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Wire drawing

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Wire drawing is a metalworking process used to reduce the cross-section of a wire by pulling the wire through one or more dies . There are many applications for wire drawing, including electrical wiring, cables, tension-loaded structural components, springs, paper clips, spokes for wheels, and stringed musical instruments. Although similar in process, drawing is different from extrusion , because in drawing the wire is pulled, rather than pushed, through the die. Drawing is usually performed at room temperature, thus classified as a cold working process, but it may be performed at elevated temperatures for large wires to reduce forces.

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73-401: Of the elemental metals, copper , silver , gold , and platinum are the most ductile and immune from many of the problems associated with cold working . The wire drawing process is quite simple in concept. The wire is prepared by shrinking the beginning of it, by hammering, filing, rolling or swaging , so that it will fit through the die; the wire is then pulled through the die. As the wire

146-579: A Gilman reagent . These can undergo substitution with alkyl halides to form coupling products ; as such, they are important in the field of organic synthesis . Copper(I) acetylide is highly shock-sensitive but is an intermediate in reactions such as the Cadiot–Chodkiewicz coupling and the Sonogashira coupling . Conjugate addition to enones and carbocupration of alkynes can also be achieved with organocopper compounds. Copper(I) forms

219-696: A covalent character and are relatively weak. This observation explains the low hardness and high ductility of single crystals of copper. At the macroscopic scale, introduction of extended defects to the crystal lattice , such as grain boundaries, hinders flow of the material under applied stress, thereby increasing its hardness. For this reason, copper is usually supplied in a fine-grained polycrystalline form, which has greater strength than monocrystalline forms. The softness of copper partly explains its high electrical conductivity ( 59.6 × 10   S /m ) and high thermal conductivity, second highest (second only to silver) among pure metals at room temperature. This

292-643: A nickel ) consists of 75% copper and 25% nickel in homogeneous composition. Prior to the introduction of cupronickel, which was widely adopted by countries in the latter half of the 20th century, alloys of copper and silver were also used, with the United States using an alloy of 90% silver and 10% copper until 1965, when circulating silver was removed from all coins with the exception of the half dollar—these were debased to an alloy of 40% silver and 60% copper between 1965 and 1970. The alloy of 90% copper and 10% nickel, remarkable for its resistance to corrosion,

365-425: A spin of 3 ⁄ 2 . The other isotopes are radioactive , with the most stable being Cu with a half-life of 61.83 hours. Seven metastable isomers have been characterized; Cu is the longest-lived with a half-life of 3.8 minutes. Isotopes with a mass number above 64 decay by β , whereas those with a mass number below 64 decay by β . Cu , which has

438-399: A blast furnace. A potential source of copper is polymetallic nodules, which have an estimated concentration 1.3%. Like aluminium , copper is recyclable without any loss of quality, both from raw state and from manufactured products. In volume, copper is the third most recycled metal after iron and aluminium. An estimated 80% of all copper ever mined is still in use today. According to

511-432: A block or Turk's-head machine are used. Lubrication in the drawing process is essential for maintaining good surface finish and long die life. The following are different methods of lubrication: Various lubricants, such as oil , are employed. Another lubrication method is to immerse the wire in a copper(II) sulfate solution, such that a film of copper is deposited which forms a kind of lubricant. In some classes of wire

584-464: A blue crystalline penta hydrate , the most familiar copper compound in the laboratory. It is used in a fungicide called the Bordeaux mixture . Polyols , compounds containing more than one alcohol functional group , generally interact with cupric salts. For example, copper salts are used to test for reducing sugars . Specifically, using Benedict's reagent and Fehling's solution the presence of

657-488: A different rotation speed for each block. One of these machines may contain 3 to 12 dies. The operation of threading the wire through all the dies and around the blocks is termed "stringing-up". The arrangements for lubrication include a pump which floods the dies, and in many cases also the bottom portions of the blocks run in lubricant. Often intermediate anneals are required to counter the effects of cold working, and to allow further drawing. A final anneal may also be used on

730-457: A green patina of compounds called verdigris . Copper is sometimes used in decorative art , both in its elemental metal form and in compounds as pigments. Copper compounds are used as bacteriostatic agents , fungicides , and wood preservatives . Copper is essential to all living organisms as a trace dietary mineral because it is a key constituent of the respiratory enzyme complex cytochrome c oxidase . In molluscs and crustaceans , copper

