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89-581: A bog or bogland is a wetland that accumulates peat as a deposit of dead plant materials – often mosses , typically sphagnum moss. It is one of the four main types of wetlands . Other names for bogs include mire , mosses, quagmire, and muskeg ; alkaline mires are called fens . A bayhead is another type of bog found in the forest of the Gulf Coast states in the United States. They are often covered in heath or heather shrubs rooted in

178-405: A carr , as silt or peat accumulates within the lake. Eventually, peat builds up to a level where the land surface is too flat for ground or surface water to reach the center of the wetland. This part, therefore, becomes wholly rain-fed (ombrotrophic), and the resulting acidic conditions allow the development of bog (even if the substrate is non-acidic). The bog continues to form peat, and over time

267-711: A sink or a source of carbon, depending on the specific wetland. If they function as a carbon sink, they can help with climate change mitigation . However, wetlands can also be a significant source of methane emissions due to anaerobic decomposition of soaked detritus , and some are also emitters of nitrous oxide . Humans are disturbing and damaging wetlands in many ways, including oil and gas extraction , building infrastructure, overgrazing of livestock , overfishing , alteration of wetlands including dredging and draining, nutrient pollution , and water pollution . Wetlands are more threatened by environmental degradation than any other ecosystem on Earth, according to

356-565: A tetrahedral arrangement. The symmetry of the isolated anion is the same as that of methane. The sulfur atom is in the +6 oxidation state while the four oxygen atoms are each in the −2 state. The sulfate ion carries an overall charge of −2 and it is the conjugate base of the bisulfate (or hydrogensulfate) ion, HSO − 4 , which is in turn the conjugate base of H 2 SO 4 , sulfuric acid . Organic sulfate esters , such as dimethyl sulfate , are covalent compounds and esters of sulfuric acid. The tetrahedral molecular geometry of

445-495: A broad definition: Because all bogs have peat, they are a type of peatland. As a peat-producing ecosystem, they are also classified as mires , along with fens. Bogs differ from fens, in that fens receive water and nutrients from mineral-rich surface or groundwater, while bogs receive water and nutrients from precipitation. Because fens are supplied with mineral-rich water, they tend to range from slightly acidic to slightly basic, while bogs are always acidic because precipitation lacks

534-808: A butterfly called the bog copper ( Lycaena epixanthe ). In Ireland, the viviparous lizard , the only known reptile in the country, dwells in bogland. The United Kingdom in its Biodiversity Action Plan establishes bog habitats as a priority for conservation. Russia has a large reserve system in the West Siberian Lowland . The highest protected status occurs in Zapovedniks ( IUCN category IV); Gydansky and Yugansky are two prominent examples. Bogs are fragile ecosystems, and have been deteriorating quickly, as archaeologists and scientists have been recently finding. Bone material found in bogs has had accelerated deterioration from first analyses in

623-610: A characteristic brown colour, which comes from dissolved peat tannins . In general, the low fertility and cool climate result in relatively slow plant growth, but decay is even slower due to low oxygen levels in saturated bog soils. Hence, peat accumulates. Large areas of the landscape can be covered many meters deep in peat. Bogs have distinctive assemblages of animal, fungal, and plant species, and are of high importance for biodiversity , particularly in landscapes that are otherwise settled and farmed. Bogs are widely distributed in cold, temperate climes , mostly in boreal ecosystems in

712-535: A debate on the relative importance of pi bonding and bond polarity ( electrostatic attraction ) in causing the shortening of the S−O bond. The outcome was a broad consensus that d orbitals play a role, but are not as significant as Pauling had believed. A widely accepted description involving pπ – dπ bonding was initially proposed by Durward William John Cruickshank . In this model, fully occupied p orbitals on oxygen overlap with empty sulfur d orbitals (principally

801-402: A frequency and duration to support, and that under normal circumstances do support, a prevalence of vegetation typically adapted for life in saturated soil conditions. Wetlands generally included swamps, marshes, bogs, and similar areas.' For each of these definitions and others, regardless of the purpose, hydrology is emphasized (shallow waters, water-logged soils). The soil characteristics and

890-570: A ligand attaching either by one oxygen (monodentate) or by two oxygens as either a chelate or a bridge. An example is the complex Co ( en ) 2 (SO 4 )] Br or the neutral metal complex Pt SO 4 ( PPh 3 ) 2 ] where the sulfate ion is acting as a bidentate ligand. The metal–oxygen bonds in sulfate complexes can have significant covalent character. Sulfates are widely used industrially. Major compounds include: Sulfate-reducing bacteria , some anaerobic microorganisms, such as those living in sediment or near deep sea thermal vents, use

