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Clayton Aniline Company

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A dye is a colored substance that chemically bonds to the substrate to which it is being applied. This distinguishes dyes from pigments which do not chemically bind to the material they color. Dye is generally applied in an aqueous solution and may require a mordant to improve the fastness of the dye on the fiber.

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94-674: The Clayton Aniline Company Ltd. was a British manufacturer of dyestuffs , founded in 1876 by Charles Dreyfus in Clayton, Manchester . Charles Dreyfus was a French emigrant chemist and entrepreneur, who founded the Clayton Aniline Company on 29 May 1876. The company obtained a lease on a parcel of land in Clayton, Manchester , sandwiched between the Manchester and Ashton Canal and Chatham Street (later known as Clipstone Street). With an initial share capital of £40,000

188-404: A broad riband or sash, passing from the right shoulder to the left hip. Knights Commander and male Commanders wear the badge from a ribbon around the neck; male Officers and Members wear the badge from a ribbon on the left chest; female recipients other than Dames Grand Cross (unless in military uniform) normally wear it from a bow on the left shoulder. An oval eight-pointed star is worn, pinned to

282-453: A circlet bearing the motto of the Order; the reverse bears George V's Royal and Imperial Cypher. (Prior to 1937 Britannia was shown within the circlet.) The size of the badges varies according to rank: the higher classes have slightly larger badges. The badges of Knights and Dames Grand Cross, Knights and Dames Commander, and Commanders are enamelled, with pale blue crosses, crimson circlets and

376-466: A citizen of a Commonwealth realm can convert their appointment from honorary to substantive, and they then enjoy all privileges of membership of the order, including use of the title of Sir and Dame for the senior two ranks of the Order. (An example of the latter is Irish broadcaster Terry Wogan , who was appointed an honorary Knight Commander of the Order in 2005, and on successful application for British citizenship, held alongside his Irish citizenship,

470-595: A commercial scale. Early industrialization was conducted by J. Pullar and Sons in Scotland. The first synthetic dye, mauve , was discovered serendipitously by William Henry Perkin in 1856. The discovery of mauveine started a surge in synthetic dyes and in organic chemistry in general. Other aniline dyes followed, such as fuchsine , safranine , and induline . Many thousands of synthetic dyes have since been prepared. The discovery of mauve also led to developments within immunology and chemotherapy . In 1863

564-410: A financial interest in the Clayton Aniline Company. During the inter war period the company continued to invest in new plant and products. The Dyestuffs (Import Regulation) Act 1920 had given British dye producers much needed protection from cheap imports and provided an impetus to increasing the range of dyes and intermediates produced at Clayton. In 1930, an additional azo dyes plant (building 187)

658-443: A gold central medallion. Officers' badges are plain silver-gilt, while those of Members are plain silver. From 1917 until 1937, the badge of the order was suspended on a purple ribbon, with a red central stripe being added for the military division in 1918. Since 1937, the ribbon has been rose-pink with pearl-grey edges (with the addition of a pearl-grey central stripe for the military division). Knights and Dames Grand Cross wear it on

752-439: A living body - administered by injection or other means (intravital staining) - as the latter is (for instance) subject to higher safety standards, and must typically be a chemical known to avoid causing adverse effects on any biochemistry (until cleared from the tissue), not just to the tissue being studied, or in the short term. The term "vital stain" is occasionally used interchangeably with both intravital and supravital stains,

846-478: A manufacturing site for direct dyes for cotton, disperse dyes for polyester and metal complex dyes for wool and nylon; and pigments used for carbonless copying and thermal printer papers. Initially the whole site was designated as part of the "Colors" business unit of Ciba Specialty Chemicals; but later the dyes manufacturing, logistics and site management became part of the Textile Effects division, while

940-406: A microscope). As the visibility is meant to allow study of the cells or tissues, it is usually important that the dye not have other effects on the structure or function of the tissue that might impair objective observation. A distinction is drawn between dyes that are meant to be used on cells that have been removed from the organism prior to study (supravital staining) and dyes that are used within

1034-538: A new aniline plant was built with an output of around 100 tons per week. On 5 October 1942, a near catastrophe befell the site when an ethylation autoclave caught fire, which threatened the adjacent phosgenation unit. Department manager Eric Shaw risked his life to disconnect and remove to safety gas cylinders filled with phosgene , that were in danger of exploding. Shaw was awarded an MBE in 1943 for his actions. Also commended for their bravery were J.T. Read, J. Wood and R. Dean. The Second World War ended in 1945 and

