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73-478: The Old Copper Complex in North America has been radiometrically dated to 9500 BP—i.e., about 7480 BCE—making it one of the oldest known examples of copper extraction in the world. The earliest evidence of the cold-hammering of native copper comes from the excavation at Çayönü Tepesi in eastern Anatolia , which dates between 7200 to 6600 BCE. Among the various items considered to be votive or amulets, there

146-413: A heap leaching or dump leaching . The resulting pregnant leach solution is purified by solvent extraction (SX). It is treated with an organic solvent and an organic chelators. The chelators bind the copper ions (and no other ions, ideally), the resulting complexes dissolve in the organic phase. This organic solvent is evaporated, leaving a residue of the copper complexes. The copper ions are liberated from

219-458: A centimeter over several million years. The average diameter of a polymetallic nodule is between 3 and 10 cm (1 and 4 in) in diameter and are characterized by enrichment in iron, manganese, heavy metals , and rare earth element content when compared to the Earth's crust and surrounding sediment. The proposed mining of these nodules via remotely operated ocean floor trawling robots has raised

292-442: A concentrates with 27–29% and 37–40% copper contents from chalcopyrite and chalcocite , respectively. Oxidised copper ores include carbonates such as azurite and malachite , the silicate chrysocolla , and sulfates such as atacamite . In some cases, sulfide ores are allowed to degrade to oxides. Such ores are amenable to hydrometallurgy. Specifically, such oxide ores are usually extracted into aqueous sulfuric acid , usually in

365-421: A direct result of metamorphism. These are the leading source of copper ore. Porphyry copper deposits form along convergent boundaries and are thought to originate from the partial melting of subducted oceanic plates and subsequent concentration of Cu, driven by oxidation. These are large, round, disseminated deposits containing on average 0.8% copper by weight. Hydrothermal Hydrothermal deposits are

438-404: A high grade copper concentrate. The roasting process is generally undertaken in combination with reverberatory furnaces . In the roaster, the copper concentrate is partially oxidised to produce " calcine ". Sulfur dioxide is liberated. The stoichiometry of the reaction is: Roasting generally leaves more sulfur in the calcined product (15% in the case of the roaster at Mount Isa Mines ) than

511-484: A higher profit. This extraction process can be applied to large quantities of low-grade ores, at a lower capital cost with minimal environmental impact. Generally, direct froth flotation is not used to concentrate copper oxide ores, as a result of the largely ionic and hydrophilic structure of the copper oxide mineral surface. Copper oxide ores are typically treated via chelating-reagent flotation and fatty-acid flotation, which use organic reagents to ensure adsorption onto

584-449: A large source of ore. They form as a result of the precipitation of dissolved ore constituents out of fluids. Laterites form from the weathering of highly mafic rock near the equator. They can form in as little as one million years and are a source of iron (Fe), manganese (Mn), and aluminum (Al). They may also be a source of nickel and cobalt when the parent rock is enriched in these elements. Banded iron formations (BIFs) are

657-644: A number of ecological concerns. The extraction of ore deposits generally follows these steps. Progression from stages 1–3 will see a continuous disqualification of potential ore bodies as more information is obtained on their viability: With rates of ore discovery in a steady decline since the mid 20th century, it is thought that most surface level, easily accessible sources have been exhausted. This means progressively lower grade deposits must be turned to, and new methods of extraction must be developed. Some ores contain heavy metals , toxins, radioactive isotopes and other potentially negative compounds which may pose

730-525: A parallel reaction the iron sulfide is converted to slag: The purity of this product is 98%, it is known as blister because of the broken surface created by the escape of sulfur dioxide gas as blister copper pigs or ingots are cooled. By-products generated in the process are sulfur dioxide and slag . The sulfur dioxide is captured and converted to sulfuric acid and either sold on the open market or used in copper leaching processes. Old Copper Complex The Old Copper complex or Old Copper culture

