Brier Hill is a neighborhood in Youngstown, Ohio , that was once viewed as the city's " Little Italy ." The neighborhood, which was the site of the city's first Italian settlement, stretches along the western edge of Youngstown's lower north side and encircles St. Anthony 's Church, an Italian-American Roman Catholic parish. Each year, at the end of August, the Brier Hill Fest attracts thousands of visitors from Northeast Ohio and Western Pennsylvania.
88-475: The area encompassing the Brier Hill neighborhood was originally owned by Youngstown industrialist George Tod, who established a farm on the neighborhood's brier-covered hills around 1801. Tod called the agricultural enterprise Brier Hill. This semi-rural area was transformed irrevocably when coal was discovered in the hills in and around Brier Hill. The neighborhood drew thousands of immigrants seeking work in
176-512: A cyclothem . Cyclothems are thought to have their origin in glacial cycles that produced fluctuations in sea level , which alternately exposed and then flooded large areas of continental shelf. The woody tissue of plants is composed mainly of cellulose, hemicellulose, and lignin. Modern peat is mostly lignin, with a content of cellulose and hemicellulose ranging from 5% to 40%. Various other organic compounds, such as waxes and nitrogen- and sulfur-containing compounds, are also present. Lignin has
264-572: A Sister-City/"Cugin" Community of San Pietro Avellana ( Isernia ). San Pietro is a small village in the Apennine hills of Southeastern Italy that is the ancestral home of many Italian Americans in the Youngstown area. Other Italian Neighborhoods in NE Ohio : 41°07′41″N 80°40′16″W / 41.128°N 80.671°W / 41.128; -80.671 Coal Coal
352-616: A bandstand, Modarelli's Salumeria, and the memorial wall. The ground floor of the ITAM Post was once the site of the Forde family butcher shop, owned and operated by Italian immigrants Frank and Catherine Forde (Fiordilisi). The structure's second floor served as the Fordes' residence, where they raised eight children. A concrete marker on the building's facade features the inscription, "Forde 1921". Although many neighborhoods and communities in
440-518: A building is subject to the local fire code, which is ordinarily enforced by the local fire prevention officer. For an Authority Having Jurisdiction , combustibility is defined by the local code. In the National Building Code of Canada , it is defined as follows: BS 476-4:1970 defines a test for combustibility in which a technician heats three specimens of a material in a furnace. Combustibile materials are those for which any of
528-553: A burning match, and spread flame rapidly. The technical definitions vary between countries so the United Nations created the Globally Harmonized System of Classification and Labeling of Chemicals , which defines the flash point temperature of flammable liquids as between 0 and 140 °F (60 °C) and combustible liquids between 140 °F (60 °C) and 200 °F (93 °C). Flammability
616-796: A comprehensive set of rules on combustible dust. When suspended in air (or any oxidizing environment), the fine particles of combustible dust present a potential for explosions. Accumulated dust , even when not suspended in air, remains a fire hazard. The National Fire Protection Association (U.S.) specifically addresses the prevention of fires and dust explosions in agricultural and food products facilities in NFPA Code section 61, and other industries in NFPA Code sections 651–664. Collectors designed to reduce airborne dust account for more than 40 percent of all dust explosions. Other important processes are grinding and pulverizing , transporting powders, filing silos and containers (which produces powder), and
704-466: A flash of fire when ignited by an external source. A lower flash point indicates higher flammability. Materials with flash points below 100 °F (38 °C ) are regulated in the United States by OSHA as potential workplace hazards . The flame point of a material is a temperature value at which sustained flame can be supported on the material once ignited by an external source. Once
792-488: A large market, manufacturers meet TB 117 in products that they distribute across the United States. The proliferation of flame retardants, and especially halogenated organic flame retardants, in furniture across the United States is strongly linked to TB 117. When it became apparent that the risk-benefit ratio of this approach was unfavorable and industry had used falsified documentation (i.e. see David Heimbach ) for
880-445: A liquid, which varies with its temperature, is a measure of how much the vapor of the liquid tends to concentrate in the surrounding atmosphere as the liquid evaporates. Vapor pressure is a major determinant of the flash point and flame point, with higher vapor pressures leading to lower flash points and higher flammability ratings. The International Code Council (ICC) developed fire code requirements to provide adequate protection to
