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128-554: Photovoltaics ( PV ) is the conversion of light into electricity using semiconducting materials that exhibit the photovoltaic effect , a phenomenon studied in physics , photochemistry , and electrochemistry . The photovoltaic effect is commercially used for electricity generation and as photosensors . A photovoltaic system employs solar modules , each comprising a number of solar cells , which generate electrical power. PV installations may be ground-mounted, rooftop-mounted, wall-mounted or floating. The mount may be fixed or use

256-413: A solar tracker to follow the sun across the sky. Photovoltaic technology helps to mitigate climate change because it emits much less carbon dioxide than fossil fuels . Solar PV has specific advantages as an energy source: once installed, its operation does not generate any pollution or any greenhouse gas emissions ; it shows scalability in respect of power needs and silicon has large availability in

384-404: A "pulse theory" and compared the spreading of light to that of waves in water in his 1665 work Micrographia ("Observation IX"). In 1672 Hooke suggested that light's vibrations could be perpendicular to the direction of propagation. Christiaan Huygens (1629–1695) worked out a mathematical wave theory of light in 1678 and published it in his Treatise on Light in 1690. He proposed that light

512-751: A DC clamp meter or shunt and logged, graphed, or charted with a chart recorder or data logger. For optimum performance, a solar panel needs to be made of similar modules oriented in the same direction perpendicular to direct sunlight. Bypass diodes are used to circumvent broken or shaded panels and optimize output. These bypass diodes are usually placed along groups of solar cells to create a continuous flow. Electrical characteristics include nominal power (P MAX , measured in W ), open-circuit voltage (V OC ), short-circuit current (I SC , measured in amperes ), maximum power voltage (V MPP ), maximum power current (I MPP ), peak power ( watt-peak , W p ), and module efficiency (%). Open-circuit voltage or V OC

640-609: A better representation of how "bright" a light appears to be than raw intensity. They relate to raw power by a quantity called luminous efficacy and are used for purposes like determining how to best achieve sufficient illumination for various tasks in indoor and outdoor settings. The illumination measured by a photocell sensor does not necessarily correspond to what is perceived by the human eye and without filters which may be costly, photocells and charge-coupled devices (CCD) tend to respond to some infrared , ultraviolet or both. Light exerts physical pressure on objects in its path,

768-556: A body could be so massive that light could not escape from it. In other words, it would become what is now called a black hole . Laplace withdrew his suggestion later, after a wave theory of light became firmly established as the model for light (as has been explained, neither a particle or wave theory is fully correct). A translation of Newton's essay on light appears in The large scale structure of space-time , by Stephen Hawking and George F. R. Ellis . The fact that light could be polarized

896-433: A circuit from a component is defined to have a negative sign. Thus passive components have positive power consumption, while power sources have negative power consumption. This is called the passive sign convention . In the case of resistive (Ohmic, or linear) loads, the power formula ( P = I·V ) and Joule's first law ( P = I^2·R ) can be combined with Ohm's law ( V = I·R ) to produce alternative expressions for

1024-449: A complete cycle of the AC waveform, results in net transfer of energy in one direction is known as real power (also referred to as active power). The amplitude of that portion of energy flow (power) that results in no net transfer of energy but instead oscillates between the source and load in each cycle due to stored energy, is known as the absolute value of reactive power . The product of

1152-547: A factor of 4 between 2004 and 2011. Module prices dropped by about 90% over the 2010s. In 2022, worldwide installed PV capacity increased to more than 1 terawatt (TW) covering nearly two percent of global electricity demand . After hydro and wind powers , PV is the third renewable energy source in terms of global capacity. In 2022, the International Energy Agency expected a growth by over 1 TW from 2022 to 2027. In some instances, PV has offered

1280-467: A force of about 3.3 piconewtons on the object being illuminated; thus, one could lift a U.S. penny with laser pointers, but doing so would require about 30 billion 1-mW laser pointers.   However, in nanometre -scale applications such as nanoelectromechanical systems (NEMS), the effect of light pressure is more significant and exploiting light pressure to drive NEMS mechanisms and to flip nanometre-scale physical switches in integrated circuits

1408-904: A fraction of the emissions caused by fossil fuels . Photovoltaic systems have long been used in specialized applications as stand-alone installations and grid-connected PV systems have been in use since the 1990s. Photovoltaic modules were first mass-produced in 2000, when the German government funded a one hundred thousand roof program. Decreasing costs has allowed PV to grow as an energy source. This has been partially driven by massive Chinese government investment in developing solar production capacity since 2000, and achieving economies of scale . Improvements in manufacturing technology and efficiency have also led to decreasing costs. Net metering and financial incentives, such as preferential feed-in tariffs for solar-generated electricity, have supported solar PV installations in many countries. Panel prices dropped by

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1536-429: A high EPBT because silicon is produced by the reduction of high-grade quartz sand in electric furnaces . This coke-fired smelting process occurs at high temperatures of more than 1000 °C and is very energy intensive, using about 11 kilowatt-hours (kWh) per produced kilogram of silicon. The energy requirements of this process makes the energy cost per unit of silicon produced relatively inelastic, which means that

1664-411: A lasting molecular change (a change in conformation) in the visual molecule retinal in the human retina, which change triggers the sensation of vision. There exist animals that are sensitive to various types of infrared, but not by means of quantum-absorption. Infrared sensing in snakes depends on a kind of natural thermal imaging , in which tiny packets of cellular water are raised in temperature by

1792-572: A loop of wire, or disc of copper between the poles of a magnet . For electric utilities , it is the first process in the delivery of electricity to consumers. The other processes, electricity transmission , distribution , and electrical energy storage and recovery using pumped-storage methods are normally carried out by the electric power industry . Electricity is mostly generated at a power station by electromechanical generators , driven by heat engines heated by combustion , geothermal power or nuclear fission . Other generators are driven by

1920-450: A medium faster than the speed of light in that medium can produce visible Cherenkov radiation . Certain chemicals produce visible radiation by chemoluminescence . In living things, this process is called bioluminescence . For example, fireflies produce light by this means and boats moving through water can disturb plankton which produce a glowing wake. Certain substances produce light when they are illuminated by more energetic radiation,

