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86-614: Table Mountain Sandstone (TMS) is a group of rock formations within the Cape Supergroup sequence of rocks. Although the term "Table Mountain Sandstone" is still widely used in common parlance, the term TMS is no longer formally recognized; the correct name is the " Peninsula Formation Sandstone ", which is part of the Table Mountain Group . The designation "Table Mountain Sandstone" will, however, in deference to

172-588: A dissected limestone pavement . This process is most effective along the joints, widening and deepening them. In unpolluted environments, the pH of rainwater due to dissolved carbon dioxide is around 5.6. Acid rain occurs when gases such as sulfur dioxide and nitrogen oxides are present in the atmosphere. These oxides react in the rain water to produce stronger acids and can lower the pH to 4.5 or even 3.0. Sulfur dioxide , SO 2 , comes from volcanic eruptions or from fossil fuels, and can become sulfuric acid within rainwater, which can cause solution weathering to

258-469: A heterogeneous mixture of lithologies, so long as this distinguishes them from adjacent bodies of rock. The concept of a geologic formation goes back to the beginnings of modern scientific geology. The term was used by Abraham Gottlob Werner in his theory of the origin of the Earth, which was developed over the period from 1774 to his death in 1817. The concept became increasingly formalized over time and

344-436: A landscape where this contrasts starkly with the bare rocky surfaces of the quartzites above and below. In several locations the quartzites immediately below the glacial horizon have been rucked into a series of folds. This is believed to have been caused by the movement of ice ploughing into the underlying unconsolidated sands. A good example of this can be seen on a ridge of rocks near Maclear's Beacon on Table Mountain, close to

430-691: A mineral crystal exposes ions whose electrical charge attracts water molecules. Some of these molecules break into H+ that bonds to exposed anions (usually oxygen) and OH- that bonds to exposed cations. This further disrupts the surface, making it susceptible to various hydrolysis reactions. Additional protons replace cations exposed on the surface, freeing the cations as solutes. As cations are removed, silicon-oxygen and silicon-aluminium bonds become more susceptible to hydrolysis, freeing silicic acid and aluminium hydroxides to be leached away or to form clay minerals. Laboratory experiments show that weathering of feldspar crystals begins at dislocations or other defects on

516-418: A more humid chemical microenvironment. The attachment of these organisms to the rock surface enhances physical as well as chemical breakdown of the surface microlayer of the rock. Lichens have been observed to pry mineral grains loose from bare shale with their hyphae (rootlike attachment structures), a process described as plucking , and to pull the fragments into their body, where the fragments then undergo

602-542: A newly designated formation could not be named the Kaibab Formation, since the Kaibab Limestone is already established as a formation name. The first use of a name has precedence over all others, as does the first name applied to a particular formation. As with other stratigraphic units, the formal designation of a formation includes a stratotype which is usually a type section . A type section

688-617: A permanent natural or artificial feature of the geographic area in which they were first described. The name consists of the geographic name plus either "Formation" or a descriptive name. Examples include the Morrison Formation , named for the town of Morrison, Colorado , and the Kaibab Limestone , named after the Kaibab Plateau of Arizona. The names must not duplicate previous formation names, so, for example,

774-403: A process of chemical weathering not unlike digestion. On a larger scale, seedlings sprouting in a crevice and plant roots exert physical pressure as well as providing a pathway for water and chemical infiltration. Most rock forms at elevated temperature and pressure, and the minerals making up the rock are often chemically unstable in the relatively cool, wet, and oxidizing conditions typical of

860-477: A result, thermal stress weathering is sometimes called insolation weathering , but this is misleading. Thermal stress weathering can be caused by any large change of temperature, and not just intense solar heating. It is likely as important in cold climates as in hot, arid climates. Wildfires can also be a significant cause of rapid thermal stress weathering. The importance of thermal stress weathering has long been discounted by geologists, based on experiments in

946-407: A slower reaction kinetics , this process is thermodynamically favored at low temperature, because colder water holds more dissolved carbon dioxide gas (due to the retrograde solubility of gases). Carbonate dissolution is therefore an important feature of glacial weathering. Carbonate dissolution involves the following steps: Carbonate dissolution on the surface of well-jointed limestone produces