968-573: A post office, and churches. During the early 20th century, the neighborhood hosted at least four churches. These included the Catholic parishes of St. Anthony's, St. Ann's, and St. Casimir 's as well as the Episcopal parish of St. Rocco 's. The neighborhood remained an unincorporated village (outside of Youngstown Township) until 1900, when it was absorbed by the city. Like many urban neighborhoods, Brier Hill faces an uncertain future. Beginning in
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#17327762353671056-417: A process called carbonization . Carbonization proceeds primarily by dehydration , decarboxylation , and demethanation. Dehydration removes water molecules from the maturing coal via reactions such as Decarboxylation removes carbon dioxide from the maturing coal: while demethanation proceeds by reaction such as In these formulas, R represents the remainder of a cellulose or lignin molecule to which
1144-552: A range of concentrations. In addition to wood, combustible dusts include metals , especially magnesium, titanium and aluminum, as well as other carbon-based dusts . There are at least 140 known substances that produce combustible dust. While the particles in a combustible dusts may be of any size, normally they have a diameter of less than 420 μm . As of 2012 , the United States Occupational Safety and Health Administration has yet to adopt
1232-540: A switch in fuels happened in London in the late sixteenth and early seventeenth centuries. Historian Ruth Goodman has traced the socioeconomic effects of that switch and its later spread throughout Britain and suggested that its importance in shaping the industrial adoption of coal has been previously underappreciated. The development of the Industrial Revolution led to the large-scale use of coal, as
1320-561: A tenth. Indonesia and Australia export the most, followed by Russia . The word originally took the form col in Old English , from reconstructed Proto-Germanic * kula ( n ), from Proto-Indo-European root * g ( e ) u-lo- "live coal". Germanic cognates include the Old Frisian kole , Middle Dutch cole , Dutch kool , Old High German chol , German Kohle and Old Norse kol . Irish gual
1408-721: A third of its electricity . Some iron and steel -making and other industrial processes burn coal. The extraction and burning of coal damages the environment , causing premature death and illness, and it is the largest anthropogenic source of carbon dioxide contributing to climate change . Fourteen billion tonnes of carbon dioxide were emitted by burning coal in 2020, which is 40% of total fossil fuel emissions and over 25% of total global greenhouse gas emissions . As part of worldwide energy transition , many countries have reduced or eliminated their use of coal power . The United Nations Secretary General asked governments to stop building new coal plants by 2020. Global coal use
1496-403: A weight basis. This composition reflects partly the composition of the precursor plants. The second main fraction of coal is ash, an undesirable, noncombustable mixture of inorganic minerals. The composition of ash is often discussed in terms of oxides obtained after combustion in air: Of particular interest is the sulfur content of coal, which can vary from less than 1% to as much as 4%. Most of
1584-406: A weight composition of about 54% carbon, 6% hydrogen, and 30% oxygen, while cellulose has a weight composition of about 44% carbon, 6% hydrogen, and 49% oxygen. Bituminous coal has a composition of about 84.4% carbon, 5.4% hydrogen, 6.7% oxygen, 1.7% nitrogen, and 1.8% sulfur, on a weight basis. The low oxygen content of coal shows that coalification removed most of the oxygen and much of the hydrogen
1672-506: Is a combustible black or brownish-black sedimentary rock , formed as rock strata called coal seams . Coal is mostly carbon with variable amounts of other elements , chiefly hydrogen , sulfur , oxygen , and nitrogen . Coal is a type of fossil fuel , formed when dead plant matter decays into peat which is converted into coal by the heat and pressure of deep burial over millions of years. Vast deposits of coal originate in former wetlands called coal forests that covered much of
1760-636: Is also a cognate via the Indo-European root. The conversion of dead vegetation into coal is called coalification . At various times in the geologic past, the Earth had dense forests in low-lying areas. In these wetlands, the process of coalification began when dead plant matter was protected from oxidation , usually by mud or acidic water, and was converted into peat . The resulting peat bogs , which trapped immense amounts of carbon, were eventually deeply buried by sediments. Then, over millions of years,
1848-481: Is also important in processes that produce combustible substances as a by-product . Special precautions are usually required for substances that are easily combustible. These measures may include installation of fire sprinklers or storage remote from possible sources of ignition. Substances with low combustibility may be selected for construction where the fire risk must be reduced, such as apartment buildings, houses, or offices. If combustible resources are used there