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1128-756: A new azo dyes plant (building 183) in 1918. TNT manufacture at the plant ceased following a series of accidents at other explosives factories such as those at Silvertown and Ashton-under-Lyne . Sylvain Dreyfus, a nephew of Charles Dreyfus, perished in the Ashton-under-Lyne disaster when the Hooley Hill Rubber and Chemical Works exploded. These and other accidents prompted the Government to concentrate explosives manufacture at factories sited well away from built up areas. The construction of

1222-409: A new azo dyes plant (building 48). An additional azo dyes plant (building 46) was added to the scheme in 1965 to replace (building 187). Extra warehousing was also added to the site including a new intermediates warehouse (building 71) and a new raw materials warehouse (building 50). 1964 marked the end of an era for the company with the decision to cease aniline production at Clayton. The aniline plant

1316-733: A new railway line was begun in 1916, that linked the works via a bridge across Ashton New Road to the existing Stuart Street Power Station branch line. In September 1918, the Basle Community of Interests was formed from an alliance between Society of Chemical Industry in Basle, the Sandoz Chemical Company Ltd and J.R. Geigy SA. The agreement between the three companies allowed the sharing of research and technical resources whilst each company retained its own autonomy. Later that same year, Sandoz and Geigy each acquired

1410-843: A world-class training and academy complex for all Manchester City men's, women's and youth football teams; a new 7,000 capacity academy stadium ; an institute of sport ; a sixth form college and their new global operational HQ on the site and its surrounding area, which would accompany the City of Manchester Stadium which opened opposite the site in 2002. These new facilities opened in December 2014 after two years of land remediation and construction work. Notes Citations Dyestuff The majority of natural dyes are derived from non-animal sources such as roots, berries, bark, leaves, wood, fungi and lichens . However, due to large-scale demand and technological improvements, most dyes used in

1504-559: Is added to the dye bath to help the uptake of the dye onto the fiber. Basic dyes are also used in the coloration of paper . Direct or substantive dyeing is normally carried out in a neutral or slightly alkaline dye bath, at or near boiling point , with the addition of either sodium chloride (NaCl) or sodium sulfate (Na 2 SO 4 ) or sodium carbonate (Na 2 CO 3 ). Direct dyes are used on cotton , paper, leather , wool, silk and nylon . They are also used as pH indicators and as biological stains . Laser dyes are used in

1598-516: Is an image of Britannia surrounded by the motto, with the words "For Meritorious Service" at the bottom; on the reverse is George V's Imperial and Royal Cypher, with the words "Instituted by King George V" at the bottom. The name of the recipient is engraved on the rim. This medal is nicknamed "the Gong", and comes in both full-sized and miniature versions – the latter for formal white-tie and semi-formal black-tie occasions. A lapel pin for everyday wear

1692-973: Is not a member of the College of Arms , as are many other heraldic officers; and the Lady Usher of the Purple Rod does not – unlike the Order of the Garter equivalent, the Lady Usher of the Black Rod – perform any duties related to the House of Lords . Since the Second World War, several Commonwealth realms have established their own national system of honours and awards and have created their own unique orders, decorations and medals. A number, though, continue to make recommendations for appointments to

1786-486: Is the food dye . Because food dyes are classed as food additives , they are manufactured to a higher standard than some industrial dyes. Food dyes can be direct, mordant and vat dyes, and their use is strictly controlled by legislation . Many are azo dyes, although anthraquinone and triphenylmethane compounds are used for colors such as green and blue . Some naturally occurring dyes are also used. A number of other classes have also been established, including: By

1880-463: Is used. The very fine particle size gives a large surface area that aids dissolution to allow uptake by the fiber. The dyeing rate can be significantly influenced by the choice of dispersing agent used during the grinding. Azoic dyeing is a technique in which an insoluble Azo dye is produced directly onto or within the fiber. This is achieved by treating a fiber with both diazoic and coupling components . With suitable adjustment of dyebath conditions

1974-600: The British Empire Medal , and the following year its recipients were granted the right to use the postnominal letters BEM. During the war, the BEM came to be used to recognise acts of bravery which did not merit the award of a George Cross or George Medal , a use which continued until the introduction of the Queen's Gallantry Medal in 1974. The designs of insignia of the order and medal were altered in 1937, prior to

