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Oca (river)

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85-554: The Oca river is a short river, about 70 kilometres (43 mi) long, in the north of Spain. It is an affluent of the Ebro river that flows through the province of Burgos. It begins in the Sistema Ibérico range and flows north through the municipalities of Rábanos , Villafranca Montes de Oca , Valle de Oca , Alcocero de Mola , Prádanos de Bureba , Briviesca , Vileña , the shire of Bureba and Oña. The Oca River rises in

170-455: A Mohs hardness of 2 to 4, dense limestone can have a crushing strength of up to 180 MPa . For comparison, concrete typically has a crushing strength of about 40 MPa. Although limestones show little variability in mineral composition, they show great diversity in texture. However, most limestone consists of sand-sized grains in a carbonate mud matrix. Because limestones are often of biological origin and are usually composed of sediment that

255-463: A bloom of cyanobacteria or microalgae . However, stable isotope ratios in modern carbonate mud appear to be inconsistent with either of these mechanisms, and abrasion of carbonate grains in high-energy environments has been put forward as a third possibility. Formation of limestone has likely been dominated by biological processes throughout the Phanerozoic , the last 540 million years of

340-434: A carbonate rock outcrop can be estimated in the field by etching the surface with dilute hydrochloric acid. This etches away the calcite and aragonite, leaving behind any silica or dolomite grains. The latter can be identified by their rhombohedral shape. Crystals of calcite, quartz , dolomite or barite may line small cavities ( vugs ) in the rock. Vugs are a form of secondary porosity, formed in existing limestone by

425-616: A central quartz grain or carbonate mineral fragment. These likely form by direct precipitation of calcium carbonate onto the ooid. Pisoliths are similar to ooids, but they are larger than 2 mm in diameter and tend to be more irregular in shape. Limestone composed mostly of ooids is called an oolite or sometimes an oolitic limestone . Ooids form in high-energy environments, such as the Bahama platform, and oolites typically show crossbedding and other features associated with deposition in strong currents. Oncoliths resemble ooids but show

510-449: A change in environment that increases the solubility of calcite. Dense, massive limestone is sometimes described as "marble". For example, the famous Portoro "marble" of Italy is actually a dense black limestone. True marble is produced by recrystallization of limestone during regional metamorphism that accompanies the mountain building process ( orogeny ). It is distinguished from dense limestone by its coarse crystalline texture and

595-949: A composition reflecting the organisms that produced them and the environment in which they were produced. Low-magnesium calcite skeletal grains are typical of articulate brachiopods , planktonic (free-floating) foraminifera, and coccoliths . High-magnesium calcite skeletal grains are typical of benthic (bottom-dwelling) foraminifera, echinoderms , and coralline algae . Aragonite skeletal grains are typical of molluscs , calcareous green algae , stromatoporoids , corals , and tube worms . The skeletal grains also reflect specific geological periods and environments. For example, coral grains are more common in high-energy environments (characterized by strong currents and turbulence) while bryozoan grains are more common in low-energy environments (characterized by quiet water). Ooids (sometimes called ooliths) are sand-sized grains (less than 2mm in diameter) consisting of one or more layers of calcite or aragonite around

680-412: A considerable fraction of the limestone bed. At depths greater than 1 km (0.62 miles), burial cementation completes the lithification process. Burial cementation does not produce stylolites. When overlying beds are eroded, bringing limestone closer to the surface, the final stage of diagenesis takes place. This produces secondary porosity as some of the cement is dissolved by rainwater infiltrating

765-483: A drop of dilute hydrochloric acid is dropped on it. Dolomite is also soft but reacts only feebly with dilute hydrochloric acid, and it usually weathers to a characteristic dull yellow-brown color due to the presence of ferrous iron. This is released and oxidized as the dolomite weathers. Impurities (such as clay , sand, organic remains, iron oxide , and other materials) will cause limestones to exhibit different colors, especially with weathered surfaces. The makeup of

850-637: A few million years, as this is the most stable form of calcium carbonate. Ancient carbonate formations of the Precambrian and Paleozoic contain abundant dolomite, but limestone dominates the carbonate beds of the Mesozoic and Cenozoic . Modern dolomite is quite rare. There is evidence that, while the modern ocean favors precipitation of aragonite, the oceans of the Paleozoic and middle to late Cenozoic favored precipitation of calcite. This may indicate

