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71-472: In this area, lava flows have created a series of tubes connecting a flat clifftop of lava rock with the ocean below. Waves breaking against the lower end of the lava tubes send water at high pressure up through the tubes, creating fountains that spray every few seconds. As most of the land in Samoa is under customary ownership , the village charges a small admission for entry to view the blowholes. The area

142-419: A molality , the proportionality constant is known as the cryoscopic constant ( K f ) and is characteristic for each solvent. If w represents the mass fraction of the solute in solution, and assuming no dissociation of the solute, the molar mass is given by The boiling point of a solution of an involatile solute is higher than that of the pure solvent , and the boiling-point elevation ( Δ T )

213-409: A compound in g/mol thus is equal to the mass of this number of molecules of the compound in grams. The molar mass of atoms of an element is given by the relative atomic mass of the element multiplied by the molar mass constant , M u  ≈  1.000 000 × 10  kg/mol = 1 g/mol. For normal samples from earth with typical isotope composition, the atomic weight can be approximated by

284-419: A continued supply of lava and its pressure on a solidified crust. Most basaltic lavas are of ʻaʻā or pāhoehoe types, rather than block lavas. Underwater, they can form pillow lavas , which are rather similar to entrail-type pahoehoe lavas on land. Ultramafic lavas, such as komatiite and highly magnesian magmas that form boninite , take the composition and temperatures of eruptions to the extreme. All have

355-455: A darker groundmass , including amphibole or pyroxene phenocrysts. Mafic or basaltic lavas are typified by relatively high magnesium oxide and iron oxide content (whose molecular formulas provide the consonants in mafic) and have a silica content limited to a range of 52% to 45%. They generally erupt at temperatures of 1,100 to 1,200 °C (2,010 to 2,190 °F) and at relatively low viscosities, around 10 to 10 cP (10 to 100 Pa⋅s). This

426-420: A dome forms on an inclined surface it can flow in short thick flows called coulées (dome flows). These flows often travel only a few kilometres from the vent. Lava tubes are formed when a flow of relatively fluid lava cools on the upper surface sufficiently to form a crust. Beneath this crust, which being made of rock is an excellent insulator, the lava can continue to flow as a liquid. When this flow occurs over

497-465: A massive dense core, which is the most active part of the flow. As pasty lava in the core travels downslope, the clinkers are carried along at the surface. At the leading edge of an ʻaʻā flow, however, these cooled fragments tumble down the steep front and are buried by the advancing flow. This produces a layer of lava fragments both at the bottom and top of an ʻaʻā flow. Accretionary lava balls as large as 3 metres (10 feet) are common on ʻaʻā flows. ʻAʻā

568-420: A precision of a few parts per million . This is accurate enough to directly determine the chemical formula of a molecule. The term formula weight has a specific meaning when used in the context of DNA synthesis: whereas an individual phosphoramidite nucleobase to be added to a DNA polymer has protecting groups and has its molecular weight quoted including these groups, the amount of molecular weight that

639-584: A prolonged period of time the lava conduit can form a tunnel-like aperture or lava tube , which can conduct molten rock many kilometres from the vent without cooling appreciably. Often these lava tubes drain out once the supply of fresh lava has stopped, leaving a considerable length of open tunnel within the lava flow. Lava tubes are known from the modern day eruptions of Kīlauea, and significant, extensive and open lava tubes of Tertiary age are known from North Queensland , Australia , some extending for 15 kilometres (9 miles). Molar mass In chemistry ,

710-414: A sample which has been distilled will be enriched in the lighter isotopes of all the elements present. This complicates the calculation of the standard uncertainty in the molar mass. A useful convention for normal laboratory work is to quote molar masses to two decimal places for all calculations. This is more accurate than is usually required, but avoids rounding errors during calculations. When

781-526: A separate dimension of measurement . Until 2019, the mole was defined as the amount of substance that has as many constituent particles as there are atoms in 12 grams of carbon-12 . During that period, the molar mass of carbon-12 was thus exactly 12 g/mol, by definition. Since 2019, a mole of any substance has been redefined in the SI as the amount of that substance containing an exactly defined number of particles, 6.022 140 76 × 10 . The molar mass of