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2068-592: The Empire Gallantry Medal , were given permission to use the postnominal letters EGM (and at the same time to add a laurel branch emblem to the ribbon of the medal); however, in 1940, awards of the EGM ceased and all holders of the medal were instructed to exchange it for a new and more prestigious gallantry award: the George Cross . In 1941, the medal of the order 'for meritorious service' was renamed

2162-559: The Order of Canada . On the other hand, the Australian Honours System unilaterally created in 1975 did not achieve bi-partisan support until 1992, which was when Australian federal and state governments agreed to cease Australian recommendations for British honours; the last Australian recommended Order of the British Empire appointments were in the 1989 Queen's Birthday Honours . New Zealand continued to use

2256-571: The Republic of Georgia in a prehistoric cave dated to 36,000 BP . Archaeological evidence shows that, particularly in India and Phoenicia , dyeing has been widely carried out for over 5,000 years. Early dyes were obtained from animal , vegetable or mineral sources, with no to very little processing. By far the greatest source of dyes has been from the plant kingdom , notably roots, berries, bark, leaves and wood, only few of which are used on

2350-444: The coronation of King George VI , 'in commemoration of the reign of King George V and Queen Mary, during which the Order was founded'. The figure of Britannia at the centre of the badge of the order was replaced with an image of the crowned heads of the late King and Queen Mary, and the words 'Instituted by King George V' were added to the reverse of the medal. The colour of the riband was also changed: twenty years earlier, prior to

2444-473: The 21st century quotas were introduced to ensure consistent representation among recipients across nine categories of eligibility: with the largest proportion of awards being reserved for community, voluntary and local service. Non-military awards of the British Empire Medal resumed in 2012, starting with 293 BEMs awarded for Queen Elizabeth II's Diamond Jubilee . In 2017 the centenary of

2538-792: The British Empire . Rather than using this chapel, the Order now holds its great services upstairs in the nave of the cathedral. In addition to the Chapel of the Order of the British Empire, St Paul's Cathedral also houses the Chapel of the Order of St Michael and St George . Religious services for the whole Order are held every four years; new Knights and Dames Grand Cross are installed at these services. Knights Grand Cross and Knights Commander prefix Sir , and Dames Grand Cross and Dames Commander prefix Dame , to their forenames. Wives of Knights may prefix Lady to their surnames, but no equivalent privilege exists for husbands of Knights or spouses of Dames. Such forms are not used by peers and princes, except when

2632-443: The British Empire for Gallantry. Any individual made a member of the order for gallantry after 14 January 1958 wears an emblem of two crossed silver oak leaves on the same ribbon as the badge, with a miniature version on the ribbon bar when worn alone. When the ribbon only is worn the emblem is worn in miniature. It could not be awarded posthumously , and was replaced in 1974 with the Queen's Gallantry Medal (QGM). If recipients of

2726-892: The Military Division of the order from the UK and across the Empire. Recommendations for all appointments to the Order of the British Empire were originally made on the nomination of the King's United Kingdom ministers (recommendations for overseas awards were made by the Foreign Office , the Colonial Office , the India Office and the Dominions Office ); but in the early 1940s the system was changed to enable

2820-436: The Order of the British Empire for Gallantry received promotion within the order, whether for gallantry or otherwise, they continued to wear also the insignia of the lower grade with the oak leaves; however, they used only the post-nominal letters of the higher grade. When the order was founded in 1917, badges, ribands and stars were appointed for wear by recipients. In 1929 mantles, hats and collars were added for recipients of

2914-520: The Order of the British Empire. In 2024 appointments to the order were made by the governments of: Most members of the order are citizens of the United Kingdom or Commonwealth realms that use the UK system of honours and awards. In addition, honorary awards may be made to citizens of nations where the monarch is not head of state ; these permit use of post-nominal letters, but not the title of Sir or Dame . Honorary appointees who later become

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3008-404: The Order, however, are not assigned any special precedence. As a general rule, only wives and children of male recipients are afforded privileges. Knights and Dames Grand Cross are also entitled to be granted heraldic supporters . They may, furthermore, encircle their arms with a depiction of the circlet (a circle bearing the motto) and the collar; the former is shown either outside or on top of

3102-486: The UK continue to make appointments to the order. Honorary awards may be made to citizens of other nations of which the order's sovereign is not the head of state. The five classes of appointment to the Order are, from highest grade to lowest grade: The senior two ranks of Knight or Dame Grand Cross and Knight or Dame Commander entitle their members to use the titles Sir for men and Dame for women before their forenames, except with honorary awards. King George V founded

