Korahe ( Somali : Qoraxeey ) is one of eleven Zones of the Somali Region of Ethiopia . Korahe is bordered on the southwest by the Shabeele Zone, on the northwest by Erer Zone , on the north by Jarar Zone , on the east by Doolo Zone, and on the southeast by Somalia 's federal state of Galmudug . The largest city in Korahe is Kabridahar.
114-505: The gas fields of Calub , Eleele , Banka Qoraxey and Dar Balayo Dar Shekosh , Elka Shilaabo (Ban Watte) lie in this Zone, making local petrochemical extraction a potentially important industry. Based on the 2007 Census conducted by the Central Statistical Agency of Ethiopia (CSA), this Zone has a total population of 901,028 of whom 463,211 are men and 437,817 women. While 47,607 or 20% are urban inhabitants,
228-503: A biochemical pump that collects carbon from the organ interior (or from the soil ) and not from the atmosphere. Cyanobacteria possess carboxysomes , which increase the concentration of CO 2 around RuBisCO to increase the rate of photosynthesis. An enzyme, carbonic anhydrase , located within the carboxysome, releases CO 2 from dissolved hydrocarbonate ions (HCO 3 ). Before the CO 2 can diffuse out, RuBisCO concentrated within
342-481: A density 0.5539 times that of air (0.678 kg per standard cubic meter). In the early 1800s, natural gas became known as "natural" to distinguish it from the dominant gas fuel at the time, coal gas . Unlike coal gas, which is manufactured by heating coal, natural gas can be extracted from the ground in its native gaseous form. When the use of natural gas overtook the use of coal gas in English speaking countries in
456-409: A different leaf anatomy from C 3 plants, and fix the CO 2 at night, when their stomata are open. CAM plants store the CO 2 mostly in the form of malic acid via carboxylation of phosphoenolpyruvate to oxaloacetate , which is then reduced to malate. Decarboxylation of malate during the day releases CO 2 inside the leaves, thus allowing carbon fixation to 3-phosphoglycerate by RuBisCO. CAM
570-722: A further 265,106 or 80% were pastoralists. The largest ethnic group reported in Korahe were the Somalis (99.98%); all other ethnic groups made up 0.02% of the population. Somali language is spoken as a first language by 99.98%; the remaining 0.02% spoke all other primary languages reported. 98.92% of the population said they were Muslim . The 1997 national census reported a total population for this Zone of 242,276 in 28,891 households, of whom 500,000-700,000 were men and 600,000- 700,000 were women; 37,226 or 15.37% of its population were urban dwellers. The largest ethnic group reported in Korahe
684-484: A major source of natural gas in the United States and Canada. Because of increased shale gas production the United States was in 2014 the number one natural gas producer in the world. The production of shale gas in the United States has been described as a "shale gas revolution" and as "one of the landmark events in the 21st century." Following the increased production in the United States, shale gas exploration
798-480: A phospholipid outer membrane, and an intermembrane space. Enclosed by the membrane is an aqueous fluid called the stroma. Embedded within the stroma are stacks of thylakoids (grana), which are the site of photosynthesis. The thylakoids appear as flattened disks. The thylakoid itself is enclosed by the thylakoid membrane, and within the enclosed volume is a lumen or thylakoid space. Embedded in the thylakoid membrane are integral and peripheral membrane protein complexes of
912-479: A photocomplex. When a photon is absorbed by a chromophore, it is converted into a quasiparticle referred to as an exciton , which jumps from chromophore to chromophore towards the reaction center of the photocomplex, a collection of molecules that traps its energy in a chemical form accessible to the cell's metabolism. The exciton's wave properties enable it to cover a wider area and try out several possible paths simultaneously, allowing it to instantaneously "choose"
1026-405: A photon by the antenna complex loosens an electron by a process called photoinduced charge separation . The antenna system is at the core of the chlorophyll molecule of the photosystem II reaction center. That loosened electron is taken up by the primary electron-acceptor molecule, pheophytin . As the electrons are shuttled through an electron transport chain (the so-called Z-scheme shown in
1140-422: A plant's photosynthetic response. Integrated chlorophyll fluorometer – gas exchange systems allow a more precise measure of photosynthetic response and mechanisms. While standard gas exchange photosynthesis systems can measure Ci, or substomatal CO 2 levels, the addition of integrated chlorophyll fluorescence measurements allows a more precise measurement of C C, the estimation of CO 2 concentration at
1254-450: A redox-active tyrosine residue that is oxidized by the energy of P680 . This resets the ability of P680 to absorb another photon and release another photo-dissociated electron. The oxidation of water is catalyzed in photosystem II by a redox-active structure that contains four manganese ions and a calcium ion ; this oxygen-evolving complex binds two water molecules and contains the four oxidizing equivalents that are used to drive
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#17327655952201368-399: A simpler method that employs a pigment similar to those used for vision in animals. The bacteriorhodopsin changes its configuration in response to sunlight, acting as a proton pump. This produces a proton gradient more directly, which is then converted to chemical energy. The process does not involve carbon dioxide fixation and does not release oxygen, and seems to have evolved separately from
1482-481: A source of carbon atoms to carry out photosynthesis; photoheterotrophs use organic compounds, rather than carbon dioxide, as a source of carbon. In plants, algae, and cyanobacteria, photosynthesis releases oxygen. This oxygenic photosynthesis is by far the most common type of photosynthesis used by living organisms. Some shade-loving plants (sciophytes) produce such low levels of oxygen during photosynthesis that they use all of it themselves instead of releasing it to
1596-541: A subsequent sequence of light-independent reactions called the Calvin cycle . In this process, atmospheric carbon dioxide is incorporated into already existing organic compounds, such as ribulose bisphosphate (RuBP). Using the ATP and NADPH produced by the light-dependent reactions, the resulting compounds are then reduced and removed to form further carbohydrates, such as glucose . In other bacteria, different mechanisms like