2048-445: A number of solar cells containing a semiconductor material. Copper solar cables connect modules (module cable), arrays (array cable), and sub-fields. Because of the growing demand for renewable energy sources, the manufacturing of solar cells and photovoltaic arrays has advanced considerably in recent years. Cells require protection from the environment and are usually packaged tightly in solar modules. Photovoltaic module power

2176-873: A panel can be expected to produce 400  kWh of energy per year. However, in Michigan, which receives only 1400 kWh/m/year, annual energy yield will drop to 280 kWh for the same panel. At more northerly European latitudes, yields are significantly lower: 175 kWh annual energy yield in southern England under the same conditions. Several factors affect a cell's conversion efficiency, including its reflectance , thermodynamic efficiency , charge carrier separation efficiency, charge carrier collection efficiency and conduction efficiency values. Because these parameters can be difficult to measure directly, other parameters are measured instead, including quantum efficiency , open-circuit voltage (V OC ) ratio, and § Fill factor . Reflectance losses are accounted for by

2304-424: A phenomenon which can be deduced by Maxwell's equations , but can be more easily explained by the particle nature of light: photons strike and transfer their momentum. Light pressure is equal to the power of the light beam divided by c , the speed of light.   Due to the magnitude of c , the effect of light pressure is negligible for everyday objects.   For example, a one-milliwatt laser pointer exerts

2432-419: A process known as fluorescence . Some substances emit light slowly after excitation by more energetic radiation. This is known as phosphorescence . Phosphorescent materials can also be excited by bombarding them with subatomic particles. Cathodoluminescence is one example. This mechanism is used in cathode-ray tube television sets and computer monitors . Certain other mechanisms can produce light: When

2560-576: A rather large amount of uncertainty. The values of human labor and water consumption, for example, are not precisely assessed due to the lack of systematic and accurate analyses in the scientific literature. One difficulty in determining effects due to PV is to determine if the wastes are released to the air, water, or soil during the manufacturing phase. Life-cycle assessments , which look at all different environment effects ranging from global warming potential , pollution, water depletion and others, are unavailable for PV. Instead, studies have tried to estimate

2688-517: A similar program with 539 residential PV systems installed. Since, many countries have continued to produce and finance PV systems in an exponential speed. Photovoltaics are best known as a method for generating electric power by using solar cells to convert energy from the sun into a flow of electrons by the photovoltaic effect . Solar cells produce direct current electricity from sunlight which can be used to power equipment or to recharge batteries . The first practical application of photovoltaics

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2816-571: A simple rooftop system, some 90% of the energy cost is from silicon, with the remainder coming from the inverters and module frame. In an analysis by Alsema et al . from 1998, the energy payback time was higher than 10 years for the former system in 1997, while for a standard rooftop system the EPBT was calculated as between 3.5 and 8 years. The EPBT relates closely to the concepts of net energy gain (NEG) and energy returned on energy invested (EROI). They are both used in energy economics and refer to

2944-421: A source or a load, depending on the voltage and current through them. For example, a rechargeable battery acts as a source when it provides power to a circuit, but as a load when it is connected to a battery charger and is being recharged. If conventional current flows through the device in a direction from higher potential (voltage) to lower potential, so positive charge moves from the positive (+) terminal to

3072-410: A source. One of Newton's arguments against the wave nature of light was that waves were known to bend around obstacles, while light travelled only in straight lines. He did, however, explain the phenomenon of the diffraction of light (which had been observed by Francesco Grimaldi ) by allowing that a light particle could create a localised wave in the aether . Newton's theory could be used to predict

3200-672: A structure of front electrode, anti-reflection film, n-layer, p-layer, and back electrode, with the sun hitting the front electrode. EPBT ranges from 1.7 to 2.7 years. The cradle to gate of CO 2 -eq/kWh ranges from 37.3 to 72.2 grams when installed in Southern Europe. Techniques to produce multi-crystalline silicon (multi-si) photovoltaic cells are simpler and cheaper than mono-si, however tend to make less efficient cells, an average of 13.2%. EPBT ranges from 1.5 to 2.6 years. The cradle to gate of CO 2 -eq/kWh ranges from 28.5 to 69 grams when installed in Southern Europe. Assuming that

3328-414: A surface between one transparent material and another. It is described by Snell's Law : where θ 1 is the angle between the ray and the surface normal in the first medium, θ 2 is the angle between the ray and the surface normal in the second medium and n 1 and n 2 are the indices of refraction , n = 1 in a vacuum and n > 1 in a transparent substance . When a beam of light crosses

3456-425: A theoretical 28% efficient device, found that, compared to monocrystalline Si, the environmental impacts from 1% SWCNT was ~18 times higher due mainly to the short lifetime of three years. Light Light , visible light , or visible radiation is electromagnetic radiation that can be perceived by the human eye . Visible light spans the visible spectrum and is usually defined as having wavelengths in

3584-557: A value of 298 000 000  m/s in 1862. Albert A. Michelson conducted experiments on the speed of light from 1877 until his death in 1931. He refined Foucault's methods in 1926 using improved rotating mirrors to measure the time it took light to make a round trip from Mount Wilson to Mount San Antonio in California. The precise measurements yielded a speed of 299 796 000  m/s . The effective velocity of light in various transparent substances containing ordinary matter ,

3712-517: Is a scalar since it is the surface integral of the Poynting vector . 2021 world electricity generation by source. Total generation was 28 petawatt-hours . The fundamental principles of much electricity generation were discovered during the 1820s and early 1830s by the British scientist Michael Faraday . His basic method is still used today: electric current is generated by the movement of

3840-530: Is also affected by the colour spectrum of light, a process known as photomorphogenesis . The speed of light in vacuum is defined to be exactly 299 792 458  m/s (approximately 186,282 miles per second). The fixed value of the speed of light in SI units results from the fact that the metre is now defined in terms of the speed of light. All forms of electromagnetic radiation move at exactly this same speed in vacuum. Different physicists have attempted to measure

3968-459: Is an active area of research. At larger scales, light pressure can cause asteroids to spin faster, acting on their irregular shapes as on the vanes of a windmill .   The possibility of making solar sails that would accelerate spaceships in space is also under investigation. Although the motion of the Crookes radiometer was originally attributed to light pressure, this interpretation

