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86-475: Chemical substances can exist in several different physical states or phases (e.g. solids , liquids , gases , or plasma ) without changing their chemical composition. Substances transition between these phases of matter in response to changes in temperature or pressure . Some chemical substances can be combined or converted into new substances by means of chemical reactions . Chemicals that do not possess this ability are said to be inert . Pure water

172-647: A body-centred cubic structure at temperatures below 912 °C (1,674 °F), and a face-centred cubic structure between 912 and 1,394 °C (2,541 °F). Ice has fifteen known crystal structures, or fifteen solid phases, which exist at various temperatures and pressures. Glasses and other non-crystalline, amorphous solids without long-range order are not thermal equilibrium ground states; therefore they are described below as nonclassical states of matter. Solids can be transformed into liquids by melting, and liquids can be transformed into solids by freezing. Solids can also change directly into gases through

258-452: A chemical reaction form a chemical compound . All compounds are substances, but not all substances are compounds. A chemical compound can be either atoms bonded together in molecules or crystals in which atoms, molecules or ions form a crystalline lattice . Compounds based primarily on carbon and hydrogen atoms are called organic compounds , and all others are called inorganic compounds . Compounds containing bonds between carbon and

344-678: A database and is popularly known as the Chemical substances index. Other computer-friendly systems that have been developed for substance information are: SMILES and the International Chemical Identifier or InChI. Often a pure substance needs to be isolated from a mixture , for example from a natural source (where a sample often contains numerous chemical substances) or after a chemical reaction (which often gives mixtures of chemical substances). Stoichiometry ( / ˌ s t ɔɪ k i ˈ ɒ m ɪ t r i / )

430-414: A glass transition when heated towards the liquid state. Glasses can be made of quite different classes of materials: inorganic networks (such as window glass, made of silicate plus additives), metallic alloys, ionic melts , aqueous solutions , molecular liquids, and polymers . Thermodynamically, a glass is in a metastable state with respect to its crystalline counterpart. The conversion rate, however,

516-453: A magnetic domain ). If the domains are also aligned, the solid is a permanent magnet , which is magnetic even in the absence of an external magnetic field . The magnetization disappears when the magnet is heated to the Curie point , which for iron is 768 °C (1,414 °F). An antiferromagnet has two networks of equal and opposite magnetic moments, which cancel each other out so that

602-574: A mixture , referencing them in the chemical substances index allows CAS to offer specific guidance on standard naming of alloy compositions. Non-stoichiometric compounds are another special case from inorganic chemistry , which violate the requirement for constant composition. For these substances, it may be difficult to draw the line between a mixture and a compound, as in the case of palladium hydride . Broader definitions of chemicals or chemical substances can be found, for example: "the term 'chemical substance' means any organic or inorganic substance of

688-420: A phase transition . Water can be said to have several distinct solid states. The appearance of superconductivity is associated with a phase transition, so there are superconductive states. Likewise, ferromagnetic states are demarcated by phase transitions and have distinctive properties. When the change of state occurs in stages the intermediate steps are called mesophases . Such phases have been exploited by

774-500: A state of matter is one of the distinct forms in which matter can exist. Four states of matter are observable in everyday life: solid , liquid , gas , and plasma . Many intermediate states are known to exist, such as liquid crystal , and some states only exist under extreme conditions, such as Bose–Einstein condensates and Fermionic condensates (in extreme cold), neutron-degenerate matter (in extreme density), and quark–gluon plasma (at extremely high energy ). Historically,

860-618: A "ligand". However, the center does not need to be a metal, as exemplified by boron trifluoride etherate BF 3 OEt 2 , where the highly Lewis acidic , but non-metallic boron center takes the role of the "metal". If the ligand bonds to the metal center with multiple atoms, the complex is called a chelate . In organic chemistry, there can be more than one chemical compound with the same composition and molecular weight. Generally, these are called isomers . Isomers usually have substantially different chemical properties, and often may be isolated without spontaneously interconverting. A common example

