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104-613: The formation was first defined by Wheeler in 1929. The Rosablanca Formation is characterised by a sequence of grey limestones , dolomites and shales with a maximum thickness of 425 metres (1,394 ft) in the Sogamoso River valley. The Rosablanca Formation overlies the Arcabuco Formation and is overlain by the Ritoque Formation . The age has been estimated to be Valanginian . Stratigraphically,

208-455: A Mohs hardness of 2 to 4, dense limestone can have a crushing strength of up to 180 MPa . For comparison, concrete typically has a crushing strength of about 40 MPa. Although limestones show little variability in mineral composition, they show great diversity in texture. However, most limestone consists of sand-sized grains in a carbonate mud matrix. Because limestones are often of biological origin and are usually composed of sediment that

312-412: A bitumen binder, which is frequently used for road surfaces , and polymer concretes that use polymers as a binder. Concrete is distinct from mortar . Whereas concrete is itself a building material, mortar is a bonding agent that typically holds bricks , tiles and other masonry units together. Grout is another material associated with concrete and cement. It does not contain coarse aggregates and

416-463: A bloom of cyanobacteria or microalgae . However, stable isotope ratios in modern carbonate mud appear to be inconsistent with either of these mechanisms, and abrasion of carbonate grains in high-energy environments has been put forward as a third possibility. Formation of limestone has likely been dominated by biological processes throughout the Phanerozoic , the last 540 million years of

520-433: A French structural and civil engineer . Concrete components or structures are compressed by tendon cables during, or after, their fabrication in order to strengthen them against tensile forces developing when put in service. Freyssinet patented the technique on 2 October 1928. Concrete is an artificial composite material , comprising a matrix of cementitious binder (typically Portland cement paste or asphalt ) and

624-434: A carbonate rock outcrop can be estimated in the field by etching the surface with dilute hydrochloric acid. This etches away the calcite and aragonite, leaving behind any silica or dolomite grains. The latter can be identified by their rhombohedral shape. Crystals of calcite, quartz , dolomite or barite may line small cavities ( vugs ) in the rock. Vugs are a form of secondary porosity, formed in existing limestone by

728-452: A cementitious material forms a cement paste by the process of hydration. The cement paste glues the aggregate together, fills voids within it, and makes it flow more freely. As stated by Abrams' law , a lower water-to-cement ratio yields a stronger, more durable concrete, whereas more water gives a freer-flowing concrete with a higher slump . The hydration of cement involves many concurrent reactions. The process involves polymerization ,

832-616: A central quartz grain or carbonate mineral fragment. These likely form by direct precipitation of calcium carbonate onto the ooid. Pisoliths are similar to ooids, but they are larger than 2 mm in diameter and tend to be more irregular in shape. Limestone composed mostly of ooids is called an oolite or sometimes an oolitic limestone . Ooids form in high-energy environments, such as the Bahama platform, and oolites typically show crossbedding and other features associated with deposition in strong currents. Oncoliths resemble ooids but show

936-449: A change in environment that increases the solubility of calcite. Dense, massive limestone is sometimes described as "marble". For example, the famous Portoro "marble" of Italy is actually a dense black limestone. True marble is produced by recrystallization of limestone during regional metamorphism that accompanies the mountain building process ( orogeny ). It is distinguished from dense limestone by its coarse crystalline texture and

1040-949: A composition reflecting the organisms that produced them and the environment in which they were produced. Low-magnesium calcite skeletal grains are typical of articulate brachiopods , planktonic (free-floating) foraminifera, and coccoliths . High-magnesium calcite skeletal grains are typical of benthic (bottom-dwelling) foraminifera, echinoderms , and coralline algae . Aragonite skeletal grains are typical of molluscs , calcareous green algae , stromatoporoids , corals , and tube worms . The skeletal grains also reflect specific geological periods and environments. For example, coral grains are more common in high-energy environments (characterized by strong currents and turbulence) while bryozoan grains are more common in low-energy environments (characterized by quiet water). Ooids (sometimes called ooliths) are sand-sized grains (less than 2mm in diameter) consisting of one or more layers of calcite or aragonite around

1144-400: A concrete component—and become a part of the binder for the aggregate. Fly ash and slag can enhance some properties of concrete such as fresh properties and durability. Alternatively, other materials can also be used as a concrete binder: the most prevalent substitute is asphalt , which is used as the binder in asphalt concrete . Admixtures are added to modify the cure rate or properties of

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1248-412: A considerable fraction of the limestone bed. At depths greater than 1 km (0.62 miles), burial cementation completes the lithification process. Burial cementation does not produce stylolites. When overlying beds are eroded, bringing limestone closer to the surface, the final stage of diagenesis takes place. This produces secondary porosity as some of the cement is dissolved by rainwater infiltrating

1352-434: A dispersed phase or "filler" of aggregate (typically a rocky material, loose stones, and sand). The binder "glues" the filler together to form a synthetic conglomerate . Many types of concrete are available, determined by the formulations of binders and the types of aggregate used to suit the application of the engineered material. These variables determine strength and density, as well as chemical and thermal resistance of

