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Department of Chemistry, University of Oxford

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Natural science is one of the branches of science concerned with the description, understanding and prediction of natural phenomena , based on empirical evidence from observation and experimentation . Mechanisms such as peer review and reproducibility of findings are used to try to ensure the validity of scientific advances.

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117-627: The Department of Chemistry is the chemistry department of the University of Oxford , England, which is part of the university's Mathematical, Physical and Life Sciences Division . The department has several laboratories in the Science Area, Oxford : In Mansfield Road In South Parks Road Chemistry has a long history at Oxford. The early pioneer of chemistry Robert Boyle and his assistant Robert Hooke began working in Oxford in

234-440: A chemical equation . While in a non-nuclear chemical reaction the number and kind of atoms on both sides of the equation are equal, for a nuclear reaction this holds true only for the nuclear particles viz. protons and neutrons. The sequence of steps in which the reorganization of chemical bonds may be taking place in the course of a chemical reaction is called its mechanism . A chemical reaction can be envisioned to take place in

351-546: A career in planetary science undergo graduate-level studies in one of the Earth sciences, astronomy, astrophysics, geophysics, or physics. They then focus their research within the discipline of planetary science. Major conferences are held annually, and numerous peer reviewed journals cater to the diverse research interests in planetary science. Some planetary scientists are employed by private research centers and frequently engage in collaborative research initiatives. Constituting

468-467: A chemical reaction is said to have occurred. A chemical reaction is therefore a concept related to the "reaction" of a substance when it comes in close contact with another, whether as a mixture or a solution ; exposure to some form of energy, or both. It results in some energy exchange between the constituents of the reaction as well as with the system environment, which may be designed vessels—often laboratory glassware . Chemical reactions can result in

585-470: A chemical transformation is the rearrangement of electrons in the chemical bonds between atoms. It can be symbolically depicted through a chemical equation , which usually involves atoms as subjects. The number of atoms on the left and the right in the equation for a chemical transformation is equal. (When the number of atoms on either side is unequal, the transformation is referred to as a nuclear reaction or radioactive decay .) The type of chemical reactions

702-412: A dense core called the atomic nucleus surrounded by a space occupied by an electron cloud . The nucleus is made up of positively charged protons and uncharged neutrons (together called nucleons ), while the electron cloud consists of negatively charged electrons which orbit the nucleus. In a neutral atom, the negatively charged electrons balance out the positive charge of the protons. The nucleus

819-535: A directed beam in a vacuum in a mass spectrometer . Charged polyatomic collections residing in solids (for example, common sulfate or nitrate ions) are generally not considered "molecules" in chemistry. Some molecules contain one or more unpaired electrons, creating radicals . Most radicals are comparatively reactive, but some, such as nitric oxide (NO) can be stable. The "inert" or noble gas elements ( helium , neon , argon , krypton , xenon and radon ) are composed of lone atoms as their smallest discrete unit, but

936-484: A key part of most scientific discourse. Such integrative fields, for example, include nanoscience , astrobiology , and complex system informatics . Materials science is a relatively new, interdisciplinary field that deals with the study of matter and its properties and the discovery and design of new materials. Originally developed through the field of metallurgy , the study of the properties of materials and solids has now expanded into all materials. The field covers

1053-447: A laboratory, using a series of (often well-tested) techniques for manipulating materials, as well as an understanding of the underlying processes. Chemistry is often called " the central science " because of its role in connecting the other natural sciences. Early experiments in chemistry had their roots in the system of alchemy , a set of beliefs combining mysticism with physical experiments. The science of chemistry began to develop with

1170-423: A level equal with theology and the debate of religious constructs in a scientific context, showed the persistence with which Catholic leaders resisted the development of natural philosophy even from a theological perspective. Aquinas and Albertus Magnus , another Catholic theologian of the era, sought to distance theology from science in their works. "I don't see what one's interpretation of Aristotle has to do with

1287-400: A matter not only for their existence but also for their definition." There was broad agreement among scholars in medieval times that natural science was about bodies in motion. However, there was division about including fields such as medicine, music, and perspective. Philosophers pondered questions including the existence of a vacuum, whether motion could produce heat, the colors of rainbows,

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1404-744: A methodical way. Still, philosophical perspectives, conjectures , and presuppositions , often overlooked, remain necessary in natural science. Systematic data collection, including discovery science , succeeded natural history , which emerged in the 16th century by describing and classifying plants, animals, minerals, and so on. Today, "natural history" suggests observational descriptions aimed at popular audiences. Philosophers of science have suggested several criteria, including Karl Popper 's controversial falsifiability criterion, to help them differentiate scientific endeavors from non-scientific ones. Validity , accuracy , and quality control , such as peer review and reproducibility of findings, are amongst

1521-411: A number of steps, each of which may have a different speed. Many reaction intermediates with variable stability can thus be envisaged during the course of a reaction. Reaction mechanisms are proposed to explain the kinetics and the relative product mix of a reaction. Many physical chemists specialize in exploring and proposing the mechanisms of various chemical reactions. Several empirical rules, like

1638-424: A particular substance per volume of solution , and is commonly reported in mol/ dm . In addition to the specific chemical properties that distinguish different chemical classifications, chemicals can exist in several phases. For the most part, the chemical classifications are independent of these bulk phase classifications; however, some more exotic phases are incompatible with certain chemical properties. A phase