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#17327762353671936-429: Is burned in a turbine). Hot exhaust gases from the turbine are used to raise steam in a heat recovery steam generator which powers a supplemental steam turbine . The overall plant efficiency when used to provide combined heat and power can reach as much as 94%. IGCC power plants emit less local pollution than conventional pulverized coal-fueled plants. Other ways to use coal are as coal-water slurry fuel (CWS), which
2024-603: Is entirely vertical; however, metamorphism may cause lateral changes of rank, irrespective of depth. For example, some of the coal seams of the Madrid, New Mexico coal field were partially converted to anthracite by contact metamorphism from an igneous sill while the remainder of the seams remained as bituminous coal. The earliest recognized use is from the Shenyang area of China where by 4000 BC Neolithic inhabitants had begun carving ornaments from black lignite. Coal from
2112-515: Is greater chance of fire accidents and deaths. Fire resistant substances are preferred for building materials and furnishings. A non-combustible material is a substance that does not ignite, burn, support combustion, or release flammable vapors when subject to fire or heat, in the form in which it is used and under conditions anticipated. Any solid substance complying with either of two sets of passing criteria listed in Section 8 of ASTM E 136 when
2200-433: Is lost, nothing is created, everything is transformed." The burning of a solid material may appear to lose weight if the mass of combustion gases (such as carbon dioxide and water vapor ) are not taken into account. The original mass of flammable material and the mass of the oxygen consumed (typically from the surrounding air) equals the mass of the flame products (ash, water, carbon dioxide, and other gases). Lavoisier used
2288-455: Is made when metallurgical coal (also known as coking coal ) is baked in an oven without oxygen at temperatures as high as 1,000 °C, driving off the volatile constituents and fusing together the fixed carbon and residual ash. Metallurgical coke is used as a fuel and as a reducing agent in smelting iron ore in a blast furnace . The carbon monoxide produced by its combustion reduces hematite (an iron oxide ) to iron. Pig iron , which
2376-409: Is more abundant, and anthracite. The % carbon in coal follows the order anthracite > bituminous > lignite > brown coal. The fuel value of coal varies in the same order. Some anthracite deposits contain pure carbon in the form of graphite . For bituminous coal, the elemental composition on a dry, ash-free basis of 84.4% carbon, 5.4% hydrogen, 6.7% oxygen, 1.7% nitrogen, and 1.8% sulfur, on
2464-425: Is much harder to ignite, even though the wood fibre is the same in all three materials. Common sense (and indeed scientific consensus until the mid-1700s) would seem to suggest that material "disappears" when burned, as only the ash is left. Further scientific research has found that conservation of mass holds for chemical reactions. Antoine Lavoisier , one of the pioneers in these early insights, stated: "Nothing
2552-520: Is of concern as cigarettes and candle accidents can trigger domestic fires. In 1975, California began implementing Technical Bulletin 117 (TB 117), which required that materials such as polyurethane foam used to fill furniture be able to withstand a small open flame, equivalent to a candle, for at least 12 seconds. In polyurethane foam, furniture manufacturers typically meet TB 117 with additive halogenated organic flame retardants . No other U.S. states had similar standards, but because California has such
2640-510: Is prepared with a generous amount of thick "Sunday sauce", bell peppers and romano cheese , as opposed to the more typical mozzarella . It is one of several dishes the Youngstown area prides itself upon, in much the same way New Yorkers value their distinctive thin-crusted New York-style pizza . Local activists from the Pro-Yo Party and the ITAM (Post 12) are working to make Brier Hill
2728-425: Is the ease with which a combustible substance can be ignited, causing fire or combustion or even an explosion. The degree of difficulty required to cause the combustion of a substance is quantified through fire testing . Internationally, a variety of test protocols exist to quantify flammability. The ratings achieved are used in building codes , insurance requirements, fire codes and other regulations governing
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2816-418: Is the most flammable synthetic fiber. A fire test can be conducted to determine the degree of flammability. Test standards used to make this determination but are not limited to the following: Combustibility is a measure of how easily a substance bursts into flame, through fire or combustion . This is an important property to consider when a substance is used for construction or is being stored. It
