88-726: The Thomas A. Greene Memorial Museum , also known as Greene Geological Museum or Greene Museum , is a mineral and fossil museum in Milwaukee, Wisconsin , administered by the Department of Geosciences at the University of Wisconsin–Milwaukee . The original fireproof museum building, designed by noted Milwaukee architect, Alexander Eschweiler , held the collection of Thomas A. Greene , Milwaukee druggist and amateur geologist , plant collector, and fossil collector. In 1913, Greene's heirs, Mrs. H.A.J. Upham and Mr. Howard Greene, had
176-579: A mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form. The geological definition of mineral normally excludes compounds that occur only in living organisms. However, some minerals are often biogenic (such as calcite ) or organic compounds in the sense of chemistry (such as mellite ). Moreover, living organisms often synthesize inorganic minerals (such as hydroxylapatite ) that also occur in rocks. The concept of mineral
264-541: A phyllosilicate , to diamond, a carbon polymorph that is the hardest natural material. The scale is provided below: A mineral's hardness is a function of its structure. Hardness is not necessarily constant for all crystallographic directions; crystallographic weakness renders some directions softer than others. An example of this hardness variability exists in kyanite, which has a Mohs hardness of 5 1 ⁄ 2 parallel to [001] but 7 parallel to [100] . Silicon dioxide Silicon dioxide , also known as silica ,
352-585: A bend in the middle that is caused by start of the twin. Penetration twins consist of two single crystals that have grown into each other; examples of this twinning include cross-shaped staurolite twins and Carlsbad twinning in orthoclase. Cyclic twins are caused by repeated twinning around a rotation axis. This type of twinning occurs around three, four, five, six, or eight-fold axes, and the corresponding patterns are called threelings, fourlings, fivelings , sixlings, and eightlings. Sixlings are common in aragonite. Polysynthetic twins are similar to cyclic twins through
440-417: A bigger coordination numbers because of the increase in relative size as compared to oxygen (the last orbital subshell of heavier atoms is different too). Changes in coordination numbers leads to physical and mineralogical differences; for example, at high pressure, such as in the mantle , many minerals, especially silicates such as olivine and garnet , will change to a perovskite structure , where silicon
528-432: A chemical compound occurs naturally with different crystal structures, each structure is considered a different mineral species. Thus, for example, quartz and stishovite are two different minerals consisting of the same compound, silicon dioxide . The International Mineralogical Association (IMA) is the generally recognized standard body for the definition and nomenclature of mineral species. As of November 2024 ,
616-473: A distinct mineral: The details of these rules are somewhat controversial. For instance, there have been several recent proposals to classify amorphous substances as minerals, but they have not been accepted by the IMA. The IMA is also reluctant to accept minerals that occur naturally only in the form of nanoparticles a few hundred atoms across, but has not defined a minimum crystal size. Some authors require
704-407: A glass with no true melting point, can be used as a glass fibre for fibreglass. Silicon dioxide is mostly obtained by mining, including sand mining and purification of quartz . Quartz is suitable for many purposes, while chemical processing is required to make a purer or otherwise more suitable (e.g. more reactive or fine-grained) product. Precipitated silica or amorphous silica is produced by
792-494: A heat capacity minimum. Its density decreases from 2.08 g/cm at 1950 °C to 2.03 g/cm at 2200 °C. The molecular SiO 2 has a linear structure like CO 2 . It has been produced by combining silicon monoxide (SiO) with oxygen in an argon matrix. The dimeric silicon dioxide, (SiO 2 ) 2 has been obtained by reacting O 2 with matrix isolated dimeric silicon monoxide, (Si 2 O 2 ). In dimeric silicon dioxide there are two oxygen atoms bridging between
880-463: A key to defining a substance as a mineral. A 2011 article defined icosahedrite , an aluminium-iron-copper alloy, as a mineral; named for its unique natural icosahedral symmetry , it is a quasicrystal . Unlike a true crystal, quasicrystals are ordered but not periodic. A rock is an aggregate of one or more minerals or mineraloids. Some rocks, such as limestone or quartzite , are composed primarily of one mineral – calcite or aragonite in
968-450: A low value of 140° in α-tridymite, up to 180° in β-tridymite. In α-quartz, the Si–O–Si angle is 144°. Alpha quartz is the most stable form of solid SiO 2 at room temperature. The high-temperature minerals, cristobalite and tridymite, have both lower densities and indices of refraction than quartz. The transformation from α-quartz to beta-quartz takes place abruptly at 573 °C. Since