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4096-400: Is around 18 grams (cradle to gate). CdTe has the fastest EPBT of all commercial PV technologies, which varies between 0.3 and 1.2 years. Third-generation PVs are designed to combine the advantages of both the first and second generation devices and they do not have Shockley-Queisser limit , a theoretical limit for first and second generation PV cells. The thickness of a third generation device

4224-421: Is called power factor and is a number always between −1 and 1. Where the currents and voltages have non-sinusoidal forms, power factor is generalized to include the effects of distortion. Electrical energy flows wherever electric and magnetic fields exist together and fluctuate in the same place. The simplest example of this is in electrical circuits, as the preceding section showed. In the general case, however,

4352-429: Is caused by the surface roughness of the reflecting surfaces, and internal scatterance is caused by the difference of refractive index between the particles and medium inside the object. Like transparent objects, translucent objects allow light to transmit through, but translucent objects also scatter certain wavelength of light via internal scatterance. Refraction is the bending of light rays when passing through

4480-435: Is due to its exposure to solar radiation as well as other external conditions. The degradation index, which is defined as the annual percentage of output power loss, is a key factor in determining the long-term production of a photovoltaic plant. To estimate this degradation, the percentage of decrease associated with each of the electrical parameters. The individual degradation of a photovoltaic module can significantly influence

4608-462: Is incorrect; the characteristic Crookes rotation is the result of a partial vacuum. This should not be confused with the Nichols radiometer , in which the (slight) motion caused by torque (though not enough for full rotation against friction) is directly caused by light pressure. As a consequence of light pressure, Einstein in 1909 predicted the existence of "radiation friction" which would oppose

4736-464: Is less than 1 μm. Two new promising thin film technologies are copper zinc tin sulfide (Cu 2 ZnSnS 4 or CZTS), zinc phosphide (Zn 3 P 2 ) and single-walled carbon nano-tubes (SWCNT). These thin films are currently only produced in the lab but may be commercialized in the future. The manufacturing of CZTS and (Zn 3 P 2 ) processes are expected to be similar to those of current thin film technologies of CIGS and CdTe, respectively. While

4864-654: Is less than in vacuum. For example, the speed of light in water is about 3/4 of that in vacuum. Two independent teams of physicists were said to bring light to a "complete standstill" by passing it through a Bose–Einstein condensate of the element rubidium , one team at Harvard University and the Rowland Institute for Science in Cambridge, Massachusetts and the other at the Harvard–Smithsonian Center for Astrophysics , also in Cambridge. However,

4992-464: Is lower in the sky in the winter. Two location dependant factors that affect solar PV yield are the dispersion and intensity of solar radiation. These two variables can vary greatly between each country. The global regions that have high radiation levels throughout the year are the middle east, Northern Chile, Australia, China, and Southwestern USA. In a high-yield solar area like central Colorado, which receives annual insolation of 2000 kWh/m/year,

5120-453: Is measured under standard test conditions (STC) in "W p " ( watts peak ). The actual power output at a particular place may be less than or greater than this rated value, depending on geographical location, time of day, weather conditions, and other factors. Solar photovoltaic array capacity factors are typically under 25% when not coupled with storage, which is lower than many other industrial sources of electricity. Solar-cell efficiency

5248-458: Is observed (which can last several months and up to two years), followed by a later stage in which the degradation stabilizes, being then comparable to that of crystalline silicon. Strong seasonal variations are also observed in such thin-film technologies because the influence of the solar spectrum is much greater. For example, for modules of amorphous silicon, micromorphic silicon or cadmium telluride, we are talking about annual degradation rates for

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5376-409: Is one of the fundamental constants of nature. Like all types of electromagnetic radiation, visible light propagates by massless elementary particles called photons that represents the quanta of electromagnetic field, and can be analyzed as both waves and particles . The study of light, known as optics , is an important research area in modern physics . The main source of natural light on Earth

5504-402: Is processed from mined quartz until it is very pure (semi-conductor grade). This is melted down when small amounts of boron , a group III element, are added to make a p-type semiconductor rich in electron holes. Typically using a seed crystal, an ingot of this solution is grown from the liquid polycrystalline. The ingot may also be cast in a mold. Wafers of this semiconductor material are cut from

5632-449: Is regarded as the start of modern physical optics. Pierre Gassendi (1592–1655), an atomist, proposed a particle theory of light which was published posthumously in the 1660s. Isaac Newton studied Gassendi's work at an early age and preferred his view to Descartes's theory of the plenum . He stated in his Hypothesis of Light of 1675 that light was composed of corpuscles (particles of matter) which were emitted in all directions from

5760-825: Is the Sun . Historically, another important source of light for humans has been fire , from ancient campfires to modern kerosene lamps . With the development of electric lights and power systems , electric lighting has effectively replaced firelight. Generally, electromagnetic radiation (EMR) is classified by wavelength into radio waves , microwaves , infrared , the visible spectrum that we perceive as light, ultraviolet , X-rays and gamma rays . The designation " radiation " excludes static electric , magnetic and near fields . The behavior of EMR depends on its wavelength. Higher frequencies have shorter wavelengths and lower frequencies have longer wavelengths. When EMR interacts with single atoms and molecules, its behavior depends on

5888-534: Is the maximum voltage the module can produce when not connected to an electrical circuit or system. V OC can be measured with a voltmeter directly on an illuminated module's terminals or on its disconnected cable. The peak power rating, W p , is the maximum output under standard test conditions (not the maximum possible output). Typical modules, which could measure approximately 1 by 2 metres (3 ft × 7 ft), will be rated from as low as 75 W to as high as 600 W, depending on their efficiency. At

6016-432: Is the portion of energy in the form of sunlight that can be converted via photovoltaics into electricity by the solar cell . The efficiency of the solar cells used in a photovoltaic system , in combination with latitude and climate, determines the annual energy output of the system. For example, a solar panel with 20% efficiency and an area of 1 m will produce 200 kWh/yr at Standard Test Conditions if exposed to

