88-566: (Redirected from Gutters ) [REDACTED] Look up gutter in Wiktionary, the free dictionary. Gutter may refer to: Water discharge structures [ edit ] Rain gutter , used on roofs and in buildings Street gutter , for drainage of streets Film [ edit ] The Gutter (1938 film) , a French film The Gutter (2024 film) , an American film Design and printing [ edit ] Gutter, in typography,
176-460: A gutter . The word gutter derives from Latin gutta (noun), meaning "a droplet". Guttering in its earliest form consisted of lined wooden or stone troughs. Lead was a popular liner and is still used in pitched valley gutters. Many materials have been used to make guttering: cast iron , asbestos cement , UPVC (PVCu), cast and extruded aluminium , galvanized steel , wood , copper , zinc , and bamboo . Gutters prevent water ingress into
264-403: A parapet gutter , a valley gutter or an eaves gutter . When two pitched roofs meet at an angle, they also form a pitched valley gutter : the join is sealed with valley flashing. Parapet gutters and valley gutters discharge into internal rainwater pipes or directly into external down pipes at the end of the run. The capacity of the gutter is a significant design consideration. The area of
352-433: A density of 11.34 g/cm , which is greater than that of common metals such as iron (7.87 g/cm ), copper (8.93 g/cm ), and zinc (7.14 g/cm ). This density is the origin of the idiom to go over like a lead balloon . Some rarer metals are denser: tungsten and gold are both at 19.3 g/cm , and osmium —the densest metal known—has a density of 22.59 g/cm , almost twice that of lead. Lead
440-492: A few radioactive isotopes. One of them is lead-210; although it has a half-life of only 22.2 years, small quantities occur in nature because lead-210 is produced by a long decay series that starts with uranium-238 (that has been present for billions of years on Earth). Lead-211, −212, and −214 are present in the decay chains of uranium-235, thorium-232, and uranium-238, respectively, so traces of all three of these lead isotopes are found naturally. Minute traces of lead-209 arise from
528-408: A gutter that is fed into a downpipe. A flat roof should have a watertight surface with a minimum finished fall of 1 in 80. They can drain internally or to an eaves gutter, which has a minimum 1 in 360 fall towards the downpipe. The pitch of a pitched roof is determined by the construction material of the covering. For slate this will be at 25%, for machine made tiles it will be 35%. Water falls towards
616-558: A neutron and become thallium-204; this undergoes beta decay to give stable lead-204; on capturing another neutron, it becomes lead-205, which has a half-life of around 17 million years. Further captures result in lead-206, lead-207, and lead-208. On capturing another neutron, lead-208 becomes lead-209, which quickly decays into bismuth-209. On capturing another neutron, bismuth-209 becomes bismuth-210, and this beta decays to polonium-210, which alpha decays to lead-206. The cycle hence ends at lead-206, lead-207, lead-208, and bismuth-209. In
704-466: A polyhedral vertex and contributes two electrons to each covalent bond along an edge from their sp hybrid orbitals, the other two being an external lone pair . They may be made in liquid ammonia via the reduction of lead by sodium . Lead can form multiply-bonded chains , a property it shares with its lighter homologs in the carbon group. Its capacity to do so is much less because the Pb–Pb bond energy
792-569: A relatively low melting point . When freshly cut, lead is a shiny gray with a hint of blue. It tarnishes to a dull gray color when exposed to air. Lead has the highest atomic number of any stable element and three of its isotopes are endpoints of major nuclear decay chains of heavier elements. Lead is a relatively unreactive post-transition metal . Its weak metallic character is illustrated by its amphoteric nature; lead and lead oxides react with acids and bases , and it tends to form covalent bonds . Compounds of lead are usually found in
880-533: A sewerage system for London, that prevented run-off being channelled into the Thames. By the 1870s all houses were constructed with cast iron gutters and down pipes. The Victorian gutter was an ogee, 115 mm in width, that was fitted directly to the fascia boards eliminating the need for brackets. Square and half-round profiles were also available. For a brief period after the first world war , asbestos-cement guttering became popular due to it being maintenance free:
968-496: A shoe and discharge directly onto the surface, but using modern construction techniques would be connected through an inspection chamber to a drain that led to a surface water drain or soakaway. Alternatively it would connect via a storm drain (u-bend) with 50 mm water seal to a combined drain. Water from rain gutters may be harvested in a rain barrel or a cistern . Rain gutters can be equipped with gutter screens, micro mesh screens, louvers or solid hoods to allow water from
