Polyether ether ketone ( PEEK ) is a colourless organic thermoplastic polymer in the polyaryletherketone (PAEK) family, used in engineering applications. It was invented in November 1978 and brought to market in the early 1980s by part of Imperial Chemical Industries (ICI) that later became Victrex PLC .
108-697: Carbon fiber-reinforced polymers ( American English ), carbon-fibre-reinforced polymers ( Commonwealth English ), carbon-fiber-reinforced plastics , carbon-fiber reinforced-thermoplastic ( CFRP , CRP , CFRTP ), also known as carbon fiber , carbon composite , or just carbon , are extremely strong and light fiber-reinforced plastics that contain carbon fibers . CFRPs can be expensive to produce, but are commonly used wherever high strength-to-weight ratio and stiffness (rigidity) are required, such as aerospace, superstructures of ships, automotive, civil engineering, sports equipment, and an increasing number of consumer and technical applications. The binding polymer
216-707: A cot–caught merger , which is rapidly spreading throughout the whole country. However, the South, Inland North, and a Northeastern coastal corridor passing through Rhode Island, New York City, Philadelphia, and Baltimore typically preserve an older cot–caught distinction. For that Northeastern corridor, the realization of the THOUGHT vowel is particularly marked , as depicted in humorous spellings, like in tawk and cawfee ( talk and coffee ), which intend to represent it being tense and diphthongal : [oə] . A split of TRAP into two separate phonemes , using different
324-520: A pronunciations for example in gap [æ] versus gas [eə] , further defines New York City as well as Philadelphia–Baltimore accents. Most Americans preserve all historical /r/ sounds, using what is known as a rhotic accent . The only traditional r -dropping (or non-rhoticity) in regional U.S. accents variably appears today in eastern New England , New York City , and some of the former plantation South primarily among older speakers (and, relatedly, some African-American Vernacular English across
432-438: A vacuum bag can be used. A fiberglass, carbon fiber, or aluminum mold is polished and waxed, and has a release agent applied before the fabric and resin are applied, and the vacuum is pulled and set aside to allow the piece to cure (harden). There are three ways to apply the resin to the fabric in a vacuum mold. The first method is manual and called a wet layup, where the two-part resin is mixed and applied before being laid in
540-399: A 2/2 weave. The process by which most CFRPs are made varies, depending on the piece being created, the finish (outside gloss) required, and how many of the piece will be produced. In addition, the choice of matrix can have a profound effect on the properties of the finished composite. Many CFRP parts are created with a single layer of carbon fabric that is backed with fiberglass. A tool called
648-435: A central wing-box made of CFRP; it is the first to have a smoothly contoured wing cross-section instead of the wings being partitioned span-wise into sections. This flowing, continuous cross section optimises aerodynamic efficiency. Moreover, the trailing edge, along with the rear bulkhead, empennage , and un-pressurised fuselage are made of CFRP. However, many delays have pushed order delivery dates back because of problems with
756-446: A chopper gun is used to quickly create these composite parts. Once a thin shell is created out of carbon fiber, the chopper gun cuts rolls of fiberglass into short lengths and sprays resin at the same time, so that the fiberglass and resin are mixed on the spot. The resin is either external mix, wherein the hardener and resin are sprayed separately, or internal mixed, which requires cleaning after every use. Manufacturing methods may include
864-631: A complex phenomenon of "both convergence and divergence": some accents are homogenizing and leveling , while others are diversifying and deviating further away from one another. Having been settled longer than the American West Coast, the East Coast has had more time to develop unique accents, and it currently comprises three or four linguistically significant regions, each of which possesses English varieties both different from each other as well as quite internally diverse: New England ,
972-447: A consonant, such as in pearl , car and fort . Non-rhotic American accents, those that do not pronounce ⟨r⟩ except before a vowel, such as some accents of Eastern New England , New York City , and African-Americans , and a specific few (often older ones) spoken by Southerners , are often quickly noticed by General American listeners and perceived as sounding especially ethnic, regional, or antiquated. Rhoticity
1080-464: A core. Applications for CFRPs include the following: The Airbus A350 XWB is built of 53% CFRP including wing spars and fuselage components, overtaking the Boeing 787 Dreamliner , for the aircraft with the highest weight ratio for CFRP, which is 50%. This was one of the first commercial aircraft to have wing spars made from composites. The Airbus A380 was one of the first commercial airliners to have
1188-591: A merger with the THOUGHT ( caught ) set. Having taken place prior to the unrounding of the cot vowel, it results in lengthening and perhaps raising, merging the more recently separated vowel into the THOUGHT vowel in the following environments: before many instances of /f/ , /θ/ , and particularly /s/ (as in Austria, cloth, cost, loss, off, often, etc.), a few instances before /ŋ/ (as in strong, long, wrong ), and variably by region or speaker in gone , on , and certain other words. Unlike American accents,
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#17327913992121296-505: A mold, with epoxy either pre-impregnated into the fibers (also known as pre-preg ) or "painted" over it. High-performance parts using single molds are often vacuum-bagged and/or autoclave -cured, because even small air bubbles in the material will reduce strength. An alternative to the autoclave method is to use internal pressure via inflatable air bladders or EPS foam inside the non-cured laid-up carbon fiber. For simple pieces of which relatively few copies are needed (one or two per day),
1404-636: A nice day , for sure); many are now distinctly old-fashioned (swell, groovy). Some English words now in general use, such as hijacking, disc jockey , boost, bulldoze and jazz , originated as American slang. American English has always shown a marked tendency to use words in different parts of speech and nouns are often used as verbs . Examples of nouns that are now also verbs are interview, advocate, vacuum, lobby, pressure, rear-end, transition, feature, profile, hashtag, head, divorce, loan, estimate, X-ray, spearhead, skyrocket, showcase, bad-mouth, vacation , major, and many others. Compounds coined in
