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110-518: The East African Rift ( EAR ) or East African Rift System ( EARS ) is an active continental rift zone in East Africa . The EAR began developing around the onset of the Miocene , 22–25 million years ago. It was formerly considered to be part of a larger Great Rift Valley that extended north to Asia Minor . A narrow zone, the rift is a developing divergent tectonic plate boundary where

220-434: A divergent boundary between two tectonic plates . Failed rifts are the result of continental rifting that failed to continue to the point of break-up. Typically the transition from rifting to spreading develops at a triple junction where three converging rifts meet over a hotspot . Two of these evolve to the point of seafloor spreading, while the third ultimately fails, becoming an aulacogen . Most rifts consist of

330-549: A fissile material . The principal sources of rare-earth elements are the minerals bastnäsite ( RCO 3 F , where R is a mixture of rare-earth elements), monazite ( XPO 4 , where X is a mixture of rare-earth elements and sometimes thorium), and loparite ( (Ce,Na,Ca)(Ti,Nb)O 3 ), and the lateritic ion-adsorption clays . Despite their high relative abundance, rare-earth minerals are more difficult to mine and extract than equivalent sources of transition metals (due in part to their similar chemical properties), making

440-449: A lacustrine environment or in a restricted marine environment, although not all rifts contain such sequences. Reservoir rocks may be developed in pre-rift, syn-rift and post-rift sequences. Effective regional seals may be present within the post-rift sequence if mudstones or evaporites are deposited. Just over half of estimated oil reserves are found associated with rifts containing marine syn-rift and post-rift sequences, just under

550-464: A 10-million-year-old ape called Chororapithecus abyssinicus , found in the Afar rift in eastern Ethiopia, and Nakalipithecus nakayamai , which is also 10 million years old. 3°00′S 35°30′E  /  3.0°S 35.5°E  / -3.0; 35.5 Rift Major rifts occur along the central axis of most mid-ocean ridges , where new oceanic crust and lithosphere is created along

660-609: A CO 2 -rich primary magma, by fractional crystallization of an alkaline primary magma, or by separation of a CO 2 -rich immiscible liquid from. These liquids are most commonly forming in association with very deep Precambrian cratons , like the ones found in Africa and the Canadian Shield. Ferrocarbonatites are the most common type of carbonatite to be enriched in REE, and are often emplaced as late-stage, brecciated pipes at

770-532: A component of magnets in hybrid car motors." The global demand for rare-earth elements (REEs) is expected to increase more than fivefold by 2030. The REE geochemical classification is usually done on the basis of their atomic weight . One of the most common classifications divides REE into 3 groups: light rare earths (LREE - from 57 La to 60 Nd), intermediate (MREE - from 62 Sm to 67 Ho) and heavy (HREE - from 68 Er to 71 Lu). REE usually appear as trivalent ions, except for Ce and Eu which can take

880-665: A few percent of yttrium). Uranium ores from Ontario have occasionally yielded yttrium as a byproduct. Well-known minerals containing cerium, and other LREE, include bastnäsite , monazite , allanite , loparite , ancylite , parisite , lanthanite , chevkinite, cerite , stillwellite , britholite, fluocerite , and cerianite. Monazite (marine sands from Brazil , India , or Australia ; rock from South Africa ), bastnäsite (from Mountain Pass rare earth mine , or several localities in China), and loparite ( Kola Peninsula , Russia ) have been

990-403: A kind of orogeneses in extensional settings, which is referred as to rifting orogeny. Once rifting ceases, the mantle beneath the rift cools and this is accompanied by a broad area of post-rift subsidence. The amount of subsidence is directly related to the amount of thinning during the rifting phase calculated as the beta factor (initial crustal thickness divided by final crustal thickness), but

1100-544: A maximum number of 25 was estimated. The use of X-ray spectra (obtained by X-ray crystallography ) by Henry Gwyn Jeffreys Moseley made it possible to assign atomic numbers to the elements. Moseley found that the exact number of lanthanides had to be 15, but that element 61 had not yet been discovered. (This is promethium, a radioactive element whose most stable isotope has a half-life of just 18 years.) Using these facts about atomic numbers from X-ray crystallography, Moseley also showed that hafnium (element 72) would not be

1210-432: A melt phase if one is present. REE are chemically very similar and have always been difficult to separate, but the gradual decrease in ionic radius from light REE (LREE) to heavy REE (HREE), called the lanthanide contraction , can produce a broad separation between light and heavy REE. The larger ionic radii of LREE make them generally more incompatible than HREE in rock-forming minerals, and will partition more strongly into

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1320-404: A melt phase, while HREE may prefer to remain in the crystalline residue, particularly if it contains HREE-compatible minerals like garnet . The result is that all magma formed from partial melting will always have greater concentrations of LREE than HREE, and individual minerals may be dominated by either HREE or LREE, depending on which range of ionic radii best fits the crystal lattice. Among

1430-438: A mid-oceanic ridge and a set of conjugate margins separated by an oceanic basin. Rifting may be active, and controlled by mantle convection . It may also be passive, and driven by far-field tectonic forces that stretch the lithosphere. Margin architecture develops due to spatial and temporal relationships between extensional deformation phases. Margin segmentation eventually leads to the formation of rift domains with variations of

1540-648: A number of active and dormant volcanoes, among them: Mount Kilimanjaro , Mount Kenya , Mount Longonot , Menengai Crater, Mount Karisimbi , Mount Nyiragongo , Mount Meru and Mount Elgon , as well as the Crater Highlands in Tanzania. Although most of these mountains lie outside of the rift valley, the EAR created them. Notable active examples of EAR volcanism include Erta Ale , Dalaffilla (also called Gabuli, Alu-Dalafilla), and Ol Doinyo Lengai . Erta Ale

