The World Green Building Council ( WorldGBC ) is a non-profit organisation and global network of national Green Building Councils (GBCs). It has member councils in over 70 countries worldwide, which collectively have 49,000 members (25,000 member companies and 24,000 individual members).
82-475: The organisation is committed to achieving the following goals by 2050: limiting global temperature rises to 2 degrees Celsius; reducing the building and construction sector's CO 2 emissions by 84 gigatonnes; and ensuring all buildings have net zero emissions. These goals will ensure the buildings and construction sector plays its part in delivering on the ambition of the Paris Agreement . In 1993,
164-424: A chemical compound ; the concept is most readily understood when considering pure chemical substances . It follows from their being composed of fixed proportions of two or more types of atoms that chemical compounds can be converted, via chemical reaction , into compounds or substances each having fewer atoms. A chemical formula is a way of expressing information about the proportions of atoms that constitute
246-419: A solid-state reaction , or the electron transfer reaction of reactive metals with reactive non-metals, such as halogen gases. Ionic compounds typically have high melting and boiling points , and are hard and brittle . As solids they are almost always electrically insulating , but when melted or dissolved they become highly conductive , because the ions are mobilized. An intermetallic compound
328-669: A Corporate Advisory Board was formed to deliver strategic insight from the industry to the WorldGBC Board. By 2012, there were 71 member GBCs. The WorldGBC began to produce reports such as The Business Case for Green Building in 2013 and Health, Wellbeing and Productivity in Offices in 2014. In 2015, the WorldGBC Board agreed a new strategic plan for the organisation with five focus areas: Membership; Regional Networks; Projects and Partnerships; Marketing, Communications and Influence; and Governance and Operations. WorldGBC's mission
410-610: A Secretariat for WorldGBC was formally established in Toronto , Ontario, Canada, supported by the Toronto and Region Conservation Authority – which continues to work with WorldGBC. Start-up funding of over $ 1 million per year for three years was provided by the Government of Ontario . Since then, WorldGBC has seen growth and evolution in its focus and structure. In 2009, WorldGBC launched five regional networks and three membership levels (Prospective, Emerging and Established). In 2010
492-412: A continuous three-dimensional network, usually in a crystalline structure . Ionic compounds containing basic ions hydroxide (OH ) or oxide (O ) are classified as bases. Ionic compounds without these ions are also known as salts and can be formed by acid–base reactions . Ionic compounds can also be produced from their constituent ions by evaporation of their solvent , precipitation , freezing ,
574-516: A decline in basic activity level and information usage at 1000 ppm, when compared to 500 ppm. However a review of the literature found that a reliable subset of studies on the phenomenon of carbon dioxide induced cognitive impairment to only show a small effect on high-level decision making (for concentrations below 5000 ppm). Most of the studies were confounded by inadequate study designs, environmental comfort, uncertainties in exposure doses and differing cognitive assessments used. Similarly
656-527: A disputed marginal case. A chemical formula specifies the number of atoms of each element in a compound molecule, using the standard chemical symbols with numerical subscripts . Many chemical compounds have a unique CAS number identifier assigned by the Chemical Abstracts Service . Globally, more than 350,000 chemical compounds (including mixtures of chemicals) have been registered for production and use. The term "compound"—with
738-611: A glass state similar to other members of its elemental family, like silicon dioxide (silica glass) and germanium dioxide . Unlike silica and germania glasses, however, carbonia glass is not stable at normal pressures and reverts to gas when pressure is released. At temperatures and pressures above the critical point, carbon dioxide behaves as a supercritical fluid known as supercritical carbon dioxide . Table of thermal and physical properties of saturated liquid carbon dioxide: Table of thermal and physical properties of carbon dioxide (CO 2 ) at atmospheric pressure: Carbon dioxide
820-649: A larger, global scale. GBCs are organised into five Regional Networks - powerful, collaborative platforms where they can effectively exchange knowledge, generate new ideas and design solutions that speed up green building in their own markets and across the region. WorldGBC's five main areas are the Americas, Africa, Asia Pacific, Europe, and the Middle East and North Africa. Member GBCs also stand at one of WorldGBC's three levels of development: Prospective, Emerging and Established. WorldGBC's Corporate Advisory Board