1512-432: A number of field applications strengthening concrete, masonry, steel, cast iron, and timber structures. Their use in industry can be either for retrofitting to strengthen an existing structure or as an alternative reinforcing (or prestressing) material instead of steel from the outset of a project. Retrofitting has become the increasingly dominant use of the material in civil engineering, and applications include increasing
1620-480: A process of extensive dialect mixture and leveling in which English varieties across the colonies became more homogeneous compared with the varieties in Britain. English thus predominated in the colonies even by the end of the 17th century's first immigration of non-English speakers from Western Europe and Africa. Additionally, firsthand descriptions of a fairly uniform American English (particularly in contrast to
1728-422: A refinery in a one-step process. Capture and reuse of the carbon and monomers is then possible. CFRPs can also be milled or shredded at low temperature to reclaim the carbon fiber; however, this process shortens the fibers dramatically. Just as with downcycled paper, the shortened fibers cause the recycled material to be weaker than the original material. There are still many industrial applications that do not need
1836-680: A series of other vowel shifts in the same region, known by linguists as the " Inland North ". The Inland North shares with the Eastern New England dialect (including Boston accents ) a backer tongue positioning of the GOOSE /u/ vowel (to [u] ) and the MOUTH /aʊ/ vowel (to [ɑʊ~äʊ] ) in comparison to the rest of the country. Ranging from northern New England across the Great Lakes to Minnesota, another Northern regional marker
1944-719: A single carbon fiber with diameter of 5–7 μm is sealed in a glass capillary. At the tip the capillary is either sealed with epoxy and polished to make carbon-fiber disk microelectrode or the fiber is cut to a length of 75–150 μm to make carbon-fiber cylinder electrode. Carbon-fiber microelectrodes are used either in amperometry or fast-scan cyclic voltammetry for detection of biochemical signalling. CFRPs are now widely used in sports equipment such as in squash, tennis, and badminton racquets, sport kite spars, high-quality arrow shafts, hockey sticks, fishing rods, surfboards , high end swim fins, and rowing shells . Amputee athletes such as Jonnie Peacock use carbon fiber blades for running. It
2052-525: A survey, completed in 2003, polling English speakers across the United States about their specific everyday word choices, hoping to identify regionalisms. The study found that most Americans prefer the term sub for a long sandwich, soda (but pop in the Great Lakes region and generic coke in the South) for a sweet and bubbly soft drink , you or you guys for the plural of you (but y'all in
2160-459: A useful operating temperature of up to 250 °C (482 °F). The thermal conductivity increases nearly linearly with temperature between room temperature and solidus temperature. It is highly resistant to thermal degradation , as well as to attack by both organic and aqueous environments. It is attacked by halogens and strong Brønsted and Lewis acids , as well as some halogenated compounds and aliphatic hydrocarbons at high temperatures. It
2268-453: A variation of American English in these islands. In 2021, about 245 million Americans, aged 5 or above, spoke English at home: a majority of the United States total population of roughly 330 million people. The United States has never had an official language at the federal level, but English is commonly used at the federal level and in states without an official language. 32 of the 50 states, in some cases as part of what has been called
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#17327913992122376-477: Is a semicrystalline thermoplastic with excellent mechanical and chemical resistance properties that are retained to high temperatures. The processing conditions used to mould PEEK can influence the crystallinity and hence the mechanical properties. Its Young's modulus is 3.6 GPa and its tensile strength is 90 to 100 MPa. PEEK has a glass transition temperature of around 143 °C (289 °F) and melts around 343 °C (662 °F). Some grades have
2484-654: Is also associated with the United States, perhaps mostly in the Midwest and the South. American accents that have not undergone the cot–caught merger (the lexical sets LOT and THOUGHT ) have instead retained a LOT – CLOTH split : a 17th-century distinction in which certain words (labeled as the CLOTH lexical set ) separated away from the LOT set. The split, which has now reversed in most British English, simultaneously shifts this relatively recent CLOTH set into
2592-664: Is also home to a creole language known commonly as Hawaiian Pidgin , and some Hawaii residents speak English with a Pidgin-influenced accent. American English also gave rise to some dialects outside the country, for example, Philippine English , beginning during the American occupation of the Philippines and subsequently the Insular Government of the Philippine Islands ; Thomasites first established
2700-436: Is also used in fused filament fabrication (FFF) printing to thermally separate the hot end from the cold end. PEEK melts at a relatively high temperature (343 °C / 649.4 °F) compared to most other thermoplastics. In the range of its melting temperature it can be processed using injection moulding or extrusion methods. It is technically feasible to process granular PEEK into filament form and 3D printing parts from
2808-538: Is common in most American accents despite being now rare in England because, during the 17th-century British colonization, nearly all dialects of English were rhotic, and most North American English simply remained that way. The preservation of rhoticity in North America was also supported by continuing waves of rhotic-accented Scotch-Irish immigrants, most intensely during the 18th century (and moderately during
2916-414: Is commonly used to produce high-quality plastic parts that are thermostable and both electrically and thermally insulating. Filled grades of PEEK can also be CNC machined, but special care must be taken to properly manage stresses in the material. PEEK is a high-performance polymer , but its high price, due to its complex production process, restricts its use to only the most demanding applications. PEEK
3024-408: Is dependent on the fiber orientation and machining condition of the cutting process. To reduce tool wear various types of coated tools are used in machining CFRP and CFRP-metal stack. The primary element of CFRPs is a carbon filament ; this is produced from a precursor polymer such as polyacrylonitrile (PAN), rayon , or petroleum pitch . For synthetic polymers such as PAN or rayon, the precursor
