Corn nuts , also known as toasted corn , are a snack food made of roasted or deep-fried corn kernels . It is referred to as cancha in Peru , chulpi in Ecuador , and cornick in the Philippines .
113-606: Corn nuts are prepared by soaking whole corn kernels in water for three days, then deep-frying them in oil until they are hard and brittle. The kernels are soaked because they shrink during the harvesting and cleaning process, and rehydration returns them to their original size. In 1936 (after the end of prohibition), Olin Huntington, an entrepreneur from the Bay Area produced them as a cheap snack to be handed out free at bars — although this fell apart when California introduced
226-583: A cascade method, Swiss chemist and physicist Raoul Pierre Pictet evaporated liquid sulfur dioxide in order to liquefy carbon dioxide, which in turn was evaporated to cool oxygen gas enough to liquefy it. He sent a telegram on December 22, 1877, to the French Academy of Sciences in Paris announcing his discovery of liquid oxygen . Just two days later, French physicist Louis Paul Cailletet announced his own method of liquefying molecular oxygen. Only
339-601: A 1 cm sample cell. Aquatic plants , algae , and other photosynthetic organisms can live in water up to hundreds of meters deep, because sunlight can reach them. Practically no sunlight reaches the parts of the oceans below 1,000 metres (3,300 ft) of depth. The refractive index of liquid water (1.333 at 20 °C (68 °F)) is much higher than that of air (1.0), similar to those of alkanes and ethanol , but lower than those of glycerol (1.473), benzene (1.501), carbon disulfide (1.627), and common types of glass (1.4 to 1.6). The refraction index of ice (1.31)
452-567: A breed of corn grown in Cusco, Peru (often referred to as Cuzco corn ) that grew large kernels (some said to have been bigger than a quarter ), the company researched developing a hybrid of the Cusco corn that could be grown effectively in California. After a decade of research, the company introduced CornNuts made with the hybrid variety in 1964. CornNuts sold on the market today are no longer of
565-477: A chemical element. The name oxygen was coined in 1777 by Antoine Lavoisier , who first recognized oxygen as a chemical element and correctly characterized the role it plays in combustion. Common industrial uses of oxygen include production of steel , plastics and textiles , brazing, welding and cutting of steels and other metals , rocket propellant , oxygen therapy , and life support systems in aircraft , submarines , spaceflight and diving . One of
678-434: A few drops of the liquid were produced in each case and no meaningful analysis could be conducted. Oxygen was liquefied in a stable state for the first time on March 29, 1883, by Polish scientists from Jagiellonian University , Zygmunt Wróblewski and Karol Olszewski . In 1891 Scottish chemist James Dewar was able to produce enough liquid oxygen for study. The first commercially viable process for producing liquid oxygen
791-481: A large amount of sediment transport that occurs on the surface of the earth. Deposition of transported sediment forms many types of sedimentary rocks , which make up the geologic record of Earth history . The water cycle (known scientifically as the hydrologic cycle) is the continuous exchange of water within the hydrosphere , between the atmosphere , soil water, surface water , groundwater, and plants. Water moves perpetually through each of these regions in
904-461: A law that forbade watering holes from handing out free food. This is what led another man, Albert Holloway, to snap up the company and pivot towards selling the corn snack in stores. He ended up trademarking the name Corn Nuts (sometimes written as "CornNuts") in the '40s, and he and his family held onto the company until 1997 when it was sold to Nabisco. Holloway later renamed his product CornNuts. After Holloway and his sons Maurice and Rich learned of
1017-481: A light sky-blue color caused by absorption in the red (in contrast with the blue color of the sky, which is due to Rayleigh scattering of blue light). High-purity liquid O 2 is usually obtained by the fractional distillation of liquefied air. Liquid oxygen may also be condensed from air using liquid nitrogen as a coolant. Liquid oxygen is a highly reactive substance and must be segregated from combustible materials. The spectroscopy of molecular oxygen
1130-564: A major role in absorbing energy from singlet oxygen and converting it to the unexcited ground state before it can cause harm to tissues. The common allotrope of elemental oxygen on Earth is called dioxygen , O 2 , the major part of the Earth's atmospheric oxygen (see Occurrence ). O 2 has a bond length of 121 pm and a bond energy of 498 kJ/mol . O 2 is used by complex forms of life, such as animals, in cellular respiration . Other aspects of O 2 are covered in
1243-438: A part of air that he called spiritus nitroaereus . In one experiment, he found that placing either a mouse or a lit candle in a closed container over water caused the water to rise and replace one-fourteenth of the air's volume before extinguishing the subjects. From this, he surmised that nitroaereus is consumed in both respiration and combustion. Mayow observed that antimony increased in weight when heated, and inferred that
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#17327826195421356-464: A popular snack known as maíz tostado ("toasted corn"), maíz frito ("fried corn"), quicos ("Frankies") and pepes ("Joes"). The base flavor is very salty, though barbecue is also available. Recently, crushed corn nuts are being introduced as a cover for battering . Water Water is an inorganic compound with the chemical formula H 2 O . It is a transparent, tasteless, odorless, and nearly colorless chemical substance . It
1469-404: A process called eutrophication and the decay of these organisms and other biomaterials may reduce the O 2 content in eutrophic water bodies. Scientists assess this aspect of water quality by measuring the water's biochemical oxygen demand , or the amount of O 2 needed to restore it to a normal concentration. Paleoclimatologists measure the ratio of oxygen-18 and oxygen-16 in