902-491: A mature forest will produce as much CO 2 from respiration and decomposition of dead specimens (e.g., fallen branches) as is used in photosynthesis in growing plants. Contrary to the long-standing view that they are carbon neutral, mature forests can continue to accumulate carbon and remain valuable carbon sinks , helping to maintain the carbon balance of Earth's atmosphere. Additionally, and crucially to life on earth, photosynthesis by phytoplankton consumes dissolved CO 2 in
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#1732765180630984-444: A meaning similar to the modern—has been used at least since 1661 when Robert Boyle's The Sceptical Chymist was published. In this book, Boyle variously used the terms "compound", "compounded body", "perfectly mixt body", and "concrete". "Perfectly mixt bodies" included for example gold, lead, mercury, and wine. While the distinction between compound and mixture is not so clear, the distinction between element and compound
1066-477: A molecule touches a surface or touches another molecule, the two bending modes can differ in frequency because the interaction is different for the two modes. Some of the vibrational modes are observed in the infrared (IR) spectrum : the antisymmetric stretching mode at wavenumber 2349 cm (wavelength 4.25 μm) and the degenerate pair of bending modes at 667 cm (wavelength 15.0 μm). The symmetric stretching mode does not create an electric dipole so
1148-566: A particular chemical compound, using chemical symbols for the chemical elements, and subscripts to indicate the number of atoms involved. For example, water is composed of two hydrogen atoms bonded to one oxygen atom: the chemical formula is H 2 O. In the case of non-stoichiometric compounds , the proportions may be reproducible with regard to their preparation, and give fixed proportions of their component elements, but proportions that are not integral [e.g., for palladium hydride , PdH x (0.02 < x < 0.58)]. Chemical compounds have
1230-496: A positively charged cation . The nonmetal will gain the electrons from the metal, making the nonmetal a negatively charged anion . As outlined, ionic bonds occur between an electron donor, usually a metal, and an electron acceptor, which tends to be a nonmetal. Hydrogen bonding occurs when a hydrogen atom bonded to an electronegative atom forms an electrostatic connection with another electronegative atom through interacting dipoles or charges. A compound can be converted to
1312-410: A possible starting point for carbon capture and storage by amine gas treating . Only very strong nucleophiles, like the carbanions provided by Grignard reagents and organolithium compounds react with CO 2 to give carboxylates : In metal carbon dioxide complexes , CO 2 serves as a ligand , which can facilitate the conversion of CO 2 to other chemicals. The reduction of CO 2 to CO
1394-678: A range of other supporters such as global project sponsors, regional project sponsors, regional partners and pro bono supporters. WorldGBC has 17 members of staff, based in two main offices, in London and Toronto. The organisation is led by CEO Terri Wills. Five members of staff are regional heads, based in Colombia, Kenya, Singapore, London and Jordan. WorldGBC's global projects enable GBCs to work together to tackle key environmental, economic and societal challenges. Current global projects include 'Advancing Net Zero', which aims to promote and support
1476-640: A selected theme: Since 2014 WorldGBC has hosted a congress - a gathering of its member councils and an international conference. The congress is jointly organised by WorldGBC and the host country's GBC. Congresses have been held in São Paulo, Brazil (2014), Hong Kong, China (2015), Stockholm, Sweden (2016), and Jaipur, India (2017). The 2018 congress will be in Toronto, Canada, and 2019's will be in Paris, France. WorldGBC presents two major annual awards recognising
1558-447: A solid state dependent on how low the temperature of the environment is. A covalent bond , also known as a molecular bond, involves the sharing of electrons between two atoms. Primarily, this type of bond occurs between elements that fall close to each other on the periodic table of elements , yet it is observed between some metals and nonmetals. This is due to the mechanism of this type of bond. Elements that fall close to each other on
1640-416: A study on the effects of the concentration of CO 2 in motorcycle helmets has been criticized for having dubious methodology in not noting the self-reports of motorcycle riders and taking measurements using mannequins. Further when normal motorcycle conditions were achieved (such as highway or city speeds) or the visor was raised the concentration of CO 2 declined to safe levels (0.2%). Poor ventilation
