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122-445: Groundwater is the water present beneath Earth 's surface in rock and soil pore spaces and in the fractures of rock formations . About 30 percent of all readily available fresh water in the world is groundwater. A unit of rock or an unconsolidated deposit is called an aquifer when it can yield a usable quantity of water. The depth at which soil pore spaces or fractures and voids in rock become completely saturated with water
244-420: A laboratory or factory . Mining in a wider sense comprises extraction of any resource (e.g. petroleum , natural gas , salt or even water ) from the earth. Mining of rock and metals has been done since prehistoric times. Modern mining processes involve prospecting for mineral deposits, analysis of the profit potential of a proposed mine, extraction of the desired materials, and finally reclamation of
366-601: A 1 cm sample cell. Aquatic plants , algae , and other photosynthetic organisms can live in water up to hundreds of meters deep, because sunlight can reach them. Practically no sunlight reaches the parts of the oceans below 1,000 metres (3,300 ft) of depth. The refractive index of liquid water (1.333 at 20 °C (68 °F)) is much higher than that of air (1.0), similar to those of alkanes and ethanol , but lower than those of glycerol (1.473), benzene (1.501), carbon disulfide (1.627), and common types of glass (1.4 to 1.6). The refraction index of ice (1.31)
488-407: A drop in the ground surface. In unconsolidated aquifers, groundwater is produced from pore spaces between particles of gravel, sand, and silt. If the aquifer is confined by low-permeability layers, the reduced water pressure in the sand and gravel causes slow drainage of water from the adjoining confining layers. If these confining layers are composed of compressible silt or clay, the loss of water to
610-399: A former lake bed, has experienced rates of subsidence of up to 40 centimetres (1 foot 4 inches) per year. For coastal cities, subsidence can increase the risk of other environmental issues, such as sea level rise . For example, Bangkok is expected to have 5.138 million people exposed to coastal flooding by 2070 because of these combining factors. If the surface water source
732-402: A fourth class of rocks alongside igneous, sedimentary, and metamorphic. Rock varies greatly in strength, from quartzites having a tensile strength in excess of 300 MPa to sedimentary rock so soft it can be crumbled with bare fingers (that is, it is friable ). (For comparison, structural steel has a tensile strength of around 350 MPa. ) Relatively soft, easily worked sedimentary rock
854-1073: A global level, although priority chemicals will vary by country. There is a lot of heterogeneity of hydrogeologic properties. For this reason, salinity of groundwater is often highly variable over space. This contributes to highly variable groundwater security risks even within a specific region. Salinity in groundwater makes the water unpalatable and unusable and often occurs in coastal areas, for example in Bangladesh and East and West Africa. Municipal and industrial water supplies are provided through large wells. Multiple wells for one water supply source are termed "wellfields", which may withdraw water from confined or unconfined aquifers. Using groundwater from deep, confined aquifers provides more protection from surface water contamination. Some wells, termed "collector wells", are specifically designed to induce infiltration of surface (usually river) water. Aquifers that provide sustainable fresh groundwater to urban areas and for agricultural irrigation are typically close to
976-406: A home and then returned to the ground in another well. During cold seasons, because it is relatively warm, the water can be used in the same way as a source of heat for heat pumps that is much more efficient than using air. Groundwater makes up about thirty percent of the world's fresh water supply, which is about 0.76% of the entire world's water, including oceans and permanent ice. About 99% of
1098-433: A huge impact on the cultural and technological development of the human race. Rock has been used by humans and other hominids for at least 2.5 million years . Lithic technology marks some of the oldest and continuously used technologies. The mining of rock for its metal content has been one of the most important factors of human advancement, and has progressed at different rates in different places, in part because of
1220-481: A large amount of sediment transport that occurs on the surface of the earth. Deposition of transported sediment forms many types of sedimentary rocks , which make up the geologic record of Earth history . The water cycle (known scientifically as the hydrologic cycle) is the continuous exchange of water within the hydrosphere , between the atmosphere , soil water, surface water , groundwater, and plants. Water moves perpetually through each of these regions in
1342-516: A long time without severe consequences. Nevertheless, over the long term the average rate of seepage above a groundwater source is the upper bound for average consumption of water from that source. Groundwater is naturally replenished by surface water from precipitation , streams , and rivers when this recharge reaches the water table. Groundwater can be a long-term ' reservoir ' of the natural water cycle (with residence times from days to millennia), as opposed to short-term water reservoirs like
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#17327830727351464-718: A permanently reduced capacity to hold water. The city of New Orleans, Louisiana is actually below sea level today, and its subsidence is partly caused by removal of groundwater from the various aquifer/aquitard systems beneath it. In the first half of the 20th century, the San Joaquin Valley experienced significant subsidence , in some places up to 8.5 metres (28 feet) due to groundwater removal. Cities on river deltas, including Venice in Italy, and Bangkok in Thailand, have experienced surface subsidence; Mexico City, built on
1586-477: A property that is exploited by cetaceans and humans for communication and environment sensing ( sonar ). Metallic elements which are more electropositive than hydrogen, particularly the alkali metals and alkaline earth metals such as lithium , sodium , calcium , potassium and cesium displace hydrogen from water, forming hydroxides and releasing hydrogen. At high temperatures, carbon reacts with steam to form carbon monoxide and hydrogen. Hydrology
1708-562: A source area and then transported to the place of deposition by water , wind , ice , mass movement or glaciers (agents of denudation ). About 7.9% of the crust by volume is composed of sedimentary rocks, with 82% of those being shales, while the remainder consists of 6% limestone and 12% sandstone and arkoses . Sedimentary rocks often contain fossils . Sedimentary rocks form under the influence of gravity and typically are deposited in horizontal or near horizontal layers or strata , and may be referred to as stratified rocks. Sediment and