935-455: A few thousand years. As rainwater mixes with groundwater, aragonite and high-magnesium calcite are converted to low-calcium calcite. Cementing of thick carbonate deposits by rainwater may commence even before the retreat of the sea, as rainwater can infiltrate over 100 km (60 miles) into sediments beneath the continental shelf. As carbonate sediments are increasingly deeply buried under younger sediments, chemical and mechanical compaction of

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1020-490: A high percentage of the mineral dolomite , CaMg(CO 3 ) 2 . Magnesian limestone is an obsolete and poorly-defined term used variously for dolomite, for limestone containing significant dolomite ( dolomitic limestone ), or for any other limestone containing a significant percentage of magnesium . Most limestone was formed in shallow marine environments, such as continental shelves or platforms , though smaller amounts were formed in many other environments. Much dolomite

1105-435: A limestone sample except in thin section and are less common in ancient limestones, possibly because compaction of carbonate sediments disrupts them. Limeclasts are fragments of existing limestone or partially lithified carbonate sediments. Intraclasts are limeclasts that originate close to where they are deposited in limestone, while extraclasts come from outside the depositional area. Intraclasts include grapestone , which

1190-471: A lower Mg/Ca ratio in the ocean water of those times. This magnesium depletion may be a consequence of more rapid sea floor spreading , which removes magnesium from ocean water. The modern ocean and the ocean of the Mesozoic have been described as "aragonite seas". Most limestone was formed in shallow marine environments, such as continental shelves or platforms . Such environments form only about 5% of

1275-525: A lower diversity of organisms and a greater fraction of silica and clay minerals characteristic of marls . The Green River Formation is an example of a prominent freshwater sedimentary formation containing numerous limestone beds. Freshwater limestone is typically micritic. Fossils of charophyte (stonewort), a form of freshwater green algae, are characteristic of these environments, where the charophytes produce and trap carbonates. Limestones may also form in evaporite depositional environments . Calcite

1360-523: A mechanism for dolomitization, with one 2004 review paper describing it bluntly as "a myth". Ordinary seawater is capable of converting calcite to dolomite, if the seawater is regularly flushed through the rock, as by the ebb and flow of tides (tidal pumping). Once dolomitization begins, it proceeds rapidly, so that there is very little carbonate rock containing mixed calcite and dolomite. Carbonate rock tends to be either almost all calcite/aragonite or almost all dolomite. About 20% to 25% of sedimentary rock

1445-448: A plausible source of mud. Another possibility is direct precipitation from the water. A phenomenon known as whitings occurs in shallow waters, in which white streaks containing dispersed micrite appear on the surface of the water. It is uncertain whether this is freshly precipitated aragonite or simply material stirred up from the bottom, but there is some evidence that whitings are caused by biological precipitation of aragonite as part of

1530-449: A radial rather than layered internal structure, indicating that they were formed by algae in a normal marine environment. Peloids are structureless grains of microcrystalline carbonate likely produced by a variety of processes. Many are thought to be fecal pellets produced by marine organisms. Others may be produced by endolithic (boring) algae or other microorganisms or through breakdown of mollusc shells. They are difficult to see in

1615-657: A rather dry climate. Summers of the Ebro Valley most often mirror those of a semiarid climate ; some of them see more breaks of storms or showers, yet others are more arid , bringing drought save where advanced irrigation is used. The valley flood plains experience annual rainfall between 300 and 600 mm (12–24 in), with maxima in fall and spring. It is often covered with chaparral vegetation. Summers are hot and winters are cold. The dry summer season has temperatures of more than 35 °C (95 °F), occasionally reaching over 40 °C (104 °F). In winter,

1700-532: A wider river valley among limestone rocks when it reaches La Rioja and Navarre . Southern tributaries rise on the nearby watershed , the Sistema Ibérico , a mountain range among those of Spain's centre. North of the headwaters is the Cantabrian mountain range (south of Bilbao and Santander ). Much of the total water volume of the Ebro comes from its northern tributaries, which drain about 2 ⁄ 3 of

1785-560: Is also favored on the seaward margin of shelves and platforms, where there is upwelling deep ocean water rich in nutrients that increase organic productivity. Reefs are common here, but when lacking, ooid shoals are found instead. Finer sediments are deposited close to shore. The lack of deep sea limestones is due in part to rapid subduction of oceanic crust, but is more a result of dissolution of calcium carbonate at depth. The solubility of calcium carbonate increases with pressure and even more with higher concentrations of carbon dioxide, which