3196-463: The United Kingdom; those who would formerly have met the criteria for the medal were instead made eligible for the MBE. In 2004, a report entitled A Matter of Honour: Reforming Our Honours System by a Commons select committee recommended phasing out the Order of the British Empire, as its title was "now considered to be unacceptable, being thought to embody values that are no longer shared by many of

3290-560: The addition of salt to produce a lake pigment . Textile dyeing dates back to the Neolithic period. Throughout history, people have dyed their textiles using common, locally available materials. Scarce dyestuffs that produced brilliant and permanent colors such as the natural invertebrate dyes Tyrian purple and crimson kermes were highly prized luxury items in the ancient and medieval world. Plant-based dyes such as woad , indigo , saffron , and madder were important trade goods in

3384-494: The announcement was made that the site would be closing with the loss of over 300 remaining jobs. A small number of staff were retained to assist in the decommissioning of the plant. The last workers left the site in 2007 and the remainder of the buildings were demolished shortly afterwards. Although initially expected to be re-used for housing, the site remained undeveloped for a number of years afterwards. Then in 2012, City Football Group (CFG) announced that they would be building

3478-403: The arts and sciences, work with charitable and welfare organisations, and public service outside the civil service . It comprises five classes of awards across both civil and military divisions, the most senior two of which make the recipient either a knight if male or a dame if female. There is also the related British Empire Medal , whose recipients are affiliated with, but not members of,

3572-455: The award of medal of the order to Lizzie Robinson, a munitions worker. The order had been established primarily as a civilian award; in August 1918, however, not long after its foundation, a number of awards were made to serving naval and military personnel. Four months later, a 'Military Division' was added to the order, to which serving personnel would in future be appointed. The classes were

3666-526: The carbonless copying paper business was made part of the Consumer Chemicals division and Clayton was designated the global centre for R&D, marketing and sales this type of product. Manufacturing was gradually transferred to China, India, Thailand and Mexico in response to sustained price competition from emerging competitors in China and India and the workforce was reduced accordingly. In 2004

3760-474: The cathedral. That year, Commonwealth awards made up 40% of all OBEs and MBEs awarded (and 35% of all living recipients of the higher awards). Gradually that proportion reduced as independent states within the Commonwealth established their own systems of honours . The last Canadian recommendation for the Order of the British Empire was an MBE for gallantry gazetted in 1966, a year before the creation of

3854-402: The centre for awards in the military division). From time to time the order was expanded: there was an increase in the maximum permitted number of recipients in 1933, and a further increase in 1937. During the Second World War, as had been the case during and after World War I, the number of military awards was greatly increased; between 1939 and 1946 there were more than 33,000 appointments to

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3948-418: The circlet. In 1929, to bring the order into line with the other orders of chivalry, members of the first class of the order (GBE) were provided with mantles, hats and collars. Only Knights/Dames Grand Cross wear these elaborate vestments; the hat is now rarely, if ever, worn. Use of the mantle is limited to important occasions (such as quadrennial services and coronations ). The mantle is always worn with

4042-492: The civil division were to be divided equally between UK and overseas awards. With regard to the Medal of the Order (but not the order itself), a distinction was made in 1922 between awards 'for gallantry' and awards 'for meritorious service' (each being appropriately inscribed, and the former having laurel leaves decorating the clasp, the latter oak leaves). In 1933 holders of the medal 'for gallantry', which had come to be known as

4136-444: The collar. Although the mantle was introduced in 1929, very few mantles would have been produced prior to the 1937 design changes, as there were few occasions for wearing them in the intervening years. On certain days designated by the sovereign, known as " collar days ", members attending formal events may wear the order's collar over their military uniform, formal day dress, evening wear or robes of office. Collars are returned upon

4230-412: The company began its post war reconstruction. The Centralite plant (building 300) was acquired from the Government and re-equipped as an intermediates plant and plans were drawn up for a new intermediates plant (building 151) which was completed in 1951. Other projects undertaken in the early 1950s included a new PAK-ice plant, a new power plant and a new waste gas tunnel and chimney. The company also began

4324-454: The company began production of aniline and aniline salt . In 1894, a brilliant young organic chemist Arthur George Green joined the company. Green had discovered the dye primuline in 1887 and under his guidance the company rapidly expanded its range of dyes. Green left the company in 1901. In 1897, the company was placed into voluntary liquidation and then reformed under the same name with an issued share capital of £140,000. Max Baerlein