1710-542: A synthetic crude that can be further refined into finished products, while MTG can produce synthetic gasoline from natural gas. STG+ can produce drop-in gasoline, diesel, jet fuel and aromatic chemicals directly from natural gas via a single-loop process. In 2011, Royal Dutch Shell's 140,000 barrels (22,000 m ) per day F–T plant went into operation in Qatar . Natural gas can be "associated" (found in oil fields ), or "non-associated" (isolated in natural gas fields ), and
1824-405: A type of non- carbon-fixing anoxygenic photosynthesis, where the simpler photopigment retinal and its microbial rhodopsin derivatives are used to absorb green light and power proton pumps to directly synthesize adenosine triphosphate (ATP), the "energy currency" of cells. Such archaeal photosynthesis might have been the earliest form of photosynthesis that evolved on Earth, as far back as
1938-591: A wide variety of colors. These pigments are embedded in plants and algae in complexes called antenna proteins. In such proteins, the pigments are arranged to work together. Such a combination of proteins is also called a light-harvesting complex . Although all cells in the green parts of a plant have chloroplasts, the majority of those are found in specially adapted structures called leaves . Certain species adapted to conditions of strong sunlight and aridity , such as many Euphorbia and cactus species, have their main photosynthetic organs in their stems. The cells in
2052-590: Is a system of biological processes by which photosynthetic organisms , such as most plants, algae , and cyanobacteria , convert light energy , typically from sunlight, into the chemical energy necessary to fuel their metabolism . Photosynthesis usually refers to oxygenic photosynthesis , a process that produces oxygen. Photosynthetic organisms store the chemical energy so produced within intracellular organic compounds (compounds containing carbon) like sugars, glycogen , cellulose and starches . To use this stored chemical energy, an organism's cells metabolize
2166-493: Is a flammable gaseous fuel made by the destructive distillation of coal . It contains a variety of calorific gases including hydrogen , carbon monoxide , methane , and other volatile hydrocarbons , together with small quantities of non-calorific gases such as carbon dioxide and nitrogen , and was used in a similar way to natural gas. This is a historical technology and is not usually economically competitive with other sources of fuel gas today. Most town "gashouses" located in
2280-421: Is a naturally occurring mixture of gaseous hydrocarbons consisting primarily of methane (95%) in addition to various smaller amounts of other higher alkanes . Traces of carbon dioxide , nitrogen , hydrogen sulfide , and helium are also usually present. Methane is colorless and odorless, and the second largest greenhouse gas contributor to global climate change after carbon dioxide. Because natural gas
2394-458: Is a schematic block flow diagram of a typical natural gas processing plant. It shows the various unit processes used to convert raw natural gas into sales gas pipelined to the end user markets. The block flow diagram also shows how processing of the raw natural gas yields byproduct sulfur, byproduct ethane, and natural gas liquids (NGL) propane, butanes and natural gasoline (denoted as pentanes +). As of mid-2020, natural gas production in
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#17327655952202508-399: Is also found in coal beds (as coalbed methane ). It sometimes contains a significant amount of ethane , propane , butane , and pentane —heavier hydrocarbons removed for commercial use prior to the methane being sold as a consumer fuel or chemical plant feedstock. Non-hydrocarbons such as carbon dioxide , nitrogen , helium (rarely), and hydrogen sulfide must also be removed before
2622-490: Is an endothermic redox reaction. In general outline, photosynthesis is the opposite of cellular respiration : while photosynthesis is a process of reduction of carbon dioxide to carbohydrates, cellular respiration is the oxidation of carbohydrates or other nutrients to carbon dioxide. Nutrients used in cellular respiration include carbohydrates, amino acids and fatty acids. These nutrients are oxidized to produce carbon dioxide and water, and to release chemical energy to drive
2736-628: Is beginning in countries such as Poland, China, and South Africa. Chinese geologists have identified the Sichuan Basin as a promising target for shale gas drilling, because of the similarity of shales to those that have proven productive in the United States. Production from the Wei-201 well is between 10,000 and 20,000 m per day. In late 2020, China National Petroleum Corporation claimed daily production of 20 million cubic meters of gas from its Changning-Weiyuan demonstration zone. Town gas
2850-502: Is both an evolutionary precursor to C 4 and a useful carbon-concentrating mechanism in its own right. Xerophytes , such as cacti and most succulents , also use PEP carboxylase to capture carbon dioxide in a process called Crassulacean acid metabolism (CAM). In contrast to C 4 metabolism, which spatially separates the CO 2 fixation to PEP from the Calvin cycle, CAM temporally separates these two processes. CAM plants have
2964-474: Is commonly measured in μmols /( m / s ), parts per million, or volume per million; and H 2 O is commonly measured in mmols /(m /s) or in mbars . By measuring CO 2 assimilation , ΔH 2 O, leaf temperature, barometric pressure , leaf area, and photosynthetically active radiation (PAR), it becomes possible to estimate, "A" or carbon assimilation, "E" or transpiration , "gs" or stomatal conductance , and "Ci" or intracellular CO 2 . However, it
3078-430: Is converted to CO 2 by an oxalate oxidase enzyme, and the produced CO 2 can support the Calvin cycle reactions. Reactive hydrogen peroxide (H 2 O 2 ), the byproduct of oxalate oxidase reaction, can be neutralized by catalase . Alarm photosynthesis represents a photosynthetic variant to be added to the well-known C4 and CAM pathways. However, alarm photosynthesis, in contrast to these pathways, operates as
3192-537: Is estimated to have 51,000 cubic kilometers (12,000 cu mi) of natural gas and 50 billion barrels (7.9 billion cubic meters) of natural gas condensates . Because natural gas is not a pure product, as the reservoir pressure drops when non-associated gas is extracted from a field under supercritical (pressure/temperature) conditions, the higher molecular weight components may partially condense upon isothermic depressurizing—an effect called retrograde condensation . The liquid thus formed may get trapped as