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1870-627: Is an end from extreme temperatures accompanied by slow-growing dwarf juniper species to unvegetated desert steppes as in "llanos de Belchite" or "Calanda desert". The mountain vegetation is mostly coniferous forests that are drought-adapted, and hardier trees in the oak genus ( Quercus ), typically less tolerant, in the wetter highlands. Halophiles ( extremophiles as to salt) abound in zones of endorheic lagoons and their feeder creeks. Tamarix -covered, these include endemic species of bryophytes , chenopodiaceas, plumbaginaceae , ruppiaceaes, Carex , lythraceaes, asteraceaes, and others. Their presence

1955-482: Is an uncommon mineral in limestone, and siderite or other carbonate minerals are rare. However, the calcite in limestone often contains a few percent of magnesium . Calcite in limestone is divided into low-magnesium and high-magnesium calcite, with the dividing line placed at a composition of 4% magnesium. High-magnesium calcite retains the calcite mineral structure, which is distinct from dolomite. Aragonite does not usually contain significant magnesium. Most limestone

2040-535: Is attributable to its ability to colonise disturbed habitats that would deter the edible iberian crayfish . The semiaquatic rodent Myocastor coypus is beginning to expand in some northwest tributaries of the head damaging crops and protected national parks in the Basque Country . Fish caught in all lower reaches of the Ebro are high in mercury and the European Union prohibits their sale, notably

2125-402: Is carbonate rock, and most of this is limestone. Limestone is found in sedimentary sequences as old as 2.7 billion years. However, the compositions of carbonate rocks show an uneven distribution in time in the geologic record. About 95% of modern carbonates are composed of high-magnesium calcite and aragonite. The aragonite needles in carbonate mud are converted to low-magnesium calcite within

2210-501: Is causing the erosion of the coastline and lack of sediment replenishment. The unstable surface is due to weather changes and tidal surges . The river floods from time to time, although advance warning can now be given as a result of monitoring within the catchment area. The river flow in Zaragoza during floods, from the end of the 19th century is as follows: The Ebro poured 1,874 million cubic metres (1,519,000 acre-feet ) into

2295-474: Is clusters of peloids cemented together by organic material or mineral cement. Extraclasts are uncommon, are usually accompanied by other clastic sediments, and indicate deposition in a tectonically active area or as part of a turbidity current . The grains of most limestones are embedded in a matrix of carbonate mud. This is typically the largest fraction of an ancient carbonate rock. Mud consisting of individual crystals less than 5 μm (0.20 mils) in length

2380-416: Is commonly white to gray in color. Limestone that is unusually rich in organic matter can be almost black in color, while traces of iron or manganese can give limestone an off-white to yellow to red color. The density of limestone depends on its porosity, which varies from 0.1% for the densest limestone to 40% for chalk. The density correspondingly ranges from 1.5 to 2.7 g/cm . Although relatively soft, with

2465-420: Is controlled largely by the amount of dissolved carbon dioxide ( CO 2 ) in the water. This is summarized in the reaction: Increases in temperature or decreases in pressure tend to reduce the amount of dissolved CO 2 and precipitate CaCO 3 . Reduction in salinity also reduces the solubility of CaCO 3 , by several orders of magnitude for fresh water versus seawater. Near-surface water of

2550-545: Is converted to low-magnesium calcite. Diagenesis is the likely origin of pisoliths , concentrically layered particles ranging from 1 to 10 mm (0.039 to 0.394 inches) in diameter found in some limestones. Pisoliths superficially resemble ooids but have no nucleus of foreign matter, fit together tightly, and show other signs that they formed after the original deposition of the sediments. Silicification occurs early in diagenesis, at low pH and temperature, and contributes to fossil preservation. Silicification takes place through

2635-503: Is deposited close to where it formed, classification of limestone is usually based on its grain type and mud content. Most grains in limestone are skeletal fragments of marine organisms such as coral or foraminifera . These organisms secrete structures made of aragonite or calcite, and leave these structures behind when they die. Other carbonate grains composing limestones are ooids , peloids , and limeclasts ( intraclasts and extraclasts  [ ca ] ). Skeletal grains have

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2720-460: Is described as coquinite . Chalk is a soft, earthy, fine-textured limestone composed of the tests of planktonic microorganisms such as foraminifera, while marl is an earthy mixture of carbonates and silicate sediments. Limestone forms when calcite or aragonite precipitate out of water containing dissolved calcium, which can take place through both biological and nonbiological processes. The solubility of calcium carbonate ( CaCO 3 )