1456-483: A drop of dilute hydrochloric acid is dropped on it. Dolomite is also soft but reacts only feebly with dilute hydrochloric acid, and it usually weathers to a characteristic dull yellow-brown color due to the presence of ferrous iron. This is released and oxidized as the dolomite weathers. Impurities (such as clay , sand, organic remains, iron oxide , and other materials) will cause limestones to exhibit different colors, especially with weathered surfaces. The makeup of

1560-637: A few million years, as this is the most stable form of calcium carbonate. Ancient carbonate formations of the Precambrian and Paleozoic contain abundant dolomite, but limestone dominates the carbonate beds of the Mesozoic and Cenozoic . Modern dolomite is quite rare. There is evidence that, while the modern ocean favors precipitation of aragonite, the oceans of the Paleozoic and middle to late Cenozoic favored precipitation of calcite. This may indicate

1664-455: A few thousand years. As rainwater mixes with groundwater, aragonite and high-magnesium calcite are converted to low-calcium calcite. Cementing of thick carbonate deposits by rainwater may commence even before the retreat of the sea, as rainwater can infiltrate over 100 km (60 miles) into sediments beneath the continental shelf. As carbonate sediments are increasingly deeply buried under younger sediments, chemical and mechanical compaction of

1768-452: A greater degree of fracture resistance even in seismically active environments. Roman concrete is significantly more resistant to erosion by seawater than modern concrete; it used pyroclastic materials which react with seawater to form Al- tobermorite crystals over time. The use of hot mixing and the presence of lime clasts are thought to give the concrete a self-healing ability, where cracks that form become filled with calcite that prevents

1872-490: A high percentage of the mineral dolomite , CaMg(CO 3 ) 2 . Magnesian limestone is an obsolete and poorly-defined term used variously for dolomite, for limestone containing significant dolomite ( dolomitic limestone ), or for any other limestone containing a significant percentage of magnesium . Most limestone was formed in shallow marine environments, such as continental shelves or platforms , though smaller amounts were formed in many other environments. Much dolomite

1976-559: A key event in the history of architecture termed the Roman architectural revolution , freed Roman construction from the restrictions of stone and brick materials. It enabled revolutionary new designs in terms of both structural complexity and dimension. The Colosseum in Rome was built largely of concrete, and the Pantheon has the world's largest unreinforced concrete dome. Concrete, as

2080-415: A large aggregate that is too large for the size of the formwork, or which has too few smaller aggregate grades to serve to fill the gaps between the larger grades, or using too little or too much sand for the same reason, or using too little water, or too much cement, or even using jagged crushed stone instead of smoother round aggregate such as pebbles. Any combination of these factors and others may result in

2184-461: A large type of industrial facility called a concrete plant , or often a batch plant. The usual method of placement is casting in formwork , which holds the mix in shape until it has set enough to hold its shape unaided. Concrete plants come in two main types, ready-mix plants and central mix plants. A ready-mix plant blends all of the solid ingredients, while a central mix does the same but adds water. A central-mix plant offers more precise control of

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2288-435: A limestone sample except in thin section and are less common in ancient limestones, possibly because compaction of carbonate sediments disrupts them. Limeclasts are fragments of existing limestone or partially lithified carbonate sediments. Intraclasts are limeclasts that originate close to where they are deposited in limestone, while extraclasts come from outside the depositional area. Intraclasts include grapestone , which

2392-471: A lower Mg/Ca ratio in the ocean water of those times. This magnesium depletion may be a consequence of more rapid sea floor spreading , which removes magnesium from ocean water. The modern ocean and the ocean of the Mesozoic have been described as "aragonite seas". Most limestone was formed in shallow marine environments, such as continental shelves or platforms . Such environments form only about 5% of

2496-525: A lower diversity of organisms and a greater fraction of silica and clay minerals characteristic of marls . The Green River Formation is an example of a prominent freshwater sedimentary formation containing numerous limestone beds. Freshwater limestone is typically micritic. Fossils of charophyte (stonewort), a form of freshwater green algae, are characteristic of these environments, where the charophytes produce and trap carbonates. Limestones may also form in evaporite depositional environments . Calcite

2600-523: A mechanism for dolomitization, with one 2004 review paper describing it bluntly as "a myth". Ordinary seawater is capable of converting calcite to dolomite, if the seawater is regularly flushed through the rock, as by the ebb and flow of tides (tidal pumping). Once dolomitization begins, it proceeds rapidly, so that there is very little carbonate rock containing mixed calcite and dolomite. Carbonate rock tends to be either almost all calcite/aragonite or almost all dolomite. About 20% to 25% of sedimentary rock

2704-469: A mixture of calcium silicates ( alite , belite ), aluminates and ferrites —compounds, which will react with water. Portland cement and similar materials are made by heating limestone (a source of calcium) with clay or shale (a source of silicon, aluminium and iron) and grinding this product (called clinker ) with a source of sulfate (most commonly gypsum ). Cement kilns are extremely large, complex, and inherently dusty industrial installations. Of

