115-546: Libbey-Owens-Ford Company (LOF) was a producer of flat glass for the automotive and building products industries both for original equipment manufacturers and for replacement use. The company's headquarters and main factories were located in Toledo, Ohio , with large float glass plants in Rossford , Ohio , Laurinburg , North Carolina , Ottawa , Illinois , Shreveport , Louisiana , and Lathrop , California . The company
230-455: A diffraction limited system, which has an increased depth of field, similar to using a small aperture in photography. This form of correction has many limitations that prevent it from gaining popularity in everyday use. Pinhole glasses can be made in a DIY fashion by making small holes in a piece of card which is then held in front of the eyes with a strap or cardboard arms. Glasses may also house other corrective or assistive devices. After
345-405: A glass (or vitreous solid) is a non-crystalline solid formed by rapid melt quenching . However, the term "glass" is often defined in a broader sense, to describe any non-crystalline ( amorphous ) solid that exhibits a glass transition when heated towards the liquid state. Glass is an amorphous solid . Although the atomic-scale structure of glass shares characteristics of the structure of
460-436: A supercooled liquid , glass exhibits all the mechanical properties of a solid. As in other amorphous solids , the atomic structure of a glass lacks the long-range periodicity observed in crystalline solids . Due to chemical bonding constraints, glasses do possess a high degree of short-range order with respect to local atomic polyhedra . The notion that glass flows to an appreciable extent over extended periods well below
575-809: A turquoise colour in glass, in contrast to copper(I) oxide (Cu 2 O) which gives a dull red-brown colour. Soda–lime sheet glass is typically used as a transparent glazing material, typically as windows in external walls of buildings. Float or rolled sheet glass products are cut to size either by scoring and snapping the material, laser cutting , water jets , or diamond-bladed saw. The glass may be thermally or chemically tempered (strengthened) for safety and bent or curved during heating. Surface coatings may be added for specific functions such as scratch resistance, blocking specific wavelengths of light (e.g. infrared or ultraviolet ), dirt-repellence (e.g. self-cleaning glass ), or switchable electrochromic coatings. Structural glazing systems represent one of
690-545: A Libbey-Owens sheet glass plant opened in Shreveport, Louisiana, becoming both the city's largest manufacturer and employer. This plant converted operations between 1972 and 1974 to Libbey Glass table-glassware manufacturing, which it continues today. In 1928, Libbey-Owens was the first company to produce automotive laminated safety glass and won a contract to supply the Ford Motor Company with windshields for
805-410: A circular lens called a lens blank. Lens blanks are cut to fit the shape of the frame that will hold them. Frame styles vary and fashion trends change over time, resulting in a multitude of lens shapes. For lower power lenses, there are few restrictions, allowing for many trendy and fashionable shapes. Higher power lenses can distort peripheral vision and may become thick and heavy if a large lens shape
920-485: A clear "ring" sound when struck. However, lead glass cannot withstand high temperatures well. Lead oxide also facilitates the solubility of other metal oxides and is used in coloured glass. The viscosity decrease of lead glass melt is very significant (roughly 100 times in comparison with soda glass); this allows easier removal of bubbles and working at lower temperatures, hence its frequent use as an additive in vitreous enamels and glass solders . The high ionic radius of
1035-529: A full-sized welding helmet is inconvenient or uncomfortable. These are often called "flash goggles" because they provide protection from welding flash. Nylon frames are usually used for protective eyewear for sports because of their lightweight and flexible properties. Unlike most regular glasses, safety glasses often include protection beside the eyes as well as in front of the eyes. Sunglasses provide more comfort and protection against bright light and often against ultraviolet (UV) light. To properly protect
1150-443: A green tint in thick sections. Manganese dioxide (MnO 2 ), which gives glass a purple colour, may be added to remove the green tint given by FeO. FeO and chromium(III) oxide (Cr 2 O 3 ) additives are used in the production of green bottles. Iron (III) oxide , on the other-hand, produces yellow or yellow-brown glass. Low concentrations (0.025 to 0.1%) of cobalt oxide (CoO) produce rich, deep blue cobalt glass . Chromium
1265-408: A human timescale. Silicon dioxide (SiO 2 ) is a common fundamental constituent of glass. Fused quartz is a glass made from chemically pure silica. It has very low thermal expansion and excellent resistance to thermal shock , being able to survive immersion in water while red hot, resists high temperatures (1000–1500 °C) and chemical weathering, and is very hard. It is also transparent to
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#17327806255621380-405: A lighter alternative to traditional glass. Molecular liquids, electrolytes , molten salts , and aqueous solutions are mixtures of different molecules or ions that do not form a covalent network but interact only through weak van der Waals forces or transient hydrogen bonds . In a mixture of three or more ionic species of dissimilar size and shape, crystallization can be so difficult that
1495-561: A long period at a temperature just insufficient to cause fusion. In this way, the crystalline, devitrified material, known as Réaumur's glass porcelain is produced. Although generally transparent to visible light, glasses may be opaque to other wavelengths of light . While silicate glasses are generally opaque to infrared wavelengths with a transmission cut-off at 4 μm, heavy-metal fluoride and chalcogenide glasses are transparent to infrared wavelengths of 7 to 18 μm. The addition of metallic oxides results in different coloured glasses as
1610-482: A mass of hot semi-molten glass, inflating it into a bubble using a hollow blowpipe, and forming it into the required shape by blowing, swinging, rolling, or moulding. While hot, the glass can be worked using hand tools, cut with shears, and additional parts such as handles or feet attached by welding. Flat glass for windows and similar applications is formed by the float glass process, developed between 1953 and 1957 by Sir Alastair Pilkington and Kenneth Bickerstaff of