1755-591: A positive hydrogen ion to another substance in a chemical reaction; by extension, a base is the substance which receives that hydrogen ion. Natural sciences Natural science can be divided into two main branches: life science and physical science . Life science is alternatively known as biology , and physical science is subdivided into branches: physics , chemistry , earth science , and astronomy . These branches of natural science may be further divided into more specialized branches (also known as fields). As empirical sciences, natural sciences use tools from

1872-405: A pure chemical substance that has its unique set of chemical properties, that is, its potential to undergo a certain set of chemical reactions with other substances. However, this definition only works well for substances that are composed of molecules, which is not true of many substances (see below). Molecules are typically a set of atoms bound together by covalent bonds , such that the structure

1989-480: A separate field in its own right, most modern workers in the field agree that it has matured to a state that it has its own paradigms and practices. Planetary science or planetology, is the scientific study of planets, which include terrestrial planets like the Earth, and other types of planets, such as gas giants and ice giants . Planetary science also concerns other celestial bodies, such as dwarf planets moons , asteroids , and comets . This largely includes

2106-400: A significant role in the other natural sciences, as represented by astrophysics , geophysics , chemical physics and biophysics . Likewise chemistry is represented by such fields as biochemistry , physical chemistry , geochemistry and astrochemistry . A particular example of a scientific discipline that draws upon multiple natural sciences is environmental science . This field studies

2223-476: A significant role in the world economy. Physics embodies the study of the fundamental constituents of the universe , the forces and interactions they exert on one another, and the results produced by these interactions. Physics is generally regarded as foundational because all other natural sciences use and obey the field's principles and laws. Physics relies heavily on mathematics as the logical framework for formulating and quantifying principles. The study of

2340-410: A step closer to direct inquiry about cause and effect in nature between 600 and 400 BC. However, an element of magic and mythology remained. Natural phenomena such as earthquakes and eclipses were explained increasingly in the context of nature itself instead of being attributed to angry gods. Thales of Miletus , an early philosopher who lived from 625 to 546 BC, explained earthquakes by theorizing that

2457-609: A substance may undergo and the energy changes that may accompany it are constrained by certain basic rules, known as chemical laws . Energy and entropy considerations are invariably important in almost all chemical studies. Chemical substances are classified in terms of their structure , phase, as well as their chemical compositions . They can be analyzed using the tools of chemical analysis , e.g. spectroscopy and chromatography . Scientists engaged in chemical research are known as chemists . Most chemists specialize in one or more sub-disciplines. Several concepts are essential for

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2574-741: A treatise by the earlier Persian scholar Al-Farabi called On the Sciences into Latin, calling the study of the mechanics of nature Scientia naturalis , or natural science. Gundissalinus also proposed his classification of the natural sciences in his 1150 work On the Division of Philosophy . This was the first detailed classification of the sciences based on Greek and Arab philosophy to reach Western Europe. Gundissalinus defined natural science as "the science considering only things unabstracted and with motion," as opposed to mathematics and sciences that rely on mathematics. Following Al-Farabi, he separated

2691-580: Is a natural science that studies celestial objects and phenomena. Objects of interest include planets, moons, stars, nebulae, galaxies, and comets. Astronomy is the study of everything in the universe beyond Earth's atmosphere, including objects we can see with our naked eyes. It is one of the oldest sciences. Astronomers of early civilizations performed methodical observations of the night sky, and astronomical artifacts have been found from much earlier periods. There are two types of astronomy: observational astronomy and theoretical astronomy. Observational astronomy

2808-414: Is a pure substance which is composed of a single type of atom, characterized by its particular number of protons in the nuclei of its atoms, known as the atomic number and represented by the symbol Z . The mass number is the sum of the number of protons and neutrons in a nucleus. Although all the nuclei of all atoms belonging to one element will have the same atomic number, they may not necessarily have

2925-409: Is a set of states of a chemical system that have similar bulk structural properties, over a range of conditions, such as pressure or temperature . Physical properties, such as density and refractive index tend to fall within values characteristic of the phase. The phase of matter is defined by the phase transition , which is when energy put into or taken out of the system goes into rearranging

3042-586: Is a very useful means for predicting the feasibility of a reaction and determining the state of equilibrium of a chemical reaction, in chemical thermodynamics . A reaction is feasible only if the total change in the Gibbs free energy is negative, Δ G ≤ 0 {\displaystyle \Delta G\leq 0\,} ; if it is equal to zero the chemical reaction is said to be at equilibrium . There exist only limited possible states of energy for electrons, atoms and molecules. These are determined by

3159-422: Is also possible to define analogs in two-dimensional systems, which has received attention for its relevance to systems in biology . Atoms sticking together in molecules or crystals are said to be bonded with one another. A chemical bond may be visualized as the multipole balance between the positive charges in the nuclei and the negative charges oscillating about them. More than simple attraction and repulsion,

3276-439: Is also used to identify the composition of remote objects – like stars and distant galaxies – by analyzing their radiation spectra. The term chemical energy is often used to indicate the potential of a chemical substance to undergo a transformation through a chemical reaction or to transform other chemical substances. When a chemical substance is transformed as a result of its interaction with another substance or with energy,

3393-420: Is an all-embracing term for the sciences related to the planet Earth , including geology , geography , geophysics , geochemistry , climatology , glaciology , hydrology , meteorology , and oceanography . Although mining and precious stones have been human interests throughout the history of civilization, the development of the related sciences of economic geology and mineralogy did not occur until