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#17327976143891056-409: A mineral defines how much it can resist scratching or indentation. This physical property is controlled by the chemical composition and crystalline structure of a mineral. The most commonly used scale of measurement is the ordinal Mohs hardness scale, which measures resistance to scratching. Defined by ten indicators, a mineral with a higher index scratches those below it. The scale ranges from talc,
1144-432: A sedimentary mineral, and silicic acid ): Under low-grade metamorphic conditions, kaolinite reacts with quartz to form pyrophyllite (Al 2 Si 4 O 10 (OH) 2 ): As metamorphic grade increases, the pyrophyllite reacts to form kyanite and quartz: Alternatively, a mineral may change its crystal structure as a consequence of changes in temperature and pressure without reacting. For example, quartz will change into
1232-410: A silicon wafer enables it to overcome the surface states that otherwise prevent electricity from reaching the semiconducting layer. The process of silicon surface passivation by thermal oxidation (silicon dioxide) is critical to the semiconductor industry . It is commonly used to manufacture metal–oxide–semiconductor field-effect transistors (MOSFETs) and silicon integrated circuit chips (with
1320-406: A tetrahedral fashion; on the other hand, graphite is composed of sheets of carbons in sp hybrid orbitals, where each carbon is bonded covalently to only three others. These sheets are held together by much weaker van der Waals forces , and this discrepancy translates to large macroscopic differences. Twinning is the intergrowth of two or more crystals of a single mineral species. The geometry of
1408-935: A variety of its SiO 2 polymorphs , such as tridymite and cristobalite at high temperatures, and coesite at high pressures. Classifying minerals ranges from simple to difficult. A mineral can be identified by several physical properties, some of them being sufficient for full identification without equivocation. In other cases, minerals can only be classified by more complex optical , chemical or X-ray diffraction analysis; these methods, however, can be costly and time-consuming. Physical properties applied for classification include crystal structure and habit, hardness, lustre, diaphaneity, colour, streak, cleavage and fracture, and specific gravity. Other less general tests include fluorescence , phosphorescence , magnetism , radioactivity , tenacity (response to mechanical induced changes of shape or form), piezoelectricity and reactivity to dilute acids . Crystal structure results from
1496-502: A variety of minerals because of the need to balance charges. Because the eight most common elements make up over 98% of the Earth's crust, the small quantities of the other elements that are typically present are substituted into the common rock-forming minerals. The distinctive minerals of most elements are quite rare, being found only where these elements have been concentrated by geological processes, such as hydrothermal circulation , to
1584-477: A very shallow layer of about 1 nm or 10 Å of so-called native oxide. Higher temperatures and alternative environments are used to grow well-controlled layers of silicon dioxide on silicon, for example at temperatures between 600 and 1200 °C, using so-called dry oxidation with O 2 or wet oxidation with H 2 O. The native oxide layer is beneficial in microelectronics , where it acts as electric insulator with high chemical stability. It can protect
1672-595: A white mica, can be used for windows (sometimes referred to as isinglass), as a filler, or as an insulator. Ores are minerals that have a high concentration of a certain element, typically a metal. Examples are cinnabar (HgS), an ore of mercury; sphalerite (ZnS), an ore of zinc; cassiterite (SnO 2 ), an ore of tin; and colemanite , an ore of boron . Gems are minerals with an ornamental value, and are distinguished from non-gems by their beauty, durability, and usually, rarity. There are about 20 mineral species that qualify as gem minerals, which constitute about 35 of
1760-524: A white powder with extremely low bulk density (0.03-0.15 g/cm ) and thus high surface area. The particles act as a thixotropic thickening agent, or as an anti-caking agent, and can be treated to make them hydrophilic or hydrophobic for either water or organic liquid applications. Silica fume is an ultrafine powder collected as a by-product of the silicon and ferrosilicon alloy production. It consists of amorphous (non-crystalline) spherical particles with an average particle diameter of 150 nm, without
1848-707: Is a sedimentary rock composed primarily of organically derived carbon. In rocks, some mineral species and groups are much more abundant than others; these are termed the rock-forming minerals. The major examples of these are quartz, the feldspars , the micas , the amphiboles , the pyroxenes , the olivines , and calcite; except for the last one, all of these minerals are silicates. Overall, around 150 minerals are considered particularly important, whether in terms of their abundance or aesthetic value in terms of collecting. Commercially valuable minerals and rocks, other than gemstones, metal ores, or mineral fuels, are referred to as industrial minerals . For example, muscovite ,