803-824: A risk to the environment or health. The exact effects an ore and its tailings have is dependent on the minerals present. Tailings of particular concern are those of older mines, as containment and remediation methods in the past were next to non-existent, leading to high levels of leaching into the surrounding environment. Mercury and arsenic are two ore related elements of particular concern. Additional elements found in ore which may have adverse health affects in organisms include iron, lead, uranium, zinc, silicon, titanium, sulfur, nitrogen, platinum, and chromium. Exposure to these elements may result in respiratory and cardiovascular problems and neurological issues. These are of particular danger to aquatic life if dissolved in water. Ores such as those of sulphide minerals may severely increase

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876-423: A significant portion of the sulfur has been eliminated during the roasting stage, and the calcine consists of a mixture of copper and iron oxides and sulfides. The reverberatory furnace acts to allow these species to approach chemical equilibrium at the furnace operating temperature (approximately 1600 °C at the burner end of the furnace and about 1200 °C at the flue end; the matte is about 1100 °C and

949-513: A single mineral, but it is mixed with other valuable minerals and with unwanted or valueless rocks and minerals. The part of an ore that is not economically desirable and that cannot be avoided in mining is known as gangue . The valuable ore minerals are separated from the gangue minerals by froth flotation , gravity concentration, electric or magnetic methods, and other operations known collectively as mineral processing or ore dressing . Mineral processing consists of first liberation, to free

1022-526: A sinter plant leaves in the sintered product (about 7% in the case of the Electrolytic Refining and Smelting smelter). As of 2005, roasting is no longer common in copper concentrate treatment because its combination with reverberatory furnaces is not energy efficient and the SO 2 concentration in the roaster offgas is too dilute for cost-effective capture. Direct smelting is now favored, and uses

1095-552: A sizeable portion of international trade in raw materials both in value and volume. This is because the worldwide distribution of ores is unequal and dislocated from locations of peak demand and from smelting infrastructure. Most base metals (copper, lead, zinc, nickel) are traded internationally on the London Metal Exchange , with smaller stockpiles and metals exchanges monitored by the COMEX and NYMEX exchanges in

1168-486: A variety of geological processes generally referred to as ore genesis and can be classified based on their deposit type. Ore is extracted from the earth through mining and treated or refined , often via smelting , to extract the valuable metals or minerals. Some ores, depending on their composition, may pose threats to health or surrounding ecosystems. The word ore is of Anglo-Saxon origin, meaning lump of metal . In most cases, an ore does not consist entirely of

1241-483: Is a mineral deposit occurring in high enough concentration to be economically viable. An ore deposit is one occurrence of a particular ore type. Most ore deposits are named according to their location, or after a discoverer (e.g. the Kambalda nickel shoots are named after drillers), or after some whimsy, a historical figure, a prominent person, a city or town from which the owner came, something from mythology (such as

1314-474: Is a minor part of a supergene profile it will not be recovered and will report to the tailings . When rich enough, native copper ore bodies may be treated to recover the contained copper by gravity separation . Often, the nature of the gangue is important, as clay-rich native copper ores prove difficult to liberate. This is because clay minerals interact with flotation reagents used in extraction processes, that are then consumed, which results in minimal recovery of

1387-419: Is a mixture of copper, iron and sulfur that is enriched in copper, which is called matte or copper matte . The term matte grade is normally used to refer to the copper content of the matte. The purpose of the matte smelting stage is to eliminate as much of the unwanted iron, sulfur and gangue minerals (such as silica, magnesia, alumina and limestone) as possible, while minimizing the loss of copper. This

1460-419: Is achieved by reacting iron sulfides with oxygen (in air or oxygen enriched air) to produce iron oxides (mainly as FeO , but with some magnetite (Fe 3 O 4 )) and sulfur dioxide . Copper sulfide and iron oxide can mix, but when sufficient silica is added, a separate slag layer is formed. Adding silica also reduces the melting point (or, more properly, the liquidus temperature) of the slag, meaning that