3510-464: Is called a mixture. Examples of mixtures are air and alloys . The mole is a unit of measurement that denotes an amount of substance (also called chemical amount). One mole is defined to contain exactly 6.022 140 76 × 10 particles ( atoms , molecules , ions , or electrons ), where the number of particles per mole is known as the Avogadro constant . Molar concentration is the amount of

3627-523: Is composed of gaseous matter that has been completely ionized, usually through high temperature. A substance can often be classified as an acid or a base . There are several different theories which explain acid–base behavior. The simplest is Arrhenius theory , which states that acid is a substance that produces hydronium ions when it is dissolved in water, and a base is one that produces hydroxide ions when dissolved in water. According to Brønsted–Lowry acid–base theory , acids are substances that donate

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3744-399: Is concerned with the characteristics, classification and behaviors of organisms , as well as how species were formed and their interactions with each other and the environment . The biological fields of botany , zoology , and medicine date back to early periods of civilization, while microbiology was introduced in the 17th century with the invention of the microscope. However, it

3861-472: Is dense; the mass of a nucleon is approximately 1,836 times that of an electron, yet the radius of an atom is about 10,000 times that of its nucleus. The atom is also the smallest entity that can be envisaged to retain the chemical properties of the element, such as electronegativity , ionization potential , preferred oxidation state (s), coordination number , and preferred types of bonds to form (e.g., metallic , ionic , covalent ). A chemical element

3978-464: Is electrically neutral and all valence electrons are paired with other electrons either in bonds or in lone pairs . Thus, molecules exist as electrically neutral units, unlike ions. When this rule is broken, giving the "molecule" a charge, the result is sometimes named a molecular ion or a polyatomic ion. However, the discrete and separate nature of the molecular concept usually requires that molecular ions be present only in well-separated form, such as

4095-533: Is focused on acquiring and analyzing data, mainly using basic principles of physics. In contrast, Theoretical astronomy is oriented towards developing computer or analytical models to describe astronomical objects and phenomena. This discipline is the science of celestial objects and phenomena that originate outside the Earth's atmosphere . It is concerned with the evolution, physics , chemistry , meteorology , geology , and motion of celestial objects, as well as

4212-537: Is more easily transferred between substances relative to light or other forms of electronic energy. For example, ultraviolet electromagnetic radiation is not transferred with as much efficacy from one substance to another as thermal or electrical energy. The existence of characteristic energy levels for different chemical substances is useful for their identification by the analysis of spectral lines . Different kinds of spectra are often used in chemical spectroscopy , e.g. IR , microwave , NMR , ESR , etc. Spectroscopy

4329-400: Is sometimes called the central science because it provides a foundation for understanding both basic and applied scientific disciplines at a fundamental level. For example, chemistry explains aspects of plant growth ( botany ), the formation of igneous rocks ( geology ), how atmospheric ozone is formed and how environmental pollutants are degraded ( ecology ), the properties of the soil on

4446-519: Is sub-categorized into more specialized cross-disciplines, such as physical oceanography and marine biology . As the marine ecosystem is vast and diverse, marine biology is further divided into many subfields, including specializations in particular species . There is also a subset of cross-disciplinary fields with strong currents that run counter to specialization by the nature of the problems they address. Put another way: In some fields of integrative application, specialists in more than one field are

4563-468: Is the crystal structure , or arrangement, of the atoms. Another phase commonly encountered in the study of chemistry is the aqueous phase, which is the state of substances dissolved in aqueous solution (that is, in water). Less familiar phases include plasmas , Bose–Einstein condensates and fermionic condensates and the paramagnetic and ferromagnetic phases of magnetic materials. While most familiar phases deal with three-dimensional systems, it

4680-458: Is the quantum mechanical model . Traditional chemistry starts with the study of elementary particles , atoms , molecules , substances , metals , crystals and other aggregates of matter . Matter can be studied in solid, liquid, gas and plasma states , in isolation or in combination. The interactions, reactions and transformations that are studied in chemistry are usually the result of interactions between atoms, leading to rearrangements of

4797-507: Is the probability of a molecule to have energy greater than or equal to E at the given temperature T. This exponential dependence of a reaction rate on temperature is known as the Arrhenius equation . The activation energy necessary for a chemical reaction to occur can be in the form of heat, light, electricity or mechanical force in the form of ultrasound . A related concept free energy , which also incorporates entropy considerations,

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4914-526: Is useful in identifying periodic trends . A compound is a pure chemical substance composed of more than one element. The properties of a compound bear little similarity to those of its elements. The standard nomenclature of compounds is set by the International Union of Pure and Applied Chemistry (IUPAC). Organic compounds are named according to the organic nomenclature system. The names for inorganic compounds are created according to

5031-576: The Ayurvedic tradition saw health and illness as a combination of three humors: wind , bile and phlegm . A healthy life resulted from a balance among these humors. In Ayurvedic thought, the body consisted of five elements: earth, water, fire, wind, and space. Ayurvedic surgeons performed complex surgeries and developed a detailed understanding of human anatomy. Pre-Socratic philosophers in Ancient Greek culture brought natural philosophy

5148-645: The Balliol-Trinity Laboratories ), Queen's College, Oxford (1900), and Jesus College, Oxford (1907). Chemistry was first recognized as a separate discipline at Oxford with the building of a laboratory attached to the Oxford University Museum of Natural History , opening in 1860. The laboratory is a small octagonal structure to the right of the museum, built in stone in the Victorian Gothic style. The design