946-439: A chemical equation, the state of matter of the chemicals may be shown as (s) for solid, (l) for liquid, and (g) for gas. An aqueous solution is denoted (aq), for example, Matter in the plasma state is seldom used (if at all) in chemical equations, so there is no standard symbol to denote it. In the rare equations that plasma is used it is symbolized as (p). Glass is a non-crystalline or amorphous solid material that exhibits

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1032-416: A chemical reaction takes place and a new substance is formed, the compound iron(II) sulfide , with chemical formula FeS. The resulting compound has all the properties of a chemical substance and is not a mixture. Iron(II) sulfide has its own distinct properties such as melting point and solubility , and the two elements cannot be separated using normal mechanical processes; a magnet will be unable to recover

1118-408: A given liquid can exist is its critical temperature . A gas is a compressible fluid. Not only will a gas conform to the shape of its container but it will also expand to fill the container. In a gas, the molecules have enough kinetic energy so that the effect of intermolecular forces is small (or zero for an ideal gas ), and the typical distance between neighboring molecules is much greater than

1204-405: A heavier analogue of the common down quark . It may be stable at lower energy states once formed, although this is not known. Quark–gluon plasma is a very high-temperature phase in which quarks become free and able to move independently, rather than being perpetually bound into particles, in a sea of gluons , subatomic particles that transmit the strong force that binds quarks together. This

1290-518: A liquid (or solid), in which case the gas pressure equals the vapor pressure of the liquid (or solid). A supercritical fluid (SCF) is a gas whose temperature and pressure are above the critical temperature and critical pressure respectively. In this state, the distinction between liquid and gas disappears. A supercritical fluid has the physical properties of a gas, but its high density confers solvent properties in some cases, which leads to useful applications. For example, supercritical carbon dioxide

1376-440: A liquid at its melting point , boils into a gas at its boiling point , and if heated high enough would enter a plasma state in which the electrons are so energized that they leave their parent atoms. Forms of matter that are not composed of molecules and are organized by different forces can also be considered different states of matter. Superfluids (like Fermionic condensate ) and the quark–gluon plasma are examples. In

1462-494: A liquid, but exhibiting long-range order. For example, the nematic phase consists of long rod-like molecules such as para-azoxyanisole , which is nematic in the temperature range 118–136 °C (244–277 °F). In this state the molecules flow as in a liquid, but they all point in the same direction (within each domain) and cannot rotate freely. Like a crystalline solid, but unlike a liquid, liquid crystals react to polarized light. Other types of liquid crystals are described in

1548-436: A metal are called organometallic compounds . Compounds in which components share electrons are known as covalent compounds. Compounds consisting of oppositely charged ions are known as ionic compounds, or salts . Coordination complexes are compounds where a dative bond keeps the substance together without a covalent or ionic bond. Coordination complexes are distinct substances with distinct properties different from

1634-459: A particular molecular identity, including – (i) any combination of such substances occurring in whole or in part as a result of a chemical reaction or occurring in nature". In the field of geology , inorganic solid substances of uniform composition are known as minerals . When two or more minerals are combined to form mixtures (or aggregates ), they are defined as rocks . Many minerals, however, mutually dissolve into solid solutions , such that

1720-582: A phenomenon known as the Meissner effect or perfect diamagnetism . Superconducting magnets are used as electromagnets in magnetic resonance imaging machines. The phenomenon of superconductivity was discovered in 1911, and for 75 years was only known in some metals and metallic alloys at temperatures below 30 K. In 1986 so-called high-temperature superconductivity was discovered in certain ceramic oxides, and has now been observed in temperatures as high as 164 K. Close to absolute zero, some liquids form

1806-438: A second liquid state described as superfluid because it has zero viscosity (or infinite fluidity; i.e., flowing without friction). This was discovered in 1937 for helium , which forms a superfluid below the lambda temperature of 2.17 K (−270.98 °C; −455.76 °F). In this state it will attempt to "climb" out of its container. It also has infinite thermal conductivity so that no temperature gradient can form in