2805-617: Is described as micrite . In fresh carbonate mud, micrite is mostly small aragonite needles, which may precipitate directly from seawater, be secreted by algae, or be produced by abrasion of carbonate grains in a high-energy environment. This is converted to calcite within a few million years of deposition. Further recrystallization of micrite produces microspar , with grains from 5 to 15 μm (0.20 to 0.59 mils) in diameter. Limestone often contains larger crystals of calcite, ranging in size from 0.02 to 0.1 mm (0.79 to 3.94 mils), that are described as sparry calcite or sparite . Sparite

2890-462: Is distinguished from micrite by a grain size of over 20 μm (0.79 mils) and because sparite stands out under a hand lens or in thin section as white or transparent crystals. Sparite is distinguished from carbonate grains by its lack of internal structure and its characteristic crystal shapes. Geologists are careful to distinguish between sparite deposited as cement and sparite formed by recrystallization of micrite or carbonate grains. Sparite cement

2975-574: Is of international importance for 8 of its plant species and 69 of its vertebrate fauna. It has some 95 breeding species of birds, is also very important for a wide range of overwintering species, and serves as an essential stopover point for large numbers of migratory birds. The Ebro delta has the world's largest colony of Audouin's gulls . In 2006 it held a record number of more than 15,000 pairs, its highest to date. The introduction of American crayfish Procambarus clarkii has resulted in economic losses, introduced elsewhere for cultivation, its success

3060-560: Is one of the first minerals to precipitate in marine evaporites. Most limestone is formed by the activities of living organisms near reefs, but the organisms responsible for reef formation have changed over geologic time. For example, stromatolites are mound-shaped structures in ancient limestones, interpreted as colonies of cyanobacteria that accumulated carbonate sediments, but stromatolites are rare in younger limestones. Organisms precipitate limestone both directly as part of their skeletons, and indirectly by removing carbon dioxide from

3145-473: Is otherwise chemically fairly pure, with clastic sediments (mainly fine-grained quartz and clay minerals ) making up less than 5% to 10% of the composition. Organic matter typically makes up around 0.2% of a limestone and rarely exceeds 1%. Limestone often contains variable amounts of silica in the form of chert or siliceous skeletal fragments (such as sponge spicules, diatoms , or radiolarians ). Fossils are also common in limestone. Limestone

3230-472: Is produced by decaying organic matter settling into the deep ocean that is not removed by photosynthesis in the dark depths. As a result, there is a fairly sharp transition from water saturated with calcium carbonate to water unsaturated with calcium carbonate, the lysocline , which occurs at the calcite compensation depth of 4,000 to 7,000 m (13,000 to 23,000 feet). Below this depth, foraminifera tests and other skeletal particles rapidly dissolve, and

3315-427: Is related to the marine origin of the valley and the extensive marine deposits. Just as it enters Catalonia, the valley narrows, and the river becomes constrained by mountain ranges, making wide bends. 3 massive dams have been built in this area: Mequinenza dam ( Province of Zaragoza , 1955), Riba-roja dam (1955), and Flix dam (1948), the latter two in the province of Tarragona . In the final section of its course

3400-518: Is secondary dolomite, formed by chemical alteration of limestone. Limestone is exposed over large regions of the Earth's surface, and because limestone is slightly soluble in rainwater, these exposures often are eroded to become karst landscapes. Most cave systems are found in limestone bedrock. Limestone has numerous uses: as a chemical feedstock for the production of lime used for cement (an essential component of concrete ), as aggregate for

3485-517: Is the most important river in Spain in terms of length, 928 km (577 mi), and area of drainage basin, 85,550 km (33,030 sq mi). However, the mean annual flow decreased by approximately 29 percent during the 20th century due to many causes: the construction of dams, the increasing demands for irrigation and the evaporation (higher than the rainfall, due to low rainfall, high sunshine and strong and dry winds) from reservoirs in

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3570-478: The comarca of Montes de Oca , near the town of Rábanos. Near its source, the river passes through the narrow, rock-lined gorge of La Hoz. This passage, 700 metres (2,300 ft) long and 100 metres (330 ft) high, was of great strategic value in the 11th century and was defended by the castle of Alba. From the right , the Oca receives the waters of the river Matapán and the streams Valsorda and Penches, while on

