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Thermal Oxide Reprocessing Plant

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19-560: The Thermal Oxide Reprocessing Plant , or THORP , is a nuclear fuel reprocessing plant at Sellafield in Cumbria , England. THORP is owned by the Nuclear Decommissioning Authority and operated by Sellafield Ltd , the site licensee. Spent nuclear fuel from nuclear reactors was reprocessed to separate the 96% uranium and the 1% plutonium from the 3% radioactive wastes, which are treated and stored at

38-483: A highly radioactive solution, which had started in July 2004. British Nuclear Group's board of inquiry determined that a design error led to the leak, while a complacent culture at the plant delayed detection for nine months. Operations staff did not discover the leak until safeguards staff reported major fluid accountancy discrepancies. Altogether 83 cubic metres (82,966 litres ) of hot nitric acid solution leaked from

57-514: A radioactive beta-emitter with a half-life of 10.7 years. The Radiological Protection Institute of Ireland (RPII) commenced 24-hour atmospheric monitoring for krypton-85 in 1993, prior to the plant's commissioning. The cooled oxide fuel is chopped up in the Shear Cell and the fuel dissolved in nitric acid. It is chemically conditioned before passing to the chemical separation plant. Pulsed columns (designated HA/HS) are used to initially separate

76-477: A small fractured feedpipe, which was discovered when a remote camera was sent in to examine THORP's Feed Clarification Cell on 19 April 2005. All the fluids collected under gravity into the secondary containment , which is a stainless steel tub embedded in 2-metre thick reinforced concrete , capable of holding 250 cubic metres of fluids. The solution from the spill was estimated to contain 20 metric tons of uranium and 160 kilograms of plutonium. The leaked solution

95-495: Is expected to occur between 2075 and 2095. The estimated cost of decommissioning is forecast as £4 billion at 2018 prices. The chemical flowsheet for THORP is designed to add less non-volatile matter to the first cycle PUREX raffinate . One way in which this is done is by avoiding the use of ferrous compounds as plutonium reducing agents. In this plant the reduction is done using either hydrazine or HAN ( hydroxylamine nitrate ). The plant releases gaseous emissions of krypton-85,

114-427: Is reduced to the +3 oxidation state, which is insoluble in the solvent phase so ends up in the aqueous phase exiting the 1BX column. The 1BXX mixer/settler completes the removal of Pu from the solvent phase. The 1BS column removes any remaining Uranium from the aqueous phase by the use of fresh solvent. Pulsed columns then purify the plutonium, removing the troublesome fission products that remain. A mixer/settler (1C)

133-475: Is used to transfer (washes) the uranium across to the aqueous phase ready for the next stage. Uranium purification is achieved using three mixer settlers (UP1 - UP3) similar to those in use on the existing Magnox reprocessing plant. Evaporation of the two product streams then occurs before further processing is undertaken. Uranium is converted to UO 3 powder while the plutonium is converted to PuO 2 powder and sent to storage. Pulsed columns were chosen to avoid

152-677: The International Bureau of Weights and Measures ) or cubic meter (in American English ) is the unit of volume in the International System of Units (SI). Its symbol is m . It is the volume of a cube with edges one metre in length. An alternative name, which allowed a different usage with metric prefixes , was the stère , still sometimes used for dry measure (for instance, in reference to wood ). Another alternative name, no longer widely used,

171-665: The Thermal Oxide Reprocessing Plant, was given the go-ahead in 1978. Construction of THORP started in 1979, and was completed in 1994. The plant went into operation in August 1997. Build cost was £1.8 billion. THORP's first irradiated fuel rod was sheared in March 1994, which was followed in January of 1995 by the chemical separation plant processing the irradiated fuel feed solution that had been produced in

190-456: The UK's PWR and AGR fleet. The decommissioning is expected to start around 2075. Between 1977 and 1978 an inquiry was held into an application by British Nuclear Fuels plc for outline planning permission to build a new plant to reprocess irradiated oxide nuclear fuel from both UK and foreign reactors. The inquiry was to answer three questions: The result of the inquiry was that the new plant,