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1892-437: A separate chemical substance. However, the polymer may be defined by a known precursor or reaction(s) and the molar mass distribution . For example, polyethylene is a mixture of very long chains of -CH 2 - repeating units, and is generally sold in several molar mass distributions, LDPE , MDPE , HDPE and UHMWPE . The concept of a "chemical substance" became firmly established in the late eighteenth century after work by

1978-400: A simple mixture. Typically these have a metal, such as a copper ion, in the center and a nonmetals atom, such as the nitrogen in an ammonia molecule or oxygen in water in a water molecule, forms a dative bond to the metal center, e.g. tetraamminecopper(II) sulfate [Cu(NH 3 ) 4 ]SO 4 ·H 2 O. The metal is known as a "metal center" and the substance that coordinates to the center is called

2064-477: A single chemical substance ( allotropes ). For instance, oxygen exists as both diatomic oxygen (O 2 ) and ozone (O 3 ). The majority of elements are classified as metals . These are elements with a characteristic lustre such as iron , copper , and gold . Metals typically conduct electricity and heat well, and they are malleable and ductile . Around 14 to 21 elements, such as carbon , nitrogen , and oxygen , are classified as non-metals . Non-metals lack

2150-430: A single manufacturing process. For example, charcoal is an extremely complex, partially polymeric mixture that can be defined by its manufacturing process. Therefore, although the exact chemical identity is unknown, identification can be made with a sufficient accuracy. The CAS index also includes mixtures. Polymers almost always appear as mixtures of molecules of multiple molar masses, each of which could be considered

2236-726: A single rock is a uniform substance despite being a mixture in stoichiometric terms. Feldspars are a common example: anorthoclase is an alkali aluminum silicate, where the alkali metal is interchangeably either sodium or potassium. In law, "chemical substances" may include both pure substances and mixtures with a defined composition or manufacturing process. For example, the EU regulation REACH defines "monoconstituent substances", "multiconstituent substances" and "substances of unknown or variable composition". The latter two consist of multiple chemical substances; however, their identity can be established either by direct chemical analysis or reference to

2322-430: A string-net liquid, atoms have apparently unstable arrangement, like a liquid, but are still consistent in overall pattern, like a solid. When in a normal solid state, the atoms of matter align themselves in a grid pattern, so that the spin of any electron is the opposite of the spin of all electrons touching it. But in a string-net liquid, atoms are arranged in some pattern that requires some electrons to have neighbors with

2408-481: A superdense conglomeration of neutrons. Normally free neutrons outside an atomic nucleus will decay with a half life of approximately 10 minutes, but in a neutron star, the decay is overtaken by inverse decay. Cold degenerate matter is also present in planets such as Jupiter and in the even more massive brown dwarfs , which are expected to have a core with metallic hydrogen . Because of the degeneracy, more massive brown dwarfs are not significantly larger. In metals,

2494-467: A superfluid. Placing a superfluid in a spinning container will result in quantized vortices . These properties are explained by the theory that the common isotope helium-4 forms a Bose–Einstein condensate (see next section) in the superfluid state. More recently, fermionic condensate superfluids have been formed at even lower temperatures by the rare isotope helium-3 and by lithium-6 . In 1924, Albert Einstein and Satyendra Nath Bose predicted

2580-499: A technical specification instead of particular chemical substances. For example, gasoline is not a single chemical compound or even a particular mixture: different gasolines can have very different chemical compositions, as "gasoline" is primarily defined through source, properties and octane rating . Every chemical substance has one or more systematic names , usually named according to the IUPAC rules for naming . An alternative system

2666-417: A uniform liquid. Transition metal atoms often have magnetic moments due to the net spin of electrons that remain unpaired and do not form chemical bonds. In some solids the magnetic moments on different atoms are ordered and can form a ferromagnet, an antiferromagnet or a ferrimagnet. In a ferromagnet —for instance, solid iron —the magnetic moment on each atom is aligned in the same direction (within