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1032-496: A thin layer (on average only about 60 m thick) in the Table Mountain Sandstone Formation of the more inland mountains to the west of a line between Swellendam and Calvinia . These diamictite rocks are composed of finely ground mud, containing a jumble of faceted pebbles. They can easily be recognized at a distance as this formation readily erodes into fertile, gently sloping, green swaths in

1118-469: A threat to the environment and occupant safety. Design strategies can moderate the impact of environmental effects, such as using of pressure-moderated rain screening, ensuring that the HVAC system is able to effectively control humidity accumulation and selecting concrete mixes with reduced water content to minimize the impact of freeze-thaw cycles. Granitic rock, the most abundant crystalline rock exposed at

1204-548: A variety of brachiopods , as well as trilobites , molluscs , echinoderms (including starfish , crinoids , and the extinct blastoids and cystoids ), foraminifera and fish with jaws ( placoderms ). The upper layers of the Bokkeveld Group become increasingly more sandy, grading into the sandstone of the Witteberg Group , named for the range of mountains to the south of Matjiesfontein and Laingsburg in

1290-426: Is acid hydrolysis , in which protons (hydrogen ions), which are present in acidic water, attack chemical bonds in mineral crystals. The bonds between different cations and oxygen ions in minerals differ in strength, and the weakest will be attacked first. The result is that minerals in igneous rock weather in roughly the same order in which they were originally formed ( Bowen's Reaction Series ). Relative bond strength

1376-473: Is endemic to areas with sand eroded from Table Mountain Sandstone. Formation (stratigraphy) A formation must be large enough that it can be mapped at the surface or traced in the subsurface. Formations are otherwise not defined by the thickness of their rock strata, which can vary widely. They are usually, but not universally, tabular in form. They may consist of a single lithology (rock type), or of alternating beds of two or more lithologies, or even

1462-449: Is not a valid lithological basis for defining a formation. The contrast in lithology between formations required to justify their establishment varies with the complexity of the geology of a region. Formations must be able to be delineated at the scale of geologic mapping normally practiced in the region; the thickness of formations may range from less than a meter to several thousand meters. Geologic formations are typically named after

1548-550: Is 14 megapascals (2,000 psi). This is still much greater than the tensile strength of granite, which is about 4 megapascals (580 psi). This makes frost wedging, in which pore water freezes and its volumetric expansion fractures the enclosing rock, appear to be a plausible mechanism for frost weathering. Ice will simply expand out of a straight open fracture before it can generate significant pressure. Thus, frost wedging can only take place in small tortuous fractures. The rock must also be almost completely saturated with water, or

1634-704: Is a crucial part of the rock cycle ; sedimentary rock , the product of weathered rock, covers 66% of the Earth's continents and much of the ocean floor . Physical weathering , also called mechanical weathering or disaggregation , is the class of processes that causes the disintegration of rocks without chemical change. Physical weathering involves the breakdown of rocks into smaller fragments through processes such as expansion and contraction, mainly due to temperature changes. Two types of physical breakdown are freeze-thaw weathering and thermal fracturing. Pressure release can also cause weathering without temperature change. It

1720-403: Is a less well characterized mechanism of physical weathering. It takes place because ice grains always have a surface layer, often just a few molecules thick, that resembles liquid water more than solid ice, even at temperatures well below the freezing point. This premelted liquid layer has unusual properties, including a strong tendency to draw in water by capillary action from warmer parts of

1806-440: Is also important, acting to oxidize many minerals, as is carbon dioxide, whose weathering reactions are described as carbonation . The process of mountain block uplift is important in exposing new rock strata to the atmosphere and moisture, enabling important chemical weathering to occur; significant release occurs of Ca and other ions into surface waters. Dissolution (also called simple solution or congruent dissolution )

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1892-715: Is also known as sheeting . As with thermal weathering, pressure release is most effective in buttressed rock. Here the differential stress directed toward the unbuttressed surface can be as high as 35 megapascals (5,100 psi), easily enough to shatter rock. This mechanism is also responsible for spalling in mines and quarries, and for the formation of joints in rock outcrops. Retreat of an overlying glacier can also lead to exfoliation due to pressure release. This can be enhanced by other physical wearing mechanisms. Salt crystallization (also known as salt weathering , salt wedging or haloclasty ) causes disintegration of rocks when saline solutions seep into cracks and joints in

