Misplaced Pages

#389610

88-581: The community lies in the Westerwald between Limburg and Siegen . From east to west through the town flows the river Nister , which is part of the Sieg drainage basin . Bad Marienberg's Stadtteile are Eichenstruth, Langenbach and Zinhain. In 1048, Bad Marienberg had its first documentary mention. It is likely that this same source gave rise to the name Westerwald, since the area around Bad Marienberg lies directly west of Herborn . In 1258, Marienberg

176-544: A humid continental climate (Köppen climate classification: Dfb ). In the lowlands of the Unterwesterwald (Lower Westerwald), summers tend to be warm to hot. Erratic convective downpours are not uncommon, yet mostly brief. Winters are mild and see a lot of precipitation, which mostly falls as rain. Snowfall occurs multiple times a year, but usually melts within hours. Thermophilic fruits like figs and peaches are hardy in this area. The mountainous areas of

264-556: A transmitter for VHF and television which has a 174-m-high freestanding tubular steel mast. Südwestrundfunk (SWR) sends all four of its radio programmes from here. In the summer of 2008, the switchover from analogue TV transmissions to DVB-T is to be carried out. Also, the Deutscher Wetterdienst runs a weather station right near this transmission facility in Bad Marienberg. In Bad Marienberg

352-579: A basalt-rich region. Wäller is another vernacular name for them. One of the 12 best-rated hiking trails in Germany is the Westerwaldsteig. The Westerwaldsteig crosses the Westerwald from east ( Herborn ) to west ( Rhine ). Tanning (leather) Tanning , or hide tanning , is the process of treating skins and hides of animals to produce leather . A tannery is the place where

440-441: A bath solution containing vegetable tannins, such as found in gallnuts , the leaves of sumac , the leaves of certain acacia trees, the outer green shells of walnuts , among other plants. The use of vegetable tanning is a process that takes longer than mineral tanning when converting rawhides into leather. Mineral tanned leather is used principally for shoes, car seats, and upholstery in homes (sofas, etc.). Vegetable tanned leather

528-427: A high content of glycine , proline , and hydroxyproline , usually in the repeat -gly-pro-hypro-gly-. These residues give rise to collagen's helical structure. Collagen's high content of hydroxyproline allows cross-linking by hydrogen bonding within the helical structure. Ionized carboxyl groups (RCO 2 ) are formed by the action of hydroxide. This conversion occurs during the liming process, before introduction of

616-480: A large factor in how hazardous wastewater results in contaminating the environment. This is especially prominent in small and medium-sized tanneries in developing countries. The UN Leather Working Group (LWG) "provides an environmental audit protocol, designed to assess the facilities of leather manufacturers," for "traceability, energy conservation, [and] responsible management of waste products." Untanned hides can be dried and made pliable by rubbing and stretching

704-521: A low mountain range a typical agreeable climate. Economically and culturally, it belongs among Germany's best known mountain ranges. The name "Westerwald" was first mentioned in 1048 in a document from the Electorate of Trier and described at that time the woodlands ( Wald is German for "forest" or "woods") around the three churches in Bad Marienberg , Rennerod and Emmerichenhain, west of

792-535: A range of handcrafted utility ware, with hand-painted swirling floral motifs. In the eastern Westerwald (the part lying in Hesse) are found interesting limestone deposits from the most varied of geological times. Erdbach limestone from the Lower Carboniferous gave one small time period the name "Erdbachian". Near Breitscheid are found the remnants of an atoll from the subtropical Devonian sea that

880-653: A short time. After further territorial exchanges within the Nassau dynasty through inheritances, Marienberg ended up, as part of the Beilstein lordly domain, under Prince William IV's governance. Once again, in 1742-1743, he succeeded in uniting all Ottonian lands within the Holy Roman Empire . Within the Orange German possessions now ruled from Dillenburg, Marienberg was at the latest by 1783 put under

968-400: A skin at a slaughterhouse, farm, or local fur trader. Before tanning, the skins are often dehaired, then have fat, meat and connective tissue removed. They are then washed and soaked in water with various compounds, and prepared to receive a tanning agent. They are then soaked, stretched, dried, and sometimes smoked. Preparing hides begins by curing them with salt to prevent putrefaction of

SECTION 10

#1732775328390

1056-640: A strip of land on the Rhine's right bank and the so-called Rhine-Westerwald; the Westerwald itself lay outside the Roman-occupied area, for the Romans preferred to maintain a little-settled, most likely pathless wilderness as their border. The Westerwald's permanent settlement and thereby its territorial history began with the Chatti (Hessians) pushing their way into the area after the Romans were driven out in