979-533: A number of governmental and conservation agencies. They can provide habitat for mammals, such as caribou , moose , and beavers , as well as for species of nesting shorebirds, such as Siberian cranes and yellowlegs . Bogs contain species of vulnerable reptilians such as the bog turtle . Bogs even have distinctive insects; English bogs give a home to a yellow fly called the hairy canary fly ( Phaonia jaroschewskii ), and bogs in North America are habitat for

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1068-1259: A polar climate, wetland temperatures can be as low as −50 °C (−58 °F). Peatlands in arctic and subarctic regions insulate the permafrost , thus delaying or preventing its thawing during summer, as well as inducing its formation. The amount of precipitation a wetland receives varies widely according to its area. Wetlands in Wales , Scotland , and western Ireland typically receive about 1,500 mm (59 in) per year. In some places in Southeast Asia , where heavy rains occur, they can receive up to 10,000 mm (390 in). In some drier regions, wetlands exist where as little as 180 mm (7.1 in) precipitation occurs each year. Temporal variation: Surface flow may occur in some segments, with subsurface flow in other segments. Wetlands vary widely due to local and regional differences in topography , hydrology , vegetation , and other factors, including human involvement. Other important factors include fertility, natural disturbance, competition, herbivory , burial and salinity. When peat accumulates, bogs and fens arise. The most important factor producing wetlands

1157-540: A portion of the overall water cycle, which also includes atmospheric water (precipitation) and groundwater . Many wetlands are directly linked to groundwater and they can be a crucial regulator of both the quantity and quality of water found below the ground. Wetlands that have permeable substrates like limestone or occur in areas with highly variable and fluctuating water tables have especially important roles in groundwater replenishment or water recharge. Substrates that are porous allow water to filter down through

1246-419: A protective barrier to coastal shoreline. Mangroves stabilize the coastal zone from the interior and will migrate with the shoreline to remain adjacent to the boundary of the water. The main conservation benefit these systems have against storms and storm surges is the ability to reduce the speed and height of waves and floodwaters. Sulfate The sulfate or sulphate ion is a polyatomic anion with

1335-526: A roothold. The result is a narrow, permanently wet habitat. After drying, peat is used as a fuel , and it has been used that way for centuries. More than 20% of home heat in Ireland comes from peat, and it is also used for fuel in Finland, Scotland, Germany, and Russia. Russia is the leading exporter of peat for fuel, at more than 90 million metric tons per year. Ireland's Bord na Móna ("peat board")

1424-402: A shallow dome of bog peat develops into a raised bog. The dome is typically a few meters high in the center and is often surrounded by strips of fen or other wetland vegetation at the edges or along streamsides where groundwater can percolate into the wetland. The various types of raised bog may be divided into: In cool climates with consistently high rainfall (on more than c. 235 days a year),

1513-422: A strong influence on wetland water chemistry, particularly in coastal wetlands and in arid and semiarid regions with large precipitation deficits. Natural salinity is regulated by interactions between ground and surface water, which may be influenced by human activity. Carbon is the major nutrient cycled within wetlands. Most nutrients, such as sulfur , phosphorus , carbon , and nitrogen are found within

1602-410: A unique kind of wetland where lush plant growth and slow decay of dead plants (under anoxic conditions) results in organic peat accumulating; bogs, fens, and mires are different names for peatlands. Variations of names for wetland systems: Some wetlands have localized names unique to a region such as the prairie potholes of North America's northern plain, pocosins , Carolina bays and baygalls of

1691-452: A wetland is "an ecosystem that arises when inundation by water produces soils dominated by anaerobic and aerobic processes, which, in turn, forces the biota, particularly rooted plants, to adapt to flooding". Sometimes a precise legal definition of a wetland is required. The definition used for regulation by the United States government is: 'The term "wetlands" means those areas that are inundated or saturated by surface or ground water at

1780-422: A wetland system includes its plants ( flora ) and animals ( fauna ) and microbes (bacteria, fungi). The most important factor is the wetland's duration of flooding. Other important factors include fertility and salinity of the water or soils. The chemistry of water flowing into wetlands depends on the source of water, the geological material that it flows through and the nutrients discharged from organic matter in

1869-403: A wetland) affects hydro-periods (temporal fluctuations in water levels) by controlling the water balance and water storage within a wetland. Landscape characteristics control wetland hydrology and water chemistry. The O 2 and CO 2 concentrations of water depend upon temperature , atmospheric pressure and mixing with the air (from winds or water flows). Water chemistry within wetlands