1978-589: Is also used informally to describe the odd shapes (forms) that rocks acquire through erosional or depositional processes. Such a formation is abandoned when it is no longer affected by the geologic agent that produced it. Some well-known cave formations include stalactites and stalagmites . Weathering Weathering is the deterioration of rocks , soils and minerals (as well as wood and artificial materials) through contact with water, atmospheric gases , sunlight , and biological organisms. It occurs in situ (on-site, with little or no movement), and so

2064-560: Is central to the geologic discipline of stratigraphy , and the formation is the fundamental unit of stratigraphy. Formations may be combined into groups of strata or divided into members . Members differ from formations in that they need not be mappable at the same scale as formations, though they must be lithologically distinctive where present. The definition and recognition of formations allow geologists to correlate geologic strata across wide distances between outcrops and exposures of rock strata . Formations were at first described as

2150-612: Is chemically weathered to iron(II) sulfate and gypsum , which then crystallize as salt lenses. Salt crystallization can take place wherever salts are concentrated by evaporation. It is thus most common in arid climates where strong heating causes strong evaporation and along coasts. Salt weathering is likely important in the formation of tafoni , a class of cavernous rock weathering structures. Living organisms may contribute to mechanical weathering, as well as chemical weathering (see § Biological weathering below). Lichens and mosses grow on essentially bare rock surfaces and create

2236-442: Is distinct from erosion , which involves the transport of rocks and minerals by agents such as water , ice , snow , wind , waves and gravity . Weathering processes are either physical or chemical. The former involves the breakdown of rocks and soils through such mechanical effects as heat, water, ice and wind. The latter covers reactions to water, atmospheric gases and biologically produced chemicals with rocks and soils. Water

2322-455: Is ideally a good exposure of the formation that shows its entire thickness. If the formation is nowhere entirely exposed, or if it shows considerably lateral variation, additional reference sections may be defined. Long-established formations dating to before the modern codification of stratigraphy, or which lack tabular form (such as volcanic formations), may substitute a type locality for a type section as their stratotype. The geologist defining

2408-577: Is in equilibrium with kaolinite. Soil formation requires between 100 and 1,000 years, a brief interval in geologic time. As a result, some formations show numerous paleosol (fossil soil) beds. For example, the Willwood Formation of Wyoming contains over 1,000 paleosol layers in a 770 meters (2,530 ft) section representing 3.5 million years of geologic time. Paleosols have been identified in formations as old as Archean (over 2.5 billion years in age). They are difficult to recognize in

2494-420: Is likely the more important mechanism in nature. Geomorphologists have begun to reemphasize the importance of thermal stress weathering, particularly in cold climates. Pressure release or unloading is a form of physical weathering seen when deeply buried rock is exhumed . Intrusive igneous rocks, such as granite , are formed deep beneath the Earth's surface. They are under tremendous pressure because of

2580-508: Is now codified in such works as the North American Stratigraphic Code and its counterparts in other regions. Geologic maps showing where various formations are exposed at the surface are fundamental to such fields as structural geology , allowing geologists to infer the tectonic history of a region or predict likely locations for buried mineral resources. The boundaries of a formation are chosen to give it

2666-547: Is now extremely hard and erosion resistant, causing it to form most of the summits, crags and high cliffs that characterize the Cape Fold Mountain ranges (see illustration second from the top left), as well as the sheer rock faces of upper 600 m of Table Mountain. A small patch of Pakhuis tillite occurs on the top of Table Mountain at Maclear's beacon, but most of the Pakhuis Formation is found as

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2752-484: Is relatively poor in potassium, the basalt weathers directly to potassium-poor montmorillonite , then to kaolinite . Where leaching is continuous and intense, as in rain forests, the final weathering product is bauxite , the principal ore of aluminium. Where rainfall is intense but seasonal, as in monsoon climates, the final weathering product is iron- and titanium-rich laterite . Conversion of kaolinite to bauxite occurs only with intense leaching, as ordinary river water