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#17327976143891936-439: Is also the primary component of rice husk ash , which is used, for example, in filtration and as supplementary cementitious material (SCM) in cement and concrete manufacturing. Silicification in and by cells has been common in the biological world and it occurs in bacteria, protists, plants, and animals (invertebrates and vertebrates). Prominent examples include: About 95% of the commercial use of silicon dioxide (sand)
2024-399: Is an oxide of silicon with the chemical formula SiO 2 , commonly found in nature as quartz . In many parts of the world, silica is the major constituent of sand . Silica is one of the most complex and abundant families of materials , existing as a compound of several minerals and as a synthetic product. Examples include fused quartz , fumed silica , opal , and aerogels . It
2112-604: Is covalently bonded in a tetrahedral manner to 4 oxygen atoms. In contrast, CO 2 is a linear molecule. The starkly different structures of the dioxides of carbon and silicon are a manifestation of the double bond rule . Based on the crystal structural differences, silicon dioxide can be divided into two categories: crystalline and non-crystalline (amorphous). In crystalline form, this substance can be found naturally occurring as quartz , tridymite (high-temperature form), cristobalite (high-temperature form), stishovite (high-pressure form), and coesite (high-pressure form). On
2200-428: Is distinct from rock , which is any bulk solid geologic material that is relatively homogeneous at a large enough scale. A rock may consist of one type of mineral or may be an aggregate of two or more different types of minerals, spacially segregated into distinct phases . Some natural solid substances without a definite crystalline structure, such as opal or obsidian , are more properly called mineraloids . If
2288-448: Is in octahedral coordination. Other examples are the aluminosilicates kyanite , andalusite , and sillimanite (polymorphs, since they share the formula Al 2 SiO 5 ), which differ by the coordination number of the Al ; these minerals transition from one another as a response to changes in pressure and temperature. In the case of silicate materials, the substitution of Si by Al allows for
2376-465: Is in the construction industry, e.g. in the production of concrete ( Portland cement concrete ). Certain deposits of silica sand, with desirable particle size and shape and desirable clay and other mineral content, were important for sand casting of metallic products. The high melting point of silica enables it to be used in such applications such as iron casting; modern sand casting sometimes uses other minerals for other reasons. Crystalline silica
2464-651: Is obtained by the dealumination of a low-sodium, ultra-stable Y zeolite with combined acid and thermal treatment. The resulting product contains over 99% silica, and has high crystallinity and specific surface area (over 800 m /g). Faujasite-silica has very high thermal and acid stability. For example, it maintains a high degree of long-range molecular order or crystallinity even after boiling in concentrated hydrochloric acid . Molten silica exhibits several peculiar physical characteristics that are similar to those observed in liquid water : negative temperature expansion, density maximum at temperatures ~5000 °C, and
2552-408: Is possible for one element to be substituted for another. Chemical substitution will occur between ions of a similar size and charge; for example, K will not substitute for Si because of chemical and structural incompatibilities caused by a big difference in size and charge. A common example of chemical substitution is that of Si by Al , which are close in charge, size, and abundance in the crust. In
2640-470: Is possible for two rocks to have an identical or a very similar bulk rock chemistry without having a similar mineralogy. This process of mineralogical alteration is related to the rock cycle . An example of a series of mineral reactions is illustrated as follows. Orthoclase feldspar (KAlSi 3 O 8 ) is a mineral commonly found in granite , a plutonic igneous rock . When exposed to weathering, it reacts to form kaolinite (Al 2 Si 2 O 5 (OH) 4 ,
2728-421: Is rapidly cooled, it does not crystallize, but solidifies as a glass. Because of this, most ceramic glazes have silica as the main ingredient. The structural geometry of silicon and oxygen in glass is similar to that in quartz and most other crystalline forms of silicon and oxygen, with silicon surrounded by regular tetrahedra of oxygen centres. The difference between the glass and crystalline forms arises from
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2816-524: Is the angle opposite the a-axis, viz. the angle between the b and c axes): The hexagonal crystal family is also split into two crystal systems – the trigonal , which has a three-fold axis of symmetry, and the hexagonal, which has a six-fold axis of symmetry. Chemistry and crystal structure together define a mineral. With a restriction to 32 point groups, minerals of different chemistry may have identical crystal structure. For example, halite (NaCl), galena (PbS), and periclase (MgO) all belong to