1725-453: A non-crystalline intergranular phase of grain boundaries . Glass-ceramics exhibit advantageous thermal, chemical, biological, and dielectric properties as compared to metals or organic polymers. The most commercially important property of glass-ceramics is their imperviousness to thermal shock. Thus, glass-ceramics have become extremely useful for countertop cooking and industrial processes. The negative thermal expansion coefficient (CTE) of
1840-401: A plastic resin with glass fibres . It is made by melting glass and stretching the glass into fibres. These fibres are woven together into a cloth and left to set in a plastic resin. Fibreglass has the properties of being lightweight and corrosion resistant and is a good insulator enabling its use as building insulation material and for electronic housing for consumer products. Fibreglass
1955-480: A recent ophthalmic prescription are required. People who need glasses to see often have corrective lens restrictions on their driver's licenses that require them to wear their glasses every time they drive or risk fines or jail time. Some militaries issue prescription glasses to servicemen and women. These are typically GI glasses . Many state prisons in the United States issue glasses to inmates, often in
2070-462: A refractive index of 1.4 to 2.4, and an Abbe number (which characterises dispersion) of 15 to 100. The refractive index may be modified by high-density (refractive index increases) or low-density (refractive index decreases) additives. Glass transparency results from the absence of grain boundaries which diffusely scatter light in polycrystalline materials. Semi-opacity due to crystallization may be induced in many glasses by maintaining them for
2185-432: A separate set of glasses for focusing on close by objects. Reading glasses are available without prescription from drugstores , and offer a cheap, practical solution, though these have a pair of simple lenses of equal power, and so will not correct refraction problems like astigmatism or refractive or prismatic variations between the left and right eye. For the total correction of the individual's sight, glasses complying to
2300-412: A spinning metal disk. Several alloys have been produced in layers with thicknesses exceeding 1 millimetre. These are known as bulk metallic glasses (BMG). Liquidmetal Technologies sells several zirconium -based BMGs. Batches of amorphous steel have also been produced that demonstrate mechanical properties far exceeding those found in conventional steel alloys. Experimental evidence indicates that
2415-700: A strap to prevent the glasses from falling off. Wearers of glasses that are used only part of the time may have the glasses attached to a cord that goes around their neck to prevent the loss and breaking of the glasses. Sunglasses allow for better vision in bright daylight and are used to protect one's eyes against damage from excessive levels of ultraviolet light . Typical sunglasses lenses are tinted for protection against bright light or polarized to remove glare; photochromic glasses are clear or lightly tinted in dark or indoor conditions, but turn into sunglasses when they come into contact with ultraviolet light. Most over-the-counter sunglasses do not have corrective power in
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#17327806255622530-435: A structural analogue of silica, fluoride , aluminate , phosphate , borate , and chalcogenide glasses) have physicochemical properties useful for their application in fibre-optic waveguides in communication networks and other specialised technological applications. Silica-free glasses may often have poor glass-forming tendencies. Novel techniques, including containerless processing by aerodynamic levitation (cooling
2645-413: A structurally metastable state with respect to its crystalline form, although in certain circumstances, for example in atactic polymers, there is no crystalline analogue of the amorphous phase. Glass is sometimes considered to be a liquid due to its lack of a first-order phase transition where certain thermodynamic variables such as volume , entropy and enthalpy are discontinuous through
2760-650: A wide range of fashions are available, using plastic, metal, wire, and other materials for frames. Glasses can be marked or found by their primary function, but also appear in combinations such as prescription sunglasses or safety glasses with enhanced magnification. Corrective lenses are used to correct refractive errors by bending the light entering the eye in order to alleviate the effects of conditions such as nearsightedness (myopia) , farsightedness (hypermetropia) or astigmatism . The ability of one's eyes to accommodate their focus to near and distant focus alters over time. A common condition in people over forty years old
2875-521: A wider spectral range than ordinary glass, extending from the visible further into both the UV and IR ranges, and is sometimes used where transparency to these wavelengths is necessary. Fused quartz is used for high-temperature applications such as furnace tubes, lighting tubes, melting crucibles, etc. However, its high melting temperature (1723 °C) and viscosity make it difficult to work with. Therefore, normally, other substances (fluxes) are added to lower
2990-404: Is presbyopia , which is caused by the eye's crystalline lens losing elasticity, progressively reducing the ability of the lens to accommodate (i.e. to focus on objects close to the eye). Few people have a pair of eyes that show exactly equal refractive characteristics; one eye may need a "stronger" (i.e. more refracting) lens than the other. Corrective lenses bring the image back into focus on
3105-455: Is "single vision", which has a uniform refractive index . For people with presbyopia and hyperopia , bifocal and trifocal glasses provide two or three different refractive indices, respectively, and progressive lenses have a continuous gradient. Lenses can also be manufactured with high refractive indices, which allow them to be more lightweight and thinner than their counterparts with "low" refractive indices. Reading glasses provide
3220-418: Is 3.25 × 10 /°C as compared to about 9 × 10 /°C for a typical soda–lime glass ). They are, therefore, less subject to stress caused by thermal expansion and thus less vulnerable to cracking from thermal shock . They are commonly used for e.g. labware , household cookware , and sealed beam car head lamps . The addition of lead(II) oxide into silicate glass lowers the melting point and viscosity of
3335-552: Is a common volcanic glass with high silica (SiO 2 ) content formed when felsic lava extruded from a volcano cools rapidly. Impactite is a form of glass formed by the impact of a meteorite , where Moldavite (found in central and eastern Europe), and Libyan desert glass (found in areas in the eastern Sahara , the deserts of eastern Libya and western Egypt ) are notable examples. Vitrification of quartz can also occur when lightning strikes sand , forming hollow, branching rootlike structures called fulgurites . Trinitite