2838-449: Is shown in the following table: This table is only a rough guide to order of weathering. Some minerals, such as illite , are unusually stable, while silica is unusually unstable given the strength of the silicon–oxygen bond . Carbon dioxide that dissolves in water to form carbonic acid is the most important source of protons, but organic acids are also important natural sources of acidity. Acid hydrolysis from dissolved carbon dioxide

2924-421: Is sometimes described as carbonation , and can result in weathering of the primary minerals to secondary carbonate minerals. For example, weathering of forsterite can produce magnesite instead of brucite via the reaction: Carbonic acid is consumed by silicate weathering, resulting in more alkaline solutions because of the bicarbonate . This is an important reaction in controlling the amount of CO 2 in

3010-427: Is the principal agent behind both kinds, though atmospheric oxygen and carbon dioxide and the activities of biological organisms are also important. Biological chemical weathering is also called biological weathering. The materials left after the rock breaks down combine with organic material to create soil . Many of Earth's landforms and landscapes are the result of weathering, erosion and redeposition. Weathering

3096-417: Is the process in which a mineral dissolves completely without producing any new solid substance. Rainwater easily dissolves soluble minerals, such as halite or gypsum , but can also dissolve highly resistant minerals such as quartz , given sufficient time. Water breaks the bonds between atoms in the crystal: [REDACTED] The overall reaction for dissolution of quartz is The dissolved quartz takes

3182-619: Is truncated by the overlying Dwyka sediments of glacial origin. The latter forms part of the Karoo Supergroup . Therefore, the Witteberg Group forms the uppermost layer of the Cape Supergroup. It tends to form the most inland outcrops of the Cape Supergroup, having been eroded away completely from all of its higher elevations above the present day Cape Fold Mountain ranges. The termite species Amitermes hastatus

3268-431: Is usually much less important than chemical weathering, but can be significant in subarctic or alpine environments. Furthermore, chemical and physical weathering often go hand in hand. For example, cracks extended by physical weathering will increase the surface area exposed to chemical action, thus amplifying the rate of disintegration. Frost weathering is the most important form of physical weathering. Next in importance

3354-426: Is wedging by plant roots, which sometimes enter cracks in rocks and pry them apart. The burrowing of worms or other animals may also help disintegrate rock, as can "plucking" by lichens. Frost weathering is the collective name for those forms of physical weathering that are caused by the formation of ice within rock outcrops. It was long believed that the most important of these is frost wedging , which results from

3440-626: The Cederberg mountains has been built into the wall. About 400 million years ago (in the early Devonian Period ) there was further subsidence of the rift valley floor. This brought about the deposition of deeper-water, fine grained sediments of the Bokkeveld Group . This is in marked contrast to the predominantly sandy sediments of the Table Mountain Group. The Bokkeveld Group consists predominantly mudstones. After

3526-720: The Graafwater Formation , reaches a maximum thickness of 400 m, but on the Cape Peninsula it is only 60–70 m thick. No fossils have been found in the Graafwater rocks, but shallow-water animal tracks have been found. A particularly good example of these tracks can be viewed in the foyer of the Geology Department of the University of Stellenbosch, where a slab of Graafwater rock from

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3612-540: The Hottentots-Holland Mountains to the east, on the opposite side of the isthmus connecting the Peninsula to the mainland, has been eroded away. The Malmesbury shale and granite basement on which this anticline mountain rested also formed an anticline; but being composed of much softer rocks, readily weathered into a 50 km wide sandy plain, called the " Cape Flats " (see diagram below, on

3698-658: The Cape Peninsula or its isthmus (the Cape Flats). Here the Stellenbosch , Franschhoek , Paarl , Durbanville , Tulbagh and Constantia vineyards have been planted on the weathered Cape Granite and Malmesbury shale soils, which form the basement rocks on which the Cape Supergroup rocks in this region rest. The bulk of the fossils found in the Cape Supergroup occur in the Bokkeveld mudstones. They include

3784-537: The Cape Supergroup had been folded into the Cape Fold Mountains, these soft mudstones readily washed away from the mountain tops, and only remain in the valleys. Here they form the fertile soils on which the vines and fruit orchards of the Western Cape flourish with the help of irrigation from the rivers that have their sources in the surrounding mountains. The Bokkeveld Group does not extend on to