1722-469: A unique and defined chemical structure held together in a defined spatial arrangement by chemical bonds . Chemical compounds can be molecular compounds held together by covalent bonds , salts held together by ionic bonds , intermetallic compounds held together by metallic bonds , or the subset of chemical complexes that are held together by coordinate covalent bonds . Pure chemical elements are generally not considered chemical compounds, failing
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#17327651806301804-469: Is Emiliania huxleyi whose calcite scales have formed the basis of many sedimentary rocks such as limestone , where what was previously atmospheric carbon can remain fixed for geological timescales. Plants can grow as much as 50% faster in concentrations of 1,000 ppm CO 2 when compared with ambient conditions, though this assumes no change in climate and no limitation on other nutrients. Elevated CO 2 levels cause increased growth reflected in
1886-419: Is 304.128(15) K (30.978(15) °C) at 7.3773(30) MPa (72.808(30) atm). Another form of solid carbon dioxide observed at high pressure is an amorphous glass-like solid. This form of glass, called carbonia , is produced by supercooling heated CO 2 at extreme pressures (40–48 GPa , or about 400,000 atmospheres) in a diamond anvil . This discovery confirmed the theory that carbon dioxide could exist in
1968-453: Is a trace gas in Earth's atmosphere at 421 parts per million (ppm) , or about 0.042% (as of May 2022) having risen from pre-industrial levels of 280 ppm or about 0.028%. Burning fossil fuels is the main cause of these increased CO 2 concentrations, which are the primary cause of climate change . Its concentration in Earth's pre-industrial atmosphere since late in
2050-447: Is a weak acid , because its ionization in water is incomplete. The hydration equilibrium constant of carbonic acid is, at 25 °C: Hence, the majority of the carbon dioxide is not converted into carbonic acid, but remains as CO 2 molecules, not affecting the pH. The relative concentrations of CO 2 , H 2 CO 3 , and the deprotonated forms HCO − 3 ( bicarbonate ) and CO 2− 3 ( carbonate ) depend on
2132-445: Is a central theme. Quicksilver ... with Aqua fortis will be brought into a ... white Powder ... with Sulphur it will compose a blood-red and volatile Cinaber. And yet out of all these exotick Compounds, we may recover the very same running Mercury. Boyle used the concept of "corpuscles"—or "atomes", as he also called them—to explain how a limited number of elements could combine into a vast number of compounds: If we assigne to
2214-856: Is a select group of companies which are leaders on sustainability and which serve to guide WorldGBC on its strategy and activities. The financial support of the Corporate Advisory Board enables WorldGBC to advance green buildings as an effective solution to environmental, social and economic issues, and help member Green Building Councils to grow and flourish. There are currently members of the Corporate Advisory Board: AkzoNobel, City Developments Ltd, JLL, JPMorgan Chase, Keppel Land, Lendlease, Majid Al Futtaim, Philips, Saint-Gobain, Shaw Contract, United Technologies Corporation and Volvo Construction Equipment. In addition to its Corporate Advisory Board, WorldGBC has
2296-403: Is a type of metallic alloy that forms an ordered solid-state compound between two or more metallic elements. Intermetallics are generally hard and brittle, with good high-temperature mechanical properties. They can be classified as stoichiometric or nonstoichiometric intermetallic compounds. A coordination complex consists of a central atom or ion, which is usually metallic and is called
2378-415: Is an end product of cellular respiration in organisms that obtain energy by breaking down sugars, fats and amino acids with oxygen as part of their metabolism . This includes all plants, algae and animals and aerobic fungi and bacteria. In vertebrates , the carbon dioxide travels in the blood from the body's tissues to the skin (e.g., amphibians ) or the gills (e.g., fish ), from where it dissolves in
2460-414: Is called sublimation . The symmetry of a carbon dioxide molecule is linear and centrosymmetric at its equilibrium geometry. The length of the carbon–oxygen bond in carbon dioxide is 116.3 pm , noticeably shorter than the roughly 140 pm length of a typical single C–O bond, and shorter than most other C–O multiply bonded functional groups such as carbonyls . Since it is centrosymmetric,
2542-452: Is comparable to benzaldehyde or strongly electrophilic α,β-unsaturated carbonyl compounds . However, unlike electrophiles of similar reactivity, the reactions of nucleophiles with CO 2 are thermodynamically less favored and are often found to be highly reversible. The reversible reaction of carbon dioxide with amines to make carbamates is used in CO 2 scrubbers and has been suggested as