3450-714: Is a glassy residue formed from the desert floor sand at the Trinity nuclear bomb test site. Edeowie glass , found in South Australia , is proposed to originate from Pleistocene grassland fires, lightning strikes, or hypervelocity impact by one or several asteroids or comets . Naturally occurring obsidian glass was used by Stone Age societies as it fractures along very sharp edges, making it ideal for cutting tools and weapons. Glassmaking dates back at least 6000 years, long before humans had discovered how to smelt iron. Archaeological evidence suggests that
3565-418: Is a very powerful colouring agent, yielding dark green. Sulphur combined with carbon and iron salts produces amber glass ranging from yellowish to almost black. A glass melt can also acquire an amber colour from a reducing combustion atmosphere. Cadmium sulfide produces imperial red , and combined with selenium can produce shades of yellow, orange, and red. Addition of copper(II) oxide (CuO) produces
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3680-449: Is achieved by homogenizing the raw materials mixture ( glass batch ), stirring the melt, and crushing and re-melting the first melt. The obtained glass is usually annealed to prevent breakage during processing. Colour in glass may be obtained by addition of homogenously distributed electrically charged ions (or colour centres ). While ordinary soda–lime glass appears colourless in thin section, iron(II) oxide (FeO) impurities produce
3795-413: Is also known to have written on the magnifying properties of lenses. The development of the first eyeglasses took place in northern Italy in the second half of the 13th century. Independently of the development of optical lenses, some cultures developed " sunglasses " for eye protection, without any corrective properties. For example, flat panes of smoky quartz were used in 12th-century China , and
3910-676: Is extensively used for fibreglass , used for making glass-reinforced plastics (boats, fishing rods, etc.), top-of-stove cookware, and halogen bulb glass. The addition of barium also increases the refractive index. Thorium oxide gives glass a high refractive index and low dispersion and was formerly used in producing high-quality lenses, but due to its radioactivity has been replaced by lanthanum oxide in modern eyeglasses. Iron can be incorporated into glass to absorb infrared radiation, for example in heat-absorbing filters for movie projectors, while cerium(IV) oxide can be used for glass that absorbs ultraviolet wavelengths. Fluorine lowers
4025-517: Is filtered so that each eye receives a slightly different image. The filters only work for the type of signal they were designed for. Anaglyph 3D glasses have a different colored filter for each eye, typically red and blue or red and green. A polarized 3D system on the other hand uses polarized filters. Polarized 3D glasses allow for color 3D, while the red-blue lenses produce an image with distorted coloration. An active shutter 3D system uses electronic shutters . Head-mounted displays can filter
4140-455: Is in widespread use in optical systems due to its ability to refract, reflect, and transmit light following geometrical optics . The most common and oldest applications of glass in optics are as lenses , windows , mirrors , and prisms . The key optical properties refractive index , dispersion , and transmission , of glass are strongly dependent on chemical composition and, to a lesser degree, its thermal history. Optical glass typically has
4255-489: Is incorrect, as once solidified, glass stops flowing. The sags and ripples observed in old glass were already there the day it was made; manufacturing processes used in the past produced sheets with imperfect surfaces and non-uniform thickness (the near-perfect float glass used today only became widespread in the 1960s). A 2017 study computed the rate of flow of the medieval glass used in Westminster Abbey from
4370-549: Is most often formed by rapid cooling ( quenching ) of the molten form. Some glasses such as volcanic glass are naturally occurring, and obsidian has been used to make arrowheads and knives since the Stone Age . Archaeological evidence suggests glassmaking dates back to at least 3600 BC in Mesopotamia , Egypt , or Syria . The earliest known glass objects were beads , perhaps created accidentally during metalworking or
4485-439: Is no measurable UV light from computer monitors. The problem of computer vision syndrome (CVS) can result from focusing the eyes on a screen for long, continuous periods. Many times the glasses do not appear to have much of a tint, or, if any, a slight yellow tint, but they may be more heavily tinted. Long hours of computer use (not blue light) may cause eye strain. Many eye symptoms caused by computer use will lessen after
4600-404: Is not yet twenty years since there was found the art of making eyeglasses, which make for good vision ... And it is so short a time that this new art, never before extant, was discovered. ... I saw the one who first discovered and practiced it, and I talked to him." Giordano's colleague Friar Alessandro della Spina of Pisa (d. 1313) was soon making eyeglasses. The Ancient Chronicle of
4715-901: Is produced by forcing molten glass through a fine mesh by centripetal force and breaking the extruded glass fibres into short lengths using a stream of high-velocity air. The fibres are bonded with an adhesive spray and the resulting wool mat is cut and packed in rolls or panels. Besides common silica-based glasses many other inorganic and organic materials may also form glasses, including metals , aluminates , phosphates , borates , chalcogenides , fluorides , germanates (glasses based on GeO 2 ), tellurites (glasses based on TeO 2 ), antimonates (glasses based on Sb 2 O 3 ), arsenates (glasses based on As 2 O 3 ), titanates (glasses based on TiO 2 ), tantalates (glasses based on Ta 2 O 5 ), nitrates , carbonates , plastics , acrylic , and many other substances. Some of these glasses (e.g. Germanium dioxide (GeO 2 , Germania), in many respects
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4830-461: Is stronger than most metals, with a theoretical tensile strength for pure, flawless glass estimated at 14 to 35 gigapascals (2,000,000 to 5,100,000 psi) due to its ability to undergo reversible compression without fracture. However, the presence of scratches, bubbles, and other microscopic flaws lead to a typical range of 14 to 175 megapascals (2,000 to 25,400 psi) in most commercial glasses. Several processes such as toughening can increase