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2752-442: A yellow-grey mixture. No chemical process occurs, and the material can be identified as a mixture by the fact that the sulfur and the iron can be separated by a mechanical process, such as using a magnet to attract the iron away from the sulfur. In contrast, if iron and sulfur are heated together in a certain ratio (1 atom of iron for each atom of sulfur, or by weight, 56 grams (1 mol ) of iron to 32 grams (1 mol) of sulfur),

2838-436: Is glucose vs. fructose . The former is an aldehyde , the latter is a ketone . Their interconversion requires either enzymatic or acid-base catalysis . However, tautomers are an exception: the isomerization occurs spontaneously in ordinary conditions, such that a pure substance cannot be isolated into its tautomers, even if these can be identified spectroscopically or even isolated in special conditions. A common example

2924-703: Is glucose , which has open-chain and ring forms. One cannot manufacture pure open-chain glucose because glucose spontaneously cyclizes to the hemiacetal form. All matter consists of various elements and chemical compounds, but these are often intimately mixed together. Mixtures contain more than one chemical substance, and they do not have a fixed composition. Butter , soil and wood are common examples of mixtures. Sometimes, mixtures can be separated into their component substances by mechanical processes, such as chromatography , distillation , or evaporation . Grey iron metal and yellow sulfur are both chemical elements, and they can be mixed together in any ratio to form

3010-592: Is a chemical substance made up of a particular kind of atom and hence cannot be broken down or transformed by a chemical reaction into a different element, though it can be transmuted into another element through a nuclear reaction . This is because all of the atoms in a sample of an element have the same number of protons , though they may be different isotopes , with differing numbers of neutrons . As of 2019, there are 118 known elements, about 80 of which are stable – that is, they do not change by radioactive decay into other elements. Some elements can occur as more than

3096-442: Is a disordered state in a system of interacting quantum spins which preserves its disorder to very low temperatures, unlike other disordered states. It is not a liquid in physical sense, but a solid whose magnetic order is inherently disordered. The name "liquid" is due to an analogy with the molecular disorder in a conventional liquid. A QSL is neither a ferromagnet , where magnetic domains are parallel, nor an antiferromagnet , where

3182-399: Is a type of matter theorized to exist in atomic nuclei traveling near the speed of light. According to Einstein's theory of relativity, a high-energy nucleus appears length contracted, or compressed, along its direction of motion. As a result, the gluons inside the nucleus appear to a stationary observer as a "gluonic wall" traveling near the speed of light. At very high energies, the density of

3268-402: Is an example of complete combustion . Stoichiometry measures these quantitative relationships, and is used to determine the amount of products and reactants that are produced or needed in a given reaction. Describing the quantitative relationships among substances as they participate in chemical reactions is known as reaction stoichiometry . In the example above, reaction stoichiometry measures

3354-417: Is an example of a chemical substance, with a constant composition of two hydrogen atoms bonded to a single oxygen atom (i.e. H 2 O). The atomic ratio of hydrogen to oxygen is always 2:1 in every molecule of water. Pure water will tend to boil near 100 °C (212 °F), an example of one of the characteristic properties that define it. Other notable chemical substances include diamond (a form of

3440-419: Is analogous to the liberation of electrons from atoms in a plasma. This state is briefly attainable in extremely high-energy heavy ion collisions in particle accelerators , and allows scientists to observe the properties of individual quarks. Theories predicting the existence of quark–gluon plasma were developed in the late 1970s and early 1980s, and it was detected for the first time in the laboratory at CERN in

3526-536: Is assumed that essentially all electrons are "free", and that a very high-energy plasma is essentially bare nuclei swimming in a sea of electrons. This forms the so-called fully ionised plasma. The plasma state is often misunderstood, and although not freely existing under normal conditions on Earth, it is quite commonly generated by either lightning , electric sparks , fluorescent lights , neon lights or in plasma televisions . The Sun's corona , some types of flame , and stars are all examples of illuminated matter in