1830-440: A structure of rigid oxygen atoms in which hydrogen atoms flowed freely. When sandwiched between layers of graphene , ice forms a square lattice. The details of the chemical nature of liquid water are not well understood; some theories suggest that its unusual behavior is due to the existence of two liquid states. Pure water is usually described as tasteless and odorless, although humans have specific sensors that can feel
1952-412: A swimming pool when the light source is sunlight reflected from the pool's white tiles. In nature, the color may also be modified from blue to green due to the presence of suspended solids or algae. In industry, near-infrared spectroscopy is used with aqueous solutions as the greater intensity of the lower overtones of water means that glass cuvettes with short path-length may be employed. To observe
2074-713: A texture are referred to as foliated ; the remainders are termed non-foliated. The name of the rock is then determined based on the types of minerals present. Schists are foliated rocks that are primarily composed of lamellar minerals such as micas . A gneiss has visible bands of differing lightness , with a common example being the granite gneiss. Other varieties of foliated rock include slates , phyllites , and mylonite . Familiar examples of non-foliated metamorphic rocks include marble , soapstone , and serpentine . This branch contains quartzite —a metamorphosed form of sandstone —and hornfels . Though most understanding of rocks comes from those of Earth, rocks make up many of
2196-461: A variety of applications including high-temperature electrochemistry and as an ecologically benign solvent or catalyst in chemical reactions involving organic compounds. In Earth's mantle, it acts as a solvent during mineral formation, dissolution and deposition. The normal form of ice on the surface of Earth is ice I h , a phase that forms crystals with hexagonal symmetry . Another with cubic crystalline symmetry , ice I c , can occur in
2318-489: Is visibly blue due to absorption of light in the region c. 600–800 nm. The color can be easily observed in a glass of tap-water placed against a pure white background, in daylight. The principal absorption bands responsible for the color are overtones of the O–H stretching vibrations . The apparent intensity of the color increases with the depth of the water column, following Beer's law . This also applies, for example, with
2440-439: Is 917 kg/m (57.25 lb/cu ft), an expansion of 9%. This expansion can exert enormous pressure, bursting pipes and cracking rocks. In a lake or ocean, water at 4 °C (39 °F) sinks to the bottom, and ice forms on the surface, floating on the liquid water. This ice insulates the water below, preventing it from freezing solid. Without this protection, most aquatic organisms residing in lakes would perish during
2562-399: Is a highly useful and often abundant resource. Most land areas on Earth have some form of aquifer underlying them, sometimes at significant depths. In some cases, these aquifers are rapidly being depleted by the human population. Such over-use, over-abstraction or overdraft can cause major problems to human users and to the environment. The most evident problem (as far as human groundwater use
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#17327830727352684-419: Is also called "water" at standard temperature and pressure . Because Earth's environment is relatively close to water's triple point , water exists on Earth as a solid , a liquid , and a gas . It forms precipitation in the form of rain and aerosols in the form of fog . Clouds consist of suspended droplets of water and ice , its solid state. When finely divided, crystalline ice may precipitate in
2806-466: Is also subject to substantial evaporation, a groundwater source may become saline . This situation can occur naturally under endorheic bodies of water, or artificially under irrigated farmland. In coastal areas, human use of a groundwater source may cause the direction of seepage to ocean to reverse which can also cause soil salinization . As water moves through the landscape, it collects soluble salts, mainly sodium chloride . Where such water enters
2928-629: Is an additional water source that was not used previously. First, flood mitigation schemes, intended to protect infrastructure built on floodplains, have had the unintended consequence of reducing aquifer recharge associated with natural flooding. Second, prolonged depletion of groundwater in extensive aquifers can result in land subsidence , with associated infrastructure damage – as well as, third, saline intrusion . Fourth, draining acid sulphate soils, often found in low-lying coastal plains, can result in acidification and pollution of formerly freshwater and estuarine streams. Groundwater
3050-493: Is at a temperature of 273.16 K (0.01 °C; 32.02 °F) and a pressure of 611.657 pascals (0.00604 atm; 0.0887 psi); it is the lowest pressure at which liquid water can exist. Until 2019 , the triple point was used to define the Kelvin temperature scale . The water/vapor phase curve terminates at 647.096 K (373.946 °C; 705.103 °F) and 22.064 megapascals (3,200.1 psi; 217.75 atm). This
3172-458: Is called the water table . Groundwater is recharged from the surface; it may discharge from the surface naturally at springs and seeps , and can form oases or wetlands . Groundwater is also often withdrawn for agricultural , municipal , and industrial use by constructing and operating extraction wells . The study of the distribution and movement of groundwater is hydrogeology , also called groundwater hydrology . Typically, groundwater
3294-415: Is concerned) is a lowering of the water table beyond the reach of existing wells. As a consequence, wells must be drilled deeper to reach the groundwater; in some places (e.g., California , Texas , and India ) the water table has dropped hundreds of feet because of extensive well pumping. The GRACE satellites have collected data that demonstrates 21 of Earth's 37 major aquifers are undergoing depletion. In
3416-458: Is formed through the cooling and solidification of magma or lava . This magma may be derived from partial melts of pre-existing rocks in either a planet 's mantle or crust . Typically, the melting of rocks is caused by one or more of three processes: an increase in temperature, a decrease in pressure, or a change in composition. Igneous rocks are divided into two main categories: Magmas tend to become richer in silica as they rise towards
3538-411: Is fresh water located in the subsurface pore space of soil and rocks . It is also water that is flowing within aquifers below the water table . Sometimes it is useful to make a distinction between groundwater that is closely associated with surface water , and deep groundwater in an aquifer (called " fossil water " if it infiltrated into the ground millennia ago). Groundwater can be thought of in
3660-428: Is greater than the repulsion between the hydrogen atoms. The O–H bond length is about 0.096 nm. Other substances have a tetrahedral molecular structure, for example methane ( CH 4 ) and hydrogen sulfide ( H 2 S ). However, oxygen is more electronegative than most other elements, so the oxygen atom has a negative partial charge while the hydrogen atoms are partially positively charged. Along with