2808-405: A number of manufactured aggregates, including air-cooled blast furnace slag and bottom ash are also permitted. The size distribution of the aggregate determines how much binder is required. Aggregate with a very even size distribution has the biggest gaps whereas adding aggregate with smaller particles tends to fill these gaps. The binder must fill the gaps between the aggregate as well as paste

2912-448: A plausible source of mud. Another possibility is direct precipitation from the water. A phenomenon known as whitings occurs in shallow waters, in which white streaks containing dispersed micrite appear on the surface of the water. It is uncertain whether this is freshly precipitated aragonite or simply material stirred up from the bottom, but there is some evidence that whitings are caused by biological precipitation of aragonite as part of

3016-449: A radial rather than layered internal structure, indicating that they were formed by algae in a normal marine environment. Peloids are structureless grains of microcrystalline carbonate likely produced by a variety of processes. Many are thought to be fecal pellets produced by marine organisms. Others may be produced by endolithic (boring) algae or other microorganisms or through breakdown of mollusc shells. They are difficult to see in

3120-424: A semi-liquid slurry (paste) that can be shaped, typically by pouring it into a form. The concrete solidifies and hardens through a chemical process called hydration . The water reacts with the cement, which bonds the other components together, creating a robust, stone-like material. Other cementitious materials, such as fly ash and slag cement , are sometimes added—either pre-blended with the cement or directly as

3224-493: A simple, fast way of getting a basic idea of the properties of the finished concrete without having to perform testing in advance. Various governing bodies (such as British Standards ) define nominal mix ratios into a number of grades, usually ranging from lower compressive strength to higher compressive strength. The grades usually indicate the 28-day cure strength. Thorough mixing is essential to produce uniform, high-quality concrete. Separate paste mixing has shown that

Rosablanca Formation - Misplaced Pages Continue

3328-467: A small empire in the regions of southern Syria and northern Jordan from the 4th century BC. They discovered the advantages of hydraulic lime , with some self-cementing properties, by 700 BC. They built kilns to supply mortar for the construction of rubble masonry houses, concrete floors, and underground waterproof cisterns . They kept the cisterns secret as these enabled the Nabataeans to thrive in

3432-484: Is exothermic , which means ambient temperature plays a significant role in how long it takes concrete to set. Often, additives (such as pozzolans or superplasticizers ) are included in the mixture to improve the physical properties of the wet mix, delay or accelerate the curing time, or otherwise change the finished material. Most concrete is poured with reinforcing materials (such as steel rebar ) embedded to provide tensile strength , yielding reinforced concrete . In

3536-405: Is a composite material composed of aggregate bonded together with a fluid cement that cures to a solid over time. Concrete is the second-most-used substance in the world after water , and is the most widely used building material. Its usage worldwide, ton for ton, is twice that of steel, wood, plastics, and aluminium combined. When aggregate is mixed with dry Portland cement and water ,

3640-416: Is a type of carbonate sedimentary rock which is the main source of the material lime . It is composed mostly of the minerals calcite and aragonite , which are different crystal forms of CaCO 3 . Limestone forms when these minerals precipitate out of water containing dissolved calcium. This can take place through both biological and nonbiological processes, though biological processes, such as

3744-560: Is also favored on the seaward margin of shelves and platforms, where there is upwelling deep ocean water rich in nutrients that increase organic productivity. Reefs are common here, but when lacking, ooid shoals are found instead. Finer sediments are deposited close to shore. The lack of deep sea limestones is due in part to rapid subduction of oceanic crust, but is more a result of dissolution of calcium carbonate at depth. The solubility of calcium carbonate increases with pressure and even more with higher concentrations of carbon dioxide, which

3848-482: Is an uncommon mineral in limestone, and siderite or other carbonate minerals are rare. However, the calcite in limestone often contains a few percent of magnesium . Calcite in limestone is divided into low-magnesium and high-magnesium calcite, with the dividing line placed at a composition of 4% magnesium. High-magnesium calcite retains the calcite mineral structure, which is distinct from dolomite. Aragonite does not usually contain significant magnesium. Most limestone

3952-402: Is carbonate rock, and most of this is limestone. Limestone is found in sedimentary sequences as old as 2.7 billion years. However, the compositions of carbonate rocks show an uneven distribution in time in the geologic record. About 95% of modern carbonates are composed of high-magnesium calcite and aragonite. The aragonite needles in carbonate mud are converted to low-magnesium calcite within

4056-474: Is clusters of peloids cemented together by organic material or mineral cement. Extraclasts are uncommon, are usually accompanied by other clastic sediments, and indicate deposition in a tectonically active area or as part of a turbidity current . The grains of most limestones are embedded in a matrix of carbonate mud. This is typically the largest fraction of an ancient carbonate rock. Mud consisting of individual crystals less than 5 μm (0.20 mils) in length

4160-416: Is commonly white to gray in color. Limestone that is unusually rich in organic matter can be almost black in color, while traces of iron or manganese can give limestone an off-white to yellow to red color. The density of limestone depends on its porosity, which varies from 0.1% for the densest limestone to 40% for chalk. The density correspondingly ranges from 1.5 to 2.7 g/cm . Although relatively soft, with