3132-438: Is first spun into filament yarns, using chemical and mechanical processes to initially align the polymer chains in a way to enhance the final physical properties of the completed carbon fiber. Precursor compositions and mechanical processes used during spinning filament yarns may vary among manufacturers. After drawing or spinning, the polymer filament yarns are then heated to drive off non-carbon atoms ( carbonization ), producing
3240-518: Is mitigated by the material's unsurpassed strength-to-weight ratio, and low weight is essential for high-performance automobile racing. Race-car manufacturers have also developed methods to give carbon fiber pieces strength in a certain direction, making it strong in a load-bearing direction, but weak in directions where little or no load would be placed on the member. Conversely, manufacturers developed omnidirectional carbon fiber weaves that apply strength in all directions. This type of carbon fiber assembly
3348-617: Is most widely used in the "safety cell" monocoque chassis assembly of high-performance race-cars. The first carbon fiber monocoque chassis was introduced in Formula One by McLaren in the 1981 season. It was designed by John Barnard and was widely copied in the following seasons by other F1 teams due to the extra rigidity provided to the chassis of the cars. Many supercars over the past few decades have incorporated CFRPs extensively in their manufacture, using it for their monocoque chassis as well as other components. As far back as 1971,
Carbon-fiber reinforced polymer - Misplaced Pages Continue
3456-412: Is much more difficult to process and more expensive. Despite their high initial strength-to-weight ratios, a design limitation of CFRPs are their lack of a definable fatigue limit . This means, theoretically, that stress cycle failure cannot be ruled out. While steel and many other structural metals and alloys do have estimable fatigue or endurance limits, the complex failure modes of composites mean that
3564-408: Is often a thermoset resin such as epoxy , but other thermoset or thermoplastic polymers, such as polyester , vinyl ester , or nylon, are sometimes used. The properties of the final CFRP product can be affected by the type of additives introduced to the binding matrix (resin). The most common additive is silica , but other additives such as rubber and carbon nanotubes can be used. Carbon fiber
3672-420: Is often identified by Americans as a "country" accent, and is defined by the /aɪ/ vowel losing its gliding quality : [aː] , the initiation event for a complicated Southern vowel shift, including a " Southern drawl " that makes short front vowels into distinct-sounding gliding vowels . The fronting of the vowels of GOOSE , GOAT , MOUTH , and STRUT tends to also define Southern accents as well as
3780-632: Is one of the few plastics compatible with ultra-high vacuum applications, which makes it suitable for aerospace, automotive, and chemical industries. PEEK is used in medical implants , for example in creating a partial replacement skull in neurosurgical applications. PEEK is used in spinal fusion devices and reinforcing rods. It is radiolucent , but it is hydrophobic causing it to not fully fuse with bone. PEEK seals and manifolds are commonly used in fluid applications. PEEK also performs well in high temperature applications (up to 260 °C/500 °F). Because of this and its low thermal conductivity, it
3888-494: Is several times stronger and tougher than typical CFRPs and is used in the Lockheed Martin F-35 Lightning II as a structural material for aircraft. CNRP still uses carbon fiber as the primary reinforcement, but the binding matrix is a carbon nanotube-filled epoxy. American English American English , sometimes called United States English or U.S. English , is the set of varieties of
3996-645: Is significantly improved if a thin layer of carbon fibers is moulded near the surface because a dense, compact layer of carbon fibers efficiently reflects heat. CFRPs are being used in an increasing number of high-end products that require stiffness and low weight, these include: CFRPs have a long service lifetime when protected from the sun. When it is time to decommission CFRPs, they cannot be melted down in air like many metals. When free of vinyl (PVC or polyvinyl chloride ) and other halogenated polymers, CFRPs can be thermally decomposed via thermal depolymerization in an oxygen-free environment. This can be accomplished in
4104-486: Is soluble in concentrated sulfuric acid at room temperature, although dissolution can take a very long time unless the polymer is in a form with a high surface-area-to-volume ratio, such as a fine powder or thin film. It has high resistance to biodegradation. PEEK is used to fabricate items for demanding applications, including bearings , piston parts, pumps , high-performance liquid chromatography columns, compressor plate valves , and electrical cable insulation . It
4212-442: Is sometimes referred to as graphite-reinforced polymer or graphite fiber-reinforced polymer ( GFRP is less common, as it clashes with glass-(fiber)-reinforced polymer ). CFRP are composite materials . In this case the composite consists of two parts: a matrix and a reinforcement. In CFRP the reinforcement is carbon fiber, which provides its strength. The matrix is usually a thermosetting plastic, such as polyester resin, to bind
4320-500: Is the common language at home, in public, and in government. Polyether ether ketone PEEK polymers are obtained by step-growth polymerization by the di alkylation of bis phenolate salts. Typical is the reaction of 4,4'-difluorobenzophenone with the disodium salt of hydroquinone , which is generated in situ by deprotonation with sodium carbonate . The reaction is conducted around 300 °C in polar aprotic solvents - such as diphenyl sulfone . [REDACTED] PEEK
4428-401: Is the total composite modulus, V m {\displaystyle V_{m}} and V f {\displaystyle V_{f}} are the volume fractions of the matrix and fiber respectively in the composite, and E m {\displaystyle E_{m}} and E f {\displaystyle E_{f}} are the elastic moduli of
Carbon-fiber reinforced polymer - Misplaced Pages Continue
4536-469: Is the variable fronting of /ɑ/ before /r/ , for example, appearing four times in the stereotypical Boston shibboleth Park the car in Harvard Yard . Several other phenomena serve to distinguish regional U.S. accents. Boston , Pittsburgh , Upper Midwestern , and Western U.S. accents have fully completed a merger of the LOT vowel with the THOUGHT vowel ( /ɑ/ and /ɔ/ , respectively):