3782-487: Is important in many geological processes. Groundwater is present in most rocks , and the pressure of this groundwater affects patterns of faulting . Water in the mantle is responsible for the melt that produces volcanoes at subduction zones . On the surface of the Earth, water is important in both chemical and physical weathering processes. Water, and to a lesser but still significant extent, ice, are also responsible for
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3904-470: Is it a noble gas (and therefore is not removed from the atmosphere through chemical reactions with other elements), but comparisons between the abundances of its nine stable isotopes in the modern atmosphere reveal that the Earth lost at least one ocean of water early in its history, between the Hadean and Archean eons. Any water on Earth during the latter part of its accretion would have been disrupted by
4026-498: Is known as the critical point . At higher temperatures and pressures the liquid and vapor phases form a continuous phase called a supercritical fluid . It can be gradually compressed or expanded between gas-like and liquid-like densities; its properties (which are quite different from those of ambient water) are sensitive to density. For example, for suitable pressures and temperatures it can mix freely with nonpolar compounds , including most organic compounds . This makes it useful in
4148-413: Is lower than that of liquid water. In a water molecule, the hydrogen atoms form a 104.5° angle with the oxygen atom. The hydrogen atoms are close to two corners of a tetrahedron centered on the oxygen. At the other two corners are lone pairs of valence electrons that do not participate in the bonding. In a perfect tetrahedron, the atoms would form a 109.5° angle, but the repulsion between the lone pairs
4270-442: Is next in importance. About 65% of the Earth's crust by volume consists of igneous rocks. Of these, 66% are basalt and gabbro , 16% are granite, and 17% granodiorite and diorite . Only 0.6% are syenite and 0.3% are ultramafic . The oceanic crust is 99% basalt, which is an igneous rock of mafic composition. Granite and similar rocks, known as granitoids , dominate the continental crust . Sedimentary rocks are formed at
4392-512: Is often cheaper, more convenient and less vulnerable to pollution than surface water . Therefore, it is commonly used for public drinking water supplies. For example, groundwater provides the largest source of usable water storage in the United States , and California annually withdraws the largest amount of groundwater of all the states. Underground reservoirs contain far more water than the capacity of all surface reservoirs and lakes in
4514-422: Is poor at dissolving nonpolar substances. This allows it to be the " solvent of life": indeed, water as found in nature almost always includes various dissolved substances, and special steps are required to obtain chemically pure water . Water is the only common substance to exist as a solid , liquid, and gas in normal terrestrial conditions. Along with oxidane , water is one of the two official names for
4636-465: Is rapidly increasing with population growth, while climate change is imposing additional stress on water resources and raising the probability of severe drought occurrence. The anthropogenic effects on groundwater resources are mainly due to groundwater pumping and the indirect effects of irrigation and land use changes. Groundwater plays a central role in sustaining water supplies and livelihoods in sub-Saharan Africa . In some cases, groundwater
4758-557: Is susceptible to saltwater intrusion in coastal areas and can cause land subsidence when extracted unsustainably, leading to sinking cities (like Bangkok ) and loss in elevation (such as the multiple meters lost in the Central Valley of California ). These issues are made more complicated by sea level rise and other effects of climate change , particularly those on the water cycle . Earth's axial tilt has shifted 31 inches because of human groundwater pumping. Groundwater
4880-399: Is the most accessed source of freshwater around the world, including as drinking water , irrigation , and manufacturing . Groundwater accounts for about half of the world's drinking water, 40% of its irrigation water, and a third of water for industrial purposes. Another estimate stated that globally groundwater accounts for about one third of all water withdrawals , and surface water for
5002-453: Is the study of Earth and its components, including the study of rock formations. Petrology is the study of the character and origin of rocks. Mineralogy is the study of the mineral components that create rocks. The study of rocks and their components has contributed to the geological understanding of Earth's history, the archaeological understanding of human history, and the development of engineering and technology in human society. While
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5124-458: Is the study of the movement, distribution, and quality of water throughout the Earth. The study of the distribution of water is hydrography . The study of the distribution and movement of groundwater is hydrogeology , of glaciers is glaciology , of inland waters is limnology and distribution of oceans is oceanography . Ecological processes with hydrology are in the focus of ecohydrology . The collective mass of water found on, under, and over
5246-495: Is thought of as water flowing through shallow aquifers, but, in the technical sense, it can also contain soil moisture , permafrost (frozen soil), immobile water in very low permeability bedrock , and deep geothermal or oil formation water. Groundwater is hypothesized to provide lubrication that can possibly influence the movement of faults . It is likely that much of Earth 's subsurface contains some water, which may be mixed with other fluids in some instances. Groundwater
5368-454: Is used for irrigation. Occasionally, sedimentary or "fossil" aquifers are used to provide irrigation and drinking water to urban areas. In Libya, for example, Muammar Gaddafi's Great Manmade River project has pumped large amounts of groundwater from aquifers beneath the Sahara to populous areas near the coast. Though this has saved Libya money over the alternative, seawater desalination,
5490-485: The Moon-forming impact (~4.5 billion years ago), which likely vaporized much of Earth's crust and upper mantle and created a rock-vapor atmosphere around the young planet. The rock vapor would have condensed within two thousand years, leaving behind hot volatiles which probably resulted in a majority carbon dioxide atmosphere with hydrogen and water vapor . Afterward, liquid water oceans may have existed despite
5612-583: The Punjab region of India , for example, groundwater levels have dropped 10 meters since 1979, and the rate of depletion is accelerating. A lowered water table may, in turn, cause other problems such as groundwater-related subsidence and saltwater intrusion . Another cause for concern is that groundwater drawdown from over-allocated aquifers has the potential to cause severe damage to both terrestrial and aquatic ecosystems – in some cases very conspicuously but in others quite imperceptibly because of