1650-400: A pre-Cambrian weakness in the crust, a suture zone of multiple cratons , displacement along large boundary faults, and the development of deep asymmetric basins. The second stage of rifting was characterized by the deactivation of large boundary faults, the development of internal fault segments, and the concentration of magmatic activity towards the rifts. Today, the narrow rift segments of

1760-407: A quarter in rifts with a non-marine syn-rift and post-rift, and an eighth in non-marine syn-rift with a marine post-rift. Rare-earth element The rare-earth elements ( REE ), also called the rare-earth metals or rare earths , and sometimes the lanthanides or lanthanoids (although scandium and yttrium , which do not belong to this series, are usually included as rare earths), are

1870-456: A rare-earth element. Moseley was killed in World War I in 1915, years before hafnium was discovered. Hence, the claim of Georges Urbain that he had discovered element 72 was untrue. Hafnium is an element that lies in the periodic table immediately below zirconium , and hafnium and zirconium have very similar chemical and physical properties. During the 1940s, Frank Spedding and others in

1980-404: A separate group of rare-earth elements (the terbium group), or europium was included in the cerium group, and gadolinium and terbium were included in the yttrium group. In the latter case, the f-block elements are split into half: the first half (La–Eu) form the cerium group, and the second half (Gd–Yb) together with group 3 (Sc, Y, Lu) form the yttrium group. The reason for this division arose from

2090-557: A series of separate segments that together form the linear zone characteristic of rifts. The individual rift segments have a dominantly half-graben geometry, controlled by a single basin-bounding fault. Segment lengths vary between rifts, depending on the elastic thickness of the lithosphere. Areas of thick colder lithosphere, such as the Baikal Rift have segment lengths in excess of 80 km, while in areas of warmer thin lithosphere, segment lengths may be less than 30 km. Along

2200-494: A set of 17 nearly indistinguishable lustrous silvery-white soft heavy metals . Compounds containing rare earths have diverse applications in electrical and electronic components, lasers, glass, magnetic materials, and industrial processes. Scandium and yttrium are considered rare-earth elements because they tend to occur in the same ore deposits as the lanthanides and exhibit similar chemical properties, but have different electrical and magnetic properties . The term 'rare-earth'

2310-420: A similar effect. In sedimentary rocks, rare-earth elements in clastic sediments are a representation of provenance. The rare-earth element concentrations are not typically affected by sea and river waters, as rare-earth elements are insoluble and thus have very low concentrations in these fluids. As a result, when sediment is transported, rare-earth element concentrations are unaffected by the fluid and instead

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2420-717: A simple relay ramp at the overlap between two major faults of the same polarity, to zones of high structural complexity, particularly where the segments have opposite polarity. Accommodation zones may be located where older crustal structures intersect the rift axis. In the Gulf of Suez rift, the Zaafarana accommodation zone is located where a shear zone in the Arabian-Nubian Shield meets the rift. Rift flanks or shoulders are elevated areas around rifts. Rift shoulders are typically about 70 km wide. Contrary to what

2530-524: A suite of Ethiopian lavas suggest multiple plume sources: at least one of deep mantle origin, and one from within the subcontinental lithosphere. In accordance, a 2014 study compares the geochemical signature of rare earth isotopes from xenoliths and lava samples collected in the EAR. The results corroborate the coexistence of a superplume "common to the entire rift" with another mantle material source being either of subcontinental type or of mid-ocean ridge type. The geophysical method of seismic tomography

2640-462: A valence of 3 and form sesquioxides (cerium forms CeO 2 ). Five different crystal structures are known, depending on the element and the temperature. The X-phase and the H-phase are only stable above 2000 K. At lower temperatures, there are the hexagonal A-phase, the monoclinic B-phase, and the cubic C-phase, which is the stable form at room temperature for most of the elements. The C-phase

2750-604: Is a misnomer because they are not actually scarce, although historically it took a long time to isolate these elements. These metals tarnish slowly in air at room temperature and react slowly with cold water to form hydroxides, liberating hydrogen. They react with steam to form oxides and ignite spontaneously at a temperature of 400 °C (752 °F). These elements and their compounds have no biological function other than in several specialized enzymes, such as in lanthanide-dependent methanol dehydrogenases in bacteria. The water-soluble compounds are mildly to moderately toxic, but

2860-789: Is a basaltic shield volcano in the Afar Region of northeastern Ethiopia, active continuously since at least 1967, with a summit lava lake documented since at least 1906. The 2008 eruption of Dalafilla, its only documented activity since the start of the Holocene , is the largest recorded eruption in Ethiopian history. Ol Doinyo Lengai is currently the only active natrocarbonatite volcano on Earth. Its magma contains almost no silica; typical lava flows have viscosities of less than 100 Pa⋅s, comparable to olive oil at 26 °C (79 °F). EAR-related volcanic structures with dated activity since

2970-447: Is a suitable tool to investigate Earth's subsurface structures deeper than the crust. It is an inverse problem technique that models which are the velocities of the inner Earth that reproduce the seismographic data recorded all around the world. Recent improvements of tomographic Earth models of P wave and S wave velocities suggest that a superplume upwelling from the lower mantle at the northeastern EAR feeds plumes of smaller scale into