1582-477: A property that is exploited by cetaceans and humans for communication and environment sensing ( sonar ). Metallic elements which are more electropositive than hydrogen, particularly the alkali metals and alkaline earth metals such as lithium , sodium , calcium , potassium and cesium displace hydrogen from water, forming hydroxides and releasing hydrogen. At high temperatures, carbon reacts with steam to form carbon monoxide and hydrogen. Hydrology
1695-458: A small proportion of manganese dioxide. Oxygen levels in the atmosphere are trending slightly downward globally, possibly because of fossil-fuel burning. At standard temperature and pressure , oxygen is a colorless, odorless, and tasteless gas with the molecular formula O 2 , referred to as dioxygen. As dioxygen , two oxygen atoms are chemically bound to each other. The bond can be variously described based on level of theory, but
1808-440: A structure of rigid oxygen atoms in which hydrogen atoms flowed freely. When sandwiched between layers of graphene , ice forms a square lattice. The details of the chemical nature of liquid water are not well understood; some theories suggest that its unusual behavior is due to the existence of two liquid states. Pure water is usually described as tasteless and odorless, although humans have specific sensors that can feel
1921-412: A swimming pool when the light source is sunlight reflected from the pool's white tiles. In nature, the color may also be modified from blue to green due to the presence of suspended solids or algae. In industry, near-infrared spectroscopy is used with aqueous solutions as the greater intensity of the lower overtones of water means that glass cuvettes with short path-length may be employed. To observe
2034-449: A triplet electronic ground state . An electron configuration with two unpaired electrons, as is found in dioxygen orbitals (see the filled π* orbitals in the diagram) that are of equal energy—i.e., degenerate —is a configuration termed a spin triplet state. Hence, the ground state of the O 2 molecule is referred to as triplet oxygen . The highest-energy, partially filled orbitals are antibonding , and so their filling weakens
2147-461: A variety of applications including high-temperature electrochemistry and as an ecologically benign solvent or catalyst in chemical reactions involving organic compounds. In Earth's mantle, it acts as a solvent during mineral formation, dissolution and deposition. The normal form of ice on the surface of Earth is ice I h , a phase that forms crystals with hexagonal symmetry . Another with cubic crystalline symmetry , ice I c , can occur in
2260-489: Is visibly blue due to absorption of light in the region c. 600–800 nm. The color can be easily observed in a glass of tap-water placed against a pure white background, in daylight. The principal absorption bands responsible for the color are overtones of the O–H stretching vibrations . The apparent intensity of the color increases with the depth of the water column, following Beer's law . This also applies, for example, with
2373-439: Is 917 kg/m (57.25 lb/cu ft), an expansion of 9%. This expansion can exert enormous pressure, bursting pipes and cracking rocks. In a lake or ocean, water at 4 °C (39 °F) sinks to the bottom, and ice forms on the surface, floating on the liquid water. This ice insulates the water below, preventing it from freezing solid. Without this protection, most aquatic organisms residing in lakes would perish during
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#17327826195422486-580: Is a corrosive byproduct of smog and thus an air pollutant . Oxygen was isolated by Michael Sendivogius before 1604, but it is commonly believed that the element was discovered independently by Carl Wilhelm Scheele , in Uppsala , in 1773 or earlier, and Joseph Priestley in Wiltshire , in 1774. Priority is often given for Priestley because his work was published first. Priestley, however, called oxygen "dephlogisticated air", and did not recognize it as
2599-477: Is absorbed by specialized respiratory organs called gills , through the skin or via the gut ; in terrestrial animals such as tetrapods , oxygen in air is actively taken into the body via specialized organs known as lungs , where gas exchange takes place to diffuse oxygen into the blood and carbon dioxide out, and the body's circulatory system then transports the oxygen to other tissues where cellular respiration takes place. However in insects ,
2712-513: Is associated with the atmospheric processes of aurora and airglow . The absorption in the Herzberg continuum and Schumann–Runge bands in the ultraviolet produces atomic oxygen that is important in the chemistry of the middle atmosphere. Excited-state singlet molecular oxygen is responsible for red chemiluminescence in solution. Table of thermal and physical properties of oxygen (O 2 ) at atmospheric pressure: Naturally occurring oxygen
2825-493: Is at a temperature of 273.16 K (0.01 °C; 32.02 °F) and a pressure of 611.657 pascals (0.00604 atm; 0.0887 psi); it is the lowest pressure at which liquid water can exist. Until 2019 , the triple point was used to define the Kelvin temperature scale . The water/vapor phase curve terminates at 647.096 K (373.946 °C; 705.103 °F) and 22.064 megapascals (3,200.1 psi; 217.75 atm). This
2938-472: Is composed of three stable isotopes , O , O , and O , with O being the most abundant (99.762% natural abundance ). Most O is synthesized at the end of the helium fusion process in massive stars but some is made in the neon burning process . O is primarily made by the burning of hydrogen into helium during the CNO cycle , making it a common isotope in the hydrogen burning zones of stars. Most O
3051-622: Is cornick ( Filipino : kornik ). Compared to the American variety, cornick pieces are typically smaller and crispier. They are also traditionally made from glutinous corn . Garlic is the most common flavor of cornick, with other common flavors including: chili cheese , adobo , barbecue , lechón manok (also known as roasted chicken), and sweet. Major brands include Boy Bawang (literally "Garlic Boy" in Tagalog , commonly sold in small packets), Corn Bits, and Safari. A popular variety of cornick
3164-428: Is greater than the repulsion between the hydrogen atoms. The O–H bond length is about 0.096 nm. Other substances have a tetrahedral molecular structure, for example methane ( CH 4 ) and hydrogen sulfide ( H 2 S ). However, oxygen is more electronegative than most other elements, so the oxygen atom has a negative partial charge while the hydrogen atoms are partially positively charged. Along with