3306-419: Is freed from its locked position through a classic "hop". The movement of the electron towards the photo center is therefore covered in a series of conventional hops and quantum walks. Fossils of what are thought to be filamentous photosynthetic organisms have been dated at 3.4 billion years old. More recent studies also suggest that photosynthesis may have begun about 3.4 billion years ago, though
3420-412: Is further excited by the light absorbed by that photosystem . The electron is then passed along a chain of electron acceptors to which it transfers some of its energy . The energy delivered to the electron acceptors is used to move hydrogen ions across the thylakoid membrane into the lumen . The electron is eventually used to reduce the coenzyme NADP with an H to NADPH (which has functions in
3534-694: Is heated and compressed deep underground. Methanogenic organisms produce methane from a variety of sources, principally carbon dioxide. During petroleum production, natural gas is sometimes flared rather than being collected and used. Before natural gas can be burned as a fuel or used in manufacturing processes, it almost always has to be processed to remove impurities such as water. The byproducts of this processing include ethane , propane , butanes , pentanes , and higher molecular weight hydrocarbons. Hydrogen sulfide (which may be converted into pure sulfur ), carbon dioxide , water vapor , and sometimes helium and nitrogen must also be removed. Natural gas
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3648-451: Is more common to use chlorophyll fluorescence for plant stress measurement , where appropriate, because the most commonly used parameters FV/FM and Y(II) or F/FM' can be measured in a few seconds, allowing the investigation of larger plant populations. Gas exchange systems that offer control of CO 2 levels, above and below ambient , allow the common practice of measurement of A/Ci curves, at different CO 2 levels, to characterize
3762-403: Is natural gas produced from shale . Because shale's matrix permeability is too low to allow gas to flow in economical quantities, shale gas wells depend on fractures to allow the gas to flow. Early shale gas wells depended on natural fractures through which gas flowed; almost all shale gas wells today require fractures artificially created by hydraulic fracturing . Since 2000, shale gas has become
3876-408: Is odorless, odorizers such as mercaptan (which smells like rotten eggs ) are commonly added to it for safety so that leaks can be readily detected. Natural gas is a fossil fuel that is formed when layers of organic matter (primarily marine microorganisms) decompose under anaerobic conditions and are subjected to intense heat and pressure underground over millions of years. The energy that
3990-406: Is often stored underground [references about geological storage needed]inside depleted gas reservoirs from previous gas wells, salt domes , or in tanks as liquefied natural gas. The gas is injected in a time of low demand and extracted when demand picks up. Storage nearby end users helps to meet volatile demands, but such storage may not always be practicable. With 15 countries accounting for 84% of
4104-406: Is passed through a food chain . The fixation or reduction of carbon dioxide is a process in which carbon dioxide combines with a five-carbon sugar , ribulose 1,5-bisphosphate , to yield two molecules of a three-carbon compound, glycerate 3-phosphate , also known as 3-phosphoglycerate. Glycerate 3-phosphate, in the presence of ATP and NADPH produced during the light-dependent stages,
4218-452: Is preparing to export natural gas. Floating liquefied natural gas (FLNG) is an innovative technology designed to enable the development of offshore gas resources that would otherwise remain untapped due to environmental or economic factors which currently make them impractical to develop via a land-based LNG operation. FLNG technology also provides a number of environmental and economic advantages: Many gas and oil companies are considering
4332-548: Is primarily dependent on proximity to markets (pipelines), and regulatory restrictions. Natural gas can be indirectly exported through the absorption in other physical output. The expansion of shale gas production in the US has caused prices to drop relative to other countries. This has caused a boom in energy intensive manufacturing sector exports, whereby the average dollar unit of US manufacturing exports has almost tripled its energy content between 1996 and 2012. A "master gas system"
4446-429: Is primarily used in the northern hemisphere. North America and Europe are major consumers. Often well head gases require removal of various hydrocarbon molecules contained within the gas. Some of these gases include heptane , pentane , propane and other hydrocarbons with molecular weights above methane ( CH 4 ). The natural gas transmission lines extend to the natural gas processing plant or unit which removes
4560-623: Is reduced to glyceraldehyde 3-phosphate . This product is also referred to as 3-phosphoglyceraldehyde (PGAL) or, more generically, as triose phosphate. Most (five out of six molecules) of the glyceraldehyde 3-phosphate produced are used to regenerate ribulose 1,5-bisphosphate so the process can continue. The triose phosphates not thus "recycled" often condense to form hexose phosphates, which ultimately yield sucrose , starch , and cellulose , as well as glucose and fructose . The sugars produced during carbon metabolism yield carbon skeletons that can be used for other metabolic reactions like
4674-716: Is sometimes informally referred to simply as "gas", especially when it is being compared to other energy sources, such as oil, coal or renewables. However, it is not to be confused with gasoline , which is also shortened in colloquial usage to "gas", especially in North America. Natural gas is measured in standard cubic meters or standard cubic feet . The density compared to air ranges from 0.58 (16.8 g/mole, 0.71 kg per standard cubic meter) to as high as 0.79 (22.9 g/mole, 0.97 kg per scm), but generally less than 0.64 (18.5 g/mole, 0.78 kg per scm). For comparison, pure methane (16.0425 g/mole) has
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4788-429: Is then translocated to specialized bundle sheath cells where the enzyme RuBisCO and other Calvin cycle enzymes are located, and where CO 2 released by decarboxylation of the four-carbon acids is then fixed by RuBisCO activity to the three-carbon 3-phosphoglyceric acids . The physical separation of RuBisCO from the oxygen-generating light reactions reduces photorespiration and increases CO 2 fixation and, thus,