4945-408: Is sufficiently rapid (relative to the characteristic crystallization time) then crystallization is prevented and instead, the disordered atomic configuration of the supercooled liquid is frozen into the solid state at T g . The tendency for a material to form a glass while quenched is called glass-forming ability. This ability can be predicted by the rigidity theory . Generally, a glass exists in
5060-436: Is transparent, easily formed, and most suitable for window glass and tableware. However, it has a high thermal expansion and poor resistance to heat. Soda–lime glass is typically used for windows , bottles , light bulbs , and jars . Borosilicate glasses (e.g. Pyrex , Duran ) typically contain 5–13% boron trioxide (B 2 O 3 ). Borosilicate glasses have fairly low coefficients of thermal expansion (7740 Pyrex CTE
5175-404: Is used. However, if the lens is too small, it can drastically reduce the field of view. Bifocal , trifocal , and progressive lenses generally require a taller lens shape to leave room for the different segments while preserving an adequate field of view through each segment. Frames with rounded edges are the most efficient for correcting myopic prescriptions, with perfectly round frames being
5290-454: The College of Optometrists (UK) is that "the best scientific evidence currently available does not support the use of blue-blocking spectacle lenses in the general population to improve visual performance, alleviate the symptoms of eye fatigue or visual discomfort, improve sleep quality or conserve macula health." The ophthalmic frame is the part of a pair of glasses that is designed to hold
5405-635: The Inuit have used snow goggles for eye protection. The earliest recorded comment on the use of lenses for optical purposes was made in 1268 by Roger Bacon . The first eyeglasses were estimated to have been made in Central Italy , most likely in Pisa or Florence , by about 1290: In a sermon delivered on 23 February 1306, the Dominican friar Giordano da Pisa ( c. 1255 –1311) wrote "It
5520-524: The Late Bronze Age , there was a rapid growth in glassmaking technology in Egypt and Western Asia . Archaeological finds from this period include coloured glass ingots , vessels, and beads. Much early glass production relied on grinding techniques borrowed from stoneworking , such as grinding and carving glass in a cold state. The term glass has its origins in the late Roman Empire , in
5635-671: The Model A . Libbey-Owens merged with the Edward Ford Plate Glass Company in 1930 to form Libbey-Owens-Ford Glass Company. In April 1986, LOF sold its glass business and name to the Pilkington Group , a multinational glass manufacturer headquartered in the United Kingdom . The remaining three business units of the company, Aeroquip, Vickers, and Sterling, were retained and the holding company
5750-535: The Renaissance period in Europe, the use of large stained glass windows became much less prevalent, although stained glass had a major revival with Gothic Revival architecture in the 19th century. During the 13th century, the island of Murano , Venice , became a centre for glass making, building on medieval techniques to produce colourful ornamental pieces in large quantities. Murano glass makers developed
5865-537: The Roman glass making centre at Trier (located in current-day Germany) where the late-Latin term glesum originated, likely from a Germanic word for a transparent , lustrous substance. Glass objects have been recovered across the Roman Empire in domestic, funerary , and industrial contexts, as well as trade items in marketplaces in distant provinces. Examples of Roman glass have been found outside of
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#17327806255625980-465: The dielectric constant of glass. Fluorine is highly electronegative and lowers the polarizability of the material. Fluoride silicate glasses are used in the manufacture of integrated circuits as an insulator. Glass-ceramic materials contain both non-crystalline glass and crystalline ceramic phases. They are formed by controlled nucleation and partial crystallisation of a base glass by heat treatment. Crystalline grains are often embedded within
6095-436: The glass batch preparation and mixing, the raw materials are transported to the furnace. Soda–lime glass for mass production is melted in glass-melting furnaces . Smaller-scale furnaces for speciality glasses include electric melters, pot furnaces, and day tanks. After melting, homogenization and refining (removal of bubbles), the glass is formed . This may be achieved manually by glassblowing , which involves gathering
6210-457: The "night mode" of different operating systems, which can usually be activated outside of nighttime hours. The American Academy of Ophthalmology (AAO) does not recommend special eyewear for computer use, although it recommends using prescription glasses measured specifically for computer screen distance (depending on individuals, but possibly 20–26 inches from the face), which are not the same as "blue-light blocking" glasses. The position of
6325-510: The 10th century onwards, glass was employed in stained glass windows of churches and cathedrals , with famous examples at Chartres Cathedral and the Basilica of Saint-Denis . By the 14th century, architects were designing buildings with walls of stained glass such as Sainte-Chapelle , Paris, (1203–1248) and the East end of Gloucester Cathedral . With the change in architectural style during
6440-585: The 12th century, coinciding with the development of " reading stones ". There are claims that single lens magnifying glasses were being used in China during the Northern Song dynasty (960–1127). Robert Grosseteste 's treatise De iride ( On the Rainbow ), written between 1220 and 1235, mentions using optics to "read the smallest letters at incredible distances". A few years later in 1262, Roger Bacon
6555-526: The 1930s to assist people bedbound by chronic illness or spinal injury, recumbent glasses have more recently been marketed not simply as an assistive device but also as 'lazy glasses'. They do not assist with vision, although they can be worn over regular corrective glasses. Yellow-tinted glasses are a type of glasses with a minor yellow tint. They perform a slight color correction, on top of reducing eyestrain from lack of blinking. They may also be considered minor corrective non-prescription glasses. Depending on
6670-461: The 1930s, which later became known as Depression glass . In the 1950s, Pilkington Bros. , England , developed the float glass process, producing high-quality distortion-free flat sheets of glass by floating on molten tin . Modern multi-story buildings are frequently constructed with curtain walls made almost entirely of glass. Laminated glass has been widely applied to vehicles for windscreens. Optical glass for spectacles has been used since
