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100-663: The area of the mountains contains some of the largest known nickel deposits in the world. The Putorana Plateau is a high-lying plateau crossed by mountain ranges at the northwestern edge of the Central Siberian Plateau . It is located east of the Yenisei River valley, between 67° and 70° N of latitude, southwest of the Anabar Plateau , north of the Syverma and Tunguska plateaus and south of

200-579: A Gilman reagent . These can undergo substitution with alkyl halides to form coupling products ; as such, they are important in the field of organic synthesis . Copper(I) acetylide is highly shock-sensitive but is an intermediate in reactions such as the Cadiot–Chodkiewicz coupling and the Sonogashira coupling . Conjugate addition to enones and carbocupration of alkynes can also be achieved with organocopper compounds. Copper(I) forms

300-696: A covalent character and are relatively weak. This observation explains the low hardness and high ductility of single crystals of copper. At the macroscopic scale, introduction of extended defects to the crystal lattice , such as grain boundaries, hinders flow of the material under applied stress, thereby increasing its hardness. For this reason, copper is usually supplied in a fine-grained polycrystalline form, which has greater strength than monocrystalline forms. The softness of copper partly explains its high electrical conductivity ( 59.6 × 10   S /m ) and high thermal conductivity, second highest (second only to silver) among pure metals at room temperature. This

400-491: A matte for further refining. Hydrometallurgical techniques are also used. Most sulfide deposits have traditionally been processed by concentration through a froth flotation process followed by pyrometallurgical extraction. The nickel matte is further processed with the Sherritt-Gordon process . First, copper is removed by adding hydrogen sulfide , leaving a concentrate of cobalt and nickel. Then, solvent extraction

500-643: A nickel ) consists of 75% copper and 25% nickel in homogeneous composition. Prior to the introduction of cupronickel, which was widely adopted by countries in the latter half of the 20th century, alloys of copper and silver were also used, with the United States using an alloy of 90% silver and 10% copper until 1965, when circulating silver was removed from all coins with the exception of the half dollar—these were debased to an alloy of 40% silver and 60% copper between 1965 and 1970. The alloy of 90% copper and 10% nickel, remarkable for its resistance to corrosion,

600-407: A pinkish-orange color . Copper is used as a conductor of heat and electricity, as a building material , and as a constituent of various metal alloys , such as sterling silver used in jewelry , cupronickel used to make marine hardware and coins , and constantan used in strain gauges and thermocouples for temperature measurement. Copper is one of the few metals that can occur in nature in

700-425: A spin of 3 ⁄ 2 . The other isotopes are radioactive , with the most stable being Cu with a half-life of 61.83 hours. Seven metastable isomers have been characterized; Cu is the longest-lived with a half-life of 3.8 minutes. Isotopes with a mass number above 64 decay by β , whereas those with a mass number below 64 decay by β . Cu , which has

800-399: A blast furnace. A potential source of copper is polymetallic nodules, which have an estimated concentration 1.3%. Like aluminium , copper is recyclable without any loss of quality, both from raw state and from manufactured products. In volume, copper is the third most recycled metal after iron and aluminium. An estimated 80% of all copper ever mined is still in use today. According to

900-464: A blue crystalline penta hydrate , the most familiar copper compound in the laboratory. It is used in a fungicide called the Bordeaux mixture . Polyols , compounds containing more than one alcohol functional group , generally interact with cupric salts. For example, copper salts are used to test for reducing sugars . Specifically, using Benedict's reagent and Fehling's solution the presence of

1000-399: A compound, nickel has a number of niche chemical manufacturing uses, such as a catalyst for hydrogenation , cathodes for rechargeable batteries, pigments and metal surface treatments. Nickel is an essential nutrient for some microorganisms and plants that have enzymes with nickel as an active site . Nickel is a silvery-white metal with a slight golden tinge that takes a high polish. It

1100-709: A directly usable metallic form ( native metals ). This led to very early human use in several regions, from c.  8000 BC . Thousands of years later, it was the first metal to be smelted from sulfide ores, c.  5000 BC ; the first metal to be cast into a shape in a mold, c.  4000 BC ; and the first metal to be purposely alloyed with another metal, tin , to create bronze , c.  3500 BC . Commonly encountered compounds are copper(II) salts, which often impart blue or green colors to such minerals as azurite , malachite , and turquoise , and have been used widely and historically as pigments. Copper used in buildings, usually for roofing, oxidizes to form

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1200-457: A green patina of compounds called verdigris . Copper is sometimes used in decorative art , both in its elemental metal form and in compounds as pigments. Copper compounds are used as bacteriostatic agents , fungicides , and wood preservatives . Copper is essential to all living organisms as a trace dietary mineral because it is a key constituent of the respiratory enzyme complex cytochrome c oxidase . In molluscs and crustaceans , copper

1300-505: A half-life of 12.7 hours, decays both ways. Cu and Cu have significant applications. Cu is used in Cu Cu-PTSM as a radioactive tracer for positron emission tomography . Copper is produced in massive stars and is present in the Earth's crust in a proportion of about 50 parts per million (ppm). In nature, copper occurs in