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1958-558: A whole. To replace these wetland ecosystem services , enormous amounts of money would need to be spent on water purification plants, dams, levees, and other hard infrastructure, and many of the services are impossible to replace. Floodplains and closed-depression wetlands can provide the functions of storage reservoirs and flood protection. The wetland system of floodplains is formed from major rivers downstream from their headwaters . "The floodplains of major rivers act as natural storage reservoirs, enabling excess water to spread out over

2047-594: A wide area, which reduces its depth and speed. Wetlands close to the headwaters of streams and rivers can slow down rainwater runoff and spring snowmelt so that it does not run straight off the land into water courses. This can help prevent sudden, damaging floods downstream." Notable river systems that produce wide floodplains include the Nile River , the Niger river inland delta, the Zambezi River flood plain,

2136-494: Is a relatively short-lived greenhouse gas), it is believed that simultaneous reductions in both would effectively cancel each other out. On regional and global scale, air pollution can affect the water cycle , in a manner similar to some natural processes. One example is the impact of Sahara dust on hurricane formation: air laden with sand and mineral particles moves over the Atlantic Ocean, where they block some of

2225-440: Is determined by the pH , salinity , nutrients, conductivity , soil composition, hardness , and the sources of water. Water chemistry varies across landscapes and climatic regions. Wetlands are generally minerotrophic (waters contain dissolved materials from soils) with the exception of ombrotrophic bogs that are fed only by water from precipitation. Because bogs receive most of their water from precipitation and humidity from

2314-633: Is either freshwater , brackish or saltwater . The main types of wetland are defined based on the dominant plants and the source of the water. For example, marshes are wetlands dominated by emergent herbaceous vegetation such as reeds , cattails and sedges . Swamps are dominated by woody vegetation such as trees and shrubs (although reed swamps in Europe are dominated by reeds, not trees). Mangrove forest are wetlands with mangroves , halophytic woody plants that have evolved to tolerate salty water . Examples of wetlands classified by

2403-412: Is hydrology, or flooding . The duration of flooding or prolonged soil saturation by groundwater determines whether the resulting wetland has aquatic, marsh or swamp vegetation . Other important factors include soil fertility, natural disturbance, competition, herbivory , burial, and salinity. When peat from dead plants accumulates, bogs and fens develop. Wetland hydrology is associated with

2492-408: Is the conjugate base of sulfuric acid ( H 2 SO 4 ). Sulfuric acid is classified as a strong acid; in aqueous solutions it ionizes completely to form hydronium ( H 3 O ) and hydrogensulfate ( HSO − 4 ) ions. In other words, the sulfuric acid behaves as a Brønsted–Lowry acid and is deprotonated to form hydrogensulfate ion. Hydrogensulfate has a valency of 1. An example of

2581-401: Is the most insoluble sulfate known. The barium derivative is useful in the gravimetric analysis of sulfate: if one adds a solution of most barium salts, for instance barium chloride , to a solution containing sulfate ions, barium sulfate will precipitate out of solution as a whitish powder. This is a common laboratory test to determine if sulfate anions are present. The sulfate ion can act as

2670-451: Is the only place in the world where both crocodiles and alligators coexist. The saltwater crocodile inhabits estuaries and mangroves. Snapping turtles also inhabit wetlands. Birds , particularly waterfowl and waders use wetlands extensively. Mammals of wetlands include numerous small and medium-sized species such as voles , bats , muskrats and platypus in addition to large herbivorous and apex predator species such as

2759-545: Is usually saturated with water". More precisely, wetlands are areas where "water covers the soil , or is present either at or near the surface of the soil all year or for varying periods of time during the year, including during the growing season". A patch of land that develops pools of water after a rain storm would not necessarily be considered a "wetland", even though the land is wet. Wetlands have unique characteristics: they are generally distinguished from other water bodies or landforms based on their water level and on

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2848-518: Is zinc sulfate heptahydrate, ZnSO 4 ·7H 2 O . Alum , a double sulfate of potassium and aluminium with the formula K 2 Al 2 (SO 4 ) 4 ·24H 2 O , figured in the development of the chemical industry. Sulfates occur as microscopic particles ( aerosols ) resulting from fossil fuel and biomass combustion. They increase the acidity of the atmosphere and form acid rain . The anaerobic sulfate-reducing bacteria Desulfovibrio desulfuricans and D. vulgaris can remove

2937-672: The Haraldskær Woman and Tollund Man in Denmark, and Lindow man found at Lindow Common in England. The Tollund Man was so well preserved that when the body was discovered in 1950, the discoverers thought it was a recent murder victim and researchers were even able to tell the last meal that the Tollund Man ate before he died: porridge and fish. This process happens because of the low oxygen levels of bogs in combination with