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2624-493: Is neutral overall, but consists of positively charged ions called cations and negatively charged ions called anions . These can be simple ions such as the sodium (Na ) and chloride (Cl ) in sodium chloride , or polyatomic species such as the ammonium ( NH 4 ) and carbonate ( CO 3 ) ions in ammonium carbonate . Individual ions within an ionic compound usually have multiple nearest neighbours, so are not considered to be part of molecules, but instead part of
2706-602: Is not observed in IR spectroscopy, but it is detected in Raman spectroscopy at 1388 cm (wavelength 7.20 μm), with a Fermi resonance doublet at 1285 cm . In the gas phase, carbon dioxide molecules undergo significant vibrational motions and do not keep a fixed structure. However, in a Coulomb explosion imaging experiment, an instantaneous image of the molecular structure can be deduced. Such an experiment has been performed for carbon dioxide. The result of this experiment, and
2788-632: Is one of the main causes of excessive CO 2 concentrations in closed spaces, leading to poor indoor air quality . Carbon dioxide differential above outdoor concentrations at steady state conditions (when the occupancy and ventilation system operation are sufficiently long that CO 2 concentration has stabilized) are sometimes used to estimate ventilation rates per person. Higher CO 2 concentrations are associated with occupant health, comfort and performance degradation. ASHRAE Standard 62.1–2007 ventilation rates may result in indoor concentrations up to 2,100 ppm above ambient outdoor conditions. Thus if
2870-402: Is operating effectively as a not for profit organisation and delivering on its mission. GBCs are independent, non-profit organisations made up of businesses and organisations working in the building and construction industry. As members of WorldGBC, they work to advance green building in their own countries, as well as working with other GBCs to achieve environmental, economic and social goals on
2952-410: Is ordinarily a difficult and slow reaction: The redox potential for this reaction near pH 7 is about −0.53 V versus the standard hydrogen electrode . The nickel-containing enzyme carbon monoxide dehydrogenase catalyses this process. Photoautotrophs (i.e. plants and cyanobacteria ) use the energy contained in sunlight to photosynthesize simple sugars from CO 2 absorbed from
3034-405: Is produced as a by-product. Ribulose-1,5-bisphosphate carboxylase oxygenase , commonly abbreviated to RuBisCO, is the enzyme involved in the first major step of carbon fixation, the production of two molecules of 3-phosphoglycerate from CO 2 and ribulose bisphosphate , as shown in the diagram at left. RuBisCO is thought to be the single most abundant protein on Earth. Phototrophs use
3116-510: Is put to commercial use, mostly in the fertilizer industry and in the oil and gas industry for enhanced oil recovery . Other commercial applications include food and beverage production, metal fabrication, cooling, fire suppression and stimulating plant growth in greenhouses. Carbon dioxide cannot be liquefied at atmospheric pressure. Low-temperature carbon dioxide is commercially used in its solid form, commonly known as " dry ice ". The solid-to-gas phase transition occurs at 194.7 Kelvin and
3198-425: Is released from organic materials when they decay or combust, such as in forest fires. When carbon dioxide dissolves in water, it forms carbonate and mainly bicarbonate ( HCO − 3 ), which causes ocean acidification as atmospheric CO 2 levels increase. Carbon dioxide is 53% more dense than dry air, but is long lived and thoroughly mixes in the atmosphere. About half of excess CO 2 emissions to
3280-639: Is therefore not a compound. A compound can be transformed into a different substance by a chemical reaction , which may involve interactions with other substances. In this process, bonds between atoms may be broken and/or new bonds formed. There are four major types of compounds, distinguished by how the constituent atoms are bonded together. Molecular compounds are held together by covalent bonds ; ionic compounds are held together by ionic bonds ; intermetallic compounds are held together by metallic bonds ; coordination complexes are held together by coordinate covalent bonds . Non-stoichiometric compounds form
3362-405: Is to "create green buildings for everyone, everywhere" - enabling people to thrive both today and tomorrow. WorldGBC has a board of directors, comprising building industry professionals who hold senior positions on the staff or boards of member GBCs (or who are closely affiliated with them). The board's role is to advise and oversee WorldGBC's organisational strategy and governance, and to ensure it
