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182-486: Quantum mechanics is a fundamental theory that describes the behavior of nature at and below the scale of atoms . It is the foundation of all quantum physics , which includes quantum chemistry , quantum field theory , quantum technology , and quantum information science . Quantum mechanics can describe many systems that classical physics cannot. Classical physics can describe many aspects of nature at an ordinary ( macroscopic and (optical) microscopic ) scale, but

364-480: A {\displaystyle a} larger we make the spread in momentum smaller, but the spread in position gets larger. This illustrates the uncertainty principle. As we let the Gaussian wave packet evolve in time, we see that its center moves through space at a constant velocity (like a classical particle with no forces acting on it). However, the wave packet will also spread out as time progresses, which means that

546-406: A common ancestor . Acceptance of a theory does not require that all of its major predictions be tested, if it is already supported by sufficiently strong evidence. For example, certain tests may be unfeasible or technically difficult. As a result, theories may make predictions that have not yet been confirmed or proven incorrect; in this case, the predicted results may be described informally with

728-404: A de Broglie wave in the manner of light . That is, under the appropriate conditions, electrons and other matter would show properties of either particles or waves. The corpuscular properties of a particle are demonstrated when it is shown to have a localized position in space along its trajectory at any given moment. The wave-like nature of light is displayed, for example, when a beam of light

910-496: A scientific fact or scientific law in that a theory seeks to explain "why" or "how", whereas a fact is a simple, basic observation and a law is an empirical description of a relationship between facts and/or other laws. For example, Newton's Law of Gravity is a mathematical equation that can be used to predict the attraction between bodies, but it is not a theory to explain how gravity works. Stephen Jay Gould wrote that "...facts and theories are different things, not rungs in

1092-443: A "root" metaphor that constrains how scientists theorize and model a phenomenon and thus arrive at testable hypotheses. Engineering practice makes a distinction between "mathematical models" and "physical models"; the cost of fabricating a physical model can be minimized by first creating a mathematical model using a computer software package, such as a computer aided design tool. The component parts are each themselves modelled, and

1274-648: A charged droplet of oil from falling as a result of gravity. This device could measure the electric charge from as few as 1–150 ions with an error margin of less than 0.3%. Comparable experiments had been done earlier by Thomson's team, using clouds of charged water droplets generated by electrolysis, and in 1911 by Abram Ioffe , who independently obtained the same result as Millikan using charged microparticles of metals, then published his results in 1913. However, oil drops were more stable than water drops because of their slower evaporation rate, and thus more suited to precise experimentation over longer periods of time. Around

1456-463: A definite prediction of what the quantum state ψ ( t ) {\displaystyle \psi (t)} will be at any later time. Some wave functions produce probability distributions that are independent of time, such as eigenstates of the Hamiltonian . Many systems that are treated dynamically in classical mechanics are described by such "static" wave functions. For example,

1638-432: A direct result. The phrase " the received view of theories " is used to describe this approach. Terms commonly associated with it are " linguistic " (because theories are components of a language) and " syntactic " (because a language has rules about how symbols can be strung together). Problems in defining this kind of language precisely, e.g., are objects seen in microscopes observed or are they theoretical objects, led to

1820-534: A distance —Einstein presumed a gravitational field. In 1907, Einstein's equivalence principle implied that a free fall within a uniform gravitational field is equivalent to inertial motion. By extending special relativity's effects into three dimensions, general relativity extended length contraction into space contraction , conceiving of 4D space-time as the gravitational field that alters geometrically and sets all local objects' pathways. Even massless energy exerts gravitational motion on local objects by "curving"

2002-510: A family of unitary operators parameterized by a variable t {\displaystyle t} . Under the evolution generated by A {\displaystyle A} , any observable B {\displaystyle B} that commutes with A {\displaystyle A} will be conserved. Moreover, if B {\displaystyle B} is conserved by evolution under A {\displaystyle A} , then A {\displaystyle A}

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2184-410: A fourth state of matter in which the mean free path of the particles is so long that collisions may be ignored. In 1883, not yet well-known German physicist Heinrich Hertz tried to prove that cathode rays are electrically neutral and got what he interpreted as a confident absence of deflection in electrostatic, as opposed to magnetic, field. However, as J. J. Thomson explained in 1897, Hertz placed

2366-494: A friction that slows the electron. This force is caused by a back-reaction of the electron's own field upon itself. Photons mediate electromagnetic interactions between particles in quantum electrodynamics . An isolated electron at a constant velocity cannot emit or absorb a real photon; doing so would violate conservation of energy and momentum . Instead, virtual photons can transfer momentum between two charged particles. This exchange of virtual photons, for example, generates

2548-426: A graphical model that represents the territory of a city or country. In this approach, theories are a specific category of models that fulfill the necessary criteria (see above ). One can use language to describe a model; however, the theory is the model (or a collection of similar models), and not the description of the model. A model of the solar system, for example, might consist of abstract objects that represent

2730-465: A hierarchy of increasing certainty. Facts are the world's data. Theories are structures of ideas that explain and interpret facts." The meaning of the term scientific theory (often contracted to theory for brevity) as used in the disciplines of science is significantly different from the common vernacular usage of theory . In everyday speech, theory can imply an explanation that represents an unsubstantiated and speculative guess , whereas in

2912-467: A loss of information, though: knowing the reduced density matrices of the individual systems is not enough to reconstruct the state of the composite system. Just as density matrices specify the state of a subsystem of a larger system, analogously, positive operator-valued measures (POVMs) describe the effect on a subsystem of a measurement performed on a larger system. POVMs are extensively used in quantum information theory. As described above, entanglement

3094-426: A mathematical formulation of quantum mechanics and survey its application to some useful and oft-studied examples. In the mathematically rigorous formulation of quantum mechanics, the state of a quantum mechanical system is a vector ψ {\displaystyle \psi } belonging to a ( separable ) complex Hilbert space H {\displaystyle {\mathcal {H}}} . This vector

3276-415: A measurement of its position and also at the same time for a measurement of its momentum . Another consequence of the mathematical rules of quantum mechanics is the phenomenon of quantum interference , which is often illustrated with the double-slit experiment . In the basic version of this experiment, a coherent light source , such as a laser beam, illuminates a plate pierced by two parallel slits, and

3458-464: A model of the electron – the Dirac equation , consistent with relativity theory, by applying relativistic and symmetry considerations to the hamiltonian formulation of the quantum mechanics of the electro-magnetic field. In order to resolve some problems within his relativistic equation, Dirac developed in 1930 a model of the vacuum as an infinite sea of particles with negative energy, later dubbed

3640-474: A more accurate theory is then required. Some theories are so well-established that they are unlikely ever to be fundamentally changed (for example, scientific theories such as evolution , heliocentric theory , cell theory , theory of plate tectonics , germ theory of disease , etc.). In certain cases, a scientific theory or scientific law that fails to fit all data can still be useful (due to its simplicity) as an approximation under specific conditions. An example

3822-456: A particle with a positive charge, such as the proton, and a repulsive force on a particle with a negative charge. The strength of this force in nonrelativistic approximation is determined by Coulomb's inverse square law . When an electron is in motion, it generates a magnetic field . The Ampère–Maxwell law relates the magnetic field to the mass motion of electrons (the current ) with respect to an observer. This property of induction supplies

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4004-471: A probability amplitude. Applying the Born rule to these amplitudes gives a probability density function for the position that the electron will be found to have when an experiment is performed to measure it. This is the best the theory can do; it cannot say for certain where the electron will be found. The Schrödinger equation relates the collection of probability amplitudes that pertain to one moment of time to

4186-410: A scale model of a house or of a solar system is clearly not an actual house or an actual solar system; the aspects of an actual house or an actual solar system represented in a scale model are, only in certain limited ways, representative of the actual entity. A scale model of a house is not a house; but to someone who wants to learn about houses, analogous to a scientist who wants to understand reality,

4368-415: A scientific context it most often refers to an explanation that has already been tested and is widely accepted as valid. The strength of a scientific theory is related to the diversity of phenomena it can explain and its simplicity. As additional scientific evidence is gathered, a scientific theory may be modified and ultimately rejected if it cannot be made to fit the new findings; in such circumstances,