4264-420: Is controlled largely by the amount of dissolved carbon dioxide ( CO 2 ) in the water. This is summarized in the reaction: Increases in temperature or decreases in pressure tend to reduce the amount of dissolved CO 2 and precipitate CaCO 3 . Reduction in salinity also reduces the solubility of CaCO 3 , by several orders of magnitude for fresh water versus seawater. Near-surface water of

Rosablanca Formation - Misplaced Pages Continue

4368-545: Is converted to low-magnesium calcite. Diagenesis is the likely origin of pisoliths , concentrically layered particles ranging from 1 to 10 mm (0.039 to 0.394 inches) in diameter found in some limestones. Pisoliths superficially resemble ooids but have no nucleus of foreign matter, fit together tightly, and show other signs that they formed after the original deposition of the sediments. Silicification occurs early in diagenesis, at low pH and temperature, and contributes to fossil preservation. Silicification takes place through

4472-503: Is deposited close to where it formed, classification of limestone is usually based on its grain type and mud content. Most grains in limestone are skeletal fragments of marine organisms such as coral or foraminifera . These organisms secrete structures made of aragonite or calcite, and leave these structures behind when they die. Other carbonate grains composing limestones are ooids , peloids , and limeclasts ( intraclasts and extraclasts  [ ca ] ). Skeletal grains have

4576-460: Is described as coquinite . Chalk is a soft, earthy, fine-textured limestone composed of the tests of planktonic microorganisms such as foraminifera, while marl is an earthy mixture of carbonates and silicate sediments. Limestone forms when calcite or aragonite precipitate out of water containing dissolved calcium, which can take place through both biological and nonbiological processes. The solubility of calcium carbonate ( CaCO 3 )

4680-617: Is described as micrite . In fresh carbonate mud, micrite is mostly small aragonite needles, which may precipitate directly from seawater, be secreted by algae, or be produced by abrasion of carbonate grains in a high-energy environment. This is converted to calcite within a few million years of deposition. Further recrystallization of micrite produces microspar , with grains from 5 to 15 μm (0.20 to 0.59 mils) in diameter. Limestone often contains larger crystals of calcite, ranging in size from 0.02 to 0.1 mm (0.79 to 3.94 mils), that are described as sparry calcite or sparite . Sparite

4784-462: Is distinguished from micrite by a grain size of over 20 μm (0.79 mils) and because sparite stands out under a hand lens or in thin section as white or transparent crystals. Sparite is distinguished from carbonate grains by its lack of internal structure and its characteristic crystal shapes. Geologists are careful to distinguish between sparite deposited as cement and sparite formed by recrystallization of micrite or carbonate grains. Sparite cement

4888-473: Is flat and had been covered with cement". "The floors were cement, in some places hard, but, by long exposure, broken, and now crumbling under the feet." "But throughout the wall was solid, and consisting of large stones imbedded in mortar, almost as hard as rock." Small-scale production of concrete-like materials was pioneered by the Nabatean traders who occupied and controlled a series of oases and developed

4992-560: Is one of the first minerals to precipitate in marine evaporites. Most limestone is formed by the activities of living organisms near reefs, but the organisms responsible for reef formation have changed over geologic time. For example, stromatolites are mound-shaped structures in ancient limestones, interpreted as colonies of cyanobacteria that accumulated carbonate sediments, but stromatolites are rare in younger limestones. Organisms precipitate limestone both directly as part of their skeletons, and indirectly by removing carbon dioxide from

5096-473: Is otherwise chemically fairly pure, with clastic sediments (mainly fine-grained quartz and clay minerals ) making up less than 5% to 10% of the composition. Organic matter typically makes up around 0.2% of a limestone and rarely exceeds 1%. Limestone often contains variable amounts of silica in the form of chert or siliceous skeletal fragments (such as sponge spicules, diatoms , or radiolarians ). Fossils are also common in limestone. Limestone

5200-472: Is produced by decaying organic matter settling into the deep ocean that is not removed by photosynthesis in the dark depths. As a result, there is a fairly sharp transition from water saturated with calcium carbonate to water unsaturated with calcium carbonate, the lysocline , which occurs at the calcite compensation depth of 4,000 to 7,000 m (13,000 to 23,000 feet). Below this depth, foraminifera tests and other skeletal particles rapidly dissolve, and

5304-518: Is secondary dolomite, formed by chemical alteration of limestone. Limestone is exposed over large regions of the Earth's surface, and because limestone is slightly soluble in rainwater, these exposures often are eroded to become karst landscapes. Most cave systems are found in limestone bedrock. Limestone has numerous uses: as a chemical feedstock for the production of lime used for cement (an essential component of concrete ), as aggregate for

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5408-559: Is then blended with aggregates and any remaining batch water and final mixing is completed in conventional concrete mixing equipment. Workability is the ability of a fresh (plastic) concrete mix to fill the form/mold properly with the desired work (pouring, pumping, spreading, tamping, vibration) and without reducing the concrete's quality. Workability depends on water content, aggregate (shape and size distribution), cementitious content and age (level of hydration ) and can be modified by adding chemical admixtures, like superplasticizer. Raising