3026-505: The Millennium Ecosystem Assessment from 2005. Methods exist for assessing wetland ecological health . These methods have contributed to wetland conservation by raising public awareness of the functions that wetlands can provide. Since 1971, work under an international treaty seeks to identify and protect " wetlands of international importance ." A simplified definition of wetland is "an area of land that

3115-1314: The Northern Hemisphere . The world's largest wetland is the peat bogs of the Western Siberian Lowlands in Russia , which cover more than a million square kilometres. Large peat bogs also occur in North America, particularly the Hudson Bay Lowland and the Mackenzie River Basin. They are less common in the Southern Hemisphere, with the largest being the Magellanic moorland , comprising some 44,000 square kilometres (17,000 sq mi) in southern South America. Sphagnum bogs were widespread in northern Europe but have often been cleared and drained for agriculture. A paper led by Graeme T. Swindles in 2019 showed that peatlands across Europe have undergone rapid drying in recent centuries owing to human impacts including drainage, peat cutting and burning. A 2014 expedition leaving from Itanga village, Republic of

3204-688: The Pantanal in South America, and the Sundarbans in the Ganges - Brahmaputra delta. Wetlands contribute many ecosystem services that benefit people. These include for example water purification , stabilization of shorelines, storm protection and flood control . In addition, wetlands also process and condense carbon (in processes called carbon fixation and sequestration ), and other nutrients and water pollutants . Wetlands can act as

3293-444: The atmosphere , their water usually has low mineral ionic composition. In contrast, wetlands fed by groundwater or tides have a higher concentration of dissolved nutrients and minerals. Fen peatlands receive water both from precipitation and ground water in varying amounts so their water chemistry ranges from acidic with low levels of dissolved minerals to alkaline with high accumulation of calcium and magnesium . Salinity has

3382-457: The barley used in making Scotch whisky . Once the peat has been extracted it can be difficult to restore the wetland , since peat accumulation is a slow process. More than 90% of the bogs in England have been damaged or destroyed. In 2011 plans for the elimination of peat in gardening products were announced by the UK government. The peat in bogs is an important place for the storage of carbon. If

3471-576: The beavers , coypu , swamp rabbit , Florida panther , jaguar , and moose . Wetlands attract many mammals due to abundant seeds, berries, and other vegetation as food for herbivores, as well as abundant populations of invertebrates, small reptiles and amphibians as prey for predators. Invertebrates of wetlands include aquatic insects such as dragonflies , aquatic bugs and beetles , midges, mosquitos , crustaceans such as crabs, crayfish, shrimps, microcrustaceans, mollusks like clams, mussels, snails and worms. Invertebrates comprise more than half of

3560-520: The empirical formula SO 2− 4 . Salts, acid derivatives, and peroxides of sulfate are widely used in industry. Sulfates occur widely in everyday life. Sulfates are salts of sulfuric acid and many are prepared from that acid. "Sulfate" is the spelling recommended by IUPAC , but "sulphate" was traditionally used in British English . The sulfate anion consists of a central sulfur atom surrounded by four equivalent oxygen atoms in

3649-414: The 1940s. This has been found to be from fluctuations in ground water and increase in acidity in lower areas of bogs that is affecting the rich organic material. Many of these areas have been permeated to the lowest levels with oxygen, which dries and cracks layers. There have been some temporary solutions to try and fix these issues, such as adding soil to the tops of threatened areas, yet they do not work in

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3738-520: The Congo , discovered a peat bog "as big as England " which stretches into neighboring Democratic Republic of Congo . Like all wetlands, it is difficult to rigidly define bogs for a number of reasons, including variations between bogs, the in-between nature of wetlands as an intermediate between terrestrial and aquatic ecosystems, and varying definitions between wetland classification systems. However, there are characteristics common to all bogs that provide

3827-639: The Okavango River inland delta, the Kafue River flood plain, the Lake Bangweulu flood plain (Africa), Mississippi River (US), Amazon River (South America), Yangtze River (China), Danube River (Central Europe) and Murray-Darling River (Australia). Groundwater replenishment can be achieved for example by marsh , swamp , and subterranean karst and cave hydrological systems. The surface water visibly seen in wetlands only represents

3916-567: The Reduction of Sulfur Emissions under the Convention on Long-Range Transboundary Air Pollution , and with similar improvements. Since changes in aerosol concentrations already have an impact on the global climate, they would necessarily influence future projections as well. In fact, it is impossible to fully estimate the warming impact of all greenhouse gases without accounting for the counteracting cooling from aerosols. Regardless of