4550-405: A single electron in an unexcited atom is pictured classically as a particle moving in a circular trajectory around the atomic nucleus , whereas in quantum mechanics, it is described by a static wave function surrounding the nucleus. For example, the electron wave function for an unexcited hydrogen atom is a spherically symmetric function known as an s orbital ( Fig. 1 ). Analytic solutions of

4732-604: A single electron. This prohibition against more than one electron occupying the same quantum energy state became known as the Pauli exclusion principle . The physical mechanism to explain the fourth parameter, which had two distinct possible values, was provided by the Dutch physicists Samuel Goudsmit and George Uhlenbeck . In 1925, they suggested that an electron, in addition to the angular momentum of its orbit, possesses an intrinsic angular momentum and magnetic dipole moment . This

4914-551: A single spatial dimension. A free particle is one which is not subject to external influences, so that its Hamiltonian consists only of its kinetic energy: The general solution of the Schrödinger equation is given by which is a superposition of all possible plane waves e i ( k x − ℏ k 2 2 m t ) {\displaystyle e^{i(kx-{\frac {\hbar k^{2}}{2m}}t)}} , which are eigenstates of

5096-482: A solution that determined the location of an electron over time, this wave equation also could be used to predict the probability of finding an electron near a position, especially a position near where the electron was bound in space, for which the electron wave equations did not change in time. This approach led to a second formulation of quantum mechanics (the first by Heisenberg in 1925), and solutions of Schrödinger's equation, like Heisenberg's, provided derivations of

5278-420: A sufficiently detailed scale model may suffice. Several commentators have stated that the distinguishing characteristic of theories is that they are explanatory as well as descriptive, while models are only descriptive (although still predictive in a more limited sense). Philosopher Stephen Pepper also distinguished between theories and models, and said in 1948 that general models and theories are predicated on

5460-437: A surplus of the charge carrier, and which situation was a deficit. Between 1838 and 1851, British natural philosopher Richard Laming developed the idea that an atom is composed of a core of matter surrounded by subatomic particles that had unit electric charges . Beginning in 1846, German physicist Wilhelm Eduard Weber theorized that electricity was composed of positively and negatively charged fluids, and their interaction

5642-542: A theory by finding even a single observation that disagrees with the predictions of the theory". Several philosophers and historians of science have, however, argued that Popper's definition of theory as a set of falsifiable statements is wrong because, as Philip Kitcher has pointed out, if one took a strictly Popperian view of "theory", observations of Uranus when first discovered in 1781 would have "falsified" Newton's celestial mechanics. Rather, people suggested that another planet influenced Uranus' orbit—and this prediction

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5824-417: A theory does not require modification despite repeated tests, this implies that the theory is very accurate. This also means that accepted theories continue to accumulate evidence over time, and the length of time that a theory (or any of its principles) remains accepted often indicates the strength of its supporting evidence. In some cases, two or more theories may be replaced by a single theory that explains

6006-411: A theory is proposed and accepted, the previous theory will be retained. This is because it is still the best available explanation for many other phenomena, as verified by its predictive power in other contexts. For example, it has been known since 1859 that the observed perihelion precession of Mercury violates Newtonian mechanics, but the theory remained the best explanation available until relativity

6188-441: A theory must include statements that have observational consequences. But, like the observation of irregularities in the orbit of Uranus, falsification is only one possible consequence of observation. The production of new hypotheses is another possible and equally important result. The concept of a scientific theory has also been described using analogies and metaphors. For example, the logical empiricist Carl Gustav Hempel likened

6370-473: Is and this provides the lower bound on the product of standard deviations: Another consequence of the canonical commutation relation is that the position and momentum operators are Fourier transforms of each other, so that a description of an object according to its momentum is the Fourier transform of its description according to its position. The fact that dependence in momentum is the Fourier transform of

6552-838: Is Newton's laws of motion , which are a highly accurate approximation to special relativity at velocities that are small relative to the speed of light . Scientific theories are testable and make verifiable predictions . They describe the causes of a particular natural phenomenon and are used to explain and predict aspects of the physical universe or specific areas of inquiry (for example, electricity, chemistry, and astronomy). As with other forms of scientific knowledge, scientific theories are both deductive and inductive , aiming for predictive and explanatory power . Scientists use theories to further scientific knowledge, as well as to facilitate advances in technology or medicine . Scientific hypotheses can never be "proven" because scientists are not able to fully confirm that their hypothesis

6734-407: Is a challenging problem of modern theoretical physics. The admission of the hypothesis of a finite radius of the electron is incompatible to the premises of the theory of relativity. On the other hand, a point-like electron (zero radius) generates serious mathematical difficulties due to the self-energy of the electron tending to infinity. Observation of a single electron in a Penning trap suggests

6916-467: Is a combination of the words electr ic and i on . The suffix - on which is now used to designate other subatomic particles, such as a proton or neutron, is in turn derived from electron. While studying electrical conductivity in rarefied gases in 1859, the German physicist Julius Plücker observed the radiation emitted from the cathode caused phosphorescent light to appear on the tube wall near

7098-617: Is a conjunction of ad- ("to, towards, at") and sumere (to take). The root survives, with shifted meanings, in the Italian assumere and Spanish sumir . The first sense of "assume" in the OED is "to take unto (oneself), receive, accept, adopt". The term was originally employed in religious contexts as in "to receive up into heaven", especially "the reception of the Virgin Mary into heaven, with body preserved from corruption", (1297 CE) but it

7280-409: Is a good theory if it satisfies two requirements: It must accurately describe a large class of observations on the basis of a model that contains only a few arbitrary elements, and it must make definite predictions about the results of future observations." He also discusses the "unprovable but falsifiable" nature of theories, which is a necessary consequence of inductive logic, and that "you can disprove

7462-477: Is a key feature of models of measurement processes in which an apparatus becomes entangled with the system being measured. Systems interacting with the environment in which they reside generally become entangled with that environment, a phenomenon known as quantum decoherence . This can explain why, in practice, quantum effects are difficult to observe in systems larger than microscopic. There are many mathematically equivalent formulations of quantum mechanics. One of

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7644-665: Is a statement that is accepted without evidence. For example, assumptions can be used as premises in a logical argument. Isaac Asimov described assumptions as follows: ...it is incorrect to speak of an assumption as either true or false, since there is no way of proving it to be either (If there were, it would no longer be an assumption). It is better to consider assumptions as either useful or useless, depending on whether deductions made from them corresponded to reality...Since we must start somewhere, we must have assumptions, but at least let us have as few assumptions as possible. Certain assumptions are necessary for all empirical claims (e.g.

7826-422: Is a valid joint state that is not separable. States that are not separable are called entangled . If the state for a composite system is entangled, it is impossible to describe either component system A or system B by a state vector. One can instead define reduced density matrices that describe the statistics that can be obtained by making measurements on either component system alone. This necessarily causes

8008-475: Is achieved. Since each new version of a theory (or a completely new theory) must have more predictive and explanatory power than the last, scientific knowledge consistently becomes more accurate over time. If modifications to the theory or other explanations seem to be insufficient to account for the new results, then a new theory may be required. Since scientific knowledge is usually durable, this occurs much less commonly than modification. Furthermore, until such

8190-496: Is actually smaller than its true value, and the charge decreases with increasing distance from the electron. This polarization was confirmed experimentally in 1997 using the Japanese TRISTAN particle accelerator. Virtual particles cause a comparable shielding effect for the mass of the electron. The interaction with virtual particles also explains the small (about 0.1%) deviation of the intrinsic magnetic moment of

8372-587: Is also resolved by either further evidence or unification. For example, physical theories in the 19th century implied that the Sun could not have been burning long enough to allow certain geological changes as well as the evolution of life. This was resolved by the discovery of nuclear fusion , the main energy source of the Sun. Contradictions can also be explained as the result of theories approximating more fundamental (non-contradictory) phenomena. For example, atomic theory

8554-559: Is also tested, and if it fulfills the necessary criteria (see above), then the explanation becomes a theory. This can take many years, as it can be difficult or complicated to gather sufficient evidence. Once all of the criteria have been met, it will be widely accepted by scientists (see scientific consensus ) as the best available explanation of at least some phenomena. It will have made predictions of phenomena that previous theories could not explain or could not predict accurately, and it will have many repeated bouts of testing. The strength of