4644-436: Is typical). As a consequence, only small cross-sectional areas of the material are used. Small areas of very high strength but moderate stiffness material will significantly increase strength, but not stiffness. CFRPs can also be used to enhance shear strength of reinforced concrete by wrapping fabrics or fibers around the section to be strengthened. Wrapping around sections (such as bridge or building columns) can also enhance
4752-412: Is used as a shank plate in some basketball sneakers to keep the foot stable, usually running the length of the shoe just above the sole and left exposed in some areas, usually in the arch. Controversially, in 2006, cricket bats with a thin carbon-fiber layer on the back were introduced and used in competitive matches by high-profile players including Ricky Ponting and Michael Hussey . The carbon fiber
4860-637: The Citroën SM offered optional lightweight carbon fiber wheels. Use of the material has been more readily adopted by low-volume manufacturers who used it primarily for creating body-panels for some of their high-end cars due to its increased strength and decreased weight compared with the glass-reinforced polymer they used for the majority of their products. CFRPs have become a notable material in structural engineering applications. Studied in an academic context as to their potential benefits in construction, CFRPs have also proved themselves cost-effective in
4968-611: The English language native to the United States. English is the most widely spoken language in the United States ; the de facto common language used in government, education, and commerce; and an official language in 32 of the 50 U.S. states . Since the late 20th century, American English has become the most influential form of English worldwide. Varieties of American English include many patterns of pronunciation, vocabulary, grammar and particularly spelling that are unified nationwide but distinct from other English dialects around
5076-482: The English-only movement , have adopted legislation granting official or co-official status to English. Typically only "English" is specified, not a particular variety like American English. (From 1923 to 1969, the state of Illinois recognized its official language as "American", meaning American English.) Puerto Rico is the largest example of a United States territory in which another language – Spanish –
5184-622: The Mid-Atlantic states (including a New York accent as well as a unique Philadelphia–Baltimore accent ), and the South . As of the 20th century, the middle and eastern Great Lakes area , Chicago being the largest city with these speakers, also ushered in certain unique features, including the fronting of the LOT /ɑ/ vowel in the mouth toward [a] and tensing of the TRAP /æ/ vowel wholesale to [eə] . These sound changes have triggered
5292-551: The Native American languages . Examples of such names are opossum , raccoon , squash , moose (from Algonquian ), wigwam , and moccasin . American English speakers have integrated traditionally non-English terms and expressions into the mainstream cultural lexicon; for instance, en masse , from French ; cookie , from Dutch ; kindergarten from German , and rodeo from Spanish . Landscape features are often loanwords from French or Spanish, and
5400-591: The brittle nature of CFRPs, in contrast to the ductility of steel. Though design codes have been drawn up by institutions such as the American Concrete Institute , there remains some hesitation among the engineering community about implementing these alternative materials. In part, this is due to a lack of standardization and the proprietary nature of the fiber and resin combinations on the market. Carbon fibers are used for fabrication of carbon-fiber microelectrodes . In this application typically
5508-478: The ductility of the section, greatly increasing the resistance to collapse under dynamic loading. Such 'seismic retrofit' is the major application in earthquake-prone areas, since it is much more economic than alternative methods. If a column is circular (or nearly so) an increase in axial capacity is also achieved by wrapping. In this application, the confinement of the CFRP wrap enhances the compressive strength of
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#17327913992125616-722: The francophile tastes of the 19th century Victorian era Britain (for example they preferred programme for program , manoeuvre for maneuver , cheque for check , etc.). AmE almost always uses -ize in words like realize . BrE prefers -ise , but also uses -ize on occasion (see: Oxford spelling ). There are a few differences in punctuation rules. British English is more tolerant of run-on sentences , called " comma splices " in American English, and American English prefers that periods and commas be placed inside closing quotation marks even in cases in which British rules would place them outside. American English also favors
5724-764: The 18th century; apartment , shanty in the 19th century; project, condominium , townhouse , mobile home in the 20th century; and parts thereof ( driveway , breezeway, backyard ) . Industry and material innovations from the 19th century onwards provide distinctive new words, phrases, and idioms through railroading (see further at rail terminology ) and transportation terminology, ranging from types of roads ( dirt roads , freeways ) to infrastructure ( parking lot , overpass , rest area ), to automotive terminology often now standard in English internationally. Already existing English words—such as store , shop , lumber —underwent shifts in meaning; others remained in
5832-546: The 20th century. The use of English in the United States is a result of British colonization of the Americas . The first wave of English-speaking settlers arrived in North America during the early 17th century, followed by further migrations in the 18th and 19th centuries. During the 17th and 18th centuries, dialects from many different regions of England and the British Isles existed in every American colony, allowing
5940-627: The British form is a back-formation , such as AmE burglarize and BrE burgle (from burglar ). However, while individuals usually use one or the other, both forms will be widely understood and mostly used alongside each other within the two systems. While written American English is largely standardized across the country and spoken American English dialects are highly mutually intelligible, there are still several recognizable regional and ethnic accents and lexical distinctions. The regional sounds of present-day American English are reportedly engaged in