5734-432: The elements hydrogen and oxygen by passing an electric current through it—a process called electrolysis . The decomposition requires more energy input than the heat released by the inverse process (285.8 kJ/ mol , or 15.9 MJ/kg). Liquid water can be assumed to be incompressible for most purposes: its compressibility ranges from 4.4 to 5.1 × 10 Pa in ordinary conditions. Even in oceans at 4 km depth, where
5856-444: The fluids of all known living organisms (in which it acts as a solvent ). It is vital for all known forms of life , despite not providing food energy or organic micronutrients . Its chemical formula, H 2 O , indicates that each of its molecules contains one oxygen and two hydrogen atoms , connected by covalent bonds . The hydrogen atoms are attached to the oxygen atom at an angle of 104.45°. In liquid form, H 2 O
5978-417: The history of geology includes many theories of rocks and their origins that have persisted throughout human history, the study of rocks was developed as a formal science during the 19th century. Plutonism was developed as a theory during this time, and the discovery of radioactive decay in 1896 allowed for the radiocarbon dating of rocks. Understanding of plate tectonics developed in the second half of
6100-442: The hydraulic pressure of groundwater in the pore spaces of the aquifer and the aquitard supports some of the weight of the overlying sediments. When groundwater is removed from aquifers by excessive pumping, pore pressures in the aquifer drop and compression of the aquifer may occur. This compression may be partially recoverable if pressures rebound, but much of it is not. When the aquifer gets compressed, it may cause land subsidence,
6222-529: The molar volumes of the liquid and solid phases, and L f {\displaystyle L_{\text{f}}} is the molar latent heat of melting. In most substances, the volume increases when melting occurs, so the melting temperature increases with pressure. However, because ice is less dense than water, the melting temperature decreases. In glaciers, pressure melting can occur under sufficiently thick volumes of ice, resulting in subglacial lakes . The Clausius-Clapeyron relation also applies to
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#17327830727356344-404: The vadose zone below plant roots and is often expressed as a flux to the water table surface. Groundwater recharge also encompasses water moving away from the water table farther into the saturated zone. Recharge occurs both naturally (through the water cycle ) and through anthropogenic processes (i.e., "artificial groundwater recharge"), where rainwater and/or reclaimed water is routed to
6466-416: The water cycle consisting of the following transfer processes: Rock (geology) In geology , rock (or stone ) is any naturally occurring solid mass or aggregate of minerals or mineraloid matter. It is categorized by the minerals included, its chemical composition , and the way in which it is formed. Rocks form the Earth's outer solid layer, the crust , and most of its interior, except for
6588-449: The water cycle of evaporation , transpiration ( evapotranspiration ), condensation , precipitation, and runoff , usually reaching the sea. Water plays an important role in the world economy . Approximately 70% of the fresh water used by humans goes to agriculture . Fishing in salt and fresh water bodies has been, and continues to be, a major source of food for many parts of the world, providing 6.5% of global protein. Much of
6710-399: The 20th century. Rocks are composed primarily of grains of minerals, which are crystalline solids formed from atoms chemically bonded into an orderly structure. Some rocks also contain mineraloids , which are rigid, mineral-like substances, such as volcanic glass , that lack crystalline structure. The types and abundance of minerals in a rock are determined by the manner in which it
6832-444: The Earth was younger and less massive , water would have been lost to space more easily. Lighter elements like hydrogen and helium are expected to leak from the atmosphere continually, but isotopic ratios of heavier noble gases in the modern atmosphere suggest that even the heavier elements in the early atmosphere were subject to significant losses. In particular, xenon is useful for calculations of water loss over time. Not only
6954-442: The Earth's crust, or lava cools on the ground surface or the seabed. Sedimentary rocks are formed by diagenesis and lithification of sediments , which in turn are formed by the weathering , transport, and deposition of existing rocks. Metamorphic rocks are formed when existing rocks are subjected to such high pressures and temperatures that they are transformed without significant melting. Humanity has made use of rocks since
7076-467: The Earth's surface, a process called magma differentiation . This occurs both because minerals low in silica crystallize out of the magma as it begins to cool ( Bowen's reaction series ) and because the magma assimilates some of the crustal rock through which it ascends ( country rock ), and crustal rock tends to be high in silica. Silica content is thus the most important chemical criterion for classifying igneous rock. The content of alkali metal oxides
7198-503: The Earth's surface: temperatures greater than 150 to 200 °C and pressures greater than 1500 bars. This occurs, for example, when continental plates collide. Metamorphic rocks compose 27.4% of the crust by volume. The three major classes of metamorphic rock are based upon the formation mechanism. An intrusion of magma that heats the surrounding rock causes contact metamorphism—a temperature-dominated transformation. Pressure metamorphism occurs when sediments are buried deep under
7320-538: The Indo-European root, with Greek ύδωρ ( ýdor ; from Ancient Greek ὕδωρ ( hýdōr ), whence English ' hydro- ' ), Russian вода́ ( vodá ), Irish uisce , and Albanian ujë . One factor in estimating when water appeared on Earth is that water is continually being lost to space. H 2 O molecules in the atmosphere are broken up by photolysis , and the resulting free hydrogen atoms can sometimes escape Earth's gravitational pull. When
7442-924: The US, including the Great Lakes . Many municipal water supplies are derived solely from groundwater. Over 2 billion people rely on it as their primary water source worldwide. Human use of groundwater causes environmental problems. For example, polluted groundwater is less visible and more difficult to clean up than pollution in rivers and lakes. Groundwater pollution most often results from improper disposal of wastes on land. Major sources include industrial and household chemicals and garbage landfills , excessive fertilizers and pesticides used in agriculture, industrial waste lagoons, tailings and process wastewater from mines, industrial fracking , oil field brine pits, leaking underground oil storage tanks and pipelines, sewage sludge and septic systems . Additionally, groundwater