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3612-415: Is no long-range magnetic order. Superconductors are materials which have zero electrical resistivity , and therefore perfect conductivity. This is a distinct physical state which exists at low temperature, and the resistivity increases discontinuously to a finite value at a sharply-defined transition temperature for each superconductor. A superconductor also excludes all magnetic fields from its interior,

3698-421: Is possible for a single compound to form different phases that are in the same state of matter. For example, ice is the solid state of water, but there are multiple phases of ice with different crystal structures , which are formed at different pressures and temperatures. In a solid, constituent particles (ions, atoms, or molecules) are closely packed together. The forces between particles are so strong that

3784-446: Is practically zero. A plastic crystal is a molecular solid with long-range positional order but with constituent molecules retaining rotational freedom; in an orientational glass this degree of freedom is frozen in a quenched disordered state. Similarly, in a spin glass magnetic disorder is frozen. Liquid crystal states have properties intermediate between mobile liquids and ordered solids. Generally, they are able to flow like

3870-411: Is the relationships among the weights of reactants and products before, during, and following chemical reactions . Stoichiometry is founded on the law of conservation of mass where the total mass of the reactants equals the total mass of the products, leading to the insight that the relations among quantities of reactants and products typically form a ratio of positive integers. This means that if

3956-497: Is used by the Chemical Abstracts Service (CAS). Many compounds are also known by their more common, simpler names, many of which predate the systematic name. For example, the long-known sugar glucose is now systematically named 6-(hydroxymethyl)oxane-2,3,4,5-tetrol. Natural products and pharmaceuticals are also given simpler names, for example the mild pain-killer Naproxen is the more common name for

4042-478: Is used to extract caffeine in the manufacture of decaffeinated coffee. A gas is usually converted to a plasma in one of two ways, either from a huge voltage difference between two points, or by exposing it to extremely high temperatures. Heating matter to high temperatures causes electrons to leave the atoms, resulting in the presence of free electrons. This creates a so-called partially ionised plasma. At very high temperatures, such as those present in stars, it

4128-576: The University of Colorado at Boulder , produced the first such condensate experimentally. A Bose–Einstein condensate is "colder" than a solid. It may occur when atoms have very similar (or the same) quantum levels , at temperatures very close to absolute zero , −273.15 °C (−459.67 °F). A fermionic condensate is similar to the Bose–Einstein condensate but composed of fermions . The Pauli exclusion principle prevents fermions from entering

4214-466: The baryon asymmetry in the universe, but little is known about it. In string theory , a Hagedorn temperature is predicted for superstrings at about 10 K, where superstrings are copiously produced. At Planck temperature (10 K), gravity becomes a significant force between individual particles. No current theory can describe these states and they cannot be produced with any foreseeable experiment. However, these states are important in cosmology because

4300-438: The "Bose–Einstein condensate" (BEC), sometimes referred to as the fifth state of matter. In a BEC, matter stops behaving as independent particles, and collapses into a single quantum state that can be described with a single, uniform wavefunction. In the gas phase, the Bose–Einstein condensate remained an unverified theoretical prediction for many years. In 1995, the research groups of Eric Cornell and Carl Wieman , of JILA at

4386-532: The amounts of the separate reactants are known, then the amount of the product can be calculated. Conversely, if one reactant has a known quantity and the quantity of the products can be empirically determined, then the amount of the other reactants can also be calculated. This is illustrated in the image here, where the balanced equation is: Here, one molecule of methane reacts with two molecules of oxygen gas to yield one molecule of carbon dioxide and two molecules of water . This particular chemical equation

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4472-501: The application, but higher tolerance of impurities is usually expected in the production of bulk chemicals. Thus, the user of the chemical in the US might choose between the bulk or "technical grade" with higher amounts of impurities or a much purer "pharmaceutical grade" (labeled "USP", United States Pharmacopeia ). "Chemicals" in the commercial and legal sense may also include mixtures of highly variable composition, as they are products made to