6048-413: The East Coast (perhaps in imitation of 19th-century London speech), even the East Coast has gradually begun to restore rhoticity, due to it becoming nationally prestigious in the 20th century. The pronunciation of ⟨r⟩ is a postalveolar approximant [ ɹ̠ ] or retroflex approximant [ ɻ ] , but a unique "bunched tongue" variant of the approximant r sound
6156-571: The Inland North. Rather than one particular accent, General American is best defined as an umbrella covering an American accent that does not incorporate features associated with some particular region, ethnicity, or socioeconomic group. Typical General American features include rhoticity , the father–bother merger , Mary–marry–merry merger , pre-nasal "short a " tensing , and other particular vowel sounds . General American features are embraced most by Americans who are highly educated or in
6264-573: The South), sneakers for athletic shoes (but often tennis shoes outside the Northeast), and shopping cart for a cart used for carrying supermarket goods. American English and British English (BrE) often differ at the levels of phonology, phonetics, vocabulary, and, to a much lesser extent, grammar and orthography. The first large American dictionary, An American Dictionary of the English Language , known as Webster's Dictionary ,
6372-528: The U.S. Several verbs ending in -ize are of U.S. origin; for example, fetishize, prioritize, burglarize, accessorize, weatherize , etc.; and so are some back-formations (locate, fine-tune, curate, donate, emote, upholster and enthuse). Among syntactic constructions that arose are outside of, headed for, meet up with, back of, etc. Americanisms formed by alteration of some existing words include notably pesky, phony, rambunctious, buddy, sundae , skeeter, sashay and kitty-corner. Adjectives that arose in
6480-570: The U.S. are for instance foothill , landslide (in all senses), backdrop , teenager , brainstorm , bandwagon , hitchhike , smalltime, and a huge number of others. Other compound words have been founded based on industrialization and the wave of the automobile: five-passenger car, four-door sedan, two-door sedan, and station-wagon (called an estate car in British English). Some are euphemistic ( human resources , affirmative action , correctional facility ). Many compound nouns have
6588-676: The U.S. are, for example, lengthy, bossy, cute and cutesy, punk (in all senses), sticky (of the weather), through (as in "finished"), and many colloquial forms such as peppy or wacky . A number of words and meanings that originated in Middle English or Early Modern English and that have been in everyday use in the United States have since disappeared in most varieties of British English; some of these have cognates in Lowland Scots . Terms such as fall ("autumn"), faucet ("tap"), diaper ("nappy"; itself unused in
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#17327913992126696-530: The U.S. while changing in Britain. Science, urbanization, and democracy have been important factors in bringing about changes in the written and spoken language of the United States. From the world of business and finance came new terms ( merger , downsize , bottom line ), from sports and gambling terminology came, specific jargon aside, common everyday American idioms, including many idioms related to baseball . The names of some American inventions remained largely confined to North America ( elevator [except in
6804-427: The U.S.), candy ("sweets"), skillet , eyeglasses , and obligate are often regarded as Americanisms. Fall for example came to denote the season in 16th century England, a contraction of Middle English expressions like "fall of the leaf" and "fall of the year." Gotten ( past participle of get ) is often considered to be largely an Americanism. Other words and meanings were brought back to Britain from
6912-597: The U.S., especially in the second half of the 20th century; these include hire ("to employ"), I guess (famously criticized by H. W. Fowler ), baggage , hit (a place), and the adverbs overly and presently ("currently"). Some of these, for example, monkey wrench and wastebasket , originated in 19th century Britain. The adjectives mad meaning "angry", smart meaning "intelligent", and sick meaning "ill" are also more frequent in American (and Irish) English than British English. Linguist Bert Vaux created
7020-538: The United States and the United Kingdom suggest that, while spoken American English deviated away from period British English in many ways, it is conservative in a few other ways, preserving certain features 21st-century British English has since lost. Full rhoticity (or "R-fulness") is typical of American accents, pronouncing the phoneme /r/ (corresponding to the letter ⟨r⟩ ) in all environments, including in syllable-final position or before
7128-605: The West and Midwest, and New York Latino English , spoken in the New York metropolitan area . Additionally, ethnic varieties such as Yeshiva English and " Yinglish " are spoken by some American Orthodox Jews , Cajun Vernacular English by some Cajuns in southern Louisiana , and Pennsylvania Dutch English by some Pennsylvania Dutch people. American Indian Englishes have been documented among diverse Indian tribes. The island state of Hawaii , though primarily English-speaking,
7236-555: The accents spoken in the " Midland ": a vast band of the country that constitutes an intermediate dialect region between the traditional North and South. Western U.S. accents mostly fall under the General American spectrum. Below, ten major American English accents are defined by their particular combinations of certain vowel sounds: In 2010, William Labov noted that Great Lakes, Philadelphia, Pittsburgh, and West Coast accents have undergone "vigorous new sound changes" since
7344-505: The aeronautical sense ], gasoline ) as did certain automotive terms ( truck , trunk ). New foreign loanwords came with 19th and early 20th century European immigration to the U.S.; notably, from Yiddish ( chutzpah , schmooze, bupkis, glitch ) and German ( hamburger , wiener ). A large number of English colloquialisms from various periods are American in origin; some have lost their American flavor (from OK and cool to nerd and 24/7 ), while others have not ( have
7452-424: The brittle fracture mechanics presents unique challenges to engineers in failure detection since failure occurs catastrophically. As such, recent efforts to toughen CFRPs include modifying the existing epoxy material and finding alternative polymer matrix. One such material with high promise is PEEK , which exhibits an order of magnitude greater toughness with similar elastic modulus and tensile strength. However, PEEK