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#17327830727357564-561: The age of groundwater obtained from different parts of the Great Artesian Basin, hydrogeologists have found it increases in age across the basin. Where water recharges the aquifers along the Eastern Divide , ages are young. As groundwater flows westward across the continent, it increases in age, with the oldest groundwater occurring in the western parts. This means that in order to have travelled almost 1000 km from
7686-405: The aquifer reduces the water pressure in the confining layer, causing it to compress from the weight of overlying geologic materials. In severe cases, this compression can be observed on the ground surface as subsidence . Unfortunately, much of the subsidence from groundwater extraction is permanent (elastic rebound is small). Thus, the subsidence is not only permanent, but the compressed aquifer has
7808-523: The aquifers are likely to run dry in 60 to 100 years. Groundwater provides critical freshwater supply, particularly in dry regions where surface water availability is limited. Globally, more than one-third of the water used originates from underground. In the mid-latitude arid and semi-arid regions lacking sufficient surface water supply from rivers and reservoirs, groundwater is critical for sustaining global ecology and meeting societal needs of drinking water and food production. The demand for groundwater
7930-597: The atmosphere and fresh surface water (which have residence times from minutes to years). Deep groundwater (which is quite distant from the surface recharge) can take a very long time to complete its natural cycle. The Great Artesian Basin in central and eastern Australia is one of the largest confined aquifer systems in the world, extending for almost 2 million km. By analysing the trace elements in water sourced from deep underground, hydrogeologists have been able to determine that water extracted from these aquifers can be more than 1 million years old. By comparing
8052-508: The atmosphere through evapotranspiration , these salts are left behind. In irrigation districts, poor drainage of soils and surface aquifers can result in water tables' coming to the surface in low-lying areas. Major land degradation problems of soil salinity and waterlogging result, combined with increasing levels of salt in surface waters. As a consequence, major damage has occurred to local economies and environments. Aquifers in surface irrigated areas in semi-arid zones with reuse of
8174-577: The bent structure, this gives the molecule an electrical dipole moment and it is classified as a polar molecule . Water is a good polar solvent , dissolving many salts and hydrophilic organic molecules such as sugars and simple alcohols such as ethanol . Water also dissolves many gases, such as oxygen and carbon dioxide —the latter giving the fizz of carbonated beverages, sparkling wines and beers. In addition, many substances in living organisms, such as proteins , DNA and polysaccharides , are dissolved in water. The interactions between water and
8296-537: The boiling point, but with the liquid/gas transition the vapor phase has a much lower density than the liquid phase, so the boiling point increases with pressure. Water can remain in a liquid state at high temperatures in the deep ocean or underground. For example, temperatures exceed 205 °C (401 °F) in Old Faithful , a geyser in Yellowstone National Park . In hydrothermal vents ,
8418-785: The chemical compound H 2 O ; it is also the liquid phase of H 2 O . The other two common states of matter of water are the solid phase, ice , and the gaseous phase, water vapor or steam . The addition or removal of heat can cause phase transitions : freezing (water to ice), melting (ice to water), vaporization (water to vapor), condensation (vapor to water), sublimation (ice to vapor) and deposition (vapor to ice). Water differs from most liquids in that it becomes less dense as it freezes. In 1 atm pressure, it reaches its maximum density of 999.972 kg/m (62.4262 lb/cu ft) at 3.98 °C (39.16 °F), or almost 1,000 kg/m (62.43 lb/cu ft) at almost 4 °C (39 °F). The density of ice
8540-523: The constituent particles, and particle size . These physical properties are the result of the processes that formed the rocks. Over the course of time, rocks can be transformed from one type into another, as described by a geological model called the rock cycle . This transformation produces three general classes of rock: igneous , sedimentary and metamorphic . Those three classes are subdivided into many groups. There are, however, no hard-and-fast boundaries between allied rocks. By increase or decrease in
8662-486: The current population growth rate. Global groundwater depletion has been calculated to be between 100 and 300 km per year. This depletion is mainly caused by "expansion of irrigated agriculture in drylands ". The Asia-Pacific region is the largest groundwater abstractor in the world, containing seven out of the ten countries that extract most groundwater (Bangladesh, China, India, Indonesia, Iran, Pakistan and Turkey). These countries alone account for roughly 60% of
8784-433: The desired result. Conversely, a pressure cooker can be used to decrease cooking times by raising the boiling temperature. In a vacuum, water will boil at room temperature. On a pressure/temperature phase diagram (see figure), there are curves separating solid from vapor, vapor from liquid, and liquid from solid. These meet at a single point called the triple point , where all three phases can coexist. The triple point
8906-496: The earliest humans. This early period, called the Stone Age , saw the development of many stone tools. Stone was then used as a major component in the construction of buildings and early infrastructure . Mining developed to extract rocks from the Earth and obtain the minerals within them, including metals . Modern technology has allowed the development of new human-made rocks and rock-like substances, such as concrete . Geology
9028-606: The earth's surface by the accumulation and cementation of fragments of earlier rocks, minerals, and organisms or as chemical precipitates and organic growths in water ( sedimentation ). This process causes clastic sediments (pieces of rock) or organic particles ( detritus ) to settle and accumulate or for minerals to chemically precipitate ( evaporite ) from a solution . The particulate matter then undergoes compaction and cementation at moderate temperatures and pressures ( diagenesis ). Before being deposited, sediments are formed by weathering of earlier rocks by erosion in
9150-427: The earth, from an ore body, vein or seam . The term also includes the removal of soil. Materials recovered by mining include base metals , precious metals , iron , uranium , coal , diamonds , limestone , oil shale , rock salt , potash , construction aggregate and dimension stone . Mining is required to obtain any material that cannot be grown through agricultural processes, or created artificially in
9272-403: The extended period over which the damage occurs. The importance of groundwater to ecosystems is often overlooked, even by freshwater biologists and ecologists. Groundwaters sustain rivers, wetlands , and lakes , as well as subterranean ecosystems within karst or alluvial aquifers. Not all ecosystems need groundwater, of course. Some terrestrial ecosystems – for example, those of