2904-405: Is the hardest natural substance, has an adamantine lustre, and belongs to the isometric crystal family, whereas graphite is very soft, has a greasy lustre, and crystallises in the hexagonal family. This difference is accounted for by differences in bonding. In diamond, the carbons are in sp hybrid orbitals, which means they form a framework where each carbon is covalently bonded to four neighbours in
2992-426: Is the major constituent of sand . Even though it is poorly soluble, silica occurs in many plants such as rice . Plant materials with high silica phytolith content appear to be of importance to grazing animals, from chewing insects to ungulates . Silica accelerates tooth wear, and high levels of silica in plants frequently eaten by herbivores may have developed as a defense mechanism against predation. Silica
3080-405: Is the only polymorph of silica stable at the Earth's surface. Metastable occurrences of the high-pressure forms coesite and stishovite have been found around impact structures and associated with eclogites formed during ultra-high-pressure metamorphism . The high-temperature forms of tridymite and cristobalite are known from silica-rich volcanic rocks . In many parts of the world, silica
3168-504: Is the process by which a semiconductor surface is rendered inert, and does not change semiconductor properties as a result of interaction with air or other materials in contact with the surface or edge of the crystal. The formation of a thermally grown silicon dioxide layer greatly reduces the concentration of electronic states at the silicon surface . SiO 2 films preserve the electrical characteristics of p–n junctions and prevent these electrical characteristics from deteriorating by
3256-456: Is typical of garnet, prismatic (elongated in one direction), and tabular, which differs from bladed habit in that the former is platy whereas the latter has a defined elongation. Related to crystal form, the quality of crystal faces is diagnostic of some minerals, especially with a petrographic microscope. Euhedral crystals have a defined external shape, while anhedral crystals do not; those intermediate forms are termed subhedral. The hardness of
3344-436: Is used as a fining agent for wine, beer, and juice, with the E number reference E551 . In cosmetics, silica is useful for its light-diffusing properties and natural absorbency. Diatomaceous earth , a mined product, has been used in food and cosmetics for centuries. It consists of the silica shells of microscopic diatoms ; in a less processed form it was sold as "tooth powder". Manufactured or mined hydrated silica
3432-489: Is used as the hard abrasive in toothpaste . Silicon dioxide is widely used in the semiconductor technology: Because silicon dioxide is a native oxide of silicon it is more widely used compared to other semiconductors like gallium arsenide or indium phosphide . Silicon dioxide could be grown on a silicon semiconductor surface. Silicon oxide layers could protect silicon surfaces during diffusion processes , and could be used for diffusion masking. Surface passivation
3520-418: Is used in hydraulic fracturing of formations which contain tight oil and shale gas . Silica is the primary ingredient in the production of most glass . As other minerals are melted with silica, the principle of freezing point depression lowers the melting point of the mixture and increases fluidity. The glass transition temperature of pure SiO 2 is about 1475 K. When molten silicon dioxide SiO 2
3608-498: Is used in structural materials , microelectronics , and as components in the food and pharmaceutical industries. All forms are white or colorless, although impure samples can be colored. Silicon dioxide is a common fundamental constituent of glass . In the majority of silicon dioxides, the silicon atom shows tetrahedral coordination , with four oxygen atoms surrounding a central Si atom ( see 3-D Unit Cell ). Thus, SiO 2 forms 3-dimensional network solids in which each silicon atom
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3696-538: Is used to produce elemental silicon . The process involves carbothermic reduction in an electric arc furnace : Fumed silica , also known as pyrogenic silica, is prepared by burning SiCl 4 in an oxygen-rich hydrogen flame to produce a "smoke" of SiO 2 . It can also be produced by vaporizing quartz sand in a 3000 °C electric arc. Both processes result in microscopic droplets of amorphous silica fused into branched, chainlike, three-dimensional secondary particles which then agglomerate into tertiary particles,
3784-618: The CIPW norm , which gives reasonable estimates for volcanic rock formed from dry magma. The chemical composition may vary between end member species of a solid solution series. For example, the plagioclase feldspars comprise a continuous series from sodium -rich end member albite (NaAlSi 3 O 8 ) to calcium -rich anorthite (CaAl 2 Si 2 O 8 ) with four recognized intermediate varieties between them (given in order from sodium- to calcium-rich): oligoclase , andesine , labradorite , and bytownite . Other examples of series include