6785-593: The Dominican Monastery of St. Catherine in Pisa records: "Eyeglasses, having first been made by someone else, who was unwilling to share them, he [Spina] made them and shared them with everyone with a cheerful and willing heart." Venice quickly became an important center of manufacture, especially due to using the high-quality glass made at Murano . By 1301, there were guild regulations in Venice governing
6900-687: The Middle Ages. The production of lenses has become increasingly proficient, aiding astronomers as well as having other applications in medicine and science. Glass is also employed as the aperture cover in many solar energy collectors. In the 21st century, glass manufacturers have developed different brands of chemically strengthened glass for widespread application in touchscreens for smartphones , tablet computers , and many other types of information appliances . These include Gorilla Glass , developed and manufactured by Corning , AGC Inc. 's Dragontrail and Schott AG 's Xensation. Glass
7015-543: The Pb ion renders it highly immobile and hinders the movement of other ions; lead glasses therefore have high electrical resistance, about two orders of magnitude higher than soda–lime glass (10 vs 10 Ω⋅cm, DC at 250 °C). Aluminosilicate glass typically contains 5–10% alumina (Al 2 O 3 ). Aluminosilicate glass tends to be more difficult to melt and shape compared to borosilicate compositions but has excellent thermal resistance and durability. Aluminosilicate glass
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#17327806255627130-533: The UK's Pilkington Brothers, who created a continuous ribbon of glass using a molten tin bath on which the molten glass flows unhindered under the influence of gravity. The top surface of the glass is subjected to nitrogen under pressure to obtain a polished finish. Container glass for common bottles and jars is formed by blowing and pressing methods. This glass is often slightly modified chemically (with more alumina and calcium oxide) for greater water resistance. Once
7245-719: The action of water, making it an ideal material for the manufacture of containers for foodstuffs and most chemicals. Nevertheless, although usually highly resistant to chemical attack, glass will corrode or dissolve under some conditions. The materials that make up a particular glass composition affect how quickly the glass corrodes. Glasses containing a high proportion of alkali or alkaline earth elements are more susceptible to corrosion than other glass compositions. The density of glass varies with chemical composition with values ranging from 2.2 grams per cubic centimetre (2,200 kg/m ) for fused silica to 7.2 grams per cubic centimetre (7,200 kg/m ) for dense flint glass. Glass
7360-646: The assets of Illinois Glass Co. of Alton, Illinois, and renamed itself the Owens-Illinois Glass Co., making it the largest glass company in the world. Owens-Illinois Glass Company acquired Libbey Glass Company in 1935, but spun it off as a separate company in 1993. In June 1916, the Libbey-Owens Sheet Glass Company was organized, and in 1917 the first Libbey-Owens plant opened in Charleston, West Virginia. In 1922,
7475-408: The basic fixed frame with another pair of lenses (optional), that are connected by four-bar linkage . For example, sun lenses could be easily lifted up and down while mixed with myopia lenses that always stay on. Presbyopia lenses could be also combined and easily removed from the field of view if needed without taking off glasses. These glasses are often used for drivers going through tunnels, with
7590-517: The cardinal Hugh de Saint-Cher reading in a scriptorium . Another early example would be a depiction of eyeglasses found north of the Alps in an altarpiece of the church of Bad Wildungen , Germany, in 1403. These early glasses had convex lenses that could correct both hyperopia (farsightedness), and the presbyopia that commonly develops as a symptom of aging . Although concave lenses for myopia (near-sightedness) had made their first appearance in
7705-764: The company, these computer or gaming glasses can also filter out high energy blue and ultra-violet light from LCD screens , fluorescent lighting , and other sources of light. This allows for reduced eye-strain. These glasses can be ordered as standard or prescription lenses that fit into standard optical frames. By the end of the 2010s, eyeglasses that filter out blue light from computers , smartphones and tablets are becoming increasingly popular in response to concerns about problems caused by blue light overexposure. The problems claimed range from dry eyes to eye strain , sleep cycle disruption, up to macular degeneration which can cause partial blindness. They may also block out ultraviolet (UV) radiation. However, there
7820-434: The corrective glass and improve aesthetic appearance (mini telescopic spectacles). They may take the form of self-contained glasses that resemble goggles or binoculars , or may be attached to existing glasses. Recumbent or prism glasses are glasses that use a prism with a 90° refraction to allow the wearer to read or view a screen while lying on their back. Developed by Liverpudlian ophthalmologist Andrew McKie Reid in
7935-411: The cost factor has a low priority. In the laboratory mostly pure chemicals are used. Care must be taken that the raw materials have not reacted with moisture or other chemicals in the environment (such as alkali or alkaline earth metal oxides and hydroxides, or boron oxide ), or that the impurities are quantified (loss on ignition). Evaporation losses during glass melting should be considered during
8050-427: The crystalline ceramic phase can be balanced with the positive CTE of the glassy phase. At a certain point (~70% crystalline) the glass-ceramic has a net CTE near zero. This type of glass-ceramic exhibits excellent mechanical properties and can sustain repeated and quick temperature changes up to 1000 °C. Fibreglass (also called glass fibre reinforced plastic, GRP) is a composite material made by reinforcing
8165-683: The desired form is obtained, glass is usually annealed for the removal of stresses and to increase the glass's hardness and durability. Surface treatments, coatings or lamination may follow to improve the chemical durability ( glass container coatings , glass container internal treatment ), strength ( toughened glass , bulletproof glass , windshields ), or optical properties ( insulated glazing , anti-reflective coating ). New chemical glass compositions or new treatment techniques can be initially investigated in small-scale laboratory experiments. The raw materials for laboratory-scale glass melts are often different from those used in mass production because
8280-466: The development of the transistor in the 1940s, combined eyeglass-hearing aids became popular. With thick-rimmed glasses the fashion at the time, a hearing aid could be concealed in the temple part of the frame. These fell out of fashion after the 1970s, but there are still occasions when combined eyeglass-hearing aids may be useful. Safety glasses are worn to protect the eyes in various situations. They are made with break-proof plastic lenses to protect