9394-406: The extent, depth and thickness of water-bearing sediments and rocks. Before an investment is made in production wells, test wells may be drilled to measure the depths at which water is encountered and collect samples of soils, rock and water for laboratory analyses. Pumping tests can be performed in test wells to determine flow characteristics of the aquifer. The characteristics of aquifers vary with
9516-486: The force of gravity . This property is relied upon by all vascular plants , such as trees. Water is a weak solution of hydronium hydroxide—there is an equilibrium 2H 2 O ⇌ H 3 O + OH , in combination with solvation of the resulting hydronium and hydroxide ions. Pure water has a low electrical conductivity , which increases with the dissolution of a small amount of ionic material such as common salt . Liquid water can be split into
9638-479: The form of snow . The gaseous state of water is steam or water vapor . Water covers about 71% of the Earth's surface, with seas and oceans making up most of the water volume (about 96.5%). Small portions of water occur as groundwater (1.7%), in the glaciers and the ice caps of Antarctica and Greenland (1.7%), and in the air as vapor , clouds (consisting of ice and liquid water suspended in air), and precipitation (0.001%). Water moves continually through
9760-450: The fundamental stretching absorption spectrum of water or of an aqueous solution in the region around 3,500 cm (2.85 μm) a path length of about 25 μm is needed. Also, the cuvette must be both transparent around 3500 cm and insoluble in water; calcium fluoride is one material that is in common use for the cuvette windows with aqueous solutions. The Raman-active fundamental vibrations may be observed with, for example,
9882-472: The geology and structure of the substrate and topography in which they occur. In general, the more productive aquifers occur in sedimentary geologic formations. By comparison, weathered and fractured crystalline rocks yield smaller quantities of groundwater in many environments. Unconsolidated to poorly cemented alluvial materials that have accumulated as valley -filling sediments in major river valleys and geologically subsiding structural basins are included among
10004-400: The globe includes canals redirecting surface water, groundwater pumping, and diverting water from dams. Aquifers are critically important in agriculture. Deep aquifers in arid areas have long been water sources for irrigation. A majority of extracted groundwater, 70%, is used for agricultural purposes. In India, 65% of the irrigation is from groundwater and about 90% of extracted groundwater
10126-414: The ground surface (within a couple of hundred metres) and have some recharge by fresh water. This recharge is typically from rivers or meteoric water (precipitation) that percolates into the aquifer through overlying unsaturated materials. In general, the irrigation of 20% of farming land (with various types of water sources) accounts for the production of 40% of food production. Irrigation techniques across
10248-402: The ground; pressure is dominant, and temperature plays a smaller role. This is termed burial metamorphism, and it can result in rocks such as jade . Where both heat and pressure play a role, the mechanism is termed regional metamorphism. This is typically found in mountain-building regions. Depending on the structure, metamorphic rocks are divided into two general categories. Those that possess
10370-403: The influence of continuous evaporation, the salt concentration of the aquifer water may increase continually and eventually cause an environmental problem. Water Water is an inorganic compound with the chemical formula H 2 O . It is a transparent, tasteless, odorless, and nearly colorless chemical substance . It is the main constituent of Earth 's hydrosphere and
10492-491: The kind of metals available from the rock of a region. Anthropic rock is synthetic or restructured rock formed by human activity. Concrete is recognized as a human-made rock constituted of natural and processed rock and having been developed since Ancient Rome . Rock can also be modified with other substances to develop new forms, such as epoxy granite . Artificial stone has also been developed, such as Coade stone . Geologist James R. Underwood has proposed anthropic rock as
10614-431: The land to prepare it for other uses once mining ceases. Mining processes may create negative impacts on the environment both during the mining operations and for years after mining has ceased. These potential impacts have led to most of the world's nations adopting regulations to manage negative effects of mining operations. Stone tools have been used for millions of years by humans and earlier hominids . The Stone Age
10736-467: The liquid outer core and pockets of magma in the asthenosphere . The study of rocks involves multiple subdisciplines of geology, including petrology and mineralogy . It may be limited to rocks found on Earth, or it may include planetary geology that studies the rocks of other celestial objects. Rocks are usually grouped into three main groups: igneous rocks , sedimentary rocks and metamorphic rocks . Igneous rocks are formed when magma cools in
10858-416: The liquid is known as boiling ). Sublimation and deposition also occur on surfaces. For example, frost is deposited on cold surfaces while snowflakes form by deposition on an aerosol particle or ice nucleus. In the process of freeze-drying , a food is frozen and then stored at low pressure so the ice on its surface sublimates. The melting and boiling points depend on pressure. A good approximation for
10980-753: The liquid or solid state can form up to four hydrogen bonds with neighboring molecules. Hydrogen bonds are about ten times as strong as the Van der Waals force that attracts molecules to each other in most liquids. This is the reason why the melting and boiling points of water are much higher than those of other analogous compounds like hydrogen sulfide. They also explain its exceptionally high specific heat capacity (about 4.2 J /(g·K)), heat of fusion (about 333 J/g), heat of vaporization ( 2257 J/g ), and thermal conductivity (between 0.561 and 0.679 W/(m·K)). These properties make water more effective at moderating Earth's climate , by storing heat and transporting it between
11102-518: The local hydrogeology , may draw in non-potable water or saltwater intrusion from hydraulically connected aquifers or surface water bodies. This can be a serious problem, especially in coastal areas and other areas where aquifer pumping is excessive. Subsidence occurs when too much water is pumped out from underground, deflating the space below the above-surface, and thus causing the ground to collapse. The result can look like craters on plots of land. This occurs because, in its natural equilibrium state,