8736-593: Is an approximation of quantum mechanics . Current theories describe three separate fundamental phenomena of which all other theories are approximations; the potential unification of these is sometimes called the Theory of Everything . In 1905, Albert Einstein published the principle of special relativity , which soon became a theory. Special relativity predicted the alignment of the Newtonian principle of Galilean invariance , also termed Galilean relativity , with

8918-543: Is analogous to the rotation of the Earth on its axis as it orbits the Sun. The intrinsic angular momentum became known as spin , and explained the previously mysterious splitting of spectral lines observed with a high-resolution spectrograph ; this phenomenon is known as fine structure splitting. In his 1924 dissertation Recherches sur la théorie des quanta (Research on Quantum Theory), French physicist Louis de Broglie hypothesized that all matter can be represented as

9100-479: Is approximately 9.109 × 10  kg , or 5.489 × 10   Da . Due to mass–energy equivalence , this corresponds to a rest energy of 0.511 MeV (8.19 × 10  J) . The ratio between the mass of a proton and that of an electron is about 1836. Astronomical measurements show that the proton-to-electron mass ratio has held the same value, as is predicted by the Standard Model, for at least half

9282-434: Is both a theory and a fact . The logical positivists thought of scientific theories as statements in a formal language . First-order logic is an example of a formal language. The logical positivists envisaged a similar scientific language. In addition to scientific theories, the language also included observation sentences ("the sun rises in the east"), definitions, and mathematical statements. The phenomena explained by

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9464-405: Is conserved under the evolution generated by B {\displaystyle B} . This implies a quantum version of the result proven by Emmy Noether in classical ( Lagrangian ) mechanics: for every differentiable symmetry of a Hamiltonian, there exists a corresponding conservation law . The simplest example of a quantum system with a position degree of freedom is a free particle in

9646-1063: Is considered as a sum over all possible classical and non-classical paths between the initial and final states. This is the quantum-mechanical counterpart of the action principle in classical mechanics. The Hamiltonian H {\displaystyle H} is known as the generator of time evolution, since it defines a unitary time-evolution operator U ( t ) = e − i H t / ℏ {\displaystyle U(t)=e^{-iHt/\hbar }} for each value of t {\displaystyle t} . From this relation between U ( t ) {\displaystyle U(t)} and H {\displaystyle H} , it follows that any observable A {\displaystyle A} that commutes with H {\displaystyle H} will be conserved : its expectation value will not change over time. This statement generalizes, as mathematically, any Hermitian operator A {\displaystyle A} can generate

9828-448: Is given by The operator U ( t ) = e − i H t / ℏ {\displaystyle U(t)=e^{-iHt/\hbar }} is known as the time-evolution operator, and has the crucial property that it is unitary . This time evolution is deterministic in the sense that – given an initial quantum state ψ ( 0 ) {\displaystyle \psi (0)} – it makes

10010-455: Is in existence, the Coulomb force from the ambient electric field surrounding an electron causes a created positron to be attracted to the original electron, while a created electron experiences a repulsion. This causes what is called vacuum polarization . In effect, the vacuum behaves like a medium having a dielectric permittivity more than unity . Thus the effective charge of an electron

10192-406: Is its associated eigenvector. More generally, the eigenvalue is degenerate and the probability is given by ⟨ ψ , P λ ψ ⟩ {\displaystyle \langle \psi ,P_{\lambda }\psi \rangle } , where P λ {\displaystyle P_{\lambda }} is the projector onto its associated eigenspace. In

10374-722: Is known as wave–particle duality . In addition to light, electrons , atoms , and molecules are all found to exhibit the same dual behavior when fired towards a double slit. Another non-classical phenomenon predicted by quantum mechanics is quantum tunnelling : a particle that goes up against a potential barrier can cross it, even if its kinetic energy is smaller than the maximum of the potential. In classical mechanics this particle would be trapped. Quantum tunnelling has several important consequences, enabling radioactive decay , nuclear fusion in stars, and applications such as scanning tunnelling microscopy , tunnel diode and tunnel field-effect transistor . When quantum systems interact,

10556-465: Is moving relative to an observer, the observer will observe it to generate a magnetic field . Electromagnetic fields produced from other sources will affect the motion of an electron according to the Lorentz force law . Electrons radiate or absorb energy in the form of photons when they are accelerated. Laboratory instruments are capable of trapping individual electrons as well as electron plasma by

10738-443: Is not possible for the solution to be a single momentum eigenstate, or a single position eigenstate, as these are not normalizable quantum states. Instead, we can consider a Gaussian wave packet : which has Fourier transform, and therefore momentum distribution We see that as we make a {\displaystyle a} smaller the spread in position gets smaller, but the spread in momentum gets larger. Conversely, by making

10920-627: Is not sufficient for describing them at very small submicroscopic (atomic and subatomic ) scales. Most theories in classical physics can be derived from quantum mechanics as an approximation, valid at large (macroscopic/microscopic) scale. Quantum systems have bound states that are quantized to discrete values of energy , momentum , angular momentum , and other quantities, in contrast to classical systems where these quantities can be measured continuously. Measurements of quantum systems show characteristics of both particles and waves ( wave–particle duality ), and there are limits to how accurately

11102-570: Is one of humanity's earliest recorded experiences with electricity . In his 1600 treatise De Magnete , the English scientist William Gilbert coined the Neo-Latin term electrica , to refer to those substances with property similar to that of amber which attract small objects after being rubbed. Both electric and electricity are derived from the Latin ēlectrum (also the root of

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11284-813: Is part of quantum communication protocols, such as quantum key distribution and superdense coding . Contrary to popular misconception, entanglement does not allow sending signals faster than light , as demonstrated by the no-communication theorem . Another possibility opened by entanglement is testing for " hidden variables ", hypothetical properties more fundamental than the quantities addressed in quantum theory itself, knowledge of which would allow more exact predictions than quantum theory provides. A collection of results, most significantly Bell's theorem , have demonstrated that broad classes of such hidden-variable theories are in fact incompatible with quantum physics. According to Bell's theorem, if nature actually operates in accord with any theory of local hidden variables, then

11466-407: Is passed through parallel slits thereby creating interference patterns. In 1927, George Paget Thomson and Alexander Reid discovered the interference effect was produced when a beam of electrons was passed through thin celluloid foils and later metal films, and by American physicists Clinton Davisson and Lester Germer by the reflection of electrons from a crystal of nickel . Alexander Reid, who

11648-540: Is postulated to be normalized under the Hilbert space inner product, that is, it obeys ⟨ ψ , ψ ⟩ = 1 {\displaystyle \langle \psi ,\psi \rangle =1} , and it is well-defined up to a complex number of modulus 1 (the global phase), that is, ψ {\displaystyle \psi } and e i α ψ {\displaystyle e^{i\alpha }\psi } represent

11830-465: Is replaced by − i ℏ ∂ ∂ x {\displaystyle -i\hbar {\frac {\partial }{\partial x}}} , and in particular in the non-relativistic Schrödinger equation in position space the momentum-squared term is replaced with a Laplacian times − ℏ 2 {\displaystyle -\hbar ^{2}} . When two different quantum systems are considered together,

12012-510: Is supported by a vast body of evidence. Many scientific theories are so well established that no new evidence is likely to alter them substantially. For example, no new evidence will demonstrate that the Earth does not orbit around the Sun (heliocentric theory), or that living things are not made of cells (cell theory), that matter is not composed of atoms, or that the surface of the Earth is not divided into solid plates that have moved over geological timescales (the theory of plate tectonics)...One of

12194-664: Is that scientific theories are rudimentary ideas that will eventually graduate into scientific laws when enough data and evidence have been accumulated. A theory does not change into a scientific law with the accumulation of new or better evidence. A theory will always remain a theory; a law will always remain a law. Both theories and laws could potentially be falsified by countervailing evidence. Theories and laws are also distinct from hypotheses . Unlike hypotheses, theories and laws may be simply referred to as scientific fact . However, in science, theories are different from facts even when they are well supported. For example, evolution

12376-415: Is the reduced Planck constant . The constant i ℏ {\displaystyle i\hbar } is introduced so that the Hamiltonian is reduced to the classical Hamiltonian in cases where the quantum system can be approximated by a classical system; the ability to make such an approximation in certain limits is called the correspondence principle . The solution of this differential equation