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852-960: A silica content greater than 63%. They include rhyolite and dacite lavas. With such a high silica content, these lavas are extremely viscous, ranging from 10 cP (10 Pa⋅s) for hot rhyolite lava at 1,200 °C (2,190 °F) to 10 cP (10 Pa⋅s) for cool rhyolite lava at 800 °C (1,470 °F). For comparison, water has a viscosity of about 1 cP (0.001 Pa⋅s). Because of this very high viscosity, felsic lavas usually erupt explosively to produce pyroclastic (fragmental) deposits. However, rhyolite lavas occasionally erupt effusively to form lava spines , lava domes or "coulees" (which are thick, short lava flows). The lavas typically fragment as they extrude, producing block lava flows. These often contain obsidian . Felsic magmas can erupt at temperatures as low as 800 °C (1,470 °F). Unusually hot (>950 °C; >1,740 °F) rhyolite lavas, however, may flow for distances of many tens of kilometres, such as in

923-450: A silica content under 45%. Komatiites contain over 18% magnesium oxide and are thought to have erupted at temperatures of 1,600 °C (2,910 °F). At this temperature there is practically no polymerization of the mineral compounds, creating a highly mobile liquid. Viscosities of komatiite magmas are thought to have been as low as 100 to 1000 cP (0.1 to 1 Pa⋅s), similar to that of light motor oil. Most ultramafic lavas are no younger than

994-441: A similar manner to ʻaʻā flows but their more viscous nature causes the surface to be covered in smooth-sided angular fragments (blocks) of solidified lava instead of clinkers. As with ʻaʻā flows, the molten interior of the flow, which is kept insulated by the solidified blocky surface, advances over the rubble that falls off the flow front. They also move much more slowly downhill and are thicker in depth than ʻaʻā flows. Pillow lava

1065-530: A solid crust that insulates the remaining liquid lava, helping to keep it hot and inviscid enough to continue flowing. The word lava comes from Italian and is probably derived from the Latin word labes , which means a fall or slide. An early use of the word in connection with extrusion of magma from below the surface is found in a short account of the 1737 eruption of Vesuvius , written by Francesco Serao , who described "a flow of fiery lava" as an analogy to

1136-575: A temperature of 1,100 to 1,200 °C (2,010 to 2,190 °F). On the Earth, most lava flows are less than 10 km (6.2 mi) long, but some pāhoehoe flows are more than 50 km (31 mi) long. Some flood basalt flows in the geologic record extend for hundreds of kilometres. The rounded texture makes pāhoehoe a poor radar reflector, and is difficult to see from an orbiting satellite (dark on Magellan picture). Block lava flows are typical of andesitic lavas from stratovolcanoes. They behave in

1207-501: A volcano extrudes silicic lava, it can form an inflation dome or endogenous dome , gradually building up a large, pillow-like structure which cracks, fissures, and may release cooled chunks of rock and rubble. The top and side margins of an inflating lava dome tend to be covered in fragments of rock, breccia and ash. Examples of lava dome eruptions include the Novarupta dome, and successive lava domes of Mount St Helens . When

1278-468: Is a stub . You can help Misplaced Pages by expanding it . Lava Lava is molten or partially molten rock ( magma ) that has been expelled from the interior of a terrestrial planet (such as Earth ) or a moon onto its surface. Lava may be erupted at a volcano or through a fracture in the crust , on land or underwater, usually at temperatures from 800 to 1,200 °C (1,470 to 2,190 °F). The volcanic rock resulting from subsequent cooling

1349-402: Is a large subsidence crater, can form in a stratovolcano, if the magma chamber is partially or wholly emptied by large explosive eruptions; the summit cone no longer supports itself and thus collapses in on itself afterwards. Such features may include volcanic crater lakes and lava domes after the event. However, calderas can also form by non-explosive means such as gradual magma subsidence. This

1420-456: Is also often called lava . A lava flow is an outpouring of lava during an effusive eruption . (An explosive eruption , by contrast, produces a mixture of volcanic ash and other fragments called tephra , not lava flows.) The viscosity of most lava is about that of ketchup , roughly 10,000 to 100,000 times that of water. Even so, lava can flow great distances before cooling causes it to solidify, because lava exposed to air quickly develops

1491-415: Is basaltic lava that has a smooth, billowy, undulating, or ropy surface. These surface features are due to the movement of very fluid lava under a congealing surface crust. The Hawaiian word was introduced as a technical term in geology by Clarence Dutton . A pāhoehoe flow typically advances as a series of small lobes and toes that continually break out from a cooled crust. It also forms lava tubes where