11224-1070: The long-distance trade of commodities (such as oil, natural gas, and manufactured products) is transported by boats through seas, rivers, lakes, and canals. Large quantities of water, ice, and steam are used for cooling and heating in industry and homes. Water is an excellent solvent for a wide variety of substances, both mineral and organic; as such, it is widely used in industrial processes and in cooking and washing. Water, ice, and snow are also central to many sports and other forms of entertainment, such as swimming , pleasure boating, boat racing , surfing , sport fishing , diving , ice skating , snowboarding , and skiing . The word water comes from Old English wæter , from Proto-Germanic * watar (source also of Old Saxon watar , Old Frisian wetir , Dutch water , Old High German wazzar , German Wasser , vatn , Gothic 𐍅𐌰𐍄𐍉 ( wato )), from Proto-Indo-European * wod-or , suffixed form of root * wed- ( ' water ' ; ' wet ' ). Also cognate , through
11346-410: The most productive sources of groundwater. Fluid flows can be altered in different lithological settings by brittle deformation of rocks in fault zones ; the mechanisms by which this occurs are the subject of fault zone hydrogeology . Reliance on groundwater will only increase, mainly due to growing water demand by all sectors combined with increasing variation in rainfall patterns . Groundwater
11468-418: The oceans and the atmosphere. The hydrogen bonds of water are around 23 kJ/mol (compared to a covalent O-H bond at 492 kJ/mol). Of this, it is estimated that 90% is attributable to electrostatics, while the remaining 10% is partially covalent. These bonds are the cause of water's high surface tension and capillary forces. The capillary action refers to the tendency of water to move up a narrow tube against
11590-538: The oceans may have always been on the Earth since the beginning of the planet's formation . Water ( H 2 O ) is a polar inorganic compound . At room temperature it is a tasteless and odorless liquid , nearly colorless with a hint of blue . The simplest hydrogen chalcogenide , it is by far the most studied chemical compound and is sometimes described as the "universal solvent" for its ability to dissolve more substances than any other liquid, though it
11712-671: The open deserts and similar arid environments – exist on irregular rainfall and the moisture it delivers to the soil, supplemented by moisture in the air. While there are other terrestrial ecosystems in more hospitable environments where groundwater plays no central role, groundwater is in fact fundamental to many of the world's major ecosystems. Water flows between groundwaters and surface waters. Most rivers, lakes, and wetlands are fed by, and (at other places or times) feed groundwater, to varying degrees. Groundwater feeds soil moisture through percolation, and many terrestrial vegetation communities depend directly on either groundwater or
11834-418: The original rock was formed. This process is called metamorphism , meaning to "change in form". The result is a profound change in physical properties and chemistry of the stone. The original rock, known as the protolith , transforms into other mineral types or other forms of the same minerals, by recrystallization . The temperatures and pressures required for this process are always higher than those found at
11956-464: The other two thirds. Groundwater provides drinking water to at least 50% of the global population. About 2.5 billion people depend solely on groundwater resources to satisfy their basic daily water needs. A similar estimate was published in 2021 which stated that "groundwater is estimated to supply between a quarter and a third of the world's annual freshwater withdrawals to meet agricultural, industrial and domestic demands." Global freshwater withdrawal
12078-425: The particles of clastic sedimentary rocks can be further classified by grain size . The smallest sediments are clay , followed by silt , sand , and gravel . Some systems include cobbles and boulders as measurements. Metamorphic rocks are formed by subjecting any rock type—sedimentary rock, igneous rock or another older metamorphic rock—to different temperature and pressure conditions than those in which
12200-679: The percolated soil moisture above the aquifer for at least part of each year. Hyporheic zones (the mixing zone of streamwater and groundwater) and riparian zones are examples of ecotones largely or totally dependent on groundwater. A 2021 study found that of ~39 million investigated groundwater wells 6-20% are at high risk of running dry if local groundwater levels decline by a few meters, or – as with many areas and possibly more than half of major aquifers – continue to decline. Fresh-water aquifers, especially those with limited recharge by snow or rain, also known as meteoric water , can be over-exploited and depending on
12322-402: The presence of water in their mouths, and frogs are known to be able to smell it. However, water from ordinary sources (including mineral water ) usually has many dissolved substances that may give it varying tastes and odors. Humans and other animals have developed senses that enable them to evaluate the potability of water in order to avoid water that is too salty or putrid . Pure water
12444-437: The pressure is 400 atm, water suffers only a 1.8% decrease in volume. The viscosity of water is about 10 Pa· s or 0.01 poise at 20 °C (68 °F), and the speed of sound in liquid water ranges between 1,400 and 1,540 metres per second (4,600 and 5,100 ft/s) depending on temperature. Sound travels long distances in water with little attenuation , especially at low frequencies (roughly 0.03 dB /km for 1 k Hz ),
12566-466: The proportions of their minerals, they pass through gradations from one to the other; the distinctive structures of one kind of rock may thus be traced, gradually merging into those of another. Hence the definitions adopted in rock names simply correspond to selected points in a continuously graduated series. Igneous rock (derived from the Latin word igneus, meaning of fire, from ignis meaning fire)
12688-587: The rate of change of the melting temperature with pressure is given by the Clausius–Clapeyron relation : d T d P = T ( v L − v S ) L f {\displaystyle {\frac {dT}{dP}}={\frac {T\left(v_{\text{L}}-v_{\text{S}}\right)}{L_{\text{f}}}}} where v L {\displaystyle v_{\text{L}}} and v S {\displaystyle v_{\text{S}}} are
12810-423: The same terms as surface water : inputs, outputs and storage. The natural input to groundwater is seepage from surface water. The natural outputs from groundwater are springs and seepage to the oceans. Due to its slow rate of turnover, groundwater storage is generally much larger (in volume) compared to inputs than it is for surface water. This difference makes it easy for humans to use groundwater unsustainably for
12932-416: The source of recharge in 1 million years, the groundwater flowing through the Great Artesian Basin travels at an average rate of about 1 metre per year. Groundwater recharge or deep drainage or deep percolation is a hydrologic process, where water moves downward from surface water to groundwater. Recharge is the primary method through which water enters an aquifer . This process usually occurs in