3080-402: Is also affected by the degree to which the rift basin is filled at each stage, due to the greater density of sediments in contrast to water. The simple 'McKenzie model' of rifting, which considers the rifting stage to be instantaneous, provides a good first order estimate of the amount of crustal thinning from observations of the amount of post-rift subsidence. This has generally been replaced by

3190-465: Is called the bixbyite structure, as it occurs in a mineral of that name ( (Mn,Fe) 2 O 3 ). As seen in the chart, rare-earth elements are found on Earth at similar concentrations to many common transition metals. The most abundant rare-earth element is cerium , which is actually the 25th most abundant element in Earth's crust , having 68 parts per million (about as common as copper). The exception

3300-852: Is caused by the configuration of mechanically weaker and stronger lithospheric regions in the EARS. Many of the African Great Lakes lie within the Rift Valley. A series of distinct rift basins, the East African Rift System extends over thousands of kilometers. North of the Afar triple junction, the rift follows two paths: west to the Red Sea Rift and east to the Aden Ridge in the Gulf of Aden . Southward from

3410-577: Is generally cool and strong. Many cratons are found throughout the EAR, such as the Tanzania and Kaapvaal cratons . The cratons are thick, and have survived for billions of years with little tectonic activity. They are characterized by greenstone belts , tonalites , and other high-grade metamorphic lithologies. The cratons are of significant importance in terms of mineral resources , with major deposits of gold, antimony, iron, chromium and nickel. A large volume of continental flood basalts erupted during

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3520-611: Is high, weathering forms a thick argillized regolith, this process is called supergene enrichment and produces laterite deposits; heavy rare-earth elements are incorporated into the residual clay by absorption. This kind of deposit is only mined for REE in Southern China, where the majority of global heavy rare-earth element production occurs. REE-laterites do form elsewhere, including over the carbonatite at Mount Weld in Australia. REE may also be extracted from placer deposits if

3630-445: Is possible to observe the serial trend of the REE by reporting their normalized concentrations against the atomic number. The trends that are observed in "spider" diagrams are typically referred to as "patterns", which may be diagnostic of petrological processes that have affected the material of interest. According to the general shape of the patterns or thanks to the presence (or absence) of so-called "anomalies", information regarding

3740-443: Is provided here. Some of the rare-earth elements are named after the scientists who discovered them, or elucidated their elemental properties, and some after the geographical locations where discovered. A mnemonic for the names of the sixth-row elements in order is "Lately college parties never produce sexy European girls that drink heavily even though you look". Rare earths were mainly discovered as components of minerals. Ytterbium

3850-438: Is spread thin across trace impurities, so to obtain rare earths at usable purity requires processing enormous amounts of raw ore at great expense, thus the name "rare" earths. Because of their geochemical properties, rare-earth elements are typically dispersed and not often found concentrated in rare-earth minerals . Consequently, economically exploitable ore deposits are sparse. The first rare-earth mineral discovered (1787)

3960-443: Is synthetically produced in nuclear reactors. Due to their chemical similarity, the concentrations of rare earths in rocks are only slowly changed by geochemical processes, making their proportions useful for geochronology and dating fossils. Rare-earth elements occur in nature in combination with phosphate ( monazite ), carbonate - fluoride ( bastnäsite ), and oxygen anions. In their oxides, most rare-earth elements only have

4070-517: Is the highly unstable and radioactive promethium "rare earth" is quite scarce. The longest-lived isotope of promethium has a half-life of 17.7 years, so the element exists in nature in only negligible amounts (approximately 572 g in the entire Earth's crust). Promethium is one of the two elements that do not have stable (non-radioactive) isotopes and are followed by (i.e. with higher atomic number) stable elements (the other being technetium ). The rare-earth elements are often found together. During

4180-683: The Afar triple junction , the EAR consists of two main branches. The Eastern Rift Valley (also known as Gregory Rift ) includes the Main Ethiopian Rift , runs southward from the Afar triple junction, and continues south as the Kenyan Rift Valley, then transects Congo DR , Uganda , Rwanda , Burundi , Zambia , Tanzania , Malawi and Mozambique . The Western Rift Valley includes the Albertine Rift , and farther south,

4290-742: The African plate is in the process of splitting into two tectonic plates, called the Somali plate and the Nubian plate , at a rate of 6–7 mm (0.24–0.28 in) per year. The rift system consists of three microplates, the Victoria microplate to the north, and the Rovuma and Lwandle microplates to the south. The Victoria microplate is rotating anti-clockwise with respect to the African plate. Its rotation

4400-556: The Ethiopian Highlands and the Kenya Highlands are hotspots of higher rainfall amid the semi-arid to arid lowlands of East Africa. Lakes which form within the rift, including Lake Victoria , have a large effect on regional climate. They are a source of water vapour, and also lead to the formation of lake breeze systems , which affect weather across large areas of East Africa. The east to west river valleys within

4510-473: The Moho topography, including proximal domain with fault-rotated crustal blocks, necking zone with thinning of crustal basement , distal domain with deep sag basins, ocean-continent transition and oceanic domain. Deformation and magmatism interact during rift evolution. Magma-rich and magma-poor rifted margins may be formed. Magma-rich margins include major volcanic features. Globally, volcanic margins represent

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4620-563: The Oddo–Harkins rule : even-numbered REE at abundances of about 5% each, and odd-numbered REE at abundances of about 1% each. Similar compositions are found in xenotime or gadolinite. Well-known minerals containing yttrium, and other HREE, include gadolinite, xenotime, samarskite , euxenite , fergusonite , yttrotantalite, yttrotungstite, yttrofluorite (a variety of fluorite ), thalenite, and yttrialite . Small amounts occur in zircon , which derives its typical yellow fluorescence from some of