6144-583: Is the production and delivery of electrical energy, an essential public utility in much of the world. Electric power is usually produced by electric generators , but can also be supplied by sources such as electric batteries . It is usually supplied to businesses and homes (as domestic mains electricity ) by the electric power industry through an electrical grid . Electric power can be delivered over long distances by transmission lines and used for applications such as motion , light or heat with high efficiency . Electric power, like mechanical power ,

6272-644: Is the rate of doing work , measured in watts , and represented by the letter P . The term wattage is used colloquially to mean "electric power in watts". The electric power in watts produced by an electric current I consisting of a charge of Q coulombs every t seconds passing through an electric potential ( voltage ) difference of V is: Work done per unit time = ℘ = W t = W Q Q t = V I {\displaystyle {\text{Work done per unit time}}=\wp ={\frac {W}{t}}={\frac {W}{Q}}{\frac {Q}{t}}=VI} where: I.e., Electric power

6400-410: Is transformed to other forms of energy when electric charges move through an electric potential difference ( voltage ), which occurs in electrical components in electric circuits. From the standpoint of electric power, components in an electric circuit can be divided into two categories: If electric current is forced to flow through the device in the direction from the lower electric potential to

6528-504: The Académie des Sciences in 1817. Siméon Denis Poisson added to Fresnel's mathematical work to produce a convincing argument in favor of the wave theory, helping to overturn Newton's corpuscular theory. By the year 1821, Fresnel was able to show via mathematical methods that polarization could be explained by the wave theory of light if and only if light was entirely transverse, with no longitudinal vibration whatsoever. The weakness of

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6656-813: The Greek φῶς ( phōs ) meaning "light", and from "volt", the unit of electromotive force, the volt , which in turn comes from the last name of the Italian physicist Alessandro Volta , inventor of the battery ( electrochemical cell ). The term "photovoltaic" has been in use in English since 1849. In 1989, the German Research Ministry initiated the first ever program to finance PV roofs (2200 roofs). A program led by Walter Sandtner in Bonn, Germany. In 1994, Japan followed in their footsteps and conducted

6784-428: The aurora borealis offer many clues as to the nature of light. A transparent object allows light to transmit or pass through. Conversely, an opaque object does not allow light to transmit through and instead reflecting or absorbing the light it receives. Most objects do not reflect or transmit light specularly and to some degree scatters the incoming light, which is called glossiness . Surface scatterance

6912-407: The kinetic energy of flowing water and wind. There are many other technologies that are used to generate electricity such as photovoltaic solar panels. A battery is a device consisting of one or more electrochemical cells that convert stored chemical energy into electrical energy. Since the invention of the first battery (or " voltaic pile ") in 1800 by Alessandro Volta and especially since

7040-431: The reflection of light, but could only explain refraction by incorrectly assuming that light accelerated upon entering a denser medium because the gravitational pull was greater. Newton published the final version of his theory in his Opticks of 1704. His reputation helped the particle theory of light to hold sway during the eighteenth century. The particle theory of light led Pierre-Simon Laplace to argue that

7168-624: The refraction of light in his book Optics . In ancient India , the Hindu schools of Samkhya and Vaisheshika , from around the early centuries AD developed theories on light. According to the Samkhya school, light is one of the five fundamental "subtle" elements ( tanmatra ) out of which emerge the gross elements. The atomicity of these elements is not specifically mentioned and it appears that they were actually taken to be continuous. The Vishnu Purana refers to sunlight as "the seven rays of

7296-681: The Earth's crust, although other materials required in PV system manufacture such as silver may constrain further growth in the technology. Other major constraints identified include competition for land use. The use of PV as a main source requires energy storage systems or global distribution by high-voltage direct current power lines causing additional costs, and also has a number of other specific disadvantages such as variable power generation which have to be balanced. Production and installation does cause some pollution and greenhouse gas emissions , though only

7424-648: The RMS value of the voltage wave and the RMS value of the current wave is known as apparent power . The real power P in watts consumed by a device is given by ℘ = 1 2 V p I p cos ⁡ θ = V r m s I r m s cos ⁡ θ {\displaystyle \wp ={1 \over 2}V_{p}I_{p}\cos \theta =V_{\rm {rms}}I_{\rm {rms}}\cos \theta } where The relationship between real power, reactive power and apparent power can be expressed by representing

7552-530: The Standard Test Condition solar irradiance value of 1000 W/m for 2.74 hours a day. Usually solar panels are exposed to sunlight for longer than this in a given day, but the solar irradiance is less than 1000 W/m for most of the day. A solar panel can produce more when the Sun is high in Earth's sky and will produce less in cloudy conditions or when the Sun is low in the sky; usually the Sun

7680-476: The U.S. market are UL listed, meaning they have gone through testing to withstand hail. Potential-induced degradation (also called PID) is a potential-induced performance degradation in crystalline photovoltaic modules, caused by so-called stray currents. This effect may cause power loss of up to 30%. The largest challenge for photovoltaic technology is the purchase price per watt of electricity produced. Advancements in photovoltaic technologies have brought about

7808-872: The absorber layer of SWCNT PV is expected to be synthesized with CoMoCAT method. by Contrary to established thin films such as CIGS and CdTe, CZTS, Zn 3 P 2 , and SWCNT PVs are made from earth abundant, nontoxic materials and have the potential to produce more electricity annually than the current worldwide consumption. While CZTS and Zn 3 P 2 offer good promise for these reasons, the specific environmental implications of their commercial production are not yet known. Global warming potential of CZTS and Zn 3 P 2 were found 38 and 30 grams CO 2 -eq/kWh while their corresponding EPBT were found 1.85 and 0.78 years, respectively. Overall, CdTe and Zn 3 P 2 have similar environmental effects but can slightly outperform CIGS and CZTS. A study on environmental impacts of SWCNT PVs by Celik et al., including an existing 1% efficient device and

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7936-409: The activation energy to decrease twenty-fold from 1.12 eV to 0.05 eV. Since the potential difference (E B ) is so low, the boron is able to thermally ionize at room temperatures. This allows for free energy carriers in the conduction and valence bands thereby allowing greater conversion of photons to electrons. The power output of a photovoltaic (PV) device decreases over time. This decrease