13054-497: The subsurface. The high specific heat capacity of water and the insulating effect of soil and rock can mitigate the effects of climate and maintain groundwater at a relatively steady temperature . In some places where groundwater temperatures are maintained by this effect at about 10 °C (50 °F), groundwater can be used for controlling the temperature inside structures at the surface. For example, during hot weather relatively cool groundwater can be pumped through radiators in
13176-413: The subunits of these biomacromolecules shape protein folding , DNA base pairing , and other phenomena crucial to life ( hydrophobic effect ). Many organic substances (such as fats and oils and alkanes ) are hydrophobic , that is, insoluble in water. Many inorganic substances are insoluble too, including most metal oxides , sulfides , and silicates . Because of its polarity, a molecule of water in
13298-488: The surface of a planet is called the hydrosphere . Earth's approximate water volume (the total water supply of the world) is 1.386 billion cubic kilometres (333 million cubic miles). Liquid water is found in bodies of water , such as an ocean, sea, lake, river, stream, canal , pond, or puddle . The majority of water on Earth is seawater . Water is also present in the atmosphere in solid, liquid, and vapor states. It also exists as groundwater in aquifers . Water
13420-537: The surface temperature of 230 °C (446 °F) due to the increased atmospheric pressure of the CO 2 atmosphere. As the cooling continued, most CO 2 was removed from the atmosphere by subduction and dissolution in ocean water, but levels oscillated wildly as new surface and mantle cycles appeared. Geological evidence also helps constrain the time frame for liquid water existing on Earth. A sample of pillow basalt (a type of rock formed during an underwater eruption)
13542-403: The temperature can exceed 400 °C (752 °F). At sea level , the boiling point of water is 100 °C (212 °F). As atmospheric pressure decreases with altitude, the boiling point decreases by 1 °C every 274 meters. High-altitude cooking takes longer than sea-level cooking. For example, at 1,524 metres (5,000 ft), cooking time must be increased by a fourth to achieve
13664-405: The unavoidable irrigation water losses percolating down into the underground by supplemental irrigation from wells run the risk of salination . Surface irrigation water normally contains salts in the order of 0.5 g/L or more and the annual irrigation requirement is in the order of 10,000 m/ha or more so the annual import of salt is in the order of 5,000 kg/ha or more. Under
13786-621: The universe's celestial bodies. In the Solar System , Mars , Venus , and Mercury are composed of rock, as are many natural satellites , asteroids , and meteoroids . Meteorites that fall to Earth provide evidence of extraterrestrial rocks and their composition. They are typically heavier than rocks on Earth. Asteroid rocks can also be brought to Earth through space missions, such as the Hayabusa mission. Lunar rocks and Martian rocks have also been studied. The use of rock has had
13908-458: The upper atmosphere. As the pressure increases, ice forms other crystal structures . As of 2024, twenty have been experimentally confirmed and several more are predicted theoretically. The eighteenth form of ice, ice XVIII , a face-centred-cubic, superionic ice phase, was discovered when a droplet of water was subject to a shock wave that raised the water's pressure to millions of atmospheres and its temperature to thousands of degrees, resulting in
14030-441: The winter. Water is a diamagnetic material. Though interaction is weak, with superconducting magnets it can attain a notable interaction. At a pressure of one atmosphere (atm), ice melts or water freezes (solidifies) at 0 °C (32 °F) and water boils or vapor condenses at 100 °C (212 °F). However, even below the boiling point, water can change to vapor at its surface by evaporation (vaporization throughout
14152-517: The world's liquid fresh water is groundwater. Global groundwater storage is roughly equal to the total amount of freshwater stored in the snow and ice pack, including the north and south poles. This makes it an important resource that can act as a natural storage that can buffer against shortages of surface water , as in during times of drought . The volume of groundwater in an aquifer can be estimated by measuring water levels in local wells and by examining geologic records from well-drilling to determine
14274-418: The world's total groundwater withdrawal. Groundwater may or may not be a safe water source. In fact, there is considerable uncertainty with groundwater in different hydrogeologic contexts: the widespread presence of contaminants such as arsenic , fluoride and salinity can reduce the suitability of groundwater as a drinking water source. Arsenic and fluoride have been considered as priority contaminants at
14396-408: Was a period of widespread stone tool usage. Early Stone Age tools were simple implements, such as hammerstones and sharp flakes. Middle Stone Age tools featured sharpened points to be used as projectile points , awls, or scrapers . Late Stone Age tools were developed with craftsmanship and distinct cultural identities. Stone tools were largely superseded by copper and bronze tools following
14518-456: Was formed. Most rocks contain silicate minerals , compounds that include silica tetrahedra in their crystal lattice , and account for about one-third of all known mineral species and about 95% of the earth's crust . The proportion of silica in rocks and minerals is a major factor in determining their names and properties. Rocks are classified according to characteristics such as mineral and chemical composition, permeability , texture of
14640-400: Was probably around 600 km per year in 1900 and increased to 3,880 km per year in 2017. The rate of increase was especially high (around 3% per year) during the period 1950–1980, partly due to a higher population growth rate, and partly to rapidly increasing groundwater development, particularly for irrigation. The rate of increase is (as per 2022) approximately 1% per year, in tune with
14762-737: Was quarried for construction as early as 4000 BCE in Egypt, and stone was used to build fortifications in Inner Mongolia as early as 2800 BCE. The soft rock, tuff , is common in Italy, and the Romans used it for many buildings and bridges. Limestone was widely used in construction in the Middle Ages in Europe and remained popular into the 20th century. Mining is the extraction of valuable minerals or other geological materials from
14884-809: Was recovered from the Isua Greenstone Belt and provides evidence that water existed on Earth 3.8 billion years ago. In the Nuvvuagittuq Greenstone Belt , Quebec, Canada, rocks dated at 3.8 billion years old by one study and 4.28 billion years old by another show evidence of the presence of water at these ages. If oceans existed earlier than this, any geological evidence has yet to be discovered (which may be because such potential evidence has been destroyed by geological processes like crustal recycling ). More recently, in August 2020, researchers reported that sufficient water to fill
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