4730-587: The Oligocene , with the majority of the volcanism coinciding with the opening of the Red Sea and the Gulf of Aden approximately 30 Ma. The composition of the volcanics are a continuum of ultra-alkaline to tholeiitic and felsic rocks. It has been suggested that the diversity of the compositions could be partially explained by different mantle source regions. The EAR also cuts through old sedimentary rocks deposited in ancient basins. The East African Rift Zone includes

4840-523: The lithosphere in saturated areas, making the thinning lithosphere behave like a mid-ocean ridge . According to marine geologist Kathleen Crane , the rift could eventually cause eastern Africa to separate from the mainland, although this potential event could take tens of millions of years. Studies that contribute to the broader understanding on the evolution of rifts can be grouped into the techniques of isotope geochemistry, seismic tomography and geodynamical modeling. The varying geochemical signatures of

4950-486: The upper mantle (200 to 600 km depth). This melt becomes enriched in incompatible elements, like the rare-earth elements, by leaching them out of the crystalline residue. The resultant magma rises as a diapir , or diatreme , along pre-existing fractures, and can be emplaced deep in the crust , or erupted at the surface. Typical REE enriched deposits types forming in rift settings are carbonatites, and A- and M-Type granitoids. Near subduction zones, partial melting of

5060-479: The upper mantle . Parallel to geological and geophysical measures (e.g. isotope ratios and seismic velocities) it is constructive to test hypotheses on computer based geodynamical models. A 3D numerical geodynamic model of the plume-crust coupling was capable of reproducing the lateral asymmetry of the EAR around the Tanzania craton . Numerical modeling of plume-induced continental break-up shows two distinct stages, crustal rifting followed by lithospheric breakup, and

5170-428: The "heavy" group from 6.965 (ytterbium) to 9.32 (thulium), as well as including yttrium at 4.47. Europium has a density of 5.24. Rare-earth elements, except scandium , are heavier than iron and thus are produced by supernova nucleosynthesis or by the s-process in asymptotic giant branch stars. In nature, spontaneous fission of uranium-238 produces trace amounts of radioactive promethium , but most promethium

5280-659: The 'flexural cantilever model', which takes into account the geometry of the rift faults and the flexural isostasy of the upper part of the crust. Some rifts show a complex and prolonged history of rifting, with several distinct phases. The North Sea rift shows evidence of several separate rift phases from the Permian through to the Earliest Cretaceous , a period of over 100 million years. Rifting may lead to continental breakup and formation of oceanic basins. Successful rifting leads to seafloor spreading along

5390-568: The 4 f orbital which acts against the electrons of the 6 s and 5 d orbitals. The lanthanide contraction has a direct effect on the geochemistry of the lanthanides, which show a different behaviour depending on the systems and processes in which they are involved. The effect of the lanthanide contraction can be observed in the REE behaviour both in a CHARAC-type geochemical system (CHArge-and-RAdius-Controlled ) where elements with similar charge and radius should show coherent geochemical behaviour, and in non-CHARAC systems, such as aqueous solutions, where

5500-648: The EAR. Others proposed an African superplume causing mantle deformation. Although the effects of deep-rooted mantle plumes are an important hypothesis, their location and dynamics are poorly understood, and a matter of active research. The question is still debated. The most recent and accepted view is the theory put forth in 2009: that magmatism and plate tectonics have a feedback with one another, controlled by oblique rifting conditions. According to this theory, lithospheric thinning generates volcanic activity, further increasing magmatic processes such as intrusions and numerous small plumes. These processes further thin

5610-539: The East African Rift system form zones of localized strain. These rifts are the result of the actions of numerous normal faults which are typical of all tectonic rift zones. As aforementioned, voluminous magmatism and continental flood basalts characterize some of the rift segments, while other segments, such as the Western branch, have only very small volumes of volcanic rock. The African continental crust

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5720-506: The LREE. This has economic consequences: large ore bodies of LREE are known around the world and are being exploited. Ore bodies for HREE are more rare, smaller, and less concentrated. Most of the current supply of HREE originates in the "ion-absorption clay" ores of Southern China. Some versions provide concentrates containing about 65% yttrium oxide, with the HREE being present in ratios reflecting

5830-609: The Somali Jet) in the western Indian Ocean . The Somali Jet supplies water vapour for the high rainfall during the Indian Monsoon and is responsible for roughly half the global cross-equatorial atmospheric mass flux in the lower-branch of Hadley Circulation . The Rift Valley in East Africa has been a rich source of hominid fossils that allow the study of human evolution. The rapidly eroding highlands quickly filled

5940-530: The United States (during the Manhattan Project ) developed chemical ion-exchange procedures for separating and purifying rare-earth elements. This method was first applied to the actinides for separating plutonium-239 and neptunium from uranium , thorium , actinium , and the other actinides in the materials produced in nuclear reactors . Plutonium-239 was very desirable because it is

6050-449: The accompanying HREE. The zirconium mineral eudialyte , such as is found in southern Greenland , contains small but potentially useful amounts of yttrium. Of the above yttrium minerals, most played a part in providing research quantities of lanthanides during the discovery days. Xenotime is occasionally recovered as a byproduct of heavy-sand processing, but is not as abundant as the similarly recovered monazite (which typically contains