2904-450: Is too rich in dissolved carbon, is also produced. Combustible A combustible material is a material that can burn (i.e., sustain a flame ) in air under certain conditions. A material is flammable if it ignites easily at ambient temperatures. In other words, a combustible material ignites with some effort and a flammable material catches fire immediately on exposure to flame. The degree of flammability in air depends largely upon
2992-452: Is used as fuel. 27.6% of world energy was supplied by coal in 2017 and Asia used almost three-quarters of it. Other large-scale applications also exist. The energy density of coal is roughly 24 megajoules per kilogram (approximately 6.7 kilowatt-hours per kg). For a coal power plant with a 40% efficiency, it takes an estimated 325 kg (717 lb) of coal to power a 100 W lightbulb for one year. In 2022, 68% of global coal use
3080-715: The Bronze Age (3000–2000 BC), where it formed part of funeral pyres . In Roman Britain , with the exception of two modern fields, "the Romans were exploiting coals in all the major coalfields in England and Wales by the end of the second century AD". Evidence of trade in coal, dated to about AD 200, has been found at the Roman settlement at Heronbridge , near Chester ; and in the Fenlands of East Anglia , where coal from
3168-521: The Fushun mine in northeastern China was used to smelt copper as early as 1000 BC. Marco Polo , the Italian who traveled to China in the 13th century, described coal as "black stones ... which burn like logs", and said coal was so plentiful, people could take three hot baths a week. In Europe, the earliest reference to the use of coal as fuel is from the geological treatise On Stones (Lap. 16) by
3256-473: The Imperial Sugar Company's plant at Port Wentworth, Georgia , resulting in thirteen deaths. A material's flash point is a metric of how easy it is to ignite the vapor of the material as it evaporates into the atmosphere . It is defined as the lowest material temperature required for fuel oils in the materials to begin to give off flammable vapors in the quantity high enough to support
3344-607: The Midlands was transported via the Car Dyke for use in drying grain. Coal cinders have been found in the hearths of villas and Roman forts , particularly in Northumberland , dated to around AD 400. In the west of England, contemporary writers described the wonder of a permanent brazier of coal on the altar of Minerva at Aquae Sulis (modern day Bath ), although in fact easily accessible surface coal from what became
3432-728: The Somerset coalfield was in common use in quite lowly dwellings locally. Evidence of coal's use for iron -working in the city during the Roman period has been found. In Eschweiler , Rhineland , deposits of bituminous coal were used by the Romans for the smelting of iron ore . No evidence exists of coal being of great importance in Britain before about AD 1000, the High Middle Ages . Coal came to be referred to as "seacoal" in
3520-491: The coal gap in the Permian–Triassic extinction event , where coal is rare. Favorable geography alone does not explain the extensive Carboniferous coal beds. Other factors contributing to rapid coal deposition were high oxygen levels, above 30%, that promoted intense wildfires and formation of charcoal that was all but indigestible by decomposing organisms; high carbon dioxide levels that promoted plant growth; and
3608-467: The mines , and Brier Hill became Youngstown's oldest working-class neighborhood. The first iron furnace in the neighborhood was opened by the Tod family in 1847. By the 1880s, blast furnaces and rolling mills were established in close proximity to the coal mines, a practical arrangement, given that Brier Hill mines provided coal for the mills. The surrounding neighborhood grew in tandem, as more housing
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3696-458: The occupancies as originally intended. In other words, if a portion of a building were designed as an apartment , one could not suddenly load it with flammable liquids and turn it into a gas storage facility, because the fire load and smoke development in that one apartment would be so immense as to overtax the active fire protection as well as the passive fire protection means for the building. The handling and use of flammable substances inside
3784-447: The steam engine took over from the water wheel . In 1700, five-sixths of the world's coal was mined in Britain. Britain would have run out of suitable sites for watermills by the 1830s if coal had not been available as a source of energy. In 1947 there were some 750,000 miners in Britain, but the last deep coal mine in the UK closed in 2015. A grade between bituminous coal and anthracite
3872-407: The 13th century; the wharf where the material arrived in London was known as Seacoal Lane, so identified in a charter of King Henry III granted in 1253. Initially, the name was given because much coal was found on the shore, having fallen from the exposed coal seams on cliffs above or washed out of underwater coal outcrops, but by the time of Henry VIII , it was understood to derive from the way it