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1562-719: Is concentrated in a thin layer in the toothpaste next to the tube and only there does the toothpaste behave as a fluid. Thixotropic behavior also hinders crystals from settling out of the lava. Once the crystal content reaches about 60%, the lava ceases to behave like a fluid and begins to behave like a solid. Such a mixture of crystals with melted rock is sometimes described as crystal mush . Lava flow speeds vary based primarily on viscosity and slope. In general, lava flows slowly, with typical speeds for Hawaiian basaltic flows of 0.40 km/h (0.25 mph) and maximum speeds of 10 to 48 km/h (6 to 30 mph) on steep slopes. An exceptional speed of 32 to 97 km/h (20 to 60 mph)

1633-451: Is distinct but related to the molar mass, which is a measure of the average molecular mass of all the molecules in a sample and is usually the more appropriate measure when dealing with macroscopic (weigh-able) quantities of a substance. Molecular masses are calculated from the atomic masses of each nuclide , while molar masses are calculated from the standard atomic weights of each element . The standard atomic weight takes into account

1704-405: Is given by Combining these two equations gives an expression for the molar mass in terms of the vapour density for conditions of known pressure and temperature : The freezing point of a solution is lower than that of the pure solvent , and the freezing-point depression ( Δ T ) is directly proportional to the amount concentration for dilute solutions. When the composition is expressed as

1775-447: Is kg/mol. However, for historical reasons, molar masses are almost always expressed in g/mol. The mole was defined in such a way that the molar mass of a compound, in g/mol, is numerically equal to the average mass of one molecule or formula unit, in daltons. It was exactly equal before the redefinition of the mole in 2019 , and is now only approximately equal, but the difference is negligible for all practical purposes. Thus, for example,

1846-436: Is limited by the knowledge of the isotopic distribution of the element. If a more accurate value of the molar mass is required, it is necessary to determine the isotopic distribution of the sample in question, which may be different from the standard distribution used to calculate the standard atomic mass. The isotopic distributions of the different elements in a sample are not necessarily independent of one another: for example,

1917-546: Is mostly determined by composition but also depends on temperature and shear rate. Lava viscosity determines the kind of volcanic activity that takes place when the lava is erupted. The greater the viscosity, the greater the tendency for eruptions to be explosive rather than effusive. As a result, most lava flows on Earth, Mars, and Venus are composed of basalt lava. On Earth, 90% of lava flows are mafic or ultramafic, with intermediate lava making up 8% of flows and felsic lava making up just 2% of flows. Viscosity also determines

1988-444: Is one of three basic types of flow lava. ʻAʻā is basaltic lava characterized by a rough or rubbly surface composed of broken lava blocks called clinker. The word is Hawaiian meaning "stony rough lava", but also to "burn" or "blaze"; it was introduced as a technical term in geology by Clarence Dutton . The loose, broken, and sharp, spiny surface of an ʻaʻā flow makes hiking difficult and slow. The clinkery surface actually covers

2059-461: Is particularly important in polymer science , where there is usually a molar mass distribution of non-uniform polymers so that different polymer molecules contain different numbers of monomer units. The average molar mass of mixtures M ¯ {\displaystyle {\overline {M}}} can be calculated from the mole fractions x i of the components and their molar masses M i : It can also be calculated from

2130-474: Is similar to the viscosity of ketchup , although it is still many orders of magnitude higher than that of water. Mafic lavas tend to produce low-profile shield volcanoes or flood basalts , because the less viscous lava can flow for long distances from the vent. The thickness of a solidified basaltic lava flow, particularly on a low slope, may be much greater than the thickness of the moving molten lava flow at any one time, because basaltic lavas may "inflate" by

2201-454: Is the lava structure typically formed when lava emerges from an underwater volcanic vent or subglacial volcano or a lava flow enters the ocean. The viscous lava gains a solid crust on contact with the water, and this crust cracks and oozes additional large blobs or "pillows" as more lava emerges from the advancing flow. Since water covers the majority of Earth 's surface and most volcanoes are situated near or under bodies of water, pillow lava

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2272-538: Is the mass of one molecule (of any single isotopic composition), and to the atomic mass , which is the mass of one atom (of any single isotope). The dalton , symbol Da, is also sometimes used as a unit of molar mass, especially in biochemistry , with the definition 1 Da = 1 g/mol, despite the fact that it is strictly a unit of mass (1 Da = 1 u = 1.660 539 068 92 (52) × 10  kg , as of 2022 CODATA recommended values). Obsolete terms for molar mass include gram atomic mass for