803-505: A half-life of 12.7 hours, decays both ways. Cu and Cu have significant applications. Cu is used in Cu Cu-PTSM as a radioactive tracer for positron emission tomography . Copper is produced in massive stars and is present in the Earth's crust in a proportion of about 50 parts per million (ppm). In nature, copper occurs in

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876-687: A layer of brown-black copper oxide which, unlike the rust that forms on iron in moist air, protects the underlying metal from further corrosion ( passivation ). A green layer of verdigris (copper carbonate) can often be seen on old copper structures, such as the roofing of many older buildings and the Statue of Liberty . Copper tarnishes when exposed to some sulfur compounds, with which it reacts to form various copper sulfides . There are 29 isotopes of copper. Cu and Cu are stable, with Cu comprising approximately 69% of naturally occurring copper; both have

949-532: A natural color other than gray or silver. Pure copper is orange-red and acquires a reddish tarnish when exposed to air. This is due to the low plasma frequency of the metal, which lies in the red part of the visible spectrum, causing it to absorb the higher-frequency green and blue colors. As with other metals, if copper is put in contact with another metal in the presence of an electrolyte , galvanic corrosion will occur. Copper does not react with water, but it does slowly react with atmospheric oxygen to form

1022-407: A red-brown precipitate with copper(II) salts. Compounds that contain a carbon-copper bond are known as organocopper compounds. They are very reactive towards oxygen to form copper(I) oxide and have many uses in chemistry . They are synthesized by treating copper(I) compounds with Grignard reagents , terminal alkynes or organolithium reagents ; in particular, the last reaction described produces

1095-407: A religious medium. It is often considered a spiritually purifying agent and is used for anointing purposes. As a particular example, holy anointing oil has been an important ritual liquid for Judaism and Christianity . Oils have been consumed since ancient times. Oils hold lots of fats and medical properties. A good example is olive oil. Olive oil holds a lot of fats within it which is why it

1168-451: A rich variety of compounds, usually with oxidation states +1 and +2, which are often called cuprous and cupric , respectively. Copper compounds promote or catalyse numerous chemical and biological processes. As with other elements, the simplest compounds of copper are binary compounds, i.e. those containing only two elements, the principal examples being oxides, sulfides, and halides . Both cuprous and cupric oxides are known. Among

1241-424: A variety of minerals, including native copper , copper sulfides such as chalcopyrite , bornite , digenite , covellite , and chalcocite , copper sulfosalts such as tetrahedite-tennantite , and enargite , copper carbonates such as azurite and malachite , and as copper(I) or copper(II) oxides such as cuprite and tenorite , respectively. The largest mass of elemental copper discovered weighed 420 tonnes and

1314-436: A variety of weak complexes with alkenes and carbon monoxide , especially in the presence of amine ligands. Copper(III) is most often found in oxides. A simple example is potassium cuprate , KCuO 2 , a blue-black solid. The most extensively studied copper(III) compounds are the cuprate superconductors . Yttrium barium copper oxide (YBa 2 Cu 3 O 7 ) consists of both Cu(II) and Cu(III) centres. Like oxide, fluoride

1387-603: Is a chemical element ; it has symbol Cu (from Latin cuprum ) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity . A freshly exposed surface of pure copper has a pinkish-orange color . Copper is used as a conductor of heat and electricity, as a building material , and as a constituent of various metal alloys , such as sterling silver used in jewelry , cupronickel used to make marine hardware and coins , and constantan used in strain gauges and thermocouples for temperature measurement. Copper

1460-583: Is a constituent of the blood pigment hemocyanin , replaced by the iron-complexed hemoglobin in fish and other vertebrates . In humans, copper is found mainly in the liver, muscle, and bone. The adult body contains between 1.4 and 2.1 mg of copper per kilogram of body weight. In the Roman era , copper was mined principally on Cyprus , the origin of the name of the metal, from aes cyprium (metal of Cyprus), later corrupted to cuprum (Latin). Coper ( Old English ) and copper were derived from this,

1533-405: Is a highly basic anion and is known to stabilize metal ions in high oxidation states. Both copper(III) and even copper(IV) fluorides are known, K 3 CuF 6 and Cs 2 CuF 6 , respectively. Some copper proteins form oxo complexes , which, in extensively studied synthetic analog systems, feature copper(III). With tetrapeptides , purple-colored copper(III) complexes are stabilized by