3960-402: The 1950s, large swaths of the neighborhood were razed to make way for urban renewal projects, including the building of modern expressways . Brier Hill was further depopulated by economic dislocations that came with the decline, and eventual collapse, of Youngstown's steel industry. Today, all that remains of a once-vibrant ethnic enclave is the ITAM Post (Italian-American War Veterans' Club),
4048-596: The Carboniferous, and suggested that climatic and tectonic factors were a more plausible explanation, reconstruction of ancestral enzymes by phylogenetic analysis corroborated a hypothesis that lignin degrading enzymes appeared in fungi approximately 200 MYa. One likely tectonic factor was the Central Pangean Mountains , an enormous range running along the equator that reached its greatest elevation near this time. Climate modeling suggests that
4136-598: The Central Pangean Mountains contributed to the deposition of vast quantities of coal in the late Carboniferous. The mountains created an area of year-round heavy precipitation, with no dry season typical of a monsoon climate. This is necessary for the preservation of peat in coal swamps. Coal is known from Precambrian strata, which predate land plants. This coal is presumed to have originated from residues of algae. Sometimes coal seams (also known as coal beds) are interbedded with other sediments in
4224-407: The Earth's tropical land areas during the late Carboniferous ( Pennsylvanian ) and Permian times. Coal is used primarily as a fuel. While coal has been known and used for thousands of years, its usage was limited until the Industrial Revolution . With the invention of the steam engine , coal consumption increased. In 2020, coal supplied about a quarter of the world's primary energy and over
4312-577: The Greek scientist Theophrastus (c. 371–287 BC): Among the materials that are dug because they are useful, those known as anthrakes [coals] are made of earth, and, once set on fire, they burn like charcoal [anthrakes]. They are found in Liguria ;... and in Elis as one approaches Olympia by the mountain road; and they are used by those who work in metals. Outcrop coal was used in Britain during
4400-437: The United States flammable liquids , by definition, have a flash point below 100 °F (38 °C)—where combustible liquids have a flash point above 100 °F (38 °C). Flammable solids are solids that are readily combustible, or may cause or contribute to fire through friction. Readily combustible solids are powdered , granular, or pasty substances that easily ignite by brief contact with an ignition source, such as
4488-463: The Youngstown area had large Italian-American populations—including Smoky Hollow , the near East Side, East Youngstown (now Campbell ), Struthers , and Lowellville —Brier Hill was widely recognized as the city's unofficial Little Italy . The neighborhood was the birthplace of "Brier Hill pizza", a home-style recipe with origins in the Basilicata region of Italy . Brier Hill pizza
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#17327762353674576-500: The building and occupants. These codes specify the combustibility rating for materials, the entrance and exit requirements, as well as active fire protection requirements, along with numerous other things. In the U.S. other agencies have also developed building codes that specify combustibility ratings such as state and/or county governing bodies. Following the requirements of these fire codes are crucial for higher occupancy buildings. For existing buildings, fire codes focus on maintaining
4664-455: The change into account. Globally Harmonized System of Classification and Labelling of Chemicals uses a four category system to classify flammable liquids using flash point and boiling point temperature. This system is used internationally to evaluate and sort substances in industrial applications, workplaces and products distributed to consumers. Prior to 2012, OSHA's classification of flammable and combustible liquids in regulation 1910.106,
4752-810: The degree of flammability and combustibility in accordance with the German DIN 4102. DIN 4102, as well as its British cousin BS 476 include for testing of passive fire protection systems , as well as some of its constituent materials. The following are the categories in order of degree of combustibility and flammability: A more recent industrial standard is the European EN 13501-1 - Fire classification of construction products and building elements—which roughly replaces A2 with A2/B, B1 with C, B2 with D/E and B3 with F. B3 or F rated materials may not be used in building unless combined with another material that reduces
4840-430: The evolution of the first trees . But bacteria and fungi did not immediately evolve the ability to decompose lignin, so the wood did not fully decay but became buried under sediment, eventually turning into coal. About 300 million years ago, mushrooms and other fungi developed this ability, ending the main coal-formation period of earth's history. Although some authors pointed at some evidence of lignin degradation during