12558-469: Is then If the state for the first system is the vector ψ A {\displaystyle \psi _{A}} and the state for the second system is ψ B {\displaystyle \psi _{B}} , then the state of the composite system is Not all states in the joint Hilbert space H A B {\displaystyle {\mathcal {H}}_{AB}} can be written in this form, however, because

12740-477: Is true. Instead, scientists say that the study "supports" or is consistent with their hypothesis. Albert Einstein described two different types of scientific theories: "Constructive theories" and "principle theories". Constructive theories are constructive models for phenomena: for example, kinetic theory . Principle theories are empirical generalisations, one such example being Newton's laws of motion . For any theory to be accepted within most academia there

12922-430: Is usually one simple criterion. The essential criterion is that the theory must be observable and repeatable. The aforementioned criterion is essential to prevent fraud and perpetuate science itself. The defining characteristic of all scientific knowledge, including theories, is the ability to make falsifiable or testable predictions . The relevance and specificity of those predictions determine how potentially useful

13104-505: The Born rule : in the simplest case the eigenvalue λ {\displaystyle \lambda } is non-degenerate and the probability is given by | ⟨ λ → , ψ ⟩ | 2 {\displaystyle |\langle {\vec {\lambda }},\psi \rangle |^{2}} , where λ → {\displaystyle {\vec {\lambda }}}

13286-461: The Dirac sea . This led him to predict the existence of a positron, the antimatter counterpart of the electron. This particle was discovered in 1932 by Carl Anderson , who proposed calling standard electrons negatrons and using electron as a generic term to describe both the positively and negatively charged variants. In 1947, Willis Lamb , working in collaboration with graduate student Robert Retherford , found that certain quantum states of

13468-458: The Lamb shift observed in spectral lines . The Compton Wavelength shows that near elementary particles such as the electron, the uncertainty of the energy allows for the creation of virtual particles near the electron. This wavelength explains the "static" of virtual particles around elementary particles at a close distance. An electron generates an electric field that exerts an attractive force on

13650-476: The Standard Model of particle physics. Individual electrons can now be easily confined in ultra small ( L = 20 nm , W = 20 nm ) CMOS transistors operated at cryogenic temperature over a range of −269 °C (4  K ) to about −258 °C (15  K ). The electron wavefunction spreads in a semiconductor lattice and negligibly interacts with the valence band electrons, so it can be treated in

13832-416: The absolute value of this function is squared , it gives the probability that a particle will be observed near a location—a probability density . Electrons are identical particles because they cannot be distinguished from each other by their intrinsic physical properties. In quantum mechanics, this means that a pair of interacting electrons must be able to swap positions without an observable change to

14014-414: The age of the universe . Electrons have an electric charge of −1.602 176 634 × 10 coulombs , which is used as a standard unit of charge for subatomic particles, and is also called the elementary charge . Within the limits of experimental accuracy, the electron charge is identical to the charge of a proton, but with the opposite sign. The electron is commonly symbolized by e , and

14196-726: The alloy of the same name ), which came from the Greek word for amber, ἤλεκτρον ( ēlektron ). In the early 1700s, French chemist Charles François du Fay found that if a charged gold-leaf is repulsed by glass rubbed with silk, then the same charged gold-leaf is attracted by amber rubbed with wool. From this and other results of similar types of experiments, du Fay concluded that electricity consists of two electrical fluids , vitreous fluid from glass rubbed with silk and resinous fluid from amber rubbed with wool. These two fluids can neutralize each other when combined. American scientist Ebenezer Kinnersley later also independently reached

14378-712: The canonical commutation relation : Given a quantum state, the Born rule lets us compute expectation values for both X {\displaystyle X} and P {\displaystyle P} , and moreover for powers of them. Defining the uncertainty for an observable by a standard deviation , we have and likewise for the momentum: The uncertainty principle states that Either standard deviation can in principle be made arbitrarily small, but not both simultaneously. This inequality generalizes to arbitrary pairs of self-adjoint operators A {\displaystyle A} and B {\displaystyle B} . The commutator of these two operators

14560-405: The double-slit experiment . The wave-like nature of the electron allows it to pass through two parallel slits simultaneously, rather than just one slit as would be the case for a classical particle. In quantum mechanics, the wave-like property of one particle can be described mathematically as a complex -valued function, the wave function , commonly denoted by the Greek letter psi ( ψ ). When

14742-462: The e / m ratio but did not take the step of interpreting their results as showing a new particle, while J. J. Thomson would subsequently in 1899 give estimates for the electron charge and mass as well: e  ~  6.8 × 10   esu and m  ~  3 × 10  g The name "electron" was adopted for these particles by the scientific community, mainly due to the advocation by G. F. FitzGerald , J. Larmor , and H. A. Lorentz . The term

14924-402: The modern evolutionary synthesis , etc. In addition, most scientists prefer to work with a theory that meets the following qualities: The United States National Academy of Sciences defines scientific theories as follows: The formal scientific definition of theory is quite different from the everyday meaning of the word. It refers to a comprehensive explanation of some aspect of nature that

15106-414: The muon and the tau , which are identical to the electron in charge, spin and interactions , but are more massive. Leptons differ from the other basic constituent of matter, the quarks , by their lack of strong interaction . All members of the lepton group are fermions because they all have half-odd integer spin; the electron has spin ⁠ 1 / 2 ⁠ . The invariant mass of an electron

15288-423: The photoelectric effect . These early attempts to understand microscopic phenomena, now known as the " old quantum theory ", led to the full development of quantum mechanics in the mid-1920s by Niels Bohr , Erwin Schrödinger , Werner Heisenberg , Max Born , Paul Dirac and others. The modern theory is formulated in various specially developed mathematical formalisms . In one of them, a mathematical entity called

15470-459: The spectral lines of the hydrogen atom. However, Bohr's model failed to account for the relative intensities of the spectral lines and it was unsuccessful in explaining the spectra of more complex atoms. Chemical bonds between atoms were explained by Gilbert Newton Lewis , who in 1916 proposed that a covalent bond between two atoms is maintained by a pair of electrons shared between them. Later, in 1927, Walter Heitler and Fritz London gave

15652-399: The spinon , the orbiton and the holon (or chargon). The electron can always be theoretically considered as a bound state of the three, with the spinon carrying the spin of the electron, the orbiton carrying the orbital degree of freedom and the chargon carrying the charge, but in certain conditions they can behave as independent quasiparticles . The issue of the radius of the electron

15834-561: The wave function provides information, in the form of probability amplitudes , about what measurements of a particle's energy, momentum, and other physical properties may yield. Quantum mechanics allows the calculation of properties and behaviour of physical systems. It is typically applied to microscopic systems: molecules, atoms and sub-atomic particles. It has been demonstrated to hold for complex molecules with thousands of atoms, but its application to human beings raises philosophical problems, such as Wigner's friend , and its application to

16016-599: The 1870s, the English chemist and physicist Sir William Crookes developed the first cathode-ray tube to have a high vacuum inside. He then showed in 1874 that the cathode rays can turn a small paddle wheel when placed in their path. Therefore, he concluded that the rays carried momentum. Furthermore, by applying a magnetic field, he was able to deflect the rays, thereby demonstrating that the beam behaved as though it were negatively charged. In 1879, he proposed that these properties could be explained by regarding cathode rays as composed of negatively charged gaseous molecules in

16198-477: The Coulomb force. Energy emission can occur when a moving electron is deflected by a charged particle, such as a proton. The deceleration of the electron results in the emission of Bremsstrahlung radiation. An inelastic collision between a photon (light) and a solitary (free) electron is called Compton scattering . This collision results in a transfer of momentum and energy between the particles, which modifies

16380-431: The Hilbert space for the spin of a single proton is simply the space of two-dimensional complex vectors C 2 {\displaystyle \mathbb {C} ^{2}} with the usual inner product. Physical quantities of interest – position, momentum, energy, spin – are represented by observables, which are Hermitian (more precisely, self-adjoint ) linear operators acting on