3655-1261: The Mediterranean Sea , forming a delta in the Terres de l'Ebre region, in southern Catalonia . In the Iberian peninsula, it ranks second in length after the Tagus and second in discharge volume , and drainage basin , after the Douro . It is the longest river entirely within Spain; the other two mentioned flow into Portugal . The Ebro flows through many cities ( Spanish : ciudades ): Reinosa in Cantabria ; Frías and Miranda de Ebro in Castile and León ; Haro , Logroño , Calahorra , and Alfaro in La Rioja ; Tudela in Navarre ; Alagón , Utebo , and Zaragoza in Aragon ; and Flix , Móra d'Ebre , Benifallet , Tivenys , Xerta , Aldover , Tortosa , and Amposta in

3740-523: The Second Punic War . One of the earliest Cistercian monasteries in Spain, Real Monasterio de Nuestra Señora de Rueda ( lit.   ' Royal ' Monastery of Our Lady of the Wheel), is located on the banks of the Ebro in Aragon . Established in 1202, the edifice survives intact. The monastery is strongly connected to the Ebro, since it used one of the first large waterwheels built for

3825-484: The Terres de l'Ebre ('Ebro Lands') region, Catalonia , is at 340 km (130 sq mi), or 20km² less, one of the largest wetlands of the western Mediterranean. Designated a Ramsar site , it has entirely grown on soils washed downriver—the historical rate of growth of the delta is demonstrated by the town of Amposta . Recorded and thus confirmed as a seaport in the Roman Warm Period in

3910-690: The province of Tarragona ( Catalonia ). The source of the river Ebro is in the Cantabrian Mountains , in Fontibre , Cantabria ( Fontibre is from Latin Fontes Iberis , i.e. 'source of the Ebro'). Close by is a large artificial lake , Embalse del Ebro , created by its damming. The upper Ebro rushes through rocky gorges in Burgos Province . Flowing roughly eastwards it passes las conchas de Haro and begins forming

3995-459: The 4th century, it is now well inland from the mouths. The rounded form of the delta attests to the subsequent balance between sediment deposition by the Ebro and removal of this material by wave erosion . The modern delta is in intensive agricultural use for rice, fruit (in particular citrus), and vegetables. The Ebro delta also has numerous beaches, marshes, and salt pans that provide habitat for over 300 species of birds. The Ebro delta

4080-496: The Earth's history. Limestone may have been deposited by microorganisms in the Precambrian , prior to 540 million years ago, but inorganic processes were probably more important and likely took place in an ocean more highly oversaturated in calcium carbonate than the modern ocean. Diagenesis is the process in which sediments are compacted and turned into solid rock . During diagenesis of carbonate sediments, significant chemical and textural changes take place. For example, aragonite

4165-661: The Ebro that Wels catfish have not colonized were not affected. The ecology of the river also now has the problem of a major increase in aquatic vegetation, seaweed and algae. Limestone Limestone ( calcium carbonate CaCO 3 ) is a type of carbonate sedimentary rock which is the main source of the material lime . It is composed mostly of the minerals calcite and aragonite , which are different crystal forms of CaCO 3 . Limestone forms when these minerals precipitate out of water containing dissolved calcium. This can take place through both biological and nonbiological processes, though biological processes, such as

4250-701: The Wels catfish's introduction in the Mequinenza reservoir in 1974, it has spread to other parts of the Ebro and its tributaries, especially the Segre . Some endemics species of iberian barbels , genus Barbus in the Cyprinidae , have declined drastically, having once been abundant, especially in the Ebro. Competition and predation by Wels catfish caused its complete disappearance in the middle channel Ebro around 1990. Barbel species from mountain stream tributaries of

4335-430: The accumulation of corals and shells in the sea, have likely been more important for the last 540 million years. Limestone often contains fossils which provide scientists with information on ancient environments and on the evolution of life. About 20% to 25% of sedimentary rock is carbonate rock, and most of this is limestone. The remaining carbonate rock is mostly dolomite , a closely related rock, which contains

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4420-434: The base of roads, as white pigment or filler in products such as toothpaste or paint, as a soil conditioner , and as a popular decorative addition to rock gardens . Limestone formations contain about 30% of the world's petroleum reservoirs . Limestone is composed mostly of the minerals calcite and aragonite , which are different crystal forms of calcium carbonate ( CaCO 3 ). Dolomite , CaMg(CO 3 ) 2 ,