4928-648: The experimental fact that some metals gained mass when they burned to support his ideas (because those chemical reactions capture oxygen atoms into solid compounds rather than gaseous water). Historically, flammable , inflammable and combustible meant capable of burning . The word "inflammable" came through French from the Latin inflammāre = "to set fire to", where the Latin preposition "in-" means "in" as in "indoctrinate", rather than "not" as in "invisible" and "ineligible". The word "inflammable" may be erroneously thought to mean "non-flammable". The erroneous usage of
5016-519: The factors involved in coalification, temperature is much more important than either pressure or time of burial. Subbituminous coal can form at temperatures as low as 35 to 80 °C (95 to 176 °F) while anthracite requires a temperature of at least 180 to 245 °C (356 to 473 °F). Although coal is known from most geologic periods , 90% of all coal beds were deposited in the Carboniferous and Permian periods. Paradoxically, this
5104-507: The flame point of a material is reached, it produces enough fuel vapors or oils to support continuous burning. The lower flammability limit or lower explosive limit (LFL/LEL) represents the lowest air to fuel vapor concentration required for combustion to take place when ignited by an external source, for any particular chemical. Any concentration lower than this could not produce a flame or result in combustion. The upper flammability limit or upper explosive limit (UFL/UEL) represents
5192-498: The form of iron pyrite (FeS 2 ). Being a dense mineral, it can be removed from coal by mechanical means, e.g. by froth flotation . Some sulfate occurs in coal, especially weathered samples. It is not volatilized and can be removed by washing. Minor components include: As minerals, Hg, As, and Se are not problematic to the environment, especially since they are only trace components. They become however mobile (volatile or water-soluble) when these minerals are combusted. Most coal
5280-475: The hazard posed by a substance during an emergency, such as a spill. In addition to GHS, flammability classifications are incorporated into various systems designed for communicating physical and health hazards in workplaces; such as American Coatings Association's Hazardous Materials Identification System (HMIS) and Lab Safety Supply's Hazardous Material Identification Guide (HMIG). Flammable substances include, but are not limited to: Flammability of furniture
5368-475: The heat and pressure of deep burial caused the loss of water, methane and carbon dioxide and increased the proportion of carbon. The grade of coal produced depended on the maximum pressure and temperature reached, with lignite (also called "brown coal") produced under relatively mild conditions, and sub-bituminous coal , bituminous coal , or anthracite coal (also called "hard coal" or "black coal") produced in turn with increasing temperature and pressure. Of
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#17327762353675456-431: The highest air to fuel vapor concentration at which combustion can take place when ignited by an external source. Any fuel-air mixture higher than this would be too concentrated to result in combustion. The values existing between these two limits represent the flammable or explosive range. Within this threshold, give an external ignition source, combustion of the particular fuel would likely happen. The vapor pressure of
5544-431: The increasing tendency of the anthracite to break with a conchoidal fracture , similar to the way thick glass breaks. As geological processes apply pressure to dead biotic material over time, under suitable conditions, its metamorphic grade or rank increases successively into: There are several international standards for coal. The classification of coal is generally based on the content of volatiles . However
5632-556: The mixing and blending of powders. Investigation of 200 dust explosions and fires, between 1980 and 2005, indicated approximately 100 fatalities and 600 injuries. In January 2003, a polyethylene powder explosion and fire at the West Pharmaceutical Services plant in Kinston, North Carolina resulted in the deaths of six workers and injuries to 38 others. In February 2008 an explosion of sugar dust rocked
5720-453: The morphology and some properties of the original plant. In many coals, individual macerals can be identified visually. Some macerals include: In coalification huminite is replaced by vitreous (shiny) vitrinite . Maturation of bituminous coal is characterized by bitumenization , in which part of the coal is converted to bitumen , a hydrocarbon-rich gel. Maturation to anthracite is characterized by debitumenization (from demethanation) and
5808-405: The most important distinction is between thermal coal (also known as steam coal), which is burnt to generate electricity via steam; and metallurgical coal (also known as coking coal), which is burnt at high temperature to make steel . Hilt's law is a geological observation that (within a small area) the deeper the coal is found, the higher its rank (or grade). It applies if the thermal gradient