4005-522: The Southeastern US, mallines of Argentina, Mediterranean seasonal ponds of Europe and California, turloughs of Ireland, billabongs of Australia, among many others. Wetlands are found throughout the world in different climates. Temperatures vary greatly depending on the location of the wetland. Many of the world's wetlands are in the temperate zones , midway between the North or South Poles and

4094-502: The US, the best known classifications are the Cowardin classification system and the hydrogeomorphic (HGM) classification system. The Cowardin system includes five main types of wetlands: marine (ocean-associated), estuarine (mixed ocean- and river-associated), riverine (within river channels), lacustrine (lake-associated) and palustrine (inland nontidal habitats). Peatlands are

4183-610: The United States' commercial fish and shellfish stocks depend solely on estuaries to survive. Amphibians such as frogs and salamanders need both terrestrial and aquatic habitats in which to reproduce and feed. Because amphibians often inhabit depressional wetlands like prairie potholes and Carolina bays, the connectivity among these isolated wetlands is an important control of regional populations. While tadpoles feed on algae, adult frogs forage on insects. Frogs are sometimes used as an indicator of ecosystem health because their thin skin permits absorption of nutrients and toxins from

4272-504: The antibonding S−OH orbitals, weakening them resulting in the longer bond length of the latter. However, Pauling's representation for sulfate and other main group compounds with oxygen is still a common way of representing the bonding in many textbooks. The apparent contradiction can be clarified if one realizes that the covalent double bonds in the Lewis structure actually represent bonds that are strongly polarized by more than 90% towards

4361-454: The black sulfate crust that often tarnishes buildings. After 1990, the global dimming trend had clearly switched to global brightening. This followed measures taken to combat air pollution by the developed nations , typically through flue-gas desulfurization installations at thermal power plants , such as wet scrubbers or fluidized bed combustion . In the United States, sulfate aerosols have declined significantly since 1970 with

4450-513: The combination of low nutrient levels and waterlogging. Sphagnum is generally abundant, along with ericaceous shrubs. The shrubs are often evergreen, which may assist in conservation of nutrients. In drier locations, evergreen trees can occur, in which case the bog blends into the surrounding expanses of boreal evergreen forest. Sedges are one of the more common herbaceous species. Carnivorous plants such as sundews ( Drosera ) and pitcher plants (for example Sarracenia purpurea ) have adapted to

4539-456: The current strength of aerosol cooling, all future climate change scenarios project decreases in particulates and this includes the scenarios where 1.5 °C (2.7 °F) and 2 °C (3.6 °F) targets are met: their specific emission reduction targets assume the need to make up for lower dimming. Since models estimate that the cooling caused by sulfates is largely equivalent to the warming caused by atmospheric methane (and since methane

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4628-420: The d z and d x – y ). However, in this description, despite there being some π character to the S−O bonds, the bond has significant ionic character. For sulfuric acid, computational analysis (with natural bond orbitals ) confirms a clear positive charge on sulfur (theoretically +2.45) and a low 3d occupancy. Therefore, the representation with four single bonds is the optimal Lewis structure rather than

4717-449: The deepest part of the valley, and a stream may run through the surface of the bog. Valley bogs may develop in relatively dry and warm climates, but because they rely on ground or surface water, they only occur on acidic substrates. These develop from a lake or flat marshy area, over either non-acidic or acidic substrates. Over centuries there is a progression from open lake, to a marsh, to a fen (or, on acidic substrates, valley bog), to

4806-556: The dissolved minerals (e.g. calcium , magnesium , carbonate ) that act to buffer the natural acidity of atmospheric carbon dioxide . Geography and geology both impact the hydrology: as groundwater mineral content reflects the bedrock geology, there can be great deal of variability in some common ions (e.g. manganese , iron ) while proximity to coastal areas is associated with higher sulfate and sodium concentrations. There are many highly specialized animals, fungi, and plants associated with bog habitat. Most are capable of tolerating

4895-460: The edges of acidic lakes. The bog vegetation, mostly sphagnum moss anchored by sedges (such as Carex lasiocarpa ), forms a floating mat approximately half a meter thick on the surface of water or above very wet peat. White spruce ( Picea glauca ) may grow in this bog regime. Walking on the surface causes it to move – larger movements may cause visible ripples on the surface, or they may even make trees sway. The bog mat may eventually spread across

4984-634: The equator. In these zones, summers are warm and winters are cold, but temperatures are not extreme. In subtropical zone wetlands, such as along the Gulf of Mexico , average temperatures might be 11 °C (52 °F). Wetlands in the tropics are subjected to much higher temperatures for a large portion of the year. Temperatures for wetlands on the Arabian Peninsula can exceed 50 °C (122 °F) and these habitats would therefore be subject to rapid evaporation. In northeastern Siberia , which has