5512-566: Is usually either pourable or thixotropic , and is used to fill gaps between masonry components or coarse aggregate which has already been put in place. Some methods of concrete manufacture and repair involve pumping grout into the gaps to make up a solid mass in situ . The word concrete comes from the Latin word " concretus " (meaning compact or condensed), the perfect passive participle of " concrescere ", from " con -" (together) and " crescere " (to grow). Concrete floors were found in

5616-399: Is usually reinforced with materials that are strong in tension, typically steel rebar . The mix design depends on the type of structure being built, how the concrete is mixed and delivered, and how it is placed to form the structure. Portland cement is the most common type of cement in general usage. It is a basic ingredient of concrete, mortar , and many plasters . It consists of

5720-480: The construction industry , whose demand is ever growing with greater impacts on raw material extraction, waste generation and landfill practices. Concrete production is the process of mixing together the various ingredients—water, aggregate, cement, and any additives—to produce concrete. Concrete production is time-sensitive. Once the ingredients are mixed, workers must put the concrete in place before it hardens. In modern usage, most concrete production takes place in

5824-496: The Earth's history. Limestone may have been deposited by microorganisms in the Precambrian , prior to 540 million years ago, but inorganic processes were probably more important and likely took place in an ocean more highly oversaturated in calcium carbonate than the modern ocean. Diagenesis is the process in which sediments are compacted and turned into solid rock . During diagenesis of carbonate sediments, significant chemical and textural changes take place. For example, aragonite

5928-508: The Romans knew it, was a new and revolutionary material. Laid in the shape of arches , vaults and domes , it quickly hardened into a rigid mass, free from many of the internal thrusts and strains that troubled the builders of similar structures in stone or brick. Modern tests show that opus caementicium had as much compressive strength as modern Portland-cement concrete (c. 200 kg/cm  [20 MPa; 2,800 psi]). However, due to

6032-643: The absence of reinforcement, its tensile strength was far lower than modern reinforced concrete , and its mode of application also differed: Modern structural concrete differs from Roman concrete in two important details. First, its mix consistency is fluid and homogeneous, allowing it to be poured into forms rather than requiring hand-layering together with the placement of aggregate, which, in Roman practice, often consisted of rubble . Second, integral reinforcing steel gives modern concrete assemblies great strength in tension, whereas Roman concrete could depend only upon

6136-430: The accumulation of corals and shells in the sea, have likely been more important for the last 540 million years. Limestone often contains fossils which provide scientists with information on ancient environments and on the evolution of life. About 20% to 25% of sedimentary rock is carbonate rock, and most of this is limestone. The remaining carbonate rock is mostly dolomite , a closely related rock, which contains

6240-434: The base of roads, as white pigment or filler in products such as toothpaste or paint, as a soil conditioner , and as a popular decorative addition to rock gardens . Limestone formations contain about 30% of the world's petroleum reservoirs . Limestone is composed mostly of the minerals calcite and aragonite , which are different crystal forms of calcium carbonate ( CaCO 3 ). Dolomite , CaMg(CO 3 ) 2 ,

6344-657: The beds. This may include the formation of vugs , which are crystal-lined cavities within the limestone. Diagenesis may include conversion of limestone to dolomite by magnesium-rich fluids. There is considerable evidence of replacement of limestone by dolomite, including sharp replacement boundaries that cut across bedding. The process of dolomitization remains an area of active research, but possible mechanisms include exposure to concentrated brines in hot environments ( evaporative reflux ) or exposure to diluted seawater in delta or estuary environments ( Dorag dolomitization ). However, Dorag dolomitization has fallen into disfavor as

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6448-462: The bottom with the concave face downwards. This traps a void space that can later be filled by sparite. Geologists use geopetal structures to determine which direction was up at the time of deposition, which is not always obvious with highly deformed limestone formations. The cyanobacterium Hyella balani can bore through limestone; as can the green alga Eugamantia sacculata and the fungus Ostracolaba implexa . Concrete Concrete

6552-526: The concrete at the time of batching/mixing. (See § Production below.) The common types of admixtures are as follows: Inorganic materials that have pozzolanic or latent hydraulic properties, these very fine-grained materials are added to the concrete mix to improve the properties of concrete (mineral admixtures), or as a replacement for Portland cement (blended cements). Products which incorporate limestone , fly ash , blast furnace slag , and other useful materials with pozzolanic properties into

6656-399: The concrete can cause the initially placed material to begin to set before the next batch is added on top. This creates a horizontal plane of weakness called a cold joint between the two batches. Once the mix is where it should be, the curing process must be controlled to ensure that the concrete attains the desired attributes. During concrete preparation, various technical details may affect

6760-461: The concrete quality. Central mix plants must be close to the work site where the concrete will be used, since hydration begins at the plant. A concrete plant consists of large hoppers for storage of various ingredients like cement, storage for bulk ingredients like aggregate and water, mechanisms for the addition of various additives and amendments, machinery to accurately weigh, move, and mix some or all of those ingredients, and facilities to dispense