5896-407: The nature of Carboniferous forests, which included lycophyte trees whose determinate growth meant that carbon was not tied up in heartwood of living trees for long periods. One theory suggested that about 360 million years ago, some plants evolved the ability to produce lignin , a complex polymer that made their cellulose stems much harder and more woody. The ability to produce lignin led to
5984-455: The number of double bonds between carbon). As carbonization proceeds, aliphatic compounds convert to aromatic compounds . Similarly, aromatic rings fuse into polyaromatic compounds (linked rings of carbon atoms). The structure increasingly resembles graphene , the structural element of graphite. Chemical changes are accompanied by physical changes, such as decrease in average pore size. The macerals are coalified plant parts that retain
6072-456: The pre-combustion treatment, turbine technology (e.g. supercritical steam generator ) and the age of the plant. A few integrated gasification combined cycle (IGCC) power plants have been built, which burn coal more efficiently. Instead of pulverizing the coal and burning it directly as fuel in the steam-generating boiler, the coal is gasified to create syngas , which is burned in a gas turbine to produce electricity (just like natural gas
6160-427: The reacting groups are attached. Dehydration and decarboxylation take place early in coalification, while demethanation begins only after the coal has already reached bituminous rank. The effect of decarboxylation is to reduce the percentage of oxygen, while demethanation reduces the percentage of hydrogen. Dehydration does both, and (together with demethanation) reduces the saturation of the carbon backbone (increasing
6248-540: The substance is tested in accordance with the procedure specified in ASTM E 136 is considered to be non-combustible. A number of industrial processes produce combustible dust as a by-product. The most common being wood dust . Combustible dust has been defined as: a solid material composed of distinct particles or pieces, regardless of size, shape, or chemical composition, which presents a fire or deflagration hazard when suspended in air or some other oxidizing medium over
6336-399: The sulfur and most of the nitrogen is incorporated into the organic fraction in the form of organosulfur compounds and organonitrogen compounds . This sulfur and nitrogen are strongly bound within the hydrocarbon matrix. These elements are released as SO 2 and NO x upon combustion. They cannot be removed, economically at least, otherwise. Some coals contain inorganic sulfur, mainly in
6424-676: The three specimens either: Otherwise, the material is classified as non-combustible. Various countries have tests for determining non-combustibility of materials. Most involve the heating of a specified quantity of the test specimen for a set duration. Usually, the material must not support combustion and must not lose more than a certain amount of mass. As a general rule of thumb, concrete, steel, and ceramics - in other words inorganic substances - pass these tests, so building codes list them as suitable and sometimes even mandate their use in certain applications. In Canada , for instance, firewalls must be made of concrete . Materials can be tested for
6512-403: The use of building materials as well as the storage and handling of highly flammable substances inside and outside of structures and in surface and air transportation. For instance, changing an occupancy by altering the flammability of the contents requires the owner of a building to apply for a building permit to make sure that the overall fire protection design basis of the facility can take
6600-479: The use of flame retardants, California modified TB 117 to require that fabric covering upholstered furniture meet a smolder test replacing the open flame test . Gov. Jerry Brown signed the modified TB117-2013, which became effective in 2014. Lightweight textiles with porous surfaces are the most flammable fabrics. Wool is less flammable than cotton, linen, silk, or viscose ( rayon ). Polyester and nylon resist ignition, and melt rather than catch fire. Acrylic
6688-441: The volatility of the material - this is related to its composition-specific vapour pressure , which is temperature dependent. The quantity of vapour produced can be enhanced by increasing the surface area of the material forming a mist or dust. Take wood as an example. Finely divided wood dust can undergo explosive flames and produce a blast wave. A piece of paper (made from wood ) catches on fire quite easily. A heavy oak desk
6776-699: The word "inflammable" is a significant safety hazard . Therefore, since the 1950s, efforts to put forward the use of "flammable" in place of "inflammable" were accepted by linguists, and it is now the accepted standard in American English and British English. Antonyms of "flammable" or "inflammable" include: non-flammable , non-inflammable , incombustible , non-combustible , not flammable , and fireproof . Flammable applies to combustible materials that ignite easily and thus are more dangerous and more highly regulated. Less easily ignited less-vigorously burning materials are combustible . For example, in