5073-504: The following areas: According to the Ramsar Convention: The economic worth of the ecosystem services provided to society by intact, naturally functioning wetlands is frequently much greater than the perceived benefits of converting them to 'more valuable' intensive land use – particularly as the profits from unsustainable use often go to relatively few individuals or corporations, rather than being shared by society as

5162-549: The global average. Because bogs and other peatlands are carbon sinks, they are releasing large amounts of greenhouse gases as they warm up. These changes have resulted in a severe decline of biodiversity and species populations of peatlands throughout Northern Europe. Bog habitats may develop in various situations, depending on the climate and topography. Bogs may be classified on their topography, proximity to water, method of recharge, and nutrient accumulation. These develop in gently sloping valleys or hollows. A layer of peat fills

5251-420: The ground surface may remain waterlogged for much of the time, providing conditions for the development of bog vegetation . In these circumstances, bog develops as a layer "blanketing" much of the land, including hilltops and slopes. Although a blanket bog is more common on acidic substrates, under some conditions it may also develop on neutral or even alkaline ones, if abundant acidic rainwater predominates over

5340-469: The groundwater. A blanket bog can occur in drier or warmer climates, because under those conditions hilltops and sloping ground dry out too often for peat to form – in intermediate climates a blanket bog may be limited to areas which are shaded from direct sunshine. In periglacial climates a patterned form of blanket bog may occur, known as a string bog . In Europe, these mostly very thin peat layers without significant surface structures are distributed over

5429-835: The headwaters of large rivers. Even the enormous Yangtze River arises in the Ruoergai peatland near its headwaters in Tibet . Blueberries , cranberries , cloudberries , huckleberries , and lingonberries are harvested from the wild in bogs. Bog oak , wood that has been partially preserved by bogs, has been used in the manufacture of furniture . Sphagnum bogs are also used for outdoor recreation, with activities including ecotourism and hunting. For example, many popular canoe routes in northern Canada include areas of peatland. Some other activities, such as all-terrain vehicle use, are especially damaging to bogs. The anaerobic environment and presence of tannic acids within bogs can result in

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5518-690: The high acidity. These anaerobic conditions lead to some of the best-preserved mummies and offer much archeological insight into society as far as 8,000 years back. Céide Fields in County Mayo in Ireland, a 5,000-year-old neolithic farming landscape has been found preserved under a blanket bog , complete with field walls and hut sites. One ancient artifact found in various bogs is bog butter , large masses of fat, usually in wooden containers. These are thought to have been food stores of both butter and tallow . Wetland Wetlands exist on every continent , except Antarctica . The water in wetlands

5607-520: The hills and valleys of Ireland, Scotland, England, and Norway. In North America, blanket bogs occur predominantly in Canada east of Hudson Bay . These bogs are often still under the influence of mineral soil water (groundwater). Blanket bogs do not occur north of the 65th latitude in the northern hemisphere. A quaking bog , schwingmoor , or swingmoor is a form of floating bog occurring in wetter parts of valley bogs and raised bogs and sometimes around

5696-468: The interface between truly terrestrial ecosystems and aquatic systems, making them inherently different from each other, yet highly dependent on both." In environmental decision-making, there are subsets of definitions that are agreed upon to make regulatory and policy decisions. Under the Ramsar international wetland conservation treaty , wetlands are defined as follows: An ecological definition of

5785-462: The known animal species in wetlands, and are considered the primary food web link between plants and higher animals (such as fish and birds). Depending on a wetland's geographic and topographic location, the functions it performs can support multiple ecosystem services , values, or benefits. United Nations Millennium Ecosystem Assessment and Ramsar Convention described wetlands as a whole to be of biosphere significance and societal importance in

5874-496: The long-term. Extreme weather like dry summers are likely the cause, as they lower precipitation and the groundwater table. It is speculated that these issues will only increase with a rise in global temperature and climate change. Since bogs take thousands of years to form and create the rich peat that is used as a resource, once they are gone they are extremely hard to recover. Arctic and sub-Arctic circles where many bogs are warming at 0.6 °C per decade, an amount twice as large as

5963-405: The low-nutrient conditions by using invertebrates as a nutrient source. Orchids have adapted to these conditions through the use of mycorrhizal fungi to extract nutrients. Some shrubs such as Myrica gale (bog myrtle) have root nodules in which nitrogen fixation occurs, thereby providing another supplemental source of nitrogen. Bogs are recognized as a significant/specific habitat type by