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3444-509: The Precambrian was regulated by organisms and geological features. Plants , algae and cyanobacteria use energy from sunlight to synthesize carbohydrates from carbon dioxide and water in a process called photosynthesis , which produces oxygen as a waste product. In turn, oxygen is consumed and CO 2 is released as waste by all aerobic organisms when they metabolize organic compounds to produce energy by respiration . CO 2
3526-425: The carbonate ion ( CO 2− 3 ): In organisms, carbonic acid production is catalysed by the enzyme known as carbonic anhydrase . In addition to altering its acidity, the presence of carbon dioxide in water also affects its electrical properties. When carbon dioxide dissolves in desalinated water, the electrical conductivity increases significantly from below 1 μS/cm to nearly 30 μS/cm. When heated,
3608-452: The coordination centre , and a surrounding array of bound molecules or ions, that are in turn known as ligands or complexing agents. Many metal-containing compounds, especially those of transition metals , are coordination complexes. A coordination complex whose centre is a metal atom is called a metal complex of d block element. Compounds are held together through a variety of different types of bonding and forces. The differences in
3690-449: The oxygen molecule (O 2 ); or it may be heteronuclear , a chemical compound composed of more than one element, as with water (two hydrogen atoms and one oxygen atom; H 2 O). A molecule is the smallest unit of a substance that still carries all the physical and chemical properties of that substance. An ionic compound is a chemical compound composed of ions held together by electrostatic forces termed ionic bonding . The compound
3772-467: The pH . As shown in a Bjerrum plot , in neutral or slightly alkaline water (pH > 6.5), the bicarbonate form predominates (>50%) becoming the most prevalent (>95%) at the pH of seawater. In very alkaline water (pH > 10.4), the predominant (>50%) form is carbonate. The oceans, being mildly alkaline with typical pH = 8.2–8.5, contain about 120 mg of bicarbonate per liter. Being diprotic , carbonic acid has two acid dissociation constants ,
3854-426: The (incorrect) assumption that all dissolved CO 2 is present as carbonic acid, so that Since most of the dissolved CO 2 remains as CO 2 molecules, K a1 (apparent) has a much larger denominator and a much smaller value than the true K a1 . The bicarbonate ion is an amphoteric species that can act as an acid or as a base, depending on pH of the solution. At high pH, it dissociates significantly into
3936-474: The Advancing Net Zero project; and 31 countries making green building policy changes at either the city, regional or national level, with contributions from GBC. Carbon dioxide Carbon dioxide is a chemical compound with the chemical formula CO 2 . It is made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in
4018-907: The Corpuscles, whereof each Element consists, a peculiar size and shape ... such ... Corpuscles may be mingled in such various Proportions, and ... connected so many ... wayes, that an almost incredible number of ... Concretes may be compos’d of them. In his Logick , published in 1724, the English minister and logician Isaac Watts gave an early definition of chemical element, and contrasted element with chemical compound in clear, modern terms. Among Substances, some are called Simple, some are Compound ... Simple Substances ... are usually called Elements, of which all other Bodies are compounded: Elements are such Substances as cannot be resolved, or reduced, into two or more Substances of different Kinds. ... Followers of Aristotle made Fire, Air, Earth and Water to be
4100-411: The Earth. Other compounds regarded as chemically identical may have varying amounts of heavy or light isotopes of the constituent elements, which changes the ratio of elements by mass slightly. A molecule is an electrically neutral group of two or more atoms held together by chemical bonds. A molecule may be homonuclear , that is, it consists of atoms of one chemical element, as with two atoms in
4182-631: The Energy Efficiency Mortgage Action Plan (EeMAP) initiative in Europe which is exploring the link between energy efficiency and borrower's reduced probability of default and the increase in value of energy efficient properties. World Green Building Week is an annual global event led by WorldGBC, its network of more than 70 GBCs and their 49,000 members. Beginning in 2009, the week involves special events promoting public awareness of sustainability and green building around
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#17327651806304264-534: The Truth ;; tho' they are not all agreed ... Compound Substances are made up of two or more simple Substances ... So a Needle is simple Body, being made only of Steel; but a Sword or a Knife is a compound because its ... Handle is made of Materials different from the Blade. Any substance consisting of two or more different types of atoms ( chemical elements ) in a fixed stoichiometric proportion can be termed