3277-435: Is important in many geological processes. Groundwater is present in most rocks , and the pressure of this groundwater affects patterns of faulting . Water in the mantle is responsible for the melt that produces volcanoes at subduction zones . On the surface of the Earth, water is important in both chemical and physical weathering processes. Water, and to a lesser but still significant extent, ice, are also responsible for
3390-470: Is it a noble gas (and therefore is not removed from the atmosphere through chemical reactions with other elements), but comparisons between the abundances of its nine stable isotopes in the modern atmosphere reveal that the Earth lost at least one ocean of water early in its history, between the Hadean and Archean eons. Any water on Earth during the latter part of its accretion would have been disrupted by
3503-498: Is known as the critical point . At higher temperatures and pressures the liquid and vapor phases form a continuous phase called a supercritical fluid . It can be gradually compressed or expanded between gas-like and liquid-like densities; its properties (which are quite different from those of ambient water) are sensitive to density. For example, for suitable pressures and temperatures it can mix freely with nonpolar compounds , including most organic compounds . This makes it useful in
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3616-413: Is lower than that of liquid water. In a water molecule, the hydrogen atoms form a 104.5° angle with the oxygen atom. The hydrogen atoms are close to two corners of a tetrahedron centered on the oxygen. At the other two corners are lone pairs of valence electrons that do not participate in the bonding. In a perfect tetrahedron, the atoms would form a 109.5° angle, but the repulsion between the lone pairs
3729-447: Is oxygen as a component of water, the major constituent of lifeforms. Oxygen in Earth's atmosphere is produced by biotic photosynthesis , in which photon energy in sunlight is captured by chlorophyll to split water molecules and then react with carbon dioxide to produce carbohydrates and oxygen is released as a byproduct . Oxygen is too chemically reactive to remain a free element in air without being continuously replenished by
3842-422: Is poor at dissolving nonpolar substances. This allows it to be the " solvent of life": indeed, water as found in nature almost always includes various dissolved substances, and special steps are required to obtain chemically pure water . Water is the only common substance to exist as a solid , liquid, and gas in normal terrestrial conditions. Along with oxidane , water is one of the two official names for
3955-441: Is produced when N (made abundant from CNO burning) captures a He nucleus, making O common in the helium-rich zones of evolved, massive stars . Fifteen radioisotopes have been characterized, ranging from O to O. The most stable are O with a half-life of 122.24 seconds and O with a half-life of 70.606 seconds. All of the remaining radioactive isotopes have half-lives that are less than 27 seconds and
4068-408: Is reasonably and simply described as a covalent double bond that results from the filling of molecular orbitals formed from the atomic orbitals of the individual oxygen atoms, the filling of which results in a bond order of two. More specifically, the double bond is the result of sequential, low-to-high energy, or Aufbau , filling of orbitals, and the resulting cancellation of contributions from
4181-712: Is temperature-dependent, and about twice as much ( 14.6 mg/L ) dissolves at 0 °C than at 20 °C ( 7.6 mg/L ). At 25 °C and 1 standard atmosphere (101.3 kPa ) of air, freshwater can dissolve about 6.04 milliliters (mL) of oxygen per liter , and seawater contains about 4.95 mL per liter. At 5 °C the solubility increases to 9.0 mL (50% more than at 25 °C) per liter for freshwater and 7.2 mL (45% more) per liter for sea water. Oxygen condenses at 90.20 K (−182.95 °C, −297.31 °F) and freezes at 54.36 K (−218.79 °C, −361.82 °F). Both liquid and solid O 2 are clear substances with
4294-636: Is the lighter, chicharrón -like chichacorn , a semi- popped style of cornick using glutinous corn from the Ilocos Region which is treated with lime before frying. Diana, a snack company in El Salvador, makes a variety of corn-nut-like snacks. These are called elotitos in Spanish, or cornbits . These come in a variety of seasonings, such as Lemon, Cheese and Chili, and Barbecue. These are sold throughout Central America. In Spain, they are
4407-431: Is the main constituent of Earth 's hydrosphere and the fluids of all known living organisms (in which it acts as a solvent ). It is vital for all known forms of life , despite not providing food energy or organic micronutrients . Its chemical formula, H 2 O , indicates that each of its molecules contains one oxygen and two hydrogen atoms , connected by covalent bonds . The hydrogen atoms are attached to
4520-435: Is the result of the oxygen cycle . This biogeochemical cycle describes the movement of oxygen within and between its three main reservoirs on Earth: the atmosphere, the biosphere, and the lithosphere . The main driving factor of the oxygen cycle is photosynthesis , which is responsible for modern Earth's atmosphere. Photosynthesis releases oxygen into the atmosphere, while respiration , decay , and combustion remove it from
4633-458: Is the study of the movement, distribution, and quality of water throughout the Earth. The study of the distribution of water is hydrography . The study of the distribution and movement of groundwater is hydrogeology , of glaciers is glaciology , of inland waters is limnology and distribution of oceans is oceanography . Ecological processes with hydrology are in the focus of ecohydrology . The collective mass of water found on, under, and over
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4746-463: Is unusual among the planets of the Solar System in having such a high concentration of oxygen gas in its atmosphere: Mars (with 0.1% O 2 by volume) and Venus have much less. The O 2 surrounding those planets is produced solely by the action of ultraviolet radiation on oxygen-containing molecules such as carbon dioxide. The unusually high concentration of oxygen gas on Earth