6052-441: The most significant resonance canonicals had two pi bonds involving d orbitals. His reasoning was that the charge on sulfur was thus reduced, in accordance with his principle of electroneutrality . The S−O bond length of 149 pm is shorter than the bond lengths in sulfuric acid of 157 pm for S−OH. The double bonding was taken by Pauling to account for the shortness of the S−O bond. Pauling's use of d orbitals provoked

6141-524: The one with two double bonds (thus the Lewis model, not the Pauling model). In this model, the structure obeys the octet rule and the charge distribution is in agreement with the electronegativity of the atoms. The discrepancy between the S−O bond length in the sulfate ion and the S−OH bond length in sulfuric acid is explained by donation of p-orbital electrons from the terminal S=O bonds in sulfuric acid into

6230-932: The oxygen atom. On the other hand, in the structure with a dipolar bond , the charge is localized as a lone pair on the oxygen. Typically metal sulfates are prepared by treating metal oxides, metal carbonates, or the metal itself with sulfuric acid : Although written with simple anhydrous formulas, these conversions generally are conducted in the presence of water. Consequently the product sulfates are hydrated , corresponding to zinc sulfate ZnSO 4 ·7H 2 O , copper(II) sulfate CuSO 4 ·5H 2 O , and cadmium sulfate CdSO 4 ·H 2 O . Some metal sulfides can be oxidized to give metal sulfates. There are numerous examples of ionic sulfates, many of which are highly soluble in water . Exceptions include calcium sulfate , strontium sulfate , lead(II) sulfate , barium sulfate , silver sulfate , and mercury sulfate , which are poorly soluble. Radium sulfate

6319-531: The passage of the Clean Air Act , which was strengthened in 1977 and 1990. According to the EPA , from 1970 to 2005, total emissions of the six principal air pollutants, including sulfates, dropped by 53% in the US. By 2010, this reduction in sulfate pollution led to estimated healthcare cost savings valued at $ 50 billion annually. Similar measures were taken in Europe, such as the 1985 Helsinki Protocol on

6408-469: The peat decays, carbon dioxide would be released to the atmosphere, contributing to global warming. Undisturbed, bogs function as a carbon sink . As one example, the peatlands of the former Soviet Union were calculated to be removing 52 Tg of carbon per year from the atmosphere. Therefore, the rewetting of drained peatlands may be one of the most cost-effective ways to mitigate climate change. Peat bogs are also important in storing fresh water, particularly in

6497-837: The plants and animals controlled by the wetland hydrology are often additional components of the definitions. Wetlands can be tidal (inundated by tides) or non-tidal. The water in wetlands is either freshwater , brackish , saline , or alkaline . There are four main kinds of wetlands – marsh , swamp , bog , and fen (bogs and fens being types of peatlands or mires ). Some experts also recognize wet meadows and aquatic ecosystems as additional wetland types. Sub-types include mangrove forests , carrs , pocosins , floodplains , peatlands, vernal pools , sinks , and many others. The following three groups are used within Australia to classify wetland by type: Marine and coastal zone wetlands, inland wetlands and human-made wetlands. In

6586-535: The reduction of sulfates coupled with the oxidation of organic compounds or hydrogen as an energy source for chemosynthesis. Some sulfates were known to alchemists. The vitriol salts, from the Latin vitreolum , glassy, were so-called because they were some of the first transparent crystals known. Green vitriol is iron (II) sulfate heptahydrate, FeSO 4 ·7H 2 O ; blue vitriol is copper (II) sulfate pentahydrate, CuSO 4 ·5H 2 O and white vitriol

6675-613: The remarkable preservation of organic material. Finds of such material have been made in Slovenia , Denmark , Germany , Ireland , Russia , and the United Kingdom. Some bogs have preserved bog-wood, such as ancient oak logs useful in dendrochronology . They have yielded extremely well-preserved bog bodies , with hair, organs, and skin intact, buried there thousands of years ago after apparent Germanic and Celtic human sacrifice . Excellent examples of such human specimens include

6764-429: The soil and underlying rock into aquifers which are the source of much of the world's drinking water . Wetlands can also act as recharge areas when the surrounding water table is low and as a discharge zone when it is high. Mangroves , coral reefs , salt marsh can help with shoreline stabilization and storm protection. Tidal and inter-tidal wetland systems protect and stabilize coastal zones. Coral reefs provide

6853-537: The soil of wetlands. Anaerobic and aerobic respiration in the soil influences the nutrient cycling of carbon, hydrogen, oxygen, and nitrogen, and the solubility of phosphorus thus contributing to the chemical variations in its water. Wetlands with low pH and saline conductivity may reflect the presence of acid sulfates and wetlands with average salinity levels can be heavily influenced by calcium or magnesium. Biogeochemical processes in wetlands are determined by soils with low redox potential. The life forms of