1533-545: Is an archaeological culture from the Archaic period of North America's Great Lakes region. Artifacts from some of these sites have been dated from 6500 to 1580 BCE. It is characterized by widespread copper artifacts, including tools and weapons, as well as ornamental objects. The archeological evidence of smelting or alloying is subject to some dispute, and it is commonly believed that objects were cold-worked into shape. Furthermore, some archaeologists are convinced by

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1606-614: Is an energy-efficient smelting process that was jointly developed from the 1970s to the 1990s by Mount Isa Mines (a subsidiary of MIM Holdings and now part of Glencore ) and the Government of Australia 's CSIRO . It has relatively low capital and operating costs for a smelting process. ISASMELT technology has been applied to lead, copper, and nickel smelting. As of 2021, 22 plants were in operation in eleven countries, along with three demonstration plants located at Mt Isa. The installed capacity of copper/nickel operating plants in 2020

1679-410: Is considered alluvial if formed via river, colluvial if by gravity, and eluvial when close to their parent rock. Polymetallic nodules , also called manganese nodules, are mineral concretions on the sea floor formed of concentric layers of iron and manganese hydroxides around a core. They are formed by a combination of diagenetic and sedimentary precipitation at the estimated rate of about

1752-465: Is constantly forced through the slurry. The air bubbles attach to the hydrophobic copper sulfide particles, which are conveyed to the surface where the froth is skimmed off. These skimmings are generally subjected to a cleaner-scavenger cell to remove excess silicates and to remove other sulfide minerals that can deleteriously impact the concentrate quality (typically, galena ), and the final concentrate sent for smelting. The rock that has not floated off in

1825-547: Is economically viable to mine and process. The grade of ore refers to the concentration of the desired material it contains. The value of the metals or minerals a rock contains must be weighed against the cost of extraction to determine whether it is of sufficiently high grade to be worth mining and is therefore considered an ore. A complex ore is one containing more than one valuable mineral. Minerals of interest are generally oxides , sulfides , silicates , or native metals such as copper or gold . Ore bodies are formed by

1898-408: Is eliminated from the concentrate). It is essentially a melting process. Consequently, wet-charged reverberatory furnaces have less copper in their matte product than calcine-charged furnaces, and they also have lower copper losses to slag. Gill quotes a copper in slag value of 0.23% for a wet-charged reverberatory furnace vs 0.37% for a calcine-charged furnace. In the case of calcine-charged furnaces,

1971-425: Is normally added to help form the slag. The furnace is fired with burners using pulverized coal, fuel oil or natural gas. Reverberatory furnaces can additionally be fed with molten slag from the later converting stage to recover the contained copper and other materials with a high copper content. Because the reverberatory furnace bath is quiescent, very little oxidation of the feed occurs (and thus very little sulfur

2044-741: The Appalachian Mountains near the Etowah Site in Georgia. The Mississippian copper plates were made by a process of annealing . Ancient copper artifacts are found over a very wide range, all around the Great Lakes region, and far south into what is now the USA. Ore Ore is natural rock or sediment that contains one or more valuable minerals , typically including metals , concentrated above background levels, and that

2117-591: The Keweenaw Peninsula , and the Brule River , and copper was deposited elsewhere by glaciation as well. Evidence of mining, deep holes chipped into the rock, can be found in Ontario , Manitoba , and around Lake Superior . By heating, annealing and hammering, these cultures worked the copper into shape and produced a variety of spearpoints, tools and decorative objects. In addition to their own use,

2190-467: The refractory bricks lining the furnace. When the removal of the matte or slag is complete, the hole is normally plugged with clay, which is removed when the furnace is ready to be tapped again. Reverberatory furnaces were often used to treat molten converter slag to recover contained copper. This would be poured into the furnaces from ladles carried by cranes. However, the converter slag is high in magnetite and some of this magnetite would precipitate from