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1606-401: Is because the resistivity to electron transport in metals at room temperature originates primarily from scattering of electrons on thermal vibrations of the lattice, which are relatively weak in a soft metal. The maximum possible current density of copper in open air is approximately 3.1 × 10  A/m , above which it begins to heat excessively. Copper is one of a few metallic elements with

1679-423: Is generally 15–25% and in larger wires is 20–45%. The exact die sequence for a particular job is a function of area reduction, input wire size and output wire size. As the area reduction changes, so does the die sequence. Very fine wires are usually drawn in bundles. In a bundle, the wires are separated by a metal with similar properties, but with lower chemical resistance so that it can be removed after drawing. If

1752-533: Is melted in a furnace and then reduced and cast into billets and ingots ; lower-purity scrap is refined by electroplating in a bath of sulfuric acid . The environmental cost of copper mining was estimated at 3.7 kg CO2eq per kg of copper in 2019. Codelco, a major producer in Chile, reported that in 2020 the company emitted 2.8t CO2eq per ton (2.8 kg CO2eq per kg) of fine copper. Greenhouse gas emissions primarily arise from electricity consumed by

1825-1202: Is no evidence that NASA has used whale oil. Some oils burn in liquid or aerosol form, generating light , and heat which can be used directly or converted into other forms of energy such as electricity or mechanical work. In order to obtain many fuel oils, crude oil is pumped from the ground and is shipped via oil tanker or a pipeline to an oil refinery . There, it is converted from crude oil to diesel fuel (petrodiesel), ethane (and other short-chain alkanes ), fuel oils (heaviest of commercial fuels, used in ships/furnaces), gasoline (petrol), jet fuel , kerosene , benzene (historically), and liquefied petroleum gas . A 42-US-gallon (35 imp gal; 160 L) barrel of crude oil produces approximately 10 US gallons (8.3 imp gal; 38 L) of diesel, 4 US gallons (3.3 imp gal; 15 L) of jet fuel, 19 US gallons (16 imp gal; 72 L) of gasoline, 7 US gallons (5.8 imp gal; 26 L) of other products, 3 US gallons (2.5 imp gal; 11 L) split between heavy fuel oil and liquified petroleum gases, and 2 US gallons (1.7 imp gal; 7.6 L) of heating oil. The total production of

1898-762: Is one of the few metals that can occur in nature in a directly usable metallic form ( native metals ). This led to very early human use in several regions, from c.  8000 BC . Thousands of years later, it was the first metal to be smelted from sulfide ores, c.  5000 BC ; the first metal to be cast into a shape in a mold, c.  4000 BC ; and the first metal to be purposely alloyed with another metal, tin , to create bronze , c.  3500 BC . Commonly encountered compounds are copper(II) salts, which often impart blue or green colors to such minerals as azurite , malachite , and turquoise , and have been used widely and historically as pigments. Copper used in buildings, usually for roofing, oxidizes to form

1971-444: Is one of the most important constituents of silver and karat gold solders used in the jewelry industry, modifying the color, hardness and melting point of the resulting alloys. Some lead-free solders consist of tin alloyed with a small proportion of copper and other metals. The alloy of copper and nickel , called cupronickel , is used in low-denomination coins, often for the outer cladding. The US five-cent coin (currently called

2044-644: Is preferred for lubricating clocks, because it does not evaporate, leaving dust, although its use was banned in the US in 1980. It is a long-running myth that spermaceti from whales has still been used in NASA projects such as the Hubble Space Telescope and the Voyager probe because of its extremely low freezing temperature. Spermaceti is not actually an oil, but a mixture mostly of wax esters, and there

2117-406: Is provided with means for rapidly coupling or uncoupling it to its vertical shaft, so that the motion of the wire may be stopped or started instantly. The block is also tapered, so that the coil of wire may be easily slipped off upwards when finished. Before the wire can be attached to the block, a sufficient length of it must be pulled through the die; this is effected by a pair of gripping pincers on

2190-496: Is pulled through the die, its volume remains the same, so as the diameter decreases, the length increases. Usually the wire will require more than one draw, through successively smaller dies, to reach the desired size. The American wire gauge scale is based on this. This can be done on a small scale with a draw plate , or on a large commercial scale using automated machinery. The process of wire drawing changes material properties due to cold working. The area reduction in small wires