4558-714: The blocks, block copolymers undergo a similar phase separation. However, because the blocks are covalently bonded to each other, they cannot demix macroscopically as water and oil can, and so instead the blocks form nanometre-sized structures. Depending on the relative lengths of each block and the overall block topology of the polymer, many morphologies can be obtained, each its own phase of matter. Ionic liquids also display microphase separation. The anion and cation are not necessarily compatible and would demix otherwise, but electric charge attraction prevents them from separating. Their anions and cations appear to diffuse within compartmentalized layers or micelles instead of freely as in

4644-407: The chemical combination of the known chemical elements. As of Feb 2021, about "177 million organic and inorganic substances" (including 68 million defined-sequence biopolymers) are in the scientific literature and registered in public databases. The names of many of these compounds are often nontrivial and hence not very easy to remember or cite accurately. Also, it is difficult to keep track of them in

4730-450: The chemical compound (S)-6-methoxy-α-methyl-2-naphthaleneacetic acid. Chemists frequently refer to chemical compounds using chemical formulae or molecular structure of the compound. There has been a phenomenal growth in the number of chemical compounds being synthesized (or isolated), and then reported in the scientific literature by professional chemists around the world. An enormous number of chemical compounds are possible through

4816-460: The chemical industry, manufactured "chemicals" are chemical substances, which can be classified by production volume into bulk chemicals, fine chemicals and chemicals found in research only: The cause of the difference in production volume is the complexity of the molecular structure of the chemical. Bulk chemicals are usually much less complex. While fine chemicals may be more complex, many of them are simple enough to be sold as "building blocks" in

4902-400: The chemical substances of which fruits and vegetables, for example, are naturally composed even when growing wild are not called "chemicals" in general usage. In countries that require a list of ingredients in products, the "chemicals" listed are industrially produced "chemical substances". The word "chemical" is also often used to refer to addictive, narcotic, or mind-altering drugs. Within

4988-417: The chemist Joseph Proust on the composition of some pure chemical compounds such as basic copper carbonate . He deduced that, "All samples of a compound have the same composition; that is, all samples have the same proportions, by mass, of the elements present in the compound." This is now known as the law of constant composition . Later with the advancement of methods for chemical synthesis particularly in

5074-507: The distinction is based on qualitative differences in properties. Matter in the solid state maintains a fixed volume (assuming no change in temperature or air pressure) and shape, with component particles ( atoms , molecules or ions ) close together and fixed into place. Matter in the liquid state maintains a fixed volume (assuming no change in temperature or air pressure), but has a variable shape that adapts to fit its container. Its particles are still close together but move freely. Matter in

5160-572: The electrons can be modeled as a degenerate gas moving in a lattice of non-degenerate positive ions. In regular cold matter, quarks , fundamental particles of nuclear matter, are confined by the strong force into hadrons that consist of 2–4 quarks, such as protons and neutrons. Quark matter or quantum chromodynamical (QCD) matter is a group of phases where the strong force is overcome and quarks are deconfined and free to move. Quark matter phases occur at extremely high densities or temperatures, and there are no known ways to produce them in equilibrium in

5246-530: The element carbon ), table salt (NaCl; an ionic compound ), and refined sugar (C 12 H 22 O 11 ; an organic compound ). In addition to the generic definition offered above, there are several niche fields where the term "chemical substance" may take alternate usages that are widely accepted, some of which are outlined in the sections below. Chemical Abstracts Service (CAS) lists several alloys of uncertain composition within their chemical substance index. While an alloy could be more closely defined as

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5332-412: The gaseous state has both variable volume and shape, adapting both to fit its container. Its particles are neither close together nor fixed in place. Matter in the plasma state has variable volume and shape, and contains neutral atoms as well as a significant number of ions and electrons , both of which can move around freely. The term phase is sometimes used as a synonym for state of matter, but it

5418-529: The gluons in this wall is seen to increase greatly. Unlike the quark–gluon plasma produced in the collision of such walls, the color-glass condensate describes the walls themselves, and is an intrinsic property of the particles that can only be observed under high-energy conditions such as those at RHIC and possibly at the Large Hadron Collider as well. Various theories predict new states of matter at very high energies. An unknown state has created