4859-522: Is usually given priority in the discovery. The French chemist Antoine Laurent Lavoisier later claimed to have discovered the new substance independently. Priestley visited Lavoisier in October 1774 and told him about his experiment and how he liberated the new gas. Scheele had also dispatched a letter to Lavoisier on September 30, 1774, which described his discovery of the previously unknown substance, but Lavoisier never acknowledged receiving it (a copy of
4972-669: The Earth , the Moon , Mars , and meteorites , but were long unable to obtain reference values for the isotope ratios in the Sun , believed to be the same as those of the primordial solar nebula . Analysis of a silicon wafer exposed to the solar wind in space and returned by the crashed Genesis spacecraft has shown that the Sun has a higher proportion of oxygen-16 than does the Earth. The measurement implies that an unknown process depleted oxygen-16 from
5085-463: The Earth's crust in the form of various oxides such as water , carbon dioxide , iron oxides and silicates . All eukaryotic organisms , including plants , animals , fungi , algae and most protists , need oxygen for cellular respiration , which extracts chemical energy by the reaction of oxygen with organic molecules derived from food and releases carbon dioxide as a waste product. In aquatic animals , dissolved oxygen in water
5198-565: The Greek roots ὀξύς (oxys) ( acid , literally 'sharp', from the taste of acids) and -γενής (-genēs) (producer, literally begetter), because he mistakenly believed that oxygen was a constituent of all acids. Chemists (such as Sir Humphry Davy in 1812) eventually determined that Lavoisier was wrong in this regard, but by then the name was too well established. Oxygen entered the English language despite opposition by English scientists and
5311-485: The Moon-forming impact (~4.5 billion years ago), which likely vaporized much of Earth's crust and upper mantle and created a rock-vapor atmosphere around the young planet. The rock vapor would have condensed within two thousand years, leaving behind hot volatiles which probably resulted in a majority carbon dioxide atmosphere with hydrogen and water vapor . Afterward, liquid water oceans may have existed despite
5424-432: The elements hydrogen and oxygen by passing an electric current through it—a process called electrolysis . The decomposition requires more energy input than the heat released by the inverse process (285.8 kJ/ mol , or 15.9 MJ/kg). Liquid water can be assumed to be incompressible for most purposes: its compressibility ranges from 4.4 to 5.1 × 10 Pa in ordinary conditions. Even in oceans at 4 km depth, where
5537-529: The molar volumes of the liquid and solid phases, and L f {\displaystyle L_{\text{f}}} is the molar latent heat of melting. In most substances, the volume increases when melting occurs, so the melting temperature increases with pressure. However, because ice is less dense than water, the melting temperature decreases. In glaciers, pressure melting can occur under sufficiently thick volumes of ice, resulting in subglacial lakes . The Clausius-Clapeyron relation also applies to
5650-470: The shells and skeletons of marine organisms to determine the climate millions of years ago (see oxygen isotope ratio cycle ). Seawater molecules that contain the lighter isotope , oxygen-16, evaporate at a slightly faster rate than water molecules containing the 12% heavier oxygen-18, and this disparity increases at lower temperatures. During periods of lower global temperatures, snow and rain from that evaporated water tends to be higher in oxygen-16, and
5763-430: The thermal decomposition of potassium nitrate . In Bugaj's view, the isolation of oxygen and the proper association of the substance to that part of air which is required for life, provides sufficient evidence for the discovery of oxygen by Sendivogius. This discovery of Sendivogius was however frequently denied by the generations of scientists and chemists which succeeded him. It is also commonly claimed that oxygen
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#17327826195425876-441: The water cycle consisting of the following transfer processes: Oxygen Oxygen is a chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table , a highly reactive nonmetal , and a potent oxidizing agent that readily forms oxides with most elements as well as with other compounds . Oxygen is the most abundant element in Earth's crust , and
5989-449: The water cycle of evaporation , transpiration ( evapotranspiration ), condensation , precipitation, and runoff , usually reaching the sea. Water plays an important role in the world economy . Approximately 70% of the fresh water used by humans goes to agriculture . Fishing in salt and fresh water bodies has been, and continues to be, a major source of food for many parts of the world, providing 6.5% of global protein. Much of
6102-557: The 17th and the 18th century but none of them recognized it as a chemical element . This may have been in part due to the prevalence of the philosophy of combustion and corrosion called the phlogiston theory , which was then the favored explanation of those processes. Established in 1667 by the German alchemist J. J. Becher , and modified by the chemist Georg Ernst Stahl by 1731, phlogiston theory stated that all combustible materials were made of two parts. One part, called phlogiston,
6215-531: The 2s electrons, after sequential filling of the low σ and σ orbitals; σ overlap of the two atomic 2p orbitals that lie along the O–O molecular axis and π overlap of two pairs of atomic 2p orbitals perpendicular to the O–O molecular axis, and then cancellation of contributions from the remaining two 2p electrons after their partial filling of the π orbitals. This combination of cancellations and σ and π overlaps results in dioxygen's double-bond character and reactivity, and
6328-480: The American scientist Robert H. Goddard became the first person to develop a rocket engine that burned liquid fuel; the engine used gasoline for fuel and liquid oxygen as the oxidizer . Goddard successfully flew a small liquid-fueled rocket 56 m at 97 km/h on March 16, 1926, in Auburn, Massachusetts , US. In academic laboratories, oxygen can be prepared by heating together potassium chlorate mixed with
6441-444: The Earth was younger and less massive , water would have been lost to space more easily. Lighter elements like hydrogen and helium are expected to leak from the atmosphere continually, but isotopic ratios of heavier noble gases in the modern atmosphere suggest that even the heavier elements in the early atmosphere were subject to significant losses. In particular, xenon is useful for calculations of water loss over time. Not only