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#17327983105121056-437: A significant partial positive charge on lead. The result is a stronger contraction of the lead 6s orbital than is the case for the 6p orbital, making it rather inert in ionic compounds. The inert pair effect is less applicable to compounds in which lead forms covalent bonds with elements of similar electronegativity, such as carbon in organolead compounds. In these, the 6s and 6p orbitals remain similarly sized and sp hybridization
1144-438: A single decay chain). In total, 43 lead isotopes have been synthesized, with mass numbers 178–220. Lead-205 is the most stable radioisotope, with a half-life of around 1.70 × 10 years. The second-most stable is lead-202, which has a half-life of about 52,500 years, longer than any of the natural trace radioisotopes. Bulk lead exposed to moist air forms a protective layer of varying composition. Lead(II) carbonate
1232-511: A song by Medina See also [ edit ] Guter (disambiguation) Topics referred to by the same term [REDACTED] This disambiguation page lists articles associated with the title Gutter . If an internal link led you here, you may wish to change the link to point directly to the intended article. Retrieved from " https://en.wikipedia.org/w/index.php?title=Gutter&oldid=1245638248 " Category : Disambiguation pages Hidden categories: Short description
1320-413: A stainless steel gutter will undergo non-negligible cycles of thermal expansion and contraction as the temperature changes; if allowance for this movement is not made during installation, there will be a potential for deformation of the gutter, which may lead to improper drainage of the gutter system. Seamless gutters have the advantage of being produced on site with a portable roll forming machine to match
1408-452: A structure, with every alternate layer of oxygen atoms absent. Negative oxidation states can occur as Zintl phases , as either free lead anions, as in Ba 2 Pb, with lead formally being lead(−IV), or in oxygen-sensitive ring-shaped or polyhedral cluster ions such as the trigonal bipyramidal Pb 5 ion, where two lead atoms are lead(−I) and three are lead(0). In such anions, each atom is at
1496-531: A variety of finishes and styles. Finlock gutters, a proprietary name for concrete gutters, can be employed on a large range of buildings. There were used on domestic properties in the 1950s and 1960s, as a replacement for cast iron gutters when there was a shortage of steel and surplus of concrete. They were discredited after differential movement was found to open joints and allow damp to penetrate, but can be fitted with an aluminium and bitumastic liner. Finlock concrete gutter units are made up of two troughs – one
1584-439: A variety of materials such as cast iron , lead , zinc , galvanised steel, painted steel , copper , painted aluminium , PVC (and other plastics) and occasionally from concrete , stone , and wood . Water collected by a rain gutter is fed, usually via a downpipe (also called a leader or conductor), from the roof edge to the base of the building where it is either discharged or collected. The down pipe can terminate in
1672-457: A wooden box gutter that drained into and through structural cast iron columns. The Industrial Revolution introduced new methods of casting-iron and the railways brought a method of distributing the heavy cast-iron items to building sites. The relocation into the cities created a demand for housing that needed to be compact. Dryer houses controlled asthma , bronchitis , emphysema as well as pneumonia . In 1849 Joseph Bazalgette proposed
1760-518: A −5 °C to 25 °C temperature range will need space to expand, 30 × 4 × 0.06 = 7.2 mm within its end stops. As a rule of thumb a 4-inch (100 mm) gutter with a single 68-millimetre (2.7 in) downpipe will drain a 600-square-foot (56 m ) roof. High quality stainless steel guttering systems are available for homes and commercial projects. The advantages of stainless steel are durability, corrosion-resistance, ease of cleaning, and superior aesthetics. Compared with concrete or wood,
1848-590: Is 6 times higher, copper 10 times, and mild steel 15 times higher); it can be strengthened by adding small amounts of copper or antimony . The melting point of lead—at 327.5 °C (621.5 °F) —is very low compared to most metals. Its boiling point of 1749 °C (3180 °F) is the lowest among the carbon-group elements. The electrical resistivity of lead at 20 °C is 192 nanoohm -meters, almost an order of magnitude higher than those of other industrial metals (copper at 15.43 nΩ·m ; gold 20.51 nΩ·m ; and aluminium at 24.15 nΩ·m ). Lead
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#17327983105121936-520: Is a neurotoxin that accumulates in soft tissues and bones. It damages the nervous system and interferes with the function of biological enzymes , causing neurological disorders ranging from behavioral problems to brain damage, and also affects general health, cardiovascular, and renal systems. Lead's toxicity was first documented by ancient Greek and Roman writers, who noted some of the symptoms of lead poisoning , but became widely recognized in Europe in