1144-492: A town with a medieval centre. The geologically old, heavily eroded range of the Westerwald is in its northern parts overlaid by a volcanic upland made of Neogene basalt layers. It covers an area of some 50 km × 70 km (31 mi × 43 mi), and therefore roughly 3,000 km (1,200 sq mi), making the Westerwald one of Germany's biggest mountain ranges by area. In areas of subsidence , it has in its flatter western part (Lower Westerwald)

1232-662: Is a part of the Rhenish Massif ( Rheinisches Schiefergebirge or Rhenish Slate Mountains). Its highest elevation, at 657 m above sea level, is the Fuchskaute in the High Westerwald. Tourist attractions include the Dornburg  [ de ] (394 metres), site of some Celtic ruins from La Tène times (5th to 1st century BC), found in the community of the same name , and Limburg an der Lahn ,

1320-694: Is also the inspiration for the South Korean military song, "Our Nation Forever". In recent years it has become somewhat controversial in Germany due to its origins during the National Socialist era, with the German military ceasing performances of it in 2017. The standard German term for a Westerwald dweller is Westerwälder ( IPA: [ˈvɛstɐvɛldɐ] ; plural: same), but they are also popularly known as Basaltköpp (“Basalt Heads”), as they are said to be thickheaded, and they live in

1408-548: Is centred on Höhr-Grenzhausen . Exports, particularly to Italy, are also important (more than one million metric tons each year). In the mid 16th century, potters from Raeren in Belgium migrated into the Westerwald, bringing with them some of their moulds . This type of pottery was taken to the New World and was found in the early Chesapeake settlements. Today one finds not only highly crafted moulded vases and mugs but also

1496-419: Is considered one of the most effective tanning compounds. Chromium-tanned leather can contain between 4 and 5% of chromium. This efficiency is characterized by its increased hydrothermal stability of the skin, and its resistance to shrinkage in heated water. Vegetable tanning uses tannins (a class of polyphenol astringent chemicals), which occur naturally in the bark and leaves of many plants. Tannins bind to

1584-403: Is consistent with cross-linking by polychromium species, of the sort arising from olation and oxolation. Before the introduction of the basic chromium species in tanning, several steps are required to produce a tannable hide. The pH must be very acidic when the chromium is introduced to ensure that the chromium complexes are small enough to fit between the fibers and residues of the collagen. Once

1672-416: Is excellent for use in handbags and garments. After application of the chromium agent, the bath is treated with sodium bicarbonate in the basification process to increase the pH to 3.8–4.0, inducing cross-linking between the chromium and the collagen. The pH increase is normally accompanied by a gradual temperature increase up to 40 °C. Chromium's ability to form such stable bridged bonds explains why it

1760-496: Is found the main branch of Europa-Haus of 128 others that have sprung up. It is sponsored through an endowment and serves as an education and meeting place. Westerwald The Westerwald ( German pronunciation: [ˈvɛstɐvalt] ; literally 'Western forest') is a low mountain range on the right bank of the river Rhine in the German federal states of Rhineland-Palatinate , Hesse and North Rhine-Westphalia . It

1848-562: Is known as a tannery . The English word for tanning is from medieval Latin tannāre , derivative of tannum ( oak bark ), from French tan (tanbark), from old-Cornish tann (oak). These terms are related to the hypothetical Proto-Indo-European * dʰonu meaning ' fir tree'. (The same word is source for Old High German tanna meaning 'fir', related to modern German Tannenbaum ). Ancient civilizations used leather for waterskins , bags, harnesses and tack, boats, armour , quivers , scabbards , boots , and sandals . Tanning

SECTION 20

#1732775328390

1936-465: Is made up of 23 council members, including the honorary and presiding mayor ( Bürgermeister ), who were elected in a municipal election on May 25, 2014. The mayor is Sabine Willwacher (SPD), re-elected in 2019. Willwacher was first elected mayor of the city of Bad Marienberg on May 25, 2014. She is succeeding fellow party member Dankwart Neufurth, who had retired after running the office from 2004 to 2014. The town maintains partnership arrangements with