7560-407: The concrete. However, although large increases are achieved in the ultimate collapse load, the concrete will crack at only slightly enhanced load, meaning that this application is only occasionally used. Specialist ultra-high modulus CFRP (with tensile modulus of 420 GPa or more) is one of the few practical methods of strengthening cast iron beams. In typical use, it is bonded to the tensile flange of
7668-406: The country), though the vowel-consonant cluster found in "bird", "work", "hurt", "learn", etc. usually retains its r pronunciation, even in these non-rhotic American accents. Non-rhoticity among such speakers is presumed to have arisen from their upper classes' close historical contact with England, imitating London's r -dropping, a feature that has continued to gain prestige throughout England from
7776-409: The desired component. The benefit is the speed of the entire process. Some car manufacturers, such as BMW, claimed to be able to cycle a new part every 80 seconds. However, this technique has a very high initial cost since the molds require CNC machining of very high precision. For difficult or convoluted shapes, a filament winder can be used to make CFRP parts by winding filaments around a mandrel or
7884-614: The diverse regional dialects of British English) became common after the mid-18th century, while at the same time speakers' identification with this new variety increased. Since the 18th century, American English has developed into some new varieties, including regional dialects that retain minor influences from waves of immigrant speakers of diverse languages, primarily European languages. Some racial and regional variation in American English reflects these groups' geographic settlement, their de jure or de facto segregation, and patterns in their resettlement. This can be seen, for example, in
7992-742: The double quotation mark ("like this") over the single ('as here'). Vocabulary differences vary by region. For example, autumn is used more commonly in the United Kingdom, whereas fall is more common in American English. Some other differences include: aerial (United Kingdom) vs. antenna, biscuit (United Kingdom) vs. cookie/cracker, car park (United Kingdom) vs. parking lot, caravan (United Kingdom) vs. trailer, city centre (United Kingdom) vs. downtown, flat (United Kingdom) vs. apartment, fringe (United Kingdom) vs. bangs, and holiday (United Kingdom) vs. vacation. AmE sometimes favors words that are morphologically more complex, whereas BrE uses clipped forms, such as AmE transportation and BrE transport or where
8100-546: The fatigue failure properties of CFRPs are difficult to predict and design against; however emerging research has shed light on the effects of low velocity impacts on composites. Low velocity impacts can make carbon fibre polymers susceptible to damage. As a result, when using CFRPs for critical cyclic-loading applications, engineers may need to design in considerable strength safety margins to provide suitable component reliability over its service life. Environmental effects such as temperature and humidity can have profound effects on
8208-457: The filament material using fused deposition modeling – FDM (or fused filament fabrication – FFF) technology. PEEK filaments have been demonstrated for producing medical devices up to class IIa . With this new filament, it is possible to use the FFF method for different medical applications like dentures . In its solid state PEEK is readily machinable, for example, by CNC milling machines and
8316-400: The final carbon fiber. The carbon fibers filament yarns may be further treated to improve handling qualities, then wound onto bobbins . From these fibers, a unidirectional sheet is created. These sheets are layered onto each other in a quasi-isotropic layup, e.g. 0°, +60°, or −60° relative to each other. From the elementary fiber, a bidirectional woven sheet can be created, i.e. a twill with
8424-517: The following two centuries) when this ethnic group eventually made up one-seventh of the colonial population. Scotch-Irish settlers spread from Delaware and Pennsylvania throughout the larger Mid-Atlantic region, the inland regions of both the South and North, and throughout the West: American dialect areas that were all uninfluenced by upper-class non-rhoticity and that consequently have remained consistently rhotic. While non-rhoticity spread on
8532-495: The following: One method of producing CFRP parts is by layering sheets of carbon fiber cloth into a mold in the shape of the final product. The alignment and weave of the cloth fibers is chosen to optimize the strength and stiffness properties of the resulting material. The mold is then filled with epoxy and is heated or air-cured. The resulting part is very corrosion-resistant, stiff, and strong for its weight. Parts used in less critical areas are manufactured by draping cloth over
8640-415: The form of hydrogen embrittlement has been blamed for the gradual deterioration of the prestressing wires in many PCCP lines. Over the past decade, CFRPs have been used to internally line PCCP, resulting in a fully structural strengthening system. Inside a PCCP line, the CFRP liner acts as a barrier that controls the level of strain experienced by the steel cylinder in the host pipe. The composite liner enables
8748-944: The hospital , BrE to hospital ; contrast, however, AmE actress Elizabeth Taylor , BrE the actress Elizabeth Taylor ). Often, these differences are a matter of relative preferences rather than absolute rules; and most are not stable since the two varieties are constantly influencing each other, and American English is not a standardized set of dialects. Differences in orthography are also minor. The main differences are that American English usually uses spellings such as flavor for British flavour , fiber for fibre , defense for defence , analyze for analyse , license for licence , catalog for catalogue and traveling for travelling . Noah Webster popularized such spellings in America, but he did not invent most of them. Rather, "he chose already existing options on such grounds as simplicity, analogy or etymology." Other differences are due to
8856-674: The influence of 18th-century Protestant Ulster Scots immigrants (known in the U.S. as the Scotch-Irish ) in Appalachia developing Appalachian English and the 20th-century Great Migration bringing African-American Vernacular English to the Great Lakes urban centers. Any phonologically unmarked North American accent falls under an umbrella known as General American. This section mostly refers to such General American features. Studies on historical usage of English in both
8964-438: The late 18th century onwards, but which has conversely lost prestige in the U.S. since at least the early 20th century. Non-rhoticity makes a word like car sound like cah or source like sauce . New York City and Southern accents are the most prominent regional accents of the country, as well as the most stigmatized and socially disfavored. Southern speech, strongest in southern Appalachia and certain areas of Texas,