1400-687: A layer of brown-black copper oxide which, unlike the rust that forms on iron in moist air, protects the underlying metal from further corrosion ( passivation ). A green layer of verdigris (copper carbonate) can often be seen on old copper structures, such as the roofing of many older buildings and the Statue of Liberty . Copper tarnishes when exposed to some sulfur compounds, with which it reacts to form various copper sulfides . There are 29 isotopes of copper. Cu and Cu are stable, with Cu comprising approximately 69% of naturally occurring copper; both have

1500-532: A natural color other than gray or silver. Pure copper is orange-red and acquires a reddish tarnish when exposed to air. This is due to the low plasma frequency of the metal, which lies in the red part of the visible spectrum, causing it to absorb the higher-frequency green and blue colors. As with other metals, if copper is put in contact with another metal in the presence of an electrolyte , galvanic corrosion will occur. Copper does not react with water, but it does slowly react with atmospheric oxygen to form

1600-713: A public controversy regarding the problems of people with nickel allergy . An estimated 3.6 million tonnes (t) of nickel per year are mined worldwide; Indonesia (1,800,000 t), the Philippines (400,000 t), Russia (200,000 t), New Caledonia ( France ) (230,000 t), Canada (180,000 t) and Australia (160,000 t) are the largest producers as of 2023. The largest nickel deposits in non-Russian Europe are in Finland and Greece . Identified land-based sources averaging at least 1% nickel contain at least 130 million tonnes of nickel. About 60%

1700-407: A red-brown precipitate with copper(II) salts. Compounds that contain a carbon-copper bond are known as organocopper compounds. They are very reactive towards oxygen to form copper(I) oxide and have many uses in chemistry . They are synthesized by treating copper(I) compounds with Grignard reagents , terminal alkynes or organolithium reagents ; in particular, the last reaction described produces

1800-451: A rich variety of compounds, usually with oxidation states +1 and +2, which are often called cuprous and cupric , respectively. Copper compounds promote or catalyse numerous chemical and biological processes. As with other elements, the simplest compounds of copper are binary compounds, i.e. those containing only two elements, the principal examples being oxides, sulfides, and halides . Both cuprous and cupric oxides are known. Among

1900-424: A variety of minerals, including native copper , copper sulfides such as chalcopyrite , bornite , digenite , covellite , and chalcocite , copper sulfosalts such as tetrahedite-tennantite , and enargite , copper carbonates such as azurite and malachite , and as copper(I) or copper(II) oxides such as cuprite and tenorite , respectively. The largest mass of elemental copper discovered weighed 420 tonnes and

2000-436: A variety of weak complexes with alkenes and carbon monoxide , especially in the presence of amine ligands. Copper(III) is most often found in oxides. A simple example is potassium cuprate , KCuO 2 , a blue-black solid. The most extensively studied copper(III) compounds are the cuprate superconductors . Yttrium barium copper oxide (YBa 2 Cu 3 O 7 ) consists of both Cu(II) and Cu(III) centres. Like oxide, fluoride

2100-504: Is Ni with 28 protons and 50 neutrons. Both are therefore unusually stable for nuclei with so large a proton–neutron imbalance . Nickel-63 is a contaminant found in the support structure of nuclear reactors. It is produced through neutron capture by nickel-62. Small amounts have also been found near nuclear weapon test sites in the South Pacific. Nickel ores are classified as oxides or sulfides. Oxides include laterite , where

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2200-411: Is $ 0.045 (90% of the face value). In the 21st century, the high price of nickel has led to some replacement of the metal in coins around the world. Coins still made with nickel alloys include one- and two- euro coins , 5¢, 10¢, 25¢, 50¢, and $ 1 U.S. coins , and 20p, 50p, £1, and £2 UK coins . From 2012 on the nickel-alloy used for 5p and 10p UK coins was replaced with nickel-plated steel. This ignited

2300-990: Is a protected area covering some 1,887,251 ha (4,663,500 acres) with a buffer zone of 1,773,300 ha (4,382,000 acres). It was set up to protect the world's largest herd of wild reindeer , as well as snow sheep . In July 2010 , the Putorana Reserve was inscribed on the World Heritage List as "a complete set of subarctic and arctic ecosystems in an isolated mountain range, including pristine taiga , forest tundra , tundra and arctic desert systems, as well as untouched cold-water lake and river systems". The Plateau's minerals include igneous basalt rocks , iron ores ( magnetite and hematite ), silicates ( prehnite , zeolite ), apatites , perovskites and highly saturated copper and nickel ores. The natural resources are presented by abundant water and coal . This Krasnoyarsk Krai location article

2400-437: Is a stub . You can help Misplaced Pages by expanding it . Nickel Nickel is a chemical element ; it has symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal . Pure nickel is chemically reactive, but large pieces are slow to react with air under standard conditions because a passivation layer of nickel oxide forms on

2500-417: Is a 3d 4s energy level, specifically the 3d ( F) 4s F, J  = 4 level. However, each of these two configurations splits into several energy levels due to fine structure , and the two sets of energy levels overlap. The average energy of states with [Ar] 3d 4s is actually lower than the average energy of states with [Ar] 3d 4s . Therefore, the research literature on atomic calculations quotes