2024-419: Is not very flexible. It is used for luggage, furniture, footwear, belts, and other clothing accessories. Wet white is a term used for leathers produced using alternative tanning methods that produce an off-white colored leather. Like wet blue, wet white is also a semifinished stage. Wet white can be produced using aldehydes , aluminum, zirconium, titanium, or iron salts, or a combination thereof. Concerns with

2112-428: Is preferred. Once bating is complete, the hides and skins are treated by first soaking them in a bath containing common salt (sodium chloride), usually 1 quart of salt to 1 gallon of hot water. When the water cools, one fluid ounce of sulfuric acid is added. Small skins are left in this liquor for 2 days, while larger skins between 1 week and as much as 2 months. In vegetable tanning, the hides are made to soak in

2200-421: Is tawed by soaking in a warm potash alum and salts solution, between 20 and 30 °C (68 and 86 °F). The process increases the hide's pliability, stretchability, softness, and quality. Then, the hide is air dried (crusted) for several weeks, which allows it to stabilize. The use of alum alone for tanning rawhides is not recommended, as it shrinks the surface area of the skin, making it thicker and hard to

2288-466: Is the Fuchskaute in the High Westerwald, meaning "fox hollow". Many peaks and crests exceed the 600-metre level. Sorted by elevation above sea level, these are some of the Westerwald's highest elevations: The following are the Westerwald's rivers and streams: Weiher is a German word meaning "pond". Through prehistoric finds it can be determined that the Celts settled in the Westerwald and were using

2376-524: Is the railway station at Montabaur on the Cologne-Frankfurt high-speed rail line , which is approximately 30 km away. The nearest airport is Siegerland Airport about 15 km northeast of Bad Marienberg. Since Siegerland Airport -as of June 2015- does not offer any scheduled passenger flights, the nearest international airports are Frankfurt and Cologne Bonn Airport , both circa 100 km away. Near Bad Marienberg, T-Systems runs

2464-420: Is the characteristic of the keratin class of proteins that gives strength to hair and wools (keratin typically makes up 90% of the dry weight of hair). The hydrogen atoms supplied by the sharpening agent weaken the cystine molecular link whereby the covalent disulfide bond links are ultimately ruptured, weakening the keratin. To some extent, sharpening also contributes to unhairing, as it tends to break down

2552-439: Is used as a leather tanning agent, can cause problems in the kidneys and liver and is also considered a carcinogen . Formaldehyde and arsenic, which are used for leather finishing, cause health problems in the eyes, lungs, liver, kidneys, skin, and lymphatic system and are also considered carcinogens. The waste from leather tanneries is detrimental to the environment and the people who live in it. The use of old technologies plays

2640-461: Is used in leather crafting and in making small leather items, such as wallets, handbags and clothes. Chromium(III) sulfate ( [Cr(H 2 O) 6 ] 2 (SO 4 ) 3 ) has long been regarded as the most efficient and effective tanning agent. Chromium(III) compounds of the sort used in tanning are significantly less toxic than hexavalent chromium , although the latter arises in inadequate waste treatment. Chromium(III) sulfate dissolves to give

2728-458: The Amt of Beilstein . The parish of Marienberg counted roughly 450 souls in 1580 and included the villages of Bach, Bölsberg, Eichenstruth, Fehl, Großseifen, Illfurth, Langenbach, Marienberg, Hof, Pfuhl, Ritzhausen, Stockhausen, Unnau and Zinhain. The Counties of Sayn-Hachenburg and Sayn-Altenkirchen both lay only a few kilometres away to the northwest. Along with the lordly domain of Beilstein,

Bad Marienberg - Misplaced Pages Continue

2816-475: The Autobahnen A ;3 ( Cologne – Frankfurt ), A 45 ( Dortmund – Aschaffenburg ) and A 48 . The most notable railway is the Cologne-Frankfurt high-speed rail line with minor stops at Montabaur and Limburg an der Lahn. The High Westerwald is served by Siegerland Airport for private use and special touristic charters, south of Burbach . Geologically , the Westerwald is part of

2904-624: The Basaltpark , a disused basalt quarry which is open to the public and laid out with hiking paths, information plaques about the geology , and a museum . Right near the Basaltpark is found the Wildpark Bad Marienberg (wildlife park). Between Bad Marienberg and Nisterau Bach is the nature reserve of Bacher Lay . Bad Marienberg is home to these worldwide operating companies: KEMPF Fahrzeugbau LEBEK International Fashion Group MENK Apparatebau Right near