2263-416: The 1980s and 1990s given that copper mining in other countries faced problems like political instability ( Peru ), increased environmental requirements (developed countries) or overall disinterest in foreign investment in a nationalized mining industry ( Zaire , Zambia ). The average grade of copper ores in the 21st century is below 0.6% copper, with a proportion of economic ore minerals being less than 2% of

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2336-524: The Copper Complex peoples traded copper goods for other exotic materials. By about 3,000 years ago copper was increasingly restricted to jewelry and other status-related items, rather than tools. This is thought to represent the development of more complex social hierarchies in the area. The Copper Culture State Park , in Oconto , northeastern Wisconsin , contains an ancient burial ground used by

2409-687: The Old Copper complex culture between 5,000 and 6,000 years ago. It was rediscovered in June 1952 by a 13-year-old boy who unearthed human bones while playing in an old quarry. By July the first archaeological dig was started by the Wisconsin Archaeological Survey. Copper is known to have been traded from the Great Lakes region to other parts of North America. However, there were also other sources of copper, including in

2482-752: The United States and the Shanghai Futures Exchange in China. The global Chromium market is currently dominated by the United States and China. Iron ore is traded between customer and producer, though various benchmark prices are set quarterly between the major mining conglomerates and the major consumers, and this sets the stage for smaller participants. Other, lesser, commodities do not have international clearing houses and benchmark prices, with most prices negotiated between suppliers and customers one-on-one. This generally makes determining

2555-553: The acidity of their immediate surroundings and of water, with numerous, long lasting impacts on ecosystems. When water becomes contaminated it may transport these compounds far from the tailings site, greatly increasing the affected range. Uranium ores and those containing other radioactive elements may pose a significant threat if leaving occurs and isotope concentration increases above background levels. Radiation can have severe, long lasting environmental impacts and cause irreversible damage to living organisms. Metallurgy began with

2628-499: The artifactual and structural evidence for metal casting by Hopewellian and Mississippian peoples. The Old Copper Complex of the Western Great Lakes is the best known, and can be dated as far back as 9,500 years ago. Great Lakes natives of the Archaic period located 99% pure copper near Lake Superior , in veins touching the surface and in nuggets from gravel beds. Major quarries were located on Isle Royale ,

2701-409: The concentrate is dispersed in an air or oxygen stream and the smelting reactions are largely completed while the mineral particles are still in flight. The reacted particles then settle in a bath at the bottom of the furnace, where they behave like calcine in a reverberatory furnace. A slag layer forms on top of the matte layer, and they can separately be tapped from the furnace. The ISASMELT process

2774-404: The converter slag (due to its higher melting point), forming an accretion on the hearth of the reverberatory furnace and necessitating shut downs of the furnace to remove the accretion. This accretion formation limits the quantity of converter slag that can be treated in a reverberatory furnace. While reverberatory furnaces have very low copper losses to slag, they are not very energy-efficient and

2847-418: The copper dissolved in slags from mattes containing less than 50% copper is sulfidic copper. Above this figure, oxidic copper begins to dominate. The loss of copper as prills suspended in the slag depends on the size of the prills, the viscosity of the slag and the settling time available. Rosenqvist suggested that about half the copper losses to slag were due to suspended prills. The mass of slag generated in

2920-465: The copper from the pregnant leach solution . To ensure the best recovery of copper, it is important to acknowledge the effect copper dissolution, acid consumption, and gangue mineral composition has on the efficacy of extraction. Supergene sulfide ores rich in native copper are refractory to treatment with sulfuric acid leaching on all practicable time scales, and the dense metal particles do not react with froth flotation media. Typically, if native copper

2993-404: The crushed ore is wetted, suspended in a slurry, and mixed with reagents that render the sulfide particles hydrophobic . Typical reagents ("collectors") include potassium ethylxanthate and sodium ethylxanthate , but dithiophosphates and dithiocarbamates are also used. The slurry is introduced to a water-filled aeration tank containing a surfactant such as methylisobutyl carbinol (MIBC). Air