3870-408: The Earth's surface, begins weathering with the destruction of hornblende . Biotite then weathers to vermiculite , and finally oligoclase and microcline are destroyed. All are converted into a mixture of clay minerals and iron oxides. The resulting soil is depleted in calcium, sodium, and ferrous iron compared with the bedrock, and magnesium is reduced by 40% and silicon by 15%. At the same time,

3956-411: The Earth's surface. Chemical weathering takes place when water, oxygen, carbon dioxide, and other chemical substances react with rock to change its composition. These reactions convert some of the original primary minerals in the rock to secondary minerals, remove other substances as solutes, and leave the most stable minerals as a chemically unchanged resistate . In effect, chemical weathering changes

4042-409: The affected rocks a reddish-brown coloration on the surface which crumbles easily and weakens the rock. Many other metallic ores and minerals oxidize and hydrate to produce colored deposits, as does sulfur during the weathering of sulfide minerals such as chalcopyrites or CuFeS 2 oxidizing to copper hydroxide and iron oxides . Mineral hydration is a form of chemical weathering that involves

4128-466: The atmosphere and can affect climate. Aluminosilicates containing highly soluble cations, such as sodium or potassium ions, will release the cations as dissolved bicarbonates during acid hydrolysis: Within the weathering environment, chemical oxidation of a variety of metals occurs. The most commonly observed is the oxidation of Fe ( iron ) by oxygen and water to form Fe oxides and hydroxides such as goethite , limonite , and hematite . This gives

4214-819: The carbon dioxide level to 30% of all soil gases, aided by adsorption of CO 2 on clay minerals and the very slow diffusion rate of CO 2 out of the soil. The CO 2 and organic acids help break down aluminium - and iron -containing compounds in the soils beneath them. Roots have a negative electrical charge balanced by protons in the soil next to the roots, and these can be exchanged for essential nutrient cations such as potassium. Decaying remains of dead plants in soil may form organic acids which, when dissolved in water, cause chemical weathering. Chelating compounds, mostly low molecular weight organic acids, are capable of removing metal ions from bare rock surfaces, with aluminium and silicon being particularly susceptible. The ability to break down bare rock allows lichens to be among

4300-536: The collision with the eastward movement of Patagonia into southern Africa). Continued subduction of the paleo-Pacific Plate beneath the Falkland Plateau and the resulting further compression of the latter into Southern Africa, raised a mountain range of immense proportions to the south of the former rift valley. The folded Cape Supergroup formed the northern foothills of this towering mountain range. Sediments, eroded from this immense Falkland Mountain range to

4386-530: The early 20th century that seemed to show that its effects were unimportant. These experiments have since been criticized as unrealistic, since the rock samples were small, were polished (which reduces nucleation of fractures), and were not buttressed. These small samples were thus able to expand freely in all directions when heated in experimental ovens, which failed to produce the kinds of stress likely in natural settings. The experiments were also more sensitive to thermal shock than thermal fatigue, but thermal fatigue

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4472-886: The edge of the plateau overlooking the Cape Town City Bowl and Table Bay. The Upper Table Mountain Sandstone Formation, above the Pakhuis and Cederberg Formations, consists of much softer sandstone than the Lower Table Mountain Sandstone Formation, and is often referred to as the Nardouw Formation . In the Cederberg this formation has been eroded by the wind into a wide variety of "sculptures", caves, and other fascinating structures for which these mountains have become well-known. The initial sediments into

4558-550: The essential geologic time markers, based on their relative ages and the law of superposition . The divisions of the geological time scale were described and put in chronological order by the geologists and stratigraphers of the 18th and 19th centuries. Geologic formations can be usefully defined for sedimentary rock layers, low-grade metamorphic rocks , and volcanic rocks . Intrusive igneous rocks and highly metamorphosed rocks are generally not considered to be formations, but are described instead as lithodemes . "Formation"

4644-427: The expansion of pore water when it freezes. A growing body of theoretical and experimental work suggests that ice segregation, whereby supercooled water migrates to lenses of ice forming within the rock, is the more important mechanism. When water freezes, its volume increases by 9.2%. This expansion can theoretically generate pressures greater than 200 megapascals (29,000 psi), though a more realistic upper limit