2600-583: Is a constituent of the blood pigment hemocyanin , replaced by the iron-complexed hemoglobin in fish and other vertebrates . In humans, copper is found mainly in the liver, muscle, and bone. The adult body contains between 1.4 and 2.1 mg of copper per kilogram of body weight. In the Roman era , copper was mined principally on Cyprus , the origin of the name of the metal, from aes cyprium (metal of Cyprus), later corrupted to cuprum (Latin). Coper ( Old English ) and copper were derived from this,

2700-405: Is a highly basic anion and is known to stabilize metal ions in high oxidation states. Both copper(III) and even copper(IV) fluorides are known, K 3 CuF 6 and Cs 2 CuF 6 , respectively. Some copper proteins form oxo complexes , which, in extensively studied synthetic analog systems, feature copper(III). With tetrapeptides , purple-colored copper(III) complexes are stabilized by

2800-725: Is a new nickel mine in Michigan's Upper Peninsula . Construction was completed in 2013, and operations began in the third quarter of 2014. In the first full year of operation, the Eagle Mine produced 18,000 t. Nickel is obtained through extractive metallurgy : it is extracted from ore by conventional roasting and reduction processes that yield metal of greater than 75% purity. In many stainless steel applications, 75% pure nickel can be used without further purification, depending on impurities. Traditionally, most sulfide ores are processed using pyrometallurgical techniques to produce

2900-401: Is a somewhat milder microclimate owing to the protection afforded by neighboring ranges from the northern winds. The higher elevations within the plateau transition to a tundra climate . Spring, summer and autumn fall respectively in the months of June, July, and August, the remaining months are winter with temperatures between −32 °C (−26 °F) and −40 °C (−40 °F). In July,

3000-501: Is a volatile, highly toxic liquid at room temperature. On heating, the complex decomposes back to nickel and carbon monoxide: This behavior is exploited in the Mond process for purifying nickel, as described above. The related nickel(0) complex bis(cyclooctadiene)nickel(0) is a useful catalyst in organonickel chemistry because the cyclooctadiene (or cod ) ligands are easily displaced. Nickel(I) complexes are uncommon, but one example

3100-442: Is also formed in nickel distillation as a by-product, but it decomposes to tetracobalt dodecacarbonyl at the reaction temperature to give a non-volatile solid. Copper Copper is a chemical element ; it has symbol Cu (from Latin cuprum ) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity . A freshly exposed surface of pure copper has

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3200-401: Is because the resistivity to electron transport in metals at room temperature originates primarily from scattering of electrons on thermal vibrations of the lattice, which are relatively weak in a soft metal. The maximum possible current density of copper in open air is approximately 3.1 × 10  A/m , above which it begins to heat excessively. Copper is one of a few metallic elements with

3300-640: Is currently being set in place by the International Seabed Authority to ensure that these nodules are collected in an environmentally conscientious manner while adhering to the United Nations Sustainable Development Goals . The one place in the United States where nickel has been profitably mined is Riddle, Oregon , with several square miles of nickel-bearing garnierite surface deposits. The mine closed in 1987. The Eagle mine project

3400-470: Is greater than both Fe and Fe , more abundant nuclides often incorrectly cited as having the highest binding energy. Though this would seem to predict nickel as the most abundant heavy element in the universe, the high rate of photodisintegration of nickel in stellar interiors causes iron to be by far the most abundant. Nickel-60 is the daughter product of the extinct radionuclide Fe (half-life 2.6 million years). Due to

3500-575: Is in laterites and 40% is in sulfide deposits. Also, extensive nickel sources are found in the depths of the Pacific Ocean , especially in an area called the Clarion Clipperton Zone in the form of polymetallic nodules peppering the seafloor at 3.5–6 km below sea level . These nodules are composed of numerous rare-earth metals and are estimated to be 1.7% nickel. With advances in science and engineering , regulation

3600-533: Is melted in a furnace and then reduced and cast into billets and ingots ; lower-purity scrap is refined by electroplating in a bath of sulfuric acid . The environmental cost of copper mining was estimated at 3.7 kg CO2eq per kg of copper in 2019. Codelco, a major producer in Chile, reported that in 2020 the company emitted 2.8t CO2eq per ton (2.8 kg CO2eq per kg) of fine copper. Greenhouse gas emissions primarily arise from electricity consumed by

3700-455: Is now Syria have been found to contain as much as 2% nickel. Some ancient Chinese manuscripts suggest that "white copper" ( cupronickel , known as baitong ) was used there in 1700–1400 BCE. This Paktong white copper was exported to Britain as early as the 17th century, but the nickel content of this alloy was not discovered until 1822. Coins of nickel-copper alloy were minted by Bactrian kings Agathocles , Euthydemus II , and Pantaleon in

3800-434: Is now known as the mineral nickeline (formerly niccolite ), a nickel arsenide . In 1751, Baron Axel Fredrik Cronstedt tried to extract copper from kupfernickel at a cobalt mine in the village of Los, Sweden , and instead produced a white metal that he named nickel after the spirit that had given its name to the mineral. In modern German, Kupfernickel or Kupfer-Nickel designates the alloy cupronickel . Originally,