2263-437: Is recovered from mine tailings and heaps. A variety of methods are used including leaching with sulfuric acid, ammonia, ferric chloride. Biological methods are also used. A significant source of copper is from recycling. Recycling is facilitated because copper is usually deployed in its metallic state. In 2001, a typical automobile contained 20–30 kg of copper. Recycling usually begins with some melting process using

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2336-465: Is remote (and was unknown at the time of its discovery), and because it is obtained in the vicinity of rocks, underground traps, and sands. Mineral oil also refers to several specific distillates of crude oil. Several edible vegetable and animal oils, and also fats , are used for various purposes in cooking and food preparation. In particular, many foods are fried in oil much hotter than boiling water. Oils are also used for flavoring and for modifying

2409-411: Is used for various objects exposed to seawater, though it is vulnerable to the sulfides sometimes found in polluted harbors and estuaries. Alloys of copper with aluminium (about 7%) have a golden color and are used in decorations. Shakudō is a Japanese decorative alloy of copper containing a low percentage of gold, typically 4–10%, that can be patinated to a dark blue or black color. Copper forms

2482-686: The British Geological Survey , in 2005, Chile was the top producer of copper with at least one-third of the world share followed by the United States, Indonesia and Peru. Copper can also be recovered through the in-situ leach process. Several sites in the state of Arizona are considered prime candidates for this method. The amount of copper in use is increasing and the quantity available is barely sufficient to allow all countries to reach developed world levels of usage. An alternative source of copper for collection currently being researched are polymetallic nodules , which are located at

2555-607: The Great Lakes may have also been mining copper during this time, making it one of the oldest known examples of copper extraction in the world. There is evidence from prehistoric lead pollution from lakes in Michigan that people in the region began mining copper c.  6000 BC . Evidence suggests that utilitarian copper objects fell increasingly out of use in the Old Copper Complex of North America during

2628-553: The International Resource Panel 's Metal Stocks in Society report , the global per capita stock of copper in use in society is 35–55 kg. Much of this is in more-developed countries (140–300 kg per capita) rather than less-developed countries (30–40 kg per capita). The process of recycling copper is roughly the same as is used to extract copper but requires fewer steps. High-purity scrap copper

2701-726: The Neolithic period and the Bronze Age was formerly termed the Chalcolithic period (copper-stone), when copper tools were used with stone tools. The term has gradually fallen out of favor because in some parts of the world, the Chalcolithic and Neolithic are coterminous at both ends. Brass, an alloy of copper and zinc, is of much more recent origin. It was known to the Greeks, but became a significant supplement to bronze during

2774-525: The Vinča culture date to 4500 BC. Sumerian and Egyptian artifacts of copper and bronze alloys date to 3000 BC. Egyptian Blue , or cuprorivaite (calcium copper silicate) is a synthetic pigment that contains copper and started being used in ancient Egypt around 3250 BC. The manufacturing process of Egyptian blue was known to the Romans, but by the fourth century AD the pigment fell out of use and

2847-548: The 9th or 10th century AD. Carbon dating has established mining at Alderley Edge in Cheshire , UK, at 2280 to 1890 BC. Ötzi the Iceman , a male dated from 3300 to 3200 BC, was found with an axe with a copper head 99.7% pure; high levels of arsenic in his hair suggest an involvement in copper smelting. Experience with copper has assisted the development of other metals; in particular, copper smelting likely led to

2920-517: The Bronze Age and a shift towards an increased production of ornamental copper objects occurred. Natural bronze, a type of copper made from ores rich in silicon, arsenic, and (rarely) tin, came into general use in the Balkans around 5500 BC. Alloying copper with tin to make bronze was first practiced about 4000 years after the discovery of copper smelting, and about 2000 years after "natural bronze" had come into general use. Bronze artifacts from

2993-541: The Middle East; a copper pendant was found in northern Iraq that dates to 8700 BC. Evidence suggests that gold and meteoric iron (but not smelted iron) were the only metals used by humans before copper. The history of copper metallurgy is thought to follow this sequence: first, cold working of native copper, then annealing , smelting , and, finally, lost-wax casting . In southeastern Anatolia , all four of these techniques appear more or less simultaneously at