6554-538: The Indo-European root, with Greek ύδωρ ( ýdor ; from Ancient Greek ὕδωρ ( hýdōr ), whence English ' hydro- ' ), Russian вода́ ( vodá ), Irish uisce , and Albanian ujë . One factor in estimating when water appeared on Earth is that water is continually being lost to space. H 2 O molecules in the atmosphere are broken up by photolysis , and the resulting free hydrogen atoms can sometimes escape Earth's gravitational pull. When
6667-484: The Philosopher's Stone drawn from the source of nature and manual experience"] (1604) described a substance contained in air, referring to it as 'cibus vitae' (food of life, ) and according to Polish historian Roman Bugaj, this substance is identical with oxygen. Sendivogius, during his experiments performed between 1598 and 1604, properly recognized that the substance is equivalent to the gaseous byproduct released by
6780-438: The Sun's disk of protoplanetary material prior to the coalescence of dust grains that formed the Earth. Oxygen presents two spectrophotometric absorption bands peaking at the wavelengths 687 and 760 nm . Some remote sensing scientists have proposed using the measurement of the radiance coming from vegetation canopies in those bands to characterize plant health status from a satellite platform. This approach exploits
6893-493: The atmosphere. In the present equilibrium, production and consumption occur at the same rate. Free oxygen also occurs in solution in the world's water bodies. The increased solubility of O 2 at lower temperatures (see Physical properties ) has important implications for ocean life, as polar oceans support a much higher density of life due to their higher oxygen content. Water polluted with plant nutrients such as nitrates or phosphates may stimulate growth of algae by
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#17327826195427006-577: The bent structure, this gives the molecule an electrical dipole moment and it is classified as a polar molecule . Water is a good polar solvent , dissolving many salts and hydrophilic organic molecules such as sugars and simple alcohols such as ethanol . Water also dissolves many gases, such as oxygen and carbon dioxide —the latter giving the fizz of carbonated beverages, sparkling wines and beers. In addition, many substances in living organisms, such as proteins , DNA and polysaccharides , are dissolved in water. The interactions between water and
7119-537: The boiling point, but with the liquid/gas transition the vapor phase has a much lower density than the liquid phase, so the boiling point increases with pressure. Water can remain in a liquid state at high temperatures in the deep ocean or underground. For example, temperatures exceed 205 °C (401 °F) in Old Faithful , a geyser in Yellowstone National Park . In hydrothermal vents ,
7232-412: The bond order from three to two. Because of its unpaired electrons, triplet oxygen reacts only slowly with most organic molecules, which have paired electron spins; this prevents spontaneous combustion. In the triplet form, O 2 molecules are paramagnetic . That is, they impart magnetic character to oxygen when it is in the presence of a magnetic field, because of the spin magnetic moments of
7345-785: The chemical compound H 2 O ; it is also the liquid phase of H 2 O . The other two common states of matter of water are the solid phase, ice , and the gaseous phase, water vapor or steam . The addition or removal of heat can cause phase transitions : freezing (water to ice), melting (ice to water), vaporization (water to vapor), condensation (vapor to water), sublimation (ice to vapor) and deposition (vapor to ice). Water differs from most liquids in that it becomes less dense as it freezes. In 1 atm pressure, it reaches its maximum density of 999.972 kg/m (62.4262 lb/cu ft) at 3.98 °C (39.16 °F), or almost 1,000 kg/m (62.43 lb/cu ft) at almost 4 °C (39 °F). The density of ice
7458-433: The desired result. Conversely, a pressure cooker can be used to decrease cooking times by raising the boiling temperature. In a vacuum, water will boil at room temperature. On a pressure/temperature phase diagram (see figure), there are curves separating solid from vapor, vapor from liquid, and liquid from solid. These meet at a single point called the triple point , where all three phases can coexist. The triple point
7571-444: The diatomic elemental molecules in those gases. The first commercial method of producing oxygen was chemical, the so-called Brin process involving a reversible reaction of barium oxide . It was invented in 1852 and commercialized in 1884, but was displaced by newer methods in early 20th century. By the late 19th century scientists realized that air could be liquefied and its components isolated by compressing and cooling it. Using
7684-466: The electron spins are paired. It is much more reactive with common organic molecules than is normal (triplet) molecular oxygen. In nature, singlet oxygen is commonly formed from water during photosynthesis, using the energy of sunlight. It is also produced in the troposphere by the photolysis of ozone by light of short wavelength and by the immune system as a source of active oxygen. Carotenoids in photosynthetic organisms (and possibly animals) play
7797-572: The fact that the Englishman Priestley had first isolated the gas and written about it. This is partly due to a poem praising the gas titled "Oxygen" in the popular book The Botanic Garden (1791) by Erasmus Darwin , grandfather of Charles Darwin . John Dalton 's original atomic hypothesis presumed that all elements were monatomic and that the atoms in compounds would normally have the simplest atomic ratios with respect to one another. For example, Dalton assumed that water's formula
7910-399: The first known experiments on the relationship between combustion and air was conducted by the 2nd century BCE Greek writer on mechanics, Philo of Byzantium . In his work Pneumatica , Philo observed that inverting a vessel over a burning candle and surrounding the vessel's neck with water resulted in some water rising into the neck. Philo incorrectly surmised that parts of the air in