3872-496: The hydrosphere , atmosphere , and biosphere . The group's scope includes mineral-forming microorganisms, which exist on nearly every rock, soil, and particle surface spanning the globe to depths of at least 1600 metres below the sea floor and 70 kilometres into the stratosphere (possibly entering the mesosphere ). Biogeochemical cycles have contributed to the formation of minerals for billions of years. Microorganisms can precipitate metals from solution , contributing to
3960-473: The olivine group . Besides the essential chemical composition and crystal structure, the description of a mineral species usually includes its common physical properties such as habit , hardness , lustre , diaphaneity , colour, streak , tenacity , cleavage , fracture , parting, specific gravity , magnetism , fluorescence , radioactivity , as well as its taste or smell and its reaction to acid . Minerals are classified by key chemical constituents;
4048-555: The planar process ). Hydrophobic silica is used as a defoamer component . In its capacity as a refractory , it is useful in fiber form as a high-temperature thermal protection fabric. Silica is used in the extraction of DNA and RNA due to its ability to bind to the nucleic acids under the presence of chaotropes . Silica aerogel was used in the Stardust spacecraft to collect extraterrestrial particles. Pure silica (silicon dioxide), when cooled as fused quartz into
4136-455: The 78 mineral classes listed in the Dana classification scheme. Skinner's (2005) definition of a mineral takes this matter into account by stating that a mineral can be crystalline or amorphous. Although biominerals are not the most common form of minerals, they help to define the limits of what constitutes a mineral proper. Nickel's (1995) formal definition explicitly mentioned crystallinity as
4224-474: The IMA recognizes 6,100 official mineral species. The chemical composition of a named mineral species may vary somewhat due to the inclusion of small amounts of impurities. Specific varieties of a species sometimes have conventional or official names of their own. For example, amethyst is a purple variety of the mineral species quartz . Some mineral species can have variable proportions of two or more chemical elements that occupy equivalent positions in
4312-431: The IMA's decision to exclude biogenic crystalline substances. For example, Lowenstam (1981) stated that "organisms are capable of forming a diverse array of minerals, some of which cannot be formed inorganically in the biosphere." Skinner (2005) views all solids as potential minerals and includes biominerals in the mineral kingdom, which are those that are created by the metabolic activities of organisms. Skinner expanded
4400-455: The IMA. They are most commonly named after a person , followed by discovery location; names based on chemical composition or physical properties are the two other major groups of mineral name etymologies. Most names end in "-ite"; the exceptions are usually names that were well-established before the organization of mineralogy as a discipline, for example galena and diamond . A topic of contention among geologists and mineralogists has been
4488-556: The Latin species , "a particular sort, kind, or type with distinct look, or appearance". The abundance and diversity of minerals is controlled directly by their chemistry, in turn dependent on elemental abundances in the Earth. The majority of minerals observed are derived from the Earth's crust . Eight elements account for most of the key components of minerals, due to their abundance in the crust. These eight elements, summing to over 98% of
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#17327976143894576-496: The acidification of solutions of sodium silicate . The gelatinous precipitate or silica gel , is first washed and then dehydrated to produce colorless microporous silica. The idealized equation involving a trisilicate and sulfuric acid is: Approximately one billion kilograms/year (1999) of silica were produced in this manner, mainly for use for polymer composites – tires and shoe soles. Thin films of silica grow spontaneously on silicon wafers via thermal oxidation , producing
4664-488: The aluminium abundance is unusually high, the excess aluminium will form muscovite or other aluminium-rich minerals. If silicon is deficient, part of the feldspar will be replaced by feldspathoid minerals. Precise predictions of which minerals will be present in a rock of a particular composition formed at a particular temperature and pressure requires complex thermodynamic calculations. However, approximate estimates may be made using relatively simple rules of thumb , such as
4752-552: The branching of the pyrogenic product. The main use is as pozzolanic material for high performance concrete. Fumed silica nanoparticles can be successfully used as an anti-aging agent in asphalt binders. Silica, either colloidal, precipitated, or pyrogenic fumed, is a common additive in food production. It is used primarily as a flow or anti- caking agent in powdered foods such as spices and non-dairy coffee creamer, or powders to be formed into pharmaceutical tablets. It can adsorb water in hygroscopic applications. Colloidal silica