6864-483: The crack from spreading. The widespread use of concrete in many Roman structures ensured that many survive to the present day. The Baths of Caracalla in Rome are just one example. Many Roman aqueducts and bridges, such as the magnificent Pont du Gard in southern France, have masonry cladding on a concrete core, as does the dome of the Pantheon . After the Roman Empire, the use of burned lime and pozzolana

6968-466: The depositional fabric of carbonate rocks. Dunham divides the rocks into four main groups based on relative proportions of coarser clastic particles, based on criteria such as whether the grains were originally in mutual contact, and therefore self-supporting, or whether the rock is characterized by the presence of frame builders and algal mats. Unlike the Folk scheme, Dunham deals with the original porosity of

7072-469: The deposits are highly porous, so that they have a spongelike texture, they are typically described as tufa . Secondary calcite deposited by supersaturated meteoric waters ( groundwater ) in caves is also sometimes described as travertine. This produces speleothems , such as stalagmites and stalactites . Coquina is a poorly consolidated limestone composed of abraded pieces of coral , shells , or other fossil debris. When better consolidated, it

7176-562: The desert. Some of these structures survive to this day. In the Ancient Egyptian and later Roman eras, builders discovered that adding volcanic ash to lime allowed the mix to set underwater. They discovered the pozzolanic reaction . The Romans used concrete extensively from 300 BC to AD 476. During the Roman Empire, Roman concrete (or opus caementicium ) was made from quicklime , pozzolana and an aggregate of pumice . Its widespread use in many Roman structures ,

7280-406: The earth's oceans are oversaturated with CaCO 3 by a factor of more than six. The failure of CaCO 3 to rapidly precipitate out of these waters is likely due to interference by dissolved magnesium ions with nucleation of calcite crystals, the necessary first step in precipitation. Precipitation of aragonite may be suppressed by the presence of naturally occurring organic phosphates in

7384-431: The finished product. Construction aggregates consist of large chunks of material in a concrete mix, generally a coarse gravel or crushed rocks such as limestone , or granite , along with finer materials such as sand . Cement paste, most commonly made of Portland cement , is the most prevalent kind of concrete binder. For cementitious binders, water is mixed with the dry cement powder and aggregate, which produces

7488-399: The first refers to the grains and the second to the cement. For example, a limestone consisting mainly of ooids, with a crystalline matrix, would be termed an oosparite. It is helpful to have a petrographic microscope when using the Folk scheme, because it is easier to determine the components present in each sample. Robert J. Dunham published his system for limestone in 1962. It focuses on

7592-575: The formation is time equivalent with the Macanal Formation . Fossils of the decapod crustacean Diaulax rosablanca have been found in and named after the Rosablanca Formation. In 2019 , fossils of brachiopod Sellithyris elizabetha were described from the formation. In 2020 remains of indeterminate pterosaurs were described from the formation, including pterodactyloids and non- Pteranodontian ornithocheiroids . In 2005

7696-572: The formation of distinctive minerals from the silica and clay present in the original limestone. Two major classification schemes, the Folk and Dunham, are used for identifying the types of carbonate rocks collectively known as limestone. Robert L. Folk developed a classification system that places primary emphasis on the detailed composition of grains and interstitial material in carbonate rocks . Based on composition, there are three main components: allochems (grains), matrix (mostly micrite), and cement (sparite). The Folk system uses two-part names;

7800-429: The geologic record are called bioherms . Many are rich in fossils, but most lack any connected organic framework like that seen in modern reefs. The fossil remains are present as separate fragments embedded in ample mud matrix. Much of the sedimentation shows indications of occurring in the intertidal or supratidal zones, suggesting sediments rapidly fill available accommodation space in the shelf or platform. Deposition

7904-554: The interlinking of the silicates and aluminate components as well as their bonding to sand and gravel particles to form a solid mass. One illustrative conversion is the hydration of tricalcium silicate: The hydration (curing) of cement is irreversible. Fine and coarse aggregates make up the bulk of a concrete mixture. Sand , natural gravel, and crushed stone are used mainly for this purpose. Recycled aggregates (from construction, demolition, and excavation waste) are increasingly used as partial replacements for natural aggregates, while

8008-406: The making of mortar. In an English translation from 1397, it reads "lyme ... is a stone brent; by medlynge thereof with sonde and water sement is made". From the 14th century, the quality of mortar was again excellent, but only from the 17th century was pozzolana commonly added. The Canal du Midi was built using concrete in 1670. Perhaps the greatest step forward in the modern use of concrete

8112-531: The material. Mineral admixtures use recycled materials as concrete ingredients. Conspicuous materials include fly ash , a by-product of coal-fired power plants ; ground granulated blast furnace slag , a by-product of steelmaking ; and silica fume , a by-product of industrial electric arc furnaces . Structures employing Portland cement concrete usually include steel reinforcement because this type of concrete can be formulated with high compressive strength , but always has lower tensile strength . Therefore, it

8216-419: The mix, are being tested and used. These developments are ever growing in relevance to minimize the impacts caused by cement use, notorious for being one of the largest producers (at about 5 to 10%) of global greenhouse gas emissions . The use of alternative materials also is capable of lowering costs, improving concrete properties, and recycling wastes, the latest being relevant for circular economy aspects of