6160-500: The anhydrous rare-earth phosphates, it is the tetragonal mineral xenotime that incorporates yttrium and the HREE, whereas the monoclinic monazite phase incorporates cerium and the LREE preferentially. The smaller size of the HREE allows greater solid solubility in the rock-forming minerals that make up Earth's mantle, and thus yttrium and the HREE show less enrichment in Earth's crust relative to chondritic abundance than does cerium and

6270-452: The axis of the rift the position, and in some cases the polarity (the dip direction), of the main rift bounding fault changes from segment to segment. Segment boundaries often have a more complex structure and generally cross the rift axis at a high angle. These segment boundary zones accommodate the differences in fault displacement between the segments and are therefore known as accommodation zones. Accommodation zones take various forms, from

6380-871: The core of igneous complexes; they consist of fine-grained calcite and hematite, sometimes with significant concentrations of ankerite and minor concentrations of siderite. Large carbonatite deposits enriched in rare-earth elements include Mount Weld in Australia, Thor Lake in Canada, Zandkopsdrift in South Africa, and Mountain Pass in the USA. Peralkaline granites (A-Type granitoids) have very high concentrations of alkaline elements and very low concentrations of phosphorus; they are deposited at moderate depths in extensional zones, often as igneous ring complexes, or as pipes, massive bodies, and lenses. These fluids have very low viscosities and high element mobility, which allows for

6490-408: The crude yttria and found the same substances that Mosander obtained, but Berlin named (1860) the substance giving pink salts erbium , and Delafontaine named the substance with the yellow peroxide terbium . This confusion led to several false claims of new elements, such as the mosandrium of J. Lawrence Smith , or the philippium and decipium of Delafontaine. Due to the difficulty in separating

6600-740: The crystallization of large grains, despite a relatively short crystallization time upon emplacement; their large grain size is why these deposits are commonly referred to as pegmatites. Economically viable pegmatites are divided into Lithium-Cesium-Tantalum (LCT) and Niobium-Yttrium-Fluorine (NYF) types; NYF types are enriched in rare-earth minerals. Examples of rare-earth pegmatite deposits include Strange Lake in Canada and Khaladean-Buregtey in Mongolia. Nepheline syenite (M-Type granitoids) deposits are 90% feldspar and feldspathoid minerals. They are deposited in small, circular massifs and contain high concentrations of rare-earth-bearing accessory minerals . For

6710-469: The development of isolated basins. In subaerial rifts, for example, drainage at the onset of rifting is generally internal, with no element of through drainage. As the rift evolves, some of the individual fault segments grow, eventually becoming linked together to form the larger bounding faults. Subsequent extension becomes concentrated on these faults. The longer faults and wider fault spacing leads to more continuous areas of fault-related subsidence along

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6820-413: The difference in solubility of rare-earth double sulfates with sodium and potassium. The sodium double sulfates of the cerium group are poorly soluble, those of the terbium group slightly, and those of the yttrium group are very soluble. Sometimes, the yttrium group was further split into the erbium group (dysprosium, holmium, erbium, and thulium) and the ytterbium group (ytterbium and lutetium), but today

6930-409: The electron structure is also an important parameter to consider as the lanthanide contraction affects the ionic potential . A direct consequence is that, during the formation of coordination bonds, the REE behaviour gradually changes along the series. Furthermore, the lanthanide contraction causes the ionic radius of Ho (0.901 Å) to be almost identical to that of Y (0.9 Å), justifying the inclusion of

7040-651: The element showing the anomaly and the predictable one based on the average of the normalized concentrations of the two elements in the previous and next position in the series, according to the equation: where [ REE i ] n {\displaystyle [{\text{REE}}_{i}]_{n}} is the normalized concentration of the element whose anomaly has to be calculated, [ REE i − 1 ] n {\displaystyle [{\text{REE}}_{i-1}]_{n}} and [ REE i + 1 ] n {\displaystyle [{\text{REE}}_{i+1}]_{n}}

7150-417: The existence of an unknown element. The fractional crystallization of the oxides then yielded europium in 1901. In 1839 the third source for rare earths became available. This is a mineral similar to gadolinite called uranotantalum (now called " samarskite ") an oxide of a mixture of elements such as yttrium, ytterbium, iron, uranium, thorium, calcium, niobium, and tantalum. This mineral from Miass in

7260-511: The following observations apply: anomalies in europium are dominated by the crystallization of feldspars . Hornblende , controls the enrichment of MREE compared to LREE and HREE. Depletion of LREE relative to HREE may be due to the crystallization of olivine , orthopyroxene , and clinopyroxene . On the other hand, the depletion of HREE relative to LREE may be due to the presence of garnet , as garnet preferentially incorporates HREE into its crystal structure. The presence of zircon may also cause

7370-433: The form of Ce and Eu depending on the redox conditions of the system. Consequentially, REE are characterized by a substantial identity in their chemical reactivity, which results in a serial behaviour during geochemical processes rather than being characteristic of a single element of the series. Sc, Y, and Lu can be electronically distinguished from the other rare earths because they do not have f valence electrons, whereas

7480-566: The fractionation of trace elements (including rare-earth elements) into the liquid phase (the melt/magma) into the solid phase (the mineral). If an element preferentially remains in the solid phase it is termed 'compatible', and if it preferentially partitions into the melt phase it is described as 'incompatible'. Each element has a different partition coefficient, and therefore fractionates into solid and liquid phases distinctly. These concepts are also applicable to metamorphic and sedimentary petrology. In igneous rocks, particularly in felsic melts,