8064-456: The amount of energy per quantum it carries. EMR in the visible light region consists of quanta (called photons ) that are at the lower end of the energies that are capable of causing electronic excitation within molecules, which leads to changes in the bonding or chemistry of the molecule. At the lower end of the visible light spectrum, EMR becomes invisible to humans (infrared) because its photons no longer have enough individual energy to cause

8192-466: The amount of power that is dissipated: ℘ = I V = I 2 R = V 2 R {\displaystyle \wp =IV=I^{2}R={\frac {V^{2}}{R}}} where R is the electrical resistance . In alternating current circuits, energy storage elements such as inductance and capacitance may result in periodic reversals of the direction of energy flow. The portion of energy flow (power) that, averaged over

8320-416: The amount of sunlight available and the efficiency of the electrical grid) and on the type of system, namely the system's components. A 2015 review of EPBT estimates of first and second-generation PV suggested that there was greater variation in embedded energy than in efficiency of the cells implying that it was mainly the embedded energy that needs to reduce to have a greater reduction in EPBT. In general,

8448-522: The apparent power, when the current and voltage are both sinusoids with a known phase angle θ between them: (real power) = (apparent power) cos ⁡ θ {\displaystyle {\text{(real power)}}={\text{(apparent power)}}\cos \theta } (reactive power) = (apparent power) sin ⁡ θ {\displaystyle {\text{(reactive power)}}={\text{(apparent power)}}\sin \theta } The ratio of real power to apparent power

8576-470: The apparent size of images. Magnifying glasses , spectacles , contact lenses , microscopes and refracting telescopes are all examples of this manipulation. There are many sources of light. A body at a given temperature emits a characteristic spectrum of black-body radiation . A simple thermal source is sunlight , the radiation emitted by the chromosphere of the Sun at around 6,000  K (5,730  °C ; 10,340  °F ). Solar radiation peaks in

8704-605: The beam from the eye travels infinitely fast this is not a problem. In 55 BC, Lucretius , a Roman who carried on the ideas of earlier Greek atomists , wrote that "The light & heat of the sun; these are composed of minute atoms which, when they are shoved off, lose no time in shooting right across the interspace of air in the direction imparted by the shove." (from On the nature of the Universe ). Despite being similar to later particle theories, Lucretius's views were not generally accepted. Ptolemy (c. second century) wrote about

8832-452: The boundary between a vacuum and another medium, or between two different media, the wavelength of the light changes, but the frequency remains constant. If the beam of light is not orthogonal (or rather normal) to the boundary, the change in wavelength results in a change in the direction of the beam. This change of direction is known as refraction . The refractive quality of lenses is frequently used to manipulate light in order to change

8960-464: The bulk material with wire saws, and then go through surface etching before being cleaned. Next, the wafers are placed into a phosphorus vapor deposition furnace which lays a very thin layer of phosphorus, a group V element, which creates an n-type semiconducting surface. To reduce energy losses, an anti-reflective coating is added to the surface, along with electrical contacts. After finishing the cell, cells are connected via electrical circuit according to

9088-462: The cheapest source of electrical power in regions with a high solar potential, with a bid for pricing as low as 0.015 US$ / kWh in Qatar in 2023. In 2023, the International Energy Agency stated in its World Energy Outlook that '[f]or projects with low cost financing that tap high quality resources, solar PV is now the cheapest source of electricity in history. The term "photovoltaic" comes from

9216-592: The concept of light is intended to include very-high-energy photons (gamma rays), additional generation mechanisms include: Light is measured with two main alternative sets of units: radiometry consists of measurements of light power at all wavelengths, while photometry measures light with wavelength weighted with respect to a standardized model of human brightness perception. Photometry is useful, for example, to quantify Illumination (lighting) intended for human use. The photometry units are different from most systems of physical units in that they take into account how

9344-532: The cost of each device by both reducing material and energy consumption during manufacturing. The global market share of CdTe was 4.7% in 2008. This technology's highest power conversion efficiency is 21%. The cell structure includes glass substrate (around 2 mm), transparent conductor layer, CdS buffer layer (50–150 nm), CdTe absorber and a metal contact layer. CdTe PV systems require less energy input in their production than other commercial PV systems per unit electricity production. The average CO 2 -eq/kWh

9472-451: The diameter of Earth's orbit. However, its size was not known at that time. If Rømer had known the diameter of the Earth's orbit, he would have calculated a speed of 227 000 000  m/s . Another more accurate measurement of the speed of light was performed in Europe by Hippolyte Fizeau in 1849. Fizeau directed a beam of light at a mirror several kilometers away. A rotating cog wheel

9600-490: The difference between the energy expended to harvest an energy source and the amount of energy gained from that harvest. The NEG and EROI also take the operating lifetime of a PV system into account and a working life of 25 to 30 years is typically assumed. From these metrics, the Energy payback Time can be derived by calculation. PV systems using crystalline silicon, by far the majority of the systems in practical use, have such

9728-412: The direction of the voltage periodically reverses, but the current always flows from the higher potential to the lower potential side. Since electric power can flow either into or out of a component, a convention is needed for which direction represents positive power flow. Electric power flowing out of a circuit into a component is arbitrarily defined to have a positive sign, while power flowing into

9856-438: The electrical output of a PV system, the manufacturer must simply add more photovoltaic components. Because of this, economies of scale are important for manufacturers as costs decrease with increasing output. While there are many types of PV systems known to be effective, crystalline silicon PV accounted for around 90% of the worldwide production of PV in 2013. Manufacturing silicon PV systems has several steps. First, polysilicon

9984-407: The environmental impact of PV have focused on carbon dioxide equivalents per kWh or energy pay-back time (EPBT). The EPBT describes the timespan a PV system needs to operate in order to generate the same amount of energy that was used for its manufacture. Another study includes transport energy costs in the EPBT. The EPBT has also been defined completely differently as "the time needed to compensate for

10112-497: The eye. Another supporter of the wave theory was Leonhard Euler . He argued in Nova theoria lucis et colorum (1746) that diffraction could more easily be explained by a wave theory. In 1816 André-Marie Ampère gave Augustin-Jean Fresnel an idea that the polarization of light can be explained by the wave theory if light were a transverse wave . Later, Fresnel independently worked out his own wave theory of light and presented it to