8395-466: The exceptionally clear colourless glass cristallo , so called for its resemblance to natural crystal, which was extensively used for windows, mirrors, ships' lanterns, and lenses. In the 13th, 14th, and 15th centuries, enamelling and gilding on glass vessels were perfected in Egypt and Syria. Towards the end of the 17th century, Bohemia became an important region for glass production, remaining so until
8510-615: The eye from flying debris or other matter. Construction workers, factory workers, machinists and lab technicians are often required to wear safety glasses to shield the eyes from flying debris or hazardous splatters such as blood or chemicals. As of 2017, dentists and surgeons in Canada and other countries are required to wear safety glasses to protect against infection from patients' blood or other body fluids. There are also safety glasses for welding , which are styled like wraparound sunglasses, but with much darker lenses, for use in welding where
8625-455: The eyes from the dangers of UV light, sunglasses should have UV-400 blocker to provide good coverage against the entire light spectrum that poses a danger. Light polarization is an added feature that can be applied to sunglass lenses. Polarization filters are positioned to remove horizontally polarized rays of light, which eliminates glare from horizontal surfaces (allowing wearers to see into water when reflected light would otherwise overwhelm
8740-613: The first fully functioning automatic bottle-blowing machine (the successor of which was honored as a Historic Mechanical Engineering Landmark by the American Society of Mechanical Engineers ), and in 1903 incorporated the Owens Bottle Machine Company. In 1912, Owens acquired rights to Irving Wightman Colburn 's invention for manufacturing plate glass . In 1929, the Owens Bottle Co. acquired
8855-459: The first true synthetic glass was made in Lebanon and the coastal north Syria , Mesopotamia or ancient Egypt . The earliest known glass objects, of the mid-third millennium BC, were beads , perhaps initially created as accidental by-products of metalworking ( slags ) or during the production of faience , a pre-glass vitreous material made by a process similar to glazing . Early glass
8970-568: The floorboards at Kloster Wienhausen , a convent near Celle in Germany; they have been dated to circa 1400. The world's first specialist shop for spectacles—what we might regard today as an optician —opened in Strasbourg (then Holy Roman Empire , now France) in 1466. The 17th-century claim by Francesco Redi that Salvino degli Armati of Florence invented eyeglasses in the 13th century has been exposed as erroneous. Marco Polo
9085-414: The form of clear plastic aviators. Adjustable-focus eyeglasses might be used to replace bifocals or trifocals, or might be used to produce cheaper single-vision glasses (since they do not have to be custom-manufactured for every person). Pinhole glasses are a type of corrective glasses that do not use a lens. Pinhole glasses do not actually refract the light or change focal length. Instead, they create
9200-754: The former Roman Empire in China , the Baltics , the Middle East , and India . The Romans perfected cameo glass , produced by etching and carving through fused layers of different colours to produce a design in relief on the glass object. In post-classical West Africa, Benin was a manufacturer of glass and glass beads. Glass was used extensively in Europe during the Middle Ages . Anglo-Saxon glass has been found across England during archaeological excavations of both settlement and cemetery sites. From
9315-555: The glass and melt phases. Important polymer glasses include amorphous and glassy pharmaceutical compounds. These are useful because the solubility of the compound is greatly increased when it is amorphous compared to the same crystalline composition. Many emerging pharmaceuticals are practically insoluble in their crystalline forms. Many polymer thermoplastics familiar to everyday use are glasses. For many applications, like glass bottles or eyewear , polymer glasses ( acrylic glass , polycarbonate or polyethylene terephthalate ) are
9430-493: The glass transition range. The glass transition may be described as analogous to a second-order phase transition where the intensive thermodynamic variables such as the thermal expansivity and heat capacity are discontinuous. However, the equilibrium theory of phase transformations does not hold for glass, and hence the glass transition cannot be classed as one of the classical equilibrium phase transformations in solids. Glass can form naturally from volcanic magma. Obsidian
9545-406: The glass transition temperature is not supported by empirical research or theoretical analysis (see viscosity in solids ). Though atomic motion at glass surfaces can be observed, and viscosity on the order of 10 –10 Pa s can be measured in glass, such a high value reinforces the fact that glass would not change shape appreciably over even large periods of time. For melt quenching, if the cooling
9660-463: The lenses in the proper position. Ophthalmic frames come in a variety of styles, sizes, materials, shapes, and colors. Various metals and alloys may be used to make glasses, such as gold, silver, aluminum, beryllium , stainless steel , titanium , Monel , and nickel titanium . Natural materials such as wood, bone, ivory, leather and semi-precious or precious stones may also be used. Corrective lenses can be produced in many different shapes from
9775-495: The lenses; however, special prescription sunglasses can be made. People with conditions that have photophobia as a primary symptom (like certain migraine disorders) often wear sunglasses or precision tinted glasses, even indoors and at night. Specialized glasses may be used for viewing specific visual information, for example, 3D glasses for 3D films ( stereoscopy ). Sometimes glasses are worn purely for fashion or aesthetic purposes. Even with glasses used for vision correction,
9890-473: The light more tolerable. Sunglasses may also have corrective lenses, which requires a prescription. Clip-on sunglasses or sunglass clips can be attached to another pair of glasses. Some wrap-around sunglasses are large enough to be worn over another pair of glasses. Otherwise, many people opt to wear contact lenses to correct their vision so that standard sunglasses can be used. The double frame uplifting glasses have one moving frame with one pair of lenses and