2992-486: The Bundesland of Rhineland-Palatinate. On 10 August 1967 the town had the title Bad (literally "bath" – the title means that the town is a recognized spa) bestowed upon it, after already having received the title of Kneipp resort in 1961. In 1972, Bad Marienberg, along with 17 other Ortsgemeinden was grouped into a Verbandsgemeinde , which today is home to just under 20,000 inhabitants (as of 2007). The council

3080-592: The Oberwesterwald (Upper Westerwald) and Hoher Westerwald (High Westerwald) feature a much colder climate and are more prone to extreme weather, such as extreme wind gusts during extratropical cyclones . Summer days are pleasantly warm and rarely become hot due to a cool breeze, while winters are cold and rich in snow. The area is home to a number of ski areas . District seats in the Westerwald are: Altenkirchen (Altenkirchen district), Montabaur (Westerwaldkreis) and Neuwied (Neuwied district). Furthermore,

3168-505: The "Neues Westerwaldlied" ("New Westerwald Song") by songwriter Ulrik Remy, "Ich bin aus 'm Westerwald" ("I am from the Westerwald") and "Das schönste Mädchen vom Westerwald" ("The Loveliest Girl from the Westerwald") by Karl-Eberhard Hain and Jürgen Hardeck, made well known by De Höhner , Die Schröders and other groups. The "Westerwaldlied" is also sung by the Chilean Armed Forces and is known as "Himno de la Sección". It

3256-474: The 3rd century. Placename endings such as –ar, –mar and –aha ("Haigraha" = Haiger ) stemming from the Migration Period ( "Völkerwanderung" ) can still be found now. These lie around the forest's outer edges in basins and dales whose soils and climate were favourable to early settlers, and include, for instance, Hadamar , Lahr and Wetzlar . From the 4th to the 6th century, the settlements from

3344-590: The Dill, also belong to the Westerwald, whereas the mountains reaching up to 680 m (2,230 ft) near the Haiger Saddle ( Haiger Sattel ) and east of Siegen are counted as part of the Rothaargebirge . The Westerwald is divided by elevation into these three regions: The climate of the region vastly qualifies as oceanic (Köppen climate classification: Cfb ), while higher altitudes experience

3432-632: The Electorate of Trier were all prominent landlords. Political relations were simplified until the 16th century. Among the four greater powers' spheres of influence (Mainz, Cologne, Trier, Hesse), the House of Nassau managed to expand and strengthen its hold on its territory on the Dill between Siegen and Nassau . After the Napoleonic upheavals, Nassau had to share broad swathes of the Westerwald with

3520-644: The Lahn-Dill-Bergland (another low mountain range), north of the Taunus and east of the Middle Rhine and stretches more or less southwards from Siegen and Burbach , southwestwards from Haiger , northwestwards from Weilburg , northwards from Limburg an der Lahn , northeastwards from Koblenz , eastwards from Linz am Rhein , southeastwards from Wissen and southwards from Betzdorf . In its centre lie Bad Marienberg and Hachenburg . Clockwise,

3608-907: The Lahn-Dill-Kreis, the Mayen-Koblenz district, the Rhein-Lahn-Kreis and the Limburg-Weilburg district each have shares of the Westerwald. If Sieg is taken as the Westerwald's northernmost limit, then the Rhein-Sieg district likewise belongs here, at least in parts (for example the Siebengebirge and the communities of Eitorf and Windeck ). The Westerwald and its outer edges are crossed by stretches of Bundesstraßen 8 , 42, 49 , 54 , 62 , 255, 256, 277, 413 and 414, over which there are connections to

Bad Marienberg - Misplaced Pages Continue

3696-656: The Ottonian- Walramian hereditary division. After a further division in 1303, the area passed to Otto's son Henry III of Nassau-Siegen, making it part of Nassau-Dillenburg. From 1343 to 1561, the overlordship in the Westerwald was then held by the Nassau-Dillenburg-Beilstein branch of the family. After they died out, Count Johann VI of Nassau-Dillenburg ("the Elder") received the inheritance, thereby uniting these German lands – albeit only for

3784-621: The Rhenish Massif, and likewise represents a heavily eroded remnant of a great Variscan mountain system which in the Mesozoic characterized a great deal of Europe. The Devonian bedrock is covered by volcanic masses from the Tertiary , particularly basalt and tuffs . Economically important, besides slate, limestone and clay quarrying , were, and still are, iron and its processing industry between Rheintal (Unkel, Linz) and