8023-486: The force of gravity . This property is relied upon by all vascular plants , such as trees. Water is a weak solution of hydronium hydroxide—there is an equilibrium 2H 2 O ⇌ H 3 O + OH , in combination with solvation of the resulting hydronium and hydroxide ions. Pure water has a low electrical conductivity , which increases with the dissolution of a small amount of ionic material such as common salt . Liquid water can be split into
8136-479: The form of snow . The gaseous state of water is steam or water vapor . Water covers about 71% of the Earth's surface, with seas and oceans making up most of the water volume (about 96.5%). Small portions of water occur as groundwater (1.7%), in the glaciers and the ice caps of Antarctica and Greenland (1.7%), and in the air as vapor , clouds (consisting of ice and liquid water suspended in air), and precipitation (0.001%). Water moves continually through
8249-450: The fundamental stretching absorption spectrum of water or of an aqueous solution in the region around 3,500 cm (2.85 μm) a path length of about 25 μm is needed. Also, the cuvette must be both transparent around 3500 cm and insoluble in water; calcium fluoride is one material that is in common use for the cuvette windows with aqueous solutions. The Raman-active fundamental vibrations may be observed with, for example,
8362-399: The idea; instead, it was based on observations of what happens when something burns, that most common objects appear to become lighter and seem to lose something in the process. Polish alchemist , philosopher , and physician Michael Sendivogius (Michał Sędziwój) in his work De Lapide Philosophorum Tractatus duodecim e naturae fonte et manuali experientia depromti ["Twelve Treatises on
8475-569: The large Cusco corn size. The most popular brand, CornNuts was owned by Holloway's original family company until the company was purchased by Nabisco in 1998. Cornnuts was a registered trademark of Kraft Foods . On February 11, 2021, Kraft sold the Planters and Corn Nuts brands to Hormel Foods . Corn Nuts are available in seven flavors: Original, Ranch, BBQ (barbecue-flavored), Chile Picante con Limon, Mexican Style Street Corn, Jalapeño Cheddar and Loaded Taco . A Filipino variant of corn nuts
8588-504: The letter was found in Scheele's belongings after his death). Lavoisier conducted the first adequate quantitative experiments on oxidation and gave the first correct explanation of how combustion works. He used these and similar experiments, all started in 1774, to discredit the phlogiston theory and to prove that the substance discovered by Priestley and Scheele was a chemical element . In one experiment, Lavoisier observed that there
8701-416: The liquid is known as boiling ). Sublimation and deposition also occur on surfaces. For example, frost is deposited on cold surfaces while snowflakes form by deposition on an aerosol particle or ice nucleus. In the process of freeze-drying , a food is frozen and then stored at low pressure so the ice on its surface sublimates. The melting and boiling points depend on pressure. A good approximation for
8814-753: The liquid or solid state can form up to four hydrogen bonds with neighboring molecules. Hydrogen bonds are about ten times as strong as the Van der Waals force that attracts molecules to each other in most liquids. This is the reason why the melting and boiling points of water are much higher than those of other analogous compounds like hydrogen sulfide. They also explain its exceptionally high specific heat capacity (about 4.2 J /(g·K)), heat of fusion (about 333 J/g), heat of vaporization ( 2257 J/g ), and thermal conductivity (between 0.561 and 0.679 W/(m·K)). These properties make water more effective at moderating Earth's climate , by storing heat and transporting it between
8927-1070: The long-distance trade of commodities (such as oil, natural gas, and manufactured products) is transported by boats through seas, rivers, lakes, and canals. Large quantities of water, ice, and steam are used for cooling and heating in industry and homes. Water is an excellent solvent for a wide variety of substances, both mineral and organic; as such, it is widely used in industrial processes and in cooking and washing. Water, ice, and snow are also central to many sports and other forms of entertainment, such as swimming , pleasure boating, boat racing , surfing , sport fishing , diving , ice skating , snowboarding , and skiing . The word water comes from Old English wæter , from Proto-Germanic * watar (source also of Old Saxon watar , Old Frisian wetir , Dutch water , Old High German wazzar , German Wasser , vatn , Gothic 𐍅𐌰𐍄𐍉 ( wato )), from Proto-Indo-European * wod-or , suffixed form of root * wed- ( ' water ' ; ' wet ' ). Also cognate , through
9040-428: The majority of these have half-lives that are less than 83 milliseconds. The most common decay mode of the isotopes lighter than O is β decay to yield nitrogen, and the most common mode for the isotopes heavier than O is beta decay to yield fluorine . Oxygen is the most abundant chemical element by mass in the Earth's biosphere , air, sea and land. Oxygen is the third most abundant chemical element in
9153-418: The most successful and biodiverse terrestrial clade , oxygen is directly conducted to the internal tissues via a deep network of airways . Many major classes of organic molecules in living organisms contain oxygen atoms, such as proteins , nucleic acids , carbohydrates and fats , as do the major constituent inorganic compounds of animal shells, teeth, and bone. Most of the mass of living organisms
9266-494: The nitroaereus must have combined with it. He also thought that the lungs separate nitroaereus from air and pass it into the blood and that animal heat and muscle movement result from the reaction of nitroaereus with certain substances in the body. Accounts of these and other experiments and ideas were published in 1668 in his work Tractatus duo in the tract "De respiratione". Robert Hooke , Ole Borch , Mikhail Lomonosov , and Pierre Bayen all produced oxygen in experiments in
9379-418: The oceans and the atmosphere. The hydrogen bonds of water are around 23 kJ/mol (compared to a covalent O-H bond at 492 kJ/mol). Of this, it is estimated that 90% is attributable to electrostatics, while the remaining 10% is partially covalent. These bonds are the cause of water's high surface tension and capillary forces. The capillary action refers to the tendency of water to move up a narrow tube against