3900-412: Is one of only four elements that are ferromagnetic at or near room temperature; the others are iron, cobalt and gadolinium . Its Curie temperature is 355 °C (671 °F), meaning that bulk nickel is non-magnetic above this temperature. The unit cell of nickel is a face-centered cube ; it has lattice parameter of 0.352 nm, giving an atomic radius of 0.124 nm. This crystal structure

4000-444: Is one of the most important constituents of silver and karat gold solders used in the jewelry industry, modifying the color, hardness and melting point of the resulting alloys. Some lead-free solders consist of tin alloyed with a small proportion of copper and other metals. The alloy of copper and nickel , called cupronickel , is used in low-denomination coins, often for the outer cladding. The US five-cent coin (currently called

4100-469: Is produced by the silicon burning process and later set free in large amounts in type Ia supernovae . The shape of the light curve of these supernovae at intermediate to late-times corresponds to the decay via electron capture of Ni to cobalt -56 and ultimately to iron-56. Nickel-59 is a long-lived cosmogenic radionuclide ; half-life 76,000 years. Ni has found many applications in isotope geology . Ni has been used to date

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4200-437: Is recovered from mine tailings and heaps. A variety of methods are used including leaching with sulfuric acid, ammonia, ferric chloride. Biological methods are also used. A significant source of copper is from recycling. Recycling is facilitated because copper is usually deployed in its metallic state. In 2001, a typical automobile contained 20–30 kg of copper. Recycling usually begins with some melting process using

4300-599: Is situated on the southern limit of the plateau, where it overlaps with the Syverma Plateau . The Putorana area is mainly composed of basalt from the Siberian Traps . The Putorana region is located above the Arctic Circle . The climate is a harsh subarctic , sharply continental , with long, severely cold winters, and short, cool summers. However, in certain lake valleys, such as Lake Lama, there

4400-572: Is stable to pressures of at least 70 GPa. Nickel is hard, malleable and ductile , and has a relatively high electrical and thermal conductivity for transition metals. The high compressive strength of 34 GPa, predicted for ideal crystals, is never obtained in the real bulk material due to formation and movement of dislocations . However, it has been reached in Ni nanoparticles . Nickel has two atomic electron configurations , [Ar] 3d 4s and [Ar] 3d 4s , which are very close in energy; [Ar] denotes

4500-446: Is the tetrahedral complex NiBr(PPh 3 ) 3 . Many nickel(I) complexes have Ni–Ni bonding, such as the dark red diamagnetic K 4 [Ni 2 (CN) 6 ] prepared by reduction of K 2 [Ni 2 (CN) 6 ] with sodium amalgam . This compound is oxidized in water, liberating H 2 . It is thought that the nickel(I) oxidation state is important to nickel-containing enzymes, such as [NiFe]-hydrogenase , which catalyzes

4600-631: Is thought to compose Earth's outer and inner cores . Use of nickel (as natural meteoric nickel–iron alloy) has been traced as far back as 3500 BCE. Nickel was first isolated and classified as an element in 1751 by Axel Fredrik Cronstedt , who initially mistook the ore for a copper mineral , in the cobalt mines of Los, Hälsingland, Sweden . The element's name comes from a mischievous sprite of German miner mythology, Nickel (similar to Old Nick ). Nickel minerals can be green, like copper ores, and were known as kupfernickel – Nickel's copper – because they produced no copper. Although most nickel in

4700-479: Is used as the cathode in many rechargeable batteries , including nickel–cadmium , nickel–iron , nickel–hydrogen , and nickel–metal hydride , and used by certain manufacturers in Li-ion batteries . Ni(IV) remains a rare oxidation state and very few compounds are known. Ni(IV) occurs in the mixed oxide BaNiO 3 . Unintentional use of nickel can be traced back as far as 3500 BCE. Bronzes from what

4800-455: Is used chiefly in alloys and corrosion-resistant plating. About 68% of world production is used in stainless steel . A further 10% is used for nickel-based and copper-based alloys, 9% for plating, 7% for alloy steels, 3% in foundries, and 4% in other applications such as in rechargeable batteries, including those in electric vehicles (EVs). Nickel is widely used in coins , though nickel-plated objects sometimes provoke nickel allergy . As

4900-411: Is used for various objects exposed to seawater, though it is vulnerable to the sulfides sometimes found in polluted harbors and estuaries. Alloys of copper with aluminium (about 7%) have a golden color and are used in decorations. Shakudō is a Japanese decorative alloy of copper containing a low percentage of gold, typically 4–10%, that can be patinated to a dark blue or black color. Copper forms

5000-412: Is used to separate the cobalt and nickel, with the final nickel content greater than 86%. A second common refining process is leaching the metal matte into a nickel salt solution, followed by electrowinning the nickel from solution by plating it onto a cathode as electrolytic nickel. The purest metal is obtained from nickel oxide by the Mond process , which gives a purity of over 99.99%. The process