209-521: The design for seismic uncoupling. The incident was classified as Level 3 out of 7 on the International Nuclear Event Scale (INES), a "serious incident", due to the amount of radioactive inventory that leaked from primary to secondary containment without discovery over a number of months. This was initially considered by BNFL to be surprisingly high, but the specifications of the scale required it. The British Nuclear Group

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228-727: The effects of the fission product technetium, has given an overall separation performance well in excess of the minimum flowsheet requirement. THORP's discharges represented a small fraction of overall discharges from the wider Sellafield site. On 14 November 2018 it was announced that reprocessing operations had ended at THORP after all existing reprocessing contracts had been fulfilled. It had reprocessed 9,331 tonnes of used nuclear fuel from 30 customers in nine countries, earning £9bn in revenue. The receipt and storage facility within THORP continues to operate. Decommissioning will take place after several decades to allow radiation levels to decline, and

247-533: The majority of the uranium and plutonium from the fission products by transferring them into the solvent phase, which comprises tri-butyl phosphate in odourless kerosene (TBP/OK). The transfer is done in the HA column with the HS column providing further removal of fission products. 2 further pulsed columns (designated BS/BX) and a mixer/settler assembly (1BXX) then separate the uranium and plutonium into separate streams. Plutonium

266-441: The plant. The uranium is then made available for customers to be manufactured into new fuel, and the plutonium incorporated into mixed oxide fuel . On 14 November 2018 it was announced that reprocessing operations had ended at THORP after earning £9bn in revenue. The receipt and storage facility (which makes up nearly half of THORP's physical footprint), will operate through to the 2070s to receive and store spent nuclear fuel from

285-622: The previous year by the Head End plant. By the Spring of 1998 over 1400 t of irradiated fuel has been reprocessed in THORP, and the plant was steadily and successfully ramped up to its normal operating throughput throughout this time. At this time, the performance of the THORP Chemical Separation Plant had been excellent, above all, the uranium-plutonium separation stage, which received extensive development to deal with

304-404: The risk of a criticality incident occurring within the plant. This can happen if sufficient fissile material comes together to start an uncontrolled chain reaction, producing a large release of neutrons. The risks and mechanisms are well understood and the plant design is arranged to prevent its occurrence, i.e.: intrinsically safe. On 9 May 2005 it was announced that THORP suffered a large leak of

323-840: Was convicted for breaches of health and safety regulations following the accident, and fined £500,000. Production at the plant restarted in late 2007, but in early 2008 stopped again for the repair of an underwater lift that moved fuel for reprocessing. Nuclear reprocessing Too Many Requests If you report this error to the Wikimedia System Administrators, please include the details below. Request from 172.68.168.132 via cp1112 cp1112, Varnish XID 946448981 Upstream caches: cp1112 int Error: 429, Too Many Requests at Thu, 28 Nov 2024 08:34:52 GMT Cubic metre The cubic metre (in Commonwealth English and international spelling as used by

342-406: Was safely recovered into primary containment using originally installed steam ejectors. Radiation levels in the cell precluded entry of humans. The pipe fractured due to lateral motion of an accountancy tank, which measures volume by weight and moves horizontally and vertically in the process. The tank's original design had restraint blocks to prevent lateral motion, but these were later removed from

361-647: Was the kilolitre . A cubic metre of pure water at the temperature of maximum density (3.98 °C) and standard atmospheric pressure (101.325 kPa) has a mass of 1000  kg , or one tonne . At 0 °C, the freezing point of water, a cubic metre of water has slightly less mass, 999.972 kilograms. A cubic metre is sometimes abbreviated to m^3 , M3 , m**3 , cum , m3 , CBM , cbm when superscript characters or markup cannot be used (e.g. in some typewritten documents and postings in Usenet newsgroups). The "cubic metre" symbol

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