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3066-796: The Roman Empire. Oil An oil is any nonpolar chemical substance that is composed primarily of hydrocarbons and is hydrophobic (does not mix with water ) and lipophilic (mixes with other oils). Oils are usually flammable and surface active . Most oils are unsaturated lipids that are liquid at room temperature. The general definition of oil includes classes of chemical compounds that may be otherwise unrelated in structure, properties, and uses. Oils may be animal , vegetable , or petrochemical in origin, and may be volatile or non-volatile. They are used for food (e.g., olive oil ), fuel (e.g., heating oil ), medical purposes (e.g., mineral oil ), lubrication (e.g. motor oil ), and

3139-521: The affected areas is highly acidic, with a pH range of 2.1–4.9, and shows elevated electrical conductivity levels between 280 and 1561 mS/cm. These changes in water chemistry make the environment inhospitable for fish, essentially rendering the water uninhabitable for aquatic life. Numerous copper alloys have been formulated, many with important uses. Brass is an alloy of copper and zinc . Bronze usually refers to copper- tin alloys, but can refer to any alloy of copper such as aluminium bronze . Copper

3212-541: The atmosphere; 150 mg/kg in soil; 30 mg/kg in vegetation; 2 μg/L in freshwater and 0.5 μg/L in seawater. Most copper is mined or extracted as copper sulfides from large open pit mines in porphyry copper deposits that contain 0.4 to 1.0% copper. Sites include Chuquicamata , in Chile, Bingham Canyon Mine , in Utah, United States, and El Chino Mine , in New Mexico, United States. According to

3285-766: The beginning of the Neolithic c.  7500 BC . Copper smelting was independently invented in different places. The earliest evidence of lost-wax casting copper comes from an amulet found in Mehrgarh , Pakistan, and is dated to 4000 BC. Investment casting was invented in 4500–4000 BC in Southeast Asia Smelting was probably discovered in China before 2800 BC, in Central America around 600 AD, and in West Africa about

3358-531: The company, especially when sourced from fossil fuels, and from engines required for copper extraction and refinement. Companies that mine land often mismanage waste, rendering the area sterile for life. Additionally, nearby rivers and forests are also negatively impacted. The Philippines is an example of a region where land is overexploited by mining companies. Copper mining waste in Valea Şesei, Romania, has significantly altered nearby water properties. The water in

3431-554: The copper is left after the final drawing to serve as a preventive of rust or to allow easy soldering .The best example of copper coated wire is in MIG wire used in welding. The strength-enhancing effect of wire drawing can be substantial. The highest strengths available on any steel have been recorded on small-diameter cold-drawn austenitic stainless wire. Drawing dies are typically made of tool steel , tungsten carbide , or diamond , with tungsten carbide and manufactured diamond being

3504-522: The deprotonated amide ligands. Complexes of copper(III) are also found as intermediates in reactions of organocopper compounds, for example in the Kharasch–Sosnovsky reaction . A timeline of copper illustrates how this metal has advanced human civilization for the past 11,000 years. Copper occurs naturally as native metallic copper and was known to some of the oldest civilizations on record. The history of copper use dates to 9000 BC in

3577-461: The depths of the Pacific Ocean approximately 3000–6500 meters below sea level. These nodules contain other valuable metals such as cobalt and nickel . Copper has been in use for at least 10,000 years, but more than 95% of all copper ever mined and smelted has been extracted since 1900. As with many natural resources, the total amount of copper on Earth is vast, with around 10 tons in

3650-443: The dies accurately in position and for drawing the wire steadily through the holes. The usual design consists of a cast-iron bench or table having a bracket standing up to hold the die, and a vertical drum which rotates and by coiling the wire around its surface pulls it through the die, the coil of wire being stored upon another drum or "swift" which lies behind the die and reels off the wire as fast as required. The wire drum or "block"

3723-563: The discovery of iron smelting . Production in the Old Copper Complex in Michigan and Wisconsin is dated between 6500 and 3000 BC. A copper spearpoint found in Wisconsin has been dated to 6500 BC. Copper usage by the indigenous peoples of the Old Copper Complex from the Great Lakes region of North America has been radiometrically dated to as far back as 7500 BC. Indigenous peoples of North America around

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3796-471: The end of a chain which is wound around a revolving drum, so drawing the wire until enough can be coiled two or three times on the block, where the end is secured by a small screw clamp or vice. When the wire is on the block, it is set in motion and the wire is drawn steadily through the die; it is very important that the block rotates evenly and that it runs true and pulls the wire at a constant velocity, otherwise "snatching" occurs which will weaken or even break