4505-657: The beds. This may include the formation of vugs , which are crystal-lined cavities within the limestone. Diagenesis may include conversion of limestone to dolomite by magnesium-rich fluids. There is considerable evidence of replacement of limestone by dolomite, including sharp replacement boundaries that cut across bedding. The process of dolomitization remains an area of active research, but possible mechanisms include exposure to concentrated brines in hot environments ( evaporative reflux ) or exposure to diluted seawater in delta or estuary environments ( Dorag dolomitization ). However, Dorag dolomitization has fallen into disfavor as

4590-839: The central Pyrenees and the Iberian System discharge large amounts of water, especially in spring during the thawing season of the mountain snow. The biomes are diverse in these Mediterranean climate zones: Mediterranean forests, woodlands, and scrub . Hinterlands are particularly distinctive on account of extensive sclerophyll shrublands known as maquis , or garrigues. The dominant species are Quercus coccifera (in drier areas) and Quercus ilex . These trees form monospecific communities or communities integrated with Pinus , Mediterranean buckthorns , Myrtus , Chamaerops humilis , junipers , Pistacia , Rosmarinus , Thymus , and so on. The hinterland climate becomes progressively more continental and drier, and therefore there

4675-538: The delta from 27 March 2007 to 11 April 2007, with an average of 117 million cubic metres (95,000 acre-feet) per day. Academics and local government have criticised ecological impacts of: In past times numerous lagoons , endorheic saltwater ponds , and freshwater swamps and marshes were drained, dried or filled. Almost entire riparian forests were cleared for crops or for pulpwood forest plantations. Due to these changes numerous plant and animal species have disappeared. Due to dams and hydraulic canalization,

4760-466: The depositional fabric of carbonate rocks. Dunham divides the rocks into four main groups based on relative proportions of coarser clastic particles, based on criteria such as whether the grains were originally in mutual contact, and therefore self-supporting, or whether the rock is characterized by the presence of frame builders and algal mats. Unlike the Folk scheme, Dunham deals with the original porosity of

4845-469: The deposits are highly porous, so that they have a spongelike texture, they are typically described as tufa . Secondary calcite deposited by supersaturated meteoric waters ( groundwater ) in caves is also sometimes described as travertine. This produces speleothems , such as stalagmites and stalactites . Coquina is a poorly consolidated limestone composed of abraded pieces of coral , shells , or other fossil debris. When better consolidated, it

4930-659: The dividing line between Roman (north) and Carthaginian (south) expansions after the First Punic War (264–241 BC). When the Roman Republic , fearful of Hannibal 's growing influence in the Iberian Peninsula, made the city of Saguntum (considerably south of the Ebro) a protectorate of Rome, Hannibal viewed the treaty violation as an aggressive action by Rome and used the event as the catalyst to

5015-407: The dynamics of the river have been altered and new scroll-bars , new oxbow lakes , and new abandoned meanders will not now be created. Over a period of time, many of these phenomena tend to dry out or fill in with sediments. Some small representatives of these river dynamics and wetlands are protected. The Ebro Delta Natural Park, covering 7,802 hectares (19,280 acres), was finalised in 1986 and

5100-406: The earth's oceans are oversaturated with CaCO 3 by a factor of more than six. The failure of CaCO 3 to rapidly precipitate out of these waters is likely due to interference by dissolved magnesium ions with nucleation of calcite crystals, the necessary first step in precipitation. Precipitation of aragonite may be suppressed by the presence of naturally occurring organic phosphates in

5185-599: The ecologic and economic resources of the delta. The Greeks called the river Ἴβηρ ( Ibēr ), abir , ah'ir and the Romans called it the Hibēr , Ibēr , or Ibērus flūmen , leading to its current name. The Iberian Peninsula and the Hibērī or Ibērī (the people of the area) were named after the river. It is not known with any certainty whether the Greeks used a local native name for

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5270-399: The first refers to the grains and the second to the cement. For example, a limestone consisting mainly of ooids, with a crystalline matrix, would be termed an oosparite. It is helpful to have a petrographic microscope when using the Folk scheme, because it is easier to determine the components present in each sample. Robert J. Dunham published his system for limestone in 1962. It focuses on

5355-572: The formation of distinctive minerals from the silica and clay present in the original limestone. Two major classification schemes, the Folk and Dunham, are used for identifying the types of carbonate rocks collectively known as limestone. Robert L. Folk developed a classification system that places primary emphasis on the detailed composition of grains and interstitial material in carbonate rocks . Based on composition, there are three main components: allochems (grains), matrix (mostly micrite), and cement (sparite). The Folk system uses two-part names;