4730-404: The expense of silica, titanium, aluminum, ferrous iron, and calcium. Buildings made of any stone, brick or concrete are susceptible to the same weathering agents as any exposed rock surface. Also statues , monuments and ornamental stonework can be badly damaged by natural weathering processes. This is accelerated in areas severely affected by acid rain . Accelerated building weathering may be

4816-488: The first colonizers of dry land. The accumulation of chelating compounds can easily affect surrounding rocks and soils, and may lead to podsolisation of soils. The symbiotic mycorrhizal fungi associated with tree root systems can release inorganic nutrients from minerals such as apatite or biotite and transfer these nutrients to the trees, thus contributing to tree nutrition. It was also recently evidenced that bacterial communities can impact mineral stability leading to

4902-461: The floor of this rift valley. Closure of the rift valley, starting 330 million years ago, resulted from the drift of the Falkland Plateau back towards Africa, during the Carboniferous and Early Permian periods. This caused the rucking of the Cape Supergroup into a series of parallel folds, running mainly east-west, but with a short section running north-south in the west (resulting from

4988-463: The form of silicic acid . A particularly important form of dissolution is carbonate dissolution, in which atmospheric carbon dioxide enhances solution weathering. Carbonate dissolution affects rocks containing calcium carbonate , such as limestone and chalk . It takes place when rainwater combines with carbon dioxide to form carbonic acid , a weak acid , which dissolves calcium carbonate (limestone) and forms soluble calcium bicarbonate . Despite

5074-522: The formation is expected to describe the stratotype in sufficient detail that other geologists can unequivocally recognize the formation. Although formations should not be defined by any criteria other than primary lithology, it is often useful to define biostratigraphic units on paleontological criteria, chronostratigraphic units on the age of the rocks, and chemostratigraphic units on geochemical criteria, and these are included in stratigraphic codes. The concept of formally defined layers or strata

5160-669: The geologic record. Indications that a sedimentary bed is a paleosol include a gradational lower boundary and sharp upper boundary, the presence of much clay, poor sorting with few sedimentary structures, rip-up clasts in overlying beds, and desiccation cracks containing material from higher beds. The degree of weathering of soil can be expressed as the chemical index of alteration , defined as 100 Al 2 O 3 /(Al 2 O 3 + CaO + Na 2 O + K 2 O) . This varies from 47 for unweathered upper crust rock to 100 for fully weathered material. Wood can be physically and chemically weathered by hydrolysis and other processes relevant to minerals and

5246-400: The greatest practical lithological consistency. Formations should not be defined by any criteria other than lithology. The lithology of a formation includes characteristics such as chemical and mineralogical composition, texture, color, primary depositional structures , fossils regarded as rock-forming particles, or other organic materials such as coal or kerogen . The taxonomy of fossils

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5332-779: The highest and most conspicuous peaks in the Western Cape, as well as the steepest cliffs of the Cape Fold Mountains , despite being the oldest, and, therefore, lowermost of the Cape Supergroup sequence. The folding of the sequence into the parallel mountain ranges of the Western Cape started about 330 million years ago, affecting the Cape Supergroup from about Clanwilliam (approximately 200 km north of Cape Town), to about Port Elizabeth (approximately 650 km east of Cape Town). The Cape Supergroup sediments beyond these points are not folded into mountain ranges, but do, in places, form steep cliffs or gorges, where

5418-439: The ice will simply expand into the air spaces in the unsaturated rock without generating much pressure. These conditions are unusual enough that frost wedging is unlikely to be the dominant process of frost weathering. Frost wedging is most effective where there are daily cycles of melting and freezing of water-saturated rock, so it is unlikely to be significant in the tropics, in polar regions or in arid climates. Ice segregation

5504-606: The mid-Jurassic Period, and started drifting to the south-west soon after Gondwana began to break up 150 million years ago, leaving the Cape Fold Belt to edge the southern portion of the newly formed African continent. Even though the mountains are very old by Andean and Alpine standards, they remain steep and rugged due to the Table Mountain Sandstone's quartzitic sandstone geology , making them very resistant to weathering . The degree to which