3872-592: The Trier and Cologne mission, this area underwent Christianization. Trier advanced up the Lahn, Cologne to the Rhine and Sieg. Trier-Lorrainian and Lower Rhine influences were nevertheless brought into the Westerwald. Among the witnesses to the art of building at that time is the monastery church at Limburg- Dietkirchen , in its oldest parts. After many changes in ownership between the Ottonian and Salian noble families, it

3960-648: The Upper Westerwald, bypassing the High Westerwald, seeing it as nothing more than a trackless wooded wilderness, after which they eventually came up against the Rhine in the 2nd century. Even in the time when the Celts found themselves having to avoid the Germanic invaders by moving to the west, the Romans were also pushing in from the Rhine's left bank to the southwest. However, the Romans only managed to seize

4048-647: The Westerwald is bordered by the following river valleys: the Rhine between Koblenz and Linz , the Sieg as far as Betzdorf, the Heller , the Dill and from its mouth near Wetzlar , the Lahn up to Lahnstein . Geomorphologically , the Westerwald belongs to the Rhenish Massif, which forms the greater part of that range's eastern half on the Rhine's right bank. Likewise, the Gladenbach Uplands , lying east of

4136-481: The Westerwald's north and southwest edges even gave two Lower Devonian layers, with their colourful slates, their names. The upper mountain layers are formed of volcanic strata made of basalt containing tuffs. In a few areas, slate and clay have long been quarried, the latter notably in the so-called Kannenbäckerland , but also in a few other places where the clay is worked into the salt- glazed grey Westerwald Pottery with cobalt blue decoration. The pottery industry

4224-411: The adoption in medicine of soaking gut sutures in a chromium (III) solution after 1840, it was discovered that this method could also be used with leather and thus was adopted by tanners. The tanning process begins with obtaining an animal skin. When an animal skin is to be tanned, the animal is killed and skinned before the body heat leaves the tissues. This can be done by the tanner, or by obtaining

4312-491: The case of Bangladesh, chickens (the nation's most common source of protein). Up to 25% of the chickens in Bangladesh contained harmful levels of hexavalent chromium, adding to the national health problem load. Chromium is not solely responsible for these diseases. Methylisothiazolinone , which is used for microbiological protection (fungal or bacterial growth), causes problems with the eyes and skin. Anthracene , which

4400-478: The characteristics of rolling hills. Typical for the economy of the Upper Westerwald, some 40% of which is actually wooded, are traditional slate mining, clay quarrying , diabase and basalt mining, pottery and the iron ore industry, and among other things mining in the Siegerländer Erzrevier (roughly "Siegerland Ore Grounds"). Despite its relatively slight elevation, the Westerwald has for

4488-436: The collagen from bacterial growth during the time lag from procuring the hide to when it is processed. Curing removes water from the hides and skins using a difference in osmotic pressure. The moisture content of hides and skins is greatly reduced, and osmotic pressure increased, to the point that bacteria are unable to grow. In wet-salting, the hides are heavily salted, then pressed into packs for about 30 days. In brine -curing,

SECTION 50

#1732775328390

4576-459: The collagen proteins in the hide and coat them, causing them to become less water-soluble and more resistant to bacterial attack. The process also causes the hide to become more flexible. The primary barks processed in bark mills and used in modern times are chestnut , oak , redoul , tanoak , hemlock , quebracho , mangrove , wattle (acacia; see catechol ), and myrobalans from Terminalia spp., such as Terminalia chebula . In Ethiopia ,

4664-416: The collagen's carboxyl groups, amine groups from the side chains of the amino acids , and masking agents. Masking agents are carboxylic acids , such as acetic acid , used to suppress formation of polychromium(III) chains. Masking agents allow the tanner to further increase the pH to increase collagen's reactivity without inhibiting the penetration of the chromium(III) complexes. Collagen is characterized by

4752-544: The combined vegetable oils of Niger seed ( Guizotia abyssinica ) and flaxseeds were used in treating the flesh side of the leather, as a means of tawing, rather than of tanning. In Yemen and Egypt , hides were tanned by soaking them in a bath containing the crushed leaves and bark of the Salam acacia (Acacia etbaica; A. nilotica kraussiana). Hides that have been stretched on frames are immersed for several weeks in vats of increasing concentrations of tannin. Vegetable-tanned hide