5100-686: The British Geological Survey , in 2005, Chile was the top producer of copper with at least one-third of the world share followed by the United States, Indonesia and Peru. Copper can also be recovered through the in-situ leach process. Several sites in the state of Arizona are considered prime candidates for this method. The amount of copper in use is increasing and the quantity available is barely sufficient to allow all countries to reach developed world levels of usage. An alternative source of copper for collection currently being researched are polymetallic nodules , which are located at

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5200-551: The Great Lakes may have also been mining copper during this time, making it one of the oldest known examples of copper extraction in the world. There is evidence from prehistoric lead pollution from lakes in Michigan that people in the region began mining copper c.  6000 BC . Evidence suggests that utilitarian copper objects fell increasingly out of use in the Old Copper Complex of North America during

5300-553: The International Resource Panel 's Metal Stocks in Society report , the global per capita stock of copper in use in society is 35–55 kg. Much of this is in more-developed countries (140–300 kg per capita) rather than less-developed countries (30–40 kg per capita). The process of recycling copper is roughly the same as is used to extract copper but requires fewer steps. High-purity scrap copper

5400-726: The Neolithic period and the Bronze Age was formerly termed the Chalcolithic period (copper-stone), when copper tools were used with stone tools. The term has gradually fallen out of favor because in some parts of the world, the Chalcolithic and Neolithic are coterminous at both ends. Brass, an alloy of copper and zinc, is of much more recent origin. It was known to the Greeks, but became a significant supplement to bronze during

5500-675: The North Siberian Lowland . The main subranges of the Putorana are the Keta Range , Lontokoisky Kamen , Kharayelakh Range , Chaya-Ayan , Brus Kamen , and Lama Range , among others. The highest mountain in the range system is Mount Kamen which stands 1,678 m (5,505 ft) above sea level and is also the highest point of the Central Siberian Plateau. Talnikovy Waterfall , is reputedly one of

5600-525: The Vinča culture date to 4500 BC. Sumerian and Egyptian artifacts of copper and bronze alloys date to 3000 BC. Egyptian Blue , or cuprorivaite (calcium copper silicate) is a synthetic pigment that contains copper and started being used in ancient Egypt around 3250 BC. The manufacturing process of Egyptian blue was known to the Romans, but by the fourth century AD the pigment fell out of use and

5700-467: The arsenide niccolite . Identified land-based resources throughout the world averaging 1% nickel or greater comprise at least 130 million tons of nickel (about the double of known reserves). About 60% is in laterites and 40% in sulfide deposits. On geophysical evidence, most of the nickel on Earth is believed to be in Earth's outer and inner cores . Kamacite and taenite are naturally occurring alloys of iron and nickel. For kamacite,

5800-484: The metal aquo complex [Ni(H 2 O) 6 ] . The four halides form nickel compounds, which are solids with molecules with octahedral Ni centres. Nickel(II) chloride is most common, and its behavior is illustrative of the other halides. Nickel(II) chloride is made by dissolving nickel or its oxide in hydrochloric acid . It is usually found as the green hexahydrate, whose formula is usually written NiCl 2 ·6H 2 O . When dissolved in water, this salt forms

5900-479: The metal aquo complex [Ni(H 2 O) 6 ] . Dehydration of NiCl 2 ·6H 2 O gives yellow anhydrous NiCl 2 . Some tetracoordinate nickel(II) complexes, e.g. bis(triphenylphosphine)nickel chloride , exist both in tetrahedral and square planar geometries. The tetrahedral complexes are paramagnetic ; the square planar complexes are diamagnetic . In having properties of magnetic equilibrium and formation of octahedral complexes, they contrast with

6000-543: The 2nd century BCE, possibly out of the Chinese cupronickel. In medieval Germany, a metallic yellow mineral was found in the Ore Mountains that resembled copper ore. But when miners were unable to get any copper from it, they blamed a mischievous sprite of German mythology, Nickel (similar to Old Nick ), for besetting the copper. They called this ore Kupfernickel from German Kupfer 'copper'. This ore

6100-548: The 9th or 10th century AD. Carbon dating has established mining at Alderley Edge in Cheshire , UK, at 2280 to 1890 BC. Ötzi the Iceman , a male dated from 3300 to 3200 BC, was found with an axe with a copper head 99.7% pure; high levels of arsenic in his hair suggest an involvement in copper smelting. Experience with copper has assisted the development of other metals; in particular, copper smelting likely led to

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6200-517: The Bronze Age and a shift towards an increased production of ornamental copper objects occurred. Natural bronze, a type of copper made from ores rich in silicon, arsenic, and (rarely) tin, came into general use in the Balkans around 5500 BC. Alloying copper with tin to make bronze was first practiced about 4000 years after the discovery of copper smelting, and about 2000 years after "natural bronze" had come into general use. Bronze artifacts from

6300-541: The Middle East; a copper pendant was found in northern Iraq that dates to 8700 BC. Evidence suggests that gold and meteoric iron (but not smelted iron) were the only metals used by humans before copper. The history of copper metallurgy is thought to follow this sequence: first, cold working of native copper, then annealing , smelting , and, finally, lost-wax casting . In southeastern Anatolia , all four of these techniques appear more or less simultaneously at