7590-581: The gadolinite but failed to recognize other elements in the ore. After this discovery in 1794, a mineral from Bastnäs near Riddarhyttan , Sweden, which was believed to be an iron – tungsten mineral, was re-examined by Jöns Jacob Berzelius and Wilhelm Hisinger . In 1803 they obtained a white oxide and called it ceria . Martin Heinrich Klaproth independently discovered the same oxide and called it ochroia . It took another 30 years for researchers to determine that other elements were contained in

7700-448: The heavy rare-earth elements (HREE), and those that fall in between are typically referred to as the middle rare-earth elements (MREE). Commonly, rare-earth elements with atomic numbers 57 to 61 (lanthanum to promethium) are classified as light and those with atomic numbers 62 and greater are classified as heavy rare-earth elements. Increasing atomic numbers between light and heavy rare-earth elements and decreasing atomic radii throughout

7810-502: The insoluble ones are not. All isotopes of promethium are radioactive, and it does not occur naturally in the earth's crust, except for a trace amount generated by spontaneous fission of uranium-238 . They are often found in minerals with thorium , and less commonly uranium . Though rare-earth elements are technically relatively plentiful in the entire Earth's crust ( cerium being the 25th-most-abundant element at 68 parts per million, more abundant than copper ), in practice this

7920-470: The latter among the REE. The application of rare-earth elements to geology is important to understanding the petrological processes of igneous , sedimentary and metamorphic rock formation. In geochemistry , rare-earth elements can be used to infer the petrological mechanisms that have affected a rock due to the subtle atomic size differences between the elements, which causes preferential fractionation of some rare earths relative to others depending on

8030-418: The logarithm to the base 10 of the value. Commonly, the rare-earth elements are normalized to chondritic meteorites , as these are believed to be the closest representation of unfractionated Solar System material. However, other normalizing standards can be applied depending on the purpose of the study. Normalization to a standard reference value, especially of a material believed to be unfractionated, allows

8140-472: The main grouping is between the cerium and the yttrium groups. Today, the rare-earth elements are classified as light or heavy rare-earth elements, rather than in cerium and yttrium groups. The classification of rare-earth elements is inconsistent between authors. The most common distinction between rare-earth elements is made by atomic numbers ; those with low atomic numbers are referred to as light rare-earth elements (LREE), those with high atomic numbers are

8250-567: The majority of passive continental margins. Magma-starved rifted margins are affected by large-scale faulting and crustal hyperextension. As a consequence, upper mantle peridotites and gabbros are commonly exposed and serpentinized along extensional detachments at the seafloor. Many rifts are the sites of at least minor magmatic activity , particularly in the early stages of rifting. Alkali basalts and bimodal volcanism are common products of rift-related magmatism. Recent studies indicate that post-collisional granites in collisional orogens are

8360-522: The metals (and determining the separation is complete), the total number of false discoveries was dozens, with some putting the total number of discoveries at over a hundred. There were no further discoveries for 30 years, and the element didymium was listed in the periodic table of elements with a molecular mass of 138. In 1879, Delafontaine used the new physical process of optical flame spectroscopy and found several new spectral lines in didymia. Also in 1879, Paul Émile Lecoq de Boisbaudran isolated

8470-697: The most part, these deposits are small but important examples include Illimaussaq-Kvanefeld in Greenland, and Lovozera in Russia. Rare-earth elements can also be enriched in deposits by secondary alteration either by interactions with hydrothermal fluids or meteoric water or by erosion and transport of resistate REE-bearing minerals. Argillization of primary minerals enriches insoluble elements by leaching out silica and other soluble elements, recrystallizing feldspar into clay minerals such kaolinite, halloysite, and montmorillonite. In tropical regions where precipitation

8580-560: The new element samarium from the mineral samarskite . The samaria earth was further separated by Lecoq de Boisbaudran in 1886, and a similar result was obtained by Jean Charles Galissard de Marignac by direct isolation from samarskite. They named the element gadolinium after Johan Gadolin , and its oxide was named " gadolinia ". Further spectroscopic analysis between 1886 and 1901 of samaria, yttria, and samarskite by William Crookes , Lecoq de Boisbaudran and Eugène-Anatole Demarçay yielded several new spectral lines that indicated

8690-424: The normalized concentration, [ REE i ] sam {\displaystyle {[{\text{REE}}_{i}]_{\text{sam}}}} the analytical concentration of the element measured in the sample, and [ REE i ] ref {\displaystyle {[{\text{REE}}_{i}]_{\text{ref}}}} the concentration of the same element in the reference material. It

8800-427: The normalized concentrations of the respectively previous and next elements along the series. The rare-earth elements patterns observed in igneous rocks are primarily a function of the chemistry of the source where the rock came from, as well as the fractionation history the rock has undergone. Fractionation is in turn a function of the partition coefficients of each element. Partition coefficients are responsible for

8910-432: The observed abundances to be compared to the initial abundances of the element. Normalization also removes the pronounced 'zig-zag' pattern caused by the differences in abundance between even and odd atomic numbers . Normalization is carried out by dividing the analytical concentrations of each element of the series by the concentration of the same element in a given standard, according to the equation: where n indicates

9020-668: The onset of the Holocene include approximately 50 in Ethiopia, 17 in Kenya , and 9 in Tanzania . The EAR is the largest seismically active rift system on Earth today. The majority of earthquakes occur near the Afar Depression, with the largest typically occurring along or near major border faults. Seismic events in the past century are estimated to have reached a maximum moment magnitude of 7.0. The seismicity trends parallel to