4840-409: The desired level of penetration of chrome into the substance is achieved, the pH of the material is raised again to facilitate the process. This step is known as basification. In the raw state, chrome-tanned skins are greyish-blue, so are referred to as wet blue . Chrome tanning is faster than vegetable tanning (taking less than a day for this part of the process) and produces a stretchable leather which

4928-520: The district of Westerburg was united with the old Oberwesterwaldkreis to form the new, bigger Oberwesterwaldkreis in 1932, Marienberg lost its function as an administrative seat to Westerburg. Having had town rights conferred on 1 April 1939, Marienberg then belonged to the French occupation zone and was part of the Upper Presidium of Rhineland-Hesse-Nassau. Since 1947, the town has been part of

5016-513: The district seat of Marienberg in the Ore Mountains ( Erzgebirge ) and with Pagny-sur-Moselle in France . Within Bad Marienberg's town limits is a spa garden with a Kneipp centre and a bandshell where concerts are regularly held in the summer. Adjoining this is a new part of the park with a herb garden and a barefoot course. Between Bad Marienberg and the outlying centre of Zinhain is

5104-425: The end use of the leather, hides may be treated with enzymes to soften them, a process called bating . In modern tanning, these enzymes are purified agents, and the process no longer requires bacterial fermentation (as from dung-water soaking) to produce them. Pickling is another term for tanning, or what is the modern equivalent of turning rawhide into leather by the use of modern chemical agents, if mineral tanning

5192-562: The fibers with a hide stretcher, and fatting. However the hide will revert to rawhide if not periodically replenished with fat or oil, especially if it gets wet. Many Native Americans of the arid western regions wore clothing made by this process. Smoke tanning is listed among the conventional methods like chrome tanning and vegetable tanning. Impregnation of the hide's cells with formaldehyde (from smoke) offers some microbial and water resistance. Leftover leather would historically be turned into glue . Tanners would place scraps of hides in

5280-535: The governance of the Lordship or County of Beilstein. The Westerwald lies mostly southwest of the three-state common point shared by Rhineland-Palatinate, Hesse and North Rhine-Westphalia in the districts of Altenkirchen , Lahn-Dill , Limburg-Weilburg , Neuwied , Rhein-Lahn , Rhein-Sieg , Westerwaldkreis and partly in Siegen-Wittgenstein . It is found south of the Rothaargebirge , southwest of

5368-418: The hair proteins. The isoelectric point of the collagen (a tissue-strengthening protein unrelated to keratin) in the hide is also shifted to around pH 4.7 due to liming. Any hairs remaining after liming are removed mechanically by scraping the skin with a dull knife, a process known as scudding. The pH of the collagen is then reduced so the enzymes may act on it in a process known as deliming. Depending on

SECTION 60

#1732775328390

5456-406: The hexaaquachromium(III) cation, [Cr(H 2 O) 6 ] , which at higher pH undergoes processes called olation to give polychromium(III) compounds that are active in tanning, being the cross-linking of the collagen subunits. The chemistry of [Cr(H 2 O) 6 ] is more complex in the tanning bath rather than in water due to the presence of a variety of ligands. Some ligands include the sulfate anion,

5544-459: The hides are agitated in a saltwater bath for about 16 hours. Curing can also be accomplished by preserving the hides and skins at very low temperatures. The steps in the production of leather between curing and tanning are collectively referred to as beamhouse operations. They include, in order, soaking, liming , removal of extraneous tissues (unhairing, scudding and fleshing), deliming , bating or puering, drenching, and pickling. In soaking,

5632-406: The hides are soaked in clean water to remove the salt left over from curing and increase the moisture so that the hide or skin can be further treated. To prevent damage of the skin by bacterial growth during the soaking period, biocides , typically dithiocarbamates , may be used. Fungicides such as TCMTB may also be added later in the process, to protect wet leathers from mold growth. After 1980,

5720-734: The institution of rural districts after the Prussian model, Marienberg became in 1867 seat of the Oberwesterwaldkreis with the Ämter of Hachenburg, Marienberg and Rennerod. The last went to the newly created Westerburg district (which also got the Amt of Wallmerod as well as a few places from the Amt of Selters from the Unterwesterwaldkreis) in 1885-1886 on the occasion of administrative reform. Although in 1890 Marienberg had only 707 (mostly Evangelical ) inhabitants and

5808-642: The iron ore deposits in the so-called Hallstatt times ( Iron Age , roughly 750 to 500 BC). In all likelihood they came into the area from the Hunsrück . From La Tène times come the Celtic ringwall-girded defensive and sheltering castles which may be found on, among other peaks, the Malberg. Already by La Tène times, Germanic peoples were thrusting in from the east and from the Sieg valley. They came about 380 BC into