5265-693: The Mesopotamian and Ancient Egyptian cultures, which produced the first known written evidence of natural philosophy , the precursor of natural science. While the writings show an interest in astronomy, mathematics, and other aspects of the physical world, the ultimate aim of inquiry about nature's workings was, in all cases, religious or mythological, not scientific. A tradition of scientific inquiry also emerged in Ancient China , where Taoist alchemists and philosophers experimented with elixirs to extend life and cure ailments. They focused on

5382-707: The Solar System , but recently has started to expand to exoplanets , particularly terrestrial exoplanets . It explores various objects, spanning from micrometeoroids to gas giants, to establish their composition, movements, genesis, interrelation, and past. Planetary science is an interdisciplinary domain, having originated from astronomy and Earth science , and currently encompassing a multitude of areas, such as planetary geology , cosmochemistry , atmospheric science , physics , oceanography , hydrology , theoretical planetology , glaciology , and exoplanetology. Related fields encompass space physics , which delves into

5499-509: The Woodward–Hoffmann rules often come in handy while proposing a mechanism for a chemical reaction. According to the IUPAC gold book, a chemical reaction is "a process that results in the interconversion of chemical species." Accordingly, a chemical reaction may be an elementary reaction or a stepwise reaction . An additional caveat is made, in that this definition includes cases where

5616-522: The cell or organic molecule . Modern biology is divided into subdisciplines by the type of organism and by the scale being studied. Molecular biology is the study of the fundamental chemistry of life, while cellular biology is the examination of the cell; the basic building block of all life. At a higher level, anatomy and physiology look at the internal structures, and their functions, of an organism, while ecology looks at how various organisms interrelate. Earth science (also known as geoscience)

5733-455: The chemical bonds which hold atoms together. Such behaviors are studied in a chemistry laboratory . The chemistry laboratory stereotypically uses various forms of laboratory glassware . However glassware is not central to chemistry, and a great deal of experimental (as well as applied/industrial) chemistry is done without it. A chemical reaction is a transformation of some substances into one or more different substances. The basis of such

5850-421: The chemical elements that make up matter and compounds made of atoms , molecules and ions : their composition, structure, properties, behavior and the changes they undergo during reactions with other substances . Chemistry also addresses the nature of chemical bonds in chemical compounds . In the scope of its subject, chemistry occupies an intermediate position between physics and biology . It

5967-493: The chemical industry . The word chemistry comes from a modification during the Renaissance of the word alchemy , which referred to an earlier set of practices that encompassed elements of chemistry, metallurgy , philosophy , astrology , astronomy , mysticism , and medicine . Alchemy is often associated with the quest to turn lead or other base metals into gold, though alchemists were also interested in many of

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6084-469: The duet rule , and in this way they are reaching the electron configuration of the noble gas helium , which has two electrons in its outer shell. Similarly, theories from classical physics can be used to predict many ionic structures. With more complicated compounds, such as metal complexes , valence bond theory is less applicable and alternative approaches, such as the molecular orbital theory, are generally used. See diagram on electronic orbitals. In

6201-420: The formal sciences , such as mathematics and logic , converting information about nature into measurements that can be explained as clear statements of the " laws of nature ". Modern natural science succeeded more classical approaches to natural philosophy . Galileo , Kepler , Descartes , Bacon , and Newton debated the benefits of using approaches which were more mathematical and more experimental in

6318-624: The formation and development of the universe . Astronomy includes examining, studying, and modeling stars, planets, and comets. Most of the information used by astronomers is gathered by remote observation. However, some laboratory reproduction of celestial phenomena has been performed (such as the molecular chemistry of the interstellar medium ). There is considerable overlap with physics and in some areas of earth science . There are also interdisciplinary fields such as astrophysics , planetary sciences , and cosmology , along with allied disciplines such as space physics and astrochemistry . While

6435-510: The inorganic nomenclature system. When a compound has more than one component, then they are divided into two classes, the electropositive and the electronegative components. In addition the Chemical Abstracts Service has devised a method to index chemical substances. In this scheme each chemical substance is identifiable by a number known as its CAS registry number . A molecule is the smallest indivisible portion of

6552-500: The interconversion of conformers is experimentally observable. Such detectable chemical reactions normally involve sets of molecular entities as indicated by this definition, but it is often conceptually convenient to use the term also for changes involving single molecular entities (i.e. 'microscopic chemical events'). An ion is a charged species, an atom or a molecule, that has lost or gained one or more electrons. When an atom loses an electron and thus has more protons than electrons,

6669-529: The intermolecular forces of a substance are such that the energy of the surroundings is not sufficient to overcome them, it occurs in a more ordered phase like liquid or solid as is the case with water (H 2 O); a liquid at room temperature because its molecules are bound by hydrogen bonds . Whereas hydrogen sulfide (H 2 S) is a gas at room temperature and standard pressure, as its molecules are bound by weaker dipole–dipole interactions . The transfer of energy from one chemical substance to another depends on

6786-438: The size of energy quanta emitted from one substance. However, heat energy is often transferred more easily from almost any substance to another because the phonons responsible for vibrational and rotational energy levels in a substance have much less energy than photons invoked for the electronic energy transfer. Thus, because vibrational and rotational energy levels are more closely spaced than electronic energy levels, heat