4902-404: Is then converted into the final carbohydrate products. The simple carbon sugars photosynthesis produces are then used to form other organic compounds , such as the building material cellulose , the precursors for lipid and amino acid biosynthesis, or as a fuel in cellular respiration . The latter occurs not only in plants but also in animals when the carbon and energy from plants
5016-604: Is traded on a "dry gas" basis and is required to be commercially free from objectionable odours, materials, and dust or other solid or liquid matter, waxes, gums and gum forming constituents, which might damage or adversely affect operation of equipment downstream of the custody transfer point. LNG carrier ships transport liquefied natural gas (LNG) across oceans, while tank trucks can carry LNG or compressed natural gas (CNG) over shorter distances. Sea transport using CNG carrier ships that are now under development may be competitive with LNG transport in specific conditions. Gas
5130-409: Is transported at high pressure, typically above 200 bars (20,000 kPa; 2,900 psi). Compressors and decompression equipment are less capital intensive and may be economical in smaller unit sizes than liquefaction/regasification plants. Natural gas trucks and carriers may transport natural gas directly to end-users, or to distribution points such as pipelines. In the past, the natural gas which
5244-416: Is turned into liquid at a liquefaction plant, and is returned to gas form at regasification plant at the terminal . Shipborne regasification equipment is also used. LNG is the preferred form for long distance, high volume transportation of natural gas, whereas pipeline is preferred for transport for distances up to 4,000 km (2,500 mi) over land and approximately half that distance offshore. CNG
5358-499: Is used by 16,000 species of plants. Calcium-oxalate -accumulating plants, such as Amaranthus hybridus and Colobanthus quitensis , show a variation of photosynthesis where calcium oxalate crystals function as dynamic carbon pools , supplying carbon dioxide (CO 2 ) to photosynthetic cells when stomata are partially or totally closed. This process was named alarm photosynthesis . Under stress conditions (e.g., water deficit ), oxalate released from calcium oxalate crystals
5472-474: Is vital for climate processes, as it captures carbon dioxide from the air and binds it into plants, harvested produce and soil. Cereals alone are estimated to bind 3,825 Tg or 3.825 Pg of carbon dioxide every year, i.e. 3.825 billion metric tons. Most photosynthetic organisms are photoautotrophs , which means that they are able to synthesize food directly from carbon dioxide and water using energy from light. However, not all organisms use carbon dioxide as
5586-578: The Paleoarchean , preceding that of cyanobacteria (see Purple Earth hypothesis ). While the details may differ between species , the process always begins when light energy is absorbed by the reaction centers , proteins that contain photosynthetic pigments or chromophores . In plants, these proteins are chlorophylls (a porphyrin derivative that absorbs the red and blue spectrums of light, thus reflecting green) held inside chloroplasts , abundant in leaf cells. In bacteria, they are embedded in
5700-637: The light reaction of photosynthesis by using chlorophyll fluorometers . Actual plants' photosynthetic efficiency varies with the frequency of the light being converted, light intensity , temperature , and proportion of carbon dioxide in the atmosphere , and can vary from 0.1% to 8%. By comparison, solar panels convert light into electric energy at an efficiency of approximately 6–20% for mass-produced panels, and above 40% in laboratory devices. Scientists are studying photosynthesis in hopes of developing plants with increased yield . The efficiency of both light and dark reactions can be measured, but
5814-434: The light-independent (or "dark") reactions, the enzyme RuBisCO captures CO 2 from the atmosphere and, in a process called the Calvin cycle , uses the newly formed NADPH and releases three-carbon sugars , which are later combined to form sucrose and starch . The overall equation for the light-independent reactions in green plants is Carbon fixation produces the three-carbon sugar intermediate , which
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#17327655952205928-417: The palisade mesophyll cells where most of the photosynthesis takes place. In the light-dependent reactions , one molecule of the pigment chlorophyll absorbs one photon and loses one electron . This electron is taken up by a modified form of chlorophyll called pheophytin , which passes the electron to a quinone molecule, starting the flow of electrons down an electron transport chain that leads to
6042-417: The photosynthetic capacity of the leaf . C 4 plants can produce more sugar than C 3 plants in conditions of high light and temperature . Many important crop plants are C 4 plants, including maize , sorghum , sugarcane , and millet . Plants that do not use PEP-carboxylase in carbon fixation are called C 3 plants because the primary carboxylation reaction , catalyzed by RuBisCO, produces
6156-462: The photosystems , quantum efficiency and the CO 2 assimilation rates. With some instruments, even wavelength dependency of the photosynthetic efficiency can be analyzed . A phenomenon known as quantum walk increases the efficiency of the energy transport of light significantly. In the photosynthetic cell of an alga , bacterium , or plant, there are light-sensitive molecules called chromophores arranged in an antenna-shaped structure called
6270-437: The plasma membrane . In these light-dependent reactions, some energy is used to strip electrons from suitable substances, such as water, producing oxygen gas. The hydrogen freed by the splitting of water is used in the creation of two important molecules that participate in energetic processes: reduced nicotinamide adenine dinucleotide phosphate (NADPH) and ATP. In plants, algae, and cyanobacteria, sugars are synthesized by
6384-454: The reverse Krebs cycle are used to achieve the same end. The first photosynthetic organisms probably evolved early in the evolutionary history of life using reducing agents such as hydrogen or hydrogen sulfide, rather than water, as sources of electrons. Cyanobacteria appeared later; the excess oxygen they produced contributed directly to the oxygenation of the Earth , which rendered
6498-427: The supply chain can result in natural gas having a similar carbon footprint to other fossil fuels overall. Natural gas can be found in underground geological formations , often alongside other fossil fuels like coal and oil (petroleum). Most natural gas has been created through either biogenic or thermogenic processes. Thermogenic gas takes a much longer period of time to form and is created when organic matter