4840-449: The bulk chemistry of the parent body. For example, in most igneous rocks, the aluminium and alkali metals (sodium and potassium) that are present are primarily found in combination with oxygen, silicon, and calcium as feldspar minerals. However, if the rock is unusually rich in alkali metals, there will not be enough aluminium to combine with all the sodium as feldspar, and the excess sodium will form sodic amphiboles such as riebeckite . If
4928-424: The case of limestone, and quartz in the latter case. Other rocks can be defined by relative abundances of key (essential) minerals; a granite is defined by proportions of quartz, alkali feldspar , and plagioclase feldspar . The other minerals in the rock are termed accessory minerals , and do not greatly affect the bulk composition of the rock. Rocks can also be composed entirely of non-mineral material; coal
5016-441: The collection irreplaceable. The mineral collection contains a wide range of minerals and ores from localities throughout North America, as well as some from overseas. It includes exquisite examples of amethyst, apatite, stibnite, copper, tungsten, molybdenum, vanadium, cobalt, nickel, mercury compounds, aluminum compounds, malachite, lapis-lazuli, tourmaline, garnet, labradorite, fluorite, beryl, and turquoise, among others. Perhaps
5104-509: The connectivity of the tetrahedral units: Although there is no long-range periodicity in the glassy network, ordering remains at length scales well beyond the SiO bond length. One example of this ordering is the preference to form rings of 6-tetrahedra. The majority of optical fibers for telecommunications are also made from silica. It is a primary raw material for many ceramics such as earthenware , stoneware , and porcelain . Silicon dioxide
5192-415: The coordination of the silicate is by a number: in the case of the silica tetrahedron, the silicon is said to have a coordination number of 4. Various cations have a specific range of possible coordination numbers; for silicon, it is almost always 4, except for very high-pressure minerals where the compound is compressed such that silicon is in six-fold (octahedral) coordination with oxygen. Bigger cations have
5280-417: The crust by weight, are, in order of decreasing abundance: oxygen , silicon , aluminium , iron , magnesium , calcium , sodium and potassium . Oxygen and silicon are by far the two most important – oxygen composes 47% of the crust by weight, and silicon accounts for 28%. The minerals that form are those that are most stable at the temperature and pressure of formation, within the limits imposed by
5368-488: The densest of the low-pressure forms, which has a density of 2.648 g/cm . The difference in density can be ascribed to the increase in coordination as the six shortest Si–O bond lengths in stishovite (four Si–O bond lengths of 176 pm and two others of 181 pm) are greater than the Si–O bond length (161 pm) in α-quartz. The change in the coordination increases the ionicity of the Si–O bond. Faujasite silica, another polymorph,
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#17327976143895456-434: The difference in charge has to accounted for by making a second substitution of Si by Al . Coordination polyhedra are geometric representations of how a cation is surrounded by an anion. In mineralogy, coordination polyhedra are usually considered in terms of oxygen, due its abundance in the crust. The base unit of silicate minerals is the silica tetrahedron – one Si surrounded by four O . An alternate way of describing
5544-414: The dipyramidal point group. These differences arise corresponding to how aluminium is coordinated within the crystal structure. In all minerals, one aluminium ion is always in six-fold coordination with oxygen. Silicon, as a general rule, is in four-fold coordination in all minerals; an exception is a case like stishovite (SiO 2 , an ultra-high pressure quartz polymorph with rutile structure). In kyanite,
5632-517: The example of plagioclase, there are three cases of substitution. Feldspars are all framework silicates, which have a silicon-oxygen ratio of 2:1, and the space for other elements is given by the substitution of Si by Al to give a base unit of [AlSi 3 O 8 ] ; without the substitution, the formula would be charge-balanced as SiO 2 , giving quartz. The significance of this structural property will be explained further by coordination polyhedra. The second substitution occurs between Na and Ca ; however,
5720-584: The facility built to house his collection, and it was declared a National Historic Landmark in 1993, in recognition of the collection's significance as a largely intact amateur geological collection. The collection has been removed from the building, and is now displayed and housed in Lapham Hall on the UWM campus. The building has been renovated and is currently used as academic space for UWM's Sam and Helen Stahl Center for Jewish Studies. Greene amassed most of