6400-504: The United States, the term "nickel" or "nick" originally applied to the copper-nickel Flying Eagle cent , which replaced copper with 12% nickel 1857–58, then the Indian Head cent of the same alloy from 1859 to 1864. Still later, in 1865, the term designated the three-cent nickel , with nickel increased to 25%. In 1866, the five-cent shield nickel (25% nickel, 75% copper) appropriated the designation, which has been used ever since for

6500-521: The affected areas is highly acidic, with a pH range of 2.1–4.9, and shows elevated electrical conductivity levels between 280 and 1561 mS/cm. These changes in water chemistry make the environment inhospitable for fish, essentially rendering the water uninhabitable for aquatic life. Numerous copper alloys have been formulated, many with important uses. Brass is an alloy of copper and zinc . Bronze usually refers to copper- tin alloys, but can refer to any alloy of copper such as aluminium bronze . Copper

6600-501: The alloy is usually in the proportion of 90:10 to 95:5, though impurities (such as cobalt or carbon ) may be present. Taenite is 20% to 65% nickel. Kamacite and taenite are also found in nickel iron meteorites . Nickel is commonly found in iron meteorites as the alloys kamacite and taenite . Nickel in meteorites was first detected in 1799 by Joseph-Louis Proust , a French chemist who then worked in Spain. Proust analyzed samples of

6700-541: The atmosphere; 150 mg/kg in soil; 30 mg/kg in vegetation; 2 μg/L in freshwater and 0.5 μg/L in seawater. Most copper is mined or extracted as copper sulfides from large open pit mines in porphyry copper deposits that contain 0.4 to 1.0% copper. Sites include Chuquicamata , in Chile, Bingham Canyon Mine , in Utah, United States, and El Chino Mine , in New Mexico, United States. According to

6800-766: The beginning of the Neolithic c.  7500 BC . Copper smelting was independently invented in different places. The earliest evidence of lost-wax casting copper comes from an amulet found in Mehrgarh , Pakistan, and is dated to 4000 BC. Investment casting was invented in 4500–4000 BC in Southeast Asia Smelting was probably discovered in China before 2800 BC, in Central America around 600 AD, and in West Africa about

6900-531: The company, especially when sourced from fossil fuels, and from engines required for copper extraction and refinement. Companies that mine land often mismanage waste, rendering the area sterile for life. Additionally, nearby rivers and forests are also negatively impacted. The Philippines is an example of a region where land is overexploited by mining companies. Copper mining waste in Valea Şesei, Romania, has significantly altered nearby water properties. The water in

7000-469: The complete argon core structure. There is some disagreement on which configuration has the lower energy. Chemistry textbooks quote nickel's electron configuration as [Ar] 4s 3d , also written [Ar] 3d 4s . This configuration agrees with the Madelung energy ordering rule , which predicts that 4s is filled before 3d. It is supported by the experimental fact that the lowest energy state of the nickel atom

7100-522: The deprotonated amide ligands. Complexes of copper(III) are also found as intermediates in reactions of organocopper compounds, for example in the Kharasch–Sosnovsky reaction . A timeline of copper illustrates how this metal has advanced human civilization for the past 11,000 years. Copper occurs naturally as native metallic copper and was known to some of the oldest civilizations on record. The history of copper use dates to 9000 BC in

7200-399: The depths of the Pacific Ocean approximately 3000–6500 meters below sea level. These nodules contain other valuable metals such as cobalt and nickel . Copper has been in use for at least 10,000 years, but more than 95% of all copper ever mined and smelted has been extracted since 1900. As with many natural resources, the total amount of copper on Earth is vast, with around 10 tons in

7300-563: The discovery of iron smelting . Production in the Old Copper Complex in Michigan and Wisconsin is dated between 6500 and 3000 BC. A copper spearpoint found in Wisconsin has been dated to 6500 BC. Copper usage by the indigenous peoples of the Old Copper Complex from the Great Lakes region of North America has been radiometrically dated to as far back as 7500 BC. Indigenous peoples of North America around

7400-484: The divalent complexes of the heavier group 10 metals, palladium(II) and platinum(II), which form only square-planar geometry. Nickelocene has an electron count of 20. Many chemical reactions of nickelocene tend to yield 18-electron products. Many Ni(III) compounds are known. Ni(III) forms simple salts with fluoride or oxide ions. Ni(III) can be stabilized by σ-donor ligands such as thiols and organophosphines . Ni(III) occurs in nickel oxide hydroxide , which

7500-701: The earth's crust exists as oxides, economically more important nickel ores are sulfides, especially pentlandite . Major production sites include the Sudbury region , Canada (which is thought to be of meteoric origin), New Caledonia in the Pacific , Western Australia , and Norilsk , Russia. Nickel is one of four elements (the others are iron , cobalt , and gadolinium ) that are ferromagnetic at about room temperature. Alnico permanent magnets based partly on nickel are of intermediate strength between iron-based permanent magnets and rare-earth magnets . The metal