5440-429: The geologic record are called bioherms . Many are rich in fossils, but most lack any connected organic framework like that seen in modern reefs. The fossil remains are present as separate fragments embedded in ample mud matrix. Much of the sedimentation shows indications of occurring in the intertidal or supratidal zones, suggesting sediments rapidly fill available accommodation space in the shelf or platform. Deposition

5525-419: The huge Wels catfish . The zebra mussel , an invasive species , is expanding upstream in the Ebro's waters. Due to its rapid rate of reproduction, the species adversely affects the port's underwater machinery as well as that of dams and hydroelectric plants, in addition to competing with native species. Following the introduction of Wels catfish, many fish species' numbers are in clear and rapid decline. Since

5610-606: The left it receives the waters of the rivers Cerratón, Anguilas and Homino, and the streams Valdazo and Hoyo. Ebro The Ebro ( Spanish and Basque [ˈeβɾo] ; Catalan : Ebre , Western: [ˈeβɾe] , Eastern: [ˈeβɾə] ) is a river of the north and northeast of the Iberian Peninsula , in Spain . It rises in Cantabria and flows 930 kilometres (580 mi), almost entirely in an east-southeast direction. It flows into

5695-407: The mouth. In addition to decreased mean annual flow, the increased river regulation in the Ebro basin has produced daily and seasonal changes in the flow pattern. With regards to the sediment load, several authors conclude that the sediment load was reduced by more than 99 percent during the last century. The drastic reduction in sediment transport implies a sediment deficit in the delta, which

5780-410: The ocean basins, but limestone is rarely preserved in continental slope and deep sea environments. The best environments for deposition are warm waters, which have both a high organic productivity and increased saturation of calcium carbonate due to lower concentrations of dissolved carbon dioxide. Modern limestone deposits are almost always in areas with very little silica-rich sedimentation, reflected in

5865-671: The production of power in Spain. The monastery also diverted flow from the Ebro to create a circulating, hydrological central heating system for its buildings. The Ebro in 1938 was the starting ground of one of the most famous Republican offensives of the Spanish Civil War . Known as the Battle of the Ebro , the offensive ended in defeat for the Republican forces, although they enjoyed success in its first stages. They were not able to reach their objective of Gandesa . The Ebro

5950-426: The reaction: Fossils are often preserved in exquisite detail as chert. Cementing takes place rapidly in carbonate sediments, typically within less than a million years of deposition. Some cementing occurs while the sediments are still under water, forming hardgrounds . Cementing accelerates after the retreat of the sea from the depositional environment, as rainwater infiltrates the sediment beds, often within just

6035-482: The relative purity of most limestones. Reef organisms are destroyed by muddy, brackish river water, and carbonate grains are ground down by much harder silicate grains. Unlike clastic sedimentary rock, limestone is produced almost entirely from sediments originating at or near the place of deposition. Limestone formations tend to show abrupt changes in thickness. Large moundlike features in a limestone formation are interpreted as ancient reefs , which when they appear in

6120-421: The river basins. This situation has a direct impact on the deltaic system at the mouth of the river because its hydrological dynamics are mainly controlled by the river discharge. The decrease in river discharge has meant introduction of the salt wedge further into the river. The mean annual river flow is approximately the critical flow which determines the formation and the break-up of the salt wedge. Thus, when

6205-614: The river bends southwards and flows through spectacular gorges. The calcareous cliffs and high, rocky hills of the Serra de Cardó almost abut the river separating the Mediterranean coastal strip. After passing the gorges, the Ebro bends again eastwards near Tortosa before discharging in a delta on the Mediterranean Sea close to Amposta in the province of Tarragona . The Ebro Delta (Catalan: Delta de l'Ebre ), in

6290-479: The river discharge is between 300 and 400 m /s (11,000 and 14,000 cu ft/s), the salt wedge can occupy the last 5 km (3 mi) of the estuary, but when the discharge is between 100 and 300 m /s (3,500 and 10,600 cu ft/s), the salt wedge can advance up to 18 km (11 mi) from the mouth. For less than 100 m /s (3,500 cu ft/s), the salt wedge quickly advances to its maximum extent, reaching 32 km (20 mi) from