6903-522: The yin and yang , or contrasting elements in nature; the yin was associated with femininity and coldness, while yang was associated with masculinity and warmth. The five phases – fire, earth, metal, wood, and water – described a cycle of transformations in nature. The water turned into wood, which turned into the fire when it burned. The ashes left by fire were earth. Using these principles, Chinese philosophers and doctors explored human anatomy, characterizing organs as predominantly yin or yang, and understood

7020-454: The 16th century, and he is considered to be the father of biology for his pioneering work in that science . He also presented philosophies about physics, nature, and astronomy using inductive reasoning in his works Physics and Meteorology . While Aristotle considered natural philosophy more seriously than his predecessors, he approached it as a theoretical branch of science. Still, inspired by his work, Ancient Roman philosophers of

7137-549: The 18th century. The study of the earth, particularly paleontology , blossomed in the 19th century. The growth of other disciplines, such as geophysics , in the 20th century led to the development of the theory of plate tectonics in the 1960s, which has had a similar effect on the Earth sciences as the theory of evolution had on biology. Earth sciences today are closely linked to petroleum and mineral resources , climate research, and to environmental assessment and remediation . Although sometimes considered in conjunction with

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7254-517: The 2019 Nobel Prize in Chemistry), and bioinorganic chemistry by Robert Williams . Heads of department have included: Current academics in the Department of Chemistry include: Other notable staff and alumni include: Chemistry Chemistry is the scientific study of the properties and behavior of matter . It is a physical science within the natural sciences that studies

7371-570: The Department of Organic Chemistry until 2003 when it was replaced by the Chemistry Research Laboratory . The Physical Chemistry Laboratory replaced the Balliol-Trinity Laboratories in 1941, and its east wing completed in 1959. The physical and theoretical chemistry departments merged in 1994 and the Physical and Theoretical Chemistry Laboratory became its base in 1995. A number of professors and scientists who worked in

7488-566: The Middle Ages brought with it further advances in natural philosophy. European inventions such as the horseshoe , horse collar and crop rotation allowed for rapid population growth, eventually giving way to urbanization and the foundation of schools connected to monasteries and cathedrals in modern-day France and England . Aided by the schools, an approach to Christian theology developed that sought to answer questions about nature and other subjects using logic. This approach, however,

7605-546: The Moon ( cosmochemistry ), how medications work ( pharmacology ), and how to collect DNA evidence at a crime scene ( forensics ). Chemistry has existed under various names since ancient times. It has evolved, and now chemistry encompasses various areas of specialisation, or subdisciplines, that continue to increase in number and interrelate to create further interdisciplinary fields of study. The applications of various fields of chemistry are used frequently for economic purposes in

7722-515: The Valence Shell Electron Pair Repulsion model ( VSEPR ), and the concept of oxidation number can be used to explain molecular structure and composition. An ionic bond is formed when a metal loses one or more of its electrons, becoming a positively charged cation, and the electrons are then gained by the non-metal atom, becoming a negatively charged anion. The two oppositely charged ions attract one another, and

7839-479: The West. Christopher Columbus 's discovery of a new world changed perceptions about the physical makeup of the world, while observations by Copernicus , Tyco Brahe and Galileo brought a more accurate picture of the solar system as heliocentric and proved many of Aristotle's theories about the heavenly bodies false. Several 17th-century philosophers, including Thomas Hobbes , John Locke and Francis Bacon , made

7956-494: The atom is a positively charged ion or cation . When an atom gains an electron and thus has more electrons than protons, the atom is a negatively charged ion or anion . Cations and anions can form a crystalline lattice of neutral salts , such as the Na and Cl ions forming sodium chloride , or NaCl. Examples of polyatomic ions that do not split up during acid–base reactions are hydroxide (OH ) and phosphate (PO 4 ). Plasma

8073-542: The chemistry, physics, and engineering applications of materials, including metals, ceramics, artificial polymers, and many others. The field's core deals with relating the structure of materials with their properties. Materials science is at the forefront of research in science and engineering. It is an essential part of forensic engineering (the investigation of materials, products, structures, or components that fail or do not operate or function as intended, causing personal injury or damage to property) and failure analysis ,

8190-512: The conclusion that something is impossible. While an impossibility assertion in natural science can never be proved, it could be refuted by the observation of a single counterexample. Such a counterexample would require that the assumptions underlying the theory that implied the impossibility be re-examined. This field encompasses a diverse set of disciplines that examine phenomena related to living organisms. The scale of study can range from sub-component biophysics up to complex ecologies . Biology

8307-412: The context of chemistry, energy is an attribute of a substance as a consequence of its atomic , molecular or aggregate structure . Since a chemical transformation is accompanied by a change in one or more of these kinds of structures, it is invariably accompanied by an increase or decrease of energy of the substances involved. Some energy is transferred between the surroundings and the reactants of

8424-580: The department had won the Nobel Prize ; they include Frederick Soddy for his work on radioactivity with Ernest Rutherford , Cyril Norman Hinshelwood for his work on chemical kinetics , and Dorothy Hodgkin on crystallography . Among the notable achievements by professors in the department are the development of the Periodic Table by William Odling , work on solid state chemistry by John Stuart Anderson and John B. Goodenough (winner of