7600-545: The fastest water exchange rate (speed of water ligands attaching and detaching) for any transition metal aquo complex . Adding aqueous sodium hydroxide causes the precipitation of light blue solid copper(II) hydroxide . A simplified equation is: Aqueous ammonia results in the same precipitate. Upon adding excess ammonia, the precipitate dissolves, forming tetraamminecopper(II) : Many other oxyanions form complexes; these include copper(II) acetate , copper(II) nitrate , and copper(II) carbonate . Copper(II) sulfate forms

7700-479: The ground state configuration as [Ar] 3d 4s . The isotopes of nickel range in atomic weight from 48  u ( Ni ) to 82 u ( Ni ). Natural nickel is composed of five stable isotopes , Ni , Ni , Ni , Ni and Ni , of which Ni is the most abundant (68.077% natural abundance ). Nickel-62 has the highest binding energy per nucleon of any nuclide : 8.7946 MeV/nucleon. Its binding energy

7800-736: The highest waterfalls in Asia. Lakes on the plateau such as the Dyupkun and Lake Lama are large and form whole ecosystems, which spread over many tens of kilometers. “Putorana” is from the native language of the Evenks and translates to “the country of lakes with steep banks”. The more than 25,000 lakes are between 180 and 420 m (590 and 1,400 ft) deep, and together they form the second-largest store of fresh water in Russia by capacity after Lake Baikal . Russia's geographical center, Lake Vivi ,

7900-697: The large deposits in the Sudbury Basin in Canada in 1883, in Norilsk -Talnakh in Russia in 1920, and in the Merensky Reef in South Africa in 1924 made large-scale nickel production possible. Aside from the aforementioned Bactrian coins, nickel was not a component of coins until the mid-19th century. 99.9% nickel five-cent coins were struck in Canada (the world's largest nickel producer at

8000-511: The later spelling first used around 1530. Copper, silver , and gold are in group 11 of the periodic table; these three metals have one s-orbital electron on top of a filled d- electron shell and are characterized by high ductility , and electrical and thermal conductivity. The filled d-shells in these elements contribute little to interatomic interactions, which are dominated by the s-electrons through metallic bonds . Unlike metals with incomplete d-shells, metallic bonds in copper are lacking

8100-419: The level of <1% Cu. Concentration of the ore is required, which begins with comminution followed by froth flotation . The remaining concentrate is the smelted, which can be described with two simplified equations: Cuprous oxide reacts with cuprous sulfide to convert to blister copper upon heating This roasting gives matte copper, roughly 50% Cu by weight, which is purified by electrolysis. Depending on

8200-784: The long half-life of Fe , its persistence in materials in the Solar System may generate observable variations in the isotopic composition of Ni . Therefore, the abundance of Ni in extraterrestrial material may give insight into the origin of the Solar System and its early history. At least 26 nickel radioisotopes have been characterized; the most stable are Ni with half-life 76,000 years, Ni (100 years), and Ni (6 days). All other radioisotopes have half-lives less than 60 hours and most these have half-lives less than 30 seconds. This element also has one meta state . Radioactive nickel-56

8300-416: The metals at a profit. The United States Mint , anticipating this practice, implemented new interim rules on December 14, 2006, subject to public comment for 30 days, which criminalized the melting and export of cents and nickels. Violators can be punished with a fine of up to $ 10,000 and/or a maximum of five years in prison. As of September 19, 2013, the melt value of a US nickel (copper and nickel included)

8400-446: The meteorite from Campo del Cielo (Argentina), which had been obtained in 1783 by Miguel Rubín de Celis, discovering the presence in them of nickel (about 10%) along with iron. The most common oxidation state of nickel is +2, but compounds of Ni , Ni , and Ni are well known, and the exotic oxidation states Ni and Ni have been characterized. Nickel tetracarbonyl (Ni(CO) 4 ), discovered by Ludwig Mond ,

8500-472: The modern world. The price of copper is volatile . After a peak in 2022 the price unexpectedly fell. The global market for copper is one of the most commodified and financialized of the commodity markets , and has been so for decades. The great majority of copper ores are sulfides. Common ores are the sulfides chalcopyrite (CuFeS 2 ), bornite (Cu 5 FeS 4 ) and, to a lesser extent, covellite (CuS) and chalcocite (Cu 2 S). These ores occur at

8600-516: The numerous copper sulfides , important examples include copper(I) sulfide ( Cu 2 S ) and copper monosulfide ( CuS ). Cuprous halides with fluorine , chlorine , bromine , and iodine are known, as are cupric halides with fluorine , chlorine , and bromine . Attempts to prepare copper(II) iodide yield only copper(I) iodide and iodine. Copper forms coordination complexes with ligands . In aqueous solution, copper(II) exists as [Cu(H 2 O) 6 ] . This complex exhibits

8700-509: The only source for nickel was the rare Kupfernickel. Beginning in 1824, nickel was obtained as a byproduct of cobalt blue production. The first large-scale smelting of nickel began in Norway in 1848 from nickel-rich pyrrhotite . The introduction of nickel in steel production in 1889 increased the demand for nickel; the nickel deposits of New Caledonia , discovered in 1865, provided most of the world's supply between 1875 and 1915. The discovery of