16562-411: The Hilbert space of the combined system is the tensor product of the Hilbert spaces of the two components. For example, let A and B be two quantum systems, with Hilbert spaces H A {\displaystyle {\mathcal {H}}_{A}} and H B {\displaystyle {\mathcal {H}}_{B}} , respectively. The Hilbert space of the composite system

16744-432: The Hilbert space. A quantum state can be an eigenvector of an observable, in which case it is called an eigenstate , and the associated eigenvalue corresponds to the value of the observable in that eigenstate. More generally, a quantum state will be a linear combination of the eigenstates, known as a quantum superposition . When an observable is measured, the result will be one of its eigenvalues with probability given by

16926-486: The Schrödinger equation are known for very few relatively simple model Hamiltonians including the quantum harmonic oscillator , the particle in a box , the dihydrogen cation , and the hydrogen atom . Even the helium atom – which contains just two electrons – has defied all attempts at a fully analytic treatment, admitting no solution in closed form . However, there are techniques for finding approximate solutions. One method, called perturbation theory , uses

17108-760: The Schrödinger equation for the particle in a box are or, from Euler's formula , Scientific theory A scientific theory is an explanation of an aspect of the natural world and universe that can be (or a fortiori , that has been) repeatedly tested and corroborated in accordance with the scientific method , using accepted protocols of observation , measurement, and evaluation of results. Where possible, theories are tested under controlled conditions in an experiment . In circumstances not amenable to experimental testing, theories are evaluated through principles of abductive reasoning . Established scientific theories have withstood rigorous scrutiny and embody scientific knowledge . A scientific theory differs from

17290-523: The aether's properties. An elegant theory, special relativity yielded its own consequences, such as the equivalence of mass and energy transforming into one another and the resolution of the paradox that an excitation of the electromagnetic field could be viewed in one reference frame as electricity, but in another as magnetism. Einstein sought to generalize the invariance principle to all reference frames, whether inertial or accelerating. Rejecting Newtonian gravitation—a central force acting instantly at

17472-399: The analytic result for a simple quantum mechanical model to create a result for a related but more complicated model by (for example) the addition of a weak potential energy . Another approximation method applies to systems for which quantum mechanics produces only small deviations from classical behavior. These deviations can then be computed based on the classical motion. One consequence of

17654-513: The assumption is valid, and does not make accurate predictions when the assumption is not valid. Such assumptions are often the point with which older theories are succeeded by new ones (the general theory of relativity works in non-inertial reference frames as well). The term "assumption" is actually broader than its standard use, etymologically speaking. The Oxford English Dictionary (OED) and online Wiktionary indicate its Latin source as assumere ("accept, to take to oneself, adopt, usurp"), which

17836-426: The assumption that reality exists). However, theories do not generally make assumptions in the conventional sense (statements accepted without evidence). While assumptions are often incorporated during the formation of new theories, these are either supported by evidence (such as from previously existing theories) or the evidence is produced in the course of validating the theory. This may be as simple as observing that

18018-420: The atmosphere. The antiparticle of the electron is called the positron ; it is identical to the electron, except that it carries electrical charge of the opposite sign. When an electron collides with a positron , both particles can be annihilated , producing gamma ray photons . The ancient Greeks noticed that amber attracted small objects when rubbed with fur. Along with lightning , this phenomenon

18200-604: The basic quantum formalism is the uncertainty principle. In its most familiar form, this states that no preparation of a quantum particle can imply simultaneously precise predictions both for a measurement of its position and for a measurement of its momentum. Both position and momentum are observables, meaning that they are represented by Hermitian operators . The position operator X ^ {\displaystyle {\hat {X}}} and momentum operator P ^ {\displaystyle {\hat {P}}} do not commute, but rather satisfy

18382-480: The beginning of the twentieth century, it was found that under certain conditions a fast-moving charged particle caused a condensation of supersaturated water vapor along its path. In 1911, Charles Wilson used this principle to devise his cloud chamber so he could photograph the tracks of charged particles, such as fast-moving electrons. By 1914, experiments by physicists Ernest Rutherford , Henry Moseley , James Franck and Gustav Hertz had largely established

18564-402: The cathode; and the region of the phosphorescent light could be moved by application of a magnetic field. In 1869, Plücker's student Johann Wilhelm Hittorf found that a solid body placed in between the cathode and the phosphorescence would cast a shadow upon the phosphorescent region of the tube. Hittorf inferred that there are straight rays emitted from the cathode and that the phosphorescence

18746-553: The charge carriers were much heavier hydrogen or nitrogen atoms. Schuster's estimates would subsequently turn out to be largely correct. In 1892 Hendrik Lorentz suggested that the mass of these particles (electrons) could be a consequence of their electric charge. While studying naturally fluorescing minerals in 1896, the French physicist Henri Becquerel discovered that they emitted radiation without any exposure to an external energy source. These radioactive materials became

18928-402: The collection of probability amplitudes that pertain to another. One consequence of the mathematical rules of quantum mechanics is a tradeoff in predictability between measurable quantities. The most famous form of this uncertainty principle says that no matter how a quantum particle is prepared or how carefully experiments upon it are arranged, it is impossible to have a precise prediction for

19110-588: The concept of an indivisible quantity of electric charge to explain the chemical properties of atoms. Irish physicist George Johnstone Stoney named this charge "electron" in 1891, and J. J. Thomson and his team of British physicists identified it as a particle in 1897 during the cathode-ray tube experiment . Electrons participate in nuclear reactions , such as nucleosynthesis in stars , where they are known as beta particles . Electrons can be created through beta decay of radioactive isotopes and in high-energy collisions, for instance, when cosmic rays enter

19292-492: The contemporary standard sense of "that which is assumed or taken for granted; a supposition, postulate" (only the 11th of 12 senses of "assumption", and the 10th of 11 senses of "assume"). Karl Popper described the characteristics of a scientific theory as follows: Popper summarized these statements by saying that the central criterion of the scientific status of a theory is its "falsifiability, or refutability, or testability". Echoing this, Stephen Hawking states, "A theory

19474-626: The continuous case, these formulas give instead the probability density . After the measurement, if result λ {\displaystyle \lambda } was obtained, the quantum state is postulated to collapse to λ → {\displaystyle {\vec {\lambda }}} , in the non-degenerate case, or to P λ ψ / ⟨ ψ , P λ ψ ⟩ {\textstyle P_{\lambda }\psi {\big /}\!{\sqrt {\langle \psi ,P_{\lambda }\psi \rangle }}} , in

19656-430: The deflecting electrodes in a highly-conductive area of the tube, resulting in a strong screening effect close to their surface. The German-born British physicist Arthur Schuster expanded upon Crookes's experiments by placing metal plates parallel to the cathode rays and applying an electric potential between the plates. The field deflected the rays toward the positively charged plate, providing further evidence that

19838-431: The dependence in position means that the momentum operator is equivalent (up to an i / ℏ {\displaystyle i/\hbar } factor) to taking the derivative according to the position, since in Fourier analysis differentiation corresponds to multiplication in the dual space . This is why in quantum equations in position space, the momentum p i {\displaystyle p_{i}}

20020-400: The effective demise of logical positivism in the 1970s. The semantic view of theories , which identifies scientific theories with models rather than propositions , has replaced the received view as the dominant position in theory formulation in the philosophy of science. A model is a logical framework intended to represent reality (a "model of reality"), similar to the way that a map is

20202-427: The effects of quantum mechanics ; in reality, the so-called classical electron radius has little to do with the true fundamental structure of the electron. There are elementary particles that spontaneously decay into less massive particles. An example is the muon , with a mean lifetime of 2.2 × 10  seconds, which decays into an electron, a muon neutrino and an electron antineutrino . The electron, on

20384-532: The electromagnetic field. By omitting from special relativity the luminiferous aether , Einstein stated that time dilation and length contraction measured in an object in relative motion is inertial —that is, the object exhibits constant velocity , which is speed with direction , when measured by its observer. He thereby duplicated the Lorentz transformation and the Lorentz contraction that had been hypothesized to resolve experimental riddles and inserted into electrodynamic theory as dynamical consequences of

20566-454: The electron from the Bohr magneton (the anomalous magnetic moment ). The extraordinarily precise agreement of this predicted difference with the experimentally determined value is viewed as one of the great achievements of quantum electrodynamics . The apparent paradox in classical physics of a point particle electron having intrinsic angular momentum and magnetic moment can be explained by