2024-401: Is a superconductor at temperatures lower than 7.19 K ; this is the highest critical temperature of all type-I superconductors and the third highest of the elemental superconductors. Natural lead consists of four stable isotopes with mass numbers of 204, 206, 207, and 208, and traces of six short-lived radioisotopes with mass numbers 209–214 inclusive. The high number of isotopes
2112-420: Is a common constituent; the sulfate or chloride may also be present in urban or maritime settings. This layer makes bulk lead effectively chemically inert in the air. Finely powdered lead, as with many metals, is pyrophoric , and burns with a bluish-white flame. Fluorine reacts with lead at room temperature, forming lead(II) fluoride . The reaction with chlorine is similar but requires heating, as
2200-780: Is a mixed sulfide derived from galena; anglesite , PbSO 4 , is a product of galena oxidation; and cerussite or white lead ore, PbCO 3 , is a decomposition product of galena. Arsenic , tin , antimony , silver , gold , copper , bismuth are common impurities in lead minerals. World lead resources exceed two billion tons. Significant deposits are located in Australia, China, Ireland, Mexico, Peru, Portugal, Russia, United States. Global reserves—resources that are economically feasible to extract—totaled 88 million tons in 2016, of which Australia had 35 million, China 17 million, Russia 6.4 million. Typical background concentrations of lead do not exceed 0.1 μg/m in
2288-426: Is a strong oxidizing agent, capable of oxidizing hydrochloric acid to chlorine gas. This is because the expected PbCl 4 that would be produced is unstable and spontaneously decomposes to PbCl 2 and Cl 2 . Analogously to lead monoxide , lead dioxide is capable of forming plumbate anions. Lead disulfide and lead diselenide are only stable at high pressures. Lead tetrafluoride , a yellow crystalline powder,
2376-404: Is a very soft metal with a Mohs hardness of 1.5; it can be scratched with a fingernail. It is quite malleable and somewhat ductile. The bulk modulus of lead—a measure of its ease of compressibility—is 45.8 GPa . In comparison, that of aluminium is 75.2 GPa; copper 137.8 GPa; and mild steel 160–169 GPa. Lead's tensile strength , at 12–17 MPa, is low (that of aluminium
2464-445: Is common for the carbon group. The divalent state is rare for carbon and silicon , minor for germanium, important (but not prevailing) for tin, and is the more important of the two oxidation states for lead. This is attributable to relativistic effects , specifically the inert pair effect , which manifests itself when there is a large difference in electronegativity between lead and oxide , halide , or nitride anions, leading to
2552-408: Is consistent with lead's atomic number being even. Lead has a magic number of protons (82), for which the nuclear shell model accurately predicts an especially stable nucleus. Lead-208 has 126 neutrons, another magic number, which may explain why lead-208 is extraordinarily stable. With its high atomic number, lead is the heaviest element whose natural isotopes are regarded as stable; lead-208
2640-453: Is different from Wikidata All article disambiguation pages All disambiguation pages Rain gutter A rain gutter , eavestrough, eaves-shoot or surface water collection channel is a component of a water discharge system for a building. It is necessary to prevent water dripping or flowing off roofs in an uncontrolled manner for several reasons: to prevent it damaging the walls, drenching persons standing below or entering
2728-414: Is exploited in the synthesis of other lead compounds. Few inorganic lead(IV) compounds are known. They are only formed in highly oxidizing solutions and do not normally exist under standard conditions. Lead(II) oxide gives a mixed oxide on further oxidation, Pb 3 O 4 . It is described as lead(II,IV) oxide , or structurally 2PbO·PbO 2 , and is the best-known mixed valence lead compound. Lead dioxide
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2816-502: Is more prevalent than most other elements with atomic numbers greater than 40. Primordial lead—which comprises the isotopes lead-204, lead-206, lead-207, and lead-208—was mostly created as a result of repetitive neutron capture processes occurring in stars. The two main modes of capture are the s- and r-processes . In the s-process (s is for "slow"), captures are separated by years or decades, allowing less stable nuclei to undergo beta decay . A stable thallium-203 nucleus can capture
2904-650: Is not stable, as both the lead(III) ion and the larger complexes containing it are radicals . The same applies for lead(I), which can be found in such radical species. Numerous mixed lead(II,IV) oxides are known. When PbO 2 is heated in air, it becomes Pb 12 O 19 at 293 °C, Pb 12 O 17 at 351 °C, Pb 3 O 4 at 374 °C, and finally PbO at 605 °C. A further sesquioxide , Pb 2 O 3 , can be obtained at high pressure, along with several non-stoichiometric phases. Many of them show defective fluorite structures in which some oxygen atoms are replaced by vacancies: PbO can be considered as having such