8800-428: The ore, sometimes other metals are obtained during the electrolysis including platinum and gold. Aside from sulfides, another family of ores are oxides. Approximately 15% of the world's copper supply derives from these oxides. The beneficiation process for oxides involves extraction with sulfuric acid solutions followed by electrolysis. In parallel with the above method for "concentrated" sulfide and oxide ores, copper

8900-407: The principal mineral mixtures are nickeliferous limonite , (Fe,Ni)O(OH), and garnierite (a mixture of various hydrous nickel and nickel-rich silicates). Nickel sulfides commonly exist as solid solutions with iron in minerals such as pentlandite and pyrrhotite with the formula Fe 9-x Ni x S 8 and Fe 7-x Ni x S 6 , respectively. Other common Ni-containing minerals are millerite and

9000-477: The reversible reduction of protons to H 2 . Nickel(II) forms compounds with all common anions, including sulfide , sulfate , carbonate, hydroxide, carboxylates, and halides. Nickel(II) sulfate is produced in large amounts by dissolving nickel metal or oxides in sulfuric acid , forming both a hexa- and heptahydrate useful for electroplating nickel. Common salts of nickel, such as chloride, nitrate, and sulfate, dissolve in water to give green solutions of

9100-750: The secret to its manufacturing process became lost. The Romans said the blue pigment was made from copper, silica, lime and natron and was known to them as caeruleum . The Bronze Age began in Southeastern Europe around 3700–3300 BC, in Northwestern Europe about 2500 BC. It ended with the beginning of the Iron Age, 2000–1000 BC in the Near East, and 600 BC in Northern Europe. The transition between

9200-468: The subsequent 5-cent pieces. This alloy proportion is not ferromagnetic . The US nickel coin contains 0.04 ounces (1.1 g) of nickel, which at the April 2007 price was worth 6.5 cents, along with 3.75 grams of copper worth about 3 cents, with a total metal value of more than 9 cents. Since the face value of a nickel is 5 cents, this made it an attractive target for melting by people wanting to sell

9300-438: The sugar is signaled by a color change from blue Cu(II) to reddish copper(I) oxide. Schweizer's reagent and related complexes with ethylenediamine and other amines dissolve cellulose . Amino acids such as cystine form very stable chelate complexes with copper(II) including in the form of metal-organic biohybrids (MOBs). Many wet-chemical tests for copper ions exist, one involving potassium ferricyanide , which gives

9400-455: The surface that prevents further corrosion. Even so, pure native nickel is found in Earth's crust only in tiny amounts, usually in ultramafic rocks , and in the interiors of larger nickel–iron meteorites that were not exposed to oxygen when outside Earth's atmosphere. Meteoric nickel is found in combination with iron , a reflection of the origin of those elements as major end products of supernova nucleosynthesis . An iron–nickel mixture

9500-399: The terrestrial age of meteorites and to determine abundances of extraterrestrial dust in ice and sediment . Nickel-78, with a half-life of 110 milliseconds, is believed an important isotope in supernova nucleosynthesis of elements heavier than iron. Ni, discovered in 1999, is the most proton-rich heavy element isotope known. With 28 protons and 20 neutrons , Ni is " doubly magic ", as

9600-563: The time) during non-war years from 1922 to 1981; the metal content made these coins magnetic. During the war years 1942–1945, most or all nickel was removed from Canadian and US coins to save it for making armor. Canada used 99.9% nickel from 1968 in its higher-value coins until 2000. Coins of nearly pure nickel were first used in 1881 in Switzerland. Birmingham forged nickel coins in c.  1833 for trading in Malaysia. In

9700-399: The top kilometer of Earth's crust, which is about 5 million years' worth at the current rate of extraction. However, only a tiny fraction of these reserves is economically viable with present-day prices and technologies. Estimates of copper reserves available for mining vary from 25 to 60 years, depending on core assumptions such as the growth rate. Recycling is a major source of copper in

9800-399: The warmest month, average air temperatures stay around 8 °C (46 °F) and may reach a maximum of 16 °C (61 °F). Precipitation is between 500 millimeters (20 in) and 800 millimeters (31 in), falling mainly in the summer in the form of rain. The snow cover in winter is relatively sparse. The Putorana Nature Reserve , established in 1988 and administered from Norilsk,

9900-527: Was found in 1857 on the Keweenaw Peninsula in Michigan, US. Native copper is a polycrystal , with the largest single crystal ever described measuring 4.4 × 3.2 × 3.2 cm . Copper is the 26th most abundant element in Earth's crust , representing 50 ppm compared with 75 ppm for zinc , and 14 ppm for lead . Typical background concentrations of copper do not exceed 1 ng/m in

10000-429: Was patented by Ludwig Mond and has been in industrial use since before the beginning of the 20th century. In this process, nickel is treated with carbon monoxide in the presence of a sulfur catalyst at around 40–80 °C to form nickel carbonyl . In a similar reaction with iron, iron pentacarbonyl can form, though this reaction is slow. If necessary, the nickel may be separated by distillation. Dicobalt octacarbonyl

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