8320-478: The mixed concrete, often to a concrete mixer truck. Modern concrete is usually prepared as a viscous fluid, so that it may be poured into forms. The forms are containers that define the desired shape. Concrete formwork can be prepared in several ways, such as slip forming and steel plate construction . Alternatively, concrete can be mixed into dryer, non-fluid forms and used in factory settings to manufacture precast concrete products. Interruption in pouring

8424-441: The mixing of cement and water into a paste before combining these materials with aggregates can increase the compressive strength of the resulting concrete. The paste is generally mixed in a high-speed , shear-type mixer at a w/c (water to cement ratio) of 0.30 to 0.45 by mass. The cement paste premix may include admixtures such as accelerators or retarders, superplasticizers , pigments , or silica fume . The premixed paste

8528-440: The mixture forms a fluid slurry that is easily poured and molded into shape. The cement reacts with the water through a process called concrete hydration that hardens it over several hours to form a hard matrix that binds the materials together into a durable stone-like material that has many uses. This time allows concrete to not only be cast in forms, but also to have a variety of tooled processes performed. The hydration process

8632-410: The ocean basins, but limestone is rarely preserved in continental slope and deep sea environments. The best environments for deposition are warm waters, which have both a high organic productivity and increased saturation of calcium carbonate due to lower concentrations of dissolved carbon dioxide. Modern limestone deposits are almost always in areas with very little silica-rich sedimentation, reflected in

8736-428: The past, lime -based cement binders, such as lime putty, were often used but sometimes with other hydraulic cements , (water resistant) such as a calcium aluminate cement or with Portland cement to form Portland cement concrete (named for its visual resemblance to Portland stone ). Many other non-cementitious types of concrete exist with other methods of binding aggregate together, including asphalt concrete with

8840-506: The properties or increase the performance envelope of the mix. Design-mix concrete can have very broad specifications that cannot be met with more basic nominal mixes, but the involvement of the engineer often increases the cost of the concrete mix. Concrete mixes are primarily divided into nominal mix, standard mix and design mix. Nominal mix ratios are given in volume of Cement : Sand : Aggregate {\displaystyle {\text{Cement : Sand : Aggregate}}} . Nominal mixes are

8944-468: The quality and nature of the product. Design mix ratios are decided by an engineer after analyzing the properties of the specific ingredients being used. Instead of using a 'nominal mix' of 1 part cement, 2 parts sand, and 4 parts aggregate (the second example from above), a civil engineer will custom-design a concrete mix to exactly meet the requirements of the site and conditions, setting material ratios and often designing an admixture package to fine-tune

9048-426: The reaction: Fossils are often preserved in exquisite detail as chert. Cementing takes place rapidly in carbonate sediments, typically within less than a million years of deposition. Some cementing occurs while the sediments are still under water, forming hardgrounds . Cementing accelerates after the retreat of the sea from the depositional environment, as rainwater infiltrates the sediment beds, often within just

9152-482: The relative purity of most limestones. Reef organisms are destroyed by muddy, brackish river water, and carbonate grains are ground down by much harder silicate grains. Unlike clastic sedimentary rock, limestone is produced almost entirely from sediments originating at or near the place of deposition. Limestone formations tend to show abrupt changes in thickness. Large moundlike features in a limestone formation are interpreted as ancient reefs , which when they appear in

9256-619: The remains of Platychelyid sea turtle Notoemys zapatocaensis were described, and in 2023 the limbs and shell elements of protostegids were described as some of the largest Early Cretaceous turtles. The Rosablanca Formation is found, apart from its type locality on the Mesa de Los Santos , Santander , in Boyacá and the Middle Magdalena Basin . Limestone Limestone ( calcium carbonate CaCO 3 )

9360-460: The rock. The Dunham scheme is more useful for hand samples because it is based on texture, not the grains in the sample. A revised classification was proposed by Wright (1992). It adds some diagenetic patterns to the classification scheme. Travertine is a term applied to calcium carbonate deposits formed in freshwater environments, particularly waterfalls , cascades and hot springs . Such deposits are typically massive, dense, and banded. When

9464-650: The royal palace of Tiryns , Greece, which dates roughly to 1400 to 1200 BC. Lime mortars were used in Greece, such as in Crete and Cyprus, in 800 BC. The Assyrian Jerwan Aqueduct (688 BC) made use of waterproof concrete . Concrete was used for construction in many ancient structures. Mayan concrete at the ruins of Uxmal (AD 850–925) is referenced in Incidents of Travel in the Yucatán by John L. Stephens . "The roof

9568-479: The sediments increases. Chemical compaction takes place by pressure solution of the sediments. This process dissolves minerals from points of contact between grains and redeposits it in pore space, reducing the porosity of the limestone from an initial high value of 40% to 80% to less than 10%. Pressure solution produces distinctive stylolites , irregular surfaces within the limestone at which silica-rich sediments accumulate. These may reflect dissolution and loss of