6942-412: The soils and plants at higher elevations. Plants and animals may vary within a wetland seasonally or in response to flood regimes. There are four main groups of hydrophytes that are found in wetland systems throughout the world. Submerged wetland vegetation can grow in saline and fresh-water conditions. Some species have underwater flowers, while others have long stems to allow the flowers to reach

7031-530: The sources of water include tidal wetlands , where the water source is ocean tides ); estuaries , water source is mixed tidal and river waters; floodplains , water source is excess water from overflowed rivers or lakes; and bogs and vernal ponds , water source is rainfall or meltwater . The world's largest wetlands include the Amazon River basin , the West Siberian Plain ,

7120-406: The spatial and temporal dispersion, flow, and physio-chemical attributes of surface and ground waters. Sources of hydrological flows into wetlands are predominantly precipitation , surface water (saltwater or freshwater), and groundwater. Water flows out of wetlands by evapotranspiration , surface flows and tides , and subsurface water outflow. Hydrodynamics (the movement of water through and from

7209-578: The sphagnum moss and peat. The gradual accumulation of decayed plant material in a bog functions as a carbon sink . Bogs occur where the water at the ground surface is acidic and low in nutrients. A bog usually is found at a freshwater soft spongy ground that is made up of decayed plant matter which is known as peat. They are generally found in cooler northern climates and are formed in poorly draining lake basins. In contrast to fens , they derive most of their water from precipitation rather than mineral-rich ground or surface water. Water flowing out of bogs has

7298-410: The sulfate ion is as predicted by VSEPR theory . The first description of the bonding in modern terms was by Gilbert Lewis in his groundbreaking paper of 1916 where he described the bonding in terms of electron octets around each atom, that is no double bonds and a formal charge of +2 on the sulfur atom and -1 on each oxygen atom. Later, Linus Pauling used valence bond theory to propose that

7387-418: The sunlight from reaching the water surface, slightly cooling it and dampening the development of hurricanes. Likewise, it has been suggested since the early 2000s that since aerosols decrease solar radiation over the ocean and hence reduce evaporation from it, they would be "spinning down the hydrological cycle of the planet." The hydrogensulfate ion ( HSO − 4 ), also called the bisulfate ion,

7476-719: The surface of the water. When trees and shrubs comprise much of the plant cover in saturated soils, those areas in most cases are called swamps . The upland boundary of swamps is determined partly by water levels. This can be affected by dams Some swamps can be dominated by a single species, such as silver maple swamps around the Great Lakes . Others, like those of the Amazon basin , have large numbers of different tree species. Other examples include cypress ( Taxodium ) and mangrove swamps. Many species of fish are highly dependent on wetland ecosystems. Seventy-five percent of

7565-496: The surface. Submerged species provide a food source for native fauna, habitat for invertebrates, and also possess filtration capabilities. Examples include seagrasses and eelgrass . Floating water plants or floating vegetation are usually small, like those in the Lemnoideae subfamily (duckweeds). Emergent vegetation like the cattails ( Typha spp.), sedges ( Carex spp.) and arrow arum ( Peltandra virginica ) rise above

7654-464: The surrounding environment resulting in increased extinction rates in unfavorable and polluted environmental conditions. Reptiles such as snakes , lizards , turtles , alligators and crocodiles are common in wetlands of some regions. In freshwater wetlands of the Southeastern US, alligators are common and a freshwater species of crocodile occurs in South Florida. The Florida Everglades

7743-440: The types of plants that live within them. Specifically, wetlands are characterized as having a water table that stands at or near the land surface for a long enough period each year to support aquatic plants . A more concise definition is a community composed of hydric soil and hydrophytes . Wetlands have also been described as ecotones , providing a transition between dry land and water bodies. Wetlands exist "...at

7832-400: The water surface to cover bays or even entire small lakes. Bogs at the edges of lakes may become detached and form floating islands . A cataract bog is a rare ecological community formed where a permanent stream flows over a granite outcropping. The sheeting of water keeps the edges of the rock wet without eroding the soil, but in this precarious location, no tree or large shrub can maintain

7921-450: Was one of the first companies to mechanically harvest peat, which is being phased out. The other major use of dried peat is as a soil amendment (sold as moss peat or sphagnum peat ) to increase the soil's capacity to retain moisture and enrich the soil. It is also used as a mulch . Some distilleries , notably in the Islay whisky-producing region, use the smoke from peat fires to dry

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