5808-778: The formation of ore deposits. They can also catalyze the dissolution of minerals. Prior to the International Mineralogical Association's listing, over 60 biominerals had been discovered, named, and published. These minerals (a sub-set tabulated in Lowenstam (1981) ) are considered minerals proper according to Skinner's (2005) definition. These biominerals are not listed in the International Mineral Association official list of mineral names; however, many of these biomineral representatives are distributed amongst
5896-799: The fossils in his collection, totaling about 75,000 specimens, during the 1880s and 1890s. The majority of these specimens come from the Silurian Racine Dolomite Formation and the Devonian Milwaukee Formation in the vicinity of southeastern Wisconsin. Preserved mostly as internal molds in dolomite, these fossils include a wide range of Silurian marine invertebrate groups including trilobites, crinoids, tabulate and rugose corals, brachiopods, cephalopods, and gastropods. Devonian fossils consist mainly of fish and plant remains. All of these fossils were collected from quarry outcrops that no longer exist, making
5984-411: The gaseous ambient environment. Silicon oxide layers could be used to electrically stabilize silicon surfaces. The surface passivation process is an important method of semiconductor device fabrication that involves coating a silicon wafer with an insulating layer of silicon oxide so that electricity could reliably penetrate to the conducting silicon below. Growing a layer of silicon dioxide on top of
6072-410: The generic AX 2 formula; these two groups are collectively known as the pyrite and marcasite groups. Polymorphism can extend beyond pure symmetry content. The aluminosilicates are a group of three minerals – kyanite , andalusite , and sillimanite – which share the chemical formula Al 2 SiO 5 . Kyanite is triclinic, while andalusite and sillimanite are both orthorhombic and belong to
6160-451: The hexaoctahedral point group (isometric family), as they have a similar stoichiometry between their different constituent elements. In contrast, polymorphs are groupings of minerals that share a chemical formula but have a different structure. For example, pyrite and marcasite , both iron sulfides, have the formula FeS 2 ; however, the former is isometric while the latter is orthorhombic. This polymorphism extends to other sulfides with
6248-563: The highlight of the mineral collection is a piece of iron meteorite that landed in nearby Washington County, Wisconsin. It was given to Greene by the scientist Increase A. Lapham , the namesake of Lapham Hall. Greene collaborated with another amateur, Dr. Fisk Holbrook Day , whose home in Wauwatosa, Wisconsin , the Dr. Fisk Holbrook Day House , has also been designated a National Historic Landmark. Mineral In geology and mineralogy ,
6336-461: The material to be a stable or metastable solid at room temperature (25 °C). However, the IMA only requires that the substance be stable enough for its structure and composition to be well-determined. For example, it has recently recognized meridianiite (a naturally occurring hydrate of magnesium sulfate ) as a mineral, even though it is formed and stable only below 2 °C. As of November 2024 , 6,100 mineral species are approved by
6424-433: The mineral's structure; for example, the formula of mackinawite is given as (Fe,Ni) 9 S 8 , meaning Fe x Ni 9- x S 8 , where x is a variable number between 0 and 9. Sometimes a mineral with variable composition is split into separate species, more or less arbitrarily, forming a mineral group ; that is the case of the silicates Ca x Mg y Fe 2- x - y SiO 4 ,
6512-494: The most common gemstones. Gem minerals are often present in several varieties, and so one mineral can account for several different gemstones; for example, ruby and sapphire are both corundum , Al 2 O 3 . The first known use of the word "mineral" in the English language ( Middle English ) was the 15th century. The word came from Medieval Latin : minerale , from minera , mine, ore. The word "species" comes from
6600-428: The most encompassing of these being the six crystal families. These families can be described by the relative lengths of the three crystallographic axes, and the angles between them; these relationships correspond to the symmetry operations that define the narrower point groups. They are summarized below; a, b, and c represent the axes, and α, β, γ represent the angle opposite the respective crystallographic axis (e.g. α
6688-402: The olivine series of magnesium-rich forsterite and iron-rich fayalite, and the wolframite series of manganese -rich hübnerite and iron-rich ferberite . Chemical substitution and coordination polyhedra explain this common feature of minerals. In nature, minerals are not pure substances, and are contaminated by whatever other elements are present in the given chemical system. As a result, it
6776-622: The orderly geometric spatial arrangement of atoms in the internal structure of a mineral. This crystal structure is based on regular internal atomic or ionic arrangement that is often expressed in the geometric form that the crystal takes. Even when the mineral grains are too small to see or are irregularly shaped, the underlying crystal structure is always periodic and can be determined by X-ray diffraction. Minerals are typically described by their symmetry content. Crystals are restricted to 32 point groups , which differ by their symmetry. These groups are classified in turn into more broad categories,