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3066-407: The depletion of copper resources. Processes including in situ, dump, and heap leaching are cost-effective methods that are suitable for extracting copper from low-grade ores. Extraction processes for secondary copper sulfides and low-grade ores includes the process of heap bioleaching. Heap bioleaching presents a cost efficient extraction method that requires a less intensive energy input resulting in

3139-426: The development of smelting technology. Until the latter half of the 20th century, smelting sulfide ores was almost the sole means of producing copper metal from mined ores ( primary copper production). As of 2002, 80% of global primary copper production was from copper–iron–sulfur minerals, and the vast majority of these were treated by smelting. Copper was initially recovered from sulfide ores by directly smelting

3212-519: The development of the giant Bingham Canyon mine in Utah possible. In the twentieth century, most ores were concentrated before smelting. Smelting was initially undertaken using sinter plants and blast furnaces , or with roasters and reverberatory furnaces . Roasting and reverberatory furnace smelting dominated primary copper production until the 1960s. In the 1960s and 1970s large copper mining operations by U.S. companies were nationalized in many of

3285-417: The direct working of native metals such as gold, lead and copper. Placer deposits, for example, would have been the first source of native gold. The first exploited ores were copper oxides such as malachite and azurite, over 7000 years ago at Çatalhöyük . These were the easiest to work, with relatively limited mining and basic requirements for smelting. It is believed they were once much more abundant on

3358-402: The flotation cell is either discarded as tailings or further processed to extract other metals such as lead (from galena) and zinc (from sphalerite ), should they exist. A variety of measures are taken to improve the efficiency of the froth flotation. Lime is used to raise the pH of the water bath, causing the collector to bond more efficiently to the copper sulfides. The process can produce

3431-448: The following smelting technologies: flash smelting , Isasmelt , Noranda, Mitsubishi or El Teniente furnaces. The initial melting of the material to be smelted is usually referred to as the smelting or matte smelting stage. It can be undertaken in a variety of furnaces, including the largely obsolete blast furnaces and reverberatory furnaces , as well as flash furnaces , Isasmelt furnaces, etc. The product of this smelting stage

3504-425: The furnace as separate streams. The slag layer is periodically allowed to flow through a hole in the wall of the furnace above the height of the matte layer. The matte is removed by draining it through a hole into ladles for it to be carried by crane to the converters. This draining process is known as tapping the furnace. The matte taphole is normally a hole through a water-cooled copper block that prevents erosion of

3577-458: The highest concentration of any single metal available. They are composed of chert beds alternating between high and low iron concentrations. Their deposition occurred early in Earth's history when the atmospheric composition was significantly different from today. Iron rich water is thought to have upwelled where it oxidized to Fe (III) in the presence of early photosynthetic plankton producing oxygen. This iron then precipitated out and deposited on

3650-459: The loss of copper to slag in the smelting stage are: This means that there is a practical limit on how high the matte grade can be if the loss of copper to slag is to be minimized. Therefore, further stages of processing (converting and fire refining) are required. The following subsections briefly describe some of the processes used in matte smelting. Reverberatory furnaces are long furnaces that can treat wet, dry, or roasted concentrate. Most of

3723-461: The low concentrations of sulfur dioxide in their off-gases make its capture uneconomic. Consequently, smelter operators devoted a lot of money in the 1970s and 1980s to developing new, more efficient copper smelting processes. In addition, flash smelting technologies had been developed in earlier years and began to replace reverberatory furnaces. By 2002, 20 of the 30 reverberatory furnaces still operating in 1994 had been shut down. In flash smelting ,

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3796-535: The main copper producing countries. Thus by the 1980s state owned enterpises overtook the dominant role U.S. companies like Anaconda Copper and Kennecott had had until then. In the late 1970s and early 1980s various oil companies like ARCO , Exxon ( Exxon Minerals ) and Standard Oil Company expanded into copper mining for a few years before selling their copper assets. Reportedly gains were not as high as anticipated. Investments in copper mining concentrated in Chile in