5504-430: The gravitational force increases, but pressure does not increase proportionally. Electron-degenerate matter is found inside white dwarf stars. Electrons remain bound to atoms but are able to transfer to adjacent atoms. Neutron-degenerate matter is found in neutron stars . Vast gravitational pressure compresses atoms so strongly that the electrons are forced to combine with protons via inverse beta-decay, resulting in

5590-398: The idea of stereoisomerism – that atoms have rigid three-dimensional structure and can thus form isomers that differ only in their three-dimensional arrangement – was another crucial step in understanding the concept of distinct chemical substances. For example, tartaric acid has three distinct isomers, a pair of diastereomers with one diastereomer forming two enantiomers . An element

5676-424: The introduction of liquid crystal technology. The state or phase of a given set of matter can change depending on pressure and temperature conditions, transitioning to other phases as these conditions change to favor their existence; for example, solid transitions to liquid with an increase in temperature. Near absolute zero , a substance exists as a solid . As heat is added to this substance it melts into

5762-410: The iron, since there is no metallic iron present in the compound. While the term chemical substance is a precise technical term that is synonymous with chemical for chemists, the word chemical is used in general usage to refer to both (pure) chemical substances and mixtures (often called compounds ), and especially when produced or purified in a laboratory or an industrial process. In other words,

5848-490: The laboratory; in ordinary conditions, any quark matter formed immediately undergoes radioactive decay. Strange matter is a type of quark matter that is suspected to exist inside some neutron stars close to the Tolman–Oppenheimer–Volkoff limit (approximately 2–3 solar masses ), although there is no direct evidence of its existence. In strange matter, part of the energy available manifests as strange quarks ,

5934-425: The large number of chemical substances reported in chemistry literature need to be indexed. Isomerism caused much consternation to early researchers, since isomers have exactly the same composition, but differ in configuration (arrangement) of the atoms. For example, there was much speculation about the chemical identity of benzene , until the correct structure was described by Friedrich August Kekulé . Likewise,

6020-409: The literature. Several international organizations like IUPAC and CAS have initiated steps to make such tasks easier. CAS provides the abstracting services of the chemical literature, and provides a numerical identifier, known as CAS registry number to each chemical substance that has been reported in the chemical literature (such as chemistry journals and patents ). This information is compiled as

6106-435: The magnetic domains are antiparallel; instead, the magnetic domains are randomly oriented. This can be realized e.g. by geometrically frustrated magnetic moments that cannot point uniformly parallel or antiparallel. When cooling down and settling to a state, the domain must "choose" an orientation, but if the possible states are similar in energy, one will be chosen randomly. Consequently, despite strong short-range order, there

6192-453: The main article on these states. Several types have technological importance, for example, in liquid crystal displays . Copolymers can undergo microphase separation to form a diverse array of periodic nanostructures, as shown in the example of the styrene-butadiene-styrene block copolymer shown at right. Microphase separation can be understood by analogy to the phase separation between oil and water. Due to chemical incompatibility between

6278-411: The metallic properties described above, they also have a high electronegativity and a tendency to form negative ions . Certain elements such as silicon sometimes resemble metals and sometimes resemble non-metals, and are known as metalloids . A chemical compound is a chemical substance that is composed of a particular set of atoms or ions . Two or more elements combined into one substance through

6364-447: The molecular size. A gas has no definite shape or volume, but occupies the entire container in which it is confined. A liquid may be converted to a gas by heating at constant pressure to the boiling point , or else by reducing the pressure at constant temperature. At temperatures below its critical temperature , a gas is also called a vapor , and can be liquefied by compression alone without cooling. A vapor can exist in equilibrium with