2343-397: Is the molar mass of the atoms multiplied by the number of atoms in each molecule: The molar mass of a compound is given by the sum of the relative atomic mass A r of the atoms which form the compound multiplied by the molar mass constant M u ≈ 1  g/mol {\displaystyle M_{u}\approx 1{\text{ g/mol}}} : Here, M r

2414-1312: Is the relative molar mass, also called formula weight. For normal samples from earth with typical isotope composition, the standard atomic weight or the conventional atomic weight can be used as an approximation of the relative atomic mass of the sample. Examples are: M ( NaCl ) = [ 22.98976928 ( 2 ) + 35.453 ( 2 ) ] × 1  g/mol = 58.443 ( 2 )  g/mol M ( C 12 H 22 O 11 ) = [ 12 × 12.0107 ( 8 ) + 22 × 1.00794 ( 7 ) + 11 × 15.9994 ( 3 ) ] × 1  g/mol = 342.297 ( 14 )  g/mol {\displaystyle {\begin{array}{ll}M({\ce {NaCl}})&={\bigl [}22.98976928(2)+35.453(2){\bigr ]}\times 1{\text{ g/mol}}\\&=58.443(2){\text{ g/mol}}\\[4pt]M({\ce {C12H22O11}})&={\bigl [}12\times 12.0107(8)+22\times 1.00794(7)+11\times 15.9994(3){\bigr ]}\times 1{\text{ g/mol}}\\&=342.297(14){\text{ g/mol}}\end{array}}} An average molar mass may be defined for mixtures of compounds. This

2485-422: Is typical of many shield volcanoes. Cinder cones and spatter cones are small-scale features formed by lava accumulation around a small vent on a volcanic edifice. Cinder cones are formed from tephra or ash and tuff which is thrown from an explosive vent. Spatter cones are formed by accumulation of molten volcanic slag and cinders ejected in a more liquid form. Another Hawaiian English term derived from

2556-457: Is ultimately added by this nucleobase to a DNA polymer is referred to as the nucleobase's formula weight (i.e., the molecular weight of this nucleobase within the DNA polymer, minus protecting groups). The precision to which a molar mass is known depends on the precision of the atomic masses from which it was calculated (and very slightly on the value of the molar mass constant , which depends on

2627-451: Is unfenced and surrounded by wet, slippery rocks which can be dangerous. Falling into one of the blowholes would be almost certainly fatal. A track along the coast can be followed west to the ancient village of Fagaloa . 13°48′08″S 172°31′11″W  /  13.8022°S 172.5197°W  / -13.8022; -172.5197 This article about a geographical location in Samoa

2698-516: Is usually of higher viscosity than pāhoehoe. Pāhoehoe can turn into ʻaʻā if it becomes turbulent from meeting impediments or steep slopes. The sharp, angled texture makes ʻaʻā a strong radar reflector, and can easily be seen from an orbiting satellite (bright on Magellan pictures). ʻAʻā lavas typically erupt at temperatures of 1,050 to 1,150 °C (1,920 to 2,100 °F) or greater. Pāhoehoe (also spelled pahoehoe , from Hawaiian [paːˈhoweˈhowe] meaning "smooth, unbroken lava")

2769-646: Is very common. Because it is formed from viscous molten rock, lava flows and eruptions create distinctive formations, landforms and topographical features from the macroscopic to the microscopic. Volcanoes are the primary landforms built by repeated eruptions of lava and ash over time. They range in shape from shield volcanoes with broad, shallow slopes formed from predominantly effusive eruptions of relatively fluid basaltic lava flows, to steeply-sided stratovolcanoes (also known as composite volcanoes) made of alternating layers of ash and more viscous lava flows typical of intermediate and felsic lavas. A caldera , which

2840-494: The Hawaiian language , a kīpuka denotes an elevated area such as a hill, ridge or old lava dome inside or downslope from an area of active volcanism. New lava flows will cover the surrounding land, isolating the kīpuka so that it appears as a (usually) forested island in a barren lava flow. Lava domes are formed by the extrusion of viscous felsic magma. They can form prominent rounded protuberances, such as at Valles Caldera . As