9130-414: The others do, but the chemical behaviour is almost the same. A distinguishing factor in the geochemical behaviour of the REE is linked to the so-called " lanthanide contraction " which represents a higher-than-expected decrease in the atomic/ionic radius of the elements along the series. This is determined by the variation of the shielding effect towards the nuclear charge due to the progressive filling of

9240-446: The principal ores of cerium and the light lanthanides. Enriched deposits of rare-earth elements at the surface of the Earth, carbonatites and pegmatites , are related to alkaline plutonism , an uncommon kind of magmatism that occurs in tectonic settings where there is rifting or that are near subduction zones. In a rift setting, the alkaline magma is produced by very small degrees of partial melting (<1%) of garnet peridotite in

9350-440: The processes at work. The geochemical study of the REE is not carried out on absolute concentrations – as it is usually done with other chemical elements – but on normalized concentrations in order to observe their serial behaviour. In geochemistry, rare-earth elements are typically presented in normalized "spider" diagrams, in which concentration of rare-earth elements are normalized to a reference standard and are then expressed as

9460-404: The product of rifting magmatism at converged plate margins. The sedimentary rocks associated with continental rifts host important deposits of both minerals and hydrocarbons . SedEx mineral deposits are found mainly in continental rift settings. They form within post-rift sequences when hydrothermal fluids associated with magmatic activity are expelled at the seabed. Continental rifts are

9570-421: The rare-earth elements relatively expensive. Their industrial use was very limited until efficient separation techniques were developed, such as ion exchange , fractional crystallization, and liquid–liquid extraction during the late 1950s and early 1960s. Some ilmenite concentrates contain small amounts of scandium and other rare-earth elements, which could be analysed by X-ray fluorescence (XRF). Before

9680-432: The rift axis. Significant uplift of the rift shoulders develops at this stage, strongly influencing drainage and sedimentation in the rift basins. During the climax of lithospheric rifting, as the crust is thinned, the Earth's surface subsides and the Moho becomes correspondingly raised. At the same time, the mantle lithosphere becomes thinned, causing a rise of the top of the asthenosphere. This brings high heat flow from

9790-688: The rift system, including the Turkana Channel in northern Kenya and the Zambezi river valley, concentrate low-level easterly winds and accelerate them towards Central Africa . This leaves East Africa drier than it otherwise would be, and also supports the high rainfall in the Congo Basin rainforest . The formation of the east–west valleys could in turn be important for the aridification of East Africa over millions of years. The barrier presented by EARS concentrates monsoonal winds (known as

9900-448: The rift system, with a shallow focal depth of 12–15 km (7.5–9.3 mi) beneath the rift axis. Further away from the rift axis, focal depths can be below 30 km (19 mi). Focal mechanism solutions strike NE and frequently demonstrate normal dip-slip faulting, although left-lateral motion is also observed. The East African Rift system affects regional, continental and even global climate. Regions of higher elevation, including

10010-636: The seafloor, bit by bit, over tens of millions of years. One square patch of metal-rich mud 2.3 kilometers wide might contain enough rare earths to meet most of the global demand for a year, Japanese geologists report in Nature Geoscience ." "I believe that rare[-]earth resources undersea are much more promising than on-land resources," said Kato. "[C]oncentrations of rare earths were comparable to those found in clays mined in China. Some deposits contained twice as much heavy rare earths such as dysprosium,

10120-493: The sedimentary parent lithology contains REE-bearing, heavy resistate minerals. In 2011, Yasuhiro Kato, a geologist at the University of Tokyo who led a study of Pacific Ocean seabed mud, published results indicating the mud could hold rich concentrations of rare-earth minerals. The deposits, studied at 78 sites, came from "[h]ot plumes from hydrothermal vents pull[ing] these materials out of seawater and deposit[ing] them on

10230-419: The sequential accretion of the Earth, the dense rare-earth elements were incorporated into the deeper portions of the planet. Early differentiation of molten material largely incorporated the rare earths into mantle rocks. The high field strength and large ionic radii of rare earths make them incompatible with the crystal lattices of most rock-forming minerals, so REE will undergo strong partitioning into

10340-497: The series causes chemical variations. Europium is exempt of this classification as it has two valence states: Eu and Eu . Yttrium is grouped as heavy rare-earth element due to chemical similarities. The break between the two groups is sometimes put elsewhere, such as between elements 63 (europium) and 64 (gadolinium). The actual metallic densities of these two groups overlap, with the "light" group having densities from 6.145 (lanthanum) to 7.26 (promethium) or 7.52 (samarium) g/cc, and

10450-471: The sites of significant oil and gas accumulations, such as the Viking Graben and the Gulf of Suez Rift . Thirty percent of giant oil and gas fields are found within such a setting. In 1999 it was estimated that there were 200 billion barrels of recoverable oil reserves hosted in rifts. Source rocks are often developed within the sediments filling the active rift ( syn-rift ), forming either in

10560-401: The southern Ural Mountains was documented by Gustav Rose . The Russian chemist R. Harmann proposed that a new element he called " ilmenium " should be present in this mineral, but later, Christian Wilhelm Blomstrand , Galissard de Marignac, and Heinrich Rose found only tantalum and niobium ( columbium ) in it. The exact number of rare-earth elements that existed was highly unclear, and

10670-420: The southern half of its length that rises to 2,300 m (7,500 ft) above the sea floor. Its movement is concurrent with the EAR. Over time, many theories have tried to clarify the evolution of the East African Rift. In 1972 it was proposed that the EAR was not caused by tectonic activity, but rather by differences in crustal density. Since the 1990s, evidence has been found in favor of mantle plumes beneath