9072-439: The load capacity of old structures (such as bridges, beams, ceilings, columns and walls) that were designed to tolerate far lower service loads than they are experiencing today, seismic retrofitting, and repair of damaged structures. Retrofitting is popular in many instances as the cost of replacing the deficient structure can greatly exceed the cost of strengthening using CFRP. Applied to reinforced concrete structures for flexure,
9180-419: The manufacture of these parts. Many aircraft that use CFRPs have experienced delays with delivery dates due to the relatively new processes used to make CFRP components, whereas metallic structures have been studied and used on airframes for decades, and the processes are relatively well understood. A recurrent problem is the monitoring of structural ageing, for which new methods are constantly investigated, due to
9288-565: The matrix and fibers respectively. The other extreme case of the elastic modulus of the composite with the fibers oriented transverse to the applied load can be found using the equation: The fracture toughness of carbon fiber reinforced plastics is governed by the mechanisms: 1) debonding between the carbon fiber and polymer matrix, 2) fiber pull-out, and 3) delamination between the CFRP sheets. Typical epoxy-based CFRPs exhibit virtually no plasticity, with less than 0.5% strain to failure. Although CFRPs with epoxy have high strength and elastic modulus,
9396-619: The matrix in CFRPs such as compressive, interlaminar shear, and impact properties. The epoxy matrix used for engine fan blades is designed to be impervious against jet fuel, lubrication, and rain water, and external paint on the composites parts is applied to minimize damage from ultraviolet light. Carbon fibers can cause galvanic corrosion when CRP parts are attached to aluminum or mild steel but not to stainless steel or titanium. Carbon Fiber Reinforced Plastics are very hard to machine, and cause significant tool wear. The tool wear in CFRP machining
9504-427: The mid-nineteenth century onwards, so they "are now more different from each other than they were 50 or 100 years ago", while other accents, like of New York City and Boston, have remained stable in that same time-frame. However, a General American sound system also has some debated degree of influence nationwide, for example, gradually beginning to oust the regional accent in urban areas of the South and at least some in
9612-433: The mold and placed in the bag. The other one is done by infusion, where the dry fabric and mold are placed inside the bag while the vacuum pulls the resin through a small tube into the bag, then through a tube with holes or something similar to evenly spread the resin throughout the fabric. Wire loom works perfectly for a tube that requires holes inside the bag. Both of these methods of applying resin require hand work to spread
9720-617: The most formal contexts, and regional accents with the most General American native features include North Midland, Western New England, and Western accents. Although no longer region-specific, African-American Vernacular English , which remains the native variety of most working- and middle-class African Americans , has a close relationship to Southern dialects and has greatly influenced everyday speech of many Americans, including hip hop culture . Hispanic and Latino Americans have also developed native-speaker varieties of English. The best-studied Latino Englishes are Chicano English , spoken in
9828-645: The need to re-true a wheel and the reduced mass reduces the moment of inertia of the wheel. CFRP spokes are rare and most carbon wheelsets retain traditional stainless steel spokes. CFRPs also appear increasingly in other components such as derailleur parts, brake and shifter levers and bodies, cassette sprocket carriers, suspension linkages, disc brake rotors, pedals, shoe soles, and saddle rails. Although strong and light, impact, over-torquing, or improper installation of CFRP components has resulted in cracking and failures, which may be difficult or impossible to repair. The fire resistance of polymers and thermo-set composites
9936-402: The past forms of a few verbs (for example, AmE/BrE: learned / learnt , burned / burnt , snuck/sneaked , dove/dived ) although the purportedly "British" forms can occasionally be seen in American English writing as well; different prepositions and adverbs in certain contexts (for example, AmE in school, BrE at school ); and whether or not a definite article is used, in very few cases (AmE to
10044-492: The polymer-based composites, including most CFRPs. While CFRPs demonstrate excellent corrosion resistance, the effect of moisture at wide ranges of temperatures can lead to degradation of the mechanical properties of CFRPs, particularly at the matrix-fiber interface. While the carbon fibers themselves are not affected by the moisture diffusing into the material, the moisture plasticizes the polymer matrix. This leads to significant changes in properties that are dominantly influenced by
10152-434: The proportion of the carbon fibers relative to the polymer. The two different equations governing the net elastic modulus of composite materials using the properties of the carbon fibers and the polymer matrix can also be applied to carbon fiber reinforced plastics. The equation: is valid for composite materials with the fibers oriented in the direction of the applied load. E c {\displaystyle E_{c}}
10260-413: The reinforcements together. Because CFRPs consist of two distinct elements, the material properties depend on these two elements. Reinforcement gives CFRPs their strength and rigidity, measured by stress and elastic modulus respectively. Unlike isotropic materials like steel and aluminum, CFRPs have directional strength properties. The properties of a CFRP depend on the layouts of the carbon fiber and
10368-649: The resin evenly for a glossy finish with very small pin-holes. A third method of constructing composite materials is known as a dry layup. Here, the carbon fiber material is already impregnated with resin (pre-preg) and is applied to the mold in a similar fashion to adhesive film. The assembly is then placed in a vacuum to cure. The dry layup method has the least amount of resin waste and can achieve lighter constructions than wet layup. Also, because larger amounts of resin are more difficult to bleed out with wet layup methods, pre-preg parts generally have fewer pinholes. Pinhole elimination with minimal resin amounts generally require