3869-626: The main tin source, began. Some 3000 years ago, the smelting of iron ores began in Mesopotamia . Iron oxide is quite abundant on the surface and forms from a variety of processes. Until the 18th century gold, copper, lead, iron, silver, tin, arsenic and mercury were the only metals mined and used. In recent decades, Rare Earth Elements have been increasingly exploited for various high-tech applications. This has led to an ever-growing search for REE ore and novel ways of extracting said elements. Ores (metals) are traded internationally and comprise

3942-435: The mineral chalcocite; a mineral formed from primary sulfides, like chalcopyrite , that undergo chemical processes such as oxidation or reduction. Typically, secondary sulfide ores are concentrated using froth flotation. Other extraction processes like leaching are effectively used for the extraction of secondary copper sulfides, but as demand for copper rises, extraction processes tailored for low-grade ores are required, due to

4015-422: The mineral surface through the formation of hydrophobic compounds on the mineral surface. Some supergene sulfide deposits can be leached using a bacterial oxidation heap leach process to oxidize the sulfides to sulfuric acid, which also allows for simultaneous leaching with sulfuric acid to produce a copper sulfate solution. For oxide ores, solvent extraction and electrowinning technologies are used to recover

4088-526: The name of a god or goddess) or the code name of the resource company which found it (e.g. MKD-5 was the in-house name for the Mount Keith nickel sulphide deposit ). Ore deposits are classified according to various criteria developed via the study of economic geology, or ore genesis . The following is a general categorization of the main ore deposit types: Magmatic deposits are ones who originate directly from magma These are ore deposits which form as

4161-408: The nature of the ore. In the usual case when it is primarily sulfide copper minerals (such as chalcopyrite , FeCuS 2 ), the ore is treated by comminution , where the rock is crushed to produce small particles (<100 μm) consisting of individual mineral phases. These particles are then ready to be separated to remove gangue (silicate rocks residues) using froth flotation. In froth flotation,

4234-582: The ocean floor. The banding is thought to be a result of changing plankton population. Sediment Hosted Copper forms from the precipitation of a copper rich oxidized brine into sedimentary rocks. These are a source of copper primarily in the form of copper-sulfide minerals. Placer deposits are the result of weathering, transport, and subsequent concentration of a valuable mineral via water or wind. They are typically sources of gold (Au), platinum group elements (PGE), sulfide minerals , tin (Sn), tungsten (W), and rare-earth elements (REEs). A placer deposit

4307-535: The oldest securely dated evidence of copper making at high temperature, from 5,000 BCE. The find in June 2010 extends for an additional 500 years, dated to 5th millennium BCE, representing the earlier record of copper smelting from Rudna Glava ( Serbia ). Copper smelting technology gave rise to the Copper Age , aka Chalcolithic Age, and then the Bronze Age . The Bronze Age would not have been possible without

4380-403: The ore from the gangue, and concentration to separate the desired mineral(s) from it. Once processed, the gangue is known as tailings , which are useless but potentially harmful materials produced in great quantity, especially from lower grade deposits. An ore deposit is an economically significant accumulation of minerals within a host rock. This is distinct from a mineral resource in that it

4453-420: The ore in a furnace. The smelters were initially located near the mines to minimize the cost of transport. This avoided the prohibitive costs of transporting the waste minerals and the sulfur and iron present in the copper-containing minerals. However, as the concentration of copper in the ore bodies decreased, the energy costs of smelting the whole ore also became prohibitive, and it became necessary to concentrate

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4526-469: The ores first. Initial concentration techniques included hand-sorting and gravity concentration. These resulted in high losses of copper. Consequently, the development of the froth flotation process was a major step forward in mineral processing. The modern froth flotation process was independently invented in the early 1900s in Australia by C.V Potter and around the same time by G. D. Delprat . It made