6612-548: The 19th century, natural gas was primarily obtained as a by-product of producing oil . The small, light gas carbon chains came out of solution as the extracted fluids underwent pressure reduction from the reservoir to the surface, similar to uncapping a soft drink bottle where the carbon dioxide effervesces . The gas was often viewed as a by-product, a hazard, and a disposal problem in active oil fields. The large volumes produced could not be used until relatively expensive pipeline and storage facilities were constructed to deliver
6726-406: The 20th century, it was increasingly referred to as simply "gas." In order to highlight its role in exacerbating the climate crisis , however, many organizations have criticized the continued use of the word "natural" in referring to the gas. These advocates prefer the term "fossil gas" or "methane gas" as better conveying to the public its climate threat. A 2020 study of Americans' perceptions of
6840-433: The CO 2 concentration in the leaves under these conditions. Plants that use the C 4 carbon fixation process chemically fix carbon dioxide in the cells of the mesophyll by adding it to the three-carbon molecule phosphoenolpyruvate (PEP), a reaction catalyzed by an enzyme called PEP carboxylase , creating the four-carbon organic acid oxaloacetic acid . Oxaloacetic acid or malate synthesized by this process
6954-722: The CSA conducted the first ever national agricultural census, of which the livestock census was an important component. For the Somali Region, the CSA generated estimated figures for the livestock population (cattle, sheep, goats, camels, and equids) and their distribution by commissioning an aerial survey. For the Korahe Zone, their results included: 6°45′N 44°30′E / 6.750°N 44.500°E / 6.750; 44.500 Natural gas Natural gas (also called fossil gas, methane gas , or simply gas )
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#17327655952207068-432: The US had peaked three times, with current levels exceeding both previous peaks. It reached 24.1 trillion cubic feet per year in 1973, followed by a decline, and reached 24.5 trillion cubic feet in 2001. After a brief drop, withdrawals increased nearly every year since 2006 (owing to the shale gas boom ), with 2017 production at 33.4 trillion cubic feet and 2019 production at 40.7 trillion cubic feet. After
7182-427: The US, over one-third of households (>40 million homes) cook with gas. Natural gas dispensed in a residential setting can generate temperatures in excess of 1,100 °C (2,000 °F) making it a powerful domestic cooking and heating fuel. Stanford scientists estimated that gas stoves emit 0.8–1.3% of the gas they use as unburned methane and that total U.S. stove emissions are 28.1 gigagrams of methane. In much of
7296-523: The United States begins with localized use. In the seventeenth century, French missionaries witnessed the American Indians setting fire to natural gas seeps around lake Erie, and scattered observations of these seeps were made by European-descended settlers throughout the eastern seaboard through the 1700s. In 1821, William Hart dug the first commercial natural gas well in the United States at Fredonia, New York , United States, which led in 1858 to
7410-419: The action spectrum is blue-green light, which allows these algae to use the blue end of the spectrum to grow in the deeper waters that filter out the longer wavelengths (red light) used by above-ground green plants. The non-absorbed part of the light spectrum is what gives photosynthetic organisms their color (e.g., green plants, red algae, purple bacteria ) and is the least effective for photosynthesis in
7524-521: The atmosphere. Although there are some differences between oxygenic photosynthesis in plants , algae , and cyanobacteria , the overall process is quite similar in these organisms. There are also many varieties of anoxygenic photosynthesis , used mostly by bacteria, which consume carbon dioxide but do not release oxygen. Carbon dioxide is converted into sugars in a process called carbon fixation ; photosynthesis captures energy from sunlight to convert carbon dioxide into carbohydrates . Carbon fixation
7638-702: The bottoms of the gashouse ovens was often used for roofing and other waterproofing purposes, and when mixed with sand and gravel was used for paving streets. Huge quantities of natural gas (primarily methane) exist in the form of clathrates under sediment on offshore continental shelves and on land in arctic regions that experience permafrost , such as those in Siberia . Hydrates require a combination of high pressure and low temperature to form. In 2013, Japan Oil, Gas and Metals National Corporation (JOGMEC) announced that they had recovered commercially relevant quantities of natural gas from methane hydrate. The image below
7752-483: The carboxysome quickly sponges it up. HCO 3 ions are made from CO 2 outside the cell by another carbonic anhydrase and are actively pumped into the cell by a membrane protein. They cannot cross the membrane as they are charged, and within the cytosol they turn back into CO 2 very slowly without the help of carbonic anhydrase. This causes the HCO 3 ions to accumulate within the cell from where they diffuse into
7866-491: The carboxysomes. Pyrenoids in algae and hornworts also act to concentrate CO 2 around RuBisCO. The overall process of photosynthesis takes place in four stages: Plants usually convert light into chemical energy with a photosynthetic efficiency of 3–6%. Absorbed light that is unconverted is dissipated primarily as heat , with a small fraction (1–2%) reemitted as chlorophyll fluorescence at longer (redder) wavelengths . This fact allows measurement of
7980-409: The conditions of non-cyclic electron flow in green plants is: Not all wavelengths of light can support photosynthesis. The photosynthetic action spectrum depends on the type of accessory pigments present. For example, in green plants , the action spectrum resembles the absorption spectrum for chlorophylls and carotenoids with absorption peaks in violet-blue and red light. In red algae ,
8094-654: The decayed organisms originally obtained from the sun via photosynthesis is stored as chemical energy within the molecules of methane and other hydrocarbons. Natural gas can be burned for heating, cooking, and electricity generation . Consisting mainly of methane, natural gas is rarely used as a chemical feedstock . The extraction and consumption of natural gas is a major industry. When burned for heat or electricity , natural gas emits fewer toxic air pollutants, less carbon dioxide, and almost no particulate matter compared to other fossil and biomass fuels. However, gas venting and unintended fugitive emissions throughout