4418-479: The country's population". The committee further suggested changing the name of the award to the Order of British Excellence, and changing the rank of Commander to Companion (as the former was said to have a "militaristic ring"), as well as advocating for the abolition of knighthoods and damehoods; the government, however, was not of the opinion that a case for change had been made, and the aforementioned suggestions and recommendations were not, therefore, pursued. In

4512-403: The death of their owners, but other insignia may be retained. The six office-holders of the order wear pearl-grey mantles lined with rose-pink, having on the right side a purple shield charged with the roundel from the badge. Each of these office-holders wears a unique badge of office, suspended from a gold chain worn around the neck. The British Empire Medal is made of silver. On the obverse

4606-626: The distinction between ranks in military operational gallantry awards will cease'. The reforms affected the order at various levels: for example the automatic award each year of a GBE to the Lord Mayor of London ceased; the OBE replaced the Imperial Service Order as an award for civil servants and the number of MBEs awarded each year was significantly increased. As part of these reforms the British Empire Medal stopped being awarded by

4700-410: The dyeing of cellulose acetate , and are water-insoluble. The dyes are finely ground in the presence of a dispersing agent and sold as a paste, or spray-dried and sold as a powder. Their main use is to dye polyester , but they can also be used to dye nylon, cellulose triacetate , and acrylic fibers. In some cases, a dyeing temperature of 130 °C (266 °F) is required, and a pressurized dyebath

4794-513: The economies of Asia and Europe. Across Asia and Africa, patterned fabrics were produced using resist dyeing techniques to control the absorption of color in piece-dyed cloth. Dyes from the New World such as cochineal and logwood were brought to Europe by the Spanish treasure fleets, and the dyestuffs of Europe were carried by colonists to America. Dyed flax fibers have been found in

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4888-500: The fabric in a solution of an organic compound, typically a nitrophenol derivative, and sulfide or polysulfide . The organic compound reacts with the sulfide source to form dark colors that adhere to the fabric. Sulfur Black 1, the largest selling dye by volume, does not have a well defined chemical structure. Some dyes commonly used in Staining: One other class that describes the role of dyes, rather than their mode of use,

4982-454: The fiber is attributed, at least partly, to salt formation between anionic groups in the dyes and cationic groups in the fiber. Acid dyes are not substantive to cellulosic fibers. Most synthetic food colors fall in this category. Examples of acid dye are Alizarine Pure Blue B, Acid red 88 , etc. Basic dyes are water-soluble cationic dyes that are mainly applied to acrylic fibers , but find some use for wool and silk. Usually acetic acid

5076-448: The fiber substrate. The covalent bonds that attach reactive dye to natural fibers make them among the most permanent of dyes. "Cold" reactive dyes, such as Procion MX , Cibacron F , and Drimarene K , are very easy to use because the dye can be applied at room temperature. Reactive dyes are by far the best choice for dyeing cotton and other cellulose fibers at home or in the art studio. Disperse dyes were originally developed for

5170-465: The first president of Israel. On 1 May 1911, the Society of Chemical Industry in Basle (later known as CIBA), took control of the company and in 1913 Charles Dreyfus resigned. The outbreak of war with Germany in 1914 led to lucrative contracts for the company including the production of 1,500 tons of TNT . The sites facilities were expanded considerably during the war including the construction of

5264-401: The forerunner to Bayer AG was formed in what became Wuppertal , Germany . In 1891, Paul Ehrlich discovered that certain cells or organisms took up certain dyes selectively. He then reasoned that a sufficiently large dose could be injected to kill pathogenic microorganisms, if the dye did not affect other cells. Ehrlich went on to use a compound to target syphilis , the first time a chemical

5358-529: The former was to be responsible for recording all proceedings connected with the order, issuing warrants under the seal of the order and making arrangements for investitures, while the latter (at that time the Permanent Secretary to the Treasury ) was responsible for collecting and tabulating the names of those who were to receive an award. The office of Dean was added in 1957. The King of Arms

5452-401: The governments of overseas dominions to make their own nominations; Canada and South Africa began doing so in 1942, followed by Australia, New Zealand and other Commonwealth realms. In May 1957, forty years after the foundation of the order, it was announced that St Paul's Cathedral was to serve as the church of the order, and in 1960 a chapel was dedicated for its use within the crypt of