6864-400: The other hand, amorphous silica can be found in nature as opal and diatomaceous earth . Quartz glass is a form of intermediate state between these structures. All of these distinct crystalline forms always have the same local structure around Si and O. In α-quartz the Si–O bond length is 161 pm, whereas in α-tridymite it is in the range 154–171 pm. The Si–O–Si angle also varies between
6952-563: The point where they can no longer be accommodated in common minerals. Changes in temperature and pressure and composition alter the mineralogy of a rock sample. Changes in composition can be caused by processes such as weathering or metasomatism ( hydrothermal alteration ). Changes in temperature and pressure occur when the host rock undergoes tectonic or magmatic movement into differing physical regimes. Changes in thermodynamic conditions make it favourable for mineral assemblages to react with each other to produce new minerals; as such, it
7040-447: The presence of repetitive twinning; however, instead of occurring around a rotational axis, polysynthetic twinning occurs along parallel planes, usually on a microscopic scale. Crystal habit refers to the overall shape of crystal. Several terms are used to describe this property. Common habits include acicular, which describes needlelike crystals as in natrolite , bladed, dendritic (tree-pattern, common in native copper ), equant, which
7128-568: The previous definition of a mineral to classify "element or compound, amorphous or crystalline, formed through biogeochemical processes," as a mineral. Recent advances in high-resolution genetics and X-ray absorption spectroscopy are providing revelations on the biogeochemical relations between microorganisms and minerals that may shed new light on this question. For example, the IMA-commissioned "Working Group on Environmental Mineralogy and Geochemistry " deals with minerals in
7216-485: The second aluminium is in six-fold coordination; its chemical formula can be expressed as Al Al SiO 5 , to reflect its crystal structure. Andalusite has the second aluminium in five-fold coordination (Al Al SiO 5 ) and sillimanite has it in four-fold coordination (Al Al SiO 5 ). Differences in crystal structure and chemistry greatly influence other physical properties of the mineral. The carbon allotropes diamond and graphite have vastly different properties; diamond
7304-401: The silicon atoms with an Si–O–Si angle of 94° and bond length of 164.6 pm and the terminal Si–O bond length is 150.2 pm. The Si–O bond length is 148.3 pm, which compares with the length of 161 pm in α-quartz. The bond energy is estimated at 621.7 kJ/mol. SiO 2 is most commonly encountered in nature as quartz , which comprises more than 10% by mass of the Earth's crust. Quartz
7392-418: The silicon, store charge, block current, and even act as a controlled pathway to limit current flow. Many routes to silicon dioxide start with an organosilicon compound, e.g., HMDSO, TEOS. Synthesis of silica is illustrated below using tetraethyl orthosilicate (TEOS). Simply heating TEOS at 680–730 °C results in the oxide: Similarly TEOS combusts around 400 °C: TEOS undergoes hydrolysis via
7480-492: The so-called sol-gel process . The course of the reaction and nature of the product are affected by catalysts, but the idealized equation is: Being highly stable, silicon dioxide arises from many methods. Conceptually simple, but of little practical value, combustion of silane gives silicon dioxide. This reaction is analogous to the combustion of methane: However the chemical vapor deposition of silicon dioxide onto crystal surface from silane had been used using nitrogen as
7568-446: The transformation is accompanied by a significant change in volume, it can easily induce fracturing of ceramics or rocks passing through this temperature limit. The high-pressure minerals, seifertite , stishovite, and coesite, though, have higher densities and indices of refraction than quartz. Stishovite has a rutile -like structure where silicon is 6-coordinate. The density of stishovite is 4.287 g/cm , which compares to α-quartz,
7656-439: The twinning is controlled by the mineral's symmetry. As a result, there are several types of twins, including contact twins, reticulated twins, geniculated twins, penetration twins, cyclic twins, and polysynthetic twins. Contact, or simple twins, consist of two crystals joined at a plane; this type of twinning is common in spinel. Reticulated twins, common in rutile, are interlocking crystals resembling netting. Geniculated twins have
7744-472: The two dominant systems are the Dana classification and the Strunz classification. Silicate minerals comprise approximately 90% of the Earth's crust . Other important mineral groups include the native elements , sulfides , oxides , halides , carbonates , sulfates , and phosphates . The International Mineralogical Association has established the following requirements for a substance to be considered
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