10240-434: The eyes and rays from a source such as the sun. In about 300 BC, Euclid wrote Optica , in which he studied the properties of light. Euclid postulated that light travelled in straight lines and he described the laws of reflection and studied them mathematically. He questioned that sight is the result of a beam from the eye, for he asks how one sees the stars immediately, if one closes one's eyes, then opens them at night. If

10368-437: The fifth century BC, Empedocles postulated that everything was composed of four elements ; fire, air, earth and water. He believed that goddess Aphrodite made the human eye out of the four elements and that she lit the fire in the eye which shone out from the eye making sight possible. If this were true, then one could see during the night just as well as during the day, so Empedocles postulated an interaction between rays from

10496-431: The first years of between 3% and 4%. However, other technologies, such as CIGS, show much lower degradation rates, even in those early years. Overall the manufacturing process of creating solar photovoltaics is simple in that it does not require the culmination of many complex or moving parts. Because of the solid-state nature of PV systems, they often have relatively long lifetimes, anywhere from 10 to 30 years. To increase

10624-691: The following countries had a high-quality grid infrastructure as in Europe, in 2020 it was calculated it would take 1.28 years in Ottawa , Canada, for a rooftop photovoltaic system to produce the same amount of energy as required to manufacture the silicon in the modules in it (excluding the silver, glass, mounts and other components), 0.97 years in Catania , Italy , and 0.4 years in Jaipur , India. Outside of Europe, where net grid efficiencies are lower, it would take longer. This ' energy payback time ' can be seen as

10752-425: The force of pressure acting on the back. Hence, as the resultant of the two forces, there remains a force that counteracts the motion of the plate and that increases with the velocity of the plate. We will call this resultant 'radiation friction' in brief." Usually light momentum is aligned with its direction of motion. However, for example in evanescent waves momentum is transverse to direction of propagation. In

10880-412: The higher, so positive charges move from the negative to the positive terminal, work will be done on the charges, and energy is being converted to electric potential energy from some other type of energy, such as mechanical energy or chemical energy . Devices in which this occurs are called active devices or power sources ; such as electric generators and batteries. Some devices can be either

11008-421: The human eye responds to light. The cone cells in the human eye are of three types which respond differently across the visible spectrum and the cumulative response peaks at a wavelength of around 555 nm. Therefore, two sources of light which produce the same intensity (W/m ) of visible light do not necessarily appear equally bright. The photometry units are designed to take this into account and therefore are

11136-443: The impact and potential impact of various types of PV, but these estimates are usually restricted to simply assessing energy costs of the manufacture and/or transport , because these are new technologies and the total environmental impact of their components and disposal methods are unknown, even for commercially available first generation solar cells , let alone experimental prototypes with no commercial viability. Thus, estimates of

11264-418: The infrared and only a fraction in the visible spectrum. The peak of the black-body spectrum is in the deep infrared, at about 10 micrometre wavelength, for relatively cool objects like human beings. As the temperature increases, the peak shifts to shorter wavelengths, producing first a red glow, then a white one and finally a blue-white colour as the peak moves out of the visible part of the spectrum and into

11392-401: The infrared radiation. EMR in this range causes molecular vibration and heating effects, which is how these animals detect it. Above the range of visible light, ultraviolet light becomes invisible to humans, mostly because it is absorbed by the cornea below 360 nm and the internal lens below 400 nm. Furthermore, the rods and cones located in the retina of the human eye cannot detect

11520-410: The junction temperature. The values of these parameters, which can be found in any data sheet of the photovoltaic module, are the following: Techniques for estimating these coefficients from experimental data can be found in the literature. The ability of solar modules to withstand damage by rain, hail , heavy snow load, and cycles of heat and cold varies by manufacturer, although most solar panels on

11648-426: The luminous body, rejecting the "forms" of Ibn al-Haytham and Witelo as well as the "species" of Roger Bacon , Robert Grosseteste and Johannes Kepler . In 1637 he published a theory of the refraction of light that assumed, incorrectly, that light travelled faster in a denser medium than in a less dense medium. Descartes arrived at this conclusion by analogy with the behaviour of sound waves. Although Descartes

11776-437: The module changes as lighting, temperature and load conditions change, so there is never one specific voltage at which the module operates. Performance varies depending on geographic location, time of day, the day of the year, amount of solar irradiance , direction and tilt of modules, cloud cover, shading, soiling , state of charge, and temperature. Performance of a module or panel can be measured at different time intervals with

11904-418: The most important component of solar panels, which accounts for much of the energy use and greenhouse gas emissions, is the refining of the polysilicon. As to how much percentage of the EPBT this silicon depends on the type of system. A fully autarkic system requires additional components ('Balance of System', the power inverters , storage, etc.) which significantly increase the energy cost of manufacture, but in

12032-413: The movement of matter. He wrote, "radiation will exert pressure on both sides of the plate. The forces of pressure exerted on the two sides are equal if the plate is at rest. However, if it is in motion, more radiation will be reflected on the surface that is ahead during the motion (front surface) than on the back surface. The backwardacting force of pressure exerted on the front surface is thus larger than

12160-531: The negative (−) terminal, work is done by the charges on the device. The potential energy of the charges due to the voltage between the terminals is converted to kinetic energy in the device. These devices are called passive components or loads ; they 'consume' electric power from the circuit, converting it to other forms of energy such as mechanical work , heat, light, etc. Examples are electrical appliances , such as light bulbs , electric motors , and electric heaters . In alternating current (AC) circuits

12288-450: The opposite. At that time, the speed of light could not be measured accurately enough to decide which theory was correct. The first to make a sufficiently accurate measurement was Léon Foucault , in 1850. His result supported the wave theory, and the classical particle theory was finally abandoned (only to partly re-emerge in the twentieth century as photons in quantum theory ). Electric power In common parlance, electric power

12416-457: The overall performance of the plant. There are several studies dealing with the power degradation analysis of modules based on different photovoltaic technologies available in the literature. According to a recent study, the degradation of crystalline silicon modules is very regular, oscillating between 0.8% and 1.0% per year. On the other hand, if we analyze the performance of thin-film photovoltaic modules, an initial period of strong degradation