2911-889: The Proterozoic , with a few ultramafic magmas known from the Phanerozoic in Central America that are attributed to a hot mantle plume . No modern komatiite lavas are known, as the Earth's mantle has cooled too much to produce highly magnesian magmas. Some silicate lavas have an elevated content of alkali metal oxides (sodium and potassium), particularly in regions of continental rifting , areas overlying deeply subducted plates , or at intraplate hotspots . Their silica content can range from ultramafic ( nephelinites , basanites and tephrites ) to felsic ( trachytes ). They are more likely to be generated at greater depths in

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2982-520: The Snake River Plain of the northwestern United States. Intermediate or andesitic lavas contain 52% to 63% silica, and are lower in aluminium and usually somewhat richer in magnesium and iron than felsic lavas. Intermediate lavas form andesite domes and block lavas and may occur on steep composite volcanoes , such as in the Andes . They are also commonly hotter than felsic lavas, in

3053-487: The isotopic distribution of the element in a given sample (usually assumed to be "normal"). For example, water has a molar mass of 18.0153(3) g/mol , but individual water molecules have molecular masses which range between 18.010 564 6863 (15) Da ( H 2 O ) and 22.027 7364 (9) Da ( H 2 O ). The distinction between molar mass and molecular mass is important because relative molecular masses can be measured directly by mass spectrometry , often to

3124-411: The mass fractions w i of the components: As an example, the average molar mass of dry air is 28.96 g/mol. Molar mass is closely related to the relative molar mass ( M r ) of a compound and to the standard atomic weights of its constituent elements. However, it should be distinguished from the molecular mass (which is confusingly also sometimes known as molecular weight), which

3195-440: The molar mass ( M ) (sometimes called molecular weight or formula weight , but see related quantities for usage) of a chemical compound is defined as the ratio between the mass and the amount of substance (measured in moles ) of any sample of the compound. The molar mass is a bulk, not molecular, property of a substance. The molar mass is an average of many instances of the compound, which often vary in mass due to

3266-418: The most abundant elements of the Earth's crust , with smaller quantities of aluminium , calcium , magnesium , iron , sodium , and potassium and minor amounts of many other elements. Petrologists routinely express the composition of a silicate lava in terms of the weight or molar mass fraction of the oxides of the major elements (other than oxygen) present in the lava. The silica component dominates

3337-422: The relative molar mass ( M r ). This is a dimensionless quantity (i.e., a pure number, without units) equal to the molar mass divided by the molar mass constant . The molecular mass ( m ) is the mass of a given molecule: it is usually measured in daltons (Da or u). Different molecules of the same compound may have different molecular masses because they contain different isotopes of an element. This

3408-989: The aspect (thickness relative to lateral extent) of flows, the speed with which flows move, and the surface character of the flows. When highly viscous lavas erupt effusively rather than in their more common explosive form, they almost always erupt as high-aspect flows or domes. These flows take the form of block lava rather than ʻaʻā or pāhoehoe. Obsidian flows are common. Intermediate lavas tend to form steep stratovolcanoes, with alternating beds of lava from effusive eruptions and tephra from explosive eruptions. Mafic lavas form relatively thin flows that can move great distances, forming shield volcanoes with gentle slopes. In addition to melted rock, most lavas contain solid crystals of various minerals, fragments of exotic rocks known as xenoliths , and fragments of previously solidified lava. The crystal content of most lavas gives them thixotropic and shear thinning properties. In other words, most lavas do not behave like Newtonian fluids, in which

3479-413: The average mass of a molecule of water is about 18.0153 daltons, and the molar mass of water is about 18.0153 g/mol. For chemical elements without isolated molecules, such as carbon and metals, the molar mass is computed dividing by the number of moles of atoms instead. Thus, for example, the molar mass of iron is about 55.845 g/mol. Since 1971, SI defined the "amount of substance" as

3550-418: The eruption. A cooling lava flow shrinks, and this fractures the flow. Basalt flows show a characteristic pattern of fractures. The uppermost parts of the flow show irregular downward-splaying fractures, while the lower part of the flow shows a very regular pattern of fractures that break the flow into five- or six-sided columns. The irregular upper part of the solidified flow is called the entablature , while