8541-494: The development of thermodynamics , and the quantum mechanical model of atomic and subatomic physics. The field of physics is vast and can include such diverse studies as quantum mechanics and theoretical physics , applied physics and optics . Modern physics is becoming increasingly specialized, where researchers tend to focus on a particular area rather than being "universalists" like Isaac Newton , Albert Einstein , and Lev Landau , who worked in multiple areas. Astronomy

8658-575: The early 13th century, although the practice was frowned upon by the Catholic church. A 1210 decree from the Synod of Paris ordered that "no lectures are to be held in Paris either publicly or privately using Aristotle's books on natural philosophy or the commentaries, and we forbid all this under pain of ex-communication." In the late Middle Ages, Spanish philosopher Dominicus Gundissalinus translated

8775-501: The early 1st century AD, including Lucretius , Seneca and Pliny the Elder , wrote treatises that dealt with the rules of the natural world in varying degrees of depth. Many Ancient Roman Neoplatonists of the 3rd to the 6th centuries also adapted Aristotle's teachings on the physical world to a philosophy that emphasized spiritualism. Early medieval philosophers including Macrobius , Calcidius and Martianus Capella also examined

8892-447: The earth sciences, due to the independent development of its concepts, techniques, and practices and also the fact of it having a wide range of sub-disciplines under its wing, atmospheric science is also considered a separate branch of natural science. This field studies the characteristics of different layers of the atmosphere from ground level to the edge of the space. The timescale of the study also varies from day to century. Sometimes,

9009-429: The energies and distributions characterize the availability of an electron to bond to another atom. The chemical bond can be a covalent bond , an ionic bond , a hydrogen bond or just because of Van der Waals force . Each of these kinds of bonds is ascribed to some potential. These potentials create the interactions which hold atoms together in molecules or crystals . In many simple compounds, valence bond theory ,

9126-400: The field also includes the study of climatic patterns on planets other than Earth. The serious study of oceans began in the early- to mid-20th century. As a field of natural science, it is relatively young, but stand-alone programs offer specializations in the subject. Though some controversies remain as to the categorization of the field under earth sciences, interdisciplinary sciences, or as

9243-444: The formation or dissociation of molecules, that is, molecules breaking apart to form two or more molecules or rearrangement of atoms within or across molecules. Chemical reactions usually involve the making or breaking of chemical bonds. Oxidation, reduction , dissociation , acid–base neutralization and molecular rearrangement are some examples of common chemical reactions. A chemical reaction can be symbolically depicted through

9360-888: The impact of the Sun on the bodies in the Solar System, and astrobiology . Planetary science comprises interconnected observational and theoretical branches. Observational research entails a combination of space exploration , primarily through robotic spacecraft missions utilizing remote sensing, and comparative experimental work conducted in Earth-based laboratories. The theoretical aspect involves extensive mathematical modelling and computer simulation . Typically, planetary scientists are situated within astronomy and physics or Earth sciences departments in universities or research centers. However, there are also dedicated planetary science institutes worldwide. Generally, individuals pursuing

9477-436: The interactions of physical, chemical, geological, and biological components of the environment , with particular regard to the effect of human activities and the impact on biodiversity and sustainability . This science also draws upon expertise from other fields, such as economics, law, and social sciences. A comparable discipline is oceanography , as it draws upon a similar breadth of scientific disciplines. Oceanography

9594-445: The ionic bond is the electrostatic force of attraction between them. For example, sodium (Na), a metal, loses one electron to become an Na cation while chlorine (Cl), a non-metal, gains this electron to become Cl . The ions are held together due to electrostatic attraction, and that compound sodium chloride (NaCl), or common table salt, is formed. In a covalent bond, one or more pairs of valence electrons are shared by two atoms:

9711-556: The latter being the key to understanding, for example, the cause of various aviation accidents. Many of the most pressing scientific problems that are faced today are due to the limitations of the materials that are available, and, as a result, breakthroughs in this field are likely to have a significant impact on the future of technology. The basis of materials science involves studying the structure of materials and relating them to their properties . Understanding this structure-property correlation, material scientists can then go on to study

9828-473: The main characteristics of a molecule is its geometry often called its structure . While the structure of diatomic, triatomic or tetra-atomic molecules may be trivial, (linear, angular pyramidal etc.) the structure of polyatomic molecules, that are constituted of more than six atoms (of several elements) can be crucial for its chemical nature. A chemical substance is a kind of matter with a definite composition and set of properties . A collection of substances

9945-485: The mid-seventeenth century. A chemistry laboratory was built in the basement of the Old Ashmolean Building in 1683, which was used until 1860. Chemical research was also conducted in laboratories set up in individual colleges – Christ Church, Oxford (1767), Magdalen College, Oxford (Daubeny Laboratory, 1848), Balliol College, Oxford (1853, later joined with Trinity College, Oxford to become

10062-454: The most respected criteria in today's global scientific community. In natural science, impossibility assertions come to be widely accepted as overwhelmingly probable rather than considered proven to the point of being unchallengeable. The basis for this strong acceptance is a combination of extensive evidence of something not occurring, combined with an underlying theory, very successful in making predictions, whose assumptions lead logically to

10179-413: The motion of the earth, whether elemental chemicals exist, and where in the atmosphere rain is formed. In the centuries up through the end of the Middle Ages, natural science was often mingled with philosophies about magic and the occult. Natural philosophy appeared in various forms, from treatises to encyclopedias to commentaries on Aristotle. The interaction between natural philosophy and Christianity