5590-546: The most effective biological agents of chemical weathering. For example, an experimental study on hornblende granite in New Jersey, US, demonstrated a 3x – 4x increase in weathering rate under lichen covered surfaces compared to recently exposed bare rock surfaces. The most common forms of biological weathering result from the release of chelating compounds (such as certain organic acids and siderophores ) and of carbon dioxide and organic acids by plants. Roots can build up

5676-473: The original Cape Fold mountains (formed during the Carboniferous and early Permian Periods) have been eroded is attested to by the fact that the 1 km high Table Mountain on the Cape Peninsula is a syncline mountain , meaning that it once formed part of the bottom of a valley when the Cape Supergroup was initially folded. The anticline , or highest elevation of the fold between Table Mountain and

5762-486: The original sandy deposits into very hard quartzitic sandstones, which in their folded configuration form the peaks, steep cliffs and rugged crags of the Cape Fold Mountains. During the deposition phase a short period of glaciation left a layer of tillite, called the Pakhuis Formation , which today divides the Table Mountain Sandstone Formation into a lower and upper layer. It is particularly the lower layer which

5848-551: The original set of minerals in the rock into a new set of minerals that is in closer equilibrium with surface conditions. True equilibrium is rarely reached, because weathering is a slow process, and leaching carries away solutes produced by weathering reactions before they can accumulate to equilibrium levels. This is particularly true in tropical environments. Water is the principal agent of chemical weathering, converting many primary minerals to clay minerals or hydrated oxides via reactions collectively described as hydrolysis . Oxygen

5934-443: The overlying rock material. When erosion removes the overlying rock material, these intrusive rocks are exposed and the pressure on them is released. The outer parts of the rocks then tend to expand. The expansion sets up stresses which cause fractures parallel to the rock surface to form. Over time, sheets of rock break away from the exposed rocks along the fractures, a process known as exfoliation . Exfoliation due to pressure release

6020-402: The production of weathering agents, such as protons, organic acids and chelating molecules. Weathering of basaltic oceanic crust differs in important respects from weathering in the atmosphere. Weathering is relatively slow, with basalt becoming less dense, at a rate of about 15% per 100 million years. The basalt becomes hydrated, and is enriched in total and ferric iron, magnesium, and sodium at

6106-416: The release of inorganic nutrients. A large range of bacterial strains or communities from diverse genera have been reported to be able to colonize mineral surfaces or to weather minerals, and for some of them a plant growth promoting effect has been demonstrated. The demonstrated or hypothesised mechanisms used by bacteria to weather minerals include several oxidoreduction and dissolution reactions as well as

6192-594: The right). Table Mountain Sandstone Formation is, barring the Graafwater Formation, the oldest component of the Cape Supergroup . It was laid down as sandy deposits, with a maximum thickness of 2000 m, in a flooded rift valley. It contains no fossils. Its subsequent burial under the other Formations in the Cape Supergroup, and thereafter under the sediments brought down from the Falkland Mountain range, compressed and partially metamorphosed

6278-448: The rigid attachment of water molecules or H+ and OH- ions to the atoms and molecules of a mineral. No significant dissolution takes place. For example, iron oxides are converted to iron hydroxides and the hydration of anhydrite forms gypsum . Bulk hydration of minerals is secondary in importance to dissolution, hydrolysis, and oxidation, but hydration of the crystal surface is the crucial first step in hydrolysis. A fresh surface of

6364-455: The rock surface, which gradually pry the rock apart. Thermal stress weathering results from the expansion and contraction of rock due to temperature changes. Thermal stress weathering is most effective when the heated portion of the rock is buttressed by surrounding rock, so that it is free to expand in only one direction. Thermal stress weathering comprises two main types, thermal shock and thermal fatigue . Thermal shock takes place when

6450-413: The rock. This results in growth of the ice grain that puts considerable pressure on the surrounding rock, up to ten times greater than is likely with frost wedging. This mechanism is most effective in rock whose temperature averages just below the freezing point, −4 to −15 °C (25 to 5 °F). Ice segregation results in growth of ice needles and ice lenses within fractures in the rock and parallel to