4346-800: The WorldGBC Congress. WorldGBC also hosts the Asia Pacific Regional Network Awards every two years, and supports the MENA Green Building Awards. WorldGBC has a partnership with the Global Alliance for Buildings and Construction. It aims to gather the support of countries, cities and public and private organisations to ensure the sector helps to meet the Paris Agreement and global goals on climate change. WorldGBC sits on
4428-590: The acceleration of net zero carbon buildings to 100% by 2050; and 'Better Places for People', which supports GBCs and their members in increasing the demand and supply of green buildings which support the health, wellbeing and productivity of people within them. WorldGBC is also a delivery partner on the 'Building Efficiency Accelerator' (BEA), a partnership of businesses, NGOs and multilateral organisations, which aims to help cities take action to improve their buildings. WorldGBC also has projects which are specific to each of its five regions. Current regional projects include
4510-439: The air and water: Carbon dioxide is colorless. At low concentrations, the gas is odorless; however, at sufficiently high concentrations, it has a sharp, acidic odor. At standard temperature and pressure , the density of carbon dioxide is around 1.98 kg/m , about 1.53 times that of air . Carbon dioxide has no liquid state at pressures below 0.51795(10) MPa (5.11177(99) atm ). At a pressure of 1 atm (0.101325 MPa),
4592-443: The atmosphere are absorbed by land and ocean carbon sinks . These sinks can become saturated and are volatile, as decay and wildfires result in the CO 2 being released back into the atmosphere. CO 2 is eventually sequestered (stored for the long term) in rocks and organic deposits like coal , petroleum and natural gas . Nearly all CO2 produced by humans goes into the atmosphere. Less than 1% of CO2 produced annually
4674-484: The conclusion of theoretical calculations based on an ab initio potential energy surface of the molecule, is that none of the molecules in the gas phase are ever exactly linear. This counter-intuitive result is trivially due to the fact that the nuclear motion volume element vanishes for linear geometries. This is so for all molecules except diatomic molecules . Carbon dioxide is soluble in water, in which it reversibly forms H 2 CO 3 (carbonic acid), which
4756-869: The condition. There are few studies of the health effects of long-term continuous CO 2 exposure on humans and animals at levels below 1%. Occupational CO 2 exposure limits have been set in the United States at 0.5% (5000 ppm) for an eight-hour period. At this CO 2 concentration, International Space Station crew experienced headaches, lethargy, mental slowness, emotional irritation, and sleep disruption. Studies in animals at 0.5% CO 2 have demonstrated kidney calcification and bone loss after eight weeks of exposure. A study of humans exposed in 2.5 hour sessions demonstrated significant negative effects on cognitive abilities at concentrations as low as 0.1% (1000 ppm) CO 2 likely due to CO 2 induced increases in cerebral blood flow. Another study observed
4838-478: The contributions of individuals to the global green building movement. The Chairman's Award is given to individuals who have made an outstanding contribution to the global green building movement, while the David Gottfried Award is presented to individuals whose contribution to the global green building movement has been shown to be unique, innovative and entrepreneurial. These awards are presented at
4920-566: The dispersing effects of wind, it can collect in sheltered/pocketed locations below average ground level, causing animals located therein to be suffocated. Carrion feeders attracted to the carcasses are then also killed. Children have been killed in the same way near the city of Goma by CO 2 emissions from the nearby volcano Mount Nyiragongo . The Swahili term for this phenomenon is mazuku . Adaptation to increased concentrations of CO 2 occurs in humans, including modified breathing and kidney bicarbonate production, in order to balance
5002-541: The effects of blood acidification ( acidosis ). Several studies suggested that 2.0 percent inspired concentrations could be used for closed air spaces (e.g. a submarine ) since the adaptation is physiological and reversible, as deterioration in performance or in normal physical activity does not happen at this level of exposure for five days. Yet, other studies show a decrease in cognitive function even at much lower levels. Also, with ongoing respiratory acidosis , adaptation or compensatory mechanisms will be unable to reverse