3621-654: The flood basalts of South America formed in this manner. Flood basalts typically crystallize little before they cease flowing, and, as a result, flow textures are uncommon in less silicic flows. On the other hand, flow banding is common in felsic flows. The morphology of lava describes its surface form or texture. More fluid basaltic lava flows tend to form flat sheet-like bodies, whereas viscous rhyolite lava flows form knobbly, blocky masses of rock. Lava erupted underwater has its own distinctive characteristics. ʻAʻā (also spelled aa , aʻa , ʻaʻa , and a-aa , and pronounced [ʔəˈʔaː] or / ˈ ɑː ( ʔ ) ɑː / )

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3692-517: The flow of water and mud down the flanks of the volcano (a lahar ) after heavy rain . Solidified lava on the Earth's crust is predominantly silicate minerals : mostly feldspars , feldspathoids , olivine , pyroxenes , amphiboles , micas and quartz . Rare nonsilicate lavas can be formed by local melting of nonsilicate mineral deposits or by separation of a magma into immiscible silicate and nonsilicate liquid phases . Silicate lavas are molten mixtures dominated by oxygen and silicon ,

3763-497: The icy satellites of the Solar System 's giant planets . The lava's viscosity mostly determines the behavior of lava flows. While the temperature of common silicate lava ranges from about 800 °C (1,470 °F) for felsic lavas to 1,200 °C (2,190 °F) for mafic lavas, its viscosity ranges over seven orders of magnitude, from 10 cP (10 Pa⋅s) for felsic lavas to 10 cP (10 Pa⋅s) for mafic lavas. Lava viscosity

3834-404: The lava's chemical composition. This temperature range is similar to the hottest temperatures achievable with a forced air charcoal forge. Lava is most fluid when first erupted, becoming much more viscous as its temperature drops. Lava flows quickly develop an insulating crust of solid rock as a result of radiative loss of heat. Thereafter, the lava cools by a very slow conduction of heat through

3905-610: The lava. Other cations , such as ferrous iron, calcium, and magnesium, bond much more weakly to oxygen and reduce the tendency to polymerize. Partial polymerization makes the lava viscous, so lava high in silica is much more viscous than lava low in silica. Because of the role of silica in determining viscosity and because many other properties of a lava (such as its temperature) are observed to correlate with silica content, silicate lavas are divided into four chemical types based on silica content: felsic , intermediate , mafic , and ultramafic . Felsic or silicic lavas have

3976-464: The lower and upper boundaries. These are described as pipe-stem vesicles or pipe-stem amygdales . Liquids expelled from the cooling crystal mush rise upwards into the still-fluid center of the cooling flow and produce vertical vesicle cylinders . Where these merge towards the top of the flow, they form sheets of vesicular basalt and are sometimes capped with gas cavities that sometimes fill with secondary minerals. The beautiful amethyst geodes found in

4047-467: The lower part that shows columnar jointing is called the colonnade . (The terms are borrowed from Greek temple architecture.) Likewise, regular vertical patterns on the sides of columns, produced by cooling with periodic fracturing, are described as chisel marks . Despite their names, these are natural features produced by cooling, thermal contraction, and fracturing. As lava cools, crystallizing inwards from its edges, it expels gases to form vesicles at

4118-422: The mantle than subalkaline magmas. Olivine nephelinite lavas are both ultramafic and highly alkaline, and are thought to have come from much deeper in the mantle of the Earth than other lavas. Tholeiitic basalt lava Rhyolite lava Some lavas of unusual composition have erupted onto the surface of the Earth. These include: The term "lava" can also be used to refer to molten "ice mixtures" in eruptions on

4189-412: The mass, in grams, of one mole of atoms of an element, and gram molecular mass for the mass, in grams, of one mole of molecules of a compound. The gram-atom is a former term for a mole of atoms, and gram-molecule for a mole of molecules. Molecular weight (M.W.) (for molecular compounds) and formula weight (F.W.) (for non-molecular compounds), are older terms for what is now more correctly called

4260-428: The measured value of the dalton ). Most atomic masses are known to a precision of at least one part in ten-thousand, often much better (the atomic mass of lithium is a notable, and serious, exception). This is adequate for almost all normal uses in chemistry: it is more precise than most chemical analyses , and exceeds the purity of most laboratory reagents. The precision of atomic masses, and hence of molar masses,

4331-521: The minimal heat loss maintains a low viscosity. The surface texture of pāhoehoe flows varies widely, displaying all kinds of bizarre shapes often referred to as lava sculpture. With increasing distance from the source, pāhoehoe flows may change into ʻaʻā flows in response to heat loss and consequent increase in viscosity. Experiments suggest that the transition takes place at a temperature between 1,200 and 1,170 °C (2,190 and 2,140 °F), with some dependence on shear rate. Pahoehoe lavas typically have