8208-482: The developed world it is supplied through pipes to homes, where it is used for many purposes including ranges and ovens, heating / cooling , outdoor and portable grills , and central heating . Heaters in homes and other buildings may include boilers, furnaces , and water heaters . Both North America and Europe are major consumers of natural gas. Photosynthesis Photosynthesis ( / ˌ f oʊ t ə ˈ s ɪ n θ ə s ɪ s / FOH -tə- SINTH -ə-sis )
8322-514: The diagram), a chemiosmotic potential is generated by pumping proton cations ( H ) across the membrane and into the thylakoid space . An ATP synthase enzyme uses that chemiosmotic potential to make ATP during photophosphorylation , whereas NADPH is a product of the terminal redox reaction in the Z-scheme . The electron enters a chlorophyll molecule in Photosystem I . There it
8436-446: The eastern US in the late 19th and early 20th centuries were simple by-product coke ovens that heated bituminous coal in air-tight chambers. The gas driven off from the coal was collected and distributed through networks of pipes to residences and other buildings where it was used for cooking and lighting. (Gas heating did not come into widespread use until the last half of the 20th century.) The coal tar (or asphalt ) that collected in
8550-446: The economic and environmental benefits of floating liquefied natural gas (FLNG). There are currently projects underway to construct five FLNG facilities. Petronas is close to completion on their FLNG-1 at Daewoo Shipbuilding and Marine Engineering and are underway on their FLNG-2 project at Samsung Heavy Industries . Shell Prelude is due to start production 2017. The Browse LNG project will commence FEED in 2019. Natural gas
8664-505: The equation for this process is: This equation emphasizes that water is both a reactant in the light-dependent reaction and a product of the light-independent reaction , but canceling n water molecules from each side gives the net equation: Other processes substitute other compounds (such as arsenite ) for water in the electron-supply role; for example some microbes use sunlight to oxidize arsenite to arsenate : The equation for this reaction is: Photosynthesis occurs in two stages. In
8778-421: The equivalent of 2.4 heads of livestock. 28.2% of the population is in non-farm related jobs, compared to the national average of 25% and an average of 28% for pastoral Regions. 18% of all eligible children are enrolled in primary school, and 4% in secondary schools. 100% of the zone is exposed to malaria , and none to Tsetse fly . The memorandum gave this zone a drought risk rating of 761. On 5–23 November 2003,
8892-518: The evolution of complex life possible. The average rate of energy captured by global photosynthesis is approximately 130 terawatts , which is about eight times the total power consumption of human civilization . Photosynthetic organisms also convert around 100–115 billion tons (91–104 Pg petagrams , or billions of metric tons), of carbon into biomass per year. Photosynthesis was discovered in 1779 by Jan Ingenhousz . He showed that plants need light, not just air, soil, and water. Photosynthesis
9006-582: The first stage, light-dependent reactions or light reactions capture the energy of light and use it to make the hydrogen carrier NADPH and the energy-storage molecule ATP . During the second stage, the light-independent reactions use these products to capture and reduce carbon dioxide. Most organisms that use oxygenic photosynthesis use visible light for the light-dependent reactions, although at least three use shortwave infrared or, more specifically, far-red radiation. Some organisms employ even more radical variants of photosynthesis. Some archaea use
9120-441: The first step of the Z-scheme , requires an external source of electrons to reduce its oxidized chlorophyll a reaction center. The source of electrons for photosynthesis in green plants and cyanobacteria is water. Two water molecules are oxidized by the energy of four successive charge-separation reactions of photosystem II to yield a molecule of diatomic oxygen and four hydrogen ions. The electrons yielded are transferred to
9234-497: The formation of the Fredonia Gas Light Company . Further such ventures followed near wells in other states, until technological innovations allowed the growth of major long distance pipelines from the 1920s onward. By 2009, 66,000 km (16,000 cu mi) (or 8%) had been used out of the total 850,000 km (200,000 cu mi) of estimated remaining recoverable reserves of natural gas. In
9348-461: The fuel found that, across political identifications, the term "methane gas" led to better estimates of its harms and risks. Natural gas can come out of the ground and cause a long-burning fire. In ancient Greece , the gas flames at Mount Chimaera contributed to the legend of the fire-breathing creature Chimera . In ancient China , gas resulting from the drilling for brines was first used by about 400 BC. The Chinese transported gas seeping from
9462-435: The gas needs to be cooled down and compressed, as the friction in the pipeline causes the gas to heat up. Many existing pipelines in the US are close to reaching their capacity, prompting some politicians representing northern states to speak of potential shortages. The large trade cost implies that natural gas markets are globally much less integrated, causing significant price differences across countries. In Western Europe ,
9576-517: The gas pipeline network is already dense. New pipelines are planned or under construction between Western Europe and the Near East or Northern Africa . Whenever gas is bought or sold at custody transfer points, rules and agreements are made regarding the gas quality. These may include the maximum allowable concentration of CO 2 , H 2 S and H 2 O . Usually sales quality gas that has been treated to remove contamination
9690-896: The gas to consumer markets. Until the early part of the 20th century, most natural gas associated with oil was either simply released or burned off at oil fields. Gas venting and production flaring are still practised in modern times, but efforts are ongoing around the world to retire them, and to replace them with other commercially viable and useful alternatives. In addition to transporting gas via pipelines for use in power generation, other end uses for natural gas include export as liquefied natural gas (LNG) or conversion of natural gas into other liquid products via gas to liquids (GTL) technologies. GTL technologies can convert natural gas into liquids products such as gasoline, diesel or jet fuel. A variety of GTL technologies have been developed, including Fischer–Tropsch (F–T), methanol to gasoline (MTG) and syngas to gasoline plus (STG+). F–T produces