4599-399: The oxygen potential of the slag increases. The oxygen potential generally increases as the copper content of the matte is increased. Thus, the loss of copper as oxide increases as the copper content of the matte increases. On the other hand, the solubility of sulfidic copper in slag decreases as the copper content of the matte increases beyond about 40%. Nagamori calculated that more than half

4672-431: The price of ores of this nature opaque and difficult. Such metals include lithium , niobium - tantalum , bismuth , antimony and rare earths . Most of these commodities are also dominated by one or two major suppliers with >60% of the world's reserves. China is currently leading in world production of Rare Earth Elements. The World Bank reports that China was the top importer of ores and metals in 2005 followed by

4745-515: The residue with sulfuric acid. The barred (denuded) sulfuric acid recycled back on to the heaps. The organic ligands are recovered and recycled as well. Alternatively, the copper can be precipitated out of the pregnant solution by contacting it with scrap iron; a process called cementation . Cement copper is normally less pure than SX-EW copper. Secondary sulfides—those formed by supergene secondary enrichment—are resistant ( refractory ) to sulfuric leaching. Secondary copper sulfides are dominated by

4818-426: The reverberatory furnaces used in the latter years treated roasted concentrate because putting dry feed materials into the reverberatory furnace is more energy efficient, and because the elimination of some of the sulfur in the roaster results in higher matte grades. The reverberatory furnace feed is added to the furnace through feed holes along the sides of the furnace, and the solid charge is melted. Additional silica

4891-401: The slag is about 1195 °C). In this equilibration process, oxygen associated with copper compounds exchanges with sulfur associated with iron compounds, increasing the iron oxide content of the furnace, and the iron oxides interact with silica and other oxide materials to form the slag. The main equilibration reaction is: The slag and the matte form distinct layers that can be removed from

4964-447: The smelting process can be operated at a lower temperature. The slag forming reaction is: Slag is less dense than matte, so it forms a layer that floats on top of the matte. Copper can be lost from the matte in three ways: as cuprous oxide (Cu 2 O) dissolved in the slag, as sulfide copper dissolved in the slag or as tiny droplets (or prills ) of matte suspended in the slag. The amount of copper lost as oxide copper increases as

5037-401: The smelting stage depends on the iron content of the material fed into the smelting furnace and the target matte grade. The greater the iron content of the feed, the more iron that will need to be rejected to the slag for a given matte grade. Similarly, increasing the target matte grade requires the rejection of more iron and an increase in the slag volume. Thus, the two factors that most affect

5110-413: The surface than today. After this, copper sulphides would have been turned to as oxide resources depleted and the Bronze Age progressed. Lead production from galena smelting may have been occurring at this time as well. The smelting of arsenic-copper sulphides would have produced the first bronze alloys. The majority of bronze creation however required tin, and thus the exploitation of cassiterite,

5183-413: The total volume of the ore rock. Thus, all mining operations, the ore must usually be beneficiated (concentrated). The concentrate is typically sold to distant smelters , although some large mines have smelters located nearby. Such colocation of mines and smelters was more typical in the 19th and early 20th centuries, when smaller smelters could be economic. The subsequent processing techniques depend on

5256-418: Was 9.76 million tonnes per year of feed materials and 750 thousand tonnes per year across lead operating plants. The matte, which is produced in the smelter, contains 30–70% copper (depending on the process used and the operating philosophy of the smelter), primarily as copper sulfide, as well as iron sulfide. The sulfur is removed at a high temperature as sulfur dioxide by blowing air through molten matte: In

5329-537: Was one that looked like a fishhook and one like an awl. Another find, at Shanidar Cave in Mergasur, Iraq, contained copper beads, and dates back to 8,700 BCE. One of the world's oldest known copper mines, as opposed to usage of surface deposits, is at Timna Valley , Israel, and has been used since the fourth millennium BC, with surface deposit usage occurring in the fifth and sixth millennium. The Pločnik archaeological site in southeastern Europe ( Serbia ) contains

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