9492-487: The oceans may have always been on the Earth since the beginning of the planet's formation . Water ( H 2 O ) is a polar inorganic compound . At room temperature it is a tasteless and odorless liquid , nearly colorless with a hint of blue . The simplest hydrogen chalcogenide , it is by far the most studied chemical compound and is sometimes described as the "universal solvent" for its ability to dissolve more substances than any other liquid, though it
9605-488: The oxygen atom at an angle of 104.45°. In liquid form, H 2 O is also called "water" at standard temperature and pressure . Because Earth's environment is relatively close to water's triple point , water exists on Earth as a solid , a liquid , and a gas . It forms precipitation in the form of rain and aerosols in the form of fog . Clouds consist of suspended droplets of water and ice , its solid state. When finely divided, crystalline ice may precipitate in
9718-454: The photosynthetic activities of autotrophs such as cyanobacteria , chloroplast -bearing algae and plants. A much rarer triatomic allotrope of oxygen , ozone ( O 3 ), strongly absorbs the UVB and UVC wavelengths and forms a protective ozone layer at the lower stratosphere , which shields the biosphere from ionizing ultraviolet radiation . However, ozone present at the surface
9831-402: The presence of water in their mouths, and frogs are known to be able to smell it. However, water from ordinary sources (including mineral water ) usually has many dissolved substances that may give it varying tastes and odors. Humans and other animals have developed senses that enable them to evaluate the potability of water in order to avoid water that is too salty or putrid . Pure water
9944-437: The pressure is 400 atm, water suffers only a 1.8% decrease in volume. The viscosity of water is about 10 Pa· s or 0.01 poise at 20 °C (68 °F), and the speed of sound in liquid water ranges between 1,400 and 1,540 metres per second (4,600 and 5,100 ft/s) depending on temperature. Sound travels long distances in water with little attenuation , especially at low frequencies (roughly 0.03 dB /km for 1 k Hz ),
10057-587: The rate of change of the melting temperature with pressure is given by the Clausius–Clapeyron relation : d T d P = T ( v L − v S ) L f {\displaystyle {\frac {dT}{dP}}={\frac {T\left(v_{\text{L}}-v_{\text{S}}\right)}{L_{\text{f}}}}} where v L {\displaystyle v_{\text{L}}} and v S {\displaystyle v_{\text{S}}} are
10170-458: The remainder of this article. Trioxygen ( O 3 ) is usually known as ozone and is a very reactive allotrope of oxygen that is damaging to lung tissue. Ozone is produced in the upper atmosphere when O 2 combines with atomic oxygen made by the splitting of O 2 by ultraviolet (UV) radiation. Since ozone absorbs strongly in the UV region of the spectrum , the ozone layer of
10283-414: The seawater left behind tends to be higher in oxygen-18. Marine organisms then incorporate more oxygen-18 into their skeletons and shells than they would in a warmer climate. Paleoclimatologists also directly measure this ratio in the water molecules of ice core samples as old as hundreds of thousands of years. Planetary geologists have measured the relative quantities of oxygen isotopes in samples from
10396-413: The subunits of these biomacromolecules shape protein folding , DNA base pairing , and other phenomena crucial to life ( hydrophobic effect ). Many organic substances (such as fats and oils and alkanes ) are hydrophobic , that is, insoluble in water. Many inorganic substances are insoluble too, including most metal oxides , sulfides , and silicates . Because of its polarity, a molecule of water in
10509-488: The surface of a planet is called the hydrosphere . Earth's approximate water volume (the total water supply of the world) is 1.386 billion cubic kilometres (333 million cubic miles). Liquid water is found in bodies of water , such as an ocean, sea, lake, river, stream, canal , pond, or puddle . The majority of water on Earth is seawater . Water is also present in the atmosphere in solid, liquid, and vapor states. It also exists as groundwater in aquifers . Water
10622-537: The surface temperature of 230 °C (446 °F) due to the increased atmospheric pressure of the CO 2 atmosphere. As the cooling continued, most CO 2 was removed from the atmosphere by subduction and dissolution in ocean water, but levels oscillated wildly as new surface and mantle cycles appeared. Geological evidence also helps constrain the time frame for liquid water existing on Earth. A sample of pillow basalt (a type of rock formed during an underwater eruption)
10735-403: The temperature can exceed 400 °C (752 °F). At sea level , the boiling point of water is 100 °C (212 °F). As atmospheric pressure decreases with altitude, the boiling point decreases by 1 °C every 274 meters. High-altitude cooking takes longer than sea-level cooking. For example, at 1,524 metres (5,000 ft), cooking time must be increased by a fourth to achieve
10848-475: The third-most abundant element in the universe after hydrogen and helium . At standard temperature and pressure , two oxygen atoms will bind covalently to form dioxygen , a colorless and odorless diatomic gas with the chemical formula O 2 . Dioxygen gas currently constitutes 20.95% molar fraction of the Earth's atmosphere , though this has changed considerably over long periods of time in Earth's history . Oxygen makes up almost half of
10961-486: The universe, after hydrogen and helium. About 0.9% of the Sun 's mass is oxygen. Oxygen constitutes 49.2% of the Earth's crust by mass as part of oxide compounds such as silicon dioxide and is the most abundant element by mass in the Earth's crust . It is also the major component of the world's oceans (88.8% by mass). Oxygen gas is the second most common component of the Earth's atmosphere , taking up 20.8% of its volume and 23.1% of its mass (some 10 tonnes). Earth
11074-401: The unpaired electrons in the molecule, and the negative exchange energy between neighboring O 2 molecules. Liquid oxygen is so magnetic that, in laboratory demonstrations, a bridge of liquid oxygen may be supported against its own weight between the poles of a powerful magnet. Singlet oxygen is a name given to several higher-energy species of molecular O 2 in which all
11187-435: The upper atmosphere functions as a protective radiation shield for the planet. Near the Earth's surface, it is a pollutant formed as a by-product of automobile exhaust . At low earth orbit altitudes, sufficient atomic oxygen is present to cause corrosion of spacecraft . The metastable molecule tetraoxygen ( O 4 ) was discovered in 2001, and was assumed to exist in one of the six phases of solid oxygen . It