10005-458: The liquid can easily be supercooled into a glass. Examples include LiCl: R H 2 O (a solution of lithium chloride salt and water molecules) in the composition range 4< R <8. sugar glass , or Ca 0.4 K 0.6 (NO 3 ) 1.4 . Glass electrolytes in the form of Ba-doped Li-glass and Ba-doped Na-glass have been proposed as solutions to problems identified with organic liquid electrolytes used in modern lithium-ion battery cells. Following
10120-481: The melt whilst it floats on a gas stream) or splat quenching (pressing the melt between two metal anvils or rollers), may be used to increase the cooling rate or to reduce crystal nucleation triggers. In the past, small batches of amorphous metals with high surface area configurations (ribbons, wires, films, etc.) have been produced through the implementation of extremely rapid rates of cooling. Amorphous metal wires have been produced by sputtering molten metal onto
10235-433: The melt. The high density of lead glass (silica + lead oxide (PbO) + potassium oxide (K 2 O) + soda (Na 2 O) + zinc oxide (ZnO) + alumina) results in a high electron density, and hence high refractive index, making the look of glassware more brilliant and causing noticeably more specular reflection and increased optical dispersion . Lead glass has a high elasticity, making the glassware more workable and giving rise to
10350-619: The melting temperature and simplify glass processing. Sodium carbonate (Na 2 CO 3 , "soda") is a common additive and acts to lower the glass-transition temperature. However, sodium silicate is water-soluble , so lime (CaO, calcium oxide , generally obtained from limestone ), along with magnesium oxide (MgO), and aluminium oxide (Al 2 O 3 ), are commonly added to improve chemical durability. Soda–lime glasses (Na 2 O) + lime (CaO) + magnesia (MgO) + alumina (Al 2 O 3 ) account for over 75% of manufactured glass, containing about 70 to 74% silica by weight. Soda–lime–silicate glass
10465-410: The metallic ions will absorb wavelengths of light corresponding to specific colours. In the manufacturing process, glasses can be poured, formed, extruded and moulded into forms ranging from flat sheets to highly intricate shapes. The finished product is brittle but can be laminated or tempered to enhance durability. Glass is typically inert, resistant to chemical attack, and can mostly withstand
10580-406: The mid-15th century, it was not until 1604 that Johannes Kepler published the first correct explanation as to why convex and concave lenses could correct presbyopia and myopia. Early frames for glasses consisted of two magnifying glasses riveted together by the handles so that they could grip the nose. These are referred to as "rivet spectacles". The earliest surviving examples were found under
10695-534: The most efficient. Before the advent of eyeglasses as a fashion item, when frames were constructed with only functionality in mind, virtually all eyeglasses were either round , oval , panto, rectangular , octagonal , or square . It was not until glasses began to be seen as an accessory that different shapes were introduced to be more aesthetically pleasing than functional. Scattered evidence exists for use of visual aid devices in Greek and Roman times, most prominently
10810-409: The most significant architectural innovations of modern times, where glass buildings now often dominate the skylines of many modern cities . These systems use stainless steel fittings countersunk into recesses in the corners of the glass panels allowing strengthened panes to appear unsupported creating a flush exterior. Structural glazing systems have their roots in iron and glass conservatories of
10925-479: The nineteenth century Glasses Glasses , also known as eyeglasses and spectacles , are vision eyewear with clear or tinted lenses mounted in a frame that holds them in front of a person's eyes , typically utilizing a bridge over the nose and hinged arms, known as temples or temple pieces, that rest over the ears. Glasses are typically used for vision correction , such as with reading glasses and glasses used for nearsightedness ; however, without
11040-922: The production of faience , which is a form of pottery using lead glazes. Due to its ease of formability into any shape, glass has been traditionally used for vessels, such as bowls , vases , bottles , jars and drinking glasses. Soda–lime glass , containing around 70% silica , accounts for around 90% of modern manufactured glass. Glass can be coloured by adding metal salts or painted and printed with vitreous enamels , leading to its use in stained glass windows and other glass art objects. The refractive , reflective and transmission properties of glass make glass suitable for manufacturing optical lenses , prisms , and optoelectronics materials. Extruded glass fibres have applications as optical fibres in communications networks, thermal insulating material when matted as glass wool to trap air, or in glass-fibre reinforced plastic ( fibreglass ). The standard definition of
11155-460: The retina. They are made to conform to the prescription of an ophthalmologist or optometrist . A lensmeter can be used to verify the specifications of an existing pair of glasses. Corrective eyeglasses can significantly improve the life quality of the wearer. Not only do they enhance the wearer's visual experience, but can also reduce problems that result from eye strain, such as headaches or squinting. The most common type of corrective lens
11270-423: The sale of eyeglasses and a separate guild of Venetian spectacle makers was formed in 1320. In the fourteenth century, they were very common objects: Francesco Petrarca says in one of his letters that, until he was 60, he did not need glasses, and Franco Sacchetti mentions them often in his Trecentonovelle . The earliest pictorial evidence for the use of eyeglasses is Tommaso da Modena 's 1352 portrait of
11385-639: The scene). Polarized sunglasses may present some difficulties for pilots since reflections from water and other structures often used to gauge altitude may be removed. Liquid-crystal displays emit polarized light, making them sometimes difficult to view with polarized sunglasses. Sunglasses may be worn for aesthetic purposes, or simply to hide the eyes. Examples of sunglasses that were popular for these reasons include tea shades and mirrorshades . Many blind people wear nearly opaque glasses to hide their eyes for cosmetic reasons. Many people with light sensitivity conditions wear sunglasses or other tinted glasses to make
11500-424: The selection of the raw materials, e.g., sodium selenite may be preferred over easily evaporating selenium dioxide (SeO 2 ). Also, more readily reacting raw materials may be preferred over relatively inert ones, such as aluminium hydroxide (Al(OH) 3 ) over alumina (Al 2 O 3 ). Usually, the melts are carried out in platinum crucibles to reduce contamination from the crucible material. Glass homogeneity