10296-409: The origins of natural science as far back as pre-literate human societies, where understanding the natural world was necessary for survival. People observed and built up knowledge about the behavior of animals and the usefulness of plants as food and medicine, which was passed down from generation to generation. These primitive understandings gave way to more formalized inquiry around 3500 to 3000 BC in

10413-419: The other isolated chemical elements consist of either molecules or networks of atoms bonded to each other in some way. Identifiable molecules compose familiar substances such as water, air, and many organic compounds like alcohol, sugar, gasoline, and the various pharmaceuticals . However, not all substances or chemical compounds consist of discrete molecules, and indeed most of the solid substances that make up

10530-603: The physical world, largely from a cosmological and cosmographical perspective, putting forth theories on the arrangement of celestial bodies and the heavens, which were posited as being composed of aether . Aristotle's works on natural philosophy continued to be translated and studied amid the rise of the Byzantine Empire and Abbasid Caliphate . In the Byzantine Empire, John Philoponus , an Alexandrian Aristotelian commentator and Christian theologian,

10647-508: The physical world; Plato criticized pre-Socratic thinkers as materialists and anti-religionists. Aristotle , however, a student of Plato who lived from 384 to 322 BC, paid closer attention to the natural world in his philosophy. In his History of Animals , he described the inner workings of 110 species, including the stingray , catfish and bee . He investigated chick embryos by breaking open eggs and observing them at various stages of development. Aristotle's works were influential through

10764-630: The principles of the universe has a long history and largely derives from direct observation and experimentation. The formulation of theories about the governing laws of the universe has been central to the study of physics from very early on, with philosophy gradually yielding to systematic, quantitative experimental testing and observation as the source of verification. Key historical developments in physics include Isaac Newton 's theory of universal gravitation and classical mechanics , an understanding of electricity and its relation to magnetism , Einstein 's theories of special and general relativity ,

10881-569: The questions of modern chemistry. The modern word alchemy in turn is derived from the Arabic word al-kīmīā ( الكیمیاء ). This may have Egyptian origins since al-kīmīā is derived from the Ancient Greek χημία , which is in turn derived from the word Kemet , which is the ancient name of Egypt in the Egyptian language. Alternately, al-kīmīā may derive from χημεία 'cast together'. The current model of atomic structure

10998-478: The reaction absorbs heat from the surroundings. Chemical reactions are invariably not possible unless the reactants surmount an energy barrier known as the activation energy . The speed of a chemical reaction (at given temperature T) is related to the activation energy E, by the Boltzmann's population factor e − E / k T {\displaystyle e^{-E/kT}} – that

11115-433: The reaction in the form of heat or light ; thus the products of a reaction may have more or less energy than the reactants. A reaction is said to be exergonic if the final state is lower on the energy scale than the initial state; in the case of endergonic reactions the situation is the reverse. A reaction is said to be exothermic if the reaction releases heat to the surroundings; in the case of endothermic reactions ,

11232-556: The relationship between the pulse, the heart, and the flow of blood in the body centuries before it became accepted in the West. Little evidence survives of how Ancient Indian cultures around the Indus River understood nature, but some of their perspectives may be reflected in the Vedas , a set of sacred Hindu texts. They reveal a conception of the universe as ever-expanding and constantly being recycled and reformed. Surgeons in

11349-426: The relative performance of a material in a particular application. The major determinants of the structure of a material and, thus, of its properties are its constituent chemical elements and how it has been processed into its final form. These characteristics, taken together and related through the laws of thermodynamics and kinetics , govern a material's microstructure and thus its properties. Some scholars trace

11466-544: The resulting electrically neutral group of bonded atoms is termed a molecule . Atoms will share valence electrons in such a way as to create a noble gas electron configuration (eight electrons in their outermost shell) for each atom. Atoms that tend to combine in such a way that they each have eight electrons in their valence shell are said to follow the octet rule . However, some elements like hydrogen and lithium need only two electrons in their outermost shell to attain this stable configuration; these atoms are said to follow

11583-403: The rules of quantum mechanics , which require quantization of energy of a bound system. The atoms/molecules in a higher energy state are said to be excited. The molecules/atoms of substance in an excited energy state are often much more reactive; that is, more amenable to chemical reactions. The phase of a substance is invariably determined by its energy and the energy of its surroundings. When

11700-474: The same mass number; atoms of an element which have different mass numbers are known as isotopes . For example, all atoms with 6 protons in their nuclei are atoms of the chemical element carbon , but atoms of carbon may have mass numbers of 12 or 13. The standard presentation of the chemical elements is in the periodic table , which orders elements by atomic number. The periodic table is arranged in groups , or columns, and periods , or rows. The periodic table

11817-504: The science that deals with bodies in motion. Roger Bacon , an English friar and philosopher, wrote that natural science dealt with "a principle of motion and rest, as in the parts of the elements of fire, air, earth, and water, and in all inanimate things made from them." These sciences also covered plants, animals and celestial bodies. Later in the 13th century, a Catholic priest and theologian Thomas Aquinas defined natural science as dealing with "mobile beings" and "things which depend on

11934-456: The sciences into eight parts, including: physics, cosmology, meteorology, minerals science, and plant and animal science. Later, philosophers made their own classifications of the natural sciences. Robert Kilwardby wrote On the Order of the Sciences in the 13th century that classed medicine as a mechanical science, along with agriculture, hunting, and theater, while defining natural science as