3869-896: The excess grime and creating a layer where new grime could form but be easily washed off in the water as oil is hydrophobic. Fish oils hold the omega-3 fatty acid. This fatty acid helps with inflammation and reduces fat in the bloodstream.   Color pigments are easily suspended in oil, making it suitable as a supporting medium for paints . The oldest known extant oil paintings date from 650 AD. Oils are used as coolants in oil cooling , for instance in electric transformers . Heat transfer oils are used both as coolants (see oil cooling ), for heating (e.g. in oil heaters ) and in other applications of heat transfer. Given that they are non-polar, oils do not easily adhere to other substances. This makes them useful as lubricants for various engineering purposes. Mineral oils are more commonly used as machine lubricants than biological oils are. Whale oil

3942-545: The fastest water exchange rate (speed of water ligands attaching and detaching) for any transition metal aquo complex . Adding aqueous sodium hydroxide causes the precipitation of light blue solid copper(II) hydroxide . A simplified equation is: Aqueous ammonia results in the same precipitate. Upon adding excess ammonia, the precipitate dissolves, forming tetraamminecopper(II) : Many other oxyanions form complexes; these include copper(II) acetate , copper(II) nitrate , and copper(II) carbonate . Copper(II) sulfate forms

4015-443: The finished product to maximize ductility and electrical conductivity . An example of product produced in a continuous wire drawing machine is telephone wire. It is drawn 20 to 30 times from hot rolled rod stock. While round cross-sections dominate most drawing processes, non-circular cross-sections are drawn. They are usually drawn when the cross-section is small and quantities are too low to justify rolling . In these processes,

4088-511: The later spelling first used around 1530. Copper, silver , and gold are in group 11 of the periodic table; these three metals have one s-orbital electron on top of a filled d- electron shell and are characterized by high ductility , and electrical and thermal conductivity. The filled d-shells in these elements contribute little to interatomic interactions, which are dominated by the s-electrons through metallic bonds . Unlike metals with incomplete d-shells, metallic bonds in copper are lacking

4161-419: The level of <1% Cu. Concentration of the ore is required, which begins with comminution followed by froth flotation . The remaining concentrate is the smelted, which can be described with two simplified equations: Cuprous oxide reacts with cuprous sulfide to convert to blister copper upon heating This roasting gives matte copper, roughly 50% Cu by weight, which is purified by electrolysis. Depending on

4234-551: The manufacture of many types of paints, plastics, and other materials. Specially prepared oils are used in some religious ceremonies and rituals as purifying agents. First attested in English 1176, the word oil comes from Old French oile , from Latin oleum , which in turn comes from the Greek ἔλαιον ( elaion ), "olive oil, oil" and that from ἐλαία ( elaia ), " olive tree", "olive fruit". The earliest attested forms of

4307-412: The modern economy. Crude oil originates from ancient fossilized organic materials , such as zooplankton and algae , which geochemical processes convert into oil. The name "mineral oil" is a misnomer , in that minerals are not the source of the oil—ancient plants and animals are. Mineral oil is organic. However, it is classified as "mineral oil" instead of as "organic oil" because its organic origin

4380-472: The modern world. The price of copper is volatile . After a peak in 2022 the price unexpectedly fell. The global market for copper is one of the most commodified and financialized of the commodity markets , and has been so for decades. The great majority of copper ores are sulfides. Common ores are the sulfides chalcopyrite (CuFeS 2 ), bornite (Cu 5 FeS 4 ) and, to a lesser extent, covellite (CuS) and chalcocite (Cu 2 S). These ores occur at

4453-423: The most common. For drawing very fine wire a single crystal diamond die is used. For hot drawing, cast-steel dies are used. For steel wire drawing, a tungsten carbide die is used. The dies are placed in a steel casing, which backs the die and allow for easy die changes. Die angles usually range from 6–15°, and each die has at least 2 different angles: the entering angle and approach angle. Copper Copper

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4526-516: The numerous copper sulfides , important examples include copper(I) sulfide ( Cu 2 S ) and copper monosulfide ( CuS ). Cuprous halides with fluorine , chlorine , bromine , and iodine are known, as are cupric halides with fluorine , chlorine , and bromine . Attempts to prepare copper(II) iodide yield only copper(I) iodide and iodine. Copper forms coordination complexes with ligands . In aqueous solution, copper(II) exists as [Cu(H 2 O) 6 ] . This complex exhibits