11615-681: The signal electronically and then transmit light directly into the viewer's eyes. Anaglyph and polarized glasses are distributed to audiences at 3D movies . Polarized and active shutter glasses are used with many home theaters. Head-mounted displays are used by a single person, but the input signal can be shared between multiple units. Glasses can also provide magnification that is useful for people with vision impairments or specific occupational demands. An example would be bioptics or bioptic telescopes which have small telescopes mounted on, in, or behind their regular lenses. Newer designs use smaller lightweight telescopes, which can be embedded into
11730-464: The specialized lenses, they are sometimes used for cosmetic purposes. Safety glasses provide eye protection against flying debris for construction workers or lab technicians; these glasses may have protection on the sides of the eyes as well as in the lenses. Some types of safety glasses are used to protect against visible and near-visible light or radiation . Glasses are worn for eye protection in some sports, such as squash . Glasses wearers may use
11845-603: The start of the 20th century. By the 17th century, glass in the Venetian tradition was also being produced in England . In about 1675, George Ravenscroft invented lead crystal glass, with cut glass becoming fashionable in the 18th century. Ornamental glass objects became an important art medium during the Art Nouveau period in the late 19th century. Throughout the 20th century, new mass production techniques led to
11960-469: The strength of glass. Carefully drawn flawless glass fibres can be produced with a strength of up to 11.5 gigapascals (1,670,000 psi). The observation that old windows are sometimes found to be thicker at the bottom than at the top is often offered as supporting evidence for the view that glass flows over a timescale of centuries, the assumption being that the glass has exhibited the liquid property of flowing from one shape to another. This assumption
12075-460: The system Al-Fe-Si may undergo a first-order transition to an amorphous form (dubbed "q-glass") on rapid cooling from the melt. Transmission electron microscopy (TEM) images indicate that q-glass nucleates from the melt as discrete particles with uniform spherical growth in all directions. While x-ray diffraction reveals the isotropic nature of q-glass, a nucleation barrier exists implying an interfacial discontinuity (or internal surface) between
12190-423: The upper frame serving as sunglasses and the second frame as transparent lenses. The illusion of three dimensions on a two-dimensional surface can be created by providing each eye with different visual information. 3D glasses create the illusion of three dimensions by filtering a signal containing information for both eyes. The signal, often light reflected off a movie screen or emitted from an electronic display,
12305-430: The usage of the computer is stopped. Decreasing evening screen time and setting devices to night mode will improve sleep. Several studies have shown that blue light from computers does not lead to eye diseases, including macular degeneration. The total amount of light entering the eyes can be adjusted without glasses using the screen brightness settings. Similarly, the blue light can often specifically be adjusted using
12420-604: The use of an emerald by Emperor Nero as mentioned by Pliny the Elder . The use of a convex lens to form an enlarged/magnified image was most likely described in Ptolemy 's Optics (which survives only in a poor Arabic translation). Ptolemy's description of lenses was commented upon and improved by Ibn Sahl (10th century) and most notably by Alhazen ( Book of Optics , c. 1021 ). Latin translations of Ptolemy's Optics and of Alhazen became available in Europe in
12535-451: The widespread availability of glass in much larger amounts, making it practical as a building material and enabling new applications of glass. In the 1920s a mould -etch process was developed, in which art was etched directly into the mould so that each cast piece emerged from the mould with the image already on the surface of the glass. This reduced manufacturing costs and, combined with a wider use of coloured glass, led to cheap glassware in
12650-402: The year 1268. The study found that the room temperature viscosity of this glass was roughly 10 Pa · s which is about 10 times less viscous than a previous estimate made in 1998, which focused on soda-lime silicate glass. Even with this lower viscosity, the study authors calculated that the maximum flow rate of medieval glass is 1 nm per billion years, making it impossible to observe in
12765-500: Was abandoned in an effort to rebrand globally under the Pilkington name. Glass Glass is an amorphous ( non-crystalline ) solid. Because it is often transparent and chemically inert, glass has found widespread practical, technological, and decorative use in window panes, tableware , and optics . Some common objects made of glass are named after the material, e.g. "glass" , " glasses ", " magnifying glass ". Glass
12880-698: Was formed in 1930 by the merger of Libbey-Owens's sheet-glass operation with the Edward Ford Plate Glass Company, both located in Toledo. The company's heritage dates back to 1818 with the founding of the New England Glass Company of East Cambridge, Massachusetts , which relocated to Toledo, Ohio , and in 1892 changed its name to Libbey Glass Company under the direction of Edward Drummond Libbey . In parallel, Michael Owens and associates completed work in 1902 on
12995-517: Was originally used in the United Kingdom and United States during World War II to manufacture radomes . Uses of fibreglass include building and construction materials, boat hulls, car body parts, and aerospace composite materials. Glass-fibre wool is an excellent thermal and sound insulation material, commonly used in buildings (e.g. attic and cavity wall insulation ), and plumbing (e.g. pipe insulation ), and soundproofing . It
13110-556: Was rarely transparent and often contained impurities and imperfections, and is technically faience rather than true glass, which did not appear until the 15th century BC. However, red-orange glass beads excavated from the Indus Valley Civilization dated before 1700 BC (possibly as early as 1900 BC) predate sustained glass production, which appeared around 1600 BC in Mesopotamia and 1500 BC in Egypt. During
13225-567: Was renamed TRINOVA Corporation. The Sterling business was later sold, and in the late 1990s the company adopted its two leading business unit names, and continued as Aeroquip-Vickers, Inc., until being absorbed by Eaton Corporation in 1999. As part of the Pilkington Group, the company retained the LOF name. However, in June 2006, Pilkington was acquired by Nippon Sheet Glass , and the LOF name
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