2992-471: Is often made from UPVC sections. The first PVC pipes were introduced in the 1930s for use in sanitary drainage systems. Polyethylene was developed in 1933. The first pressurised plastic drinking water pipes were installed in the Netherlands in the 1950s. During the 1960s rain water pipes, guttering and down pipes using plastic materials were introduced followed by PVC soil systems which became viable with
3080-741: Is over three and a half times lower than that of the C–C bond . With itself, lead can build metal–metal bonds of an order up to three. With carbon, lead forms organolead compounds similar to, but generally less stable than, typical organic compounds (due to the Pb–C bond being rather weak). This makes the organometallic chemistry of lead far less wide-ranging than that of tin. Lead predominantly forms organolead(IV) compounds, even when starting with inorganic lead(II) reactants; very few organolead(II) compounds are known. The most well-characterized exceptions are Pb[CH(SiMe 3 ) 2 ] 2 and plumbocene . The lead analog of
3168-415: Is stable, but less so than the difluoride . Lead tetrachloride (a yellow oil) decomposes at room temperature, lead tetrabromide is less stable still, and the existence of lead tetraiodide is questionable. Some lead compounds exist in formal oxidation states other than +4 or +2. Lead(III) may be obtained, as an intermediate between lead(II) and lead(IV), in larger organolead complexes; this oxidation state
3256-413: Is still energetically favorable. Lead, like carbon, is predominantly tetravalent in such compounds. There is a relatively large difference in the electronegativity of lead(II) at 1.87 and lead(IV) at 2.33. This difference marks the reversal in the trend of increasing stability of the +4 oxidation state going down the carbon group; tin, by comparison, has values of 1.80 in the +2 oxidation state and 1.96 in
3344-438: Is that the pores quickly get clogged and thus need replacement due to not allowing water to pass through. Reverse curve or surface tension guards reduce clogged gutters by narrowing the opening of the gutters. Many find them to be unattractive and difficult to maintain. Screen gutter guards are among the most common and most effective. They can be snapped on or mounted, made of metal or plastic. Micromesh gutter guards provide
3432-448: Is the heaviest stable nucleus. (This distinction formerly fell to bismuth , with an atomic number of 83, until its only primordial isotope , bismuth-209, was found in 2003 to decay very slowly.) The four stable isotopes of lead could theoretically undergo alpha decay to isotopes of mercury with a release of energy, but this has not been observed for any of them; their predicted half-lives range from 10 to 10 years (at least 10 times
3520-538: Is the origin of the English word " plumbing ". Its ease of working, its low melting point enabling the easy fabrication of completely waterproof welded joints, and its resistance to corrosion ensured its widespread use in other applications, including pharmaceuticals, roofing, currency, warfare. Writers of the time, such as Cato the Elder , Columella , and Pliny the Elder , recommended lead (and lead-coated) vessels for
3608-525: Is the so-called inert pair effect : the 6s electrons of lead become reluctant to participate in bonding, stabilising the +2 oxidation state and making the distance between nearest atoms in crystalline lead unusually long. Lead's lighter carbon group congeners form stable or metastable allotropes with the tetrahedrally coordinated and covalently bonded diamond cubic structure. The energy levels of their outer s- and p-orbitals are close enough to allow mixing into four hybrid sp orbitals. In lead,
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3696-625: Is the visible gutter and the other sits across the cavity wall. The blocks which can range from 8 to 12 inches (200 to 300 mm) can be joined using reinforcing rods and concrete , to form lintels for doors and windows. Guttering can be made from any locally available material such as stone or wood. Porous materials may be lined with pitch or bitumen . Today in Western construction we use mainly three types of gutter - K-Style, round, and square. In days past there were 12 gutter shapes/styles. K-Style gets its name from its letter designation being
3784-446: Is usefully exploited: lead tetraacetate is an important laboratory reagent for oxidation in organic synthesis. Tetraethyllead, once added to automotive gasoline, was produced in larger quantities than any other organometallic compound, and is still widely used in fuel for small aircraft . Other organolead compounds are less chemically stable. For many organic compounds, a lead analog does not exist. Lead's per-particle abundance in
3872-630: The Phoenicians worked deposits in the Iberian peninsula ; by 1600 BC, lead mining existed in Cyprus , Greece , and Sardinia . Rome's territorial expansion in Europe and across the Mediterranean, and its development of mining, led to it becoming the greatest producer of lead during the classical era , with an estimated annual output peaking at 80,000 tonnes. Like their predecessors,