20748-560: The electron has an intrinsic magnetic moment along its spin axis. It is approximately equal to one Bohr magneton , which is a physical constant that is equal to 9.274 010 0657 (29) × 10  J⋅T . The orientation of the spin with respect to the momentum of the electron defines the property of elementary particles known as helicity . The electron has no known substructure . Nevertheless, in condensed matter physics , spin–charge separation can occur in some materials. In such cases, electrons 'split' into three independent particles,

20930-456: The energy states of an electron in a hydrogen atom that were equivalent to those that had been derived first by Bohr in 1913, and that were known to reproduce the hydrogen spectrum. Once spin and the interaction between multiple electrons were describable, quantum mechanics made it possible to predict the configuration of electrons in atoms with atomic numbers greater than hydrogen. In 1928, building on Wolfgang Pauli's work, Paul Dirac produced

21112-534: The evidence is evaluated by the scientific community, and the most important experiments will have been replicated by multiple independent groups. Theories do not have to be perfectly accurate to be scientifically useful. For example, the predictions made by classical mechanics are known to be inaccurate in the relativistic realm, but they are almost exactly correct at the comparatively low velocities of common human experience. In chemistry , there are many acid-base theories providing highly divergent explanations of

21294-446: The experimental design was sound, and if so they confirm the results by independent replication . A search for potential improvements to the theory then begins. Solutions may require minor or major changes to the theory, or none at all if a satisfactory explanation is found within the theory's existing framework. Over time, as successive modifications build on top of each other, theories consistently improve and greater predictive accuracy

21476-557: The fabrication tolerances are specified. An exploded view drawing is used to lay out the fabrication sequence. Simulation packages for displaying each of the subassemblies allow the parts to be rotated, magnified, in realistic detail. Software packages for creating the bill of materials for construction allows subcontractors to specialize in assembly processes, which spreads the cost of manufacturing machinery among multiple customers. See: Computer-aided engineering , Computer-aided manufacturing , and 3D printing An assumption (or axiom )

21658-448: The first high-energy particle collider was ADONE , which began operations in 1968. This device accelerated electrons and positrons in opposite directions, effectively doubling the energy of their collision when compared to striking a static target with an electron. The Large Electron–Positron Collider (LEP) at CERN , which was operational from 1989 to 2000, achieved collision energies of 209 GeV and made important measurements for

21840-406: The formation of virtual photons in the electric field generated by the electron. These photons can heuristically be thought of as causing the electron to shift about in a jittery fashion (known as zitterbewegung ), which results in a net circular motion with precession . This motion produces both the spin and the magnetic moment of the electron. In atoms, this creation of virtual photons explains

22022-568: The full explanation of the electron-pair formation and chemical bonding in terms of quantum mechanics . In 1919, the American chemist Irving Langmuir elaborated on the Lewis's static model of the atom and suggested that all electrons were distributed in successive "concentric (nearly) spherical shells, all of equal thickness". In turn, he divided the shells into a number of cells each of which contained one pair of electrons. With this model Langmuir

22204-415: The general case. The probabilistic nature of quantum mechanics thus stems from the act of measurement. This is one of the most difficult aspects of quantum systems to understand. It was the central topic in the famous Bohr–Einstein debates , in which the two scientists attempted to clarify these fundamental principles by way of thought experiments . In the decades after the formulation of quantum mechanics,

22386-545: The geometrical "surface" of 4D space-time. Yet unless the energy is vast, its relativistic effects of contracting space and slowing time are negligible when merely predicting motion. Although general relativity is embraced as the more explanatory theory via scientific realism , Newton's theory remains successful as merely a predictive theory via instrumentalism . To calculate trajectories, engineers and NASA still uses Newton's equations, which are simpler to operate. Both scientific laws and scientific theories are produced from

22568-421: The hydrogen atom, which should have the same energy, were shifted in relation to each other; the difference came to be called the Lamb shift . About the same time, Polykarp Kusch , working with Henry M. Foley , discovered the magnetic moment of the electron is slightly larger than predicted by Dirac's theory. This small difference was later called anomalous magnetic dipole moment of the electron. This difference

22750-458: The interference pattern appears via the varying density of these particle hits on the screen. Furthermore, versions of the experiment that include detectors at the slits find that each detected photon passes through one slit (as would a classical particle), and not through both slits (as would a wave). However, such experiments demonstrate that particles do not form the interference pattern if one detects which slit they pass through. This behavior

22932-425: The light passing through the slits is observed on a screen behind the plate. The wave nature of light causes the light waves passing through the two slits to interfere , producing bright and dark bands on the screen – a result that would not be expected if light consisted of classical particles. However, the light is always found to be absorbed at the screen at discrete points, as individual particles rather than waves;

23114-489: The magnetic field and the electron velocity. This centripetal force causes the electron to follow a helical trajectory through the field at a radius called the gyroradius . The acceleration from this curving motion induces the electron to radiate energy in the form of synchrotron radiation. The energy emission in turn causes a recoil of the electron, known as the Abraham–Lorentz–Dirac Force , which creates

23296-462: The magnetic field that drives an electric motor . The electromagnetic field of an arbitrary moving charged particle is expressed by the Liénard–Wiechert potentials , which are valid even when the particle's speed is close to that of light ( relativistic ). When an electron is moving through a magnetic field, it is subject to the Lorentz force that acts perpendicularly to the plane defined by

23478-432: The momentum operator with momentum p = ℏ k {\displaystyle p=\hbar k} . The coefficients of the superposition are ψ ^ ( k , 0 ) {\displaystyle {\hat {\psi }}(k,0)} , which is the Fourier transform of the initial quantum state ψ ( x , 0 ) {\displaystyle \psi (x,0)} . It

23660-622: The most useful properties of scientific theories is that they can be used to make predictions about natural events or phenomena that have not yet been observed. From the American Association for the Advancement of Science : A scientific theory is a well-substantiated explanation of some aspect of the natural world, based on a body of facts that have been repeatedly confirmed through observation and experiment. Such fact-supported theories are not "guesses" but reliable accounts of

23842-426: The negatively charged particles produced by radioactive materials, by heated materials and by illuminated materials were universal. Thomson measured m / e for cathode ray "corpuscles", and made good estimates of the charge e , leading to value for the mass m , finding a value 1400 times less massive than the least massive ion known: hydrogen. In the same year Emil Wiechert and Walter Kaufmann also calculated

24024-412: The oldest and most common is the " transformation theory " proposed by Paul Dirac , which unifies and generalizes the two earliest formulations of quantum mechanics – matrix mechanics (invented by Werner Heisenberg ) and wave mechanics (invented by Erwin Schrödinger ). An alternative formulation of quantum mechanics is Feynman 's path integral formulation , in which a quantum-mechanical amplitude

24206-412: The one-dimensional case in the x {\displaystyle x} direction, the time-independent Schrödinger equation may be written With the differential operator defined by with state ψ {\displaystyle \psi } in this case having energy E {\displaystyle E} coincident with the kinetic energy of the particle. The general solutions of

24388-454: The original quantum system ceases to exist as an independent entity (see Measurement in quantum mechanics ). The time evolution of a quantum state is described by the Schrödinger equation: Here H {\displaystyle H} denotes the Hamiltonian , the observable corresponding to the total energy of the system, and ℏ {\displaystyle \hbar }

24570-430: The other hand, is thought to be stable on theoretical grounds: the electron is the least massive particle with non-zero electric charge, so its decay would violate charge conservation . The experimental lower bound for the electron's mean lifetime is 6.6 × 10 years, at a 90% confidence level . As with all particles, electrons can act as waves. This is called the wave–particle duality and can be demonstrated using

24752-551: The photon, have symmetric wave functions instead. In the case of antisymmetry, solutions of the wave equation for interacting electrons result in a zero probability that each pair will occupy the same location or state. This is responsible for the Pauli exclusion principle , which precludes any two electrons from occupying the same quantum state. This principle explains many of the properties of electrons. For example, it causes groups of bound electrons to occupy different orbitals in an atom, rather than all overlapping each other in

24934-426: The planets. For most planets, the Newtonian model's predictions are accurate; for Mercury , it is slightly inaccurate and the model of general relativity must be used instead. The word " semantic " refers to the way that a model represents the real world. The representation (literally, "re-presentation") describes particular aspects of a phenomenon or the manner of interaction among a set of phenomena. For instance,