9672-662: The sediments of the ocean floor abruptly transition from carbonate ooze rich in foraminifera and coccolith remains ( Globigerina ooze) to silicic mud lacking carbonates. In rare cases, turbidites or other silica-rich sediments bury and preserve benthic (deep ocean) carbonate deposits. Ancient benthic limestones are microcrystalline and are identified by their tectonic setting. Fossils typically are foraminifera and coccoliths. No pre-Jurassic benthic limestones are known, probably because carbonate-shelled plankton had not yet evolved. Limestones also form in freshwater environments. These limestones are not unlike marine limestone, but have

9776-411: The strength of the concrete bonding to resist tension. The long-term durability of Roman concrete structures has been found to be due to its use of pyroclastic (volcanic) rock and ash, whereby the crystallization of strätlingite (a specific and complex calcium aluminosilicate hydrate) and the coalescence of this and similar calcium–aluminium-silicate–hydrate cementing binders helped give the concrete

9880-497: The surface of concrete for a decorative "exposed aggregate" finish, popular among landscape designers. Admixtures are materials in the form of powder or fluids that are added to the concrete to give it certain characteristics not obtainable with plain concrete mixes. Admixtures are defined as additions "made as the concrete mix is being prepared". The most common admixtures are retarders and accelerators. In normal use, admixture dosages are less than 5% by mass of cement and are added to

9984-535: The surfaces of the aggregate together, and is typically the most expensive component. Thus, variation in sizes of the aggregate reduces the cost of concrete. The aggregate is nearly always stronger than the binder, so its use does not negatively affect the strength of the concrete. Redistribution of aggregates after compaction often creates non-homogeneity due to the influence of vibration. This can lead to strength gradients. Decorative stones such as quartzite , small river stones or crushed glass are sometimes added to

10088-655: The various ingredients used to produce a given quantity of concrete, the cement is the most energetically expensive. Even complex and efficient kilns require 3.3 to 3.6 gigajoules of energy to produce a ton of clinker and then grind it into cement . Many kilns can be fueled with difficult-to-dispose-of wastes, the most common being used tires. The extremely high temperatures and long periods of time at those temperatures allows cement kilns to efficiently and completely burn even difficult-to-use fuels. The five major compounds of calcium silicates and aluminates comprising Portland cement range from 5 to 50% in weight. Combining water with

10192-533: The water by photosynthesis and thereby decreasing the solubility of calcium carbonate. Limestone shows the same range of sedimentary structures found in other sedimentary rocks. However, finer structures, such as lamination , are often destroyed by the burrowing activities of organisms ( bioturbation ). Fine lamination is characteristic of limestone formed in playa lakes , which lack the burrowing organisms. Limestones also show distinctive features such as geopetal structures , which form when curved shells settle to

10296-439: The water content or adding chemical admixtures increases concrete workability. Excessive water leads to increased bleeding or segregation of aggregates (when the cement and aggregates start to separate), with the resulting concrete having reduced quality. Changes in gradation can also affect workability of the concrete, although a wide range of gradation can be used for various applications. An undesirable gradation can mean using

10400-553: The water. Although ooids likely form through purely inorganic processes, the bulk of CaCO 3 precipitation in the oceans is the result of biological activity. Much of this takes place on carbonate platforms . The origin of carbonate mud, and the processes by which it is converted to micrite, continue to be a subject of research. Modern carbonate mud is composed mostly of aragonite needles around 5 μm (0.20 mils) in length. Needles of this shape and composition are produced by calcareous algae such as Penicillus , making this

10504-524: Was Smeaton's Tower , built by British engineer John Smeaton in Devon , England, between 1756 and 1759. This third Eddystone Lighthouse pioneered the use of hydraulic lime in concrete, using pebbles and powdered brick as aggregate. A method for producing Portland cement was developed in England and patented by Joseph Aspdin in 1824. Aspdin chose the name for its similarity to Portland stone , which

10608-602: Was greatly reduced. Low kiln temperatures in the burning of lime, lack of pozzolana, and poor mixing all contributed to a decline in the quality of concrete and mortar. From the 11th century, the increased use of stone in church and castle construction led to an increased demand for mortar. Quality began to improve in the 12th century through better grinding and sieving. Medieval lime mortars and concretes were non-hydraulic and were used for binding masonry, "hearting" (binding rubble masonry cores) and foundations. Bartholomaeus Anglicus in his De proprietatibus rerum (1240) describes

10712-416: Was likely deposited in pore space between grains, suggesting a high-energy depositional environment that removed carbonate mud. Recrystallized sparite is not diagnostic of depositional environment. Limestone outcrops are recognized in the field by their softness (calcite and aragonite both have a Mohs hardness of less than 4, well below common silicate minerals) and because limestone bubbles vigorously when

10816-622: Was quarried on the Isle of Portland in Dorset , England. His son William continued developments into the 1840s, earning him recognition for the development of "modern" Portland cement. Reinforced concrete was invented in 1849 by Joseph Monier . and the first reinforced concrete house was built by François Coignet in 1853. The first concrete reinforced bridge was designed and built by Joseph Monier in 1875. Prestressed concrete and post-tensioned concrete were pioneered by Eugène Freyssinet ,

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