3960-671: The Solar System is 0.121 ppb (parts per billion). This figure is two and a half times higher than that of platinum , eight times more than mercury , and seventeen times more than gold . The amount of lead in the universe is slowly increasing as most heavier atoms (all of which are unstable) gradually decay to lead. The abundance of lead in the Solar System since its formation 4.5 billion years ago has increased by about 0.75%. The solar system abundances table shows that lead, despite its relatively high atomic number,
4048-805: The Tower of London had external gutters. In March 1240 the Keeper of the Works at the Tower of London was ordered by King Henry "to have the Great Tower whitened both inside and out". This was according to the fashion at the time. Later that year the king wrote to the Keeper, commanding that the White Tower's lead guttering should be extended with the effect that "the wall of the tower ... newly whitened, may be in no danger of perishing or falling outwards through
4136-804: The fall of Rome and did not reach comparable levels until the Industrial Revolution . Lead played a crucial role in the development of the printing press , as movable type could be relatively easily cast from lead alloys. In 2014, the annual global production of lead was about ten million tonnes, over half of which was from recycling. Lead's high density, low melting point, ductility and relative inertness to oxidation make it useful. These properties, combined with its relative abundance and low cost, resulted in its extensive use in construction , plumbing , batteries , bullets , shots , weights , solders , pewters , fusible alloys , lead paints , leaded gasoline , and radiation shielding . Lead
4224-401: The nucleus , and more shielded by smaller orbitals. The sum of the first four ionization energies of lead exceeds that of tin, contrary to what periodic trends would predict. This is explained by relativistic effects , which become significant in heavier atoms, which contract s and p orbitals such that lead's 6s electrons have larger binding energies than its 5s electrons. A consequence
4312-624: The +2 oxidation state rather than the +4 state common with lighter members of the carbon group . Exceptions are mostly limited to organolead compounds . Like the lighter members of the group, lead tends to bond with itself ; it can form chains and polyhedral structures. Since lead is easily extracted from its ores , prehistoric people in the Near East were aware of it . Galena is a principal ore of lead which often bears silver. Interest in silver helped initiate widespread extraction and use of lead in ancient Rome . Lead production declined after
4400-468: The +4 state. Lead(II) compounds are characteristic of the inorganic chemistry of lead. Even strong oxidizing agents like fluorine and chlorine react with lead to give only PbF 2 and PbCl 2 . Lead(II) ions are usually colorless in solution, and partially hydrolyze to form Pb(OH) and finally [Pb 4 (OH) 4 ] (in which the hydroxyl ions act as bridging ligands ), but are not reducing agents as tin(II) ions are. Techniques for identifying
4488-626: The Egyptians had used lead for sinkers in fishing nets , glazes , glasses , enamels , ornaments . Various civilizations of the Fertile Crescent used lead as a writing material , as coins , and as a construction material . Lead was used by the ancient Chinese as a stimulant , as currency , as contraceptive , and in chopsticks . The Indus Valley civilization and the Mesoamericans used it for making amulets ; and
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#17327983105124576-475: The Romans obtained lead mostly as a by-product of silver smelting. Lead mining occurred in central Europe , Britain , Balkans , Greece , Anatolia , Hispania , the latter accounting for 40% of world production. Lead tablets were commonly used as a material for letters. Lead coffins, cast in flat sand forms and with interchangeable motifs to suit the faith of the deceased, were used in ancient Judea . Lead
4664-607: The atmosphere; 100 mg/kg in soil; 4 mg/kg in vegetation, 5 μg/L in fresh water and seawater. The modern English word lead is of Germanic origin; it comes from the Middle English leed and Old English lēad (with the macron above the "e" signifying that the vowel sound of that letter is long). The Old English word is derived from the hypothetical reconstructed Proto-Germanic * lauda- ('lead'). According to linguistic theory, this word bore descendants in multiple Germanic languages of exactly
4752-703: The building, and to direct the water to a suitable disposal site where it will not damage the foundations of the building. In the case of a flat roof, removal of water is essential to prevent water ingress and to prevent a build-up of excessive weight. Water from a pitched roof flows down into a valley gutter, a parapet gutter or an eaves gutter. An eaves gutter is also known as an eavestrough (especially in Canada ), spouting in New Zealand , rhone or rone ( Scotland ), eaves-shoot ( Ireland ) eaves channel, dripster , guttering , rainspouting or simply as