6864-415: The world's coal-generated electricity. Efforts around the world to reduce the use of coal have led some regions to switch to natural gas and renewable energy . In 2018 coal-fired power station capacity factor averaged 51%, that is they operated for about half their available operating hours. Coke is a solid carbonaceous residue that is used in manufacturing steel and other iron-containing products. Coke
6952-590: Was 8.3 billion tonnes in 2022, and is set to remain at record levels in 2023. To meet the Paris Agreement target of keeping global warming below 2 °C (3.6 °F) coal use needs to halve from 2020 to 2030, and "phasing down" coal was agreed upon in the Glasgow Climate Pact . The largest consumer and importer of coal in 2020 was China , which accounts for almost half the world's annual coal production, followed by India with about
7040-574: Was based on the trading of this commodity. Coal continues to arrive on beaches around the world from both natural erosion of exposed coal seams and windswept spills from cargo ships. Many homes in such areas gather this coal as a significant, and sometimes primary, source of home heating fuel. Coal consists mainly of a black mixture of diverse organic compounds and polymers. Of course, several kinds of coals exist, with variable dark colors and variable compositions. Young coals (brown coal, lignite) are not black. The two main black coals are bituminous, which
7128-446: Was built for miners, iron workers, and their families. By the opening of the 20th century, the rapid expansion of the industry in Brier Hill had turned the area into the main entry point for Youngstown's immigrants. The largest groups were Italians , Welsh , Irish , Germans , and African Americans . Given its relative isolation from downtown Youngstown , Brier Hill developed independently and established its own schools as well as
7216-510: Was carried to London by sea. In 1257–1259, coal from Newcastle upon Tyne was shipped to London for the smiths and lime -burners building Westminster Abbey . Seacoal Lane and Newcastle Lane, where coal was unloaded at wharves along the River Fleet , still exist. These easily accessible sources had largely become exhausted (or could not meet the growing demand) by the 13th century, when underground extraction by shaft mining or adits
7304-612: Was developed in the Soviet Union , or in an MHD topping cycle . However these are not widely used due to lack of profit. In 2017 38% of the world's electricity came from coal, the same percentage as 30 years previously. In 2018 global installed capacity was 2 TW (of which 1TW is in China) which was 30% of total electricity generation capacity. The most dependent major country is South Africa, with over 80% of its electricity generated by coal; but China alone generates more than half of
7392-408: Was developed. The alternative name was "pitcoal", because it came from mines. Cooking and home heating with coal (in addition to firewood or instead of it) has been done in various times and places throughout human history, especially in times and places where ground-surface coal was available and firewood was scarce, but a widespread reliance on coal for home hearths probably never existed until such
7480-497: Was during the Late Paleozoic icehouse , a time of global glaciation . However, the drop in global sea level accompanying the glaciation exposed continental shelves that had previously been submerged, and to these were added wide river deltas produced by increased erosion due to the drop in base level . These widespread areas of wetlands provided ideal conditions for coal formation. The rapid formation of coal ended with
7568-550: Was nearly identical to the National Fire Protective Association (NFPA) Flammable and Combustible Liquids Code , NFPA 30. While no longer used for occupational regulations, NFPA 30's definitions are still commonly used in fire codes and NFPA codes and standards. Other systems for classifications of flammable liquids exist for more specialist applications, such as NFPA 704 , which uses five categories, intended for emergency workers to understand
7656-564: Was once known as "steam coal" as it was widely used as a fuel for steam locomotives . In this specialized use, it is sometimes known as "sea coal" in the United States. Small "steam coal", also called dry small steam nuts (DSSN), was used as a fuel for domestic water heating . Coal played an important role in industry in the 19th and 20th century. The predecessor of the European Union , the European Coal and Steel Community ,
7744-430: Was used for electricity generation. Coal burnt in coal power stations to generate electricity is called thermal coal . It is usually pulverized and then burned in a furnace with a boiler . The furnace heat converts boiler water to steam , which is then used to spin turbines which turn generators and create electricity. The thermodynamic efficiency of this process varies between about 25% and 50% depending on
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