11300-458: The upper atmosphere. As the pressure increases, ice forms other crystal structures . As of 2024, twenty have been experimentally confirmed and several more are predicted theoretically. The eighteenth form of ice, ice XVIII , a face-centred-cubic, superionic ice phase, was discovered when a droplet of water was subject to a shock wave that raised the water's pressure to millions of atmospheres and its temperature to thousands of degrees, resulting in
11413-451: The vessel were converted into the classical element fire and thus were able to escape through pores in the glass. Many centuries later Leonardo da Vinci built on Philo's work by observing that a portion of air is consumed during combustion and respiration . In the late 17th century, Robert Boyle proved that air is necessary for combustion. English chemist John Mayow (1641–1679) refined this work by showing that fire requires only
11526-441: The winter. Water is a diamagnetic material. Though interaction is weak, with superconducting magnets it can attain a notable interaction. At a pressure of one atmosphere (atm), ice melts or water freezes (solidifies) at 0 °C (32 °F) and water boils or vapor condenses at 100 °C (212 °F). However, even below the boiling point, water can change to vapor at its surface by evaporation (vaporization throughout
11639-428: Was HO, leading to the conclusion that the atomic mass of oxygen was 8 times that of hydrogen, instead of the modern value of about 16. In 1805, Joseph Louis Gay-Lussac and Alexander von Humboldt showed that water is formed of two volumes of hydrogen and one volume of oxygen; and by 1811 Amedeo Avogadro had arrived at the correct interpretation of water's composition, based on what is now called Avogadro's law and
11752-408: Was first discovered by Swedish pharmacist Carl Wilhelm Scheele . He had produced oxygen gas by heating mercuric oxide (HgO) and various nitrates in 1771–72. Scheele called the gas "fire air" because it was then the only known agent to support combustion. He wrote an account of this discovery in a manuscript titled Treatise on Air and Fire , which he sent to his publisher in 1775. That document
11865-451: Was given off when the substance containing it was burned, while the dephlogisticated part was thought to be its true form, or calx . Highly combustible materials that leave little residue , such as wood or coal, were thought to be made mostly of phlogiston; non-combustible substances that corrode, such as iron, contained very little. Air did not play a role in phlogiston theory, nor were any initial quantitative experiments conducted to test
11978-491: Was independently developed in 1895 by German engineer Carl von Linde and British engineer William Hampson . Both men lowered the temperature of air until it liquefied and then distilled the component gases by boiling them off one at a time and capturing them separately. Later, in 1901, oxyacetylene welding was demonstrated for the first time by burning a mixture of acetylene and compressed O 2 . This method of welding and cutting metal later became common. In 1923,
12091-445: Was no overall increase in weight when tin and air were heated in a closed container. He noted that air rushed in when he opened the container, which indicated that part of the trapped air had been consumed. He also noted that the tin had increased in weight and that increase was the same as the weight of the air that rushed back in. This and other experiments on combustion were documented in his book Sur la combustion en général , which
12204-465: Was not sensibly different from that of common air , but I fancied that my breast felt peculiarly light and easy for some time afterwards." Priestley published his findings in 1775 in a paper titled "An Account of Further Discoveries in Air", which was included in the second volume of his book titled Experiments and Observations on Different Kinds of Air . Because he published his findings first, Priestley
12317-408: Was proven in 2006 that this phase, created by pressurizing O 2 to 20 GPa , is in fact a rhombohedral O 8 cluster . This cluster has the potential to be a much more powerful oxidizer than either O 2 or O 3 and may therefore be used in rocket fuel . A metallic phase was discovered in 1990 when solid oxygen is subjected to a pressure of above 96 GPa and it
12430-504: Was published in 1777. In the meantime, on August 1, 1774, an experiment conducted by the British clergyman Joseph Priestley focused sunlight on mercuric oxide contained in a glass tube, which liberated a gas he named "dephlogisticated air". He noted that candles burned brighter in the gas and that a mouse was more active and lived longer while breathing it. After breathing the gas himself, Priestley wrote: "The feeling of it to my lungs
12543-462: Was published in 1777. In that work, he proved that air is a mixture of two gases; 'vital air', which is essential to combustion and respiration, and azote (Gk. ἄζωτον "lifeless"), which did not support either. Azote later became nitrogen in English, although it has kept the earlier name in French and several other European languages. Lavoisier renamed 'vital air' to oxygène in 1777 from
12656-809: Was recovered from the Isua Greenstone Belt and provides evidence that water existed on Earth 3.8 billion years ago. In the Nuvvuagittuq Greenstone Belt , Quebec, Canada, rocks dated at 3.8 billion years old by one study and 4.28 billion years old by another show evidence of the presence of water at these ages. If oceans existed earlier than this, any geological evidence has yet to be discovered (which may be because such potential evidence has been destroyed by geological processes like crustal recycling ). More recently, in August 2020, researchers reported that sufficient water to fill
12769-420: Was shown in 1998 that at very low temperatures, this phase becomes superconducting . Oxygen dissolves more readily in water than nitrogen, and in freshwater more readily than in seawater. Water in equilibrium with air contains approximately 1 molecule of dissolved O 2 for every 2 molecules of N 2 (1:2), compared with an atmospheric ratio of approximately 1:4. The solubility of oxygen in water
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