12544-462: The performance of a complete string. Furthermore, not all modules in the same installation decrease their performance at exactly the same rate. Given a set of modules exposed to long-term outdoor conditions, the individual degradation of the main electrical parameters and the increase in their dispersion must be considered. As each module tends to degrade differently, the behavior of the modules will be increasingly different over time, negatively affecting

12672-436: The popular description of light being "stopped" in these experiments refers only to light being stored in the excited states of atoms, then re-emitted at an arbitrary later time, as stimulated by a second laser pulse. During the time it had "stopped", it had ceased to be light. The study of light and the interaction of light and matter is termed optics . The observation and study of optical phenomena such as rainbows and

12800-569: The portion of time during the useful lifetime of the module in which the energy production is polluting. At best, this means that a 30-year old panel has produced clean energy for 97% of its lifetime, or that the silicon in the modules in a solar panel produce 97% less greenhouse gas emissions than a coal-fired plant for the same amount of energy (assuming and ignoring many things). Some studies have looked beyond EPBT and GWP to other environmental effects. In one such study, conventional energy mix in Greece

12928-443: The power output of a solar cell and the working temperature of its junction depends on the semiconductor material, and is due to the influence of T on the concentration, lifetime, and mobility of the intrinsic carriers, i.e., electrons and gaps. inside the photovoltaic cell. Temperature sensitivity is usually described by temperature coefficients, each of which expresses the derivative of the parameter to which it refers with respect to

13056-404: The process of "doping" the silicon substrate to lower the activation energy thereby making the panel more efficient in converting photons to retrievable electrons. Chemicals such as boron (p-type) are applied into the semiconductor crystal in order to create donor and acceptor energy levels substantially closer to the valence and conductor bands. In doing so, the addition of boron impurity allows

13184-483: The production process itself will not become more efficient in the future. Nonetheless, the energy payback time has shortened significantly over the last years, as crystalline silicon cells became ever more efficient in converting sunlight, while the thickness of the wafer material was constantly reduced and therefore required less silicon for its manufacture. Within the last ten years, the amount of silicon used for solar cells declined from 16 to 6 grams per watt-peak . In

13312-479: The p–n junction also influences the main electrical parameters: the short circuit current ISC, the open circuit voltage VOC and the maximum power Pmax. In general, it is known that VOC shows a significant inverse correlation with T, while for ISC this correlation is direct, but weaker, so that this increase does not compensate for the decrease in VOC. As a consequence, Pmax decreases when T increases. This correlation between

13440-780: The quantities as vectors. Real power is represented as a horizontal vector and reactive power is represented as a vertical vector. The apparent power vector is the hypotenuse of a right triangle formed by connecting the real and reactive power vectors. This representation is often called the power triangle . Using the Pythagorean Theorem , the relationship among real, reactive and apparent power is: (apparent power) 2 = (real power) 2 + (reactive power) 2 {\displaystyle {\text{(apparent power)}}^{2}={\text{(real power)}}^{2}+{\text{(reactive power)}}^{2}} Real and reactive powers can also be calculated directly from

13568-542: The quantum efficiency value, as they affect "external quantum efficiency". Recombination losses are accounted for by the quantum efficiency, V OC ratio, and fill factor values. Resistive losses are predominantly accounted for by the fill factor value, but also contribute to the quantum efficiency and V OC ratio values. Module performance is generally rated under standard test conditions (STC): irradiance of 1,000 W/m , solar spectrum of AM 1.5 and module temperature at 25 °C. The actual voltage and current output of

13696-702: The range of 400–700 nanometres (nm), corresponding to frequencies of 750–420 terahertz . The visible band sits adjacent to the infrared (with longer wavelengths and lower frequencies) and the ultraviolet (with shorter wavelengths and higher frequencies), called collectively optical radiation . In physics , the term "light" may refer more broadly to electromagnetic radiation of any wavelength, whether visible or not. In this sense, gamma rays , X-rays , microwaves and radio waves are also light. The primary properties of light are intensity , propagation direction, frequency or wavelength spectrum , and polarization . Its speed in vacuum , 299 792 458  m/s ,

13824-536: The same period, the thickness of a c-Si wafer was reduced from 300 μm, or microns , to about 160–190 μm. The sawing techniques that slice crystalline silicon ingots into wafers have also improved by reducing the kerf loss and making it easier to recycle the silicon sawdust. Crystalline silicon modules are the most extensively studied PV type in terms of LCA since they are the most commonly used. Mono-crystalline silicon photovoltaic systems (mono-si) have an average efficiency of 14.0%. The cells tend to follow

13952-521: The simple equation P = IV may be replaced by a more complex calculation. The closed surface integral of the cross-product of the electric field intensity and magnetic field intensity vectors gives the total instantaneous power (in watts) out of the volume: ℘ = ∮ area ( E × H ) ⋅ d A . {\displaystyle \wp =\oint _{\text{area}}(\mathbf {E} \times \mathbf {H} )\cdot d\mathbf {A} .} The result

14080-540: The size of rooms that provide standby power for telephone exchanges and computer data centers . The electric power industry provides the production and delivery of power, in sufficient quantities to areas that need electricity , through a grid connection . The grid distributes electrical energy to customers. Electric power is generated by central power stations or by distributed generation . The electric power industry has gradually been trending towards deregulation – with emerging players offering consumers competition to

14208-458: The specific application and prepared for shipping and installation. Solar photovoltaic power is not entirely "clean energy": production produces greenhouse gas emissions, materials used to build the cells are potentially unsustainable and will run out eventually, the technology uses toxic substances which cause pollution, and there are no viable technologies for recycling solar waste. Data required to investigate their impact are sometimes affected by

14336-601: The spectrum of each atom. Emission can be spontaneous , as in light-emitting diodes , gas discharge lamps (such as neon lamps and neon signs , mercury-vapor lamps , etc.) and flames (light from the hot gas itself—so, for example, sodium in a gas flame emits characteristic yellow light). Emission can also be stimulated , as in a laser or a microwave maser . Deceleration of a free charged particle, such as an electron , can produce visible radiation: cyclotron radiation , synchrotron radiation and bremsstrahlung radiation are all examples of this. Particles moving through