6375-519: The river. Nor is it known what the word " Ibēr " or " Hibēr " might mean. In modern Basque the word ibar means 'valley' or 'watered meadow', while ibai means 'river', but there is no proof relating the etymology of the Ebro River with these Basque words. There are rivers in the Balkans called Ibar (Montenegro and Serbia) and Evros (Bulgaria and Greece). In antiquity , the Ebro was used as

6460-460: The rock. The Dunham scheme is more useful for hand samples because it is based on texture, not the grains in the sample. A revised classification was proposed by Wright (1992). It adds some diagenetic patterns to the classification scheme. Travertine is a term applied to calcium carbonate deposits formed in freshwater environments, particularly waterfalls , cascades and hot springs . Such deposits are typically massive, dense, and banded. When

6545-479: The sediments increases. Chemical compaction takes place by pressure solution of the sediments. This process dissolves minerals from points of contact between grains and redeposits it in pore space, reducing the porosity of the limestone from an initial high value of 40% to 80% to less than 10%. Pressure solution produces distinctive stylolites , irregular surfaces within the limestone at which silica-rich sediments accumulate. These may reflect dissolution and loss of

6630-662: The sediments of the ocean floor abruptly transition from carbonate ooze rich in foraminifera and coccolith remains ( Globigerina ooze) to silicic mud lacking carbonates. In rare cases, turbidites or other silica-rich sediments bury and preserve benthic (deep ocean) carbonate deposits. Ancient benthic limestones are microcrystalline and are identified by their tectonic setting. Fossils typically are foraminifera and coccoliths. No pre-Jurassic benthic limestones are known, probably because carbonate-shelled plankton had not yet evolved. Limestones also form in freshwater environments. These limestones are not unlike marine limestone, but have

6715-472: The southern slopes of the Pyrenees mountains, which run along the border with France . All of Andorra's drainage basin is in the Ebro, through the Segre . Downstream from Cantabria the climate in the Ebro basin – the valley being isolated from sea air masses by surrounding mountains – becomes Mediterranean/Atlantic influenced and continental . This implies summer/winter seasonal contrast and

6800-465: The surface is organically poor and quick-draining: calcareous, pebbly, stony layers. These are in places salt-rich, seeing some saltwater endorheic lagoons. Karst geological processes shaped the landscape of layers of soluble carbonate rock of extensive limestone bedrock formed in an ancient seabed. The valley expands and the Ebro's flow then becomes slower as its water volume increases, flowing across Aragon. There, larger tributaries flowing from

6885-417: The temperatures often drop below 0 °C (32 °F). In some areas the vegetation depends heavily on moisture produced by condensation fog . It is a continental Mediterranean climate with extreme temperatures. There are many ground frosts on clear nights, and sporadic snowfalls . The natural topsoils across the plains are, outside of historically well-forested zones, thin. The subsoil being close to

6970-533: The water by photosynthesis and thereby decreasing the solubility of calcium carbonate. Limestone shows the same range of sedimentary structures found in other sedimentary rocks. However, finer structures, such as lamination , are often destroyed by the burrowing activities of organisms ( bioturbation ). Fine lamination is characteristic of limestone formed in playa lakes , which lack the burrowing organisms. Limestones also show distinctive features such as geopetal structures , which form when curved shells settle to

7055-553: The water. Although ooids likely form through purely inorganic processes, the bulk of CaCO 3 precipitation in the oceans is the result of biological activity. Much of this takes place on carbonate platforms . The origin of carbonate mud, and the processes by which it is converted to micrite, continue to be a subject of research. Modern carbonate mud is composed mostly of aragonite needles around 5 μm (0.20 mils) in length. Needles of this shape and composition are produced by calcareous algae such as Penicillus , making this

7140-493: Was classified as a wetland area of international interest by Spain's Bureau Mar in 1962. Since a phased-introduction law (1983 to 1986) Spain has designated 7,736 hectares (29.87 sq mi) as the Ebro Delta Natural Park (Catalan: Parc Natural del Delta de l'Ebre ) to protect its natural resources. A network of canals and irrigation ditches dug by agricultural and conservation groups help to maintain

7225-416: Was likely deposited in pore space between grains, suggesting a high-energy depositional environment that removed carbonate mud. Recrystallized sparite is not diagnostic of depositional environment. Limestone outcrops are recognized in the field by their softness (calcite and aragonite both have a Mohs hardness of less than 4, well below common silicate minerals) and because limestone bubbles vigorously when

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