25116-425: The position becomes more and more uncertain. The uncertainty in momentum, however, stays constant. The particle in a one-dimensional potential energy box is the most mathematically simple example where restraints lead to the quantization of energy levels. The box is defined as having zero potential energy everywhere inside a certain region, and therefore infinite potential energy everywhere outside that region. For

25298-456: The positive protons within atomic nuclei and the negative electrons without allows the composition of the two known as atoms . Ionization or differences in the proportions of negative electrons versus positive nuclei changes the binding energy of an atomic system. The exchange or sharing of the electrons between two or more atoms is the main cause of chemical bonding . In 1838, British natural philosopher Richard Laming first hypothesized

25480-452: The positron is symbolized by e . The electron has an intrinsic angular momentum or spin of ⁠ ħ / 2 ⁠ . This property is usually stated by referring to the electron as a spin-1/2 particle. For such particles the spin magnitude is ⁠ ħ / 2 ⁠ , while the result of the measurement of a projection of the spin on any axis can only be ± ⁠ ħ / 2 ⁠ . In addition to spin,

25662-413: The previous theories as approximations or special cases, analogous to the way a theory is a unifying explanation for many confirmed hypotheses; this is referred to as unification of theories. For example, electricity and magnetism are now known to be two aspects of the same phenomenon, referred to as electromagnetism . When the predictions of different theories appear to contradict each other, this

25844-463: The proposal and testing of hypotheses , by deriving predictions from the hypotheses about the results of future experiments, then performing those experiments to see whether the predictions are valid. This provides evidence either for or against the hypothesis. When enough experimental results have been gathered in a particular area of inquiry, scientists may propose an explanatory framework that accounts for as many of these as possible. This explanation

26026-400: The question of what constitutes a "measurement" has been extensively studied. Newer interpretations of quantum mechanics have been formulated that do away with the concept of " wave function collapse " (see, for example, the many-worlds interpretation ). The basic idea is that when a quantum system interacts with a measuring apparatus, their respective wave functions become entangled so that

26208-403: The rays carried negative charge. By measuring the amount of deflection for a given electric and magnetic field , in 1890 Schuster was able to estimate the charge-to-mass ratio of the ray components. However, this produced a value that was more than a thousand times greater than what was expected, so little credence was given to his calculations at the time. This is because it was assumed that

26390-483: The real world. The theory of biological evolution is more than "just a theory". It is as factual an explanation of the universe as the atomic theory of matter or the germ theory of disease. Our understanding of gravity is still a work in progress. But the phenomenon of gravity, like evolution, is an accepted fact. Note that the term theory would not be appropriate for describing untested but intricate hypotheses or even scientific models. The scientific method involves

26572-412: The result can be the creation of quantum entanglement : their properties become so intertwined that a description of the whole solely in terms of the individual parts is no longer possible. Erwin Schrödinger called entanglement "... the characteristic trait of quantum mechanics, the one that enforces its entire departure from classical lines of thought". Quantum entanglement enables quantum computing and

26754-562: The results of a Bell test will be constrained in a particular, quantifiable way. Many Bell tests have been performed and they have shown results incompatible with the constraints imposed by local hidden variables. It is not possible to present these concepts in more than a superficial way without introducing the mathematics involved; understanding quantum mechanics requires not only manipulating complex numbers, but also linear algebra , differential equations , group theory , and other more advanced subjects. Accordingly, this article will present

26936-455: The same conclusion. A decade later Benjamin Franklin proposed that electricity was not from different types of electrical fluid, but a single electrical fluid showing an excess (+) or deficit (−). He gave them the modern charge nomenclature of positive and negative respectively. Franklin thought of the charge carrier as being positive, but he did not correctly identify which situation was

27118-423: The same orbit. In a simplified picture, which often tends to give the wrong idea but may serve to illustrate some aspects, every photon spends some time as a combination of a virtual electron plus its antiparticle, the virtual positron, which rapidly annihilate each other shortly thereafter. The combination of the energy variation needed to create these particles, and the time during which they exist, fall under

27300-463: The same physical system. In other words, the possible states are points in the projective space of a Hilbert space, usually called the complex projective space . The exact nature of this Hilbert space is dependent on the system – for example, for describing position and momentum the Hilbert space is the space of complex square-integrable functions L 2 ( C ) {\displaystyle L^{2}(\mathbb {C} )} , while

27482-578: The scientific method through the formation and testing of hypotheses, and can predict the behavior of the natural world. Both are also typically well-supported by observations and/or experimental evidence. However, scientific laws are descriptive accounts of how nature will behave under certain conditions. Scientific theories are broader in scope, and give overarching explanations of how nature works and why it exhibits certain characteristics. Theories are supported by evidence from many different sources, and may contain one or several laws. A common misconception

27664-489: The single particle formalism, by replacing its mass with the effective mass tensor . In the Standard Model of particle physics, electrons belong to the group of subatomic particles called leptons , which are believed to be fundamental or elementary particles . Electrons have the lowest mass of any charged lepton (or electrically charged particle of any type) and belong to the first generation of fundamental particles. The second and third generation contain charged leptons,

27846-435: The state of the system. The wave function of fermions, including electrons, is antisymmetric, meaning that it changes sign when two electrons are swapped; that is, ψ ( r 1 , r 2 ) = − ψ ( r 2 , r 1 ) , where the variables r 1 and r 2 correspond to the first and second electrons, respectively. Since the absolute value is not changed by a sign swap, this corresponds to equal probabilities. Bosons , such as

28028-405: The structure of a scientific theory to a "complex spatial network:" Electron Electrons play an essential role in numerous physical phenomena, such as electricity , magnetism , chemistry , and thermal conductivity ; they also participate in gravitational , electromagnetic , and weak interactions . Since an electron has charge, it has a surrounding electric field ; if that electron

28210-484: The structure of an atom as a dense nucleus of positive charge surrounded by lower-mass electrons. In 1913, Danish physicist Niels Bohr postulated that electrons resided in quantized energy states, with their energies determined by the angular momentum of the electron's orbit about the nucleus. The electrons could move between those states, or orbits, by the emission or absorption of photons of specific frequencies. By means of these quantized orbits, he accurately explained

28392-504: The subject of much interest by scientists, including the New Zealand physicist Ernest Rutherford who discovered they emitted particles. He designated these particles alpha and beta , on the basis of their ability to penetrate matter. In 1900, Becquerel showed that the beta rays emitted by radium could be deflected by an electric field, and that their mass-to-charge ratio was the same as for cathode rays. This evidence strengthened

28574-419: The sun and the planets. These objects have associated properties, e.g., positions, velocities, and masses. The model parameters, e.g., Newton's Law of Gravitation, determine how the positions and velocities change with time. This model can then be tested to see whether it accurately predicts future observations; astronomers can verify that the positions of the model's objects over time match the actual positions of

28756-625: The superposition principle implies that linear combinations of these "separable" or "product states" are also valid. For example, if ψ A {\displaystyle \psi _{A}} and ϕ A {\displaystyle \phi _{A}} are both possible states for system A {\displaystyle A} , and likewise ψ B {\displaystyle \psi _{B}} and ϕ B {\displaystyle \phi _{B}} are both possible states for system B {\displaystyle B} , then

28938-423: The term electrolion in 1881. Ten years later, he switched to electron to describe these elementary charges, writing in 1894: "... an estimate was made of the actual amount of this most remarkable fundamental unit of electricity, for which I have since ventured to suggest the name electron ". A 1906 proposal to change to electrion failed because Hendrik Lorentz preferred to keep electron . The word electron

29120-420: The term "theoretical". These predictions can be tested at a later time, and if they are incorrect, this may lead to the revision or rejection of the theory.As Feynman puts it: It doesn't matter how beautiful your theory is, it doesn't matter how smart you are. If it doesn't agree with experiment, it's wrong. If experimental results contrary to a theory's predictions are observed, scientists first evaluate whether

29302-477: The theories, if they could not be directly observed by the senses (for example, atoms and radio waves ), were treated as theoretical concepts. In this view, theories function as axioms : predicted observations are derived from the theories much like theorems are derived in Euclidean geometry . However, the predictions are then tested against reality to verify the predictions, and the "axioms" can be revised as