12051-475: The scientific study of matter at the atomic and molecular scale, chemistry deals primarily with collections of atoms, such as gases , molecules, crystals , and metals . The composition, statistical properties, transformations, and reactions of these materials are studied. Chemistry also involves understanding the properties and interactions of individual atoms and molecules for use in larger-scale applications. Most chemical processes can be studied directly in

12168-593: The solid crust, mantle, and core of the Earth are chemical compounds without molecules. These other types of substances, such as ionic compounds and network solids , are organized in such a way as to lack the existence of identifiable molecules per se . Instead, these substances are discussed in terms of formula units or unit cells as the smallest repeating structure within the substance. Examples of such substances are mineral salts (such as table salt ), solids like carbon and diamond, metals, and familiar silica and silicate minerals such as quartz and granite. One of

12285-695: The structure of the system, instead of changing the bulk conditions. Sometimes the distinction between phases can be continuous instead of having a discrete boundary' in this case the matter is considered to be in a supercritical state. When three states meet based on the conditions, it is known as a triple point and since this is invariant, it is a convenient way to define a set of conditions. The most familiar examples of phases are solids , liquids , and gases . Many substances exhibit multiple solid phases. For example, there are three phases of solid iron (alpha, gamma, and delta) that vary based on temperature and pressure. A principal difference between solid phases

12402-415: The study of celestial features and phenomena can be traced back to antiquity, the scientific methodology of this field began to develop in the middle of the 17th century. A key factor was Galileo 's introduction of the telescope to examine the night sky in more detail. The mathematical treatment of astronomy began with Newton 's development of celestial mechanics and the laws of gravitation . However, it

12519-421: The study of chemistry; some of them are: In chemistry, matter is defined as anything that has rest mass and volume (it takes up space) and is made up of particles . The particles that make up matter have rest mass as well – not all particles have rest mass, such as the photon . Matter can be a pure chemical substance or a mixture of substances. The atom is the basic unit of chemistry. It consists of

12636-491: The teaching of the faith," he wrote in 1271. By the 16th and 17th centuries, natural philosophy evolved beyond commentary on Aristotle as more early Greek philosophy was uncovered and translated. The invention of the printing press in the 15th century, the invention of the microscope and telescope, and the Protestant Reformation fundamentally altered the social context in which scientific inquiry evolved in

12753-520: The time of the Abbasid Caliphate from the 9th century onward, when Muslim scholars expanded upon Greek and Indian natural philosophy. The words alcohol , algebra and zenith all have Arabic roots. Aristotle's works and other Greek natural philosophy did not reach the West until about the middle of the 12th century, when works were translated from Greek and Arabic into Latin . The development of European civilization later in

12870-447: The work of Robert Boyle , the discoverer of gases , and Antoine Lavoisier , who developed the theory of the conservation of mass . The discovery of the chemical elements and atomic theory began to systematize this science, and researchers developed a fundamental understanding of states of matter , ions , chemical bonds and chemical reactions . The success of this science led to a complementary chemical industry that now plays

12987-457: The world floated on water and that water was the fundamental element in nature. In the 5th century BC, Leucippus was an early exponent of atomism , the idea that the world is made up of fundamental indivisible particles. Pythagoras applied Greek innovations in mathematics to astronomy and suggested that the earth was spherical . Later Socratic and Platonic thought focused on ethics, morals, and art and did not attempt an investigation of

13104-547: Was based on the Abbot's Kitchen at Glastonbury and it adopted the same name despite being a laboratory. The building was one of the first ever purpose-built chemical laboratories anywhere and was extended in 1878. The Abbot's Kitchen in Oxford was expanded considerably in 1957 to become the main Inorganic Chemistry Laboratory (ICL). The Dyson Perrins Laboratory opened in 1916 and was the centre of

13221-440: Was complex during this period; some early theologians, including Tatian and Eusebius , considered natural philosophy an outcropping of pagan Greek science and were suspicious of it. Although some later Christian philosophers, including Aquinas, came to see natural science as a means of interpreting scripture, this suspicion persisted until the 12th and 13th centuries. The Condemnation of 1277 , which forbade setting philosophy on

13338-410: Was not until the 19th century that biology became a unified science. Once scientists discovered commonalities between all living things, it was decided they were best studied as a whole. Some key developments in biology were the discovery of genetics , evolution through natural selection , the germ theory of disease , and the application of the techniques of chemistry and physics at the level of

13455-556: Was seen by some detractors as heresy . By the 12th century, Western European scholars and philosophers came into contact with a body of knowledge of which they had previously been ignorant: a large corpus of works in Greek and Arabic that were preserved by Islamic scholars. Through translation into Latin, Western Europe was introduced to Aristotle and his natural philosophy. These works were taught at new universities in Paris and Oxford by

13572-541: Was the first to question Aristotle's physics teaching. Unlike Aristotle, who based his physics on verbal argument, Philoponus instead relied on observation and argued for observation rather than resorting to a verbal argument. He introduced the theory of impetus . John Philoponus' criticism of Aristotelian principles of physics served as inspiration for Galileo Galilei during the Scientific Revolution . A revival in mathematics and science took place during

13689-435: Was triggered by earlier work of astronomers such as Kepler . By the 19th century, astronomy had developed into formal science, with the introduction of instruments such as the spectroscope and photography , along with much-improved telescopes and the creation of professional observatories. The distinctions between the natural science disciplines are not always sharp, and they share many cross-discipline fields. Physics plays

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