled by Persian chemists , with clear descriptions given in Arabic handbooks such as those of Abu Bakr al-Razi (Rhazes). The streets of Baghdad were paved with tar , derived from petroleum that became accessible from natural fields in the region. In the 9th century, oil fields were exploited in

7921-544: Was used in the construction of the walls and towers of Babylon ; there were oil pits near Ardericca and Babylon, and a pitch spring on Zakynthos . Great quantities of it were found on the banks of the river Issus , one of the tributaries of the Euphrates . Ancient Persian tablets indicate the medicinal and lighting uses of petroleum in the upper levels of their society. The use of petroleum in ancient China dates back to more than 2000 years ago. The I Ching , one of

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