29484-441: The theory is that it usually cannot predict with certainty what will happen, but only give probabilities. Mathematically, a probability is found by taking the square of the absolute value of a complex number , known as a probability amplitude. This is known as the Born rule , named after physicist Max Born . For example, a quantum particle like an electron can be described by a wave function, which associates to each point in space

29666-480: The theory is. A would-be theory that makes no observable predictions is not a scientific theory at all. Predictions not sufficiently specific to be tested are similarly not useful. In both cases, the term "theory" is not applicable. A body of descriptions of knowledge can be called a theory if it fulfills the following criteria: These qualities are certainly true of such established theories as special and general relativity , quantum mechanics , plate tectonics ,

29848-449: The theory makes accurate predictions, which is evidence that any assumptions made at the outset are correct or approximately correct under the conditions tested. Conventional assumptions, without evidence, may be used if the theory is only intended to apply when the assumption is valid (or approximately valid). For example, the special theory of relativity assumes an inertial frame of reference . The theory makes accurate predictions when

30030-522: The threshold of detectability expressed by the Heisenberg uncertainty relation , Δ E  · Δ t  ≥  ħ . In effect, the energy needed to create these virtual particles, Δ E , can be "borrowed" from the vacuum for a period of time, Δ t , so that their product is no more than the reduced Planck constant , ħ ≈ 6.6 × 10  eV·s . Thus, for a virtual electron, Δ t is at most 1.3 × 10  s . While an electron–positron virtual pair

30212-498: The underlying nature of acidic and basic compounds, but they are very useful for predicting their chemical behavior. Like all knowledge in science, no theory can ever be completely certain , since it is possible that future experiments might conflict with the theory's predictions. However, theories supported by the scientific consensus have the highest level of certainty of any scientific knowledge; for example, that all objects are subject to gravity or that life on Earth evolved from

30394-434: The universe as a whole remains speculative. Predictions of quantum mechanics have been verified experimentally to an extremely high degree of accuracy . For example, the refinement of quantum mechanics for the interaction of light and matter, known as quantum electrodynamics (QED), has been shown to agree with experiment to within 1 part in 10 when predicting the magnetic properties of an electron. A fundamental feature of

30576-426: The upper limit of the particle's radius to be 10  meters. The upper bound of the electron radius of 10  meters can be derived using the uncertainty relation in energy. There is also a physical constant called the " classical electron radius ", with the much larger value of 2.8179 × 10  m , greater than the radius of the proton. However, the terminology comes from a simplistic calculation that ignores

30758-624: The use of electromagnetic fields. Special telescopes can detect electron plasma in outer space. Electrons are involved in many applications, such as tribology or frictional charging, electrolysis, electrochemistry, battery technologies, electronics , welding , cathode-ray tubes , photoelectricity, photovoltaic solar panels, electron microscopes , radiation therapy , lasers , gaseous ionization detectors , and particle accelerators . Interactions involving electrons with other subatomic particles are of interest in fields such as chemistry and nuclear physics . The Coulomb force interaction between

30940-526: The value of a physical quantity can be predicted prior to its measurement, given a complete set of initial conditions (the uncertainty principle ). Quantum mechanics arose gradually from theories to explain observations that could not be reconciled with classical physics, such as Max Planck 's solution in 1900 to the black-body radiation problem, and the correspondence between energy and frequency in Albert Einstein 's 1905 paper , which explained

31122-487: The view that electrons existed as components of atoms. In 1897, the British physicist J. J. Thomson , with his colleagues John S. Townsend and H. A. Wilson , performed experiments indicating that cathode rays really were unique particles, rather than waves, atoms or molecules as was believed earlier. By 1899 he showed that their charge-to-mass ratio, e / m , was independent of cathode material. He further showed that

31304-473: The wavelength of the photon by an amount called the Compton shift . The maximum magnitude of this wavelength shift is h / m e c , which is known as the Compton wavelength . For an electron, it has a value of 2.43 × 10  m . When the wavelength of the light is long (for instance, the wavelength of the visible light is 0.4–0.7 μm) the wavelength shift becomes negligible. Such interaction between

31486-503: Was Thomson's graduate student, performed the first experiments but he died soon after in a motorcycle accident and is rarely mentioned. De Broglie's prediction of a wave nature for electrons led Erwin Schrödinger to postulate a wave equation for electrons moving under the influence of the nucleus in the atom. In 1926, this equation, the Schrödinger equation , successfully described how electron waves propagated. Rather than yielding

31668-416: Was able to qualitatively explain the chemical properties of all elements in the periodic table, which were known to largely repeat themselves according to the periodic law . In 1924, Austrian physicist Wolfgang Pauli observed that the shell-like structure of the atom could be explained by a set of four parameters that defined every quantum energy state, as long as each state was occupied by no more than

31850-540: Was also simply used to refer to "receive into association" or "adopt into partnership". Moreover, other senses of assumere included (i) "investing oneself with (an attribute)", (ii) "to undertake" (especially in Law), (iii) "to take to oneself in appearance only, to pretend to possess", and (iv) "to suppose a thing to be" (all senses from OED entry on "assume"; the OED entry for "assumption" is almost perfectly symmetrical in senses). Thus, "assumption" connotes other associations than

32032-734: Was caused by the rays striking the tube walls. Furthermore, he also discovered that these rays are deflected by magnets just like lines of current. In 1876, the German physicist Eugen Goldstein showed that the rays were emitted perpendicular to the cathode surface, which distinguished between the rays that were emitted from the cathode and the incandescent light. Goldstein dubbed the rays cathode rays . Decades of experimental and theoretical research involving cathode rays were important in J. J. Thomson 's eventual discovery of electrons. Goldstein also experimented with double cathodes and hypothesized that one ray may repulse another, although he didn't believe that any particles might be involved. During

32214-672: Was governed by the inverse square law . After studying the phenomenon of electrolysis in 1874, Irish physicist George Johnstone Stoney suggested that there existed a "single definite quantity of electricity", the charge of a monovalent ion . He was able to estimate the value of this elementary charge e by means of Faraday's laws of electrolysis . However, Stoney believed these charges were permanently attached to atoms and could not be removed. In 1881, German physicist Hermann von Helmholtz argued that both positive and negative charges were divided into elementary parts, each of which "behaves like atoms of electricity". Stoney initially coined

32396-627: Was indeed eventually confirmed. Kitcher agrees with Popper that "There is surely something right in the idea that a science can succeed only if it can fail." He also says that scientific theories include statements that cannot be falsified, and that good theories must also be creative. He insists we view scientific theories as an "elaborate collection of statements", some of which are not falsifiable, while others—those he calls "auxiliary hypotheses", are. According to Kitcher, good scientific theories must have three features: Like other definitions of theories, including Popper's, Kitcher makes it clear that

32578-426: Was later explained by the theory of quantum electrodynamics , developed by Sin-Itiro Tomonaga , Julian Schwinger and Richard Feynman in the late 1940s. With the development of the particle accelerator during the first half of the twentieth century, physicists began to delve deeper into the properties of subatomic particles . The first successful attempt to accelerate electrons using electromagnetic induction

32760-415: Was made in 1942 by Donald Kerst . His initial betatron reached energies of 2.3 MeV, while subsequent betatrons achieved 300 MeV. In 1947, synchrotron radiation was discovered with a 70 MeV electron synchrotron at General Electric . This radiation was caused by the acceleration of electrons through a magnetic field as they moved near the speed of light. With a beam energy of 1.5 GeV,

32942-413: Was originally coined by George Johnstone Stoney in 1891 as a tentative name for the basic unit of electrical charge (which had then yet to be discovered). The electron's charge was more carefully measured by the American physicists Robert Millikan and Harvey Fletcher in their oil-drop experiment of 1909, the results of which were published in 1911. This experiment used an electric field to prevent

33124-443: Was supported by sufficient evidence. Also, while new theories may be proposed by a single person or by many, the cycle of modifications eventually incorporates contributions from many different scientists. After the changes, the accepted theory will explain more phenomena and have greater predictive power (if it did not, the changes would not be adopted); this new explanation will then be open to further replacement or modification. If

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