4840-489: The course of the Earth's history, have remained in the crust instead of sinking deeper into the Earth's interior. This accounts for lead's relatively high crustal abundance of 14 ppm; it is the 36th most abundant element in the crust. The main lead-bearing mineral is galena (PbS), which is mostly found with zinc ores. Most other lead minerals are related to galena in some way; boulangerite , Pb 5 Sb 4 S 11 ,
4928-419: The current age of the universe). Three of the stable isotopes are found in three of the four major decay chains : lead-206, lead-207, and lead-208 are the final decay products of uranium-238 , uranium-235 , and thorium-232 , respectively. These decay chains are called the uranium chain , the actinium chain , and the thorium chain . Their isotopic concentrations in a natural rock sample depends greatly on
5016-428: The diiodide . Many lead(II) pseudohalides are known, such as the cyanide, cyanate, and thiocyanate . Lead(II) forms an extensive variety of halide coordination complexes , such as [PbCl 4 ] , [PbCl 6 ] , and the [Pb 2 Cl 9 ] n chain anion. Lead(II) sulfate is insoluble in water, like the sulfates of other heavy divalent cations . Lead(II) nitrate and lead(II) acetate are very soluble, and this
5104-436: The disadvantages however ensured this was a short period: it was more bulky and fractured on impact. Cast iron gutters were introduced in the late 18th century as an alternative to lead. Cast iron enabled eaves gutters to be mass-produced: they were rigid and non-porous while lead could only be used as a liner within timber gutters. Installation was a single process and didn't require heat. They could be attached directly to
5192-525: The eastern and southern Africans used lead in wire drawing . Because silver was extensively used as a decorative material and an exchange medium, lead deposits came to be worked in Asia Minor from 3000 BC; later, lead deposits were developed in the Aegean and Laurion . These three regions collectively dominated production of mined lead until c. 1200 BC . Beginning c. 2000 BC,
5280-578: The element its chemical symbol Pb . The word * ɸloud-io- is thought to be the origin of Proto-Germanic * bliwa- (which also means 'lead'), from which stemmed the German Blei . The name of the chemical element is not related to the verb of the same spelling, which is derived from Proto-Germanic * laidijan- ('to lead'). Metallic lead beads dating back to 7000–6500 BC have been found in Asia Minor and may represent
5368-702: The eleventh out of the twelve. Gutter guards (also called gutter covers , gutter protection or leaf guards ) are primarily aimed at preventing damage caused from clogged gutters and reducing the need for regular gutter cleaning. They are a common add-on or included as an option for custom-built homes . Brush gutter guards resemble pipe cleaners and are easy to install. They prevent large debris from clogging gutters, but are less effective at reducing smaller debris. Foam gutter guards are also easy to install. They fit into gutters, so they prevent large objects from obstructing waterflow, but they do not prevent algae and plant growth. A negative feature of foam type filters
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#17327983105125456-402: The fabric of the building by channelling the rainwater away from the exterior of the walls and their foundations. Water running down the walls causes dampness in the affected rooms and provides a favourable environment for growth of mould , and wet rot in timber. A rain gutter may be a: A roof must be designed with a suitable fall to allow the rainwater to discharge. The water drains into
5544-404: The fascia board. Cast iron gutters are still specified for restoration work in conservation areas , but are usually replaced with cast aluminium made to the same profile. Extruded aluminium gutters can be made to a variety of profiles from a roll of aluminium sheet on site in lengths of up to 30 m. They feature internal brackets at 400 mm spacing. In UK domestic architecture, guttering
5632-413: The first example of metal smelting . At that time, lead had few (if any) applications due to its softness and dull appearance. The major reason for the spread of lead production was its association with silver, which may be obtained by burning galena (a common lead mineral). The Ancient Egyptians were the first to use lead minerals in cosmetics, an application that spread to Ancient Greece and beyond;
5720-430: The group. Lead dihalides are well-characterized; this includes the diastatide and mixed halides, such as PbFCl. The relative insolubility of the latter forms a useful basis for the gravimetric determination of fluorine. The difluoride was the first solid ionically conducting compound to be discovered (in 1834, by Michael Faraday ). The other dihalides decompose on exposure to ultraviolet or visible light, especially
5808-449: The inert pair effect increases the separation between its s- and p-orbitals, and the gap cannot be overcome by the energy that would be released by extra bonds following hybridization. Rather than having a diamond cubic structure, lead forms metallic bonds in which only the p-electrons are delocalized and shared between the Pb ions. Lead consequently has a face-centered cubic structure like