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4402-703: The molar mass is greater than 1000 g/mol, it is rarely appropriate to use more than one decimal place. These conventions are followed in most tabulated values of molar masses. Molar masses are almost never measured directly. They may be calculated from standard atomic masses, and are often listed in chemical catalogues and on safety data sheets (SDS). Molar masses typically vary between: While molar masses are almost always, in practice, calculated from atomic weights, they can also be measured in certain cases. Such measurements are much less precise than modern mass spectrometric measurements of atomic weights and molecular masses, and are of mostly historical interest. All of

4473-470: The most authoritative sources define it differently. The difference is that molecular mass is the mass of one specific particle or molecule, while the molar mass is an average over many particles or molecules. The molar mass is an intensive property of the substance, that does not depend on the size of the sample. In the International System of Units (SI), the coherent unit of molar mass

4544-446: The physical behavior of silicate magmas. Silicon ions in lava strongly bind to four oxygen ions in a tetrahedral arrangement. If an oxygen ion is bound to two silicon ions in the melt, it is described as a bridging oxygen, and lava with many clumps or chains of silicon ions connected by bridging oxygen ions is described as partially polymerized. Aluminium in combination with alkali metal oxides (sodium and potassium) also tends to polymerize

4615-579: The presence of isotopes . Most commonly, the molar mass is computed from the standard atomic weights and is thus a terrestrial average and a function of the relative abundance of the isotopes of the constituent atoms on Earth. The molar mass is appropriate for converting between the mass of a substance and the amount of a substance for bulk quantities. The molecular mass (for molecular compounds) and formula mass (for non-molecular compounds, such as ionic salts ) are commonly used as synonyms of molar mass, differing only in units ( daltons vs g/mol); however,

4686-443: The procedures rely on colligative properties , and any dissociation of the compound must be taken into account. The measurement of molar mass by vapour density relies on the principle, first enunciated by Amedeo Avogadro , that equal volumes of gases under identical conditions contain equal numbers of particles. This principle is included in the ideal gas equation : where n is the amount of substance . The vapour density ( ρ )

4757-440: The range of 850 to 1,100 °C (1,560 to 2,010 °F). Because of their lower silica content and higher eruptive temperatures, they tend to be much less viscous, with a typical viscosity of 3.5 × 10 cP (3,500 Pa⋅s) at 1,200 °C (2,190 °F). This is slightly greater than the viscosity of smooth peanut butter . Intermediate lavas show a greater tendency to form phenocrysts . Higher iron and magnesium tends to manifest as

4828-409: The rate of flow is proportional to the shear stress . Instead, a typical lava is a Bingham fluid , which shows considerable resistance to flow until a stress threshold, called the yield stress, is crossed. This results in plug flow of partially crystalline lava. A familiar example of plug flow is toothpaste squeezed out of a toothpaste tube. The toothpaste comes out as a semisolid plug, because shear

4899-625: The rocky crust. For instance, geologists of the United States Geological Survey regularly drilled into the Kilauea Iki lava lake, formed in an eruption in 1959. After three years, the solid surface crust, whose base was at a temperature of 1,065 °C (1,949 °F), was still only 14 m (46 ft) thick, even though the lake was about 100 m (330 ft) deep. Residual liquid was still present at depths of around 80 m (260 ft) nineteen years after

4970-486: The standard atomic weight or the conventional atomic weight. Multiplying by the molar mass constant ensures that the calculation is dimensionally correct: standard relative atomic masses are dimensionless quantities (i.e., pure numbers) whereas molar masses have units (in this case, grams per mole). Some elements are usually encountered as molecules , e.g. hydrogen ( H 2 ), sulfur ( S 8 ), chlorine ( Cl 2 ). The molar mass of molecules of these elements

5041-480: Was recorded following the collapse of a lava lake at Mount Nyiragongo . The scaling relationship for lavas is that the average speed of a flow scales as the square of its thickness divided by its viscosity. This implies that a rhyolite flow would have to be about a thousand times thicker than a basalt flow to flow at a similar speed. The temperature of most types of molten lava ranges from about 800 °C (1,470 °F) to 1,200 °C (2,190 °F) depending on

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