4599-428: The ore, sometimes other metals are obtained during the electrolysis including platinum and gold. Aside from sulfides, another family of ores are oxides. Approximately 15% of the world's copper supply derives from these oxides. The beneficiation process for oxides involves extraction with sulfuric acid solutions followed by electrolysis. In parallel with the above method for "concentrated" sulfide and oxide ores, copper

4672-435: The reduction in area is greater than 50%, the process may require an intermediate step of annealing before it can be redrawn. Commercial wire drawing usually starts with a coil of hot rolled 9 mm (0.35 in) diameter wire. The surface is first treated to remove scales. It is then fed into a wire drawing machine which may have one or more blocks in series. Single block wire drawing machines include means for holding

4745-750: The secret to its manufacturing process became lost. The Romans said the blue pigment was made from copper, silica, lime and natron and was known to them as caeruleum . The Bronze Age began in Southeastern Europe around 3700–3300 BC, in Northwestern Europe about 2500 BC. It ended with the beginning of the Iron Age, 2000–1000 BC in the Near East, and 600 BC in Northern Europe. The transition between

4818-438: The sugar is signaled by a color change from blue Cu(II) to reddish copper(I) oxide. Schweizer's reagent and related complexes with ethylenediamine and other amines dissolve cellulose . Amino acids such as cystine form very stable chelate complexes with copper(II) including in the form of metal-organic biohybrids (MOBs). Many wet-chemical tests for copper ions exist, one involving potassium ferricyanide , which gives

4891-399: The texture of foods (e.g. stir fry ). Cooking oils are derived either from animal fat, as butter , lard and other types, or plant oils from olive , maize , sunflower and many other species. Oils are applied to hair to give it a lustrous look, to prevent tangles and roughness and to stabilize the hair to promote growth. See hair conditioner . Oil has been used throughout history as

4964-399: The top kilometer of Earth's crust, which is about 5 million years' worth at the current rate of extraction. However, only a tiny fraction of these reserves is economically viable with present-day prices and technologies. Estimates of copper reserves available for mining vary from 25 to 60 years, depending on core assumptions such as the growth rate. Recycling is a major source of copper in

5037-533: The way that they are made by an organism, their chemical structure and their limited solubility in water compared to oils. They have a high carbon and hydrogen content and are considerably lacking in oxygen compared to other organic compounds and minerals; they tend to be relatively nonpolar molecules, but may include both polar and nonpolar regions as in the case of phospholipids and steroids. Crude oil, or petroleum , and its refined components, collectively termed petrochemicals , are crucial resources in

5110-404: The wire. The speeds at which wire is drawn vary greatly, according to the material and the amount of reduction. Machines with continuous blocks differ from single block machines by having a series of dies through which the wire is drawn in a continuous fashion. Due to the elongation and slips, the speed of the wire changes after each successive redraw. This increased speed is accommodated by having

5183-786: The word are the Mycenaean Greek 𐀁𐀨𐀺 , e-ra-wo and 𐀁𐁉𐀺 , e-rai-wo , written in the Linear B syllabic script. Organic oils are produced in remarkable diversity by plants, animals, and other organisms through natural metabolic processes. Lipid is the scientific term for the fatty acids , steroids and similar chemicals often found in the oils produced by living things, while oil refers to an overall mixture of chemicals. Organic oils may also contain chemicals other than lipids, including proteins , waxes (class of compounds with oil-like properties that are solid at common temperatures) and alkaloids . Lipids can be classified by

5256-419: Was also used in lighting in ancient Greece and Rome. So people would use it to bulk out food so they would have more energy to burn through the day. Olive oil was also used to clean the body in this time as it would trap the moisture in the skin while pulling the grime to the surface. It was used as an ancient form of unsophisticated soap. It was applied on the skin then scrubbed off with a wooden stick pulling off

5329-527: Was found in 1857 on the Keweenaw Peninsula in Michigan, US. Native copper is a polycrystal , with the largest single crystal ever described measuring 4.4 × 3.2 × 3.2 cm . Copper is the 26th most abundant element in Earth's crust , representing 50 ppm compared with 75 ppm for zinc , and 14 ppm for lead . Typical background concentrations of copper do not exceed 1 ng/m in

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