14464-435: The speed of light throughout history. Galileo attempted to measure the speed of light in the seventeenth century. An early experiment to measure the speed of light was conducted by Ole Rømer , a Danish physicist, in 1676. Using a telescope , Rømer observed the motions of Jupiter and one of its moons , Io . Noting discrepancies in the apparent period of Io's orbit, he calculated that light takes about 22 minutes to traverse

14592-406: The sun". The Indian Buddhists , such as Dignāga in the fifth century and Dharmakirti in the seventh century, developed a type of atomism that is a philosophy about reality being composed of atomic entities that are momentary flashes of light or energy. They viewed light as being an atomic entity equivalent to energy. René Descartes (1596–1650) held that light was a mechanical property of

14720-645: The technically improved Daniell cell in 1836, batteries have become a common power source for many household and industrial applications. According to a 2005 estimate, the worldwide battery industry generates US$ 48 billion in sales each year, with 6% annual growth. There are two types of batteries: primary batteries (disposable batteries), which are designed to be used once and discarded, and secondary batteries (rechargeable batteries), which are designed to be recharged and used multiple times. Batteries are available in many sizes; from miniature button cells used to power hearing aids and wristwatches to battery banks

14848-404: The time of testing, the test modules are binned according to their test results, and a typical manufacturer might rate their modules in 5 W increments, and either rate them at +/- 3%, +/-5%, +3/-0% or +5/-0%. The performance of a photovoltaic (PV) module depends on the environmental conditions, mainly on the global incident irradiance G in the plane of the module. However, the temperature T of

14976-409: The total renewable- and non-renewable primary energy required during the life cycle of a PV system" in another study, which also included installation costs. This energy amortization, given in years, is also referred to as break-even energy payback time . The lower the EPBT, the lower the environmental cost of solar power . The EPBT depends vastly on the location where the PV system is installed (e.g.

15104-424: The traditional public utility companies. Electric power, produced from central generating stations and distributed over an electrical transmission grid, is widely used in industrial, commercial, and consumer applications. A country's per capita electric power consumption correlates with its industrial development. Electric motors power manufacturing machinery and propel subways and railway trains. Electric lighting

15232-486: The ultraviolet. These colours can be seen when metal is heated to "red hot" or "white hot". Blue-white thermal emission is not often seen, except in stars (the commonly seen pure-blue colour in a gas flame or a welder 's torch is in fact due to molecular emission, notably by CH radicals emitting a wavelength band around 425 nm and is not seen in stars or pure thermal radiation). Atoms emit and absorb light at characteristic energies. This produces " emission lines " in

15360-624: The very short (below 360 nm) ultraviolet wavelengths and are in fact damaged by ultraviolet. Many animals with eyes that do not require lenses (such as insects and shrimp) are able to detect ultraviolet, by quantum photon-absorption mechanisms, in much the same chemical way that humans detect visible light. Various sources define visible light as narrowly as 420–680 nm to as broadly as 380–800 nm. Under ideal laboratory conditions, people can see infrared up to at least 1,050 nm; children and young adults may perceive ultraviolet wavelengths down to about 310–313 nm. Plant growth

15488-427: The visible region of the electromagnetic spectrum when plotted in wavelength units, and roughly 44% of the radiation that reaches the ground is visible. Another example is incandescent light bulbs , which emit only around 10% of their energy as visible light and the remainder as infrared. A common thermal light source in history is the glowing solid particles in flames , but these also emit most of their radiation in

15616-480: The wave theory was that light waves, like sound waves, would need a medium for transmission. The existence of the hypothetical substance luminiferous aether proposed by Huygens in 1678 was cast into strong doubt in the late nineteenth century by the Michelson–Morley experiment . Newton's corpuscular theory implied that light would travel faster in a denser medium, while the wave theory of Huygens and others implied

15744-466: Was compared to multi-si PV and found a 95% overall reduction in effects including carcinogens, eco-toxicity, acidification, eutrophication, and eleven others. Cadmium telluride (CdTe) is one of the fastest-growing thin film based solar cells which are collectively known as second-generation devices. This new thin-film device also shares similar performance restrictions ( Shockley-Queisser efficiency limit ) as conventional Si devices but promises to lower

15872-576: Was emitted in all directions as a series of waves in a medium called the luminiferous aether . As waves are not affected by gravity, it was assumed that they slowed down upon entering a denser medium. The wave theory predicted that light waves could interfere with each other like sound waves (as noted around 1800 by Thomas Young ). Young showed by means of a diffraction experiment that light behaved as waves. He also proposed that different colours were caused by different wavelengths of light and explained colour vision in terms of three-coloured receptors in

16000-432: Was for the first time qualitatively explained by Newton using the particle theory. Étienne-Louis Malus in 1810 created a mathematical particle theory of polarization. Jean-Baptiste Biot in 1812 showed that this theory explained all known phenomena of light polarization. At that time the polarization was considered as the proof of the particle theory. To explain the origin of colours , Robert Hooke (1635–1703) developed

16128-404: Was incorrect about the relative speeds, he was correct in assuming that light behaved like a wave and in concluding that refraction could be explained by the speed of light in different media. Descartes is not the first to use the mechanical analogies but because he clearly asserts that light is only a mechanical property of the luminous body and the transmitting medium, Descartes's theory of light

16256-521: Was placed in the path of the light beam as it traveled from the source, to the mirror and then returned to its origin. Fizeau found that at a certain rate of rotation, the beam would pass through one gap in the wheel on the way out and the next gap on the way back. Knowing the distance to the mirror, the number of teeth on the wheel and the rate of rotation, Fizeau was able to calculate the speed of light as 313 000 000  m/s . Léon Foucault carried out an experiment which used rotating mirrors to obtain

16384-567: Was to power orbiting satellites and other spacecraft , but today the majority of photovoltaic modules are used for grid-connected systems for power generation. In this case an inverter is required to convert the DC to AC . There is also a smaller market for stand alone systems for remote dwellings, boats , recreational vehicles , electric cars , roadside emergency telephones, remote sensing , and cathodic protection of pipelines . Photovoltaic power generation employs solar modules composed of

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