5896-609: The jurisdiction of the Dillenburg Criminal Court. In the course of a short-lived administrative reform, Marienberg was annexed in 1849 to the newly founded Landkreis (rural district) of Hachenburg, before the old arrangement was brought back into force in 1854. In 1866 the Duchy of Nassau passed to Prussia and became, as the Regierungsbezirk of Wiesbaden, part of the province of Hesse-Nassau . With

5984-603: The lower Wied, pumice gravel in the Neuwied Basin, various mineral springs and, once, brown coal mining. The whole Westerwald region lay under a tropically warm arm of the sea in the Palaeozoic (600 to 270 million years ago). This sea deposited layers of sediments many kilometres thick into the Variscan geosyncline , which were heavily folded in the orogeny that followed. The towns of Siegen and Koblenz on

6072-501: The newly minted power Prussia . A sovereign Duchy of Nassau existed until it was annexed by Prussia in 1866. Nowadays, the Westerwald is shared among three German federal states: Hesse, North Rhine-Westphalia and Rhineland-Palatinate. The Westerwald is also internationally known in songs, above all in folksongs , and particularly the "Westerwaldlied" ("Westerwald Song"), as well as "Westerwald-Marsch" ("Westerwald March"), "Westerwald, du bist so schön" ("Westerwald, you are so lovely"),

6160-427: The outskirts of town, among the poor. Tanning by ancient methods is so foul-smelling that tanneries are still isolated from those towns today where the old methods are used. Skins typically arrived at the tannery dried stiff and dirty with soil and gore. First, the ancient tanners would soak the skins in water to clean and soften them. Then they would pound and scour the skin to remove any remaining flesh and fat . Hair

6248-508: The process. Chemicals used in tanned leather production increase the levels of chemical oxygen demand and total dissolved solids in water when not disposed of responsibly. These processes also use large quantities of water and produce large amounts of pollutants. Boiling and sun drying can oxidize and convert the various chromium(III) compounds used in tanning into carcinogenic hexavalent chromium , or chromium(VI). This hexavalent chromium runoff and scraps are then consumed by animals, in

6336-528: The royal court at Herborn . Only since the mid 19th century has the name come into common usage for the whole range. The High Westerwald has since the Middle Ages formed the heart of the Herrschaft zum (also vom or auf dem ) Westerwald ("Lordship over the Westerwald"). This comprised the three court districts of Marienberg , Emmerichenhain and Neukirch . The Lordship later fell under

6424-521: The skins are processed. Historically, vegetable based tanning used tannin , an acidic chemical compound derived from the bark of certain trees, in the production of leather. An alternative method, developed in the 1800s, is chrome tanning, where chromium salts are used instead of natural tannins. Tanning hide into leather involves a process which permanently alters the protein structure of skin, making it more durable and less susceptible to decomposition and coloring. The place where hides are processed

6512-403: The tanning agent (chromium salts). Later during pickling, collagen carboxyl groups are temporarily protonated for ready transport of chromium ions. During basification step of tanning, the carboxyl groups are ionized and coordinate as ligands to the chromium(III) centers of the oxo-hydroxide clusters. Tanning increases the spacing between protein chains in collagen from 10 to 17 Å. The difference

6600-564: The time of the taking of the land arose in formerly pathless areas, taking endings such as –ingen and –heim , like Bellingen and Bladernheim ; these lie on the broad, raised plains in the Upper Westerwald. The Franks built their old settlements on the edge of the Westerwald in the central areas of their districts, to build up slowly and permanently strongholds in the interior. There arose places with names ending in –rode, –scheid, –hahn, –berg, –tal and –seifen . Once clearing settlements had been established and logging for iron ore smelting

6688-407: The touch. If alum is applied to the fur, it makes the fur dull and harsh. Depending on the finish desired, the leather may be waxed, rolled, lubricated, injected with oil, split, shaved, or dyed. The tanning process involves chemical and organic compounds that can have a detrimental effect on the environment. Agents such as chromium, vegetable tannins, and aldehydes are used in the tanning step of