5546-482: The gradual demise of the British textile industry, most textile production shifted to countries such as China and India with the textile dye industry following. CIBA merged their life science businesses with Sandoz in 1997, forming Novartis and Syngenta , and spinning off their respective industrial chemicals ' businesses separately to form Ciba Speciality Chemicals and Clariant respectively. This left Clayton as

5640-450: The highest class of the order (GBE). The designs of all these items underwent major changes in 1937. The badge is worn by all members of the order; the size, colour and design depends on the class of award. The badge for all classes is in the form of a cross patonce (having the arms growing broader and floriated toward the end) with a medallion in the centre, the obverse of which bears a crowned image of George V and Queen Mary within

5734-446: The insignia to Buckingham Palace and by ceasing to make reference to their honour, but they still hold the honour unless and until annulled by the monarch. In 2003, The Sunday Times published a list of the people who had rejected the Order of the British Empire, including David Bowie , John Cleese , Nigella Lawson , Elgar Howarth , L. S. Lowry , George Melly , and J. G. Ballard . In addition, Ballard voiced his opposition to

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5828-640: The junior post-nominal letters. The British sovereign is the sovereign of the order and appoints all other officers of the order (by convention, on the advice of the governments of the United Kingdom and some Commonwealth realms ). The second-most senior officer is the Grand Master (a 'Prince of the Blood Royal, or other exalted personage' appointed by the sovereign, who, by virtue of their appointment, becomes 'the First or Principal Knight Grand Cross of

5922-528: The latter. Knights and Dames Commander and Commanders may display the circlet, but not the collar, surrounding their arms. The badge is depicted suspended from the collar or circlet. See List of current honorary knights and dames of the Order of the British Empire Only the monarch can annul an honour. The Honours Forfeiture Committee considers cases and makes recommendations for forfeiture. An individual can renounce their honour by returning

6016-463: The left breast, by Knights and Dames Grand Cross; Knights and Dames Commander wear a smaller star composed of 'four equal points and four lesser'. The star is not worn by the more junior classes. Prior to 1937 each star had in the centre a gold medallion with a figure of Britannia, surrounded by a crimson circlet inscribed with the motto of the order ('For God and the Empire'); since 1937 the effigies of King George V and Queen Mary have been shown within

6110-559: The modern world are synthetically produced from substances such as petrochemicals. Some are extracted from insects and/or minerals . Synthetic dyes are produced from various chemicals. The great majority of dyes are obtained in this way because of their superior cost, optical properties (color), and resilience (fastness, mordancy). Both dyes and pigments are colored, because they absorb only some wavelengths of visible light . Dyes are usually soluble in some solvent, whereas pigments are insoluble. Some dyes can be rendered insoluble with

6204-473: The names of the former are written out in their fullest forms. Male clergy of the Church of England or the Church of Scotland do not use the title Sir (unless they were knighted before being ordained) as they do not receive the accolade (they are not dubbed "knight" with a sword), although they do append the post-nominal letters ; dames do not receive the accolade, and therefore female clergy are free to use

6298-718: The nature of their chromophore , dyes are divided into: Dyes produced by the textile, printing and paper industries are a source of pollution of rivers and waterways. An estimated 700,000 tons of dyestuffs are produced annually (1990 data). The disposal of that material has received much attention, using chemical and biological means. A "vital dye" or stain is a dye capable of penetrating living cells or tissues without causing immediate visible degenerative changes. Such dyes are useful in medical and pathological fields in order to selectively color certain structures (such as cells) in order to distinguish them from surrounding tissue and thus make them more visible for study (for instance, under

6392-399: The numbers restricted to the order as full members do. Although the Order of the British Empire has by far the highest number of members of the British orders of chivalry, with more than 100,000 living members worldwide, there are fewer appointments to knighthoods than in other orders. From time to time, individuals may be promoted to a higher grade within the Order, thereby ceasing usage of

6486-620: The order alongside its own honours until the establishment of the New Zealand Order of Merit in 1996. Other Commonwealth realms have continued to use the Order of the British Empire alongside their own honours. In 1993 the Prime Minister, John Major , instituted a reform of the honours system with the aim 'that exceptional service or achievement will be more widely recognised; that greater importance will be given to voluntary service; that automatic honours will end; that

6580-581: The order to fill gaps in the British honours system : In particular, George V wished to create an order to honour the many thousands of individuals from across the Empire who had served in a variety of non-combat roles during the First World War . From its foundation the order consisted of five classes (GBE, KBE/DBE, CBE, OBE and MBE) and was open to both women and men; provision was also made for conferring honorary awards on foreign recipients. At