6536-408: The rocks and evaporate, leaving salt crystals behind. As with ice segregation, the surfaces of the salt grains draw in additional dissolved salts through capillary action, causing the growth of salt lenses that exert high pressure on the surrounding rock. Sodium and magnesium salts are the most effective at producing salt weathering. Salt weathering can also take place when pyrite in sedimentary rock

6622-425: The rocks on which it falls. Hydrolysis (also called incongruent dissolution ) is a form of chemical weathering in which only part of a mineral is taken into solution. The rest of the mineral is transformed into a new solid material, such as a clay mineral . For example, forsterite (magnesium olivine ) is hydrolyzed into solid brucite and dissolved silicic acid: Most hydrolysis during weathering of minerals

6708-536: The soil is enriched in aluminium and potassium by at least 50%; by titanium, whose abundance triples, and ferric iron, whose abundance increases by an order of magnitude compared with the bedrock. Basaltic rock is more easily weathered than granitic rock due to its formation at higher temperatures and drier conditions. The fine grain size and presence of volcanic glass also hasten weathering. In tropical settings, it rapidly weathers to clay minerals, aluminium hydroxides, and titanium-enriched iron oxides. Because most basalt

6794-426: The south, buried the folded Cape Supergroup rocks, and the plains beyond (to the north) to ultimately form the Karoo Supergroup , a sequence of sediments that eventually covered most of southern Africa and other parts of Gondwana. The Cape Supergroup re-emerged as mountains when uplift of the subcontinent, about 180 million years ago, and again 20 million years ago, started an episode of continuous erosion that

6880-523: The southern Karoo . These rocks were laid down 370 - 330 million years ago in the silted up, and therefore shallow marine conditions of what remained of the Agulhas Sea. The group contains fewer fossils than the Bokkeveld Group, but the assemblage that is preserved includes primitive fish, an extinct species of shark, brachiopods, bivalves , and a metre long sea scorpion . There are also plant fossils and numerous animal tracks. The Witteberg Group

6966-402: The still shallow rift valley, that was to turn into the Agulhas Sea, were alternating layers of maroon coloured mudstones and buff coloured sandstones, each mostly between 10 and 30 cm thick. The mudstone units commonly display ripple marks from the ebb and flow of tidal currents, as well as polygonal sand-filled mud cracks that indicate occasional exposure to desiccation. This layer, known as

7052-419: The stresses are so great that the rock cracks immediately, but this is uncommon. More typical is thermal fatigue, in which the stresses are not great enough to cause immediate rock failure, but repeated cycles of stress and release gradually weaken the rock. Thermal stress weathering is an important mechanism in deserts , where there is a large diurnal temperature range, hot in the day and cold at night. As

7138-454: The surface of the crystal, and that the weathering layer is only a few atoms thick. Diffusion within the mineral grain does not appear to be significant. Mineral weathering can also be initiated or accelerated by soil microorganisms. Soil organisms make up about 10 mg/cm of typical soils, and laboratory experiments have demonstrated that albite and muscovite weather twice as fast in live versus sterile soil. Lichens on rocks are among

7224-553: The surrounding sediments have been eroded away (see, for instance, Oribi Gorge in KwaZulu-Natal ). The Cape Supergroup rocks were laid down as sediments in a rift valley that developed in southern Gondwana , just south of Southern Africa, during the Cambrian - Ordovician Periods (starting about 510 million years ago, and ending about 330-350 million years ago). An 8 km thick layer of sediment accumulated on

7310-469: The title, continue to be used in the rest of this article. The name is derived from the famous landmark in Cape Town , Table Mountain . Table Mountain Sandstone is made up predominantly of quartzitic sandstone laid down between 510 ( Cambrian Period ) and 400 ( Silurian Period ) million years ago. It is the hardest, and most erosion resistant layer of the Cape Supergroup. It therefore forms most of

7396-451: Was to remove many kilometres of surface deposits from Southern Africa. Although the tops of the original Cape Fold Mountains were eroded away, the hard Table Mountain Sandstone component eroded much slower, forming the backbone of the Cape Fold Mountains, with the younger, but very much softer Bokkeveld shales remaining only in the valleys (see diagram on the left). The Falkland Mountain range had probably eroded into relative insignificance by

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