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#17327651806305084-510: The first Green Building Council was founded in the US, formed by Rick Fedrizzi , David Gottfried and Mike Italiano with a mission to promote sustainability-focused practices in the building and construction industry. Around the world, other green leaders in the industry looked at the impact of the USGBC and decided to start similar movements in their own countries, led by a GBC. Individuals from across
5166-410: The first one for the dissociation into the bicarbonate (also called hydrogen carbonate) ion ( HCO − 3 ): This is the true first acid dissociation constant, defined as where the denominator includes only covalently bound H 2 CO 3 and does not include hydrated CO 2 (aq). The much smaller and often-quoted value near 4.16 × 10 (or pK a1 = 6.38) is an apparent value calculated on
5248-400: The fixed ratios. Many solid chemical substances—for example many silicate minerals —are chemical substances, but do not have simple formulae reflecting chemically bonding of elements to one another in fixed ratios; even so, these crystalline substances are often called " non-stoichiometric compounds ". It may be argued that they are related to, rather than being chemical compounds, insofar as
5330-513: The four Elements, of which all earthly Things were compounded; and they suppos'd the Heavens to be a Quintessence, or fifth sort of Body, distinct from all these : But, since experimental Philosophy ... have been better understood, this Doctrine has been abundantly refuted. The Chymists make Spirit, Salt, Sulphur, Water and Earth to be their five Elements, because they can reduce all terrestrial Things to these five : This seems to come nearer
5412-469: The gas deposits directly to a solid at temperatures below 194.6855(30) K (−78.4645(30) °C) and the solid sublimes directly to a gas above this temperature. In its solid state, carbon dioxide is commonly called dry ice . Liquid carbon dioxide forms only at pressures above 0.51795(10) MPa (5.11177(99) atm); the triple point of carbon dioxide is 216.592(3) K (−56.558(3) °C) at 0.51795(10) MPa (5.11177(99) atm) (see phase diagram). The critical point
5494-439: The gas state at room temperature and at normally-encountered concentrations it is odorless. As the source of carbon in the carbon cycle , atmospheric CO 2 is the primary carbon source for life on Earth. In the air, carbon dioxide is transparent to visible light but absorbs infrared radiation , acting as a greenhouse gas . Carbon dioxide is soluble in water and is found in groundwater , lakes , ice caps , and seawater . It
5576-643: The globe were supported by the USGBC. Gottfried seeded and managed the formation of the “United Nations of the Green Building Councils” with the mission of supporting the development of GBCs, and uniting them with a common voice and purpose. In 1999, the founding meeting of WorldGBC was held in California, US. In 2002, WorldGBC was officially formed with eight founding GBCs: Australia, Brazil, Canada, India, Japan, Mexico, Spain, and USA. In 2007,
5658-601: The harvestable yield of crops, with wheat, rice and soybean all showing increases in yield of 12–14% under elevated CO 2 in FACE experiments. Increased atmospheric CO 2 concentrations result in fewer stomata developing on plants which leads to reduced water usage and increased water-use efficiency . Studies using FACE have shown that CO 2 enrichment leads to decreased concentrations of micronutrients in crop plants. This may have knock-on effects on other parts of ecosystems as herbivores will need to eat more food to gain
5740-585: The interim steering committee of the Alliance, developing strong governance to support the 24 countries and 72 non-state organisations which are affiliated with it. In December 2017, WorldGBC published its latest annual report, outlining the achievements of the organisation and its global network of GBCs over the previous year. These include 1.24 billion m2 of green building space around the world that has been certified by member Green Building Councils; five new net zero building certifications launched by GBCs through
5822-403: The molecule has no electric dipole moment . As a linear triatomic molecule, CO 2 has four vibrational modes as shown in the diagram. In the symmetric and the antisymmetric stretching modes, the atoms move along the axis of the molecule. There are two bending modes, which are degenerate , meaning that they have the same frequency and same energy, because of the symmetry of the molecule. When
5904-559: The outdoor concentration is 400 ppm, indoor concentrations may reach 2,500 ppm with ventilation rates that meet this industry consensus standard. Concentrations in poorly ventilated spaces can be found even higher than this (range of 3,000 or 4,000 ppm). Chemical compound A chemical compound is a chemical substance composed of many identical molecules (or molecular entities ) containing atoms from more than one chemical element held together by chemical bonds . A molecule consisting of atoms of only one element