6450-471: The net magnetization is zero. For example, in nickel(II) oxide (NiO), half the nickel atoms have moments aligned in one direction and half in the opposite direction. In a ferrimagnet , the two networks of magnetic moments are opposite but unequal, so that cancellation is incomplete and there is a non-zero net magnetization. An example is magnetite (Fe 3 O 4 ), which contains Fe and Fe ions with different magnetic moments. A quantum spin liquid (QSL)

6536-478: The particles cannot move freely but can only vibrate. As a result, a solid has a stable, definite shape, and a definite volume. Solids can only change their shape by an outside force, as when broken or cut. In crystalline solids , the particles (atoms, molecules, or ions) are packed in a regularly ordered, repeating pattern. There are various different crystal structures , and the same substance can have more than one structure (or solid phase). For example, iron has

6622-459: The plasma state. Plasma is by far the most abundant of the four fundamental states, as 99% of all ordinary matter in the universe is plasma, as it composes all stars . A state of matter is also characterized by phase transitions . A phase transition indicates a change in structure and can be recognized by an abrupt change in properties. A distinct state of matter can be defined as any set of states distinguished from any other set of states by

6708-475: The pressure is higher than the triple point of the substance. Intermolecular (or interatomic or interionic) forces are still important, but the molecules have enough energy to move relative to each other and the structure is mobile. This means that the shape of a liquid is not definite but is determined by its container. The volume is usually greater than that of the corresponding solid, the best known exception being water , H 2 O. The highest temperature at which

6794-409: The process of sublimation , and gases can likewise change directly into solids through deposition . A liquid is a nearly incompressible fluid that conforms to the shape of its container but retains a (nearly) constant volume independent of pressure. The volume is definite if the temperature and pressure are constant. When a solid is heated above its melting point , it becomes liquid, given that

6880-410: The realm of organic chemistry ; the discovery of many more chemical elements and new techniques in the realm of analytical chemistry used for isolation and purification of elements and compounds from chemicals that led to the establishment of modern chemistry , the concept was defined as is found in most chemistry textbooks. However, there are some controversies regarding this definition mainly because

6966-411: The relationship between the quantities of methane and oxygen that react to form carbon dioxide and water. Because of the well known relationship of moles to atomic weights , the ratios that are arrived at by stoichiometry can be used to determine quantities by weight in a reaction described by a balanced equation. This is called composition stoichiometry . State of matter In physics ,

7052-479: The same energy and are thus interchangeable. Degenerate matter is supported by the Pauli exclusion principle , which prevents two fermionic particles from occupying the same quantum state. Unlike regular plasma, degenerate plasma expands little when heated, because there are simply no momentum states left. Consequently, degenerate stars collapse into very high densities. More massive degenerate stars are smaller, because

7138-451: The same quantum state, but a pair of fermions can behave as a boson, and multiple such pairs can then enter the same quantum state without restriction. Under extremely high pressure, as in the cores of dead stars, ordinary matter undergoes a transition to a series of exotic states of matter collectively known as degenerate matter , which are supported mainly by quantum mechanical effects. In physics, "degenerate" refers to two states that have

7224-454: The synthesis of more complex molecules targeted for single use, as named above. The production of a chemical includes not only its synthesis but also its purification to eliminate by-products and impurities involved in the synthesis. The last step in production should be the analysis of batch lots of chemicals in order to identify and quantify the percentages of impurities for the buyer of the chemicals. The required purity and analysis depends on

7310-487: The universe may have passed through these states in the Big Bang . A supersolid is a spatially ordered material (that is, a solid or crystal) with superfluid properties. Similar to a superfluid, a supersolid is able to move without friction but retains a rigid shape. Although a supersolid is a solid, it exhibits so many characteristic properties different from other solids that many argue it is another state of matter. In

7396-532: The year 2000. Unlike plasma, which flows like a gas, interactions within QGP are strong and it flows like a liquid. At high densities but relatively low temperatures, quarks are theorized to form a quark liquid whose nature is presently unknown. It forms a distinct color-flavor locked (CFL) phase at even higher densities. This phase is superconductive for color charge. These phases may occur in neutron stars but they are presently theoretical. Color-glass condensate

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