6674-409: The order was celebrated with a service at St Paul's Cathedral. The order is limited to 300 Knights and Dames Grand Cross, 845 Knights and Dames Commander, and 8,960 Commanders. There are no limits applied to the total number of members of the fourth and fifth classes, but no more than 858 officers and 1,464 members may be appointed per year. Foreign appointees, as honorary members, do not contribute to

6768-410: The order's establishment, Queen Mary had made it known that pink would be her preferred colour for the riband of the proposed new order, but, in the event, purple was chosen. Following her appointment as Grand Master of the order in 1936 a change was duly made and since 9 March 1937 the riband of the order has been 'rose pink edged with pearl grey’ (with the addition of a vertical pearl grey stripe in

6862-402: The order. The order was established on 4 June 1917 by King George V , who created the order to recognise 'such persons, male or female, as may have rendered or shall hereafter render important services to Our Empire'. Equal recognition was to be given for services rendered in the UK and overseas. Today the majority of recipients are UK citizens, though a number of Commonwealth realms outside

6956-618: The percentage of total cells that stain negatively. Because the dye determines whether the staining is supravital or intravital, a combination of supravital and vital dyes can be used to more accurately classify cells into various groups (e.g., viable, dead, dying). Member of the Most Excellent Order of the British Empire The Most Excellent Order of the British Empire is a British order of chivalry , rewarding contributions to

7050-474: The production of some lasers, optical media ( CD-R ), and camera sensors ( color filter array ). Mordant dyes require a mordant , which improves the fastness of the dye against water, light and perspiration . The choice of mordant is very important as different mordants can change the final color significantly. Most natural dyes are mordant dyes and there is therefore a large literature base describing dyeing techniques. The most important mordant dyes are

7144-449: The removal of a chemical spoil heap nicknamed the “mucky mountain”, which was left behind by a soda ash manufacturer that previously occupied the site. In 1957, a plan was drawn up to re-build virtually the whole of the site. The project involved the construction of a new triphenylmethane dyes plant (building 75), a new laboratories block (building 80), a milling and blending plant (building 81), an intermediates plant (building 74) and

7238-603: The same Order'). The position of Grand Master has been held by the following people: In addition to the sovereign and the grand master , the order has six further officers: At its foundation the order was served by three officers: the King of Arms, the Registrar & Secretary and the Gentleman Usher of the Purple Rod. In 1922 the Prelate was added, and the office of Registrar was separated from that of Secretary:

7332-466: The same as for the Civil Division (as it was now termed), but military awards were distinguished by the addition of a central vertical red stripe to the purple riband of the civil awards. In 1920 appointment as an MBE 'for an act of gallantry' was granted for the first time, to Sydney Frank Blanck Esq, who had rescued an injured man from a burning building containing explosives. In December 1922

7426-573: The same time, alongside the order, the Medal of the Order of the British Empire was instituted, to serve as a lower award granting recipients affiliation but not membership. The first investiture took place at Ibrox Stadium , as part of a royal visit to the Glasgow shipyards, with the appointment of Alexander Ure, 1st Baron Strathclyde as a GBE (in recognition of his role as chairman of the Scottish War Savings Committee) and

7520-461: The standard of the George Medal (even though, as appointments to an order of chivalry, they were listed before it on the Order of Wear . In contrast to awards for meritorious service, which usually appear without a citation, there were often citations for gallantry awards, some detailed and graphic. From 14 January 1958, these awards were designated Commander, Officer or Member of the Order of

7614-416: The statutes of the order were amended; there having been a large number of awards for war work prior to this date, these amended statutes placed the order on more of a peacetime footing. For the first time numbers of appointments were limited, with the stipulation that senior awards in the Civil Division were to outnumber those in the Military Division by a proportion of six to one. Furthermore appointments in

7708-532: The synthetic mordant dyes, or chrome dyes, used for wool; these comprise some 30% of dyes used for wool, and are especially useful for black and navy shades. The mordant potassium dichromate is applied as an after-treatment. It is important to note that many mordants, particularly those in the heavy metal category, can be hazardous to health and extreme care must be taken in using them. Vat dyes are essentially insoluble in water and incapable of dyeing fibres directly. However, reduction in alkaline liquor produces