5986-536: The periodic table tend to have similar electronegativities , which means they have a similar affinity for electrons. Since neither element has a stronger affinity to donate or gain electrons, it causes the elements to share electrons so both elements have a more stable octet . Ionic bonding occurs when valence electrons are completely transferred between elements. Opposite to covalent bonding, this chemical bond creates two oppositely charged ions. The metals in ionic bonding usually lose their valence electrons, becoming
6068-499: The presence of sufficient oxygen, manifesting as dizziness, headache, visual and hearing dysfunction, and unconsciousness within a few minutes to an hour. Concentrations of more than 10% may cause convulsions, coma, and death. CO 2 levels of more than 30% act rapidly leading to loss of consciousness in seconds. Because it is heavier than air, in locations where the gas seeps from the ground (due to sub-surface volcanic or geothermal activity) in relatively high concentrations, without
6150-496: The products of their photosynthesis as internal food sources and as raw material for the biosynthesis of more complex organic molecules, such as polysaccharides , nucleic acids , and proteins. These are used for their own growth, and also as the basis of the food chains and webs that feed other organisms, including animals such as ourselves. Some important phototrophs, the coccolithophores synthesise hard calcium carbonate scales. A globally significant species of coccolithophore
6232-420: The same amount of protein. The concentration of secondary metabolites such as phenylpropanoids and flavonoids can also be altered in plants exposed to high concentrations of CO 2 . Plants also emit CO 2 during respiration, and so the majority of plants and algae, which use C3 photosynthesis , are only net absorbers during the day. Though a growing forest will absorb many tons of CO 2 each year,
6314-494: The two or more atom requirement, though they often consist of molecules composed of multiple atoms (such as in the diatomic molecule H 2 , or the polyatomic molecule S 8 , etc.). Many chemical compounds have a unique numerical identifier assigned by the Chemical Abstracts Service (CAS): its CAS number . There is varying and sometimes inconsistent nomenclature differentiating substances, which include truly non-stoichiometric examples, from chemical compounds, which require
6396-455: The types of bonds in compounds differ based on the types of elements present in the compound. London dispersion forces are the weakest force of all intermolecular forces . They are temporary attractive forces that form when the electrons in two adjacent atoms are positioned so that they create a temporary dipole . Additionally, London dispersion forces are responsible for condensing non polar substances to liquids, and to further freeze to
6478-535: The upper ocean and thereby promotes the absorption of CO 2 from the atmosphere. Carbon dioxide content in fresh air (averaged between sea-level and 10 kPa level, i.e., about 30 km (19 mi) altitude) varies between 0.036% (360 ppm) and 0.041% (412 ppm), depending on the location. In humans, exposure to CO 2 at concentrations greater than 5% causes the development of hypercapnia and respiratory acidosis . Concentrations of 7% to 10% (70,000 to 100,000 ppm) may cause suffocation, even in
6560-421: The variability in their compositions is often due to either the presence of foreign elements trapped within the crystal structure of an otherwise known true chemical compound , or due to perturbations in structure relative to the known compound that arise because of an excess of deficit of the constituent elements at places in its structure; such non-stoichiometric substances form most of the crust and mantle of
6642-458: The water begins to gradually lose the conductivity induced by the presence of C O 2 {\displaystyle \mathrm {CO_{2}} } , especially noticeable as temperatures exceed 30 °C. The temperature dependence of the electrical conductivity of fully deionized water without CO 2 saturation is comparably low in relation to these data. CO 2 is a potent electrophile having an electrophilic reactivity that
6724-546: The water, or to the lungs from where it is exhaled. During active photosynthesis, plants can absorb more carbon dioxide from the atmosphere than they release in respiration. Carbon fixation is a biochemical process by which atmospheric carbon dioxide is incorporated by plants, algae and cyanobacteria into energy-rich organic molecules such as glucose , thus creating their own food by photosynthesis. Photosynthesis uses carbon dioxide and water to produce sugars from which other organic compounds can be constructed, and oxygen
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