5896-532: The introduction of ring seals. A British Standard was launched for soil systems, local authorities started to specify PVC systems. By 1970 plastic rainwater systems accounted for over 60% of new installations. A European Standard EN607 has existed since 2004. It is easy to install, economical, lightweight requires minimum maintenance and has a life expectancy of 50 years. The material has a disadvantageous coefficient of thermal expansion 0.06 mm/m°C, so design allowances have to be made. A 4-metre gutter, enduring
5984-447: The late 19th century AD. A lead atom has 82 electrons , arranged in an electron configuration of [ Xe ]4f 5d 6s 6p . The sum of lead's first and second ionization energies —the total energy required to remove the two 6p electrons—is close to that of tin , lead's upper neighbor in the carbon group . This is unusual; ionization energies generally fall going down a group, as an element's outer electrons become more distant from
6072-560: The latter being stable only above around 488 °C. Litharge is the most commonly used inorganic compound of lead. There is no lead(II) hydroxide; increasing the pH of solutions of lead(II) salts leads to hydrolysis and condensation. Lead commonly reacts with heavier chalcogens. Lead sulfide is a semiconductor , a photoconductor , and an extremely sensitive infrared radiation detector . The other two chalcogenides, lead selenide and lead telluride , are likewise photoconducting. They are unusual in that their color becomes lighter going down
6160-441: The latter is not; this allows for lead–lead dating . As uranium decays into lead, their relative amounts change; this is the basis for uranium–lead dating . Lead-207 exhibits nuclear magnetic resonance , a property that has been used to study its compounds in solution and solid state, including in the human body. Apart from the stable isotopes, which make up almost all lead that exists naturally, there are trace quantities of
6248-418: The most protection from small and large debris. PVC type gutter guards are a less costly option, however, they tend to quickly become brittle due to sun exposure. Lead Lead (pronounced "led") is a chemical element ; it has symbol Pb (from Latin plumbum ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable , and also has
6336-539: The neutrons are arranged in complete shells in the atomic nucleus, and it becomes harder to energetically accommodate more of them. When the neutron flux subsides, these nuclei beta decay into stable isotopes of osmium , iridium , platinum . Lead is classified as a chalcophile under the Goldschmidt classification , meaning it is generally found combined with sulfur. It rarely occurs in its native , metallic form. Many lead minerals are relatively light and, over
6424-418: The preparation of sweeteners and preservatives added to wine and food. The lead conferred an agreeable taste due to the formation of "sugar of lead" ( lead(II) acetate ), whereas copper vessels imparted a bitter flavor through verdigris formation. This metal was by far the most used material in classical antiquity, and it is appropriate to refer to the (Roman) Lead Age. Lead was to the Romans what plastic
6512-414: The presence of the Pb ion in water generally rely on the precipitation of lead(II) chloride using dilute hydrochloric acid. As the chloride salt is sparingly soluble in water, in very dilute solutions the precipitation of lead(II) sulfide is instead achieved by bubbling hydrogen sulfide through the solution. Lead monoxide exists in two polymorphs , litharge α-PbO (red) and massicot β-PbO (yellow),
6600-422: The presence of these three parent uranium and thorium isotopes. For example, the relative abundance of lead-208 can range from 52% in normal samples to 90% in thorium ores; for this reason, the standard atomic weight of lead is given to only one decimal place. As time passes, the ratio of lead-206 and lead-207 to lead-204 increases, since the former two are supplemented by radioactive decay of heavier elements while
6688-432: The r-process (r is for "rapid"), captures happen faster than nuclei can decay. This occurs in environments with a high neutron density, such as a supernova or the merger of two neutron stars . The neutron flux involved may be on the order of 10 neutrons per square centimeter per second. The r-process does not form as much lead as the s-process. It tends to stop once neutron-rich nuclei reach 126 neutrons. At this point,
6776-541: The resulting chloride layer diminishes the reactivity of the elements. Molten lead reacts with the chalcogens to give lead(II) chalcogenides. Lead metal resists sulfuric and phosphoric acid but not hydrochloric or nitric acid ; the outcome depends on insolubility and subsequent passivation of the product salt. Organic acids, such as acetic acid , dissolve lead in the presence of oxygen. Concentrated alkalis dissolve lead and form plumbites . Lead shows two main oxidation states: +4 and +2. The tetravalent state