10780-766: The subducting plate within the asthenosphere (80 to 200 km depth) produces a volatile-rich magma (high concentrations of CO 2 and water), with high concentrations of alkaline elements, and high element mobility that the rare earths are strongly partitioned into. This melt may also rise along pre-existing fractures, and be emplaced in the crust above the subducting slab or erupted at the surface. REE-enriched deposits forming from these melts are typically S-Type granitoids. Alkaline magmas enriched with rare-earth elements include carbonatites, peralkaline granites (pegmatites), and nepheline syenite . Carbonatites crystallize from CO 2 -rich fluids, which can be produced by partial melting of hydrous-carbonated lherzolite to produce

10890-399: The system under examination and the occurring geochemical processes can be obtained. The anomalies represent enrichment (positive anomalies) or depletion (negative anomalies) of specific elements along the series and are graphically recognizable as positive or negative "peaks" along the REE patterns. The anomalies can be numerically quantified as the ratio between the normalized concentration of

11000-479: The time that ion exchange methods and elution were available, the separation of the rare earths was primarily achieved by repeated precipitation or crystallization . In those days, the first separation was into two main groups, the cerium earths (lanthanum, cerium, praseodymium, neodymium, and samarium) and the yttrium earths (scandium, yttrium, dysprosium, holmium, erbium, thulium, ytterbium, and lutetium). Europium, gadolinium, and terbium were either considered as

11110-484: The two ores ceria and yttria (the similarity of the rare-earth metals' chemical properties made their separation difficult). In 1839 Carl Gustav Mosander , an assistant of Berzelius, separated ceria by heating the nitrate and dissolving the product in nitric acid . He called the oxide of the soluble salt lanthana . It took him three more years to separate the lanthana further into didymia and pure lanthana. Didymia, although not further separable by Mosander's techniques,

11220-491: The upwelling asthenosphere into the thinning lithosphere, heating the orogenic lithosphere for dehydration melting, typically causing extreme metamorphism at high thermal gradients of greater than 30 °C. The metamorphic products are high to ultrahigh temperature granulites and their associated migmatite and granites in collisional orogens, with possible emplacement of metamorphic core complexes in continental rift zones but oceanic core complexes in spreading ridges. This leads to

11330-463: The upwelling between stages of an upper mantle plume. Prior to the rift's formation, enormous continental flood basalts erupted, uplifting the Ethiopian , Somali, and East African plateaus. The first stage of rifting of the EAR was characterized by rift localization and magmatism along the entire rift zone. Periods of extension alternated with relative inactivity. There was also the reactivation of

11440-619: The valley of Lake Malawi . The rift also continues offshore from the coast of Mozambique along the Kerimba and Lacerda grabens , which are joined by the Davie Ridge, a 2,200 km-long (1,400 mi) relic fracture zone that cuts across the West Somali basin, straddling the boundary between Tanzania and Mozambique. The Davie Ridge ranges between 30–120 km (19–75 mi) wide, with a west-facing scarp (east-plunging arch) along

11550-454: The valley with sediments, creating a favorable environment for the preservation of remains. The bones of several hominid ancestors of modern humans have been found here, including those of " Lucy ", a partial australopithecine skeleton discovered by anthropologist Donald Johanson dating back over 3 million years. Richard and Mary Leakey have also done significant work in this region. In 2008, two other hominid ancestors were discovered here:

11660-478: Was gadolinite , a black mineral composed of cerium, yttrium, iron, silicon, and other elements. This mineral was extracted from a mine in the village of Ytterby in Sweden ; four of the rare-earth elements bear names derived from this single location. A table listing the 17 rare-earth elements, their atomic number and symbol, the etymology of their names, and their main uses (see also Applications of lanthanides )

11770-478: Was found in the "ytterbite" (renamed to gadolinite in 1800) discovered by Lieutenant Carl Axel Arrhenius in 1787 at a quarry in the village of Ytterby , Sweden and termed "rare" because it had never yet been seen. Arrhenius's "ytterbite" reached Johan Gadolin , a Royal Academy of Turku professor, and his analysis yielded an unknown oxide ("earth" in the geological parlance of the day ), which he called yttria . Anders Gustav Ekeberg isolated beryllium from

11880-492: Was in fact still a mixture of oxides. In 1842 Mosander also separated the yttria into three oxides: pure yttria, terbia, and erbia (all the names are derived from the town name "Ytterby"). The earth giving pink salts he called terbium ; the one that yielded yellow peroxide he called erbium . In 1842 the number of known rare-earth elements had reached six: yttrium, cerium, lanthanum, didymium, erbium, and terbium. Nils Johan Berlin and Marc Delafontaine tried also to separate

11990-494: Was once thought to be in space group I 2 1 3 (no. 199), but is now known to be in space group Ia 3 (no. 206). The structure is similar to that of fluorite or cerium dioxide (in which the cations form a face-centred cubic lattice and the anions sit inside the tetrahedra of cations), except that one-quarter of the anions (oxygen) are missing. The unit cell of these sesquioxides corresponds to eight unit cells of fluorite or cerium dioxide, with 32 cations instead of 4. This

12100-549: Was previously thought, elevated passive continental margins (EPCM) such as the Brazilian Highlands , the Scandinavian Mountains and India's Western Ghats , are not rift shoulders. The formation of rift basins and strain localization reflects rift maturity. At the onset of rifting, the upper part of the lithosphere starts to extend on a series of initially unconnected normal faults , leading to

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