6776-529: The town runs Bundesstraße 414 leading from Driedorf -Hohenroth to Altenkirchen . The nearest Autobahn interchange is Haiger-Burbach on the A 45 ( Dortmund – Gießen ), roughly 22 km away. Bad Marienberg is connected to the Oberwesterwaldbahn railway (Limburg - Au (Sieg)) only by bus. Nistertal-Bad Marienberg station is situated in the village of Nistertal , 6 km away from Bad Marienberg. The nearest InterCityExpress stop

6864-492: The toxicity and environmental impact of any chromium (VI) that may form during the tanning process have led to increased research into more efficient wet white methods. The conditions present in bogs, including highly acidic water, low temperature, and a lack of oxygen, combine to preserve but severely tan the skin of bog bodies . Tawing is a method that uses alum and other aluminium salts , generally in conjunction with binders such as egg yolk, flour, or other salts. The hide

6952-418: The use of pentachlorophenol and mercury -based biocides and their derivatives was forbidden. After soaking, the hides are treated with milk of lime (a basic agent) typically supplemented by "sharpening agents" (disulfide reducing agents) such as sodium sulfide , cyanides , amines , etc. This: The weakening of hair is dependent on the breakdown of the disulfide link of the amino acid cystine , which

7040-658: The village fell in 1806 to the Napoleonic Grand Duchy of Berg, in which, in 1808, it was grouped into the Arrondissement of Dillenburg within the Département of Sieg. In 1815, Marienberg went to the Duchy of Nassau . The Amt of Marienberg, which was newly organized in 1816, comprised 43 villages and 20 estates with 1,805 families and 7,085 persons. At the same time, the Amt of Marienberg lay under

7128-419: Was a fermentative process that relied on enzymes produced by bacteria found in the dung. Among the kinds of dung commonly used were those of dogs or pigeons. Historically the actual tanning process used vegetable tanning. In some variations of the process, cedar oil , alum , or tannin was applied to the skin as a tanning agent. As the skin was stretched, it would lose moisture and absorb the agent. Following

7216-533: Was being carried out by the inhabitants of Mehrgarh in Pakistan between 7000 and 3300 BCE. Around 2500 BCE , the Sumerians began using leather, affixed by copper studs , on chariot wheels . The process of tanning was also used for boats and fishing vessels: ropes, nets, and sails were tanned using tree bark. Formerly, tanning was considered a noxious or "odoriferous trade" and relegated to

7304-450: Was described as Mons sanctae Mariae . In the 18th century, the formerly separate communities of Obermarienberg, still an easily recognizable ring-shaped settlement around the parish church today, and Untermarienberg grew together. Marienberg was part of the lordly domain in the Westerwald that was formed out of the three Gerichte (official regions) of Marienberg, Emmerichenhain and Neukirch, and which Count Otto I of Nassau won in 1255 in

7392-463: Was here 380,000,000 years ago. Parts of this limestone formation are worked in open-pit mining ; near Enspel , a " fossil conservation area" has been instituted, in which institutes from several colleges conduct research and excursions. A few karst caves are of interest to spelaeology and bring about the temporary disappearance and reappearance of the Erdbach. The Westerwald's highest mountain

7480-575: Was in the end the Counts of Sayn, Diez and Wied who managed to take hold of extensive landholdings. Particular importance was achieved by the Counts of Laurenburg, who later called themselves the Counts of Nassau . In the east, the Landgraves of Hesse put it about that they could beat the Archbishopric of Mainz on the battlefield. Moreover, the Counts of Wied, the Counts of Sayn-Wittgenstein and

7568-549: Was officially said to be a village, it already had a considerable infrastructure at its disposal: the village had a provincial council office ( Landratsamt ), a court ( Landgericht Limburg an der Lahn ), a taxation and land registry office, a post and telegraph office, a credit union and an agency for the Nassauische Landesbank . Moreover, there was a tannery in the village, and nearby were brown coal and ironstone mines along with clay pits. When

7656-424: Was removed by soaking the skin in urine , painting it with an alkaline lime mixture, or simply allowing the skin to putrefy for several months then dipping it in a salt solution. After the hair was loosened, the tanners scraped it off with a knife. Once the hair was removed, the tanners would " bate " (soften) the material by pounding dung into the skin, or soaking the skin in a solution of animal brains. Bating

7744-403: Was under way, the widespread destruction of the forest began. Between the 6th and 9th centuries came settlement expansion from the old settlements towards the edges, a process still witnessed in placename endings such as –hausen, –hofen, –kirch, –burg or –tal . The last settlement period in the Westerwald began in the 10th century and ended about 1300. Through Carolingian policy and therefore

#389610