10476-490: The section, both increasing the stiffness of the section and lowering the neutral axis , thus greatly reducing the maximum tensile stress in the cast iron. In the United States, prestressed concrete cylinder pipes (PCCP) account for a vast majority of water transmission mains. Due to their large diameters, failures of PCCP are usually catastrophic and affect large populations. Approximately 19,000 miles (31,000 km) of PCCP were installed between 1940 and 2006. Corrosion in
10584-708: The steel cylinder to perform within its elastic range, to ensure the pipeline's long-term performance is maintained. CFRP liner designs are based on strain compatibility between the liner and host pipe. CFRPs are more costly materials than commonly used their counterparts in the construction industry, glass fiber-reinforced polymers (GFRPs) and aramid fiber-reinforced polymers (AFRPs), though CFRPs are, in general, regarded as having superior properties. Much research continues to be done on using CFRPs both for retrofitting and as an alternative to steel as reinforcing or prestressing materials. Cost remains an issue and long-term durability questions still remain. Some are concerned about
10692-428: The strength of full-length carbon fiber reinforcement. For example, chopped reclaimed carbon fiber can be used in consumer electronics, such as laptops. It provides excellent reinforcement of the polymers used even if it lacks the strength-to-weight ratio of an aerospace component. In 2009, Zyvex Technologies introduced carbon nanotube-reinforced epoxy and carbon pre-pregs . Carbon nanotube reinforced polymer (CNRP)
10800-570: The traditional standard accent of (southern) England, Received Pronunciation (RP), has evolved a trap–bath split . Moreover, American accents preserve /h/ at the start of syllables, while perhaps a majority of the regional dialects of England participate in /h/ dropping , particularly in informal contexts. However, General American is also innovative in a number of its own ways: The process of coining new lexical items started as soon as English-speaking British-American colonists began borrowing names for unfamiliar flora, fauna, and topography from
10908-712: The unusual multi-material and anisotropic nature of CFRPs. In 1968 a Hyfil carbon-fiber fan assembly was in service on the Rolls-Royce Conways of the Vickers VC10s operated by BOAC . Specialist aircraft designers and manufacturers Scaled Composites have made extensive use of CFRPs throughout their design range, including the first private crewed spacecraft Spaceship One . CFRPs are widely used in micro air vehicles (MAVs) because of their high strength-to-weight ratio. CFRPs are extensively used in high-end automobile racing. The high cost of carbon fiber
11016-407: The use of autoclave pressures to purge the residual gases out. A quicker method uses a compression mold , also commonly known as carbon fiber forging. This is a two (male and female), or multi-piece mold, usually made out of aluminum or steel and more recently 3D printed plastic. The mold components are pressed together with the fabric and resin loaded into the inner cavity that ultimately becomes
11124-422: The use of CFRPs typically has a large impact on strength (doubling or more the strength of the section is not uncommon), but only moderately increases stiffness (as little as 10%). This is because the material used in such applications is typically very strong (e.g., 3 GPa ultimate tensile strength , more than 10 times mild steel) but not particularly stiff (150 to 250 GPa elastic modulus, a little less than steel,
11232-417: The verb-and-preposition combination: stopover, lineup, tryout, spin-off, shootout , holdup, hideout, comeback, makeover , and many more. Some prepositional and phrasal verbs are in fact of American origin ( win out, hold up, back up/off/down/out, face up to and many others). Noun endings such as -ee (retiree), -ery (bakery), -ster (gangster) and -cian (beautician) are also particularly productive in
11340-775: The word corn , used in England to refer to wheat (or any cereal), came to denote the maize plant, the most important crop in the U.S. Most Mexican Spanish contributions came after the War of 1812 , with the opening of the West, like ranch (now a common house style ). Due to Mexican culinary influence, many Spanish words are incorporated in general use when talking about certain popular dishes: cilantro (instead of coriander), queso, tacos, quesadillas, enchiladas, tostadas, fajitas, burritos, and guacamole. These words usually lack an English equivalent and are found in popular restaurants. New forms of dwelling created new terms ( lot , waterfront) and types of homes like log cabin , adobe in
11448-609: The world. Any American or Canadian accent perceived as lacking noticeably local, ethnic, or cultural markers is known in linguistics as General American ; it covers a fairly uniform accent continuum native to certain regions of the U.S. but especially associated with broadcast mass media and highly educated speech. However, historical and present linguistic evidence does not support the notion of there being one single mainstream American accent . The sound of American English continues to evolve, with some local accents disappearing, but several larger regional accents having emerged in
11556-956: Was claimed to merely increase the durability of the bats, but it was banned from all first-class matches by the ICC in 2007. A CFRP bicycle frame weighs less than one of steel, aluminum, or titanium having the same strength. The type and orientation of the carbon-fiber weave can be designed to maximize stiffness in required directions. Frames can be tuned to address different riding styles: sprint events require stiffer frames while endurance events may require more flexible frames for rider comfort over longer periods. The variety of shapes it can be built into has further increased stiffness and also allowed aerodynamic tube sections. CFRP forks including suspension fork crowns and steerers, handlebars , seatposts , and crank arms are becoming more common on medium as well as higher-priced bicycles. CFRP rims remain expensive but their stability compared to aluminium reduces
11664-469: Was written by Noah Webster in 1828, codifying several of these spellings. Differences in grammar are relatively minor, and do not normally affect mutual intelligibility; these include: typically a lack of differentiation between adjectives and adverbs, employing the equivalent adjectives as adverbs he ran quick / he ran quickly ; different use of some auxiliary verbs ; formal (rather than notional) agreement with collective nouns ; different preferences for
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