7802-506: The title Dame . Knights and Dames Grand Cross use the post-nominal GBE; Knights Commander, KBE; Dames Commander, DBE; Commanders, CBE; Officers, OBE; and Members, MBE. The post-nominal for the British Empire Medal is BEM. Members of all classes of the order are assigned positions in the order of precedence . Wives of male members of all classes also feature on the order of precedence, as do sons, daughters and daughters-in-law of Knights Grand Cross and Knights Commander; relatives of Ladies of

7896-404: The two components react to produce the required insoluble azo dye. This technique of dyeing is unique, in that the final color is controlled by the choice of the diazoic and coupling components. This method of dyeing cotton is declining in importance due to the toxic nature of the chemicals used. Sulfur dyes are inexpensive dyes used to dye cotton with dark colors. Dyeing is effected by heating

7990-408: The underlying concept in either case being that the cells examined are still alive. In a stricter sense, the term "vital staining" means the polar opposite of "supravital staining." If living cells absorb the stain during supravital staining, they exclude it during "vital staining"; for example, they color negatively while only dead cells color positively, and thus viability can be determined by counting

8084-565: The visible region (some examples are nitro , azo , quinoid groups) and an auxochrome which serves to deepen the color. This theory has been superseded by modern electronic structure theory which states that the color in dyes is due to excitation of valence π-electrons by visible light. Dyes are classified according to their solubility and chemical properties. Acid dyes are water - soluble anionic dyes that are applied to fibers such as silk , wool , nylon and modified acrylic fibers using neutral to acid dye baths. Attachment to

8178-412: The water-soluble alkali metal salt of the dye. This form is often colorless, in which case it is referred to as a Leuco dye , and has an affinity for the textile fibre. Subsequent oxidation reforms the original insoluble dye. The color of denim is due to indigo , the original vat dye. Reactive dyes utilize a chromophore attached to a substituent that is capable of directly reacting with

8272-406: Was appointed as company chairman with Charles Dreyfus as managing director. On 31 January 1900 a young worker, Thomas Musgrave, became caught in machinery and was killed instantly. Chaim Weizmann joined the company in 1905 as a part-time research consultant, leaving in 1908 to pursue an academic career. Weizmann would later achieve fame through his work on bacterial fermentation and go on to become

8366-495: Was completed followed in 1938 by the construction of a new vat dyes complex (buildings 188, 189 and 190). The completion of the vat dyes project was held up by the outbreak of war in 1939. In 1940, a new Ministry of Supply factory (building 300) was constructed adjacent to the site for the manufacture of explosives additive Centralite I . The company also gained an important contract to manufacture monomethylaniline used as an antiknock agent in high octane aviation fuel. In 1941,

8460-436: Was demolished the following year. In 1971, CIBA and Geigy merged to form CIBA-GEIGY. The combined group retained a majority shareholding in the Clayton Aniline Company with Sandoz holding the remaining 25% of the equity. CAC was allowed to continue as a separate subsidiary under the chairmanship of Sir Arthur Vere Harvey . At its peak in the 1970s, the site occupied over 57 acres and employed over 2,000 people. However, due to

8554-402: Was first announced at the end of December 2006, and is available to recipients of all levels of the order, as well as to holders of the British Empire Medal . The pin design is not unique to any level. The pin features the badge of the order, enclosed in a circle of ribbon of its colours of pink and grey. Lapel pins must be purchased separately by a member of the order. The creation of such a pin

8648-469: Was made a substantive member and subsequently styled as Sir Terry Wogan). Although initially intended to recognise meritorious service, the order began to also be awarded for gallantry. There were an increased number of cases in the Second World War for service personnel and civilians including the merchant navy, police, emergency services and civil defence, mostly MBEs but with a small number of OBEs and CBEs. Such awards were for gallantry that did not reach

8742-585: Was recommended in Sir Hayden Phillips ' review of the honours system in 2004. The Chapel of the Order of the British Empire is in St Paul's Cathedral . It occupies the far eastern end of the cathedral crypt and was dedicated in 1960. The only heraldic banners normally on display in the chapel are those of the Sovereign of the Order of the British Empire and of the Grand Master of the Order of

8836-448: Was used in order to selectively kill bacteria in the body. He also used methylene blue to target the plasmodium responsible for malaria . The color of a dye is dependent upon the ability of the substance to absorb light within the visible region of the electromagnetic spectrum (380–750 nm). An earlier theory known as Witt theory stated that a colored dye had two components, a chromophore which imparts color by absorbing light in

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