6864-748: The roof is calculated (metres) and this is multiplied by rainfall (litres/sec/metres²) which is assumed to be 0.0208. This gives a required discharge outfall capacity. (litres/sec) . Rainfall intensity, the amount of water likely to generated in a two-minute rainstorm is more important than average rainfall, the British Standards Institute notes that an indicative storm in Essex, (annual rainfall 500 mm per annum) delivers 0.022 L/s/m²- while one in Cumbria (annual rainfall 1800 mm per annum) delivers 0.014 L/s/m². Eaves gutters can be made from
6952-484: The roof to flow through, while reducing passage of roof debris into the gutter. Clogged gutters can also cause water ingress into the building as the water backs up. Clogged gutters can also lead to stagnant water build up which in some climates allows mosquitoes to breed. The Romans brought rainwater systems to Britain. The technology was subsequently lost, but was re-introduced by the Normans. The White Tower , at
7040-518: The same meaning. There is no consensus on the origin of the Proto-Germanic * lauda- . One hypothesis suggests it is derived from Proto-Indo-European * lAudh- ('lead'; capitalization of the vowel is equivalent to the macron). Another hypothesis suggests it is borrowed from Proto-Celtic * ɸloud-io- ('lead'). This word is related to the Latin plumbum , which gave
7128-491: The similarly sized divalent metals calcium and strontium . Pure lead has a bright, shiny gray appearance with a hint of blue. It tarnishes on contact with moist air and takes on a dull appearance, the hue of which depends on the prevailing conditions. Characteristic properties of lead include high density , malleability, ductility, and high resistance to corrosion due to passivation . Lead's close-packed face-centered cubic structure and high atomic weight result in
7216-588: The simplest organic compound , methane , is plumbane . Plumbane may be obtained in a reaction between metallic lead and atomic hydrogen. Two simple derivatives, tetramethyllead and tetraethyllead , are the best-known organolead compounds. These compounds are relatively stable: tetraethyllead only starts to decompose if heated or if exposed to sunlight or ultraviolet light. With sodium metal, lead readily forms an equimolar alloy that reacts with alkyl halides to form organometallic compounds such as tetraethyllead. The oxidizing nature of many organolead compounds
7304-456: The space between columns of printed text Gutter, in bookbinding , page edges joined to the spine Gutter (philately) , the space between panes of postage stamps that creates configurations of "gutter pairs" or "gutter blocks" Other uses [ edit ] Gutters, in bowling and table shuffleboard , the trough hazards on either side of the playing lane into which the bowling ball or shuffleboard puck may fall "Gutter" (song) ,
7392-557: The specifications of the structure and are generally installed by experienced tradesman. Seamless gutter is .027" thick and if properly installed will last 30+ years. In commercial and domestic architecture, guttering is often made from zinc coated mild steel for corrosion resistance. Metal gutters with bead stiffened fronts is governed in the UK by BS EN612:2005. Aluminium gutters offer good corrosion resistance, are lightweight, and are easy to install. Additionally, aluminium gutters come in
7480-536: The trickling of the rain". In Saxon times, the thanes erected buildings with large overhanging roofs to throw the water clear of the walls in the same way that occurs in thatched cottages . The cathedral builder used lead parapet gutters , with elaborate gargoyles for the same purpose. With the dissolution of the monasteries - those buildings were recycled and there was plenty of lead that could be used for secular building. The yeoman would use wooden gutters or lead lined wooden gutters. When The Crystal Palace
7568-403: The very rare cluster decay of radium-223, one of the daughter products of natural uranium-235, and the decay chain of neptunium-237, traces of which are produced by neutron capture in uranium ores. Lead-213 also occurs in the decay chain of neptunium-237. Lead-210 is particularly useful for helping to identify the ages of samples by measuring its ratio to lead-206 (both isotopes are present in
7656-434: Was designed in 1851 by Joseph Paxton with its innovative ridge-and-furrow roof, the rafters that spanned the space between the roof girders of the glass roof also served as the gutters. The wooden Paxton gutters had a deep semi-circular channel to remove the rainwater and grooves at the side to handle the condensation. They were under trussed with an iron plate and had preformed notches for the glazing bars: they drained into
7744-534: Was used to make sling bullets from the 5th century BC. In Roman times, lead sling bullets were amply used, and were effective at a distance of between 100 and 150 meters. The Balearic slingers , used as mercenaries in Carthaginian and Roman armies, were famous for their shooting distance and accuracy. Lead was used for making water pipes in the Roman Empire ; the Latin word for the metal, plumbum ,
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