9804-526: The ground in crude pipelines of bamboo to where it was used to boil salt water to extract the salt in the Ziliujing District of Sichuan . Natural gas was not widely used before the development of long distance pipelines in the early twentieth century. Before that, most use was near to the source of the well, and the predominant gas for fuel and lighting during the industrial revolution was manufactured coal gas. The history of natural gas in
9918-442: The higher-molecular weight hydrocarbons to produce natural gas with energy content between 35–39 megajoules per cubic metre (950–1,050 British thermal units per cubic foot). The processed natural gas may then be used for residential, commercial and industrial uses. Natural gas flowing in the distribution lines is called mid-stream natural gas and is often used to power engines which rotate compressors. These compressors are required in
10032-399: The interior of a cell, giving the membrane a very large surface area and therefore increasing the amount of light that the bacteria can absorb. In plants and algae, photosynthesis takes place in organelles called chloroplasts . A typical plant cell contains about 10 to 100 chloroplasts. The chloroplast is enclosed by a membrane. This membrane is composed of a phospholipid inner membrane,
10146-433: The interior tissues of a leaf, called the mesophyll , can contain between 450,000 and 800,000 chloroplasts for every square millimeter of leaf. The surface of the leaf is coated with a water-resistant waxy cuticle that protects the leaf from excessive evaporation of water and decreases the absorption of ultraviolet or blue light to minimize heating . The transparent epidermis layer allows light to pass through to
10260-612: The largest proven gas reserves. Sources that consider that Russia has by far the largest proven reserves include the US Central Intelligence Agency (47,600 km ) and Energy Information Administration (47,800 km ), as well as the Organization of Petroleum Exporting Countries (48,700 km ). Contrarily, BP credits Russia with only 32,900 km , which would place it in second, slightly behind Iran (33,100 to 33,800 km , depending on
10374-434: The light reaction, and infrared gas analyzers can measure the dark reaction . An integrated chlorophyll fluorometer and gas exchange system can investigate both light and dark reactions when researchers use the two separate systems together. Infrared gas analyzers and some moisture sensors are sensitive enough to measure the photosynthetic assimilation of CO 2 and of Δ H 2 O using reliable methods . CO 2
10488-433: The light-independent reaction); at that point, the path of that electron ends. The cyclic reaction is similar to that of the non-cyclic but differs in that it generates only ATP, and no reduced NADP (NADPH) is created. The cyclic reaction takes place only at photosystem I. Once the electron is displaced from the photosystem, the electron is passed down the electron acceptor molecules and returns to photosystem I, from where it
10602-432: The more common types of photosynthesis. In photosynthetic bacteria, the proteins that gather light for photosynthesis are embedded in cell membranes . In its simplest form, this involves the membrane surrounding the cell itself. However, the membrane may be tightly folded into cylindrical sheets called thylakoids , or bunched up into round vesicles called intracytoplasmic membranes . These structures can fill most of
10716-439: The most efficient route, where it will have the highest probability of arriving at its destination in the minimum possible time. Because that quantum walking takes place at temperatures far higher than quantum phenomena usually occur, it is only possible over very short distances. Obstacles in the form of destructive interference cause the particle to lose its wave properties for an instant before it regains them once again after it
10830-433: The natural gas can be transported. Natural gas extracted from oil wells is called casinghead gas (whether or not truly produced up the annulus and through a casinghead outlet) or associated gas. The natural gas industry is extracting an increasing quantity of gas from challenging, unconventional resource types : sour gas , tight gas , shale gas , and coalbed methane . There is some disagreement on which country has
10944-498: The organic compounds through cellular respiration . Photosynthesis plays a critical role in producing and maintaining the oxygen content of the Earth's atmosphere, and it supplies most of the biological energy necessary for complex life on Earth. Some bacteria also perform anoxygenic photosynthesis , which uses bacteriochlorophyll to split hydrogen sulfide as a reductant instead of water, producing sulfur instead of oxygen. Archaea such as Halobacterium also perform
11058-410: The organism's metabolism . Photosynthesis and cellular respiration are distinct processes, as they take place through different sequences of chemical reactions and in different cellular compartments (cellular respiration in mitochondria ). The general equation for photosynthesis as first proposed by Cornelis van Niel is: Since water is used as the electron donor in oxygenic photosynthesis,
11172-556: The photosynthetic system. Plants absorb light primarily using the pigment chlorophyll . The green part of the light spectrum is not absorbed but is reflected, which is the reason that most plants have a green color. Besides chlorophyll, plants also use pigments such as carotenes and xanthophylls . Algae also use chlorophyll, but various other pigments are present, such as phycocyanin , carotenes , and xanthophylls in green algae , phycoerythrin in red algae (rhodophytes) and fucoxanthin in brown algae and diatoms resulting in
11286-441: The pores of the gas reservoir get depleted. One method to deal with this problem is to re-inject dried gas free of condensate to maintain the underground pressure and to allow re-evaporation and extraction of condensates. More frequently, the liquid condenses at the surface, and one of the tasks of the gas plant is to collect this condensate. The resulting liquid is called natural gas liquid (NGL) and has commercial value. Shale gas
11400-476: The production of amino acids and lipids . In hot and dry conditions , plants close their stomata to prevent water loss. Under these conditions, CO 2 will decrease and oxygen gas , produced by the light reactions of photosynthesis, will increase, causing an increase of photorespiration by the oxygenase activity of ribulose-1,5-bisphosphate carboxylase/oxygenase (RuBisCO) and decrease in carbon fixation. Some plants have evolved mechanisms to increase
11514-486: The relationship between the two can be complex. For example, the light reaction creates ATP and NADPH energy molecules , which C 3 plants can use for carbon fixation or photorespiration . Electrons may also flow to other electron sinks. For this reason, it is not uncommon for authors to differentiate between work done under non-photorespiratory conditions and under photorespiratory conditions . Chlorophyll fluorescence of photosystem II can measure
11628-462: The respective organisms . In plants , light-dependent reactions occur in the thylakoid membranes of the chloroplasts where they drive the synthesis of ATP and NADPH . The light-dependent reactions are of two forms: cyclic and non-cyclic . In the non-cyclic reaction, the photons are captured in the light-harvesting antenna complexes of photosystem II by chlorophyll and other accessory pigments (see diagram at right). The absorption of
11742-479: The site of carboxylation in the chloroplast, to replace Ci. CO 2 concentration in the chloroplast becomes possible to estimate with the measurement of mesophyll conductance or g m using an integrated system. Photosynthesis measurement systems are not designed to directly measure the amount of light the leaf absorbs, but analysis of chlorophyll fluorescence , P700 - and P515-absorbance, and gas exchange measurements reveal detailed information about, e.g.,
11856-550: The source). It is estimated that there are about 900,000 km of "unconventional" gas such as shale gas, of which 180,000 km may be recoverable. In turn, many studies from MIT , Black & Veatch and the US Department of Energy predict that natural gas will account for a larger portion of electricity generation and heat in the future. The world's largest gas field is the offshore South Pars / North Dome Gas-Condensate field , shared between Iran and Qatar. It
11970-654: The third peak in December 2019, extraction continued to fall from March onward due to decreased demand caused by the COVID-19 pandemic in the US . The 2021 global energy crisis was driven by a global surge in demand as the world quit the economic recession caused by COVID-19, particularly due to strong energy demand in Asia. Because of its low density, it is not easy to store natural gas or to transport it by vehicle. Natural gas pipelines are impractical across oceans, since
12084-468: The three-carbon 3-phosphoglyceric acids directly in the Calvin-Benson cycle . Over 90% of plants use C 3 carbon fixation, compared to 3% that use C 4 carbon fixation; however, the evolution of C 4 in over sixty plant lineages makes it a striking example of convergent evolution . C 2 photosynthesis , which involves carbon-concentration by selective breakdown of photorespiratory glycine,
12198-412: The transmission line to pressurize and repressurize the mid-stream natural gas as the gas travels. Typically, natural gas powered engines require 35–39 MJ/m (950–1,050 BTU/cu ft) natural gas to operate at the rotational name plate specifications. Several methods are used to remove these higher molecular weighted gases for use by the natural gas engine. A few technologies are as follows: In
12312-424: The ultimate reduction of NADP to NADPH . In addition, this creates a proton gradient (energy gradient) across the chloroplast membrane , which is used by ATP synthase in the synthesis of ATP . The chlorophyll molecule ultimately regains the electron it lost when a water molecule is split in a process called photolysis , which releases oxygen . The overall equation for the light-dependent reactions under
12426-408: The water-oxidizing reaction (Kok's S-state diagrams). The hydrogen ions are released in the thylakoid lumen and therefore contribute to the transmembrane chemiosmotic potential that leads to ATP synthesis . Oxygen is a waste product of light-dependent reactions, but the majority of organisms on Earth use oxygen and its energy for cellular respiration , including photosynthetic organisms . In
12540-502: The worldwide extraction, access to natural gas has become an important issue in international politics, and countries vie for control of pipelines. In the first decade of the 21st century, Gazprom , the state-owned energy company in Russia, engaged in disputes with Ukraine and Belarus over the price of natural gas, which have created concerns that gas deliveries to parts of Europe could be cut off for political reasons. The United States
12654-462: Was emitted, hence the name cyclic reaction . Linear electron transport through a photosystem will leave the reaction center of that photosystem oxidized . Elevating another electron will first require re-reduction of the reaction center. The excited electrons lost from the reaction center ( P700 ) of photosystem I are replaced by transfer from plastocyanin , whose electrons come from electron transport through photosystem II . Photosystem II, as
12768-494: Was invented in Saudi Arabia in the late 1970s, ending any necessity for flaring. Satellite and nearby infra-red camera observations, however, shows that flaring and venting are still happening in some countries. Natural gas is used to generate electricity and heat for desalination . Similarly, some landfills that also discharge methane gases have been set up to capture the methane and generate electricity. Natural gas
12882-567: Was recovered in the course of recovering petroleum could not be profitably sold, and was simply burned at the oil field in a process known as flaring . Flaring is now illegal in many countries. Additionally, higher demand in the last 20–30 years has made production of gas associated with oil economically viable. As a further option, the gas is now sometimes re- injected into the formation for enhanced oil recovery by pressure maintenance as well as miscible or immiscible flooding. Conservation, re-injection, or flaring of natural gas associated with oil
12996-535: Was the Somali (98.75%); a similar proportion spoke Somali (99.13%) as their primary language. Only 14,256 or 5.88% were literate. According to a May 24, 2004 World Bank memorandum, 2% of the inhabitants of Korahe have access to electricity, this zone has a road density of 6.1 kilometers per 1000 square kilometers, the average rural household has 0.7 hectare of land (compared to the national average of 1.01 hectare of land and an average of 2.25 for pastoral Regions) and
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